Document XR6Qe1xOwRBVnmX0mJBEaZVyd

-- U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration I oSawKSai -- - MATERIAL SAFETY DATA SHEET _ ./ Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) MANUFACTURER'S NAME MALLINCKRODT. INC. ADDRESS (Number. Street, City. State, end ZIP Code) P.O. Box 5439 St. Louis. Mo. 63147 chemical name and synonyms CALCIUM STEARATE chemical family Orcranometallic comDound SECTION 1 EMERGENCY TELEPHONE NO. 314-231-8980 TRADE NAME AND SYNONYMS Calcium Stearate RSN 11-4, Code 21: formula Ca(C18H3502)2 SECTION II HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES. & SOLVENTS X TLV (Unil ALLOYS AND METALLIC COATINGS P'GMENTS BASE METAL catalyst ALLOYS vehicle SOLVENTS ADDITIVES - METALLIC COATINGS filler metal PLUS COATING OR CORE FLUX OTHERS OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIOS, SOLIDS. OR GASES X TLV (Unitt) TLV % (Units) -.tr-v v- - * r ; .'.SECTION III - PHYSICAL DATA BOILING POINT (F.| . , SPECIFIC GRAVITY IHjO'D . VAPOR PRESSURE (mm H.)- - VAPOR DENSITY (AIR>1) ' solubility inXvater .. v . ---- PERCENT, VOLATILE BY VOLUME () EVAPORATION RATE --t -D " Insoluble mm 1* -- appearance and odor white ` to. yellow-white fine powder with a characteristic odor SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (M*tno uwdj FLAMMABLE LIMITS LN Usl EXTINGUISHING MEOIA COj* dry powder, or fog nozzle SPECIAL FIRE FIGHTING procedures Pressure _frnm the extinguishing media mav cause severe dusting. Po_not use water as melted fatty acid will float on the surface and spread. UNUSUAL FIRE AND EXPLOSION HAZARDS Melted fattv acid can give a "grease" tvpe fi.re._ Dust can cause potential dust explosions. Avoid ignition sources. Cse factory Insuranc Association Fane lit publication "Oust^Lxplcnions Analysis and Control". DO 08593? CONFIDENT T Al E ' - ~~ "------" SECTION V HEALTH HAZARD DATA - --^ - '-- THRESHOLD LIMIT VALUE "None indicated "' . r^'_- 'r?.v r-j.ivi EFFECTS OF OVEREXPOSURE May cause mechanical irritation of the eyes j' :: =------ 1- - .1 -*-- --- j=*z------ 1 -- -- ------ '-- EMERGENCY AND FIRST AID PROCEDURES R,, emove f_rom area.. _I_f eyes are i.rritat^ed. .> ? see a physician. Wear protective goggles. , - i t' * 1. , - SECTION VI . REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID ''f ' STABLE - XXXXX INCOMPATABILITY (Alalrrielt loatuui) ,:t - iL HAZARDOUS DECOMPOSITION PROOUCTS __ . '- HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR : CONDITIONS TO AVOID XXXXX 1 , : > 1 - 'It l t ; J .i - . T * 1, '-- ? j. - - ; L4 :' "***1 . * . ; ' 1 ^ \ . ,l i#iiT ' r / --- .* - M'i.'. ... SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - Sweep up. Inert material. - ' ' - ^ _\ WASTE DISPOSAL METHOD j: vjj , . * II., .1 ( ! T 4_. I ; * s ' # -A .;j * May be incineratedvor used in a land fill. - ^3 " ' ' , .... . - - - L . s -' I , A ;-J.r 1 - l. -V". Vf: VT< : . j-'- ; J T:::V : . , SECTION VIII - SPECIAL PROTECTION INFORMATION .... ; :: RESPIRA-TwORiY. PROTECTIO--N /Specify.it*y-p?e);'-. D- ust respirator if necessary "-.t; _ VENTILATION = LOCAL l E'XrH,|A-|UwSrTjiiflii-ryw--ffi *l . *--*x. SP\ E.CI,A'L-i 1i*;:. , MECHA N- ICXAA. -L (Gr.ef nera!)`t AwA * J p t OTHER ; i PROTECTIVE GLOVES 1 -Slz-M ... . RubberTT"^ VI EVE PROTECTION- " .. : Goggles " _>r-I V A`i-*! L iii k. i! - tv'v-* : j ' -||4 '. J 1 ~ } i i'l OTHER P.R.O-TEC-TIVE EQUIPMENT .1 ' Clothing because oMf . the . ten.dency, to coa^ t everything 71 * : i 11 ..Vf ** VT - :J ^ SECTION IX - SPECIAL PRECAUTIONS 1 - ; . t = !f.f 'll ` , V;'- 'Hi PHCAU-TjI.O~NS*";TO BE TA. KEN IN HA. N. OUirN:,.O ,,ApND 5TORJNQ ` 'i. i Store in a cool place.' Avoid dusting* OTHER-PRECAUTIONS . ... - : :r % i ^r "7"*" 5 ' l;i - i .. * *5 - .i t PAGE 12): : ; cpo : i > A ' , H..,. * '* ,*Lk * - , ' DO 085933 i> Form OSHA-20 * R*. My TZ~ ! ` i! , * 'I >! CONFIDENTIAL " '- CALCIUM OXIDE Sheet Emergency Telephone Number 314-982-5000 Mallinckrodt. Inc. P.O. Box 5439 St. Louis, Mo. 63147 Effective Date: 9B/L6/B5 Product .Identification: JSyjiDnyinsT'Eime unslakfed- Lime bugntr--tflUcklimeT~ealx Formula CAS No.: 1305-78-8 Molecular Weight: 56.08 Hazardous Ingredients: Not applicable. Chemical Formula: CaO PRECAUTIONARY MEASURES Do not get in eyes, on skin, or on clothing. Avoid breathing dust. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. EMERGENCY/FIRST AID In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes. If swallowed, DO NOT INDUCE VOMITING! Give large quantities of water or milk if available. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases call a physician. SEE SECTION 5. DOT Hazard Class: ORM-B Physical Data SECTION 1 Appearance: White to slightly yellow powder. Odor: Odorless. Solubility: Slightly soluble in water with release of heat, formation of calcium hydroxide. Boiling Point: 2850C (5162F). Melting Point: 2572C (4662F). Specific Gravity: 3.37 Vapor Density (Air-1): No information found. Vapor Pressure (mm Hg):No information found. Evaporation Rate: No information found. nn 08ft934 CAOXI - CALCIUM OXIDE Mallinckrodt, Inc. / Ftre and Explosion Information FIRE: Explosion: Fire Extinguishing Media: Special Information: Reactivity Data Stability: Hazardous Decomposition Products: Hazardous Polymerization: Incompatabilities: 2- SECTION 2 Not considered to be a fire hazard. Lime and water can react exothermically with sufficient heat to ignite combustible materials in certain instances. Not considered to be an explosion hazard. The combination of lime and water at high temperatures may be explosive. Use any means suitable for extinguishing surrounding fire. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. SECTION 3 Stable at room temperature in sealed containers. Will react with moisture and carbon dioxide in air. None. This substance does not polymerize. Water, acids, humid air, hydrogen fluoride, phosphorous pentoxide, boric oxide, steam, many organic substances. Leek/Spill Disposal Information SECTION 4 Clean-up personnel require protective clothing and respiratory protection from dust. Spills: Pick up and place in a suitable container for reclamation or disposal in a method that does not generate dust. Disposal: Whatever cannot be saved for reclamation may be disposed in a RCRA approved hazardous waste facility. Ensure compliance with local, state and federal regulations. CAOXI - CALCIUM OXIDE Mallinckrodt, Inc. DO 085935 CONFIDENTIAL t Health Hazard Information L,___Exposure/Health Effects Inhalation: -3SECTION 5 Inhalation of dust is highly irritating and possibly corrosive to the upper respiratory tract. May cause coughing, sneezing, labored breathing, and possibly burns. Ingestion: Skin contact: Corrosive. May attack the esophagus. Abdominal pain, nausea, vomiting may result. May cause serious alkali burns in mouth and throat. Irritant; may cause severe corrosive damage. Eye contact: Severe irritant, may damage eye tissues. Causes redness, tearing, blurred vision, pain. Chronic Exposure: Chronic inhalation of dust may cause inflammation of the respiratory passages, ulcers of the mucous membranes, and possible perforation of nasal scutum. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of the substance. B, FIRST AID Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. * 6 Ingestion: DO NOT INDUCE VOMITING! Give large quantities of water or milk if available. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Call a physician immediately. Eye contact: Wash thoroughly with running water. Get medical advice if irritation develops. C, TOXICITY DATA (RTECS, 1982) No LD50/LC50 information found relating to normal routes of occupational exposure CAOXI - CALCIUM OXIDE Mallinckrodt, Inc. Do 085936 CONFIDENT IA[. Occupational Control Measures Airborne Exposure Limits: Ventilation System: Personal Respirators: (NIOSH Approved) Skin Protection: Eye Protection: SECTION 6 -OSHA Permissible Exposure Limit (PEL): 5 mg/m3 ppm (TWA). -ACGIH_Threshold Limit Value (TLV): 2 mg/m3 (TWA). A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details. If the TLV is exceeded, a dust/mist respirator with chemical goggles may be worn, in general, up to ten times the TLV. Consult respirator supplier for limitations. Alternatively, a supplied air full facepiece respirator or airlined hood may be worn. Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls to prevent skin contact. Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Contact lenses should not be worn when working with this material. Maintain eye wash fountain and quick-drench facilities in work area. Storage and Special Information SECTION 7 Keep In a tightly closed container.Protect from physical damage. Store in a cool,dry, ventilated area away from sources of heat, moisture and incompatibilities. This strongly alkaline material will swell and generate heat when moistened and could burst container. ******************************************************************************** The information contained herein is provided in good faith and Is believed to be correct as of the date hereof. However, Mallinckrodt, Inc. makes no repre sentation as to the comprehensiveness or accuracy of the information. It Is expected that individuals receiving the information will exercise their in dependent judgment in determining its appropriateness for a particular purpose. Accordingly, Mallinckrodt, Inc. will not be responsible for damages of any kind resulting from the use of or reliance upon such information. NO REPRESENTATIONS, OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION SET FORTH H**E*R*E*IN**O**R**TO***TH*E***PR**O*D*U*C*T**TO**W**H*IC*H**T*H*E***IN*F*O*R*M**A*T*IO*N**R*E**FE*R**S*. *********************** CAOXI - CALCIUM OXIDE Mallinckrodt, Inc. DO 085937 conftdfnttai MATERIAL SAFETY DATA SHEET ************************** The C.P. Hall Company 7300 S. Central Avenue, Chicago, IL 60638 Emergency Telephone Nc: 312/767-4605 Chemical Name: Calcium Oxide SECTION I t' *' - *~ *y product Name: CALCIUM OXIDE HPa Chemical Family: Alkali Earth Formula: CaO HMIS Number Gloves & Safety Goggles SECTION II - HAZARDOUS INGREDIENTS Under the Federal Hazardous Substance Labeling Act the signal word for Lime is "DANGER". SECTION III - PHYSICAL DATA Boiling Point: Vapor Pressure: Vapor Density: Solubility in Water: 2850C N/A N/A Reacts to foam Calcium Hydroxide Specific Gravity: (H20=1) % Volatile by Vol: Evaporation Rate: (HaO=l) 3.30 N/A N/A Appearance & Odor: White powder SECTION IV ~ FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): Not Available Extinguishing Media: Not flammable or explosive, but generates large amounts of heat on contact with water. Flammability Limits: Not Available Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: Reaction between lime and ester produces steam. If this reaction takes place in a confined space on explosion may result. ________ ' _____________ SECTION V - HEALTH HAZARD DATA Threshold Limit Value: 5 milligrams per cubicme.ter of air. Effects of Overexposure: Will cause burns on mucous membrane and skin. Will cause sneezing when inhaled. Emergency & First Aid Procedures: Inhalation: Move subject to fresh air. Eye and Skin Contact: Flush eyes with large amounts of water for at least 15 minutes; consult a physician if irritation persists. Wash affected skin areas with soap and water. If swallowed, drink water followed by vinegar or fruit juice and get immediate medical attention. N/A = NOT AVAILABLE 00 085938 00NFTDFNTTA1 Product Name: CALCIUM OXIDE HP SECTION VI - REACTIVITY DATA Stability Unstable: X Conditions to Avoid: Exposure to water, humid Stable: air and acids. Incompatibility (Materials to Avoid): Reacts with water generating heat. Hazardous Decomposition Products: None Hazardous Polymerization May Occur: Conditions to Avoid: Will Not Occur: X Not Available SECTION VII " SPILL OR LEAK PROCEDURES Steps To Be Taken In Case Material Is Released or Spilled: Normal clean-up procedures. Waste Disposal Method: Normal methods. Landfill contaminated diking