Document Xzqp768kmEBdK6DN6b1w0wO0x

rlnoLTH <1, EN't LRUNMENTAL 3G lE'JCES INFORMATION OEM EK Cl'UUPA T .1. L; PiL. HrALTH : Kft. |,',i i'ii.v F.LPCR. : AGE i o / /E? ' : 1 ? 8 6 VINYL C H!.. Li f ' P E i': l N!, ; A. AI N :!1 G ! i;; i N I GTR AI N 1 r*GT -A 1 M J Nb i r- .-i l N [ :v v i R AINI:!;v I A A v' N'i A.. N v : H L L, REPQft'T DOES NOT SUBS I' ITUTE FOR AN i-i SOS AND IS NOT' IN TENTED L INCLUSION IN WRITTEN UmCAKD COi'.NbNICATION PROGRAM MANUALS IT IS DESIGNED AS A REFERENCE TO HELP PRESENTERS PREPARE -Oft AND RE SEN'! OCCUPATIONAL HEALTH/RTK RAINING SESSIONS USING P ! CCS i P ; q i q g r a p h i c Chemical. t;o;rrtm p. i ca t i on Systauw MATERIALS P i'OCS-ha ed 'trainin'? a - . inci. udi introductory y r deorapeo, -1 a r h e a a p r n j r f j q n t ran s p a r e n c i e s , a n d F` IC C 3 a a? + s o n = p c i f i c c;! c a !, iiia ter i a i.-s and r. he m I c a *. groups may be obtained b eaLLing Octavia Cabsy, H N E 3 Information Center, < 5 i 7 > O-36-0244 (overheads a I. ac available via TINE reporting r/itesi) , F'reaenter ; r a i n i ng teg. T i* -ii I r T h e T r a 1 ner .4 o r 1/ ^ h o p s } is a i. w o availaa !. e, t'l L,, L. V' CCS PRE.LP NTFP S SHOULD K in. A 0 ,r pj'-"? UNDERSTAND Ti-,I S REi-'UK " BEFii'FE C U Nt)UC v r ni " " m r:-1 GY EE T R AINING Q-' TH T p MATERI Al. * 1 n . * } Tor maf i on i n t his- r e v L i ,j * r a n g e d i n t h e a tii e s g* i. u G? VIC 0 rf 0i n Pic CS Ira ini n -j s s t s * T i t i. e s (-? Q rn the PICCS sets have ".? r, l. n f J` e a i n t o i: i i s report to gu i do /**--* rn 3 r eport and the PICCS ae r-i of u. a i. a o Vi v i'i i s m a t e rial P r e c f; e n o m t i -A b i. e w ft A 7` ING t i o n s +'o" P r o t e o t i '-k X ; j LI ' 4 ill ovrt and met hoc S &fJ5c',i on i vi f o r ma l i on* AC 1U r' 1T* rC**.L riON REQUIRENE NTS ARE SET UNITS a Vi d ni ay vary % O fit W !`i ^ * from the reco mmenda r i '.!!'[ Ti due to such consi derat ians as physical surroundings avid other c h e fii i c a m a t e rial s p r s e n t * s i'i t BY 00 H O -- cr\ GO 00 iccspiccspiccspiccspiccspiccspj:ccspiccspiccspiccspiccspicc;s? iccspiccj?p ccs m :: >.- x- at -st x -wat at at at at * : at # at at at at at at a* x- at at at at -x- at at at at at at st at at at -x x at at at at at : at at at . at at at x at at at at at at -y- a*- at :t G E N E H, A L x : xxatxx x atxxatxxxatatatatatatxat xxioxxxvatatxx'jtxata; at at at x at x x at at-x at at at at-at at at at-at x D 0 Y ft e g , _-> t o r y N u m b e r : D R - 01 1 4 - i 9 3 6 NALLS w it x-x-x x-x C o m m o n ; VIN Y L C H i_ 0 R. X D E Y N 0 N Y NS: C H L 0 ft G* E':' H E N E VCM m c n o c k ;:.i ft o e t h y l e n e 33 0) oroo <o Copyright 'i987 The Dow ChemicaL a ny -th ,! Hr -,i(- {'( -/t- *V* V -j{> .Jf. ,irf. ,`fi -)L :,4 ft ft. ft ft .)( ft. .)(; .J,. ft V it* ft ft -ft .) .y; ft ft ft. ft ft ft ft ft ft ft AfL - ; ft, ft ,}t, ft ft. .ft ft .Ji|. ft, ft ft i:: ..CCS PAGE 1: " BASIC liANDLING PRECAUTIONS" !> i,:: -.