Document XY8Rz25oJRVa47mZdJv1gerw

Vcnai me Versar, DJc. . OPTS 62017 PCBs Controlled Wastes Csrmunication N .y A File v. MEMORANDUM 3 rl TO: Liz Bryan, Mika Callahan, Richiiaond, Bill Center, Karen o Hammerstran, Denise Keehnef/'my and Sherry Sterling, V 5^3m"O. EJSV/0S5 ` two r" o 7101: Leslie Adkins and Randy Freed, terser 2* !2 tn QA3E: September 8, 1582 SUBJECT: List of Plants' and Chemical Manufacturing Processes known or - . Suspected to Generate KSs as Ispurities ro 09 715-M-147 .Per Amy Moll's request, this memo transmits a-list of plants and processes that are potential inadvertent generators of PCBs. The method used to compile this list was to systematically review the SRI 1982 Directory of Organic Chemical Producers and list the suspect products pcoduced by each plant, regardless of plant size. The suspect products belong to the generic families of products listed in the materials balance that submitted on April 23, 1982 or to one of the following families that we have added to that list: e dyes/pigments made with halogenated solvents e chlorosilane derivatives e organo phosphorus trichloride derivative e chlorinated naphthalene derivatives . e alkyl chlotcpfaosphine derivatives e chlorinated, aryl phosphines halogenated dyes/pigoents chlorotoutane derivatives e cfaloraxylene derivatives e halogenated solvents, unspecified . e biphenyl derivatives chlorinat`ed.phosphate` ester ' , ' l Zn preparing this table, we have also modified the categorization used in the previous work by combining some entries into larger families. *- ** * A comparison of the old and new estimates of suspect plants and processes, shown below, indicates that the ruober of plants and processes in the attached table is approximately twice the number estimated in the .April 23 submittal. .' 0755784 TOWOLDMONOQ59992 715-H-147 Page 2 Old Estimate New Estimate Mb. plants 79 Ns. processes 242 159 467 Two factors account for this discrepancy. Son* new products/prccesses appear in the attached table because they belong to the new generic fanilies of chemicals listed above. Most of the additions, however, result from the fact that this time.w examined every company listed in SRI 1982, while in April we concentrated on the larger companies, disregarding seme stall producers with specialty products. Almost all of the additional products are produced in very snail quantities, thus are not expected to contribute significantly to the actual tonnage of PCBs produced. . LA:jar Attachment i 0755785 TOWOLDMONOQ59993 DISCLAIMED This docvment was produced on quick response,basis for the U.S. Environmental Protection Agency, Office of Toxic Substances. It is a PCS a in closed and controlled waste manufacturing processes. Ary information provided in this docvsnerit should be used only with extreme caution, recognizing its tentative nature. No final version of the document has been produced. i I. 0755786 TOWOLDMON0059994 Table 1. Sunnary of Plants and Processes Known or Suspected to Generate PC3s as Impurities plant Aceto Chemical Carlstadt-NJ ' Allied Corp. Baton Rouge, LA 1 Segundo, a ' American Color t Chemical Lock Haven, PA American Cyanamide Sound Brook, NJ , Ames Laboratories Milford, CT Anderson Development Co. Adrian, MI Atlantic Chemical Charlotte, NC ' Ataaeric Chemicals Plainviev, NT BASF Wyandotte Ransalaer, NY Chemical Generic Chemical Class 3 cbloro 1, 2 propanediol 1,3 dichloro 2 propanol 1,2 dichlorotetrafluoroethane cfalorodlfluoromethane trichlorofluoroethane chloroethane derivative chloropropane derivative chloroethane derivative cblorcmethane derivative chloroethane derivative. chlotodifluorcoethane dichlorofluoromethane 4-cfalororesorcinol cblorcmethane derivative chloranethane derivative chlorcphenol derivative p chlorobenzenesulfonamide _ o- (p) chlorobenzene benzoic acid phthalocyanine blue st-chlorobenzylamine o-chlorobenzylamine p-chlorobenzylamine printing ink additives . phenyl triethcxysilane silicone products . m-cfaloroaniline hydrochloride miscellaneous dyes chlorobutanbl chlorotenzene derivative chlorobenzene derivative dye made with halcgenated solvent . ' chlorinated benzyl compounds chlorinated benzyl ccnpounds chlorinated benzyl canpounds chlorinated benzyl canpounds chlorosilane derivative . chlorosilane derivative chloroanilines chloroanilines chlotobutane derivative o- (p) -chlorobenzene benzoic acid phthalocyanine blue chlorinated benzoic acid dye_made with halcgenated solvent *1 f 0755787 TOWOLDMONOQ59995 Table 1. Stannary of Plants and Processes Known or Suspected to Generate PCSs as Ispurities (Continued) Plant Chemical, Generic Chemical Class LASF SoHand, Ml phthalocyanlne blue Huntington, WV ' phthalocyanine blue ofots Lakeway 'uskegon, MI 2,4-dichlorotanzoic acid 2 cfaloro 4 nitxobenzoic acid 3,3*-dlcfalorofcenzidene ' dichlorochloride pigment Intemediates Ordinal Chemical loltssbia, SC 1,4-dichlorobutane dichlorodibutyl ether 'iba Geigy Glens Palls, NT phthalocyanine blue Tara River, NJ dye intermediates (chlorinated) lolianbia Organic Chemicals . 