-N ew Field s
Perspective. Vision. Solutions,
M EM O RAN DUM
700 5W Higgins Ste. 15 Missoula M l 59803
To:
Sara Sparks
Remedial Project Manager
T: 406,549.8270 F: 406,549.8277
From: Project No:
David Tooke PhD. Project Coordinator 350.0065.001
Subject: Date:
Metal and Common Ion Results for 5- 23-18 Water Samples Collected at The former Smurfit-Stone / Frenchtown Mill Site June 6, 2018
Sara,
Please see the brief summary of metals and common ion results below for water samples collected on 5/23/18 during high river flows in the Clark Fork River (CFR) at the former Smurfit-Stone / Frenchtown Mill (Site).
In summary, aluminum, copper, iron and lead were detected in the background samples upriver from the mill at concentrations above relevant water quality standards. A sample of "tea-colored" water was collected from floodwaters adjacent to pond HP-13A. This "tea colored" water was first observed in the CFR after the PRP's placed additional fill material along the inner berm in this area to minimize "boils" observed in the immediate vicinity. Samples of "tea water" collected adjacent to the Site, and pond water, and groundwater collected on the Site contained concentrations of arsenic above relevant water quality standards and background concentrations. These samples also contained manganese above background concentrations. As with previous risk assessment screening at the site, a constituent of potential concern (COPC) is defined as a contaminant that exceeds a risk-based screening level (i.e.: water quality standard) and significantly exceeds the background concentration. Sample (CFR-2) collected in the CFR immediately downgradient of the 'tea-water' sample did not contain any COPCs.
Sampling and Analysis As part of the ongoing work concerning potential impacts to the CFR during high flows, the Potential Responsible Parties (PRPs) collected surface water and groundwater samples as directed by the EPA and in accordance with a work plan approved by EPA on 5/23/18. Two (2) water samples were collected from pond 13A and pond 2 on the Site adjacent to the river. Two (2) background surface water samples were collected in the river upstream (CFR-HB-1) and along the southern part of the Site (CFR-1). A sample of 'tea-colored' water (CFR-HP-13A) was collected from floodwaters on the river side of the southern berm of HP-13A. CFR-2 was collected about 200 yards downstream of the 'tea-water' location in CFR floodwaters where the tea-water appeared to be mixing with turbid upstream CFR water. Sample locations are shown on Figure 1 (attached). Results of metals and common ion analysis are provided in the attached Table 1 and Table 2 respectively.
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Memorandum Meta! and Common Ion Results for 5-23-18 Water Samples Smurfit-Stone / Prenchtown Mill Site NewFields Project No. 350.0065.001 June 6, 2018
Screening Metal concentrations were compared to applicable Federal and State water quality standards and background concentrations to identify COPCs. In accordance with previous risk assessment screening done by EPA at this Site, a chemical is identified as a COPC if the maximum detected concentration exceeds an available water quality standard, and Site concentrations for that chemical are significantly higher than background concentrations.
Water Quality Standards - Surface water results were compared to Montana DEQ Circular-7 human health and aquatic life standards (MDEQ, 2017). The aquatic life standards for some metals were adjusted to water hardness in the samples (Table 3). Groundwater was compared to EPA Maximum Contaminant Levels (MCLs) (EPA, 2018) and the Montana DEQ Circular-7 groundwater standards (MDEQ, 2017).
Background Samples - Four wells within the boundary of the Smurfit-Stone/Frenchtown Mill Site (County MW, SMW1, SMW5, SMW6) have been identified as background groundwater locations for shallow groundwater at the Site (EPA 2017). These wells were identified as being upgradient from any potential Site contamination. Up to five groundwater samples have been collected from each of these wells between April 2014 and December 2017 as part of ongoing Rl activities (NewFields 2018).
Two background surface water samples were collected on May 23, 2018. These include CFR-HB-1 collected on the east side of the river at Harpers Bridge, and CFR-1 collected on the east side of the river adjacent to the production well field at the southern end of the site near the CFR1 staff gage (Figure 1). The highest observed concentrations from the background samples were used as upper threshold values for comparison to downgradient samples.
Results The results presented in Table 1 and Table 2 show the following:
The 'tea-water', pond water, and groundwater samples contained arsenic at concentrations higher than relevant water quality standards and background levels.
Copper was detected above water quality standards in all surface water samples collected, including the background river samples.
Background (upriver) samples contained aluminum, copper, iron and lead concentrations above relevant water quality standards.
The surface water sample collected at CFR-2 downgradient to the 'tea-water' sample in the river did not contain any COPCs. This sample was collected adjacent to the CFR berm.
Concentrations of analytes observed in the groundwater sample (SMW11) are consistent with previous groundwater sample results.
Aluminum, iron and manganese were detected in the groundwater sample (SMW11) above secondary MCLs and background concentrations.
The water quality profile of the pond water and groundwater samples (sodium sulfate signature) are similar and distinct from the water quality profile of the CFR water (calcium carbonate signature). The 'tea-water' sample has a calcium carbonate profile similar to the CFR samples but is higher in TDS and has slightly higher sodium and sulfate than the CFR water.
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Memorandum Meta! and Common Ion Results for 5-23-18 Water Samples Smurfit-Stone / Prenchtown Mill Site NewFields Project No. 350.0065.001 June 6, 2018
Exceedances of water quality standards are highlighted with a yellow background in Table 1. Exceedances of background levels are shown with bold font and, groundwater concentrations and relevant groundwater standards are shown with blue font in Table 1.
A field duplicate and a field blank were collected to help measure the precision and accuracy of the sample results. The field blank consisted of deionized (Millipore) water and preservative respective of analytical methods. Original laboratory results are also attached for your review.
References EPA, 2017. Draft Human Health Risk Assessment for the Smurfit-Stone/Frenchtown Mill Operable Unit 3 Site Located in Missoula County, Montana. December.
EPA, 2018. Regional Screening Levels for Chemical Contaminants at Superfund Sites, May. on-line. https://www.epa.gov/risk/regional-screening-levels-rsls-generic-tables. Office of Superfund Remediation and Technology Innovation.
MTDEQ, 2017. Water Quality Circulars by Program, DEQ7. http://deq.mt.gov/wqinfo/circulars.mcpx, Accessed May 2018. Montana Department of Environmental Quality.
NewFields, 2018. December 2017 Groundwater Data Summary Report. Smurfit Stone / Frenchtown Mill Site, Missoula County Montana. April. 2873p.
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Memorandum Meta! and Common Ion Results for 5-23-18 Water Samples Smurfit-Stone / Prenchtown Mill Site NewFields Project No. 350.0065.001 June 6, 2018
Attach ment A Figure 1
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Aerial Photo Source: N AIF 201 ! and Newfieids 2016 (Within Site Boundary)
SNewFields
^Floodplain Source: As defined by the Federal Emergency Management Agency (FEMA) 2013 Digital Flood Insurance Rate Map (DFIRM). (N FIP 2 0I3 )
Notes
AG - Agricultural Land AB - Aeration Stabilization Basin C FR - Clark Fork River C L - Clarifier FP - Rood plain HP - Holding or Storage Pond IB - Rapid Infiltration Basin NPP - North Polishing Pond
P - Settling Pond SB - Spoils Basin SPP - South Polishing Pond SWB - Solid Waste Basin W R - West of River
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May 23, 2018 Sample Locations Former Frenchtown Mill Site Missoula County, Montana FIGURE 1
ED 002061 00090997-00005
Memorandum Meta! and Common Ion Results for 5-23-18 Water Samples Smurfit-Stone / Prenchtown Mill Site NewFields Project No. 350.0065.001 June 6, 2018
Attachment B Tables
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TABLE 1 - Total and Dissolved Metals (ug/L) in Surface Water and Groundwater Samples Collected on 5/23/18 Former Smurfit-Stone / Frenchtown Mill Site Missoula County, Montana
Total Metals Sample Date
DeScripti
Sample Results SM W -ll 5/23/2018 Groundwater CFR-HB-1 5/23/2018 Background SW CFR-1 5/23/2018 Background SW
HP-2 Pond 5/23/2018 Upgradient Pondwater HP-13A Pond 5/23/2018 Upgradient Pondwater CFR-HP-13A 5/23/2018 'tea-water'
CFR-2 5/23/2018 Downgradient to tea-water Quality Control Samples
SW-DUP 5/23/2018 'tea-water' Field Blank 5/23/2018 Blank
Water Quality Standards3and Background Concentrations Background Groundwater (Total) EPA MCL EPA secondary MCL
MDEQ-7 Human Health Standard for Groundwater MDEQ-7 Human Health Standard for Surface Water
MDEQ-7 Acute Aquatic Life Standard MDEQ-7 Chronic Aquatic Life Standard
175 J 1260 1220
218 J 138 J 81.8 J 747
87.3 J 48.6
34.6
50
750 87
0.87 0.3 J
0.26 J 1.3 1.4
0.57 0.29 J
0.56 0.12 U
0.25 6
37.5 4.6 4.6 5.4
16.2 21.5
7.3
22.2 0.21 U
5.1 10
10 10 340 150
161 85.6 85.2 105 90.3 123 81.8
127 0.8
359 2000
1000 1000
0.11 J 0.089 J 0.091 J 0.079 J 0.064 U 0.064 U 0.064 U
0.064 U 0.064 U
0 4
Chromium
0.028 U 0.1
0.088 0.3 0.43 0.27
0.086
0.24 0.028 U
0.08 5
5 5
1,04 0.48
4.3 1.2 1.1 1.6 1.5 0.41 UJ 0.75
0.41 UJ 0.41 J
4.6 100
100 100
0.51 0.54 0.54
1.6 0.75 0.31 J
0.4 J
0.32 J 0.15 U
0.5
0.58 J 15.4
15 13.8 19.6 24.5 13.1
25.4 0.22 J
2.4 1300 1000 1300 1300
7.86 5.53
1530 1170 1180 480
615 159 721
163 37.5 J
50
300
1000
0.27 2.4 2.5
0.63 1
0.62 1.6
0.62 0.072 J
0.1 15
15 15
37,4 1.46
6830 71.4 72.9 428 953 277 163
287 1.7
2.2
50
5.6 1.1 1.1 4.3 3.4 0.86 0.91
0.88 0.28 J
0.8
100 100 27Q 3
31,1
0.69 0.17 U 0.17 U 0.24 J 0.36 J 0.17 U 0.17 U
0.17 U 0.17 U
0.5 50
50 50 20 5
0.17 U 0.17 U 0.17 U 0.17 U 0.17 U 0.19 J 0.17 U
0.2 J 0.17 U
0.5
100 100 100
1.41
0.028 U 0.028 U 0.028 U 0.028 U 0.028 U 0.028 U 0.028 U
0.028 U 0.028 U
0.1 2
2 0.24
22.1 2 2
5.3 6.9 1.3 1.9
1.3 0.27 U
1.6
1.6 J 23.6 24.1
22 43 13.9 15.3
13.3 1.4 J
5
5000 2000 7400
71,3 71.3
d Metals Sample Date
Aluminum
Sample Results SM W -ll 5/23/2018 Groundwater CFR-HB-1 5/23/2018 Background SW CFR-1 5/23/2018 Background SW
HP-2 Pond 5/23/2018 Upgradient Pondwater HP-13A Pond 5/23/2018 Upgradient Pondwater CFR-HP-13A 5/23/2018 'tea-water'
CFR-2 5/23/2018 Downgradient to tea-water
Quality Control Samples SW-DUP 5/23/2018 'tea-water'
Field Blank 5/23/2018 blank Background Concentrations
Background Groundwater (Dissolved)
152 61.2 69.4 76.6 48.6 32.1 70.9
36.6 2.9 J
11.3
Antim
0.87 0.23 J 0.24 J
1.2 1.6 0.92 0.5 J
0.74 0.12 U
0.84
Arsenic
36.6 3.1 2.8 5.1
14.4 21.5
6.2
21.8 0.21 U
5.6
Barium Beryllium Cadmium Chromium
163 60.8 55.8 100 84.3 120 67.4
120 0.14 U
363
0.098 J 0.064 U 0.064 U 0.064 U 0.064 U 0.064 U 0.064 U
0.064 U 0.064 U
0
0.028 U 0.028 U 0.029 J 0.24 0.28 0.19 0.048 J
0.2 0.028 U
0.08
4 0.34 J 0.27 J
1.2 1.1 0.5 J 0.25 UJ
0.34 J 0.25 J
1.1
Cob
0.48 J 0.37 J 0.15 U
1.9 0.74 0.43 J 0.22 J
0.34 J 0.15 U
0.5
I
0.58 J 4
3.8 11.2 14.8 18.8 6.1
1440 53.4 54.5 266 398 91.6 73.5
19.2 0.2 U
95.2 6.8 U
3.4
50
0.31 0.13 0.13 0.39 0.73 0.36 0.25
0.38 0.028 U
0.18
Nickef
Seleniu
7300 18.9 17.7 360 897 247 118
247 0.26 J
68.5
4.9 0.29 J
0.4 J 3.7 2.9 0.97 0.46 J
0.85 0.12 U
1
0.6 0.17 U 0.17 U
0.3 J 0.38 J 0.17 U 0.17 U
0.17 U 0.17 U
0.5
Notes:
CFR - Clark Fork River J - Concentration is considered estimated. U - Concentration is below the reporting limit. Reporting limit shown
DUP - duplicate sample (associated natural sample) ug/L - All units in microgram s per liter (ug/L)
- exceeds the lowest applicable water quality standard BOLD - exceeds background sample concentration BLUE - Groundwater concentrations and standards
a Some aquatic-life water quality standards have been adjusted to account for changes in sample hardness. Adjusted values are shown with green font. Calculations are shown in Table 3. Calculations were completed in accordance with M DEQ Circular-7 guidance.
Silver
0.17 U 0.17 U 0.17 U 0.17 U 0.17 U 0.17 U 0.17 U
0.17 U 0.17 U
0.5
Thalfium Vanadium
0.028 U 0.028 U 0.028 U 0.028 U 0.028 U 0.028 U 0.028 U
0.028 U 0.028 U
0.1
21.3 0.59 J 0.53 J
4.8 6.5 1.4 0.95 J
1.3 0.27 U
1.8
Zinc
2.5 J 4.1 J 4.4 J 14.6 26 10 7.3
9.5 1.4 J
5.6
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TABLE 2 - Common Ions in Surface Water and Groundwater Samples Collected on 5/23/18 Former Smurfit-Stone / Frenchtown Mill Site Missoula County, Montana
Sample identification Sample Date
Sample Results CFR-HB-1 CFR-1 HP-2 Pond SMW-11
HP-13A Pond CFR-HP-13A CFR-2
5/23/2018 5/23/2018 5/23/2018 5/23/2018 5/23/2018 5/23/2018 5/23/2018
Quality Control Samples CFR HP13A (Dup) 5/23/2018 Filtered Dl Water 5/23/2018
Chloride (mg/L)
1.2 J 1.2 J 37.3 J 54.3 J 78.5 J 10 J 3.8 J
9.8 J 0.37 J
Fluoride (mg/L)
Nitrogen, N02 plus Phosphorus N03 (mg/L) (m g/L)
Sulfate (mg/L)
A .......... B uirboriijte
(CaC03)
(m g /L)
Carbonate (CaC03) (mg/L)
Total Dissolved
Solids (mg/L)
Total Organic Carbon (mg/L)
Specific Conductance
(uS/cm)
pH (s.u.)
