Document XRJkzwVjrzBMKxqaynEbyOZjy

DEPARTMENT OF THE NAVY HAVA L S fkfACB WA RFA RE CENTER CARDE ROCK OiVlSIOH isAvAL SHIR SYS'iEW? EHOIHEER DC TATION 500! E EECAO STREET PHiLAOEI "Hin PA 1S117:-*.40 HREPT-V REFER TO 9593 Ser 635/18 1 -635(0-480 From: To: Commander, Division, Naval Philade Surfa lphia c e War Site, f are Phi Ce lad nter, elphia C , a r?Ad e r o c k 15112-1403 " Commanding Officer, Navy Environmental Health CPeonrttsemr,o u6th20, VJAohn2 3 7Pa0u8l-2 1J0o3nes Circle, Suite 1100, S u b j: REQUEST FOR ADMINISTRATIVE HEALTH HAZARD ASSESSMENT Ref: (a) (b) NENPHAA-OMVVNEEaCNNiOVVl NIIRNRHNAHTVATHSVHUCCSREEUFNNRWFWMMArRAr.CR. ECNMMENiikMkseMe.sSS. SwwSaaararrartthaoohuuAttAscooshffcehn22eb46nabcJJahaac/nnh / 06 06 End: (1) (2) AMaEtRe-Or-iWaAlTESRa fe62tKy D6%ata Sheet AMaNtSeUrLiIaTlE S6%afeAtFyFFDa(tAaFCS-h5)eet (MSDS (MSDS) for for ACaCS1.neousddnxse*tefseA(asr6s2cm3e) .5ed(NWniEaitssHrcfCu(Aar)sHreseHqceoAudn)Ceddseuotuncnirnttiegtrnha,genthCraAdeatdafrmtedaitrehnrepeionsxcc*kNteorsavaDvitydi(ieavdvE)iesniiavonHninerdoaenln((NtmcbShleW)on,sHCtuCatarD1hze)aesHr,deNaa(l1v)tahl 2. Please a d dress any questions or concerns to Ms. Sarah A s c h e n b a c h at NSWCCD, Code 635, Philadelphia, PA. ( 2 1 5 )Me. A s c h e n b a c h can be reached at Commercial -897-7401 (DSN)or D efense Secure Network 443-7401. STE LKEN NOVIELLI Bv direction US00003937 Subj; REQUEST FOR ADMINISTRATIVE HEALTH HAZARD ASSESSMENT Copy to : N S W C C D (Code 635) Writer: S, Aschenbach, Code 635, X7401 Typist : E. Lupinacc, Code 635S, 26 J an 06 US00003938 IO Kattana! Foam MATERIAL SAFETY DATA SHEET #NMS22 AER-O-WATER 6EM 6% 6% AFFF AQUEOUS FILM FORMING FOAM (AFFF) Liquid Concentrate Section L CHEMICAL PRODUCT/COMPANY IDENTIFICATION SCPMyrAoanSdtoeunNrcyitoam::lAsMI:edrAiex-nOqtutu-irWefeiocua-atsNteiFrooin6lsmEinMgFl,oerFmCirAienSFgiiFgt hoatapimnpgli(cFAaobFalFemFC; oncentrate PNCM1.5aoGa0tmin.oGuBpnofaoaarnlxdcyfto6oun9Iard5Dmeerrn.:itvIineficc.ation EFEaxmxtoe(rn6g,1eP0nA)cy512P94h3-o94n01e-703N69u5mber (Red Alert): (610) 363-1400 (U.S.A.) www.Kidde-Fire.com Section 2. COMPOSITION / INFORMATION ON INGREDIENTS Components CAS Number Water 7732-18-5 2-(2-Butoxyethoxv) Ethanol 112-34-5 Ethylene Glycol 107-21-1 Proprietary' Mixture of Synthetic Detergents Nc single CAS Number applicable Fluoroalkyl Surfactant Confidential % Weight 78-89% 4-6% 2-4% 3-7% C.f-2.0% ***,%'! y/ii: US00003939 Section 3. HAZARDS IDENTIFICATION Potential Health Effects IVmnaahpteaorlraiastliaomrneamy icnaiums:aelraetsproiroamtorteymirpreirtaattiuorne.. If product is heated or sprayed as an aerosol, airborne Skin Contact Cskoinn.tact with liquid may cause moderate irritation or dermatitis due to removal o f oils from the EPryoedCucotnitsaacnt eye irritant. oINnpogetreaastthiiooannzsaradreinnnotorlimkaellyintoducsaturisael iunsjuer.y'S;mswalalllaomwoiunngtslasrwgealalomwoeudntdsumrianygcnaoursmeailnhjuarnydolirng irritation. AExdidstiitniogneayleHoeraslkthinEseffnescittsivity may be aggravated by exposure. NCoardcaitnaoagveaniilcaibtyle.Information Section 4. FIRST AID MEASURES aIINfnttoehexnaspptliaoeotcsnieiofdinifcteotfrfeeexactctmesseosncitvcueisrl.neveceelsssoafryairsibnocrenethaiesrmosaotlermiailstiss, nroetmliokveelytotofrbesehhaaizra. rdSoeueks by inhalation. medical SInkcinasCeoonftsakcitn contact, wash off in flowing water or shower. Launder clothing before