3-chloro-2-methylpropane Columbia, SC - diamond Shamrock . * Greens Bayou, `DC chlorinated pesticides Belle, WV chloroform methyl chloride methylene chloride chlorinated paraffins perchloroethylene , . Ashtabula, Ohio t Dow Oremical Freeport, DC . ( hssachlorofautadiene * x, x'-hescachlocoparaxylene * carbon, tetrachloride chloroform 1,2-dichloropropane ethylchloride methylehlorlde mdthylenechlbride perchloroethylene ' , ' chlorinated pesticides 1*,3 dichloropropane ' . 2 dye made with halogenated solvent dye made with halogenated solvent chlorobenzoic acid derivative chlorobenzoic acid derivative chlorobenzoic acid derivative chlorinated pigments/dyes chlorinated paraffins chlorinated paraffins dye made with halogenated solvents halogenated dye chloropropane derivative chlorinated pesticide chlorcmethane derivative chloromethane derivative chlorcmethane derivative chlorinated paraffin chloroethane derivative . ehlorobutane derivative chloroxylene derivative * chlorcmethane derivative chlorcmethane derivative chloropropane chloroethane derivative chloromethane derivative chlorcmethane derivative chloroethane derivative chlorinated pesticide chloropropane derivative 0755788 TOWOLDMONOQ59996 Table 1. Siaanary of Plants and Processes Known or Suspected to Generate PCSs as Inpurities. . ` (Continued) Plant Qwoical Generic Chemical Class . . Midland, MI tr icbloroethanes trichloroethylene vinyl chloride . ' vinylidene chloride chlorobenzene chlorophenols phenol chlorostyrene dichlorobenzenes trichlotophenoIs chlorinated pesticides tatrachlorobenzene trichlorobenzene vinyl benzyl chloride , * - Oyster Creek, TX . vinylJbenzyl chloride. ' vinyl chloride Pittsburg, Oi ` carbon tetrachloride perchloroethylene Plaquemine, IA carbon tetrachloride chloroform methyl chloride methylene chloride perchloroethylene trichloroethanes trichloropropanes vinyl chloride vinylidene chloride .* i. Oow Coming Carrolton, KY Hemlock, MI methyl chloride silicone fluids chlorosilanes silicone products Dupont . Deepwater, HI i, chloroanilines , ' dichloroanilines methyl chloride ^richlorofluo rope thane Louisville, KY ' ( r '* triehlorofluoromethane dichlorofluoraoethaoe. chlorodifluoromethanes chloroethane derivative chloroethane derivative chloroethane derivative chloroethane derivative _ chlorobenzene chlorophenol derivatives phenol chlorobenzene derivative chlorobenzene derivative chlorophenol derivative chlorinated pesticide chlorobenzene derivative chlorobenzene derivative chloroethane derivative chloroethane derivative chloroethane derivative chloroaethane derivative chloroethane derivative chlorcmethane derivative chloranethane. derivative chlorcmethane derivative chlorcmethane derivative chloroethane derivative chloroethane derivative chloropropane derivative chloroethane derivative chloroethane derivative chloramethane derivative chlorosilane derivative chlocosilane derivative . chlorosilane derivative chloroaniline derivative chlocoaniline derivative chloranethane derivative chlorcmethane derivative chlorcmethane derivative chlorcmethane derivative dhlorcmethane derivative 3 0755789 TOWOLDMONOQ59997 Tabic 1. Stannary of Plants and Processes Known or Suspected to Generate PCSs as Inpuritias (Continued) Plant T Chemical Generic Qiemical Class Montague, MI trichlorofluorernethane chlorodifluorasethane tr ichloroduccanethane chloranethane derivative ehloranethane derivative chloranethane derivative Oynamit Mabel Stony Point, NJ vinyl trichlorosilane chlorosilane derivative Eastern Color & Chem Co. Providence, RI alkylbenzenesulfonic acid & salts pigment`printing color & auxiliaries alkyl benzene alkyl benzene Easeaan Kodak Kodak Lab & Specialty Chan. Oiv. Kingsport, TN chlorohydroquinone 5-chlorosalicy Laldehyde 2,3-dichloro-l-propenol chlorophenol derivative chlorobenzaldehyde derivative chloroprcpane derivative last Shore Qranical'Co. Inc. 'lusksgon, MI S-cbloro-4-diethylamino . benzenediazoniisn chlocozincate chlorobenzene derivative chlorohydroquinone, dibutylether chlorophenol derivative ` H-4-diazo-2-diethcxy-l-(4-tolyl- mercaptobenzene) ehlorozincate 2-ethoxy-1-napthoyl chloride chlorinated napthalene derivative 2.5-dietbaxy chloronitrobenzene chlorobenzene derivative p-diethylaminoben2ene diazqniixn chlorobenzene derivative salts .. 