Document XRq0yVo9ZKKejbar61wXy9Gjx

SM-32-OPC (<-rs| SHELL OIL COMPANY , SHELL CHEMICAL COMPANY DEER PARK MANUFACTURING COMPLEX PLAINTIFF'S EXHIBIT TO HEAD OFFICE - MANUFACTURING HEALTH AND SAFETY - MANAGER DATE FROM NOVEMBER 11, 1977 I SUPERINTENDENT ENVIRONMENTAL CONSERVATION DEER PARK MFG. COMPLEX SUBJECT TOXIC SUBSTANCES* CONTROL ACT (TOSCA) INVENTORY LIST We have reviewed your memorandum of September 8, 1977, with regard to all products, raw and process materials and intermediate streams manufactured or consumed at Deer Park Manu facturing Complex. The attached lists summarize additions to the attachments of the September 8 subject memorandum. j If you have any questions concerning this survey, please contact our V.J. Moravec. Original Signed by R. V. Mattern VJM:oc R* v* Mattern Attachments be: H. J. Bettencourt/K. R. Arnold R. Lopez/H. R. Campbell R. V. Maf^^rnke-thbcopyfo* J. L. flivard C. H. Rivers/V. J. Moravec File Env. Con. Chron (2) I \, i I * j i DPMC-09045 LAM 002932 (-7S) SHELL OIL COMPANY SHELL CHEMICAL COMPANY DEER PARK MANUFACTURING COMPLEX TO DEER PARK MANUFACTURING COMPLEX SUPERINTENDENT ENVIRONMENTAL CONSERVATION DATE OCTOBER 31, 1977 FROM MANAGER PROCESS ENGINEERING - RESINS - DEER PARK MANUFACTURING COMPLEX SUBJECT TOXIC SUBSTANCES CONTROL ACT (TOSCA) INVENTORY LIST We have reviewed the memorandum of September 8, 1977, from Manager Manufacturing - Safety and Health Office with regard to that portion of the Resins Business Center materials and products list that involves the Deer Park Manufacturing Complex, and suggest the changes as noted in the attachment. Please contact Messrs. D. C. Merdian or H. H. Jenkins if you have questions regarding these changes. HllJ/sp Attachment cc - L. S. Alpert K. R. Arnold M. S. Johnsen D, C. Merdian Resins Business Center E. R. Bell J (Lcsc^z E. L. Acosta DPMC-09046 LAM 002933 ATTACHMENT Add "Tetramethylammonium Chloride" as noted in E. R. Bell'smemo of February 2, 1977, to Mr. R. F. Glassner, HS&E. LIST B Item 2 - Add "Tween 20". Item 4 - Add "Modaflow". Item 6 - Add "and solutions containing xylene". Item 7 - Should read "Solid Epichlorohydrin/Tetraphenolethane Epoxy Resin or solution in Methyl Ethyl Ketone". Item 9 - Omit "WPE* 6000". Item 22 - Should read "contains small quantities of 2,2-Bis (o,p'-hydroxyphenyl)" Item 25 - Amine nitrogen content range should be "3.5-5.5%w". We do not see any items in Curing Agents list that would include Curing Agents S-4, S-5, S-6, which have been made within the stated time period and which are in inventory at DPMC; thus, add: Item 45 - "Solutions of Ethylenediamine, Diethylene Triamine, or Versamid 140. Mixture and/or solution containing one or more: Dutrex 298, Dinonyl Phenol, Hexylene Glycol, Shell Oil 60 Spray Base." Also add as: Item 46 - "Meta-phenylenediamine" Item 47 - "Adduct of Aniline and Meta-aminophenol with Liquid Bisphenol-A/Epichlorohydrin