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ARR26-0673
Centre
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RAosneaarlchyOtrvie cal
LaboraStioerCoiloeges,,PAITnEcR.
Phone: (814) 231-8032 Fax:(814) 231-1253or (814)231-1580
-- Analytical Report
Fluorochemical Characterization of Surface WaterSamples
Mobile, Alabama (W2151)
Centre Analytical Laboratory Report No. 023-014D
_--
Testing Laboratory
Centre Analytical Laboratory, Inc.
3048 Research Drive'
State College, PA 16801
TT
M3MEEnvironmental Laboratory Contact
Kent R. Lindstrom
Bldg. 2-3E-09
P.O. Box 33331
St. Paul, MN 55133-3331 Phone: (651) 778-5352
Requester
A
Kris J. Hansen, Ph.D.
3M Environmental Technology& Safety Services
Bldg. 2-3E-09
.
P.O. Box 33331
St. Paul, MN 55133-3331
racerors 000970
1 Introduction
coARlneeacslttsecdaafrLoeambroerMpaootrbotrleiede,sf,AolrIactb.hae(mCaaon.anlvTyehs)iesorCoemntartseees3rtuMedyEoufnvmsiuborenfmarceeanstwsaeilgtnLreobdsaatrmoapihloeren.s roTchseoiseadG3mb%yegGrceneirto (`SpeLcifiGc fMluoSwroacsIhreemNiqcuaSelstc)headraocrtearlilzaatmipoinesb.y lAiquoidachofromsatoogprapwho/yretarnedceomwemsasosy`osprecetrmometry Thesampleswere preparedandansizedby LOMSIMSforth flowing istoffuorochemicals:
+ Table 1: Target Analysis
Periuoroocane Soma
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2 Sample Receipt
ciTnohdleievicsdiuaoamnlpsdltaeesmspwlweeerrceeonnstuoabtimnsieutrptspelwdieeirdne.iCrnhdeiacviiendui.avl cpulSasastmtoipcdlyecosfnotwaemirnteerorsencaenipdvredewaseernneGtSneo0dt3i0npAr0e.tseaTrhvceemd.soouEtinghet
3 Holding Times
tTahbei anaoyfitchaelanmaleyttheosdofusiecdewsasfrvalliodnagteerdpeargiaoidnsshaesnmaoxibmouam dhoeldeinmgetdime of 14 days, The
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4 Methods - Analytical and Preparatory 44111 SLaCm/plMoSP/rMepSaration for LCMSIMS Analysis
`rLeSOsaiMmdpSulaIelsMScwhearoneraei.ln.aSloAlrdfeosrpttheyad-smwieiltfhetxr2v0pa0octiuiolo.nnoof(f2Ss5Pa0Em)mplowealwsassoudstieaudnms1te0hrioepsrduelpf(aa0rte8e.sCohyluetSiPosnEatmcoparetesmioo1vne TmdhieesichcaaarrndveliddwaganesdwactashlfoerScstPtdEfuoctoeladunwmailnyhswi5assbmyLtohLefOn4McS0uI%tMeSmd.elwihtaThnhoi1ls0it0nrw%eaatmtmeeetrnhstaonlrouelts.iuotne,Ad"STinhmeaisnlposeaarriteosineosonf
`concentration of the samples prior to analysis.