2.6-dimethaxytoenzoyl chloride dilorobenzene derivative 2rtcay Chemical Co. Elizabeth, NJ dedacylbenzene sulfonic acid dodecyllbenzene sulfonic acid .sodiia salt , (dodecyllbenzyl) trimethylanmoniisi chloride . . alkyl benzene derivative alkyl benzene derivative . alkyl benzene derivative Essex Chemical Corp Baltimore, { benzylchlorofonnate' . chlorobenzene derivative 2-ethylhexyl chlorofonnata chloranethane derivative isopropyl phenyl chloranethane derivative n-butyl chloroformate chloranethane derivative diethyleneglycolbis (chloroformate) chloranethane derivative ethyl chlorofossata chloranethane derivative tsobutyl chloroformats chloranethane derivative isopropyl chloroformate chloranethane derivative 4 0755790 TOWOLDMONOQ59998 Tnhim i. Stannary of Plants and Processes Known or Suspected to Generate H2s as Impurities . (Continued) Plant Qianical Generic Oienical Cia.M Ethyl Corp. Zhem. Group Baton Rouge/ IA Orangeburg/ SC Pasadena, Texas Magnolia, AR Hardwick Chen. Co. (subsid.) Elgin, SC rabricclor, Inc. Paterson, KJ raiment Chen. Co., Inc 'tewark, BJ methyl chlorofonnate n-propyl chlorofonnate triethylene glycolbis (chlorofonnate) chloranethane derivative chloranethane derivative chloronethane derivative ethyl chloride ethylene dichloride methyl chloride perchloroethylene vinyl chloride ooncner ( ' ethylphosphonothioic dichloride ethylphosphorus dichloride methylpbosphonothioic dichloride h-propylbenzene-1,3,5-trimetbyl?,4,6, tris (3,5-tert-butyl) 4-hydroxyphenyl) ben2ene ethylene dichloride 4^hlorobutyronitrile chloroethane derivative chloroethane derivative chloranethane derivative chloroethane derivative chloroethane derivative . organo phosphorous trichlorid derivative organo phosphorous trichloric- derivative organo phosphorous trichlorid- derivative alkyl benzene alkyl benzene chloroethane derivative derivative chlorobucane derivative n**bexyl chloride isooctyl chloride a-octyl chloride chlorinated paraffiA chlorinated paraffin chlorinated paraffin .1 dyes 6 pi^nents halogenated dyes t apid, basic, direct, & disperse dyes halogenated dyes 5-chlorobenzotriazole * 3- chloco-4-diathylanino- benzenediazoniun-chloride-zinc ' chloride 4- chloro-o-pbenylenedisnine chlorobenzene derivative chlorobenzene derivative . chlorobenzene derivative S 0755791 i TOWOLDMONOQ59999 Table 1. Sunnary of Plants and Processes Known or Suspected to Generate PCBs as Lrpurities (Continued) Plant Chemical X Generic Chemical Class p-dimethylasninobenzenediazoniun chloride-zinc chloride p-(N-*thylbenziaido) benzenedlazonim chloride-zinc chloride chlorobenzene derivative chlorobenzene derivative Ferro Corp. Kell Chem. Div. Esmond, IK Sreminated-chlorinated flame retardants chlorinated fatty confounds , chlorinated paraffins chlorinated paraffins Ottawa Chem. Div. Toledo, CB p-chloro-m-oresol 47Chloro-3,5-xylenol chlorophenol derivatives chlorophenol derivatives Productol Chem. Div. 'anta Fe Springs, A FJJce Owmicals, Inc. Mtro, WV ' phenol . 2,3-dichloropropene phenol chloroprcpylene derivati' FMC Industrial Chemical Group oaltiacre, 3-chloro-2-methyl-l-propene chloropropylene derivati- Foramost McKesson, Inc. Cham, droup . McKesson Envirosystems Co. (subsid). Dolton, H Maaati, I& fewmrk, KJ chlorinated solvents chlorofluoro solvents parfaon tetrariilocida chlorinated solvents chlorofluoro solvents carbon tetrachloride chlorinated benzene chlorinated solvents chlorofluoro solvents chloroform chlorinated paraffins chlorinated paraffins chloromethane derivative chlorinated paraffins chlorinated paraffins chloromethane derivative chlorobenzene derivative chlorinated paraffins ' chlorinated paraffins chlorcmethane derivative Newcastle, KZ qhlocinatad solvents chlorofluoro solvents halogenated solvents, unspecified, 0755792 TOWOLDMONOO6OOOO Tabla 1. Summary of Plants and Processes Known or Suspected to Generate FG3s as Iopurities " (Continued) Plant Chemical Generic Chemical Class Formosa Plastics Corp. CSA . Baton Rouge, LA ' . ethylene dichloride vinyl chloride monpmer . ehloroethane derivative ehloroethane derivative Frank Enterprises, Inc. Toluntous, CH ' derivative _ '. . ` ' . i . 2-chloroacetophenone ' p-chloromercuriphenol 5-chlorosalicylie acid p-diisoprepylbenzene 4,4 '-dimethcDcyben2ophenone 2,4,-dimetbylbenzcphenone DTheptylhenzene . n-hexylbenzene * 3-nitro-4-chloroacHtanilide 3-nitro-4-chlocoaniline n*cctyibenzene o-propylbenzene chloroacetcphenone derivative phenol derivative chlorophenol derivatives alkyl benzene derivative chlorobenzophenone ' chlorotenzophenone alkylbenzene derivative alkylbenzenederivative chlorinated aniline derivative chlorinated aniline derivative . alkylbenzene derivative alkylbenzene derivative ar corp. Chem. Products . Calvert City, KX . * - Linden, MJ ' ' -. a General Electric . Silicone Products Bus. Olv. 