Epoxy Resin (WPE 185-192)','. DPMC HHJ 10/31/77 DPMC-09047 LAM 002934 Nove~ver 1, 1977 R. V. pkt-tern Additions to TOSCA Inventory List R. L. Brunner's memorandum of September 8, 977, requested that DPMC review the inventory f our products, raw and process materials, nd intermediate streams as required by he Toxic Substances Control Act (TOSCA). Since.there were a number of nconsolidated inventory lists for the ntermediates area appended to Brunner's emo, we selected two which appeared the ost complete for review. We have attached hose two lists which we used as our starting 3int plus lists by process area of idltional chemicals which should also be lcluded in the TOSCA inventory. This review was time-consuming, ... lefficient and most likely incomplete. There . obviously a need for a company-wide ocedure for routinely capturing such (formation and inputting it into a central, mputerized data bank, so that Shell has an ergreen, quickly-accessible inventory the chemicals it uses and makes. tachments - K.R. Arnold L.W. Horstman Brsib C. A. BAYENS DPMC-090AO LAM 002935 DEER PARK MANUFACTURING COMPLEX ADDITIONS TO TOSCA INVENTORY LIST ALLYL CHLORIDE/D-D*/CRUDE EPICHLOROHYDRIN Raw and Process'Material Additions Alumina Sulfuric Acid Betz J-12 Betz 39A Natural Gas Ammonia Acetic Acid Acetonitrile Octane Methanol n-Propyl Alcohol Acetone Ethylene Glycol Carbon Monoxide Carbon Dioxide Hydrogen In Propylene and AC LE Driers * For CWT Treatment For CWT Treatment For CWT Treatment As Furnace Fuel For HC1/C10 Leak Detection In AC Titrator in Crude ECH Unit In GPH Quantities in Crude AC Prefractionator For Outer Seal Flush on C,/HC1 Pumps As De-icing Agent in Crude AC Unit As De-Icing Agent in Crude AC Unit To clean D-D Columns As Antifreeze for Instrument Seal Legs In Sniff Gas to Crude ECH In Sniff Gas to Crude ECH In Sniff Gas to Crude ECH Intermediate and Impurity Additions 1 Chloroprene (Listed) cis 1,2,3 Trichloropropene trans 1,2,3 Trichloropropene 1.1 Dichloropropane 2.2 Dichloropropane 1.2 Dichloropropene 1.1 Dichloroethane 1.2 Dichloroethane Acrolein Allyl Alcohol Sodium Hypochlorite Benzene Iron/Nickel Chlorides Has both cis and trans isomers Present with 1,2,3 Trichloropropane Present with 1,2,3 Trichloropropane Present at Tenths of % levels in D-D Present at Tenths of% levels in D-D Present at Tenths of % levels in D-D Present at Tenths of% levels in D-D Present at Tenths of % levels in D-D Present in Small Amounts In Crude ECH Present in Small Amounts in Crude ECH A By-Product in Sniff Gas Absorber Present at 0.2% By Weight Level in D-D Flasher Bottom Corrosion Products Product Additions None *Registered Trademark U.S. Patent Office DPMC CAB:sib 11/1/77 DPMC-09049 LAM 002936 DEER PARK MANUFACTURING COMPLEX ADDITIONS TO TOSCA INVENTORY LIST FINISHED EPICHLOROHYDRIN/TRIOL (SC-2590) Raw and Process Material Additions "Ethyl" Antioxidant - A mixture of: Anti-Fouling Agent in LE Column Or tho-Ter t-Butylphenol 2.6 Dl-Tert Butylphenol 2.4.6 Di-Tert Butylphenol and Other Phenols Intermediates and Impurity Additions 2-Chloropropene Ethyl Chloride 2-Chloropropane > J n-Propyl Chloride Acrolein 1.1 Dichloromethane Isopropyl Alcohol Dichloroethane Benzene 1.2 Dichloropropene Acetonitrile *1 3.3 Dichloropropene f Chloroform J 1.2 Dichloroethane 2.3 Butanedione Hydroxyacetone Chloroacetone 1,2:5,6 Diepoxyhexane Products Replace Glycerine with TRIOL (SC-2590) Constitutes ca. 17% of ECH LE Constitutes ca. 15% of ECH LE Present at ca. 4% in ECH LE Present at ca. 4% in ECH LE Less than 1% in ECH LE Less than 1% in ECH LE Less than 1% in ECH LE About 1% in ECH LE Constitutes ca. 4% of ECH LE Less than 1% in ECH LE PPM Traces in Finished ECH Product Intermediate of 2,3 Butanedione in G-300 Intermediate of 2,3 Butanedione in G-300 Present at 100 PPM levels in ECH HE DPMC CAB:sib 11/1/77 DPMC-09050 LAM 002937 DEER PARK MANUFACTURING COMPLEX ADDITIONS TO TOSQA INVENTORY LIST CHLORO-ALKALI Raw and Process Material Additions Calcium Sulfate Ammonia Bromine Sodium Carbonate Betz.2820 Hydrochloric Acid Asbestos 1,1,1 Trichloroethane Methylene Chloride Sulfuric Acid Intermediate and Impurity Additions Sodium Sulfate Hypochloric Acid Hypochlorous Acid Sodium Hypochlorite Sodium Chlorate Nitrogen Trichloride Carbon Monoxide In Raw Brine In Raw Brine In Raw Brine Used to Precipitate Calcium from Raw Brine Flocculent (Polyacrylamide co-Polymer) Used to Acidify Raw Brine Used for Cathode Diaphragm Degresser for Cell Parts Used to Clean Chlorine Process Equipment For Drying Chlorine Co-Product of Calcium Carbonate Precipitatioi From Chlorine Absorption in Water From Chlorine Absorption in Water From Chlorine Absorption in Caustic From Chlorine Absorption in Caustic Results from Chlorination of Ammonia in Brin< Trace Concentrations in Chlorine By-Product from Chlorine Drying Process By-Product from Chlorine Drying Process Product Additions None DPMC CAB:sib 11/1/77 DPMC-09051 LAM 002938 DEER PARK h^UFACTURING COMPLEX ADDITIONS TO TOSCA INVENTORY LIST VINYL CHLORIDE MONOMER/ORGANIC CHLORIDE INCINERATOR Raw and Process'Material Additions Silica Gel Iron Chloride on Alumina Molecular Sieves Sodium Sulfite Sodium Phosphate Propane Isopropyl Chloride #2 Fuel Oil Natural Gas Fuel Gas 1 Calcium Carbonate Hydrogen In Instrument Air Driers Catalyst in Fifth Stage Reactor In VCM LE Driers In Oxy Boiler Water In Oxy Boiler Water In Propylene Supply In HC1 From G For Furnaces To Neutralize Incinerator Acid To Reduce Chlorine to HC1 Downstream of Incinerator Intermediate & Impurity Additions ef *7 ___ - Acidic Acid Dichlorometnane Ethyl Chloride Sodium Carbonate " Calcium Carbonate Calcium Hydroxide Iron Hydroxide Nickel Hydroxide Nickel Chloride Nickel Carbonate Sodium Formate Calcium Formate Copper Chloride