`t- vV vs -K* -X* ,'v X X* W -'I *j`: vO X- X- X; X X X: *X* `X* X* X* X* X* X X* -Is' *k m,{' X X X X* X* X* X X X X X X ,,11, ; : X X: X X X- CHEMICAL AND PHYSICAL PROPERTIES ; h : o .Jeta comp: Led from various sources and not verified* X X X X ;,f* P E FRANCE: GAS < 0 0 L 0 R!... E S S > at TRADEMARK OP THE DOW CHEMICAL COMPANY RESTR liLTED DOW ONLY HE.Ai.TH 5. ENVIRONMENTAL SCIENCES INFORMATION . CCUPATIONAL. HEftL'T H IRA THING REPORT BR--01 1 > - 1 9S6 VINYL CMLOR 1 D L (LLECULAR WEIGHT: os *5 .LING POINT ' -13*8 C HALTING OINT: -133*71 8 VA!1'.j!:f. PE G ..SORE': 2330 tor r 8 20 C MAX AIRBORNE CONC 2*15 :,:LaSH PGINI. -78 L (0 C> 8 T h BILIT Y /REA C TI y IT Y : fii ay pr a d u c s p e r o * i e s G.OOR DESCRIPTION: sweet .. etherea:. thresaold varies gi WARNING PROPERTIES -1 d o i i j i /;f l. e * i * a 1 e w a r n ; n g o* r e a c e s s f v e e x p o s u * s * - Reported odor t n r esho I. ds vary gieatly (300-4000 f-- ;> f i'ER PAlE 2 ' 2/09/87 ST0I6I8I9 11 GENERAL HAZARDS " o rent i al heal th effec ts This section presents a general, sufiinny. ; y of the hazard o: the subject chemlcaL or irtixture to the eyes or skin and by inhalation or i ages ! ion. The nazard Levels given are Ddsed upon the Levels of c'-'-v expose re > h a,r fnight reasonably occur in a cent retied industrial, or occupat ienv. Vi.' t i -jo <3 with properly trained adult workers.. Accjaents and other rare 'or severe c i r earns t a vices were not considered in assigning these general, ht-isra Levels., since any hour i >: a L can produce extreme da in age if trie dose is sufficiently high* This section is intended only as a general h <:> 7 r a g u i d e f o r p r u :.! e n t w o v k p r a c i i c e c o n d i i o n s . JJ 8 (/> oro o <cno iC0N REPRESENTATION: ;; i a { o r t e xposure of the eyea can cauze inj u > b u t generally '::: G V G V `if s i n g 1. G o r P e r- fii a n e n t n *=- h G !' .1.. i. xposuTe u re * of the sirin to tr.s 1. i m i d c a n c a ii se i nj u v y an e r a 1. Ly n o t o f s e v e r e o r p e r rn a n a nt nature* s i r. g 1. ii- n or , xPosure by i nha i. a t i o n fu a y c a u s e s eve r e i n j u r y b u t no t bu t n e r a L l y VI ot O f: a permanent nature. u iting!. s h O " t e x p o s r e i:r y n g e s t i o n g a n a r a i. 1 y i. G J> s 0X P 0 i_ re is p a r t i c u !. a r L y i n t e nse * w i 1 i. not c au se i nj u r y z a rd i. 3 *d i f ! C at ions snown by icon s above baseo upon e Is o r ''ii a t t n 9 i VS i'l ii e L o w u n d e i- " P IC C 3 Page 2J*) of " A C 0 E P T E D E X P 0 3 U R E i... IMIT 8 inyl chi. or; rle: ACGIi-I i" L V is 5 ppm, Aia* 03! 7 Ri-iOEilAAK OF THE DOW CHEMICAL COMPANY R. E 3 f R (0 f E D - v 0 W U 8 E >j N L Y r....... , TH & ENVIRONMENT 'c EC I /E j! i-i.-i CEE OCCUF A ! I ONAL i"!EAL'. i . ' r< i N1NtV F< 2P0R t V !. id Y... .! L. u lt~l. i. i.' i- I" AGE 2 12/09/87 rep r t r . , * . i i.. V tiuns *'Uf't : Th r eo p :>!. d L I m i + V's L u ? T i me-we ; 9:V; d Aver a ,;e c ore on i ,* ' i on ror a pc riti-'.i S-hr. "!o:' /:iay am.:; a nG'-h r ^ weeK to which . aari. / i , 0 r !