Document XRRaDXn6y4bkYX8XX1yeoLaXG

I Material Safety iData Sheet (conoco) [ Emergency Medical Telephone (800) 441-3637 C I 0 65 MTBE L MATERIAL IDENTIFICATION Name MTBE CAS Registry Number Mixture; See Section XI Synonyms Methyl Tertiary Butyl Ether or 2-Methyl 2-Methoxy Propane Product Code 1515 Chemical Family Alkyl Ether Transportation Emergency Phone l-(800) 424-9300 (Chemtrec) H. OSHA HAZARD DETERMINATION The material Is hazardous as defined by OSHA's Hazard Communication St^adard% 29 CFR 1910.1200. Refer to Section XI of this MSDS for federal and state regulatory information. Hazardous Ingredients CAS Registry Number Concentration /~~ Methyl Tertiary Butyl Ether 1634-04-4 40-100% Hazardous Physical Properties Class IB Flammable - NFPA 30-1987 TIL PHYSICAL DATA Appearance and Odor Colorless, clear liquid; Terpene-lilce odor Specific Gravity (HaO=l) 0.75 Boiling Point/Range 128F % Volatiles (by volume) 100% Vapor Pressure (psl @ 100*F) 93 Solubility In Water (WL %) 5, Approx. Vapor Density (Air = 1.0) 3.1 @ 70"F Evaporation Rate (Ether = 1) 1 rv REACTIVITY DATA Stable; X Unstable; Hazardous Decomposition Materials: Oxides of carbon. Conditions to Avoid: Flame, spark, or heat Hazardous Polymerization: Will not occur. GASCOOOS/December 1988 SAL 000009451 Conoco Inc., P.O. Box 2197, Houston, TX 77252 General Information No. (713) 293-5550 C I 0 65 V. FIRE AND EXPLOSION HAZARD DATA LKLi l& UEU y Flash Point (Method used): -16*F <TOQ AntolgaltSoa Temperature: 815*F Handle and store tn accordance with NFPA procedure for Class IB Flammable Liquid. Extinguishing Medhu Use water spray, dry chemical, COj, alcohol-resistant foam. Special Fire Fighting Procedures: Water may be Ineffective, but water should be used to keep flre-exposed containers cooL If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from exposure*. Unusual Fire and Explosion Hazards: Highly flammable. Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. National Fire Protection Association fNFPAl Classification Health 1 Fire 3 Reactivity 0 HAZARD RATING Least-0 Slight-2 Moderate-2 High-3 Extreme-4 VL TRANSPORTATION AND STORAGE Storage Conditions: Store In accordance with National Fire Protection Association regulations. Shipping Information: DOT: Proper Shipping Name: Flammable Liquid, N.O.S. (Methyl Tertiary Butyl Ether) Hazard Class: Flammable Liquid UN/NA N04 UN 1993 DOT Label(f): Flammable Liquid DOT Placard: Flammable Liquid IATA* Proper Shipping Names McthyLtert-butylether Hazard Class: 3 UNNoj UN 2398 IMO/ICAO Label; Flammable Liquid Packaging Groups n IMO: Proper Shipping Names Methyl-tertiary butyl ether Hazard Class: 3.1 UN No-* UN 2398 IMO/ICAO Label: Packaging Group: Flammable Liquid n m HEALTH HAZARD INFORMATION Exposure limits for MTBE PELs None Established TLV: None Established Primary Routes of Exposere/Entry; Skin, inhalation, eyes. OASCOOOS/December 1988 2 sal 000009452 Cl 065 VHL IX. X. Signs and Symptoms of Exposurc/Mcdkal Conditions Aggravated fey Exposures Methyl tertiary butyl ether may cause irritation to the eyes, skin and lungs after prolonged or repeated exposure. Animal studies involving high daily exposure to methyl tertiary butyl ether showed some liver damage. Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, concision, blurred vision, drowsiness, and other nervous system effects; greater exposure may cause dtzrtneM, burred speech, flushed face, unconsciousness or convulsions. as Carcinogen or Potential Carcinogen by: Material NTP No IARC No OSHA No EMERGENCY AND FIRST AID INFORMATION In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Sldm In case of contact, immediately wash sldn with soap and plenty of water. If irritation develops, consult a physician. Inhalation: If Inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. Notes to Physician: Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. SPILL, LEAK AND DISPOSAL INFORMATION In Case of Spin or Leak: Evacuate areas downwind of release. Extinguish all ignition sources. If released indoors, evacuate building until vapors have been cleared. NOTE: Review FIRE AND EXPLOSION HAZARDS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Waste Disposal Method: If spilled as liquid, this product will evaporate completely. Vapors should be dispersed mechanically, if possible. 'Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provintial, and Local regulations. PRECAUTIONARY MEASURES Respiratory Protection: No occupational standards for airborne concentrations have been developed for this