Copper Hydroxide Copper Carbonate Iron Carbonate Ethanol Ethylene Oxide Alpha Glycols Ethylene Glycols Bis-2 Chloroethyl Ether"\ Pentachloroethanes j Hypochlorite 4. Sodium Hypochloride Calcium Chloride Hydrochloric Acid DPMC CAB:sib In Finished VCM In Finished VCM In VCM LE In VCM LE Column Reflux Accumulator In VCM LE In Quench Column Purge . In Incinerator Acid Stream In Incinerator Acid Stream From Neutralization of Incinerator Acid Major Intermediate From Incineration DPMC-09052 LAM 002939 JO-i-l- M HOUSTON AND NORCO rL , f TH u)oot> to Ufl< 0^ui-ceo. VINYL CHLORIDE MONOMER Vinyl Chloride 1, 2 Diehloroethane (EDC) Hydrogen Chloride Chloromethane Chloroform Carbon tetrachloride Acetylene Methyl Acetylene Mono vinyl acetylene 1, 1 Dichloroethene 1, 2 Dichloroethene .. 1, 1 Diehloroethane 1,1,2 Trlchloroethane Trlchloroethene Tetr.achloroethene 1, 1, 1, 2 Tetrachloroethane 1, 1, 2, 2 Tetrachloroethane Pentachloroethane 2 Chloropropene 1`Chloropropane 1, 2 01chloropropane 1, 3 Dichloropropane 3 Chloro 1, 3 butadiene (chlproprene) Butene-2 .Butadiene 1, 2 Dichlorobutane 1, 3 Dichlorobutane 1, 4 Dichlorobutane 1,1,2 Trlchlorobutar.e 1, 2, 4 Trichlorobutane 1, 4 D1chloro-2 butene . Vinyl bromide Acetaldehyde Carbon monoxide Carbon dioxide Trlchloroethanal (Chloral) Chlorine Ethane Ethylene Methane Sodium hydroxide Sodium chloride Ferric chloride Ammonia Cuprous chloride on Alumina Alumina Propylene ALLYL CHLORIDE - CRUDE EPICHLOROHYORIN Allyl Chloride Epichlorohydrln Ethyl Chloride 1 Chloro propane 2 Chloro propane ' , 1 Chloropropene 2 Chloropropene Cls 1, 3 Oichloropropene Trans 1, 3 Oichloropropene 2, 3 Oichloropropene 3, 3 Oichloropropene 1, 2 Dichloropropane 1, 2, 3 Trichloropropane 1, 5 Hexadiene 1, 2 Oichlorohydrln 1, 3 Dichlorohydrin Monochlorohydri n Glycidol 2 Chloro allyl alcohol Hydrogen chloride Hydrochloric acid Methyl isobutyl ketone Chlorine Propylene Propane Ethylene Ethane Butane Cutylene Mercaptans Carbonyl sulfide Sodium nercaptides Sodium hydroxide Sodium chloride v Calcium hydroxide Calcium carbonate Calcium chloride Sodium carbonate Carbon dioxide Armohib-28 (H.i-ed long chain fatty amine) DPMC-09053 LAM 002940 HOUSTON PLANTS ALLYL ALCOHOL Allyl chloride Allyl alcohol 2 chloro propane 1 chloro propane 1 chloro propene 2 chloro propene Isopropyl alcohol Normal propyl alcohol Dlallyl ether Sodium hydroxide Sodium chloride ETHYL CHLORIDE Ethylene Ethane Acetylene Ethyl chloride Methane 1, 1 Dichloroethane Vinyl chloride 2 chloropropane Secondary butyl chloride Hydrogen chloride Ferric chloride Carbon dioxide Hydrogen CHLORO-ALKALI UNIT Sodium chloride Sodium hydroxide Chlorine Calcium chloride Magnesium chloride Calcium hydroxide Calcium carbonate Magnesium carbonate Carbon dioxide Hydrogen Oxygen Nitrogen CRUDE EPICHOLROHYDRIN-EPICHLOROHYDRIN- 6LYCER1NE " Epichlorohydrln Glycerine Allyl chloride 1, 2 Dichloropropane 1, 