0.089 J
0.024 J
0.11
5.8 J
56.3
0.086 J
0.053 J
0.097 J
5.5 J
56.5
0.22 J
0.016 J
0.24
1220 J
341
0.22 J
0.011 U
0.77
947 J
846
0.27 J
0.023 J
0.28
1540 J
545
0.12 J
0.011 U
0.27
45.7 J
172
0.096 J
0.038 J
0.1
17 J
79.8
1 U
99
5
1 U
100
4.9
1 u
2120
37.5
1 u
2450
41.4
43.4
2980
50.5
1 U
296
17.2
1 U
123
5.7
124 160 2970 3210 4240 419 199
7.8 J 7 J
8.1 J 7.5 J 8.2 J 6.8 J
7 J
0.12 J 0.015 UJ
0.019 J 0.011 U
0.3 0.043 U
44.5 J 0.53 J
165 1 U
1 U
293
17.7
1 U
50 U
0.42 J
423
7.6 J
1.7
4.6 J
Notes: CFR - Clark Fork River J - Concentration is considered estimated. U - Concentration is below the reporting limit. Reporting limit shown
DUP (NM) - duplicate sample (associated natural sample) NM - natural sample
mg/L - milligrams per liter Pg/L - micrograms per liter s.u. - standard units pS/cm - micro Siemens per centimeter
Calcium (ug/L)
Magnesium Potassium
(ug/L)
(ug/M
18100 17400 99300 108000 91300 30900 19000
5550 5240 57700 32500 45500 8800 5640
1470 1430 46800 29700 44400 7490 2050
31400J 176
9380 75.1
7840 19.8 J
Sodium (ug/M
Calcium, Dissolved
(ug/M
Magnesium, Dissolved (ug/L)
Potassium, Dissolved
(*Jg/L)
Sodium, Dissolved
(ug/M
3200 2900 611000 773000 957000 54900 22500
15800J 14900J 97100J 112000J 85600J 28600J 17500J
4380 4120 55500 33500 41900 8430 4970
1010 978
46400 29900 41200
7220 1720
2640 J 2530 J 590000J 773000J 885000J 55500J 20400J
57600J 21.7 J
40000J 31.3 J
8400 5.5 J
7100 12.5 U
78200J 153 J
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TABLE 3 - MDEQ-7 Aquatic Life Standards Adjusted for Hardness Concentrations Former Smurfit-Stone / Frenchtown Mill Site Missoula County, Montana
Sample Results
Sample
Calcium Dissolved
(ug/L)
Magnesium Dissolved Hardness (mg/L)
(ug/L)
Hardness, limits (mg/L)1 Cadmium
CFR-HB-1
15800
4380
57.5
57.5
1.11
CFR-1
14900
4120
54.2
54.2
1.04
HP-2 Pond
97100
55500
471
400
7.38
HP-13A Pond
85600
41900
386
386
7.13
CFR-HP-13A
28600
8430
106
106
2.01
CFR-2
17500
4970
64.2
64.2
1.23
SW-DUP
40000
8400
134
134
2.54
Low est Adjusted Standard
1.04
Notes:
1 If hardness is <25 mg/L as CaC03, 25 must be used in calculation
If hardness is >400 mg/L as CaC03, 400 must be used in calculation
Copper
8.31 7.86 51.7 50.0 14.8 9.22 18.5
7.86
Chromium {HD
1146 1091 5612 5454 1893 1254 2298
1091
Acute
Lead
40.4 37.4 476.8 456.1 88.1 46.4 119.0
37.4
Freshwater Aquatic Life Standards (ug/L)
Chronic
Nickel Silver
Zinc.
Cadmium Copper
Chromium (!!!)
Lead
294
1.57
75.0 0.508
5.81
279
1.41
71.3 0.485
5.53
1516
44.0 387.8
2.39
30.5
1472
41.5 376.5
2.32
29.6
493
4.50 126.0 0.829
9.82
322
1.89
82.3 0.555
6.39
603
6.76 154.0
1.00
12.0
279
1.41
71.3
0.48
5.53
54.8
1.57
52.2
1.46
268.2
18.6
260.7
17.8
90.5
3.43
59.9
1.81
109.8
4.64
52.2
1.46
Nickel
32.7 31.1 168.5 163.6 54.9 35.8 67.0
31.1
Silver
-
Zinc
75.0 71.3 387.8 376.5 126.0 82.3 154.0
71.3
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Memorandum Meta! and Common Ion Results for 5-23-18 Water Samples Smurfit-Stone / Prenchtown Mill Site NewFields Project No. 350.0065.001 June 6, 2018
Attach m e n t C Laboratory Report
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/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
June 04, 2018
David Tooke Newfields 700 SW Higgins Ave. Suite 15 Missoula, MT 59803
RE: Project: 350.0065.001 Ph15 Frenchtown Pace Project No.: 10432836
Dear David Tooke: Enclosed are the analytical results for sample(s) received by the laboratory on May 25, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kang Khang kang.khang@pacelabs.com (406)254-7226 Project Manager
Enclosures
cc: Accounts Payable (Donna McCammon), Newfields Companies LLC Chris Cerquone, Newfields Adam Johnson, NewFields Katie Sitler, Newfields Sydney Stewart, Newfields
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.
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ED 002061 00090997-00011
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Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
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REPORT OF LABORATORY ANALYSIS
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Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Lab ID
Sample ID
10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008 10432831001
CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB CFR-HP-13A
SAMPLE SUMMARY
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Matrix
\AMer \AMer \AMer \AMer \AMer \AMer \AMer \AMer \AMer
Date Collected
05/23/18 19:10 05/23/18 17:40 05/23/18 15:40 05/23/18 16:15 05/23/18 18:40 05/23/18 19:50 05/23/18 00:00 05/23/18 20:55 05/23/18 16:40
Date Received
05/25/18 10:00 05/25/18 10:00 05/25/18 10:00 05/25/18 10:00 05/25/18 10:00 05/25/18 10:00 05/25/18 10:00 05/25/18 10:00 05/25/18 10:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
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Page 3 of 58 ED 002061 00090997-00013
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
SAMPLE ANALYTE COUNT
Lab ID 10432836001
Sample ID CFR-1
10432836002 CFR-2
10432836003 SMW-11
10432836004 HP-13A Pond
Method
EPA 6020A EPA 6020A SM 2320B SM 2540C SM 4500-H+B SM 2510 EPA 300.0 EPA 353.2 SM 5310C SM 4500-P E EPA 6020A EPA 6020A SM 2320B SM 2540C SM 4500-H+B SM 2510 EPA 300.0 EPA 353.2 SM 5310C SM 4500-P E EPA 6020A EPA 6020A SM 2320B SM 2540C SM 4500-H+B SM 2510 EPA 300.0 EPA 353.2 SM 5310C SM 4500-P E EPA 6020A EPA 6020A SM 2320B SM 2540C SM 4500-H+B SM 2510 EPA 300.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Analysts
TT3 TT3 AR3 NAS AR3 AR3 KEO JFP JK1 KEO TT3 TT3 AR3 NAS AR3 AR3 KEO JFP JK1 KEO TT3 TT3 AR3 NAS AR3 AR3 KEO JFP JK1 KEO TT3 TT3 AR3 NAS AR3 AR3 KEO
Analytes Reported Laboratory
22 PASI-M 22 PASI-M
2 PASI-M 1 PASI-M 1 PASI-M 1 PASI-M 3 PASI-M 1 PASI-M 1 PASI-V 1 PASI-M 22 PASI-M 22 PASI-M 2 PASI-M 1 PASI-M 1 PASI-M 1 PASI-M 3 PASI-M 1 PASI-M 1 PASI-V 1 PASI-M 22 PASI-M 22 PASI-M 2 PASI-M 1 PASI-M 1 PASI-M 1 PASI-M 3 PASI-M 1 PASI-M 1 PASI-V 1 PASI-M 22 PASI-M 22 PASI-M 2 PASI-M 1 PASI-M 1 PASI-M 1 PASI-M 3 PASI-M
Page 4 of 58
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Tier 10
ED 002061 00090997-00014
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
SAMPLE ANALYTE COUNT
Lab ID
Sample ID
10432836005 HP-2 Pond
10432836006 CFR-HB-1
10432836007 SW-DUP
10432836008 ERB
Method
EPA 353.2 SM 5310C SM 4500-P E EPA 6020A EPA 6020A SM 2320B SM 2540C SM 4500-H+B SM 2510 EPA 300.0 EPA 353.2 SM 5310C SM 4500-P E EPA 6020A EPA 6020A SM 2320B SM 2540C SM 4500-H+B SM 2510 EPA 300.0 EPA 353.2 SM 5310C SM 4500-P E EPA 6020A EPA 6020A SM 2320B SM 2540C SM 4500-H+B SM 2510 EPA 300.0 EPA 353.2 SM 5310C SM 4500-P E EPA 6020A EPA 6020A SM 2320B SM 2540C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Analysts
JFP JK1 KEO TT3 TT3 AR3 NAS AR3 AR3 KEO JFP JK1 KEO TT3 TT3 AR3 NAS AR3 AR3 KEO JFP JK1 KEO TT3 TT3 AR3 NAS AR3 AR3 KEO JFP JK1 KEO TT3 TT3 AR3 NAS
Analytes Reported Laboratory
1 PASI-M 1 PASI-V 1 PASI-M 22 PASI-M 22 PASI-M 2 PASI-M 1 PASI-M 1 PASI-M 1 PASI-M 3 PASI-M 1 PASI-M 1 PASI-V 1 PASI-M 22 PASI-M 22 PASI-M 2 PASI-M 1 PASI-M 1 PASI-M 1 PASI-M 3 PASI-M 1 PASI-M 1 PASI-V 1 PASI-M 22 PASI-M 22 PASI-M 2 PASI-M 1 PASI-M 1 PASI-M 1 PASI-M 3 PASI-M 1 PASI-M 1 PASI-V 1 PASI-M 22 PASI-M 22 PASI-M 2 PASI-M 1 PASI-M
Page 5 of 58
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ED 002061 00090997-00015
/*2aoeAnalytical mm.pacabs.cem
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
SAMPLE ANALYTE COUNT
Lab ID
Sample ID
10432831001 CFR-HP-13A
Method
SM 4500-H+B SM 2510 EPA 300.0 EPA 353.2 SM 5310C
SM 4500-P E EPA 6020A EPA 6020A SM 2320B SM 2540C SM 4500-H+B SM 2510 EPA 300.0 EPA 353.2 SM 5310C SM 4500-P E
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Analysts
AR3 AR3 KEO JFP JK1 KEO TT3 TT3 AR3 NAS AR3 AR3 KEO JFP JK1 KEO
Analytes Reported Laboratory
1 PASI-M 1 PASI-M 3 PASI-M 1 PASI-M 1 PASI-V 1 PASI-M 22 PASI-M 22 PASI-M 2 PASI-M 1 PASI-M 1 PASI-M 1 PASI-M 3 PASI-M 1 PASI-M 1 PASI-V 1 PASI-M
REPORT OF LABORATORY ANALYSIS
This report shaii not be reproduced, except in fuii, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 6 of 58 ED 002061 00090997-00016
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: EPA 6020A
Description: 6020A MET ICPMS
Client:
Newfields
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCU R) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation: The samples were prepared In accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below.
Continuing Calibration: All criteria were within method requirements with any exceptions noted below.
Internal Standards: All internal standards were within QC limits with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 7 of 58 ED 002061 00090997-00017
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: EPA 6020A
Description: 6020A MET ICPMS, Dissolved
Client:
Newfields
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCU R) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation: The samples were prepared In accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below.
Continuing Calibration: All criteria were within method requirements with any exceptions noted below.
Internal Standards: All internal standards were within QC limits with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: 541156
B: Analyte was detected in the associated method blank. BLANK for HBN 541156 [MPRP/824 (Lab ID: 2943635) Manganese, Dissolved
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: 541156
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10432836001 M1 : Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS (Lab ID: 2943637) Calcium, Dissolved MSD (Lab ID: 2943638) Calcium, Dissolved
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 8 of 58 ED 002061 00090997-00018
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: SM 2320B
Description: 2320B Alkalinity
Client:
Newflelds
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCU R) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 9 of 58 ED 002061 00090997-00019
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: SM 2540C
Description: 2540C Total Dissolved Solids
Client:
Newfields
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for SM 2540C. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCU R) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
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Page 10 o f 58 ED 002061 00090997-00020
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: SM4500-H+B
Description: 4500H+ pH, Electrometric
Client:
Newfields
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for SM 4500-H+B. All samples were received in acceptable condition with any exceptions noted below or on the chaln-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
H6: Analysis initiated outside of the 15 minute EPA required holding time. CFR-1 (Lab ID: 10432836001) CFR-2 (Lab ID: 10432836002) CFR-HB-1 (Lab ID: 10432836006) CFR-HP-13A (Lab ID: 10432831001) ERB (Lab ID: 10432836008) HP-13A Pond (Lab ID: 10432836004) HP-2 Pond (Lab ID: 10432836005) SMW-11 (Lab ID: 10432836003) SW-DUP (Lab ID: 10432836007)
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 11 of 58 ED 002061 00090997-00021
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: SM 2510
Description: SM2510 Specific Conductance
Client:
Newfields
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for SM 2510. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCU R) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 12 o f 58 ED 002061 00090997-00022
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: EPA 300.0
Description: 300.0 IC Anions
Client:
Newfields
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCU R) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: 541303
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10431928006,10432489006 M1 : Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS (Lab ID: 2944285) Fluoride MS (Lab ID: 2944309) Chloride Sulfate MSD (Lab ID: 2944286) Fluoride MSD (Lab ID: 2944310) Chloride Sulfate
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
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Page 13 o f 58 ED 002061 00090997-00023
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: EPA 353.2
Description: 353.2 Nitrate + Nitrite
Client:
Newfields
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCU R) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
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Page 14 o f 58 ED 002061 00090997-00024
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: SM 5310C
Description: 531 OC TOC
Client:
Newfields
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for SM 5310C. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCU R) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
Sierra Club v. EPA 18cv3472 NDCA
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Page 15 o f 58 ED 002061 00090997-00025
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Method: SM 4500-P E
Description: SM4500P-E, Total Phosphorus
Client:
Newfields
Date:
June 04, 2018
PRO JECT NARRATIVE
General Information: 9 samples were analyzed for SM 4500-P E. All samples were received in acceptable condition with any exceptions noted below or on the chaln-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation: The samples were prepared In accordance with SM 4500-P B with any exceptions noted below.
Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: 541342
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10432366001,10432717001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. MS (Lab ID: 2944466) Phosphorus MSD (Lab ID: 2944467) Phosphorus
Additional Comments: This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC .
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Page 16 o f 58 ED 002061 00090997-00026
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project: Pace Project No.: Sample: CFR-1
350.0065.001 Ph15 Frenchtown 10432836
Lab ID: 10432836001
Parameters
Results
Units
Collected: 05/23/18 19:10 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
6020A MET ICPMS
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper
Iron
Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium
Z in c
6020A MET ICPMS, Dissolved
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Analytical Method: EPA 6020A Preparation Method: EPA 3020
1220
ug/L
0.26J
ug/L
4.6
ug/L
85.2
ug/L
0.091 J
ug/L
0.088
ug/L
17400
ug/L
1.1
ug/L
0.54
ug/L
15.0
ug/L
1180
ug/L
2.5
ug/L
5240
ug/L
72.9
ug/L
1.1
ug/L
1430
ug/L
ND
ug/L
ND
ug/L
2900
ug/L
ND
ug/L
2.0
ug/L
24.1
ug/L
10.0 1 05/30/18 08:53 06/01/18 10:12 7429-90-5 0.50 1 05/30/18 08:53 06/01/18 10:12 7440-36-0 0.50 1 05/30/18 08:53 06/01/18 10:12 7440-38-2 0.30 1 05/30/18 08:53 06/01/18 10:12 7440-39-3 0.20 1 05/30/18 08:53 06/01/18 10:12 7440-41 -7 0.080 1 05/30/18 08:53 06/01/18 10:12 7440-43-9 40.0 1 05/30/18 08:53 06/01/18 10:12 7440-70-2 0.50 1 05/30/18 08:53 06/01/18 10:12 7440-47-3 0.50 1 05/30/18 08:53 06/01/18 10:12 7440-48-4
1.0 1 05/30/18 08:53 06/01/18 10:12 7440-50-8 50.0 1 05/30/18 08:53 06/01/18 10:12 7439-89-6 0.10 1 05/30/18 08:53 06/01/18 10:12 7439-92-1 10.0 1 05/30/18 08:53 06/01/18 10:12 7439-95-4 0.50 1 05/30/18 08:53 06/01/18 10:12 7439-96-5 0.50 1 05/30/18 08:53 06/01/18 10:12 7440-02-0 50.0 1 05/30/18 08:53 06/01/18 10:12 7440-09-7 0.50 1 05/30/18 08:53 06/01/18 10:12 7782-49-2 0.50 1 05/30/18 08:53 06/01/18 10:12 7440-22-4 50.0 1 05/30/18 08:53 06/01/18 10:12 7440-23-5 0.10 1 05/30/18 08:53 06/01/18 10:12 7440-28-0
1.0 1 05/30/18 08:53 06/01/18 10:12 7440-62-2 5.0 1 05/30/18 08:53 06/01/18 10:12 7440-66-6
Analytical Method: EPA 6020A Preparation Method: EPA 3020
69.4
ug/L
0.24J
ug/L
2.8
ug/L
55.8
ug/L
ND
ug/L
0.029J
ug/L
14900
ug/L
0.27J
ug/L
ND
ug/L
3.8
ug/L
54.5
ug/L
0.13
ug/L
4120
ug/L
17.7
ug/L
0.40J
ug/L
978
ug/L
ND
ug/L
ND
ug/L
2530
ug/L
ND
ug/L
0.53J
ug/L
4.4J
ug/L
10.0 1 05/30/18 09:28 06/01/18 20:45 7429-90-5 0.50 1 05/30/18 09:28 06/01/18 20:45 7440-36-0 0.50 1 05/30/18 09:28 06/01/18 20:45 7440-38-2 0.30 1 05/30/18 09:28 06/01/18 20:45 7440-39-3 0.20 1 05/30/18 09:28 06/01/18 20:45 7440-41 -7 0.080 1 05/30/18 09:28 06/01/18 20:45 7440-43-9 40.0 1 05/30/18 09:28 06/01/18 20:45 7440-70-2 0.50 1 05/30/18 09:28 06/01/18 20:45 7440-47-3 0.50 1 05/30/18 09:28 06/01/18 20:45 7440-48-4
1.0 1 05/30/18 09:28 06/01/18 20:45 7440-50-8 50.0 1 05/30/18 09:28 06/01/18 20:45 7439-89-6 0.10 1 05/30/18 09:28 06/01/18 20:45 7439-92-1 10.0 1 05/30/18 09:28 06/01/18 20:45 7439-95-4 0.50 1 05/30/18 09:28 06/01/18 20:45 7439-96-5 0.50 1 05/30/18 09:28 06/01/18 20:45 7440-02-0 50.0 1 05/30/18 09:28 06/01/18 20:45 7440-09-7 0.50 1 05/30/18 09:28 06/01/18 20:45 7782-49-2 0.50 1 05/30/18 09:28 06/01/18 20:45 7440-22-4 50.0 1 05/30/18 09:28 06/01/18 20:45 7440-23-5 0.10 1 05/30/18 09:28 06/01/18 20:45 7440-28-0
1.0 1 05/30/18 09:28 06/01/18 20:45 7440-62-2 5.0 1 05/30/18 09:28 06/01/18 20:45 7440-66-6
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 17 of 58
ED 002061 00090997-00027
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project: Pace Project No.: Sample: CFR-1
350.0065.001 Ph15 Frenchtown 10432836
Lab ID: 10432836001
Collected: 05/23/18 19:10 Received: 05/25/18 10:00 Matrix: Water
Parameters
Results
Units
Report Limit DF
Prepared
Analyzed
C A S No.
Qua!
2320B Alkalinity Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03) 2540C Total Dissolved Solids Total Dissolved Solids 4500H+ pH, Electrometric pH at 25 Degrees C SM2510 Specific Conductance Specific Conductance 300.0 IC Anions Chloride Fluoride Sulfate 353.2 Nitrate + Nitrite Nitrogen, N02 plus N03 5310C TOC Total Organic Carbon SM4500P-E, Total Phosphorus Phosphorus
Analytical Method: SM 2320B
56.5
mg/L
ND
mg/L
5.0 1 5.0 1
05/29/18 16:24 05/29/18 16:24
Analytical Method: SM 2540C
100
mg/L
10.0 1
05/30/18 20:26
Analytical Method: SM 4500-H+B
7.0 Std. Units
0.10 1
05/29/18 17:51
Analytical Method: SM 2510
160 umhos/cm
1.0 1
05/29/18 16:44
Analytical Method: EPA 300.0
1.2 0.086
5.5
mg/L mg/L mg/L
1.2 1 0.050 1
1.2 1
05/30/18 04:04 16887-00-6 05/30/18 04:04 16984-48-8 05/30/18 04:04 14808-79-8
Analytical Method: EPA 353.2
0.053J
mg/L
0.10 1
05/31/18 09:35
Analytical Method: SM 5310C
4.9
mg/L
1.0 1
05/29/18 14:08 7440-44-0
Analytical Method: SM 4500-P E Preparation Method: SM 4500-P B
0.097J
mg/L
0.10 1 05/30/18 09:39 05/30/18 12:53 7723-14-0
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 18 of 58
ED 002061 00090997-00028
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project: Pace Project No.: Sample: CFR-2
350.0065.001 Ph15 Frenchtown 10432836
Lab ID: 10432836002
Parameters
Results
Units
Collected: 05/23/18 17:40 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
6020A MET ICPMS
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
6020A MET ICPMS, Dissolved
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Analytical Method: EPA 6020A Preparation Method: EPA 3020
747
ug/L
0.29J
ug/L
7.3
ug/L
81.8
ug/L
ND
ug/L
0.086
ug/L
19000
ug/L
0.75
ug/L
0.40J
ug/L
13.1
ug/L
721
ug/L
1.6
ug/L
5640
ug/L
163
ug/L
0.91
ug/L
2050
ug/L
ND
ug/L
ND
ug/L
22500
ug/L
ND
ug/L
1.9
ug/L
15.3
ug/L
10.0 1 05/30/18 08:53 06/01/18 10:09 7429-90-5 0.50 1 05/30/18 08:53 06/01/18 10:09 7440-36-0 0.50 1 05/30/18 08:53 06/01/18 10:09 7440-38-2 0.30 1 05/30/18 08:53 06/01/18 10:09 7440-39-3 0.20 1 05/30/18 08:53 06/01/18 10:09 7440-41 -7 0.080 1 05/30/18 08:53 06/01/18 10:09 7440-43-9 40.0 1 05/30/18 08:53 06/01/18 10:09 7440-70-2 0.50 1 05/30/18 08:53 06/01/18 10:09 7440-47-3 0.50 1 05/30/18 08:53 06/01/18 10:09 7440-48-4
1.0 1 05/30/18 08:53 06/01/18 10:09 7440-50-8 50.0 1 05/30/18 08:53 06/01/18 10:09 7439-89-6 0.10 1 05/30/18 08:53 06/01/18 10:09 7439-92-1 10.0 1 05/30/18 08:53 06/01/18 10:09 7439-95-4 0.50 1 05/30/18 08:53 06/01/18 10:09 7439-96-5 0.50 1 05/30/18 08:53 06/01/18 10:09 7440-02-0 50.0 1 05/30/18 08:53 06/01/18 10:09 7440-09-7 0.50 1 05/30/18 08:53 06/01/18 10:09 7782-49-2 0.50 1 05/30/18 08:53 06/01/18 10:09 7440-22-4 250 5 05/30/18 08:53 06/01/18 10:33 7440-23-5 0.10 1 05/30/18 08:53 06/01/18 10:09 7440-28-0
1.0 1 05/30/18 08:53 06/01/18 10:09 7440-62-2 5.0 1 05/30/18 08:53 06/01/18 10:09 7440-66-6
Analytical Method: EPA 6020A Preparation Method: EPA 3020
70.9
ug/L
0.50J
ug/L
6.2
ug/L
67.4
ug/L
ND
ug/L
0.048J
ug/L
17500
ug/L
0.24J
ug/L
0.22J
ug/L
6.1
ug/L
73.5
ug/L
0.25
ug/L
4970
ug/L
118
ug/L
0.46J
ug/L
1720
ug/L
ND
ug/L
ND
ug/L
20400
ug/L
ND
ug/L
0.95J
ug/L
7.3
ug/L
10.0 1 05/30/18 09:28 06/04/18 08:34 7429-90-5 0.50 1 05/30/18 09:28 06/04/18 08:34 7440-36-0 0.50 1 05/30/18 09:28 06/04/18 08:34 7440-38-2 0.30 1 05/30/18 09:28 06/04/18 08:34 7440-39-3 0.20 1 05/30/18 09:28 06/01/18 21:27 7440-41 -7 0.080 1 05/30/18 09:28 06/04/18 08:34 7440-43-9 40.0 1 05/30/18 09:28 06/04/18 08:34 7440-70-2 0.50 1 05/30/18 09:28 06/04/18 08:34 7440-47-3 0.50 1 05/30/18 09:28 06/04/18 08:34 7440-48-4
1.0 1 05/30/18 09:28 06/04/18 08:34 7440-50-8 50.0 1 05/30/18 09:28 06/04/18 08:34 7439-89-6 0.10 1 05/30/18 09:28 06/04/18 08:34 7439-92-1 10.0 1 05/30/18 09:28 06/04/18 08:34 7439-95-4 0.50 1 05/30/18 09:28 06/04/18 08:34 7439-96-5 0.50 1 05/30/18 09:28 06/04/18 08:34 7440-02-0 50.0 1 05/30/18 09:28 06/04/18 08:34 7440-09-7 0.50 1 05/30/18 09:28 06/01/18 21:27 7782-49-2 0.50 1 05/30/18 09:28 06/04/18 08:34 7440-22-4 50.0 1 05/30/18 09:28 06/04/18 08:34 7440-23-5 0.10 1 05/30/18 09:28 06/04/18 08:34 7440-28-0
1.0 1 05/30/18 09:28 06/04/18 08:34 7440-62-2 5.0 1 05/30/18 09:28 06/04/18 08:34 7440-66-6
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 19 of 58
ED 002061 00090997-00029
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project: Pace Project No.: Sample: CFR-2
350.0065.001 Ph15 Frenchtown 10432836
Lab ID: 10432836002
Collected: 05/23/18 17:40 Received: 05/25/18 10:00 Matrix: Water
Parameters
Results
Units
Report Limit DF
Prepared
Analyzed
C A S No.
Qua!