material. MTBE has a very low odor threshold (approximately 4 ppm), which may be offensive to some individuals. NIOSH-approved respiratory protection is recommended where exposure through inhalation may occur. Due to the relatively fast breakthrough of MTBE for respirators with organic vapor cartridges and because of its low odor threshold, it is recommended that a full-facepiece respirator with organic vapor canister be used. Ventilation: General mechanical ventilation normally adequate. Protective Gloves: Neoprene or vinyl gloves are recommended to minimize skin exposure. Eye Protection! Face shield recommended where splashing can occur. Other Protective Equipment: Sufficient to minimize skin exposure. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. Safety Precautions; Avoid contact with eyes, skin, or clothing. GASCOOOS/December 1988 3 SAL 000009^53 cI o65 XL REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 4Q CFR 261 and 302 The material contains the following hazardous substance which, when released in quantities equal to or exceeding the Reportable Quantity, triggers National Response Center notification requirements. Hazardous Substance None Reportable Quantity SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE ID SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances (40 CFR 355) The material does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spOl could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements (40 CFR 370) The material should be reported under the following EPA hazard categories: x Immediate (Acute) Health Hazard x Delayed (Chronic) Health Hazard x Fire ___ Sudden Release of Pressure __ Reactive __ Not Applicable NOTE: See Section II for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - List of Toxic Chemicals (40 CFR 372) The material contains the following chemicals) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and is subject to toxic chemical release reporting requirements. Toxic Chemical MTBE CAS Registry Number 1634-04-4 Approx. Concentration (Upper Bound! 100% TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is a mixture as defined by TSCA. The chemical ingredients in this material are in Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA. In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed oC is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it Is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 268 may apply. GASC0008/December 1988 SAL 000009454 4 C I 0 65 FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15, 40 CFR 114 The material contains the following Ingrcdlent(s) which is considered hazardous if spilled in navigable water*. Ingredient None Reportable Quantity HAZARDOUS MATERIALS TRANSPORTATION ACT, 49 CFR 172 The material contains the following lngredient(s) which is considered hazardous if spilled while being transported in commerce. Ingredient None Reportable Quantity STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1984 (PROPOSITION 45*) The material contains Ingredients) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using all petroleum products. Ingredient None PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced in Pennsylvania. Please notify us at the telephone number noted below if the material results In Pennsylvania commerce. MSDS COde: GASC0008 DATE OF LATEST REVISION/REVIEW: DEPARTMENT RESPONSIBLE FOR MSDS: PRODUCT INFORMATION CONTACT: 12/88 - Replaces MSDS dated 2/22/88 Environmental and Occupational Health Services MSDS Analyst Conoco Inc. (713) 293-5550 The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufacturers. In these instances, Conoco, in good faith relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. GASCOOOS/December 1988 sAL 000009*55 5 19-Jul-90 Conoco Material Safety Data Sheet C P 0 39 Page 1 MATERIAL IDENTIFICATION NUMBER NAME : CSPI0140 9 "CONOSOL" C-140 CHEMICAL FAMILY s Mixed Petroleum Hydrocarbons TRADE NAMES /SYNONYMS : Paraffinic/Naphtbenic Solvent CAS NUMBER NFPA RATINS NPCA-HMIS RATING WHMIS CLASSIFICATION Not Determined. I 64742-47-8 i Healths 0 Flammability: 2 Reactivity: 0 1 Healths 1 Flammability: 2 Reactivity: O Personal Protection rating to be supplied by user depending on use conditions. MANUFACTURER/D1STRIBUTQR: Conoco Inc. P.O, Box 2197 Houston, TX 77252 GENERAL INFORMATION PHONE 1 l-(?13)2V'J-55S0 TRANSPORTATION EMERGENCYPHONE : 1-<800>424-9300 MEDICAL EMERGENCY PHONE * 1-(800)441-3637 a-******#***#**## a************* *##*#***********##*****##*#***-**** ******* OSHA