< e I s mi y b v? r ; fir u'j v-`` d L y 0 xposeo, da y t ; t . Li \t .. w 1 t n 0 u d V*;? r e 0? f f e c t * LL1L1NG !! snec i a i. T L V c> n c e n t r a > 1 0 n t fi [ ::: n 0 u 1. d v, 0 : 0 - y X c & s (j e d vein 1 ns t an fa neon :i 1. y * STc.L : A ; ,**' a:: i a i. I L. V 0 011 c O' 0 t r a t 1 0,1 0 wh i c h w l r #%r/* -T- C '3 Ti / vT1 X {" e in 0 a !"= n t i nuou sly for a h 0 r t e r i 0 d 0 f t i i n 0 w i 'l' n 0 i ?>u f f e r : 1"! g f r 0 m i / * ^ 1 l S*l t i 0 n , t 2 c it ! (Z* 5 \1 0 T ! r r 'v 'v' 0 r s i b i, e t 1 4L' 'I *i vf 0 -1* , c7 (0 j r\ a r c o s i 0 s s u f f i c i e n t l; 0 i n c r- e .'?! L-? t. 1 if Ci i. I l"i 0 0 d O !' vi"i C C ! d Y\ "t a i. i r. j u !' i ;ti p d 1 r =y L f -rest: u e , or recuce W O i" K e 111 c i <' n c y P r ov 1 TL.V,,TU A l 'z> i 1 of ex ceeiied* i"' E e T frt i ss 1 b e ;; p 0 s u r e ;... i fll 1 t C O ! i V./ } i XS i- a t i t r; u su a '. v me a t, i rt 9 cS wo r j/ ah i f FUA. W'EEL Uor,- ; l a c: e Er-v i r on.men ..-j | v i TL V _Tl-j.A * 3a L. eve i. nean Ts 9 the r= <a (iie? a s I i"i iju d v r i a 1 c-ne Gu 1 J 0 , Vi T fi ; . , v, ^ era,,,. Dew 0 i'j r * 1 W f"! exposure to a i r b 0 r n 0 c 0 n c t?n t r a t i 0 ns l r W *v T v a l u e 0 f T L V s , U t:.L. V- . P fc. r IMG s are r icalLy noted others, is -i 1 d 0 l 1 ft 0 f f"> t of mat 0 r i a Is* The > ffCI t.i .J' .rL.-- u... w unless X- X- X :$ :n ;i--y. .*. y if X X X X' C i< K- V- X if X -X -X- if -A- if if if h if ri X X -X if -X if -X- X- if X- if -X -X if -X X it it it it X X it X- -X- X- if it X: it if it P 1 C C S Y-HI Lv C. "POTENTIAL EFFECTS OF EXPOSURE TO HAZARDOUS AMOUNTS' X X X X 4v X- X X v * :v X !- X X- -a -iff' -X' X X X- X X X X -}> X X* X- X X X X- X X X X X- X* X K* X* X- X X X : *X- : X* X X44 44 >? X X- >( X vt X* X X X 44 -X X This section. Includes possible adverse effects which o u. L d occur i f i s ma t a :. .a not h a n d L ein the recommended manner* 3D flo CO o fo 0 (O 01 CO -H O cn oo ro Q If the l i ,:l u i d under pressure were to contact the. eve severe injury to cornea and soft t1ssues might result l R - 'i ,! * If liquid contacts eye. evaporation :iuiy cause f r os t i t e-1 ype injury rapid coo L ing * the due to. i-k IN EFFECTS If the i. i`-i.u . d funder pressure/ were to c0ntac a1; i r a f r osi-h i t a `type burn could resu L t l FU-; > * Si--, i it absorpt iori uni ike! / since mater i a l is a gas a rroc mi amp e r a i u ' e * If liquid contacts skin, evaporation may cause r a p i d c o o i. m3, d iii t " b 1 t e t v p e i Vi J u r / d u e b k i Vi a i? s o ; p t i i_;* i i s u Vi i. i k e l y du e t o p h y s1 0 a I. p r op e r t 1 e1 A A D E M A P. K G I- E H E D n W C H E M ]' C A L rN' ... RESTRICTED DOW USE GNL f GAi. IN A !!iiV I R0NiiENTAL SCIENCES IN;-CRM A FI ON CCA'. SR 01 !.'i'FIUNAL i-!F_'A!: AG HE RCA r R ! ' 1 Vljo VINYL. 