reuse. EIennysceuarCseeotonhfotareocytuegchonritnascitn,gf.luCshoneysuelstparpomhypstilcyiawnitihf iwrraittaetriofonrp1e5rsmistisn.utes Retract eyelids often to npISnoewrgtaseiolsnlntodi.wouncSienegevkolemmssiettidnhigacn.alaGantitvoeenutnmicoienlk.isonrowtaetxepr.ecNteedvetor gciavueseansiygtnhiifnigcabnyt hmaormut,h Ftooarnlaurgnecronasmcoiouunsts, do NMS2 Page 2 of 8 tW JO /03 US00003940 Section 5. FIRE FIGHTING MEASURES Flammable Properties Flash Point - >200F AFivroeidancdonEtaxcptlowsiitohnwHataezrarredasctive materials, burning metals and electrically energized equipment. EPrxotdinugctuiisshainngexMtinegduiaishing media. Use media appropriate for surrounding materials. Special Fire This product wFiigllhptirnogduIcnestfrouacmtiownhsen mixed with water. Section 6. ACCIDENTAL RELEASE MEASURES Safeguards (Personnel) NOTE: Review proceeding with cFlIeRaEn-FupIG. UHsTeINapGprMopEriAatSeUPRerEsSonaanldPHroAteNcDtivLeINEGqu(ipPmeresnotndnuerl)insgecctlieoanns-ubpe.fore Accidental Release Measures wnlrCSaeotarooltegnlpeaoecrsnfewvelgnoosae,wltyrurcsamfoi.otfleelaDpemrociestsspls.seiopbEasislxaleelel.esr,dsUchcicsosooeeunntlacdacapeiupnnbtrteiaoronmpandtr,aeiacdswtuoeelriltipfenharccaotaectbfsecoscomortrriuadvbysaeeennbectwqeemuhswielapiritpmteephrepeianfroelyts;d.sdpeiPubrlarraleeicln,v.egesFitnnlcatulleasedahpianspnacrrudhoepaval.roegwFdceaoictlrohorfsnewmctgaoauaintnllelcaeretvrinu.ootnnlruFtsaimo.ltreeitto mdFSieoaseacdhmaeabi/rnoFgvoaeeac.icmnFotloruSdbsoahilnoucwltoeiiogtwhniciatwhlastfeeerdw.eePrrarlet,rveseatnatmttedeainsntcdhsyalosrtcgeaeml orsfewgfouiatlhamotiuoftonaps.mriosroaluptpiroonvatol. wDaitseprowsaalyss.hDouoldnobte Section 7. HANDLING AND STORAGE Handling (Personnel) Avoid contact with eyes, skin thoroughly in case of contact. oRrecvlioetwhiHngA. ZAAvoRiDd SinagnedstFioInRSorTinAhIaDlasteiocnti.oRnsin. se skin and eyes oRSrteiocgroinamgalme sehnidpepdinsgtocroangteaiennevriororntmaneknstdisesbigetnwedeefnor35p'rFo>du2c'tDstoarnadge120:F {49' C). Store product in NMSM20 Page 3 o fS il9-1fl/3 US00003941 Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Special ventilation is not required. Personal Protective Equipment tRRheeiscspommiramateteorniradyledTheexpnoeseudrefolrimreistpsi(rOatSoHryAp-rPoEteLctaionnd sAhCoGulIdHb-eTeLvVal)uhaatevde bnyotabqeuenaldifeietedrmheianlethd for specialist. Protective Clothing Rubber or PVC gloves recommended. Eye Protection eSyaefectyongtlaacsts.eCs,onfatcaectshleinelsdesosrhcohuelmd incoatl bspelwasohrng.oEggyleews amsuhstfabceilwitioersnawrehreencopmosmsiebnildietyd.exists for UtOositleheetgrofaoHcdiylpgiteiieernsso.icnParPlormhaycpgttiilceyenrseemproavceticsoesil.eWd aclsohthhianngdasnbdefwoaresheathtionrgo,udgrhinlykibnegf,osrme roek-iunsge,. or using Exposure Guidelines Exposure Limits Component CAS Number PEL (OSHA) TLV (ACG1H) 2-(2-Butoxyethoxy)Ethanol 112-34-5 none none Ethylene Glycol 107-21-1 50 ppm 50 ppm Section 9. PHYSICAL AND CHEMICAL PROPERTIES Physical Data Boiling Point: Vapor Pressure: Not applicable Not applicable Vapor Density: Not applicable Melting Point: Evaporation Rate: Solubility in Water: pH: Specific Gravity: Not applicable <1 (Butyl Acetate = 1.0) 100% 8.0 1.04 @ 25C NMS8220 Page 4 of S 09/10/03 US00003942 Freezing Point: Odor: Form: Color: 17F (-8C) Mild, pleasant Liquid Straw yellow Section 10. STABILITY AND REACTIVITY Chemical Stability Stable. AInvcooimd