3 Dichloropropene 3, 3 Dichloropropene 2, 3 Dichloropropene 1, 2, 3 Trichloropropane 2 Chloroallyl alcohol Mono chlorohydrin 1, 2 Di chlorohydrin 1, 3 Dichlorohydrin Glycidol Methyl Isobutyl Ketone Tetra chloropropyl ether Diglycerol Poly'jlycerol s 2, 5 bis (hydroxy methyl) p dioxane 2, 6 bis (hydroxy methyl) p dioxane Hydroacrylaldehyde glycerol acetal Glycerol -n propyl ether Glycerol allyl ether Sodium carbonate Sodium chloride Carbon dioxide Aqueous hydrochloric acid Calcium carbonate Calcium hydroxide Calcium oxide Calcium chloVide Activated carbon Toluene DPMC-09054 LAM 002941 ATTACHMENT CHEMICALS EXISTING IN CHEMICAL INTERMEDIATED PROCESSES HYDROCARBONS Methane Ethane Ethylene Acetylene Propane Propylene Methyl acetylene 2-Butene Butadiene Mono vinyl acetylene 1.5 Hexadlene Monasol 125 ORGANIC CHLORINE COMPOUNDS Chloromethane Chloroform Carbon tetrachloride Ethyl chloride Vinyl Chloride Monomer 1.1 Dichlorethane 1.2 Dlchloroethane 1.1 Dlchloroethene 1.2 Dlchloroethene 1.1.2 Trichloroethane Trichloroethene 1.1.1.2 Tetrachloroethane ). 1.1.2.2 Tetrachloroethane y Pentachloroethane 1 Chloropropane 2 Chloropropane 1 Chloropropene 2 Chlrorpropene 1 Chloro 2 Propene (AC) 1.2 Dichloropropane 1.3 Dichloropropane cis, 1.3 Dichloropropene trans 1.3 Dichloropropene2.3 Dichloropropene 3.3 Dichloropropene Minor tron-.poncn1.-C3 feed to AC Minor component HC feeds to post processes Major feedstock item Minor component In feed to EC (being reduced Component to 30% in propylene feeds Major feedstock item PPM traces in VCM product PPM traces in VCM system PPM traces in VCM system PPM traces In VCM system 8.3% in fin. AC, to 1% in ACLE and AA CBM (PCD Prodncr) Extractive distillation Solver AN unit To 70 pjnu In VCM product VCM LE streams contain to 25% VCM LE streams contain to 30% Major pure product and 30% of EDC LE Major pure product VCM 11 glit end steams contain to 1% Major Intermediate to VCM Various VCM LE streams contain to 1% Various VCM I.E streams contain to 15% Various VCM HE streams contain to 90% Numerous VCM streams contain to 2% Component of EDC $E to 6% Trace in VCM-EDC Heavy ends To 1% in VCM 1.E and AC streams 90% of 1PC column butts, AC plants To 0.5% In finished AC, to 4% in AC LE To 60% in AC LE, 0.2% in finished AC, PPM in VCM system Major pure product 19-28% of D-D, fraciton of % in VCM HE and Crude ECH . Fraction of a Z in VCM HE and Crude ECH stre 23-29% of D-D 23-29% oT D-D 5-9% of D-D, 10% of D-D.botts 3-4% of D-D DPMC-09055 lam 002942 io/N/7^i dm* ORGANIC CHLORINE COMPUJNDS (Cont'd.) , 1.2.3 Trichloropropane (TCP) 2 Chlorobutane 1.2 Olchlorobucane 1.3 Olchlorobucane 1.4 Dlchlorobutane 1.1.2 Trlchlorobutane 1.2.4 Trlchlorobutane 1.4 Dichloro 2 Butene 3 Chloro 1.3 butadiene (Chloroprene) Trichloroethanal (Chloral) Eplchlorohydrln 2 Chloro allyl alcohol Monochlorohydrln . 