material according to current local, state and federal regulation. SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type): Any type respirator prescribed for fine dust. Ventilation Local Exhaust: Adequate ventilation to keep dust cone, under TLV. Special: Mechanical (General): Other: Protective Gloves: Impervious Eye Protection: Safety Goggles Other Protective Equipment: Use protective cream over exposed skin. SECTION IX ~ SPECIAL PRECAUTIONS Precautions To Be Taken In Handling And Storing: Avoid contact with water or acids. Other Precautions: None. Revision Date: ^/86 JTH Supersedes: 5/85 JTH 085939 2 CONFrOFNTTAI MATERIAL SAFETY DATA SHEET ISIeSJSental PHENATE FOR R&D USE ONLY CieioBr`Pheiiate (1.5ZM/1.2ZV Treat Rate) MANUFACTURER/SUPPLIER: Amoco Petroleum Additives Co. 231 South Bemlston Avenue Clayton, Missouri 63105 TEL.314/854-8000 EMERGENCY HEALTH INFORMATION: (800) 447-8735 EMERGENCY SPILL INFORMATION: (800) 424-9300 OTHER PRODUCT SAFETY INFORMATION: (312) 856-3304 IMPORTANT COMPONENTS: Calcium alkyl phenate: trade secret. No exposure limit established. WARNING STATEMENT: This product has been evaluated and does not require any hazard warning label under the OSHA Hazard Communication Standard. HMIS/NFPA CODES:(HEALTH;0)(FLAMMABILITY;1)(REACTIVITY;0) APPEARANCE AND ODOR: Yellow-brown, viscous liquid. HEALTH HAZARD INFORMATION EYE EFFECT: No significant irritation expected. FIRST AID: Flush eyes with plenty of water. PROTECTION: None required; however, use of safety glasses Is good Industrial practice. SKIN EFFECT: No significant irritation expected. FIRST AID: None required. PROTECTION: None required. INHALATION EFFECT: None expected under normal conditions of use. FIRST AID: None required. PROTECTION: None required for normal conditions of use. EFFECT: FIRST AID: (' \ INGESTION Relatively non-toxic. If swallowed, get medical attention. DO 085940 CONFIDENTIAL EXPERIMENTAL PHENATE PAGE 02 OF 03 FIRE AND EXPLOSION INFORMATION FLASHPOINT: Above 302F (150C) ASTM D93 EXTINGUISHING MEDIA: Agents approved for Class B hazards (e.g., dry chemical, carbon dioxide, halogenated agents, foam, steam) or water fog. UNUSUAL FIRE AND EXPLOSION HAZARDS: None. REACTIVITY INFORMATION DANGEROUS REACTIONS: None Identified. HAZARDOUS DECOMPOSITION: None. Polymerization will not occur. Incomplete burning can produce carbon monoxide, carbon dioxide, and other harmful products. STABILITY: Stable. _____________________________ CHEMICAL AND PHYSICAL PROPERTIES SOLUBILITY IN WATER: Slight, 0.1 to 1.0%. SPECIFIC GRAVITY (WATER =1): 1 STORAGE AND ENVIRONMENTAL PROTECTION STORAGE REQUIREMENTS: No special requirements. SPILLS AND LEAKS: Remove mechanically or contain on an absorbent material. Treat as an oil spill. WASTE DISPOSAL: Disposal must be in accordance with applicable federal, state, or local regulations. Determine waste classification at time of disposal. Conditions of use may render the spent product a hazardous waste. Enclosed-controlled incineration Is recommended unless directed otherwise by applicable ordinances. EMPTY CONTAINERS: The container for this product can present explosion or fire hazards, even when emptied! To avoid risk of injury, do not cut, puncture or weld on or near this container. TOXICOLOGICAL INFORMATION EYE: For a similar material, irritation scores 9.0/110.0 In rabbits. SKIN: For a similar material, irritation score in rabbits 6.3/8.0. Acute dermal LD50 greater than 2000 mg/kg (rabbits). Essentially non-irritating in human repeated patch testing. INHALATION: For a similar material, no death or signs of toxicity were observed in a 4-hour rat inhalation study at the maximum attainable air concentrations. INGESTION: For a similar material, acute oral LD50 greater than 15,380 mg/kg (rats). A phenate has been reported to produce testicular atrophy, aspermatogenesis and tubular hyperplasia when applied to the backs of sexually immature rabbits for 28 days (2 ml/kg) at concentrations of 25% and 100% in medicinal white oil. DO 