pusaetiobfilpitryo,dMucattoenribaulsrntoinAg vmoeidtals, electrically-energized equipment and contact with water reactive materials. Polymerization Will not occur. Section 11. TOXICOLOGICAL INFORMATION MiTrhraiitsmaptmiroonad,liuoacrntphTraiomsxnaircoyittbyskeeinn tested as irritation. a whole for acute oral and inhalation toxicity, primary eye Section 12. ECOLOGICAL INFORMATION Ecotoxicological Information Aquatic Toxicity 96 hr. Flow Through LC50 for Saltwater Minnows (Fundulus heteroclitus) is reported to be greater than 1000 ppm. Environmental Fate BOD20 Concentrate 274,000 nig/kg COD Concentrate 341,000 mg/kg NMS220 Page 5 of 8 09/1/03 US00003943 Section 13. DISPOSAL CONSIDERATIONS DmacCocooacndnecnpeceoteritannndbstailrseacacrcttheooearhtrdihggaeehntcirBneetOaowtDmibtiheloonlfaotedgdpielcaarannaldlt,smfseotwaaaytmeerbianetnrghedateetllompncfdeuaenllnt.rcseDyyg.soutleLnamtooitwosnfwldsu.iostshhaogtuoetwfplaroitwoerrrwaapatepyrso.orvaDanli.tsipfSoopaseamcliisfnhigcoaugldenbtes wihrAFnaioeagttoreathe-moObrBwri/-oOFaWalnoyoDtaasgi.tmiflecoorDaaaSl6dmisEso.pielnMuowDgstieialfoaruolgntatseirmhonenoatsustwmoladliceulcnlbteiteropefnmtadacucabiacdllineeetiBtbeionseOtamthDrceeacaaoyttnrrebedddaeaCtbnmdOycoeenDwnewtafpwisattlhciaettnhofwterpdasmrtepieraorrayrolt,pbarseopetarpahttrtmieeoolvenpanaafntlutd.elf.lalSyocD.pcileaoiLctlioinerfweosicg.t ducfDlloouaisntssaicchogehnetraosnrf.slgoeawre NOTE: As a service to our customers, facilities throughout the U.S. for waste NwaattieorntarleaFtomaemnthaansdaspoplridovifaiclsatiinopnlaanced with disposal landfill of our foam liquid concentrates and foam solutions. If required, National Foam, Finofaomrm'satRioisnkoMn athneagdeismpeonstalAodfmdirnuimstsrautoserdatfo(r61sh0i)p3p6in3g-1o4u0r0cfoonrcaedndtritaitoensa. l PInleca. sceancoanltsaoctprNoavtiidoenal information. Section 14. TRANSPORTATION INFORMATION NHPSrhaaotzippiaoeprnrdianSClghMliaIpsnopstf:ioonNrrgmFoNnraeaetimigohent: CFiordeeE: x6t9in16gu0isShuebr0Charges or Compounds N.O.I., Class 70 UN Number: None Section 15. REGULATORY INFORMATION U.S. Federal Regulations TAollxcicomSupobnsteanntsceosf Control Act (TSCA) this product are listed in the TSCA inventory. Superfund Amendments and Reauthorization Act of 1986 (SARA), Title III Section 302/304 TEhxetrreemaerleynHoaczoamrdpoounsenSutsbostfatnhcisesm(aEtHerSia)llwistit.h known CAS numbers which are on the NMS#220 Page 6 of 8 09/10/03 BSeacsteidonon31a1va&ila3b1le2 information, this material contains the following components which are classified as the following health and/or physical hazards according to Section 311 & 312: 2-(2-Butoxyethoxy)Ethano1 112-34-5 Health - Immediate Ethylene Glycol 107-21-1 Health - Immediate and Chronic Section 313 This material contains the following chemical components subject to Section 313 reporting requirements. 2-(2-Butoxyethoxy)Ethanol 112-34-5 Ethylene Glycol 107-21-1 COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND CTLhEIAiRsBCmILaLtAeITriaYl AcoCntTai(nCsEthReCfoLlAlo)wing components subject to the reporting requirements of Ethylene Glycol 107-21-1 4% by weight maximum 2-(2-Butoxyethoxy) Ethanol 112-34-5 6% by weight maximum OTHER REGULATORY INFORMATION oCnAtNheADDSILAN(DEoNmVesItRicOSNubMstEanNcTeALListP) ROTECTION ACT (CEPA). All ingredients are listed STATE REGULATIONS PENNSYLVANIA RIGHT-TO-KNOW HAZARDOUS SUBSTANCES LIST 2EP-At(h2yH-lBeaunzetaorGxdyloyeucthosolSx1uy0b)7sE-t2ta1hn-a1cneosl present at 112-34-5 levels greater than 1%: NMS#220 Page 7 o f1 09/) 0/03 US00003945 Section 16. OTHER INFORMATION NFFA Rating WHMIS Rating HFleaamltmh a0bility 0 Reactivity 0 D2B ADDITIONAL INFORMATION Revision Summary 10/2/96 ,,...,,....Revised to ANSI Format. 