'aterford, NX .' . .> . '' . alkylphenols, mixed 2,4 dinonylphenol p-dcdecylphenol i alkylphenols, mixed 4-chloro-3,5-dinitrobenzene sulfonic acid, potassiua salt 2,6-di-tert butyl-4-nonylp*ienol 2,4-dinortylphenol nonylphenol , . ' methyl chloride . . . methyl chlorosilane phenyl chlorosilane silicone resins , . . silicone Quids ' silicone products - phenol derivative phenol derivative phenol derivative . phenol derivative chlorobenzene derivative ( phenol derivative phenol derivative phenol derivative . chlocomethane derivative chlorosilane derivative chlorosilane derivative chlorosilane derivative chlorosilane derivative chlorosilane derivative 7 0755793 _ [ __ J TOWOLDMONOO6OOOI Table 1. Seminary of Plants and Processes Known or Suspected to Generate PGBs as Inpurities. - . (Continued) Plant ` ghawriral Generic Chemical Class Georgia Pacific Co. 2wn. Div. Bound Brook, KJ Flaquanine, LA. phenol ethylene dichloride polyvinyl chloride vinyl chloride monomer Givaudan Corp. Clifton, RJ phenyl ether? 3F Goodrich Calvert City, KY vinyl chloride monomer , Deer Park, TX ethylene dichloride LaPorte, TX , `vinyl chloride monomer ethylene dichloride Convent Gien. Corp. (subsid.) Calvert City, KY I Convent, LA ' ethylene dichloride ethylene dichloride Goodyear Akron, CB phenol, alkylated v* Grace Waterloo, RJ lHhilorotanzyl mercaptan 3-chloco-propancdiol Guardian Chem. Hai^pauge, tCf* 2- cfaloro-2-nethylpropane Gulf Oil Berkeley Heeights, NJ a Balocarbon Products * Hackensack, tU Hanpden Color & Qiemical Springfield, MA Hercules Bcpewdll, VA 3- chloro-l, 2-propanediol chlorod!fluoco acetic acid chlorotrifluroethylane chlorinated solvents * chloro acetic acid . phenol chlocoethane derivative ' chloroethare derivative chloroethane derivative phenol derivative chloroethane derivative chloroethane derivative chloroethane derivative chloroethane derivative chloroethane derivative chloroethane derivative phenol derivative * chlorobenzene derivative chloropropane derivative chloccprcpane derivative chloropropane derivative chloroethane derivative chloroethane derivative unspecified chlorinated solvi ' chloroethane derivative 0755794 ! TOWOLDMONOO6OOO2 Zable 1. Stannary of Plants and Processes Known or Suspected to Generate PC3s as Iqpurities (Continued) . Plant . Chemical Generic Chemical Class Parlin', KJ ICC Industries Dovers OH Id Industries Bayonne, NJ ' ac . .Ashtabula, CB Barrington, ME Linden Cieaiicals & Plastics Mcundsville, WV . riagruder Color Co. Elizabeth, NJ Carteret, KJ chlorinated paraffins chlorinated paraffins chlorinated paraffins chlorinated pesticides chlorinated pesticides chloroform . methyl chloride methylene chloride phthalocyanine blue *ben2idine yellows phthalocyanine dyes '' ' Martin Marietta Sodyeco,, SC McQian Sil Corp. Carpenters, CA Millikan Chemical Iran, SC Mcbay Chemical 'Kansas City, to Baledon, NJ l-chlor-2,4-dinitrobenzene. silicone resins and products a-cfalorcphenyldiethanolaniine 1-chloro, 3,3-dioethylbutanone chlorinated pesticides phthalocyanine dyes * Bushy Park, SC New Martinsville, WV * 2,5-dichloro sulfonic acid tt-chlorophenyl isocyanate p-chlorcphenyl isocyanate 3,4-dichlorophenyl isocyanate . chlorinated paraffin chlorinated paraffin chlorinated paraffin chlorinated pesticide chlorinated pesticide chlorcoethane derivative chlororaethane derivative chlorcoethane derivative dye produced with chlorinated solvent halogenated dye dye produced with chlorinated solvents chlorobenzene derivative chlorosilane derivative chlorobenzene derivative chlorinated pesticide chlorinated pesticide dye produced with chlorinated solvent chlorobenzene derivative chlorobenzene derivative chlorobenzene derivative chlorobenzene derivative 0755795 TOWOLDMON0060003 rM Sunnary of Plants and Processes Known or Suspected to Generate PCSs as Impurities . (Continued) Plant Chemical Generic Qwmical Class ' ; Mobil Oil Corporation Charleston# ~ SC Monsanto# : Sauget, IL Luling, LA Montrose Chemical Sanderson# HV Tbcrance# CA Seville Gusnical Co. anta Fe Springs# CA Norda# Inc. Newark# Northwest Industries Wtlsicol Div.) Qiattanooga# TH Marshall# ,IL Memphis, IS . Occidental Petroleum Sooker Csemical i Niagara Falls# NY . Bis (2-chlorcethy1)-2-chloro tbyl phosphorate chlorobenzene ehlorophenols chloroni trobenzenes dichlorophenols dichlorobenzenes chloroaniline 3,4-dlchloroanillne chlorinated pesticides chloral chlorobenzene . dicblorobenzil mixed polychlorobenzenes chlorinated pesticides chlorinated paraffins chlorinated phosphate ester chlorobenzene & chlorcphenol derivatives chloroaniline derivative chloroaniline derivative chlorinated pesticide chlocopropane