0HL. GAli : P P j.' "j j ........... ....... . T I' ORAL. ,7.r ! C. *-* f s 11 i.i 7 O o iVt r xmp e r a t ii r e c n I. ! t 1 f' " '* 1 n g e a; ; r i - ! i> os s e i i t . a !. 1. y n i. a f' i ; s u T: l .< e L y `iiu. Kw t 'j P" ..* -- ----- - ------------ i. T!:;. INHA L r{ ! *L ON c. h 1" ir '...- i H CH i c 3 a S ; O : J Z : f. ; V-.J ,i^ (ri r\ h 0 . K e 1. ' h o c a CO ^ < - '/ > : i . n. a I. per. me vi t s u i. i m ! t 0 d t O ii a r l t e r w exp og; v 0 .b..- +\ Cl vch o - j p O T G 1 v a f y i vi g b a t s e n 150 ''OO and 400 ,e>oo p p in l R - K-3 , R.--4 , R-5 , ft-6 R-7 , iX ":2 > cn i. n :! ; c e ; b- gu ; visa p i gs 7 ri ij i:.. i t s a i". d -; G gs a n e- is r 1 s s i a , ci .5 e n ri 7 r rj [ -- C -'ii 7 -A j Vi Q a r r h y : h m i as and La r, a 1. e l" f s c ' i.'.! o r 0 c s e r v e d i i'i t h i s r ri i'i ge of OO o n s u . e bu f v'- o r e . s . a ri t o f 9 ri ' J ri ` i i.) 1. fg y w ri `r- :riO t 0 d 0 7/ " d 0 7 C O vi j e s t f V 0 her.or rha g i c c h a ; g e ai i n i. u i'i g L i v e ' n Ci i< dn eyai on fata1, eve n t s <"* ,,J O_ i; r i. if G 5 ' s a r e :r P C'.> v : e d a s f . 1. O Iw S> : i l Z t -f " ' ''' , t'ff 1n mice, i 50,0 0 0 ! * 7 3 ? :i ,, a n (TO _ c30,000 ? p i n g .j i n e a g> i gs 3 Vi d i a ,000 i '\ r anbil-s (R--32, . I ne P r i ilia r y v.i c '.a t e P / ,'* ! G- O g i ca .; .i- r_ ;. f v C T 0 d e p v s ir a i ov i," '!' r. h 0 C e n t r v r. 0 r V .7' u <s. :: YS . I'M'l i oh be 9 i :' o c u r a r c \t n c 0 i'i t r -:i ".' ; O i'i S C f o , 0 v G 1 0,0 C vv p p m * V; ..i m a n s f' R - 7 ) * " !'.^e 'i> "j ci C c i d e'. i i a i. i vi K 0- T r i a L ;' f a 1 ! r i 0 s have been repo r t e d ' f)a ; z 1 je r : n f( - ) , T i'i Liv 7 11 V 0 "*) 0 0 fi .>. gge :i T i O i i s e !' ! de !. a yed ca t~ , no gen ! C r a -.i: p o la ss '!' I .. i,W i V: -*'n3 := :r : v e a c u f e e x osures 1 P. ~ 9) * - A s i n g Le !:; r i 0 f ( m . . i u i'ii ) ' V5H a fat; O Vi e X p O 0 V. re to e ii s i i y at r "i t. 0 C . .. s ;; ". r a i' { C`*`i a iiia/ caus..v .b 0 r i o u s ri *,! vs; V 0 f f 0 0 iT -ri , eve v ** J F JV k|* S ! and .! .,1* Gl... !. * sym p o:ns of ex 7 0 "ii> '> i V 0 ,{-4 xposid r 0 m ay be anes theric or n a r o: o i' c ,-j V i d F t o in s -.j " e x C tc S . '.& 0 x p c- s u r 0 in ay i3e central, ne T' VO j s s y s t 0 frt |3 T f e c. i; LOGHRON L' C F F C IS . a r k " jr.1. o t 3 i. .'E-iO,1 c omiu *. e d rspe^i tea exposure s t u d : e on a n i f- 3 .. s for V h r - / >:l j y , c- days/week for 4*5 to 6 m o n : h s .. At 5 0 0 ppm for s "homed increased L i v ( me.3 r t s and h i s l op a h t r- i. o g y .. At 1 0G end 2 GO ppm ratt i= x; owed t nc ' ev ::: e d !. ;voi' me. gn1::; j'it no i-icahnacn: vrgi rei swwe er reeoobbse'7.rrvve0d in dogs -and gu i 5303 pigs. A!.:, P in ! o r- 6 ill D n T h ^t 1 hr tha r a y a t i Vf P * `v* 0 7' e o b s e r ri 1 0d j0 f V ri G L 0 d and s i nee the y m e r >3) i i Q t 6 -- 3 <v; 0 i`. '.:> i ( and Vi t h expo<s= u* re0s cc ee aa sSet'dd** S3eeee WC, GNJC sec: ion al.se* C..i ,L. ,,' i - P o sure m .aa y c ari ui.,i sV e0 l./ ./ j-' i.J :: tA i M' S............................. ri ^ri t;... V0 in e vi il. uU nVi gq .,. 