1.2 Dichlorohydrln 1.3 Dichlorohydrln Tetrachloropropylether To 75% in Major ECU by-product streams PPM in rear l mu product - EC process Several tenths 2 in VCM HE screams To 52 in VCM heavy ends screams To 1.5/. in VCM heavy ends streams Traces In VCM heavy ends streams Traces in VCM heavy ends streams Traces in VCM'heavy ends streams 0.1% in VCM col- bottoms ^ 0.12 in HOC. side screams Major pure product Minor impurity In ECH and AA systems Major intermediate - Houston plycerine proce Major intermediate - Houston glycerine proce Major intermediate - Houston glycerine proce To several /. in crude Trichloropropane ORCANIC BROMINE COMPOUNDS Vinyl Bromide Lov PPM in KIC reactor product. Eliminated ALCOHOLS Allyl Alcohol Isopropyl Alcohol Methyl Alcohol Normal propyl alcohol Secondary butyl alcohol Major pure product, and a major intermediate 852 of major feedstock stream to HP Trace quant it lte in AN-AA side streams To 1% in major AA plant streams Major intermediate product KETONES AND ALDEHYDES Acetaldehyde Acetone Acrolein Dihydroxyacetone Formaldehyde Glyceraldehyde Methyl ehtyl ketone Methyl isobutyl ketone Methyl Vinyl ketone Propionaldehyde Major by-product. Shipped in tank cars Major by-product of HP manufacture Major product t 94% pure min. Trace quantities in Norco crude glycerine Minor component of crude HP Trace quantities in Norco crude glycerine Major hy-product of AA process Minor component of recycle ECH - Houston About 0. 3". in crude acrolein' To 3.5'.' in 1 ini sited acrolein, to 72 of AA C< DPMC-09056 Lam 002943 POLYOLS Glycerine Glycidol Diglylerol Polyglycerols ACIDS Acetic acid Dipertungstic acid Formic acid Hydrochloric acid Hydrogen chloride Nitric acid Phosphoric acid Propionic acid Sulfuric acid Tungstic acid GASSES Oxygen Nitrogen Carbon dioxide Hydrogen OTHER CATALYSTS AND RESINS Copper on Macroport SA 5218 Cuprous chloradejon alumina Ferric chloride * Aaberlite IRA 904 Resin OXIDES Hydrogen peroxide Propylene oxide Ethylene oxide Major pure produce Major intermediate in glycerine processes To 15% in glycerine Foots Still bottoms To 15% in glycerine Foots Still bottoms. Minor impurity - Crude HP Intermediate in Norco Clycerinc Process Minor impurity - Crude HP Major by-product stream on solution of HCI Major chemical in EC, AC, VCM plants Inhibitor fur hydrogen peroxlcde Inhibitor ofr hydrogen peroxide Minor impurity - Crude HP Inhibitor for hydrogen peroxide Catalyst lor Norco glycerine process Major feed gas to acrolein Residual from oxygen production Major by-product - glycerine, ECH plants, CaCl2 mt'KTo 20% chlor-alkali sniff gas Catalyst for acrolein reaciton Catalyst for ethylene oxychlorination process Catalyst for ethylene dichloride manufacture Rohm (> Haas resin for Tungsten recovery - Norco glycerine Major product to 90% concentration 0.3% in crude acrolein; to 15% in AA LE col'-rat To 0.4 in finished acetaldehyde' \ DPMC-09057 LAM 002944 CHEMICALS