1/20/00 ...........Updated Section 15. 2/5/99............. Added MSDS number, updated Sections 3,2, 3, 4, 6, 7, 9,11, 12, 13,15. 08/10/00.........Revised Section 1and 3. 9/10/03........... Updated Sections 2, 5, 9, 14,15, 16. For further information, see National Foam Product Data Sheet f _______rater 6EM. dohuaHhiTmbniesehorerrdlpeewieegolcfiiceatnfreiovlntodtymieihfmo.sroenop,Tr,bsrlmehieytoliimaisnrwietsdvaidioleitttiarhnedahetrbeacfitiaecotlrlsodliyesthbnei.seeertpfNseaarcotioalonn,fmtioresissroirdtbenantcitharolhetietelteolyFariaruaenoonsiIpdanesfcameoltorohib,tfscoeItaoanntflhiufcuni.sgtarseehsunndrhepiiydsafrohrelioclfnoledoimfndntnuohoetrcetsrswmtsoabeaiacauetnthntrmldicdoiooaeaunfpsbtNterslberaacoweioltcfaelinoeiaol.edsrtrnvaTruaateaihronlndneeeytFsitdynoiolfnovaobhfseemroesiestrtrs,ohgimeagreeIifanarnnedttecaeih,reoo,maxarnaulpnalsnyrogcdsdeouemlrsinemneasirtlsergaseisdaitsiisanaboinnnnenloedddgosr. September 10, 2003 NMSH20 Page 8 of 8 09/10/03 US00003946 A N S I ! ! NSUl irvCCRPOSATE MABNETIE. W> 5A1d3-55AS ANSULITE 6% AFFF (AFC-5) MATERIAL SAFETY DATA SHEET CONFORMS TO DIRECTIVE 2001/58/EC 1, IDENTIFICATION OF THE SUBSTANCE/FREFARATION AND OF THE COMFANY/UNDERTAKING 1.1. Identification of the preparation Product Name: "ANSULITE 6% AFFF (AFC-5)'. Chemical Name: N/A - This is a mixture/preparation. CAS No.: N/A - This is a mixture/preparation Chemical Formula: N/A - This is a mixture/preparation. EINECS Number: N/A - This is a mixture/preparation. 1.2. Use of the preparation The intended or recommended use of this preparation is as a FIRE EXTINGUISHING AGENT, 1.3. Company Identification Manufacturer/Supplier: ANSUL INCORPORATED Address: One Stanton Street, Marinette, Wt 54143-2542 Prepared by: Safety and Health Department Phone: 715-735-7411 interneVHome Page: http://wwvr.artsul.com Dale of Issue: September, 2003 1.4. Emergency telephone CHEMTREC 800-424-9300 or 703-527-3887 2. COM POSITION/! INFORMATION ON INGREDIENTS 2.1. Ingredient Name: Chemical Formula: CAS No.: EINECS Number: Concentration, Wt %: Hazard Identification: Proprietary' mixture consisting of hydrocarbon surfactants, fiuorosudactants, inorganic salts, and water. Not otherwise specified. N /A -T h is is a mixture/preparation. N/A - This is a mixture/preparation. N/A - This is a mixture/preparation. >80%. See Heeding 3 Ingredient Name: Chemical Formula: CAS No.: EINECS Number: Concentration. Wt %: Hazard identification: Diethylene Glycol Monobutyl Ether (a). C4HB0CCH2CH20 )eH. 112-34-5. 203-961-6. 19%. See Heading 3. Ingredient Name: Chemical Formula: CAS No.: EINECS Number: Concentration, Wt %: Hazard Identification: 1-Propanol. c h 3c h 2c h 2o h . 71-23-fl. 200-746-9 0.2% . See Heading 3. Ingredient Name: Chemical Formula: CAS No.: EINECS Number: Concentration, Wt %: Hazard fdentilication: Hexylene Glycol (2-Methylpentane-2,4-diol}. CgH^Gj. 107-41-5. 203-489-0. 