1!.. ii v11e,7.*. . 7reper V . . d t a n d i: ; dn e > s f f e c + s . vascular system, pP ari :7* :t i cc uu uL ri rr ii.. yy ii nn ttbhs extremities of vne body 30 flo CO i K i'iA C oc ii c ST I C S / h T A B G i... i! 3 ii Oro o a. <> Numerous sre, Lee indicate that probac. y a reactive metabol. its, no:- v in"/:, c...rid.r p.-;. r 2*2, is r^rparmLiU i ts " ,<icity* Although some inhales |i' i n'/i chloride i =; excreted u nc h a n ge cl , depen ding on the dose, a varying |,i:vi t . meW.;,. ' :od* The metabci. ism of :nyl. c h 1. o " i has been the subject . i: );;!.! .' *f"vr .- *., tJHf i-\i" < 1 coccha * - -J. 4- ^ / O '.Z- V I M 1i.. CH!. iti 4 O 'J, bl . rfil 1 u !*'( ] \? t i. X : 1 ' -> thou gh { V i m' '.Jt i`.` ;; j. .1 V! i P o d u c. t i o l.*i - l : c n w i i; h g i. U t Hi th i i 1 lit? L- - * r?g " ' 3 !. . ary ab O V -::'J ' O J , I < iYi .Vs 3 . 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J 3 t A i^ CR-27} ;[ ii -V1 t e e m v, t W i !; h a vi umber of Li' i* ,v> , <d. }' \i ? ; j v p Lj r T' d i h "f t > i0 ' k r Z O ' f-i U r'1 3 j Y) I) l L y 0 y p f\ 3 e G to * n y j. i'i!. o - . !i a o a ii i v: r rease , V'l t 1*' l fi ,Jeviee of ::: r O fit ) d o n r .n a a i -r i 3 3 n v! e i r L .yp h *:n:y fee by c Oiiip a r i o i't W i f h 2 4 c: o n f r a!. w o r k S'- 'iii ` r* c a th a i i (H 0 . j ^ / i 9 ? i 1. ^ v1 Li 1. 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For n za r d c ofiiau. n 1 C at i 0n purp 0 *> 0 4s> *JL Ti d 0 r 0 HA 31 a n da r d 2? Cr a p a r f- 1 T* f 0 * 1 2 0 h . this c 0 ;n i c at is l { 0 <1 a a C a r v- 1 no 90 vi !j / NTR .. .*1r. ta*i 1 . t, j a Vl 0 0 7 SS:;l "* I ' ' -! Ofe "3 t' ' i S , n -.:iG V 3 O V V -3 m ! ti -:ii !- G- % S * (3 L i G- -3 j ra ts jnd ribs i ts to 500 ppm ''CM 7 hr-:; dally du'lvig org-in !'i a l c. i vi a t o x i c i t y was ouserve1.' mu 3 11 yin luica, ou l' trie axpO'Eii re p rde ;:: ? d i.o ..villi c a Vi i m H v y c vi a I. or f s t 3 I. t ex ; c iy o r t r + n j.g . c a I. *' f c f s ,, U iv g - a v y .3 i.expo-ii'ifj pregnant r a t s son nuo .!- 1. y to 1500 pat, >rJu r i ng Hf3!, R. .;.. EM:`:R;' OF fY:E .. >.jW CHEMICAL COMPANY kes'v'y i'Er - Y-.jui o'c... R&s 20199 i"1 E A L D:'i ^ 4 ? S : & ENVIRONMENTAL SCIENCES INFORMATION occupational health training fetor? VINYL CHLORIDE E. F. 7 ;> t second or ti> . rd tr i m~str o f p r e -3 n -v. vi c > w i t h n o Irera to^sn i c effects, OSU T 0 GU I ng fi 0 3 t t i iiie s t 0 r cn I. y res u L t&d i n f e t a L rue r t a L i t y a n d o t L 0 r f > t o t o x i c - r r et a , a a I- n a t e r a (.