2320B Alkalinity Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03) 2540C Total Dissolved Solids Total Dissolved Solids 4500H+ pH, Electrometric pH at 25 Degrees C SM2510 Specific Conductance Specific Conductance 300.0 IC Anions Chloride Fluoride Sulfate 353.2 Nitrate + Nitrite Nitrogen, N02 plus N03 5310C TOC Total Organic Carbon SM4500P-E, Total Phosphorus Phosphorus
Analytical Method: SM 2320B
79.8
mg/L
ND
mg/L
5.0 1 5.0 1
05/29/18 16:28 05/29/18 16:28
Analytical Method: SM 2540C
123
mg/L
10.0 1
05/30/18 20:26
Analytical Method: SM 4500-H+B
7.0 Std. Units
0.10 1
05/29/18 17:52
Analytical Method: SM 2510
199 umhos/cm
1.0 1
05/29/18 16:46
Analytical Method: EPA 300.0
3.8 0.096
17.0
mg/L mg/L mg/L
1.2 1 0.050 1
1.2 1
05/30/18 04:19 16887-00-6 05/30/18 04:19 16984-48-8 05/30/18 04:19 14808-79-8
Analytical Method: EPA 353.2
0.038J
mg/L
0.10 1
05/31/18 09:36
Analytical Method: SM 5310C
5.7
mg/L
1.0 1
05/29/18 14:21 7440-44-0
Analytical Method: SM 4500-P E Preparation Method: SM 4500-P B
0.10
mg/L
0.10 1 05/30/18 09:39 05/30/18 12:54 7723-14-0
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 20 of 58
ED 002061 00090997-00030
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: SMW-11
Lab ID: 10432836003
Parameters
Results
Units
Collected: 05/23/18 15:40 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
6020A MET ICPMS
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
6020A MET ICPMS, Dissolved
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Analytical Method: EPA 6020A Preparation Method: EPA 3020
175
ug/L
0.87
ug/L
37.5
ug/L
161
ug/L
0.11J
ug/L
ND
ug/L
108000
ug/L
4.3
ug/L
0.51
ug/L
0.58J
ug/L
1530
ug/L
0.27
ug/L
32500
ug/L
6830
ug/L
5.6
ug/L
29700
ug/L
0.69
ug/L
ND
ug/L
773000
ug/L
ND
ug/L
22.1
ug/L
1.6J
ug/L
10.0 1 05/30/18 08:53 06/01/18 10:36 7429-90-5 0.50 1 05/30/18 08:53 06/01/18 10:36 7440-36-0 0.50 1 05/30/18 08:53 06/01/18 10:36 7440-38-2 0.30 1 05/30/18 08:53 06/01/18 10:36 7440-39-3 0.20 1 05/30/18 08:53 06/01/18 10:36 7440-41 -7 0.080 1 05/30/18 08:53 06/01/18 10:36 7440-43-9 2000 50 05/30/18 08:53 06/01/18 10:43 7440-70-2 0.50 1 05/30/18 08:53 06/01/18 10:36 7440-47-3 0.50 1 05/30/18 08:53 06/01/18 10:36 7440-48-4
1.0 1 05/30/18 08:53 06/01/18 10:36 7440-50-8 50.0 1 05/30/18 08:53 06/01/18 10:36 7439-89-6 0.10 1 05/30/18 08:53 06/01/18 10:36 7439-92-1 500 50 05/30/18 08:53 06/01/18 10:43 7439-95-4 25.0 50 05/30/18 08:53 06/01/18 10:43 7439-96-5 0.50 1 05/30/18 08:53 06/01/18 10:36 7440-02-0 2500 50 05/30/18 08:53 06/01/18 10:43 7440-09-7 0.50 1 05/30/18 08:53 06/01/18 10:36 7782-49-2 0.50 1 05/30/18 08:53 06/01/18 10:36 7440-22-4 2500 50 05/30/18 08:53 06/01/18 10:43 7440-23-5 0.10 1 05/30/18 08:53 06/01/18 10:36 7440-28-0
1.0 1 05/30/18 08:53 06/01/18 10:36 7440-62-2 5.0 1 05/30/18 08:53 06/01/18 10:36 7440-66-6
Analytical Method: EPA 6020A Preparation Method: EPA 3020
152
ug/L
0.87
ug/L
36.6
ug/L
163
ug/L
0.098J
ug/L
ND
ug/L
112000
ug/L
4.0
ug/L
0.48J
ug/L
0.58J
ug/L
1440
ug/L
0.31
ug/L
33500
ug/L
7300
ug/L
4.9
ug/L
29900
ug/L
0.60
ug/L
ND
ug/L
773000
ug/L
ND
ug/L
21.3
ug/L
2.5J
ug/L
10.0 1 05/30/18 09:28 06/04/18 08:21 7429-90-5 0.50 1 05/30/18 09:28 06/04/18 08:21 7440-36-0 0.50 1 05/30/18 09:28 06/04/18 08:21 7440-38-2 0.30 1 05/30/18 09:28 06/04/18 08:21 7440-39-3 0.20 1 05/30/18 09:28 06/01/18 21:10 7440-41 -7 0.080 1 05/30/18 09:28 06/04/18 08:21 7440-43-9 2000 50 05/30/18 09:28 06/04/18 08:23 7440-70-2 0.50 1 05/30/18 09:28 06/04/18 08:21 7440-47-3 0.50 1 05/30/18 09:28 06/04/18 08:21 7440-48-4
1.0 1 05/30/18 09:28 06/04/18 08:21 7440-50-8 50.0 1 05/30/18 09:28 06/04/18 08:21 7439-89-6 0.10 1 05/30/18 09:28 06/04/18 08:21 7439-92-1 500 50 05/30/18 09:28 06/04/18 08:23 7439-95-4 25.0 50 05/30/18 09:28 06/04/18 08:23 7439-96-5 0.50 1 05/30/18 09:28 06/04/18 08:21 7440-02-0 2500 50 05/30/18 09:28 06/04/18 08:23 7440-09-7 0.50 1 05/30/18 09:28 06/01/18 21:10 7782-49-2 0.50 1 05/30/18 09:28 06/04/18 08:21 7440-22-4 2500 50 05/30/18 09:28 06/04/18 08:23 7440-23-5 0.10 1 05/30/18 09:28 06/04/18 08:21 7440-28-0
1.0 1 05/30/18 09:28 06/04/18 08:21 7440-62-2 5.0 1 05/30/18 09:28 06/04/18 08:21 7440-66-6
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 21 of 58
ED 002061 00090997-00031
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: SMW-11
Lab ID: 10432836003
Parameters
Results
Units
Collected: 05/23/18 15:40 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
2320B Alkalinity Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03) 2540C Total Dissolved Solids Total Dissolved Solids 4500H+ pH, Electrometric pH at 25 Degrees C SM2510 Specific Conductance Specific Conductance 300.0 IC Anions Chloride Fluoride Sulfate 353.2 Nitrate + Nitrite Nitrogen, N02 plus N03 5310C TOC Total Organic Carbon SM4500P-E, Total Phosphorus Phosphorus
Analytical Method: SM 2320B
846
mg/L
ND
mg/L
5.0 1 5.0 1
05/29/18 16:32 05/29/18 16:32
Analytical Method: SM 2540C
2450
mg/L
100 1
05/30/18 20:26
Analytical Method: SM 4500-H+B
7.5 Std. Units
0.10 1
05/29/18 17:54
Analytical Method: SM 2510
3210 umhos/cm
1.0 1
05/29/18 16:48
Analytical Method: EPA 300.0
54.3
mg/L
0.22
mg/L
947
mg/L
1.2 1 0.050 1
24.0 20
05/30/18 04:34 16887-00-6 05/30/18 04:34 16984-48-8 05/30/18 10:11 14808-79-8
Analytical Method: EPA 353.2
ND
mg/L
0.10 1
05/31/18 09:37
Analytical Method: SM 5310C
41.4
mg/L
1.0 1
05/29/18 15:01 7440-44-0
Analytical Method: SM 4500-P E Preparation Method: SM 4500-P B
0.77
mg/L
0.10 1 05/30/18 09:39 05/30/18 12:54 7723-14-0
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 22 of 58
ED 002061 00090997-00032
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: HP-13A Pond
Lab ID: 10432836004
Parameters
Results
Units
Collected: 05/23/18 16:15 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
6020A MET ICPMS
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
6020A MET ICPMS, Dissolved
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Analytical Method: EPA 6020A Preparation Method: EPA 3020
138
ug/L
1.4
ug/L
16.2
ug/L
90.3
ug/L
ND
ug/L
0.43
ug/L
91300
ug/L
1.5
ug/L
0.75
ug/L
19.6
ug/L
615
ug/L
1.0
ug/L
45500
ug/L
953
ug/L
3.4
ug/L
44400
ug/L
0.36J
ug/L
ND
ug/L
957000
ug/L
ND
ug/L
6.9
ug/L
43.0
ug/L
10.0 1 05/30/18 08:53 06/01/18 10:38 7429-90-5 0.50 1 05/30/18 08:53 06/01/18 10:38 7440-36-0 0.50 1 05/30/18 08:53 06/01/18 10:38 7440-38-2 0.30 1 05/30/18 08:53 06/01/18 10:38 7440-39-3 0.20 1 05/30/18 08:53 06/01/18 10:38 7440-41 -7 0.080 1 05/30/18 08:53 06/01/18 10:38 7440-43-9 2000 50 05/30/18 08:53 06/01/18 10:48 7440-70-2 0.50 1 05/30/18 08:53 06/01/18 10:38 7440-47-3 0.50 1 05/30/18 08:53 06/01/18 10:38 7440-48-4
1.0 1 05/30/18 08:53 06/01/18 10:38 7440-50-8 50.0 1 05/30/18 08:53 06/01/18 10:38 7439-89-6 0.10 1 05/30/18 08:53 06/01/18 10:38 7439-92-1 500 50 05/30/18 08:53 06/01/18 10:48 7439-95-4 25.0 50 05/30/18 08:53 06/01/18 10:48 7439-96-5 0.50 1 05/30/18 08:53 06/01/18 10:38 7440-02-0 2500 50 05/30/18 08:53 06/01/18 10:48 7440-09-7 0.50 1 05/30/18 08:53 06/01/18 10:38 7782-49-2 0.50 1 05/30/18 08:53 06/01/18 10:38 7440-22-4 2500 50 05/30/18 08:53 06/01/18 10:48 7440-23-5 0.10 1 05/30/18 08:53 06/01/18 10:38 7440-28-0
1.0 1 05/30/18 08:53 06/01/18 10:38 7440-62-2 5.0 1 05/30/18 08:53 06/01/18 10:38 7440-66-6
Analytical Method: EPA 6020A Preparation Method: EPA 3020
48.6
ug/L
1.6
ug/L
14.4
ug/L
84.3
ug/L
ND
ug/L
0.28
ug/L
85600
ug/L
1.1
ug/L
0.74
ug/L
14.8
ug/L
398
ug/L
0.73
ug/L
41900
ug/L
897
ug/L
2.9
ug/L
41200
ug/L
0.38J
ug/L
ND
ug/L
885000
ug/L
ND
ug/L
6.5
ug/L
26.0
ug/L
10.0 1 05/30/18 09:28 06/04/18 08:25 7429-90-5 0.50 1 05/30/18 09:28 06/04/18 08:25 7440-36-0 0.50 1 05/30/18 09:28 06/04/18 08:25 7440-38-2 0.30 1 05/30/18 09:28 06/04/18 08:25 7440-39-3 0.20 1 05/30/18 09:28 06/01/18 21:15 7440-41 -7 0.080 1 05/30/18 09:28 06/04/18 08:25 7440-43-9 2000 50 05/30/18 09:28 06/04/18 08:27 7440-70-2 0.50 1 05/30/18 09:28 06/04/18 08:25 7440-47-3 0.50 1 05/30/18 09:28 06/04/18 08:25 7440-48-4
1.0 1 05/30/18 09:28 06/04/18 08:25 7440-50-8 50.0 1 05/30/18 09:28 06/04/18 08:25 7439-89-6 0.10 1 05/30/18 09:28 06/04/18 08:25 7439-92-1 500 50 05/30/18 09:28 06/04/18 08:27 7439-95-4 25.0 50 05/30/18 09:28 06/04/18 08:27 7439-96-5 0.50 1 05/30/18 09:28 06/04/18 08:25 7440-02-0 2500 50 05/30/18 09:28 06/04/18 08:27 7440-09-7 0.50 1 05/30/18 09:28 06/01/18 21:15 7782-49-2 0.50 1 05/30/18 09:28 06/04/18 08:25 7440-22-4 2500 50 05/30/18 09:28 06/04/18 08:27 7440-23-5 0.10 1 05/30/18 09:28 06/04/18 08:25 7440-28-0
1.0 1 05/30/18 09:28 06/04/18 08:25 7440-62-2 5.0 1 05/30/18 09:28 06/04/18 08:25 7440-66-6
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 23 of 58
ED 002061 00090997-00033
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: HP-13A Pond
Lab ID: 10432836004
Parameters
Results
Units
Collected: 05/23/18 16:15 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
2320B Alkalinity Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03) 2540C Total Dissolved Solids Total Dissolved Solids 4500H+ pH, Electrometric pH at 25 Degrees C SM2510 Specific Conductance Specific Conductance 300.0 IC Anions Chloride Fluoride Sulfate 353.2 Nitrate + Nitrite Nitrogen, N02 plus N03 5310C TOC Total Organic Carbon SM4500P-E, Total Phosphorus Phosphorus
Analytical Method: SM 2320B
545
mg/L
43.4
mg/L
5.0 1 5.0 1
05/30/18 13:13 05/30/18 13:13
Analytical Method: SM 2540C
2980
mg/L
200 1
05/30/18 20:26
Analytical Method: SM 4500-H+B
8.2 Std. Units
0.10 1
05/29/18 17:55
Analytical Method: SM 2510
4240 umhos/cm
1.0 1
05/29/18 16:49
Analytical Method: EPA 300.0
78.5
mg/L
0.27
mg/L
1540
mg/L
1.2 1 0.050 1
24.0 20
05/30/18 05:19 16887-00-6 05/30/18 05:19 16984-48-8 05/30/18 10:28 14808-79-8
Analytical Method: EPA 353.2
0.023J
mg/L
0.10 1
05/31/18 09:38
Analytical Method: SM 5310C
50.5
mg/L
2.0 2
05/30/18 08:00 7440-44-0
Analytical Method: SM 4500-P E Preparation Method: SM 4500-P B
0.28
mg/L
0.10 1 05/30/18 09:39 05/30/18 12:55 7723-14-0
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 24 of 58
ED 002061 00090997-00034
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: HP-2 Pond
Lab ID: 10432836005
Parameters
Results
Units
Collected: 05/23/18 18:40 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
6020A MET ICPMS
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper
Iron
Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium
Z in c
6020A MET ICPMS, Dissolved
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Analytical Method: EPA 6020A Preparation Method: EPA 3020
218
ug/L
1.3
ug/L
5.4
ug/L
105
ug/L
0.079J
ug/L
0.30
ug/L
99300
ug/L
1.6
ug/L
1.6
ug/L
13.8
ug/L
480
ug/L
0.63
ug/L
57700
ug/L
428
ug/L
4.3
ug/L
46800
ug/L
0.24J
ug/L
ND
ug/L
611000
ug/L
ND
ug/L
5.3
ug/L
22.0
ug/L
10.0 1 05/30/18 08:53 06/01/18 10:41 7429-90-5 0.50 1 05/30/18 08:53 06/01/18 10:41 7440-36-0 0.50 1 05/30/18 08:53 06/01/18 10:41 7440-38-2 0.30 1 05/30/18 08:53 06/01/18 10:41 7440-39-3 0.20 1 05/30/18 08:53 06/01/18 10:41 7440-41 -7 0.080 1 05/30/18 08:53 06/01/18 10:41 7440-43-9 2000 50 05/30/18 08:53 06/01/18 10:51 7440-70-2 0.50 1 05/30/18 08:53 06/01/18 10:41 7440-47-3 0.50 1 05/30/18 08:53 06/01/18 10:41 7440-48-4