derivative chlorofcenzene derivative chlorobenzene derivative chlorobenzene derivative chlorinated pesticide - chlorinated paraffin p-chlorobenzopbenol chlorophenol derivative chloro (p-chlorophenyl) phenylether chlorophenol derivative chlorophenylmethane p-chlorophenyl acetonitrile chlorobenzene derivative chlorobenzene derivative 6-chlorothymol ( chlorobenzene derivative chlorofcenzoic acid esters soc-trichlorotoluene ehlorendic diesters chlorinated pesticides 1 hexachlorocyclcpentadiene chlorinated norborene esters chlorinated pesticides chlorobenzene derivative chlorotoluene derivative ` chlocotoluene derivative chlorinated pesticide' chlorinated pesticide chlorinated pesticide chlorinated pesticide 1-cfalocobenza ldehyda e-chl6robenzoyl chloride o-chlocotoluene , '* * 10 chlorobenzene derivative chlorobenzene derivative chlorotoluene derivative 0755796 TOWOLDMON0060004 Tahi j.. Suanary of Plants and Processes Known or Suspected to Generate PC3s as Impurities (Continued) Plant Chemical Generic Chemical Class ' Zolcsn Group (subsid.) ' Palo Alto, A >Lin Cbem. McIntosh, AL Rochester, NY Parish Oaeraical Cram, Utah p4n-cfaloro-x-tr ifloorotoluene 2.4- dichlorobenzotrichloride 2.4- dlcfalorotenzotrifluoride 2.4-dictalorotoluene _ hexarhlnrocyclopyitadienc 1,4,5,6,7,7-hexachloro-5-norbornene- 2,3-dicarbcocylic anhydride ;2-nitro-4-chlorobenzotrifluoride dienochlor methyl pentachlorete&rate scoc-tricfalorotoluene . chlorotoluene derivative ctalorotoluene derivative chlorotoluene derivative chlorotoluene derivative chlorinated pesticide, chlorinated pesticide chlorotoluene derivative chlorinated pesticide chlorinated pesticide chlorinated toluene dienochlor * chlorinated pesticide JOB 2-aaino-5-chlorobenrotrifluoride brcmotrichlbrcoethane <*^hloro-3-aminobenzotrifluoride 3-chlbro-4-fluoroaniline ,o,a and p-chlorofluorobenzene chloro-6-fluorofcenzyl chloride 3-chloro-4-fluoronitrobenzene 2-chloro~6-fluorotoluene o6p-luorobenzotrichloride o,atp-fluorobenzoyl chloride o,a4p-luorobenzyi chloride triehloroacatonitrila chlorinated pesticide chlorotoluene derivative chlorooethane derivative chlorotoluene derivative chloroaniline derivative chlorobenzene derivative chlorobenzene derivative chlorobenzene derivative chlorotoluene derivative chlorotoluene derivative chlorotoluene derivative chlorotoluene derivative chloroethane derivative biphenyl, 4,4' -disulfonyl chloride o-chlorobenzenethiol . *l-chlorobenzotxiazole 2-chloroethyl-p-chlorophenyl sulfone and sulfide 2-chloroethyl-p-ptaenyl sulfone and sulfide . p-chlorobenzyl-2-hydrtocyethylsulfide p-chloroaethyl-chlorophenyLsuflide chlorcoethyl methyl sulfide chloranethyl phenyl sulfide U. Biphenyl derivative chlorobenzene derivative chlorobenzene derivative chlorobenzene derivative chlorobenzene derivative chlorobenzene derivative chlorobenzene derivative chlorooethane derivative chlorooethane derivative 0755797 TOWOLDMON0060005 tkt suanary of Plants and Processes Known or Suspected to Generate PQs as Impurities (Continued) Plant Chemical Generic Qiemical Class Pennwalt Corp. Calvert City, Ef :*fister Chemical Inc 'idgefield, RJ $ Pierce Qnsn. Co. Rockford, XL * chloroaethyl phenyl sulfone p-chlorophenyl-2-hydracyetbyl sulfide p-chlorophenylthioacetonitr ile 3,4-dichlocophenyLacetic acid trichlorcmethanesulfonyl chloride 2,2,2-trifluoroethyltrichloro- aethanesulfcnate chloramethane derivative chlorobenzene derivative chlorobenzene derivative chlorobenzene derivative chloramethane derivative chloramethane derivative 1 chlore-1,1 difluoroethane ' chlorodifluorcmethane dichlorodifluorcmethane trichlorofluorcmethane . chlorcethane derivative chlorcmethane derivative chloranethane derivative chlorcmethane derivative 4-chloro-o-anisidine 5-chloro-2,4-dime thoxyaniline 4'chloro-3 hydroxy-2', 5'-dimethoxy- 2-naphthanilide Vchloro-3 hydroxy-2' 4' -dimethoxy- 2-naphthanilide 4' and 3' chloro-3 hydroxy-2'4'- dimethoxy- 2-napththanllide. 5'chloro-3 hydroxy-2-naphth-o-anisidide S'chloro-3 hydroxy-2-naphth-o-toluidide 4'chloro-3 hydroxy-2-naphth-o-toluidide S-chlorosalicylanilide 5-chloro-o-toluidide 4-chloro-o-taluidide ,' cfalorophenol derivative chloroaniline derivative chloroaniline derivative chloroaniline derivative chloroaniline derivative chlorophenol derivative chloroaniline derivative chloroaniline derivative chloroaniline derivative chloroaniline derivative chloroaniline derivative . , chloroailane* derivative 5-dimethylanino-l-naphthalanesulfonyl ehloronapthalene derivat .chloride p-nitrophenylsulfenyl chloride . chlorobenzene derivative trimethylchlorosilane chlorosilane derivative I 0755798 TOWOLDMONOO6OOO6 Table 1. Stannary of Plants and Processes Known or Suspected to Generate