0.3 %. See Heading 3, (a) This chemical is subject to reporting requirements of SARA Title 111Section 313 and 40 CFR Section 372. NOTE: Unless a component presents a severe hazard, it does not need to be considered in the MSDS if the concentration is less than 1%. [According to Directive 1998/45/EC.j Enclosure (2) US00003947 ftNSWLITE 6% AFFF AFC-5) (Continued) Page 2 3. HAZARDS IDENTIFICATION FOR HUMANS: Product: EU Classification: irritant R Phrases: 36 Irritating to eyes. S Phrases: 2 Keep out of the reach of children. 24 Avoid contact with skin. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Components: ethylene Glycol Monobutyl Einer: EU Classification: Irritant - Xi. R Phrases: 36 Irritating to eyes. S Phrases: 224 Keep out of ihe reach of children. Avoid contact with skin. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Limit Values far Exposure: Diethylene Glycol Monobutyl Ether: OSHA PEL (General Industry) 8 hour TWA: Non established. MAK IDE) Limit value: 100 mg/m3. (8 5Short term exposure limit value times, minulesj: 200 mg/m3. Neither this preparation nor the substances contained in it have been listed as carcinogenic by National Toxicology Program, I.A.R.C., or OSHA. AS PART OF GOOD INDUSTRIAL AND PERSONAL HYGIENE AND SAFETY PROCEDURE, avoid all unnecessary exposure to the chemical substance and ensure prompt removal from skin, eyes, and clothing. SIGNS AND SYMPTOMS: Acute Exposure: Eye Contact: Skin Contact: Inhalation: Ingestion: Chronic Overexposure: May cause mild transient irritation. May cause mild transient irritation and/or dermatitis. Not an expected route of entry. Irritating to mucous membranes. Large oral doses could produce narcosis. Kidney, liver, gastrointestinal, and spleen. Did not interfere with reproduction However, body weights ol newborn animals were decreased. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Diseases of the kidney and liver. FOR ENVIRONMENT: As much as possible, keep from being washed into surface waters. See Heading 12. 4. FIRST AID MEASURES Eye Contact: Skin Contact: Inhalation: Ingestion: flush with large amounts of water. If irritation persists, seek medical attention. Wash thoroughly with soap and water. If irritation persists, seek medical attention. Move to fresh air, Seek medical attention i! discomfort continues. If patient is conscious, give large quantities of water and induce vomiting. Seek medical attention. 5. FIRE-FIGHTING MEASURES This preparation is an extinguishing media There are NO extinguishing media which must not be used for safety reasons. NO special protective equipment is needed for fire-lighters 6. ACCIDENTAL RELEASE MEASURES _________ _____________________________________ For personal prelection: Prevent skin and eye contact, see Heading 8. Clean op: Use an absorbent material such as diatomaceous earth, sawdust, etc., and sweep up, see Heading 13. As much as possible, keep from being washed into surface waters, See Heading 12. US00003948 ANSULITE 6% AFFF (AFC-5) (Continued) 7. HANDLING AND STORAGE 7.1. Handling Care should be taken in handling all chemical substances and preparations. See Incompatibility information in Heading 10. 7.2. Storage NO special conditions are needed for safe storage. See Incompatibility information in Heading 10, Store in original container. Keep lightly closed until used. As much as possible, keep from being washed into surface water. See Heading 12 7.3. Specific use The intended or recommended use ol this preparation is as a FIRE EXTINGUISHING AGENT. 