1.0 1 05/30/18 08:53 06/01/18 10:41 7440-50-8 50.0 1 05/30/18 08:53 06/01/18 10:41 7439-89-6 0.10 1 05/30/18 08:53 06/01/18 10:41 7439-92-1 500 50 05/30/18 08:53 06/01/18 10:51 7439-95-4 0.50 1 05/30/18 08:53 06/01/18 10:41 7439-96-5 0.50 1 05/30/18 08:53 06/01/18 10:41 7440-02-0 2500 50 05/30/18 08:53 06/01/18 10:51 7440-09-7 0.50 1 05/30/18 08:53 06/01/18 10:41 7782-49-2 0.50 1 05/30/18 08:53 06/01/18 10:41 7440-22-4 2500 50 05/30/18 08:53 06/01/18 10:51 7440-23-5 0.10 1 05/30/18 08:53 06/01/18 10:41 7440-28-0
1.0 1 05/30/18 08:53 06/01/18 10:41 7440-62-2 5.0 1 05/30/18 08:53 06/01/18 10:41 7440-66-6
Analytical Method: EPA 6020A Preparation Method: EPA 3020
76.6
ug/L
1.2
ug/L
5.1
ug/L
100
ug/L
ND
ug/L
0.24
ug/L
97100
ug/L
1.2
ug/L
1.9
ug/L
11.2
ug/L
266
ug/L
0.39
ug/L
55500
ug/L
360
ug/L
3.7
ug/L
46400
ug/L
0.30J
ug/L
ND
ug/L
590000
ug/L
ND
ug/L
4.8
ug/L
14.6
ug/L
10.0 1 05/30/18 09:28 06/04/18 08:30 7429-90-5 0.50 1 05/30/18 09:28 06/04/18 08:30 7440-36-0 0.50 1 05/30/18 09:28 06/04/18 08:30 7440-38-2 0.30 1 05/30/18 09:28 06/04/18 08:30 7440-39-3 0.20 1 05/30/18 09:28 06/01/18 21:21 7440-41 -7 0.080 1 05/30/18 09:28 06/04/18 08:30 7440-43-9 2000 50 05/30/18 09:28 06/04/18 08:32 7440-70-2 0.50 1 05/30/18 09:28 06/04/18 08:30 7440-47-3 0.50 1 05/30/18 09:28 06/04/18 08:30 7440-48-4
1.0 1 05/30/18 09:28 06/04/18 08:30 7440-50-8 50.0 1 05/30/18 09:28 06/04/18 08:30 7439-89-6 0.10 1 05/30/18 09:28 06/04/18 08:30 7439-92-1 500 50 05/30/18 09:28 06/04/18 08:32 7439-95-4 0.50 1 05/30/18 09:28 06/04/18 08:30 7439-96-5 0.50 1 05/30/18 09:28 06/04/18 08:30 7440-02-0 2500 50 05/30/18 09:28 06/04/18 08:32 7440-09-7 0.50 1 05/30/18 09:28 06/01/18 21:21 7782-49-2 0.50 1 05/30/18 09:28 06/04/18 08:30 7440-22-4 2500 50 05/30/18 09:28 06/04/18 08:32 7440-23-5 0.10 1 05/30/18 09:28 06/04/18 08:30 7440-28-0
1.0 1 05/30/18 09:28 06/04/18 08:30 7440-62-2 5.0 1 05/30/18 09:28 06/04/18 08:30 7440-66-6
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 25 of 58
ED 002061 00090997-00035
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: HP-2 Pond
Lab ID: 10432836005
Parameters
Results
Units
Collected: 05/23/18 18:40 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
2320B Alkalinity Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03) 2540C Total Dissolved Solids Total Dissolved Solids 4500H+ pH, Electrometric pH at 25 Degrees C SM2510 Specific Conductance Specific Conductance 300.0 IC Anions Chloride Fluoride Sulfate 353.2 Nitrate + Nitrite Nitrogen, N02 plus N03 5310C TOC Total Organic Carbon SM4500P-E, Total Phosphorus Phosphorus
Analytical Method: SM 2320B
341
mg/L
ND
mg/L
5.0 1 5.0 1
05/30/18 13:46 05/30/18 13:46
Analytical Method: SM 2540C
2120
mg/L
100 1
05/30/18 20:26
Analytical Method: SM 4500-H+B
8.1 Std. Units
0.10 1
05/29/18 17:57
Analytical Method: SM 2510
2970 umhos/cm
1.0 1
05/29/18 16:50
Analytical Method: EPA 300.0
37.3
mg/L
0.22
mg/L
1220
mg/L
1.2 1 0.050 1
24.0 20
05/30/18 05:34 16887-00-6 05/30/18 05:34 16984-48-8 05/30/18 10:45 14808-79-8
Analytical Method: EPA 353.2
0.016J
mg/L
0.10 1
05/31/18 09:39
Analytical Method: SM 5310C
37.5
mg/L
1.0 1
05/29/18 15:54 7440-44-0
Analytical Method: SM 4500-P E Preparation Method: SM 4500-P B
0.24
mg/L
0.10 1 05/30/18 09:39 05/30/18 12:56 7723-14-0
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 26 of 58
ED 002061 00090997-00036
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: CFR-HB-1
Lab ID: 10432836006
Parameters
Results
Units
Collected: 05/23/18 19:50 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
6020A MET ICPMS
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
6020A MET ICPMS, Dissolved
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Analytical Method: EPA 6020A Preparation Method: EPA 3020
1260
ug/L
0.30J
ug/L
4.6
ug/L
85.6
ug/L
0.089J
ug/L
0.10
ug/L
18100
ug/L
1.2
ug/L
0.54
ug/L
15.4
ug/L
1170
ug/L
2.4
ug/L
5550
ug/L
71.4
ug/L
1.1
ug/L
1470
ug/L
ND
ug/L
ND
ug/L
3200
ug/L
ND
ug/L
2.0
ug/L
23.6
ug/L
10.0 1 05/30/18 08:53 06/01/18 10:46 7429-90-5 0.50 1 05/30/18 08:53 06/01/18 10:46 7440-36-0 0.50 1 05/30/18 08:53 06/01/18 10:46 7440-38-2 0.30 1 05/30/18 08:53 06/01/18 10:46 7440-39-3 0.20 1 05/30/18 08:53 06/01/18 10:46 7440-41 -7 0.080 1 05/30/18 08:53 06/01/18 10:46 7440-43-9 40.0 1 05/30/18 08:53 06/01/18 10:46 7440-70-2 0.50 1 05/30/18 08:53 06/01/18 10:46 7440-47-3 0.50 1 05/30/18 08:53 06/01/18 10:46 7440-48-4
1.0 1 05/30/18 08:53 06/01/18 10:46 7440-50-8 50.0 1 05/30/18 08:53 06/01/18 10:46 7439-89-6 0.10 1 05/30/18 08:53 06/01/18 10:46 7439-92-1 10.0 1 05/30/18 08:53 06/01/18 10:46 7439-95-4 0.50 1 05/30/18 08:53 06/01/18 10:46 7439-96-5 0.50 1 05/30/18 08:53 06/01/18 10:46 7440-02-0 50.0 1 05/30/18 08:53 06/01/18 10:46 7440-09-7 0.50 1 05/30/18 08:53 06/01/18 10:46 7782-49-2 0.50 1 05/30/18 08:53 06/01/18 10:46 7440-22-4 50.0 1 05/30/18 08:53 06/01/18 10:46 7440-23-5 0.10 1 05/30/18 08:53 06/01/18 10:46 7440-28-0
1.0 1 05/30/18 08:53 06/01/18 10:46 7440-62-2 5.0 1 05/30/18 08:53 06/01/18 10:46 7440-66-6
Analytical Method: EPA 6020A Preparation Method: EPA 3020
61.2
ug/L
0.23J
ug/L
3.1
ug/L
60.8
ug/L
ND
ug/L
ND
ug/L
15800
ug/L
0.34J
ug/L
0.37J
ug/L
4.0
ug/L
53.4
ug/L
0.13
ug/L
4380
ug/L
18.9
ug/L
0.29J
ug/L
1010
ug/L
ND
ug/L
ND
ug/L
2640
ug/L
ND
ug/L
0.59J
ug/L
4.1J
ug/L
10.0 1 05/30/18 09:28 06/04/18 08:48 7429-90-5 0.50 1 05/30/18 09:28 06/04/18 08:48 7440-36-0 0.50 1 05/30/18 09:28 06/04/18 08:48 7440-38-2 0.30 1 05/30/18 09:28 06/04/18 08:48 7440-39-3 0.20 1 05/30/18 09:28 06/01/18 22:09 7440-41 -7 0.080 1 05/30/18 09:28 06/04/18 08:48 7440-43-9 40.0 1 05/30/18 09:28 06/04/18 08:48 7440-70-2 0.50 1 05/30/18 09:28 06/04/18 08:48 7440-47-3 0.50 1 05/30/18 09:28 06/04/18 08:48 7440-48-4
1.0 1 05/30/18 09:28 06/04/18 08:48 7440-50-8 50.0 1 05/30/18 09:28 06/04/18 08:48 7439-89-6 0.10 1 05/30/18 09:28 06/04/18 08:48 7439-92-1 10.0 1 05/30/18 09:28 06/04/18 08:48 7439-95-4 0.50 1 05/30/18 09:28 06/04/18 08:48 7439-96-5 0.50 1 05/30/18 09:28 06/04/18 08:48 7440-02-0 50.0 1 05/30/18 09:28 06/04/18 08:48 7440-09-7 0.50 1 05/30/18 09:28 06/01/18 22:09 7782-49-2 0.50 1 05/30/18 09:28 06/04/18 08:48 7440-22-4 50.0 1 05/30/18 09:28 06/04/18 08:48 7440-23-5 0.10 1 05/30/18 09:28 06/04/18 08:48 7440-28-0
1.0 1 05/30/18 09:28 06/04/18 08:48 7440-62-2 5.0 1 05/30/18 09:28 06/04/18 08:48 7440-66-6
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 27 of 58
ED 002061 00090997-00037
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: CFR-HB-1
Lab ID: 10432836006
Collected: 05/23/18 19:50 Received: 05/25/18 10:00 Matrix: Water
Parameters
Results
Units
Report Limit DF
Prepared
Analyzed
C A S No.
Qua!
2320B Alkalinity Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03) 2540C Total Dissolved Solids Total Dissolved Solids 4500H+ pH, Electrometric pH at 25 Degrees C SM2510 Specific Conductance Specific Conductance 300.0 IC Anions Chloride Fluoride Sulfate 353.2 Nitrate + Nitrite Nitrogen, N02 plus N03 5310C TOC Total Organic Carbon SM4500P-E, Total Phosphorus Phosphorus
Analytical Method: SM 2320B
56.3
mg/L
ND
mg/L
5.0 1 5.0 1
05/30/18 13:50 05/30/18 13:50
Analytical Method: SM 2540C
99.0
mg/L
10.0 1
05/30/18 20:26
Analytical Method: SM 4500-H+B
7.8 Std. Units
0.10 1
05/29/18 17:59
Analytical Method: SM 2510
124 umhos/cm
1.0 1
05/29/18 16:51
Analytical Method: EPA 300.0
1.2 0.089
5.8
mg/L mg/L mg/L
1.2 1 0.050 1
1.2 1
05/30/18 05:49 16887-00-6 05/30/18 05:49 16984-48-8 05/30/18 05:49 14808-79-8
Analytical Method: EPA 353.2
0.024J
mg/L
0.10 1
05/31/18 09:43
Analytical Method: SM 5310C
5.0
mg/L
1.0 1
05/29/18 16:07 7440-44-0
Analytical Method: SM 4500-P E Preparation Method: SM 4500-P B
0.11
mg/L
0.10 1 05/30/18 09:39 05/30/18 12:57 7723-14-0
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 28 of 58
ED 002061 00090997-00038
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: SW-DUP
Lab ID: 10432836007
Parameters
Results
Units
Collected: 05/23/18 00:00 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
6020A MET ICPMS
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
6020A MET ICPMS, Dissolved
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Analytical Method: EPA 6020A Preparation Method: EPA 3020
87.3
ug/L
0.56
ug/L
22.2
ug/L
127
ug/L
ND
ug/L
0.24
ug/L
31400
ug/L
0.37J
ug/L
0.32J
ug/L
25.4
ug/L
163
ug/L
0.62
ug/L
9380
ug/L
287
ug/L
0.88
ug/L
7840
ug/L
ND
ug/L
0.20J
ug/L
57600
ug/L
ND
ug/L
1.3
ug/L
13.3
ug/L
10.0 1 05/30/18 08:53 06/01/18 11:05 7429-90-5 0.50 1 05/30/18 08:53 06/01/18 11:05 7440-36-0 0.50 1 05/30/18 08:53 06/01/18 11:05 7440-38-2 0.30 1 05/30/18 08:53 06/01/18 11:05 7440-39-3 0.20 1 05/30/18 08:53 06/01/18 11:05 7440-41 -7 0.080 1 05/30/18 08:53 06/01/18 11:05 7440-43-9 200 5 05/30/18 08:53 06/01/18 11:09 7440-70-2 0.50 1 05/30/18 08:53 06/01/18 11:05 7440-47-3 0.50 1 05/30/18 08:53 06/01/18 11:05 7440-48-4
1.0 1 05/30/18 08:53 06/01/18 11:05 7440-50-8 50.0 1 05/30/18 08:53 06/01/18 11:05 7439-89-6 0.10 1 05/30/18 08:53 06/01/18 11:05 7439-92-1 10.0 1 05/30/18 08:53 06/01/18 11:05 7439-95-4 0.50 1 05/30/18 08:53 06/01/18 11:05 7439-96-5 0.50 1 05/30/18 08:53 06/01/18 11:05 7440-02-0 50.0 1 05/30/18 08:53 06/01/18 11:05 7440-09-7 0.50 1 05/30/18 08:53 06/01/18 11:05 7782-49-2 0.50 1 05/30/18 08:53 06/01/18 11:05 7440-22-4 250 5 05/30/18 08:53 06/01/18 11:09 7440-23-5 0.10 1 05/30/18 08:53 06/01/18 11:05 7440-28-0
1.0 1 05/30/18 08:53 06/01/18 11:05 7440-62-2 5.0 1 05/30/18 08:53 06/01/18 11:05 7440-66-6
Analytical Method: EPA 6020A Preparation Method: EPA 3020
36.6
ug/L
0.74
ug/L
21.8
ug/L
120
ug/L
ND
ug/L
0.20
ug/L
40000
ug/L
0.34J
ug/L
0.34J
ug/L
19.2
ug/L
95.2
ug/L
0.38
ug/L
8400
ug/L
247
ug/L
0.85
ug/L
7100
ug/L
ND
ug/L
ND
ug/L
78200
ug/L
ND
ug/L
1.3
ug/L
9.5
ug/L
10.0 1 05/30/18 09:28 06/04/18 08:38 7429-90-5 0.50 1 05/30/18 09:28 06/04/18 08:38 7440-36-0 0.50 1 05/30/18 09:28 06/04/18 08:38 7440-38-2 0.30 1 05/30/18 09:28 06/04/18 08:38 7440-39-3 0.20 1 05/30/18 09:28 06/01/18 21:32 7440-41 -7 0.080 1 05/30/18 09:28 06/04/18 08:38 7440-43-9 200 5 05/30/18 09:28 06/04/18 08:40 7440-70-2 0.50 1 05/30/18 09:28 06/04/18 08:38 7440-47-3 0.50 1 05/30/18 09:28 06/04/18 08:38 7440-48-4
1.0 1 05/30/18 09:28 06/04/18 08:38 7440-50-8 50.0 1 05/30/18 09:28 06/04/18 08:38 7439-89-6 0.10 1 05/30/18 09:28 06/04/18 08:38 7439-92-1 10.0 1 05/30/18 09:28 06/04/18 08:38 7439-95-4 0.50 1 05/30/18 09:28 06/04/18 08:38 7439-96-5 0.50 1 05/30/18 09:28 06/04/18 08:38 7440-02-0 50.0 1 05/30/18 09:28 06/04/18 08:38 7440-09-7 0.50 1 05/30/18 09:28 06/01/18 21:32 7782-49-2 0.50 1 05/30/18 09:28 06/04/18 08:38 7440-22-4 250 5 05/30/18 09:28 06/04/18 08:40 7440-23-5 0.10 1 05/30/18 09:28 06/04/18 08:38 7440-28-0
1.0 1 05/30/18 09:28 06/04/18 08:38 7440-62-2 5.0 1 05/30/18 09:28 06/04/18 08:38 7440-66-6
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 29 of 58
ED 002061 00090997-00039
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: SW-DUP
Lab ID: 10432836007
Collected: 05/23/18 00:00 Received: 05/25/18 10:00 Matrix: Water
Parameters
Results
Units
Report Limit DF
Prepared
Analyzed
C A S No.