PC3s as Inpurities ' (Continued) Plant Chemical Generic Chemical Class Polysciences, Inc. Warrington, PA : PPG Barberton, OB 'LaFocte, TX Lake Charles, LA Hetxiian, WV Publicker Industries Philadelphia, PA Pegis Chemical Co. Martin Grove, IL I Seichold Chmical Tacoma, HA * butyl-n-chloroacrylate chlorostyrene nethyl-n-chloroacrylate chloropropane derivative chlorobenzene derivative . chloropropane derivative sec-butyl chlorofonnate 2-ethylhexyl chlorofonnate isopropyl chlorofonnate n-propyl chlorofonnate chloropham (pesticide) . < ethyl chlorofonnate benzyl chlorofonnate n-butyl chlorofonnate sec-butyl chlorofonnate decyl chlorofonnate 2-etbylhexyl chlorofonnate isobutyl chlorofonnate isopropyl chlorofonnate methyl chlorofonnate octadecyl chlorofonnate t\-octyl chlorofonnate phenyl chlorofonnate . * n-propyl chlorofonnate ethyl chloride ethylene dichloride perchloroethylene 1,1,1-trichloroethane trichloroethylene vinyl chloride monaner vlnylidene chloride monomer (none) chlorobenzene ocp dichlorobenzene trichlorobenzene , chlorarnethane derivative chloranethane derivative chloranethane derivative ' chlorarnethane derivative chlorinated pesticide chloranethane derivative chloranethane derivative chloranethane derivative chloranethane derivative chloranethane derivative chloranethane derivative chlorcoethane derivative chloranethane derivative chloranethane derivative chloranethane derivative chloranethane derivative chloranethane derivative chloranethane derivative chloroethane derivative chloroethane derivatiye chloroethane. derivative chloroethane derivative chloroethane derivative chloroethane derivative chloroethane derivative chlorobenzene derivative chlorobenzene derivative . chlorobenzene derivative 1-chlorobutane 4tchloro-l-napthol chlorinated pesticides chlorobutane chlorinated naphthalene derivative . chlorinated pesticide 13 0755799 TOWOLDMON0060007 ^bla 1. Suaaary of Plants and Processes Known or Suspected to Generate PCSs as Impurities '. (Continued) Plant Qwmical Generic Clerical Class Rhcae-Boulane Inc. Portland, OR Riverdale Chemical Co. Chicago Heights, IL ASA Ardsley, N2f Reutgers-Naese Chemical Co. *tate College, SR * ' SOI Corp. (POl Subsidiary) Gainesville, FL Shall Oil Deer Park, TC . Denver, CD Mobile, AL Horco, CA p-chlorophenol 2,4-dichlorophenol trichlorcphenol chlorinated pesticides chlorophenol derivative chlorophenol derivative chlorophenol derivative chlorinated pesticide chlocoacetnnitrile a-chloroanisole 2-chloroethylcarbamate 2-chloroetbylchlocofonnata 2-chlorolactic acid B-chloropbenetole (T-chlorcpropionamide B-chlorcprcpione'trile ethyl a ehloropropionmida ethyl a chloropropionate , ` chloropropane derivative chlorophenol derivative chloroethane derivative chloroethane derivative chlorinated paraffin chlorinated paraffin chloropropane derivative chloropropane derivative chloropropane derivative chloropropane derivative p-chlorobenzenesulfanate chlorobenzene derivative p-chlorobenzenesulfuric acid chlorobenzene derivative p-chlocobenzenesu)forachloride chlorobenzene derivative 2-efxlCroethyl anine bydrocholoride chloroethane derivative l-chloro-2-fluoroethylane chloroethane.derivative dichlocofluoroethylenes chloroethane derivative chlorinated pesticides allyl chloride ethylene dichloride chlorinatad pesticides phenol trichloropropane vinyl chloride i chlorinated pesticide chloropropane derivative chloroethane derivative chlorinated pesticide phenol ' chloropropane derivative chloroethane derivative chlorinatad pesticides chlorinatad pesticides chlorinate. d pesticide chlorinated pesticide chlorinated pesticides eptchlorohydrin ethylene dichloride vinyl chloride - chlorinated pesticide chloropropane derivative chloroethylene derivative chloroethylene derivative 14 0755800 TOWOLDMONOO6OOO8 Table 1. Sunnary of Plants and Processes Known or Suspected to Generate P<2s as Impurities * (Continued) - Plant Qiralcal T Generic Qtemical Class Sherwin Williams ~t. Bernard, GB . o-chlorobenzoic acid chlorobenzene derivative Salisbury Laboratories CSiarles City, A 2-amino, 5,6-dichlorobenzotriazole 2-amino, 6,7-dichlorobenzotriazole 2-chloro, 4-nitro benzoic acid chlorobenzene derivative chlorobenzene derivative chlorobenzene derivative Southland Cor?. Great Meadows, NJ chloroacetone 2-chloro dimethyliscproxylaffline hydrochloroide ' 2-chloro. NN dimethylpropylanine _ hydrochloride t' chloro dinitrobenzoic acids ' chloroethyl amines 2-chloro-4-nitxo benzoic acid chloroprcpane derivative chloroprcpane derivative chloropropane derivative chlorobenzene derivative chloroethane derivative chlorobenzene derivative 'cecialty Organics Inc. Vrvindale, CA chlorcmetbylphosphonic dichloride chlorophenols .. dichlorobenzenes dichlorcphenols methylphospborodichloride 9% ' methy lphosphonicdichlor ide chlorcmethane derivative chlorophenol chlorobenzene chlorophenol alkyl chlorophosphine derivative alkyl chlorophosphine derivative ctauffer> Chemical Cold Creek, AL diethylchlorophosphate chlorinated pesticides chlorinated phosphate ester chlorinated pesticide Beiderson, SI Mt. Pleasant, IN Carson, Of p-chlocobenzene sulfonic acid i o-o dietfaylphosphorochloridothioate o-o diathylpbosphocochloridothioate chlorinated pesticides benzene phosphorous dichloride benzene phosphorous thiochloride ft vinyl chloride - chlorobenzene derivative chlorinated phosphate ester chlorinated phosphate ester chlorinated pesticide chlorinated aryl phosphine chlorinated aryl phosphine thloroethylene derivative Edison, HJ benzal' chloride benzyl chloride . 2,4-dichlorobenzylchloride dodecylbenzylchloride ethylbenzyl chloride chlorotoluene derivative chlorotoluene derivative chlorotoluene derivative chlorotoluene derivative chlorotoluene derivative *Gallipolis Perry, WV* . ... . . ' bis (2-chloroethyl) phosphanata chlorinated phosphate ester \ bis (2-chloroethyl) vinyl phosphanata, chlorinated phosphate ester . benzene phosphinic acid chlorinated aryl phosphine .' '. derivative IS 0755801 TOWOLDMON0060009 tm i. stannary of Plants and Processes Known or Suspected to Generate PCSs as Inpurities ' (Continued) Plant Chemical Generic Chemical Class Sterling Drug Cincinnati, CH Sun Chemical Posedale, NY Cincinnati, OB Muskegon, MI SV5 Silicones Irian, MI ` axas Gulf (M&T Subsidiary) South San Francisco, CA Onion Carbide Ambler, PA * '_ Clinton, XA 4 freemont, CA . St. Joseph, MD Institute, WV benzene phosphorous dichloride tri (B-chlocoethyli phosphate tri (dichloropropyl) phosphate chlorinated aryl phosphine derivative chlorinated aryl phosphine derivative chlorinated aryl phosphine derivative _ 3-chloro-2-hydroxypropanesulfuric acid chloropropane derivative tetrachloronitrobenzene chlorobenzene derivative , phthalocyanine pigments % t dye made with chlorinated solvent phthalocyanine pigments dye made with chlorinated solvent diarylide yellow halogenated pigment silicone products chlorosilane derivative' chlorinated silanes chlorosilane derivative 2-chloroetbylphospfacnic acid tricfalorobenzoic acid, diethylaniline salt tzichloropbenoxy acetic acid, sodium salt ' chlorinated pesticides chlorinated pesticides . chlorinated pesticides chlorinated pesticides 1-chlorobutane methylehloride . chloreethane derivative chlorobenzene derivative chlorobenzene derivative chlorinated pesticide chlorinated pesticide chlorinated pesticide 'chlorinated pesticide * chlorinated paraffin chloronethane derivative 16 0755802 TOWOLDMONOO6OOIO Table 1. Sisanary of Plants and Processes Known or Suspected to Generate PCSs as Inpurities (Continued) Plant T QMHnical T Generic Chemical Class , Sistarsville, WV So. Charleston, WV Cprjohn Co. >5octh Haven, CT ertac Jacksonville, AR Vicksburg, Vij Lean Geisnar, LA Wichita, ES Jim waiter Birmingham, AL Warner-Lambert Holland, MI, White Qiemical Carp. Bayonne, NJ chlocotrimethylsilane dichlocametfaylsllane dichlorosilane trichlorosilane trichlorouethylsilane silicone products 1-chlorobutane cblorosilane derivative cblorosilane derivative cblorosilane derivative cblorosilane derivative cblorosilane derivative cblorosilane derivative chlorinated paraffin o-chlorbanil o-cbloraniline 4-chloro-o-xylene 3,3'dichlorobenzidine dihydrochloride * ' ' cbloroacetic acid chlorinated pesticides . 2,4-dichlorophencl dblorinated pesticides carbon tetrachloride chloroform etbylenedichlocide . methylenechloride percbloroethylene, trichloroetbane _ carbon tetrachloride i chloroform methylene chloride perchlorathylene chlorinated pesticides ' | p-chlorobenzene sulfonic acid p-ehlorobenrene sulfonylchloride o-chlorocyclopentyDeetone chloroaniline derivative chloroaniline derivative chlorobenzene derivative chlorobenzene derivative cfalorcethane derivative chlorinated pesticide chlorophenol derivatives chlorinated pesticide chlorcmethane derivative cbloronethane derivative chloroethane derivative chlocanethane derivative chloroethane derivative chloroe' thane derivativ e chloromethane derivative chloromethane derivative chlorcmethane derivative chloroethane derivative chlorinated pesticide chlorobenzene derivative chlorobenzene derivative chlorinated pesticide dichloroace.tic acid ^ichloroacetylchloride chloroethane derivative chloroethane derivative . 