412 Sample Analysis by LCIMSIMS
{`cHhInoPelHLuPmCuLni.Csde,Bpmaaaorsnabtelaideoonl,pnihtEahosSqfeeMea,ufxSfhtoirepnairtctoatyvoniifdsateislhnjeaesacrntaraepedlitydaatineanfdneoddpraftaoschrsceueasrdtacathtteehirromaonceuaigarrhyinapssthfilacoisrqeaaumiindona-ultpnyhhtaieosncefgoclaihumrwoemim.ndarteeFolagoartlnaiogpvweheiintcgo. mkornigodawnntiecfmupcecorrmaoptcouhrueenmsd;isc,maolilnaecrcueudlbienssgeerfruvecerdooncaihnzedemdiq,cuaaflnr.iaigaEmtleeendctteardgo,asipanrsnatdysidtseagtneedncaetrreddas.l.lyIpoensatcohadraacireermtuionoyf AanHaelwydztet-tPheacskaamrpdleHPe1x1a0c0tsH.PLACnaslyyssitsemwcaosupploerdtfoomaedMicursionmgassselUelcttiemda MreSaIcMiSownamsoutseedrto (S2o.nRdM)M.SSIaMmSplmeetshwoedrseuesxetdrafcotreadnoalnys5i/s1a7n/d00iannsdtraunmaelntyzpeadrbamyetMeSrIsMcSaon nbe5/f2o0u/n0d0i,n aTihteacHnPeLnCt
5 Analysis
51 CAaTl-piobirntatciaotnaioncurvewas analyzedatthebeginingandendofth analyticalsequence pcf5oo0r0m,etllhaaeniocdooron1emct0apo0cos0hufneingpcldoiLsdinn(totpf1pi)Un)tsaTeinrhnedgsetcr.oenTssefhapireocrnecensaglterioebosrffasttidhieooetnqneuwrPamoiniihtnnaittsa1itwoinewoern(ie1gl)hpotwrnievenpergare,rsedutdehstoaeSttrhlme0oi,cpnoee2n5dy,c.-e5nn0Aei,rrcao1at0uii0pp,ntaa2at5coa0ss., curve is acceptable f20.985 (2 0970), Calibration standards are prepared using the same SPE procedure used forsamples. tcGhaorlonturcgahetoounnttcrhtheaecrtkeiasnwotaialntnyidssniasr+d-ss2ew0qe%ureoenfcatenh.aelaycCztooumdaplplviaaarlnoucdeei..caly (eavbeiraynheodeIftotfhee. ssamipnledinjaenctaogresr)
Forthe resus reported here, calbation criteria were met,
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52 `BEexlxttraraanccttkiiosonnbbllaenrkkssswheoruledpnroetphaarevde aannyd taanraglelyzaendawietsh epverry eeaxriaoscrieo3nb0nbvaetttchheocfosnacmmptleast.onThaey helowievel clbraton standard. For these samples he extraction Hawenr cokmpsan lhIeanvvseeltucamaenlnybtatbtaraogrnektsstaaninnadyattrhdee,sfoaprnrmdeosfaefntdtreaakfnnoomrwentahbhaoinvgoehl-etsvhoeellvlesnoatwmepwvleeersle. caasAtograaant.aoltnyhzsedtbaaatfneesrd,esvheraayiigpohet-r `samples presented here the nsiument blaarecnompkianst.
53 `SSuurmorgoagleasptieksesarenotacomponeofntteLMSIMS analytical method 54 MM1a0at0trnrigxisxpiSukspeisinwkgeearlslecpormeppoaurneddsfoorfeivnetrreysft.edMaslarmixplsep(kexrcelcuodvienrgibeasankes)gaivtenaicnoAnctenttaractihoenof
cPoOmApoRunshdoswsehdowleodwmmattispsipkiekse rreeccoovveerriieessbientswaemepnle7s0-M1C3-04%0iTnHalasnadmpMlCe-s4.64Fs. Al mbar `sFiheoolwdmesdppirkeoecsootvfewriennirteedrsesbpster.tepwaeFrieeenldd70ospn-i1ks3e0a%mre.pcloeveMriCesOa1reHalaslo gaivceonnicneAntaractihoneonf 1C0.0Agl losumspinrgaasll 55 AtDlhuepfsileailmdcpsalaetmerpslese(ienxsActutdauincgh.msbeantnk5.)were analyzed in duplicate. Rests are given longwith 5.6 MiLolamibpoowrautanetsrowwraeysrCasbopenitktwerdeowelinthS7aa0llm-1pc3ol0me%psionuenadocfh LtCeSr.estRat 2e5ancd2a5ro0egnvge.newAlhlrrheocirovweedrfeoivsrsea1lsl Atachment D. 57 Sample Related Comments mtFhaiernlonduegbrhlaaasntkhhyespaoemrepclererbsscacamorpntsliiedssgt.eedwaofseamdpdteydctoonttahieneerms.plyFo-crotnytamiinletrearnsdoafntaylpyeze|dwIantethrefiSteermead 6 Data Summary Plseeotaachsmeent 8 for adetaled stingofthe anata results.
7 Data/Sample Retention
`Samplesaredisposedof one monthaferthereportsissued unlessotherwisespecified. Al efloelcdterrosnimcadianttaaiinesdarbcyhCievnetdeo,nretievablemedia andhardcopy reportsare storedin data
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8 Attachments
81 AtachmenCranckCusoy 62 Aten Rots. 83 Aachen: C:MatixSokaRecovers (Fi andLabor Spee) 84 AtatmentD; LOMSMSRawAraceli
9 Signatures
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