Qua!
2320B Alkalinity Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03) 2540C Total Dissolved Solids Total Dissolved Solids 4500H+ pH, Electrometric pH at 25 Degrees C SM2510 Specific Conductance Specific Conductance 300.0 IC Anions Chloride Fluoride Sulfate 353.2 Nitrate + Nitrite Nitrogen, N02 plus N03 5310C TOC Total Organic Carbon SM4500P-E, Total Phosphorus Phosphorus
Analytical Method: SM 2320B
165
mg/L
ND
mg/L
5.0 1 5.0 1
05/30/18 13:57 05/30/18 13:57
Analytical Method: SM 2540C
293
mg/L
10.0 1
05/30/18 20:26
Analytical Method: SM 4500-H+B
7.6 Std. Units
0.10 1
05/29/18 17:59
Analytical Method: SM 2510
423 umhos/cm
1.0 1
05/29/18 16:52
Analytical Method: EPA 300.0
9.8
mg/L
0.12
mg/L
44.5
mg/L
1.2 1 0.050 1
1.2 1
05/30/18 06:05 16887-00-6 05/30/18 06:05 16984-48-8 05/30/18 06:05 14808-79-8
Analytical Method: EPA 353.2
0.019J
mg/L
0.10 1
05/31/18 09:44
Analytical Method: SM 5310C
17.7
mg/L
1.0 1
05/29/18 16:20 7440-44-0
Analytical Method: SM 4500-P E Preparation Method: SM 4500-P B
0.30
mg/L
0.10 1 05/30/18 09:39 05/30/18 12:58 7723-14-0
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 30 of 58
ED 002061 00090997-00040
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project: Pace Project No.: Sample: ERB
350.0065.001 Ph15 Frenchtown 10432836
Lab ID: 10432836008
Parameters
Results
Units
Collected: 05/23/18 20:55 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
6020A MET ICPMS
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
6020A MET ICPMS, Dissolved
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Analytical Method: EPA 6020A Preparation Method: EPA 3020
48.6
ug/L
ND
ug/L
ND
ug/L
0.80
ug/L
ND
ug/L
ND
ug/L
176
ug/L
0.41J
ug/L
ND
ug/L
0.22J
ug/L
37.5J
ug/L
0.072J
ug/L
75.1
ug/L
1.7
ug/L
0.28J
ug/L
19.8J
ug/L
ND
ug/L
ND
ug/L
21.7J
ug/L
ND
ug/L
ND
ug/L
1.4J
ug/L
10.0 1 05/30/18 08:53 06/01/18 11:12 7429-90-5 0.50 1 05/30/18 08:53 06/01/18 11:12 7440-36-0 0.50 1 05/30/18 08:53 06/01/18 11:12 7440-38-2 0.30 1 05/30/18 08:53 06/01/18 11:12 7440-39-3 0.20 1 05/30/18 08:53 06/01/18 11:12 7440-41 -7 0.080 1 05/30/18 08:53 06/01/18 11:12 7440-43-9 40.0 1 05/30/18 08:53 06/01/18 11:12 7440-70-2 0.50 1 05/30/18 08:53 06/01/18 11:12 7440-47-3 0.50 1 05/30/18 08:53 06/01/18 11:12 7440-48-4
1.0 1 05/30/18 08:53 06/01/18 11:12 7440-50-8 50.0 1 05/30/18 08:53 06/01/18 11:12 7439-89-6 0.10 1 05/30/18 08:53 06/01/18 11:12 7439-92-1 10.0 1 05/30/18 08:53 06/01/18 11:12 7439-95-4 0.50 1 05/30/18 08:53 06/01/18 11:12 7439-96-5 0.50 1 05/30/18 08:53 06/01/18 11:12 7440-02-0 50.0 1 05/30/18 08:53 06/01/18 11:12 7440-09-7 0.50 1 05/30/18 08:53 06/01/18 11:12 7782-49-2 0.50 1 05/30/18 08:53 06/01/18 11:12 7440-22-4 50.0 1 05/30/18 08:53 06/01/18 11:12 7440-23-5 0.10 1 05/30/18 08:53 06/01/18 11:12 7440-28-0
1.0 1 05/30/18 08:53 06/01/18 11:12 7440-62-2 5.0 1 05/30/18 08:53 06/01/18 11:12 7440-66-6
Analytical Method: EPA 6020A Preparation Method: EPA 3020
2.9J
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
31.3J
ug/L
0.25J
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
5.5J
ug/L
0.26J
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
153
ug/L
ND
ug/L
ND
ug/L
1.4J
ug/L
10.0 1 05/30/18 09:28 06/04/18 08:50 7429-90-5 0.50 1 05/30/18 09:28 06/04/18 08:50 7440-36-0 0.50 1 05/30/18 09:28 06/04/18 08:50 7440-38-2 0.30 1 05/30/18 09:28 06/04/18 08:50 7440-39-3 0.20 1 05/30/18 09:28 06/01/18 22:06 7440-41 -7 0.080 1 05/30/18 09:28 06/04/18 08:50 7440-43-9 40.0 1 05/30/18 09:28 06/04/18 08:50 7440-70-2 0.50 1 05/30/18 09:28 06/04/18 08:50 7440-47-3 0.50 1 05/30/18 09:28 06/04/18 08:50 7440-48-4
1.0 1 05/30/18 09:28 06/04/18 08:50 7440-50-8 50.0 1 05/30/18 09:28 06/04/18 08:50 7439-89-6 0.10 1 05/30/18 09:28 06/04/18 08:50 7439-92-1 10.0 1 05/30/18 09:28 06/04/18 08:50 7439-95-4 0.50 1 05/30/18 09:28 06/04/18 08:50 7439-96-5 0.50 1 05/30/18 09:28 06/04/18 08:50 7440-02-0 50.0 1 05/30/18 09:28 06/04/18 08:50 7440-09-7 0.50 1 05/30/18 09:28 06/01/18 22:06 7782-49-2 0.50 1 05/30/18 09:28 06/04/18 08:50 7440-22-4 50.0 1 05/30/18 09:28 06/04/18 08:50 7440-23-5 0.10 1 05/30/18 09:28 06/04/18 08:50 7440-28-0
1.0 1 05/30/18 09:28 06/04/18 08:50 7440-62-2 5.0 1 05/30/18 09:28 06/04/18 08:50 7440-66-6
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 31 of 58
ED 002061 00090997-00041
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project: Pace Project No.: Sample: ERB
350.0065.001 Ph15 Frenchtown 10432836
Lab ID: 10432836008
Collected: 05/23/18 20:55 Received: 05/25/18 10:00 Matrix: Water
Parameters
Results
Units
Report Limit DF
Prepared
Analyzed
C A S No.
Qua!
2320B Alkalinity Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03) 2540C Total Dissolved Solids Total Dissolved Solids 4500H+ pH, Electrometric pH at 25 Degrees C SM2510 Specific Conductance Specific Conductance 300.0 IC Anions Chloride Fluoride Sulfate 353.2 Nitrate + Nitrite Nitrogen, N02 plus N03 5310C TOC Total Organic Carbon SM4500P-E, Total Phosphorus Phosphorus
Analytical Method: SM 2320B
ND
mg/L
ND
mg/L
5.0 1 5.0 1
05/30/18 14:02 05/30/18 14:02
Analytical Method: SM 2540C
ND
mg/L
100 1
05/30/18 20:26
Analytical Method: SM 4500-H+B
4.6 Std. Units
0.10 1
05/29/18 18:06
Analytical Method: SM 2510
1.7 umhos/cm
1.0 1
05/29/18 16:53
Analytical Method: EPA 300.0
0.37J ND
0.53J
mg/L mg/L mg/L
1.2 1 0.050 1
1.2 1
05/30/18 06:20 16887-00-6 05/30/18 06:20 16984-48-8 05/30/18 06:20 14808-79-8
Analytical Method: EPA 353.2
ND
mg/L
0.10 1
05/31/18 09:45
Analytical Method: SM 5310C
0.42J
mg/L
1.0 1
05/29/18 16:32 7440-44-0
Analytical Method: SM 4500-P E Preparation Method: SM 4500-P B
ND
mg/L
0.10 1 05/30/18 09:39 05/30/18 12:59 7723-14-0
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 32 of 58
ED 002061 00090997-00042
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: CFR-HP-13A
Lab ID: 10432831001
Parameters
Results
Units
Collected: 05/23/18 16:40 Received: 05/25/18 10:00 Matrix: Water
Report Limit DF
Prepared
Analyzed
C A S No.
6020A MET ICPMS
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper
Iron
Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium
Z in c
6020A MET ICPMS, Dissolved
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Analytical Method: EPA 6020A Preparation Method: EPA 3020
81.8
ug/L
0.57
ug/L
21.5
ug/L
123
ug/L
ND
ug/L
0.27
ug/L
30900
ug/L
0.38J
ug/L
0.31J
ug/L
24.5
ug/L
159
ug/L
0.62
ug/L
8800
ug/L
277
ug/L
0.86
ug/L
7490
ug/L
ND
ug/L
0.19J
ug/L
54900
ug/L
ND
ug/L
1.3
ug/L
13.9
ug/L
10.0 1 05/30/18 08:53 06/01/18 09:40 7429-90-5 0.50 1 05/30/18 08:53 06/01/18 09:40 7440-36-0 0.50 1 05/30/18 08:53 06/01/18 09:40 7440-38-2 0.30 1 05/30/18 08:53 06/01/18 09:40 7440-39-3 0.20 1 05/30/18 08:53 06/01/18 09:40 7440-41 -7 0.080 1 05/30/18 08:53 06/01/18 09:40 7440-43-9 200 5 05/30/18 08:53 06/01/18 09:44 7440-70-2 0.50 1 05/30/18 08:53 06/01/18 09:40 7440-47-3 0.50 1 05/30/18 08:53 06/01/18 09:40 7440-48-4
1.0 1 05/30/18 08:53 06/01/18 09:40 7440-50-8 50.0 1 05/30/18 08:53 06/01/18 09:40 7439-89-6 0.10 1 05/30/18 08:53 06/01/18 09:40 7439-92-1 10.0 1 05/30/18 08:53 06/01/18 09:40 7439-95-4 0.50 1 05/30/18 08:53 06/01/18 09:40 7439-96-5 0.50 1 05/30/18 08:53 06/01/18 09:40 7440-02-0 50.0 1 05/30/18 08:53 06/01/18 09:40 7440-09-7 0.50 1 05/30/18 08:53 06/01/18 09:40 7782-49-2 0.50 1 05/30/18 08:53 06/01/18 09:40 7440-22-4 250 5 05/30/18 08:53 06/01/18 09:44 7440-23-5 0.10 1 05/30/18 08:53 06/01/18 09:40 7440-28-0
1.0 1 05/30/18 08:53 06/01/18 09:40 7440-62-2 5.0 1 05/30/18 08:53 06/01/18 09:40 7440-66-6
Analytical Method: EPA 6020A Preparation Method: EPA 3020
32.1
ug/L
0.92
ug/L
21.5
ug/L
120
ug/L
ND
ug/L
0.19
ug/L
28600
ug/L
0.50J
ug/L
0.43J
ug/L
18.8
ug/L
91.6
ug/L
0.36
ug/L
8430
ug/L
247
ug/L
0.97
ug/L
7220
ug/L
ND
ug/L
ND
ug/L
55500
ug/L
ND
ug/L
1.4
ug/L
10
ug/L
10.0 1 05/30/18 09:28 06/01/18 20:42 7429-90-5 0.50 1 05/30/18 09:28 06/01/18 20:42 7440-36-0 0.50 1 05/30/18 09:28 06/01/18 20:42 7440-38-2 0.30 1 05/30/18 09:28 06/01/18 20:42 7440-39-3 0.20 1 05/30/18 09:28 06/01/18 20:42 7440-41 -7 0.080 1 05/30/18 09:28 06/01/18 20:42 7440-43-9 200 5 05/30/18 09:28 06/01/18 20:59 7440-70-2 0.50 1 05/30/18 09:28 06/01/18 20:42 7440-47-3 0.50 1 05/30/18 09:28 06/01/18 20:42 7440-48-4
1.0 1 05/30/18 09:28 06/01/18 20:42 7440-50-8 50.0 1 05/30/18 09:28 06/01/18 20:42 7439-89-6 0.10 1 05/30/18 09:28 06/01/18 20:42 7439-92-1 10.0 1 05/30/18 09:28 06/01/18 20:42 7439-95-4 0.50 1 05/30/18 09:28 06/01/18 20:42 7439-96-5 0.50 1 05/30/18 09:28 06/01/18 20:42 7440-02-0 50.0 1 05/30/18 09:28 06/01/18 20:42 7440-09-7 0.50 1 05/30/18 09:28 06/01/18 20:42 7782-49-2 0.50 1 05/30/18 09:28 06/01/18 20:42 7440-22-4 250 5 05/30/18 09:28 06/01/18 20:59 7440-23-5 0.10 1 05/30/18 09:28 06/01/18 20:42 7440-28-0
1.0 1 05/30/18 09:28 06/01/18 20:42 7440-62-2 5.0 1 05/30/18 09:28 06/01/18 20:42 7440-66-6
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 33 of 58
ED 002061 00090997-00043
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
ANALYTICAL RESULTS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Sample: CFR-HP-13A
Lab ID: 10432831001
Collected: 05/23/18 16:40 Received: 05/25/18 10:00 Matrix: Water
Parameters
Results
Units
Report Limit DF
Prepared
Analyzed
C A S No.