REFINERY \ ' hy ~ ^,z/W/77 Nalco 6RB-837 Nalco 5170 Nalco 169' ROKON Nalco 4RE-238 WRIGHT Ethyl Package 9 Toluene Ethyl 733 Dowcorning 200 fluid Methyl ethyl ketone' Kontol 430-W ~ Diethanolamine Sytfolane Kontol 424 Diisopropanolamine Zimmite - ZC332 Sodium Carbonate R16H Platinum Catalyst Ar|uad 2-C Nickel Carbonyl M. D. A. Sulfur . Methanation Catalyst KAT-11-3 . Shell Hydrotreating Catalyst 214 SMR Catalyst Katalco 22635 Shell Hydrotreating Catalyst 244 Hi Temp Shift Cat C-12-1-05 Shell Hydrotreating Catalyst 324 Lo Temp Shift Cat KAT-52-1 & 1G Shell Hydrotreating Catalyst 344 Shell Hydrotreating Catalyst 514 Shell Hydrotreating Catalyst 524 Shell Hydrotreating Catalyst 544 WASTE PRODUCTS To Desalter brine Spent Sulfuric Acid Spent Sulfide Caustic RAW MATERIALS Isopentane BLENDING COMPONENTS BEU Raffinates Mixed Xylenes C^ Aromatics PRODUCTS Blended Liquid Refinery Fuel SR Mixed Butanes BYPRODUCTS Or Disposal Streams Pyrolysis Pitch DPMC-09058 LAM 002945 INTERMEDIATES SR Kerosene Mol Sieve feed kerosene SR Flasher liquid tops Debutanized naphtha C^/200 Secondary naphtha 200/425 HYI Gas Oil HVI.100 Distillate .HVI 250 Distillate HVI Heavy Distillate HVI Short Residue LVI Gas Oil LVI 65 Distillate LVI 200 Distillate. LVI 750 Distillate LVI Slop LVI Flux ' Deasphalted Oil 100 Distillate Raffinate 250 TQ Distillate Raffinate 250 MQ Distillate Raffinate Heavy Distillate Raffinate Deasphalted Oil Raffinate Naphtha 100 Distillate Extract 250 TQ Distillate Extract 250 MQ Distillate Extract Heavy Distillate Extract Deasphalted Oil Extract 100 Dewaxed Raffinate 250 TQ Dewaxed Raffinate 250 MQ Dewaxed Raffinate Heavy Dewaxed Raffinate Deasphalted Oil Dewaxed Raffinate Crude 115/120 Wax Crude 130/137 Wax Crude 140/150 Wax Crude 160/170 Wax Raw 124/126 Wax Raw 140/142 Wax Raw 158/162 Wax Raw 170/180 Wax Raw 145/150 Wax Raw HMP Wax 100 Soft Wax 250 Soft Wax Heavy Soft Wax Deasphalted oil Soft wax CR-3 Reformate Hydrotreated Cat Feed Cat Cracked P.D. CC Heavy Naphtha CC LGO CC HGO CC Tray 12 CC Slurry A list of proprietary chemicals presently used, or used occasionally in water treating in the Shell Manufacturing Complex: Betz 39A Betz 35 Betz 419 Betz J-12 Betz 2890 Betz 2820 Betz C-20 Foam-Trol 260C Adjunct 2V Liqui-Treat AL Corrogen Betz 46S Betz 50 Betz 408 Betz 633 Betz 2885 Betz 2810 Betz NA-7 Wrico 55 Wrico D-9336 Wrico E-1927 Wrico BGA Zimmite ZC-322 Zimmite Chemtrol 12 Zimmite AF-198 Zimmite ZM-136 Zimmite Chemtrol 5B Zimmite Chemtrol 850 Water Treating Resins Calgon TG-10 Calgon BA-11 , Calgon C-l Antifoam Calgon K-91 Calgon NL-80 Calgon Catflock T Calgon CL-50 Calgon CL-707A United Chemical Boiler-Hib 1000 A list of bulk commodities used (not mentioned elsewhere): Water Ferrous Sulfate Solution Sodium Sulfite Sodium Hexametaphosphate Sodium Silicate Nitrogen Air Fuel Gases Fuel Oils DPMC-09060 LAM 002947 November 14, 1977 TO: L, J.Lambin - Process