HA2ARD DETERMINATION Hazardous Ingredients CAS Number x Paraf f imc/Naphthenic Hydrocarbons MIXTURE l VOX Hazardous Physical Properties* Class 1iIA Combustible Liquid - NFPA Code 30-1987* The material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Refer to the Regulatory Information Section of this MSDS for other federal and state regulatory information. *****-** ******** ******** **** *#*#***** ***#********* **** *-***** ******** *#**** PHYSICAL DATA Boiling Point Vapor Pressure Vapor Density X Volatiles Evaporation Rate Solubility in Water Odor Form Color Specific Gravity 365 - 410 deg F 2 mm Hg at 100 deg F 6.2 (Air = 1.0) Nil Not Applicable Insoluble Hydrocarbon Liquid S/\^ Clear, colorless (H20sl) 0.80-0.61 19-Ju1-90 CP 0 59 Conoco Material Safety Data Sheet Page 2 MSDS Nos CSPI0140 HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Combustion products will include carbon dioxide and possibly carbon monoxide. Conditions to Avoids materials. Excessive heat, flame and oxidizing Hazardous Polymerization: Will not occur. ##***##***#*#********-*-**** **#*#**#** *** **#*****#***-**-#**.***#-#****.**..* FIRE AND EXPLOSION DATA Flash Point : 140-150 deg F Method : TCC Flammable Limits in Air, X by LEL : 1.0 UEL : 6.0 Vol. FIRE AND EXPLOSION HAZARDS Class IIIA Combustible Liquid (NFPA), EXTINGUISHING MEDIA ^ Water Spray. Foam. Dry Chemical. CQ2. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protect ion. ***.-** ***************-************-*****************-***#*-**##******** * *4 HEALJH HAZARD INFORMATION Primary Route(s) of Exposure/Entrys Skin, inhalation. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Extreme exposure or aspiration into the lungs may cause pneumonia. Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other nervous system effects* greater exposure may cause dizziness, slurred speech, flushed face, unconsciousness or SAL 000009457 19-Jul~90 Conoco Material Safety Data Sheet Page 3 MSDS Noi CSP10140 (HEALTH HAZARD INFORMATION - CONTINUED) convulsions* The product contains petroleum hydrocarbons and, as with many petroleum products, it may cause irritation to the eyes, lungs, or skin after prolonged or repeated exposure. It is highly unlikely that human exposure at or below the recommended exposure level poses a significant health hazard. In this regard, good workplace practices and proper engineering designs will minimise exposure. Animal studies show that prolonged or repeated inhalation exposure to high concentrations of some petroleum distillates has caused adverse kidney effects in male rats. However, kidney effects were not seen in similar studies involving female rats, guinea pigs, dogs, or monkeys* Also, human studies do not indicate this peculiar sensitivity for kidney damage. The significance of liver tumors in mice is highly speculative and not a good indicator for predicting a potential human health hazard. Carcinogenicity None of the components m this material is listed by IARC, NTP, OSHA, or ACGIH as a carcinogen. Exposure Limits for "CONOSOL" C-140 ALL * TLV PEL Other (Du Pont)s (ACGIH) : (OSHA) { : None Established None Established None Established Ceiling values None Established * AEL is Du Pont's Acceptable Exposure Limit. Other Applicable Exposure Limits: Exposure Limits for Component (Petroleum Distillates): PEL: 400 ppm, 1600 mg/m3 Safety Precautions Wash thoroughly after handling. Wash clothing after use. ************** *********^*******# ********#*****************-**************' FIRST AID SAL 000009458 INHALATION If inhaled, remove to fresh air. If not respiration. If breathing is difficult, phys icun. breathing, give artificial give oxygen. Call a 19-Jul-9Q Conoco Material Safety Data Sheet Page 4 MSDS Nol CSPI0140 C P 0 39 (FIRST AID - CONTINUED) SKIN CONTACT In case of contact, immediately wash skin with soap and water. Wash contaminated clothing before reuse. If irritation develops, consult a physician. EYE CONTACT In case of erontact( immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed* do not of water. Never give Call a physician. induce vomiting. Immediately give two glasses anything by mouth to an unconscious person. NOTES TO PHYSICIAN Activated charcoal slurry may be administered. To prepare activated charcoal slurry, suspend 50 grams activated charcoal in 400mL water and mix thoroughly. Administer SmL/kg, or U50mL for an average adult. **#*******#************************************************************ n ** PROTECTION INFQRMATION Generally Applicable Control Measures