Qua!
2320B Alkalinity Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03) 2540C Total Dissolved Solids Total Dissolved Solids 4500H+ pH, Electrometric pH at 25 Degrees C SM2510 Specific Conductance Specific Conductance 300.0 IC Anions Chloride Fluoride Sulfate 353.2 Nitrate + Nitrite Nitrogen, N02 plus N03 5310C TOC Total Organic Carbon SM4500P-E, Total Phosphorus Phosphorus
Analytical Method: SM 2320B
172
mg/L
ND
mg/L
5.0 1 5.0 1
05/29/18 16:19 05/29/18 16:19
Analytical Method: SM 2540C
296
mg/L
10.0 1
05/30/18 20:26
Analytical Method: SM 4500-H+B
6.8 Std. Units
0.10 1
05/29/18 17:50
Analytical Method: SM 2510
419 umhos/cm
1.0 1
05/29/18 16:37
Analytical Method: EPA 300.0
10.0
mg/L
0.12
mg/L
45.7
mg/L
1.2 1 0.050 1
1.2 1
05/30/18 03:49 16887-00-6 05/30/18 03:49 16984-48-8 05/30/18 03:49 14808-79-8
Analytical Method: EPA 353.2
ND
mg/L
0.10 1
05/31/18 09:31
Analytical Method: SM 5310C
17.2
mg/L
1.0 1
05/29/18 13:28 7440-44-0
Analytical Method: SM 4500-P E Preparation Method: SM 4500-P B
0.27
mg/L
0.10 1 05/30/18 09:39 05/30/18 12:53 7723-14-0
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 34 of 58
ED 002061 00090997-00044
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541158
Analysis Method:
EPA6020A
QC Batch Method: EPA 3020
Analysis Description: 6020A Water UPD4
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
METHOD BLANK: 2943643
Matrix: Water
Associated Lab Samples: Parameter
10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
ug/L
3.4J
10.0 06/01/18 09:22
ug/L
ND
0.50 06/01/18 09:22
ug/L
ND
0.50 06/01/18 09:22
ug/L
ND
0.30 06/01/18 09:22
ug/L
ND
0.20 06/01/18 09:22
ug/L
ND
0.080 06/01/18 09:22
ug/L
ND
40.0 06/01/18 09:22
ug/L
ND
0.50 06/01/18 09:22
ug/L
ND
0.50 06/01/18 09:22
ug/L
ND
1.0 06/01/18 09:22
ug/L
ND
50.0 06/01/18 09:22
ug/L
ND
0.10 06/01/18 09:22
ug/L
5.6J
10.0 06/01/18 09:22
ug/L
ND
0.50 06/01/18 09:22
ug/L
ND
0.50 06/01/18 09:22
ug/L
ND
50.0 06/01/18 09:22
ug/L
ND
0.50 06/01/18 09:22
ug/L
ND
0.50 06/01/18 09:22
ug/L
ND
50.0 06/01/18 09:22
ug/L
ND
0.10 06/01/18 09:22
ug/L
ND
1.0 06/01/18 09:22
ug/L
ND
5.0 06/01/18 09:22
LABORATORY CONTROL SAMPLE: 2943644
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper iron Lead
Parameter
Units
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
Spike Cone.
2000 100 100 100 100 100
2000 100 100 100
2000 100
LCS Result
2170 105 104 104 116 107
2240 111 109 111
2260 106
LCS % Ree
109 105 104 104 116 107 112 111 109 111 113 106
% Ree Limits
80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 35 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00045
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
LABORATORY CONTROL SAMPLE: 2943644
Parameter
Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
Units
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
QUALITY CONTROL DATA
Spike Cone.
2000 100 100
2000 100 50
2000 100 100 100
LCS Result
2250 108 111
2190 114 49.9
2230 105 108 109
LCS % Ree
112 108 111 110 114 100 112 105 108 109
% Ree Limits
80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120
Qualifiers
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 2943645
MS
10432836001 Spike
Parameter
Units
Result Cone.
Aluminum Antimony Arsenic Barium Beryllium Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc
ug/L
1220 2000
ug/L
0.26J
100
ug/L
4.6
100
ug/L
85.2
100
ug/L
0.091 J
100
ug/L
0.088
100
ug/L
17400 2000
ug/L
1.1
100
ug/L
0.54
100
ug/L
15.0
100
ug/L
1180 2000
ug/L
2.5
100
ug/L
5240
2000
ug/L
72.9
100
ug/L
1.1
100
ug/L
1430 2000
ug/L
ND
100
ug/L
ND
50
ug/L
2900
2000
ug/L
ND
100
ug/L
2.0
100
ug/L
24.1
100
MSD Spike Cone.
2943646
MS Result
2000 100 100 100 100 100
2000 100 100 100
2000 100
2000 100 100
2000 100 50
2000 100 100 100
3530 104 109 192 113 108
19500 114 110 126
3470 108
7460 181 110
3600 111 50.5
5140 105 112 132
MSD Result
MS % Ree
MSD % Ree
Max
% Ree Limits RPD RPD Quai
3590
115
118 75-125 2 20
105
103
105 75-125 1 20
112
104
107 75-125 2 20
193
107
108 75-125 0 20
109
112
109 75-125 3 20
110
107
110 75-125 3 20
19500
104
108 75-125 0 20
114
113
113 75-125 1 20
112
109
111 75-125 2 20
128
111
113 75-125 2 20
3480
114
115 75-125 0 20
111
106
109 75-125 3 20
7460
111
111 75-125 0 20
184
108
111 75-125 2 20
112
109
111 75-125 2 20
3650
108
111 75-125 2 20
108
111
108 75-125 3 20
51.2
101
102 75-125 1 20
5080
112
109 75-125 1 20
108
105
108 75-125 3 20
113
110
111 75-125 1 20
134
108
110 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 36 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00046
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541156
Analysis Method:
EPA6020A
QC Batch Method: EPA 3020
Analysis Description: 6020A Water Dissolved UPD4
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
METHOD BLANK: 2943635
Matrix: Water
Associated Lab Samples: Parameter
10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
ug/L
ND
10.0 06/01/18 20:39
ug/L
ND
0.50 06/01/18 20:39
ug/L
ND
0.50 06/01/18 20:39
ug/L
ND
0.30 06/01/18 20:39
ug/L
ND
0.20 06/01/18 20:39
ug/L
ND
0.080 06/01/18 20:39
ug/L
ND
40.0 06/01/18 20:39
ug/L
ND
0.50 06/01/18 20:39
ug/L
ND
0.50 06/01/18 20:39
ug/L
ND
1.0 06/01/18 20:39
ug/L
ND
50.0 06/01/18 20:39
ug/L
ND
0.10 06/01/18 20:39
ug/L
ND
10.0 06/01/18 20:39
ug/L
0.20J
0.50 06/01/18 20:39
ug/L
ND
0.50 06/01/18 20:39
ug/L
ND
50.0 06/01/18 20:39
ug/L
ND
0.50 06/01/18 20:39
ug/L
ND
0.50 06/01/18 20:39
ug/L
ND
50.0 06/01/18 20:39
ug/L
ND
0.10 06/01/18 20:39
ug/L
ND
1.0 06/01/18 20:39
ug/L
ND
5.0 06/01/18 20:39
LABORATORY CONTROL SAMPLE: 2943636
Parameter
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved
Units
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
Spike Cone.
2000 100 100 100 100 100
2000 100 100 100
2000 100
LCS Result
2170 107 106 108 106 108
2310 112 107 108
2250 111
LCS % Ree
108 107 106 108 106 108 115 112 107 108 112 111
% Ree Limits
80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 37 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00047
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
LABORATORY CONTROL SAMPLE: 2943636
Parameter
Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
Units
ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L
QUALITY CONTROL DATA
Spike Cone.
2000 100 100
2000 100 50
2000 100 100 100
LCS Result
2240 110 109
2170 104 56.1
2240 109 108 110
LCS % Ree
112 110 109 109 104 112 112 109 108 110
% Ree Limits
80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120 80-120
Qualifiers
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 2943637
MS
10432836001 Spike
Parameter
Units
Result Cone.
Aluminum, Dissolved Antimony, Dissolved Arsenic, Dissolved Barium, Dissolved Beryllium, Dissolved Cadmium, Dissolved Calcium, Dissolved Chromium, Dissolved Cobalt, Dissolved Copper, Dissolved Iron, Dissolved Lead, Dissolved Magnesium, Dissolved Manganese, Dissolved Nickel, Dissolved Potassium, Dissolved Selenium, Dissolved Silver, Dissolved Sodium, Dissolved Thallium, Dissolved Vanadium, Dissolved Zinc, Dissolved
ug/L
69.4
2000
ug/L
0.24J
100
ug/L
2.8
100
ug/L
55.8
100
ug/L
ND
100
ug/L
0.029J
100
ug/L
14900 2000
ug/L
0.27J
100
ug/L
ND
100
ug/L
3.8
100
ug/L
54.5
2000
ug/L
0.13
100
ug/L
4120
2000
ug/L
17.7
100
ug/L
0.40J
100
ug/L
978 2000
ug/L
ND
100
ug/L
ND
50
ug/L
2530
2000
ug/L
ND
100
ug/L
0.53J
100
ug/L
4.4J
100
MSD Spike Cone.
2943638
MS Result
2000 100 100 100 100 100
2000 100 100 100
2000 100
2000 100 100
2000 100 50
2000 100 100 100
2230 107 109 168 111 106
18600 111 105 108
2280 109
6610 125 106
3230 107 54.9
4900 108 110 112
MSD Result
2220 108 110 168 111 108
18200 110 105 109
2290 108
6540 126 106
3190 109 55.6
4840 108 110 112
MS % Ree
108 107 107 112 111 106 184 110 105 105 111 108 124 108 106 113 107 110 119 108 109 108
MSD % Rec
Max
% Ree Limits RPD RPD Quai
108 75-125 108 75-125 107 75-125 112 75-125 111 75-125 108 75-125 167 75-125 110 75-125 105 75-125 105 75-125 112 75-125 108 75-125 121 75-125 108 75-125 106 75-125 111 75-125 109 75-125 111 75-125 116 75-125 108 75-125 109 75-125 108 75-125
0 20 1 20 1 20 0 20 0 20 2 20 2 20 M1 0 20 0 20 0 20 0 20 0 20 1 20 0 20 0 20 1 20 1 20 1 20 1 20 0 20 0 20 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 38 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00048
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541240
Analysis Method:
SM 2320B
QC Batch Method: SM 2320B
Analysis Description: 2320B Alkalinity
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003
METHOD BLANK: 2944027
Matrix: Water
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003
Parameter
Units
Blank Result
Reporting Limit
Analyzed
Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03)
mg/L mg/L
ND
5.0 05/29/18 14:07
ND
5.0 05/29/18 14:07
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 39 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00049
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541421
Analysis Method:
SM 2320B
QC Batch Method: SM 2320B
Analysis Description: 2320B Alkalinity
Associated Lab Samples: 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
METHOD BLANK: 2944820
Matrix: Water
Associated Lab Samples: 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
Parameter
Units
Blank Result
Reporting Limit
Analyzed
Alkalinity,Bicarbonate (CaC03) Alkalinity,Carbonate (CaC03)
mg/L mg/L
ND
5.0 05/30/18 12:27
ND
5.0 05/30/18 12:27
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 40 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00050
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541393
Analysis Method:
SM 2540C
QC Batch Method: SM 2540C
Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
METHOD BLANK: 2944685
Matrix: Water
Associated Lab Samples: Parameter
10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers
Total Dissolved Solids
mg/L
ND
10.0 05/30/18 20:26
LABORATORY CONTROL SAMPLE: 2944686
Parameter Total Dissolved Solids
Units mg/L
Spike Cone.
1000
LCS Result
954
LCS % Ree
95
% Ree Limits
80-120
Qualifiers
SAM PLE DUPLICATE: 2944687
Parameter Total Dissolved Solids
Units mg/L
10432831001 Result
296
Dup Result
288
RPD 3
Max RPD
10
Qualifiers
SAM PLE DUPLICATE: 2944688
Parameter Total Dissolved Solids
Units mg/L
10432836001 Result
100
Dup Result
97.9
RPD 2
Max RPD
10
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 41 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00051
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541214
Analysis Method:
SM 4500-H+B
QC Batch Method: SM 4500-H+B
Analysis Description: 4500H+B pH
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
LABORATORY CONTROL SAMPLE: 2943914
Parameter pH at 25 Degrees C
Units Std. Units
Spike Cone.
5
LCS Result
5.0
LCS % Ree
100
% Ree Limits
Qualifiers
98-102 H6
SAM PLE DUPLICATE: 2943915
Parameter pH at 25 Degrees C
10432836004
Dup
Units
Result
Result
RPD
Std. Units
8.2
8.2
Max
RPD
Qualifiers
3 H6
SAM PLE DUPLICATE: 2943945
Parameter pH at 25 Degrees C
Units Std. Units
10431815003 Result
7.5
Dup Result
7.5
RPD 0
Max
RPD
Qualifiers
3 H6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 42 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00052
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541212
Analysis Method:
SM 2510
QC Batch Method: SM 2510
Analysis Description: SM2510 Specific Conductance
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
METHOD BLANK: 2943904
Matrix: Water
Associated Lab Samples: Parameter
10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers
Specific Conductance
umhos/cm
ND
1.0 05/29/18 16:35
LABORATORY CONTROL SAMPLE: 2943905
Parameter Specific Conductance
Units umhos/cm
Spike Cone.
1000
LCS Result
976
LCS % Ree
98
% Ree Limits
90-110
Qualifiers
SAM PLE DUPLICATE: 2943906
Parameter Specific Conductance
10432831001
Dup
Units
Result
Result
RPD
umhos/cm
419
425
Max RPD
20
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 43 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00053
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541303
Analysis Method:
EPA 300.0
QC Batch Method: EPA 300.0
Analysis Description: 300.0 IC Anions
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
METHOD BLANK: 2944283
Matrix: Water
Associated Lab Samples: Parameter
10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers
Chloride Fluoride Sulfate
mg/L mg/L mg/L
ND
1.2 05/30/18 01:52
ND
0.050 05/30/18 01:52
ND
1.2 05/30/18 01:52
LABORATORY CONTROL SAMPLE: 2944284
Chloride Fluoride Sulfate
Parameter
Units
mg/L mg/L mg/L
Spike Cone.