Engineering-East FROM: T. J. Nedderman - Phenol/Acetone Plant Start-up SUBJECT: List of Raw Materials, Products, and Chemicals and Catalysts Used in the Phenol/Acetone Plant The following list was compiled per your request. If you need additional information, please let me know. Raw Materials Propylene Propane Benzene Hydrogen Finished Product Phenol Acetone Intermediates (Suitable for Sale) Cumene For catalysts and chemicals used in the process, see the attached list. cc: VAM T. J. Nedderman DPMC-0906I LAM 002948 CATALYST, CHEMICALS & FEED STOCKS N U. o -s cV O 5>g-E i) t & o <o. A 2a Qgs o V g fc S-f c ft 5 > Is *>Vb43> *DCs- o E .' O S; e CM ^ SO 5? *5 -- crs JOt oo --o< >> O 40 . I0-- <M CM 0 O0 > s!- > 3O wE o --o O>O) >00 to*o\ frOo <o***Nn 00*0 00 Sc E9 E3 E3 aa Z*4>/ SQvj o /g| It D i) 22 I VV 00 % s 2 *3. s! c* <c Ol CM S S. > -O' O sN Oo aCr\n o w^ ^ own 0id0 CD E3c bE3 E3b OOQ L> J > i.O <5. J< iI *vs7 U%.!*: *O Sp bi -S'S < KNKKNK fO (*\ f'S > NO N0 wrJri O aJ si awo a. 2 |s 3w !* as O D o c00 ID 6.i => u < u <40> o: fc >j s < <- u <u4Q) XVt * o *bD. W s3 < X X WO 8> k. 40 <O 05 2o cu (DO u 4c0 0* fc V >* 8 E 3 <u U s 4) < O tu? > X kO 5 < <S oo EE v0 ; NO oE o o E ^i J*e LO *C>0*M4N0 O 2J) V4Qe-1 S| 2 4 IS E Q3 -rv* '<tf*r *? E 3 V> 2u #0 JoP\ t- o < O .1 .O 4 cg AC 88 8 HH E3b> a -g * gl g *-5 H -- oo 82 o *Mb43-04* *Mbv34*-0i Z LO 4^ o Ts3 ul It z> k N* N On. NO --0< OCM 0 2 X= iEi o fS -- ONON 00 - K ?IE 06 u E(0 S'* Si *orss *nos\ * * .fc bO > =cs vo- iO XU i fuc J* del* 8 o 2 D OK 2 IU 2 u <a/) IU to ts o v 2 2c <0. sz D o cc Je=x oO 2^ <y ys 22 UJ 3 O-* 2 2c 8 o u U-5 u SI 15 1 *Vo *^S3 o3c^; 6 > 1 E E 8 t;, E < * 2"C < v I X o DPMC-09062 LAM 002949 o & N ON J oNOOn o0N "8- fc > z> "S V 4-- IE ^y u ao ^ CSJou<v^Kvlo 2tfr fWf0"0XMl "44 T? J " *n >N> W X o *\ J> H 2> d> -sg h- mON d> v- 2 OON I oo f' *0 OO Jt I I ' C > > Ci 0 * S>3s u 8.8. aa je 0 C 4c> 0 C & 0 a. oa a c0 S3 JL 4Mg4 Sf0c3 1 --* < oo -a o -a o -- o -a O -- o c o 4c3 6 si o II U ft I uO) *5 *5 ft u 1t/*5> oJV>fr .1 fs. iii *o-No. r> 5[ *n fM <M *fNN wJ C* S N8 N 0 cm4 oQ * so fN*. M N * <rV\| fM CM .1 Oo so CM N NO 5 s u 404 V) r 4 1. 0 a >* u t- && oo 88 O > au> >O * *oo r*N ON 2 50 z6 1 o *0 8 j> 0 O & 0 3 1 0 a 41 C4N3 0C (0 # ac40wOo3. 6 -0DoL>0.> X 4) 4Co4 0 u < , #* Jc0 >s %j & is , On *4 --4 fM ON ^o u t >0 HL. 0 0 S* 0c0 1 a 560 gal 560 gal W0N-OMKhNOV^On0O\O0--ONK Ovini/)^ O--4 Or\ NOO'**\ K NNNN V 0 V00 (Q CQ tU CQ CQ Betz *>6S Betz 633 Sustained Operation Inhibitor Inhibitor 0 44*4 2 0vC>C*0- fOe kO k.i> 44 44 5:0.-25 SzqO. .'a O V: i/i JC DPMC-09063 LAM 002950  V -i K November 8, 1977 Mr.'yfy'^/Mattern: I have reviewed the Toxic Substances Control Act (TOSCA) inventory list. If there are any chemicals we are using or making that are not included in here, I can't find them. As best I can tell this is complete. CES:pab . *3 DPMC-09064 LAM 002951