8. EXPOSURE COMTROLS/PERSONAL PROTECTION 8.1. Exposure lim it values Limit Values for Exposure: Diethylene Glycol Monobutyl Ether: OSHA PEL (General Industry) 8 hour TWA MAK (OE) Limit value: Short term exposure limit value (8 times, 5 minutes): None established. 100 mg/m3. 200 mg/m3. 8.2. Exposure controls 8.2.1. Occupational exposure controls 8.2.1.1. Respiralary protection None expected to be needed. Mechanical ventilation is recommended. 8.2.1.2. Hand protection Use chemical resistant gloves when handling the preparation. 8.2.1.3. Eye protection Chemical goggles are recommended. 8.2.1.4. Skin protection Standard lire lighting equipment should provide all protection which Is necessary, 8.2.2. Environmental exposure controls As much as possible, keep from being washed into surface water. See Heading 12. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. General Information Appearance: Odor: Straw yellow, clear liquid. Mild, sweet odor. 9.2. Important health, safety, and environmental Information pH: 6.5 to 6.5, Boiling point/boiling range: 97 C. Flash point: None to boiling. Flammability (solid/gas): Not flammable. Explosive properties: Not explosive. Oxidizing properties: Not an oxidizer. Vapor Pressure: Not determined. Relative Density (Water = 1): 1.02. Solubility: - Water solubility: Completely soluble. - Fat solubility: Not determined. Partition coefficient, n-octanolAvater: Not determined. Viscosity: Not determined. Vapor density (Air * 1): <1. Evaporation rate (Butyl acetate = 1): Approximately 0.005. 9.3. Other information Aulo-ignition temperature: Does not ignite. Page 3 US00003949 ANSUUTE 8% AFFF (AFC-5) (Continued) Page 4 10. STABILITY AND REACTIVITY 10.1. Conditions to avoid There are NO known conditions such as temperature, pressure, light, shock, etc., which may cause a dangerous reaction. 10.2. Materials to avoid Reactive metals, electrically energized equipment, any material reactive with water, and strong oxidizers. 10.3. Hazardous decomposition products Normally stable. Hazardous polymerization will NOT occur. Combustion or decomposition products are not known, oxides of nitrogen and sulfur may be found. Hydrogen sulfide may be produced under anaerobic bacterial decomposition. 11. TOXICOLOGICAL INFORMATION Product: The toxicity of the product mixture has not been determined Components: Diethylene glycol monobutyl ether: Toxicity Data: Oral (rat) LOgg 5,660 mg/kg. [Dow Chemical Co.]. Oral (rat) LDS0 9,623 mg/kg. [EINICS ESIS]. Dermal (rabbit) LDEQ 4.000 mg/kg. [Dow Chemical Co.]. Dermal (rabbit) LDS0 2,764 mg/kg. (EINICS ESIS], Irritation Data: Eye (rabbit) 20 mg/24 hrs. Moderate. [EINICS ESIS], Eye (rabbit) Draize test Highly irritating. [EINICS ESIS], Skin (rabbit) 1000 mg/kg/day Moderate with edema, Assuring, and leathery appearance [EINICS ESI5J. Target organs: Kidney, blood, liver, lungs, gastrointestinal, spleen. 12. ECOLOGICAL INFORMATION 12.1. Ecotoxiclty Components: Diethylene glycol monobutyl ether: Fish, Lepomis marcrochinus: Carrassius auratus: DaphnitJs, Daphrua magna: Algae. Scenedesmus subspicatus: LG (96hrs) 1,300 mg/L LCgp (24hrs) 2,700 mg/L. EC50 (24hrs) 3,184 mg/L. ECS0 (96 hrs) >100 mg/L 12.2, Mobility Diethylene glycol monobutyl ether: Should not partition from a water column to organic matter contained in sediments and suspended solids 12.3. Persistence and degradability Diethylene glycol monobutyl ether: Indirect photedegradation is about 50 % in 3.5 hours. Aerobic degradation with adapted activated sludge is 60 % after 28 days. COD = 2080 mg/g substance. BODS = 250 mg 02/g substance. Theoretical oxygen demand = 2.17 mg/mg. 12.4. Bloaccumutative potential Diethylene glycol monobutyl ether: Should not bioaccumulate. Estimated bioaccumulation factor (log BCF) = 0.46. 