088941 OONFtOFNTTAl PAGE 03 OF 03 EXPERIMENTAL PHENATE TOXICOLOGICAL INFORMATION - CONTINUED ^ The testicular toxicity was rapidly reversible at the 25% level. At the 100% level, the recovery period (30 days) may have been too short to observe rever sal of effects. No testicular effects were seen at the concentration of 10% In medicinal white oil. No adverse effects are expected to occur when the recommended hygiene measures for handling this product are followed. ___________________________________ REGULATORY INFORMATION ______________________ OSHA HAZARD COMMUNICATION STANDARD: Not hazardous per 29 CFR 1910.1200(d). DOT PROPER SHIPPING NAME (BULK, UNO): Not regulated. ____ __________________________________ ISSUE INFORMATION___________________________ BY: Stephen A. Elbert Mgr., Product Safety & Toxicology ISSUED: ecember 08, 198G ) This material safety data sheet and the information It contains Is offered to you In good faith as accurate. We have reviewed any Information contained In this data sheet which we received <rom sources outside our company. We believe that information to be correct but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and/or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. No statement made in this data sheet shall be construed as a permission or recommendation for the use of any product In a manner that might infringe existing patents. No warranty is made, either express or Implied. \ Tt'^NT7AlDO DQNp- DGS94^ 608 DOC. NO. 1320 I.c. No. ; bcn^uy-suuMJj 16220, X16230, 16240, 16290 16300, 16350, X16360, 16400 16600, 16700, 16820, 16910 Telephone 817-457-4474 MATERIAL SAFETY DATA SHEET Anderaon Laboratories, Inc. 5901 Fltzhugh Avanua Fort Worth, Texas 76119 EMERGENCY TEL.800-424-9300(CHEMTREC) DATE: e*/25/e'5* The materials listed in thia Date Sheet are classified in accordance with the definitions set forth in 29CFR Parts 1915, 1916 and 1917. I. PRODUCT NAMES: CALCIUM CARBONATE, 1ml - leg CaCQ3 <?ALCIUM,,.CHLORIDE, J^ercentoge Solutions other than listed to and including 10X. CALCIUM CHLORIDE, 1ml - 25mg CaC03, USGS for Be CALCIUM CHLORIDE, 2.75* APHA for BOD CALCIUM CHLORIDE, M/40, Quick for Prothrombintime CALCIUM CHLORIDE, 0.02M, For Prothrombintime, Quick CALCIUM CHLORIDE, Normal solutions other than listed to and 'ncluding 1.0 Normal CALCIUM CHLORIDE STANDARD, 1ml - lmg CaC03, APHA CALCIUM STANDARD, 100 mEq Ca per Liter CALCIUM STANDARD, Coleman Reagent No. 10 CALCIUM STANDARD, 1ml * 0.5mg Ca in Dilute HC1. CALCIUM STANDARD, 1ml * lmg Ca CHEMICAL FAMILY: Calcium Salt TRADE NAME: BANCO DOT SHIPPING NAME: NOT REGULATED DOT HAZARD CLASS: NOT REGULATED DOT I.D. NO.: NOT REGULATED II. COMPONENTS: Colcium Chloride...<CAS NO 10043-52-4)... to 10X w/v Max. HC1 ...(CAS NO 7647-01-0)................to lx w/v Max. III. PERTINENT PHYSICAL DATA: Boiling pt. 100 C Flash pt.NA Vapor pressure 20 mm Hg at 20 C. APPEARANCE AND ODOR: Colorless and odorless liquids except for I.C. No. 16220 which is dark reddish-brown. IV. FIRE AND EXPLOSION DATA: N/A V. HEALTH HAZARD DATA: TOXICITY DATA: Oral-rot; LD50, lOOOmg/Kg. 100ml of these solutions contain no more than 10,000mg of calcium chloride. VI. REACTIVITY DATA: Does not form harmful polymerization products.i VII. SPILL AND LEAK PROCEDURES: Flush with water. ^ VIII.SPECIAL PROTECTION INFORMATION: Use normal laboratory safety devices. IX. SPECIAL PRECAUTIONARY INFORMATION: Use prudent laboratory practices. X. FIRST AID AND OTHER PROCEDURES: This product is to be used only by or under the supervision of qualified personnel. All chemical re gents should be treated as potentially hazardous. DISCLAIMER OF LIABILITY The information in this MSDS was obtained from sources which we believe are r liable. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS ACCURACY OR CORRECTNESS. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY DIRECTLY OR INDIRECTLY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT OR THE INFORMATION FURNISHED THEREWITH.** DO 085943 CONFIDENTIAL