* a i. o g y . A y si La b I. d a t a i n d i c a t s t h a t V C ri 3 o . t & r a t o g e h i c I o h u m a n s Sirt h de f e c t s a r a .u, n L i k e L y . Exp o 3 u r a a having no e f f e c t o n t h e m o t n e r BilO'J L j have no effect on the fetus. Did not cause birth de fee'ts in a vi i 1Vi a .5; other effects were seen in the fetus only at dose a w h i c h c a u a e ci t OX i c e f f e c t <: t o t h e m other. reit0DHe r ive e:efects ....................... OTHER EFFECTS fi 0> o N> o 0NJ x-x x x xx x x x x x x x x x x x x x x x x x x m x x x x x x x x x x y y x x x x x x x -x x x x x x x x x x x x x x x x x x x x x If CCS PACE 3 . "PROTECTION- X X X X X X X X -X X X X X X X X X X X- X X: X X- X- x X X X X X X: X X K -X X X X X X X X X X X X: X X X X X X X X X X X X X X X X X X X VENTILATION - C o n t r o L a i r b o r n e c o n c e n t r a t i o n s b e !. o w ; h e exposur e g u i (j e i. me. Use on:, y with adequate ventilation. - L.oa l. exhaus t ven i i L a t i on may be necessa r y f or some operaticns . INGESTION ~ Css good personal hygiene. Do not consume or store food in the work area Wash hands before smoking or eating* *AA4A 4 t, * A 11 PEKS0NAL Pft0TECTION" AA* AAA* AA AAAA A HANDLING PRECAUTIONS AND PROTECTIVE EQUIPMENT 1 hese- r 0c omrnended p v ec a t i 011s a re : ;: : end<:.*d f or u se du r i ng no r ma i. operating conditions; emergency conditions could require additional P recall t 1 ons . E X P L A N A T10 N 0 F P 0 T E N r IA L E X P Cl SURE CAT G U ft I S GO O CT> T!'.e following categories are based on the conditions of use or m a n u f a c: t u r e a n d t h e p r; y s 1 a l p r o p e r t i e s o f t h e m a ter i a L a n d s h o u I. d b e u s0 d t c d& i e r m 1 ne t h e a p p r op r i a t e iv a n d l i n g p r ec a u i ions for po t en t i a L eye , ski n and i 11ha La t i on 0xpo3u res . Th0y a r0 i nteitded to be used pr differeriT work tasks -not necessarily for a job c I. a ss i f i c a t i on ause the exposure potential may vary during the work day. OO ro -cr * TRADEMARK OF THE DOW CHEMICAL COMPANY RESTRICTED - DOW USE ONL :alth & ENVIRONMENTAL sciences inform AII on center 0 C C U i-:' A ; ION A L H E A L T l-l 1 R AI NINE, R E P-0 R T D R 01 1-4-1 936 VINYL CHLORIDE PACE 8 12/09/87 :pt r ST0I6I825 r&s 020201 W : No fij o r e t h a n m i no r a mou n t o f c o n t a c t is Li l< e !. y * < F o r x a m p L e : w o r k a r o u n d c I. o s e a s y s t e m s ; u s e o f v e n t i L a t e d l u i P m e n t ; handling of malar i al in 3 m a L !. amounts or with vary Low vapor pressure) MODERATE : Modo a si: u u ; it of c o n x a c t c ou i. d oc c u r f. Fo r 0 x a mp L s : sa mp I. i n g , p a c:: a g i n g , or- du mp i n g o f ma t e r i a i. s w i f h moderate to Low volatility or dustiness; similar handling o- material with high volatili ry or dustiness but with some ven t i L a t i on y ov i do? d High amount of contact is possible; even if for brief periods* (For example: sampling, packaging or dumping of materials with high volatili t y o r d u s t i n e = s w i t It o u t v e n t i i. a t ion; m a n > * a I. i. y e !. e a 11 i n g , draining or repairing e-iu \ p m an + ; changing fiL+er=j cleaning sp i 1st -_0W EXPOSURE EYE iNHALATION POSSIBLE 1J <, ft f -i?