17* 0755803 TOWOLDMONOO6OO11 thi l. Stannary of Plants and Processes Known or Suspected to Generate PQ3s as Inpurities (Continued) Plant Chemical Generic Chemical Class Whittaker Corp. Delaware Water Gap, FA * vitea Chemical (Pearsall Chan. Div.) Phillipsfcurg, NJ tr ichlorcacetasnide chlorinated paraffins chlorinated aniline derivative chlorinated paraffin I 13 0755804 TOWOLDMON0060012 Vvrsiii W\C. OPTS 62UI7 PCBs Controlled Wastes Ccirmjnication N . --L File MEMO RAN DO M TO: FROM: Denise Keehner, EPA/OTS Leslie Adkins, Tfersar ^ DATE: August 11, 1982 SUBJECT: List of Products that may Contain PCBs ' Generated as' Inpurities or* By-Products inn <9 CC: Liz Bryan *3 Mike Callahdtf Rich Guimondrs Bill Gunter * -o-d SZ do in ( Karen Hanmerr&trcm Sherry Sterlgig w 715-M-134 I have attached a table containing the information that you requested on products that may contain PCBs as iapurities. This table provides the information that should be useful in choosing appropriate sample sizes for analyzing FQJ concentrations. In addition to professional judgment of the Versar staff, the following sources of information ^re used to ccnpile this table: ' ' Bull i Company. 1980. Brployee exposure to chlorobenzene products. Greenwich, CN. 1980. Kirk-Othmer encyclopedia of chemical technology. Vsl. 5, 3rd ed. New York,. NY: John Wiley and Sons. LA: jaz Attachment 0755805 TOWOLDMON0060013 DISCLAIMS This document was produced on. a quick response basis for the U.S. Enviroroental Protection Agency, Office of Toxic Substances. It is a preliminary draft and contains numerous unverified estimates, meant to support a general, hypothetical analysis of the pending rule on use of PCBs in closed and controlled waste manufacturing processes. Any information provided in this docuneht should be used only with extreme caution, recognizing its tentative nature. No final version of the document has been produced. 0755806 TOWOLDMONOO6OOI4 Known Qses of Organic Chemicals Potentially Contaminated with PCBs at Concentrations Below SO ppm (cent.) ` Doe/product Compounds providing potential PCB contamination , in products* " Adhesive and paint stripper solvents Asphalt, rubber, and wax solvents Drycleaning solvent Low ten^erature extraction solvent0 Jhenolic resins Antioxidants _ Ethylating agents ' Antiknock additive for. motor fuel (tetraethyllead) Grain funigation . local and general anesthetic Berbicides Insecticides Pesticides ' .* Pha cfnaceuticals . Silicone fluids t ' I . # Chloroethylenes Carbon tetrachloride Ttetrachloroethylene . Chloroethylenes , Phenols a Phenyl ethers . ' Chloroethanes Chloroethanes Carbon tetrachloride Chloroethanes Chlornitrobenzenes, chlorofluorobenzenes, chlorobenzides, chlorotoluenes, chlorobenzenes, chlorophenols ' Chloronitrobenienes, chlorobenzenes, . chlorophenols, ehlorocyclohexanes Chlorobenzyl derivatives, chlorophenyl sulfides, chlorotoluenes, chlorophenyl phosphenes % Chlorotoluenes, chloroethanes ' Chlorophenyl silanes t * . 0755807 TOWOLDMON0060015 Known Uses of Organic Chemicals Potentially Contaminated with PQ3s at Concentrations Below 50 ppm 4 dee/product Cccgounds providing potential FCB contamination . in products3 Fire retardant and waterproof canvas and plastic Chlorinated paraffins Sigh pressure lubricants Sealants and caulks . ' Chlorinated paraffins, chlorobenzenes Chlorinated paraffins Tear gas Beat transfer fluid Chlorinated acetophenones . ' Chlorobenzenes, chloroethylenes Refrigerants Carbon tetrachloride, chloroethanes Cdor control products Chlorobenzenes Mothballs Chlorobenzenes Disinfectants Qilorobenzehes, chlorophenols Auto radiator flush * Chlorobenzenes Industrial cleaners . Degreasers QiXorobenzenes Qilorobenzenes, chloroethylenes . Antifungal agents*3 Antibacterial agents Chloronitrobenzenes, chlorobenzoyl compounds, chlorobenzenes, chlorophenols , * 1 Chloronitrobenzenes, chlorophenols Preservatives ' Chlorophenols ,< Dyes - Adhesive solven.ts . Chloroanilines, chlorobenzyl derivatives, chlorophenyl sulfides, chlorotoluidines, ' chlorobenzides, chlorobenzoyl confounds, chlototoluenes, chlorobenzenes, chlorophenols, chloroethylenes Chlorobenzenes, phenols t' % 0755808 TOWOLDMONOO6OOI6 Known Uses of Organic Chemicals Potentially Contaminated with PG3s at Concentrations Below 50 ppm (cont.) * Ose/product , Fragrances General solvents Confounds providing potential PC3 contamination . in productsa Chlorobenzophenones Chlorotoluenes, chloroethanes, chloroethylenes _ a The compounds listed above are sometimes used to formulate products and sometimes used only as intermediates in the production process. b Gsed in cooling water, metal vrerfcing fluids, litex paints, photographic solutions, leather dressings end finishes, the vood industry, construction industry, pulp and paper industry, and textile industry. c Used for dyes, perfuses, lacquers, and thermoplastics. 1I 0755809 L TOWOLDMON0060017