12,5. Other adverse effects Ozone depletion potential: Photochemical ozone creation potential: Global warming potential: None. None None 13. DISPOSAL CONSIDERATIONS _________________________________ _ As much as possible, keep from being washed into surface water. See Heading 12 Dispose of in compliance with national, regional, and local provisions that may be in force. US00003950 ANSUUTE 6% APFF (Af'C-5) (Continued) 14, TRANSPORT INFORMATION __________ _______ ____________ ____ Hazard Class or Division: Not hazardous. For additional transport information, contact Ansul Incorporated. As much as possible, keep from being washed into surface wafer. See Heading 12. PageS 15. REGULATORY INFORMATION EU Classification* Irritant - XI. R Phrases: 38 Irritating to eyes. S Phrases: 2 Keep out of the reach of children. 24 Avoid contact with skin. 26 In case of contact with eyes, rinse immediaiely with plenty of water and seek medical advice. Exposure Limit Values: Diethylene Glycol Monobutyl Ether: OSHA PEL (General Industry) 8 hour TWA: None established. MAK (DE) Limit value: 100 mg/m3. Short term exposure limit value (8 times, 5 minutes): 200 mg/mT EINECS Status: All components are included in EINECS inventories or are exempt tram listing. EPA TSCA Status: All components are included in TSCA inventories or are exempt from listing. Canadian DSL (Domestic Substances List): All components are included in the DSL or are exempt from listing. Environmental restrictions; None are known. Restrictions on Marketing and Use: None are known. Refer to any other national measures that may Be relevant. 16. OTHER INFORMATION (HMIS) HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS: HEALTH: 1 4. Severe Hazard FLAMMABILITY: 0 3. Serious Hazard REACTIVITY: 0 2. Moderate Hazard 1. Slight Hazard 0. Minimal Hazard (WHMIS) CANADIAN WORKPLACE HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS: This product is rated D2B - Product may Irritate eyes, skin or mucous membrane. Format is from directive 2001/5B/EC. EINECS data is Irom http://exb.jrc.it/exlsiing-chemicals/ Data used to compile the data sheet is from Ansul Material Safely Data Sheet. February. 2002. The EU Classification has been changed ir. accordance with Directive 1999/45/EC and information in the EINICS ESIS fifes {Existing Substances Information System). Toxicological information added from the EINiCS ESIS {Existing Substances Information System) and from Dow Chemical Company. A rating under WHMIS has been added, following the Canadian guidelines Limit values tor exposure for diethylene glycol monobutyl ether were changed, based on EINICS ESIS data. 17. DISCLAIMER THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. ANSUL SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT. N/A Not Applicable NDA = No Data Available MSDS available at http://www.ansul.com ANSUL is s iratsefnaris of Anou* `n t o r / A o its alWjaies flf'.SUl 0 0 STANTON S n ^fT WtATOFHf ',V 5 J 1<3^- : ; -orti Wc . .* ? * ! > ? . * * & .. t US00003951