` *,*v-:. -I\* i./ g l a s s e A No P r ecau i; i o n s O i* her b e X mj e de d A - Foorr O s c a p tL\ pur P OS e s , res P i r a t T o n o r s o n than ca r r at a Cl. : !C. S!< IN I itH AL AT10h x IRE I- 0 b Si IB LE U s e '.Si- afet y *3 & {", -Uf - Use p r o t ac t i vs c L o f h i n g i mp e r v i ou s f o t h i s ma t e r i a i. Se !. ec t I on of spec i f i c i tems such as g L oves , boots , apron, or fulL-body suit w i i. L depend on operation. A t mosp h e r i c I. e ve I. s sh ou l d D e ma i n t a i ue d b e i. o w t h e x p o su r e guideline* When respiratory protection is required for c r t a i n op e- r a t i one .. >.i ss a n a p p r o ve d a i r pur j f y i n g r esp i r a t o r HIGH EXPOSURE POSSIBLE EYE Use :: n e m i c a I. g o g g i e s * I f v apor exp osu r e ca.u ses eye d i scom f or t , uss a f u i. I. - race , s u p p L i s (j - a i r re s p ; r a tor* SKIN Use protective clothing impervious to this material* S e L e c. t i o n o f s p e c i f . c it e m s s u c h a s g i. o v e s , b o ot s . a p ; o r-, o r fu L I. -body su it will depend on opera t i on* I -i H A L A T11j N - W h e n a i r ): o r n e e xposurs g u i d e L i n e s a n d / o r c o m f o v t !. s v e Is m a yb e exceiede d , u se a n app r ove d positive-p r essur e se L f -con t a i neci b rea th j ng appa ra tue * RCTECTIVE EQUIPMENT INFORMATION r& j P r o 1 f i ve c loth i n g t est a a t a a va i La b L e f o r t h i s c h em i D a t a f a r r e I. a f e d c h e m i c a i. s i n d i c a t e t It a t t h e f o Lowing s h o u I. d b o e f f e c t i Protective clothing material s: Nitrile butadiene rubber and 't i ton*. ~ Th ; following should be effective types of air-purifying respirators: ve FOR MORE INFORMATION CONTACT YOUR LOCAL INDUSTRIAL HYGIENIST TRADEMARK OF THE DOW CHEMICAL COMPANY KElFi K .l 0 \ E.v D 0 i'i iJ S i- Li N L. Hp.AL.TH & ENVIKONHE N T AL SC LANCES INFORMA fION CENTER FACE 9 I DCCORATIONAL HEALTH TRAINING REPORT 12/09/87 D Ft - 0 . . - : : >3V E NY L C H L 0 R .i: D E ________ ____ _... .. .............. . ,, ....................................... R E !- !' I' ........ ........... ............... .......... 'RESCUE ------ EMERGENCY TREATMENT AND MEDICAL NOTES E'. E - I ri gates : fume d i a i e L / with water for at Least 5 minutes* Si< No a dve i se e f f ec t s a n t i e i p a t e d ,:< / t h i s fT-ostb i te.. >* ou t e o e x p osu r e ex cep t fo r INGESTION - No adverse effects anticipated Dy this P roper t i es * route of exposure due to p y s i c a i. IN,-: Li.. AT ION - Resisove t ;, r ei r A if not breathing, give mou t h~ t o-mou t h X f b r e-a t* n i n g i s d i f f i c u L t , g i vs o x y gen * Ca I. i. a p h ys i c i a n * r 0 R A P DI710 N A L IN F 0 R M A T10 N C 0 N T A C T : H&ES INFORMATION CENTER DDL CHEMICAL OSA MIDLAND hi 48674 PHONE : !5i 7--6S6-1 909 realise i Station, - trademark of ;he DOW CKEM.!.CAL companv C/> H O <T OO PO cr> 33 fio CO o otroo oto RES TRIC7EP PON OSE ONLY