and Procedures Keep away from heat, sparks and flames. Keep container closed. Ground container when pouring. Do not mix with oxidizers. Ventilations General mechanical ventilation normally adequate. tightly strong personal Protective Equipment Respiratory Protections Select appropriate NIQSHapproved respiratory protection where necessary to maintain exposures below the acceptable limits in the Health Hazard Information Section. Proper respiratory selection should be determined by adequately trained personnel and based on the contaminant(s), the degree of potential exposure, and published respiratory protection factors. Protective gloves: Should be worn when any potential exists for skin contact. NBR or neoprene recommended. Eye Protection: Chemical splash goggles or face shield recommended where splashing can occur. Other Protective Equipment: Sufficient to minimize skin exposure. Coveralls with long sleeves if splashing is probable. Launder contaminated clothing before reuse. Extremely contaminated leather shoes should be discarded. SAL 000009459 19-Jul-90 Conoco Material Safety Data Sheet CPO 39 Page 5 MSDS No: CSPI0140 SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE* Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Evacuate personnel, thoroughly ventilate area, use self-contained breathing apparatus. Remove source of heat, sparks, flame, impact, friction or electricity. Dike spill. Prevent liquid from enterinq sewers, waterways or low areas. Recover free liquid for reuse or reclamation. Soak up with sawdust, sand, oil dry or other absorbent materia 1. Waste Disposal Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. Recover nonusable free liquid and dispose of in an approved and permitted incinerator. ***#**********^****#*****# **********#******#******** ***-*-*** SHIPPING INFORMATION DOT Proper Shipping Name Petroleum distil Hazard Class UN/NA No. DOT Label(s) DOT Placard IATA/IMO Proper Shipping Name Not restricted i ate : i i : Combustible UN X 26>Q None Combustible liquid *#***-****************** **>******# #***#**********************-***-**- ***** STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. ***** ************************************************************* ******* TITLE III HAZARD CLASSIFICATIONS Acute: Chronics Fxre: Reactivityi Pressure* Yes Yes Yes No No REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 Not Applicable sAt 000009460 19-.JuJ.-90 Conoco Material Safety Data Sheet Page 6 MSDS Noi CSPI0140 C P 0 ^^RE0ULATORY INFORMATION - CONTINUED) SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1906, TITLE HI - SECTIONS 302, 304, 313 SECTION 302/304 - Extremely Hazardous Substances, 40 CFR 355 The material is not known to contain extremely hazardous substances at greater than 1.0% concentration* however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 313 - List of Toxic Chemicals, 40 CFR 372 The material is not known to contain chemical(s) at a level of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and is subject to toxic chemical release reporting requirements. TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 This material is in the TSCA Inventory of Chemical Substances and/or is otherwise in compliance with TSCA. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262-265 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116.4A, Section 311 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178. Not Applicable SAL 000009461 U, I*, yu it.: lb UJNUUj-iHfcH ttKl UUo 19-Jul-90 Conoco Material Safety Data _CPO 39 Sheet Page 7 MSDS Not CSPI0140 (REGULATORY INFORMATION - CONTINUED) STATE REGULATIONS CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT OF 1986 ("PROPOSITION 65") The material is not known to contain ingredient(s) subject to the Act. ACT PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT To the best of our knowledge the material is not sold or produced in Pennsylvania. Please notify Conoco at the telephone number noted below if the material results in Pennsyivana.-* commerce. ******* ****-**************************#*******************************. . * * + ADDITIONAL INFORMATION AND REFERENCES "CONOSOL" is a Conoco trademark. ******************************************** **#*****#*****.*-* *#*#*,i.*.**** ** The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, in good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FF^EEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS 90/07/19 SHEA Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 SAL 0000094-62