12.5 1
12.5
LCS Result
12.4 1.0
12.8
LCS % Ree
99 102 102
% Rec Limits
90-110 90-110 90-110
Qualifiers
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 2944285
MS
10431928006 Spike
Parameter
Units
Result Cone.
Chloride Fluoride Sulfate
mg/L mg/L mg/L
5.4
12.5
ND
1
10
12.5
MSD Spike Cone.
2944286
MS Result
12.5
17.3
1
0.71
12.5
22.5
MSD Result
17.3 0.72 22.6
MS % Rec
95 71 100
MSD % Rec
Max
% Rec Limits RPD RPD Qual
95 90-110 72 90-110 101 90-110
0 20 1 20 M1 1 20
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 2944309
MS
10432489006 Spike
Parameter
Units
Result Cone.
Chloride Fluoride Sulfate
mg/L mg/L mg/L
14.1
12.5
0.66
1
43.3
12.5
MSD Spike Cone.
2944310
MS Result
12.5
24.9
1
1.6
12.5
51.5
MSD Result
25.1 1.6
51.9
MS % Rec
87 96 66
MSD % Rec
Max
% Rec Limits RPD RPD Qual
88 90-110 97 90-110 69 90-110
1 20 M1 1 20 1 20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 44 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00054
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541432
Analysis Method:
EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, preserved
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
METHOD BLANK: 2944878
Matrix: Water
Associated Lab Samples: Parameter
10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers
Nitrogen, N02 plus N03
mg/L
ND
0.10 05/31/18 10:03 FS
LABORATORY CONTROL SAMPLE: 2944879
Parameter Nitrogen, N02 plus N03
Units mg/L
Spike Cone.
1
LCS Result
0.98
LCS % Ree
98
% Ree Limits
Qualifiers
90-110 FS
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 2944880
MS
10432831001 Spike
Parameter
Units
Result Cone.
MSD Spike Cone.
2944881
MS Result
MSD Result
MS % Ree
MSD % Rec
Max
% Ree Limits RPD RPD Qual
Nitrogen, N02 plus N03
mg/L
ND
1
1
0.96
1.0
96
103 90-110 7 20
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 2944882
MS
10432698005 Spike
Parameter
Units
Result Cone.
MSD Spike Cone.
2944883
MS Result
MSD Result
MS % Ree
MSD % Rec
Max
% Ree Limits RPD RPD Qual
Nitrogen, N02 plus N03
mg/L
8.4
10
10
18.0
18.3
96
98 90-110 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 45 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00055
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
143886
Analysis Method:
SM 5310C
QC Batch Method: SM 5310C
Analysis Description: 5310C TOC
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
METHOD BLANK: 568093
Matrix: Water
Associated Lab Samples: Parameter
10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers
Total Organic Carbon
mg/L
ND
1.0 05/29/18 13:01
LABORATORY CONTROL SAMPLE: 568094
Parameter Total Organic Carbon
Units mg/L
Spike Cone.
25
LCS Result
25.8
LCS % Rec
103
% Rec Limits
90-110
Qualifiers
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 568095
MS
10432831001 Spike
Parameter
Units
Result Cone.
Total Organic Carbon
mg/L
17.2
25
MSD Spike Cone.
568096
MS Result
25
43.7
MSD Result
43.1
MS % Rec
MSD % Rec
Max
% Rec Limits RPD RPD Qual
106
104 80-120 1 20
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 568097
MS
10432836002 Spike
Parameter
Units
Result Cone.
Total Organic Carbon
mg/L
5.7
25
MSD Spike Cone.
568098
MS Result
25
32.2
MSD Result
31.8
MS % Rec
MSD % Rec
Max
% Rec Limits RPD RPD Qual
106
104 80-120 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 46 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00056
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
QC Batch:
541342
Analysis Method:
SM 4500-P E
QC Batch Method: SM 4500-P B
Analysis Description: SM4500P-E, Total Phosphorus
Associated Lab Samples: 10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
METHOD BLANK: 2944464
Matrix: Water
Associated Lab Samples: Parameter
10432831001, 10432836001,10432836002, 10432836003, 10432836004, 10432836005, 10432836006, 10432836007, 10432836008
Blank
Reporting
Units
Result
Limit
Analyzed
Qualifiers
Phosphorus
mg/L
ND
0.10 05/30/18 12:44
LABORATORY CONTROL SAMPLE: 2944465
Parameter Phosphorus
Units mg/L
Spike Cone.
1
LCS Result
1.0
LCS % Rec
103
% Rec Limits
90-110
Qualifiers
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 2944466
MS
10432366001 Spike
Parameter
Units
Result Cone.
Phosphorus
mg/L
180
1
MSD Spike Cone.
2944467
MS Result
1
173
MSD Result
175
MS % Rec
-705
MSD % Rec
Max
% Rec Limits RPD RPD Qual
-520 80-120 1 30 M6
MATRIX SP IK E & MATRIX SP IK E DUPLICATE: 2944468
MS
10432717001 Spike
Parameter
Units
Result Cone.
MSD Spike Cone.
2944469
MS Result
MSD Result
MS % Rec
MSD % Rec
Max
% Rec Limits RPD RPD Qual
Phosphorus
mg/L
ND
1
1
0.99
1.0
96
101 80-120 4 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 47 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00057
/*2aoeAnalytical mm.pacabs.cem
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALIFIERS
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute.
LABORATORIES
PASI-M PASI-V
Pace Analytical Services - Minneapolis Pace Analytical Services - Virginia
ANALYTE QUALIFIERS
B
Analyte was detected in the associated method blank.
FS
The sample was filtered in the laboratory prior to analysis.
H6
Analysis initiated outside of the 15 minute EPA required holding time.
M1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 48 of 58
ED 002061 00090997-00058
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA CRO SS REFEREN CE TABLE
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Lab ID
10432831001 10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008
10432831001 10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008
10432831001 10432836001 10432836002 10432836003
10432836004 10432836005 10432836006 10432836007 10432836008
10432831001 10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008
10432831001 10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008
10432831001
Sample ID
CFR-HP-13A CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
CFR-HP-13A CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
CFR-HP-13A CFR-1 CFR-2 SMW-11
HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
CFR-HP-13A CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
CFR-HP-13A CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
CFR-HP-13A
QC Batch Method
EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020
EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020 EPA 3020
SM 2320 B SM 2320 B SM 2320 B SM 2320 B
SM 2320 B SM 2320 B SM 2320 B SM 2320 B SM 2320 B
SM 2540C SM 2540C SM 2540C SM 2540C SM 2540C SM 2540C SM 2540C SM 2540C SM 2540C
SM 4500-H+B SM 4500-H+B SM 4500-H+B SM 4500-H+B SM 4500-H+B SM 4500-H+B SM 4500-H+B SM 4500-H+B SM 4500-H+B
SM 2510
QC Batch
541158 541158 541158 541158 541158 541158 541158 541158 541158
541156 541156 541156 541156 541156 541156 541156 541156 541156
541240 541240 541240 541240
541421 541421 541421 541421 541421
541393 541393 541393 541393 541393 541393 541393 541393 541393
541214 541214 541214 541214 541214 541214 541214 541214 541214
541212
Analytical Method
EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A
EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Batch 541946 541946 541946 541946 541946 541946 541946 541946 541946 542050 542050 542050 542050 542050 542050 542050 542050 542050
Page 49 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00059
/*2faoeAnalytical www.peceisb&coin
Pace Analytical Services, LLC 150 N Ninth Street Billings, MT 59101 (406)254-7226
QUALITY CONTROL DATA CRO SS REFEREN CE TABLE
Project:
350.0065.001 Ph15 Frenchtown
Pace Project No.: 10432836
Lab ID
10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008
10432831001 10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008
10432831001 10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008
10432831001 10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008
10432831001 10432836001 10432836002 10432836003 10432836004 10432836005 10432836006 10432836007 10432836008
Sample ID
CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
CFR-HP-13A CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
CFR-HP-13A CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
CFR-HP-13A CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
CFR-HP-13A CFR-1 CFR-2 SMW-11 HP-13A Pond HP-2 Pond CFR-HB-1 SW-DUP ERB
QC Batch Method
SM 2510 SM 2510 SM 2510 SM 2510 SM 2510 SM 2510 SM 2510 SM 2510
EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0
EPA 353.2 EPA 353.2 EPA 353.2 EPA 353.2 EPA 353.2 EPA 353.2 EPA 353.2 EPA 353.2 EPA 353.2
SM 531 OC SM 531 OC SM 531 OC SM 531 OC SM 531 OC SM 531 OC SM 531 OC SM 531 OC SM 531 OC
SM 4500-P B SM 4500-P B SM 4500-P B SM 4500-P B SM 4500-P B SM 4500-P B SM 4500-P B SM 4500-P B SM 4500-P B
QC Batch
541212 541212 541212 541212 541212 541212 541212 541212
541303 541303 541303 541303 541303 541303 541303 541303 541303
541432 541432 541432 541432 541432 541432 541432 541432 541432
143886 143886 143886 143886 143886 143886 143886 143886 143886
541342 541342 541342 541342 541342 541342 541342 541342 541342
Analytical Method
SM 4500-P E SM 4500-P E SM 4500-P E SM 4500-P E SM 4500-P E SM 4500-P E SM 4500-P E SM 4500-P E SM 4500-P E
Analytical Batch
541437 541437 541437 541437 541437 541437 541437 541437 541437
Date: 06/04/2018 05:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 50 of 58
ED 002061 00090997-00060
Sierra Club v. EPA 18cv3472 NDCA
c e A n a /y tic a f
m w .p a c e fa b s .c o fi
CHAIN-OF-CUSTODY / Analytical Request Doc
The Gbain-of-Custodfy is a LEGAL DOCUMENT. All relevant fields must be completed a
IdOtt: 10432836
10432836
Section A Required Client information:
Company: NewFieldS
Section B Required Project Information'.
Report Ta: dtooke@newfields.com
Section C invoice information:
Attention: Donna McCammon
10432836
Address: 700 SW Higgins, Suite 15
Missoula, MT 59803
Email To: David Tooke Phone: 406-549-8270
Requested Due Date/TAT:
Standard (except where noted)
CopyTo: ajohnson@newfields.com; ksitler@newfrelds.com Company Name: N ew FieldS
Address: Same
Purchase Order No.:
Project Name: Frenchtown Mill
Pace Quote Reference:
Project Number 350.0065.001 Phase 15
Pace Profile#: 3 2 6 3 4
REGULATORY a g e n c y
r r N P D E S
G R O U N D W A T E R I" D R IN K IN G W A T E R
r U ST
r RCRA
r OTHER
_______
S ite L o c a tio n
MT
STATE:
R e q u e ste d A n a ly s is Filtere d (Y/N)
|
Section D Required Client Information
SAMPLE ID
(A-Z, 0-9 /,-) Sample IDs MUST BE UNIQUE
Valid M atrix Codes
MATRIX
CODE
DRrNKIMGWATER DW
WATER
WT
WASTE WATER WW
PRODUCT
P
SOIL/SOLID
$L
Oll
OL
WAIIRPE
TMARp
OTHER
OT
tissu e
ts
8
t
1
CFR-1
2
CFR-2
3
SMW-11
4
HP-13A Pond
5
CFR-HP-13A (48-hr TAT)
6
HP-2 Pond
SAMPLE TYPE (G=GRAB C=COMP)
I -B
!
uj
Q O U X HX.
WT G WT G WT G WT G WT G WT G
COLLECTED
COMPOSITE START
COMPOSITE END/GRAB
DATE
TIME
DATE 05/23/18 05/23/18 05/23/18 05/23/18 05/23/18 05/23/18
TIME 19:10 17:40 15:40 16:15 16:40 18:40
SAMPLE TEMP AT COLLECTION
9 OF CONTAINERS
z
Preservatives
P
1
I
|
Total Metals (6010/6020)* Diss. Metals (6010/6020)*
I Unpreserved
<3
Z z TX 4 XXX 5 XXX 4 XXX 5 XXX 4 XXX 4 XXX
I HCl
m
4 X o
0
1z
1Methanol
1O ther
<0
4
J
Z
*5
+
>>
Z
04
CO
o
UD CO
P
XXXXXXXXX
XXXXXXXXX
XXXXX XXXX
XXXXXXXXX
XXXXXXXXX
XXXXXXXXX
SM4500 PE Total Phos 2S40C TDS 300.0 IC Anions Alk, pH SM2510 Spec. Cond
I Residua! C hlorine (Y/N) |
Wk
Pace Project No./ Lab I.D. erti \ O CX 003 <5<y-t fro s~
7
CFR-HB-1
WT G
05/23/18 19:50
4 XXX
XXXXXXXXX
8
SW -D U P
WT G
05/23/18 __
4 XXX
XXXXXXXXX
s
ERB
Wt G
05/23/18 20:55
6 XXX
XXXXXXXXX
e (p G~?
10
11
12
ADDITIONAL COMMENTS 6010:Ca, Mg, Na, K *6020:AI, V, Cr, Fe, Mn, Co, Zn, As, Se, Ag, Cd, Sb. Ba, Tl, Pb
Please See attached project table for reference.
RELINQUISHED B Y /AFFILIATION
Heather Grotbo/NewFieids
DATE mms
TIME
fe o -
A CCEPTED BY / AFFILIATION
DATE y j /fc
TIME
t O O O 3 .0
3*
SAMPLE CONDITIONS
'Y
T
.
Tier 10
ED_002061_00090997-00061
SA M PLER NAME AND SIGNATURE
cn
PRINT Name of SAMPLER: H E A T H E R G R O T B O
o
Important Note: By signing this form you are accepting Pace's N ET 30 day payment terms and
F-ALL-Q-020rev.08,12-0ct-2007
C ourier:
Commercial
Document Name:
Docum ent Revised: 02May2018
x ' ry
/ PaceAnalytical
r Sam ple C o n d itio n Upon R eceipt Form Docum ent No.:
Page 1 o f 2 Issuing A u th o rity :
Client Name:
F-MN-L-213-rev.23 Project #:
Pace M innesota Q uality O ffice
WOtt: 10432836
A /e tu
J T j f e d E*
I IPace
Q RS
I ISpeeDee
Q U SPS
Q Other:
c lie n t
PM: KSK1
Due Date: 06/04/18
CLIENT: 11 N eufleIds
Tracking Number: i H l
Q> % Y
Q % T
0,7 s S Custody Seal on Cooler/Box Present? JlJY e s
W
r~iN o
Seals intact? PtYes N o
Optional: Proj. Due Date: Proj, Name;
Packing Material: J P [B ubble W rap Q B ubble Bags I IN one d th e r :_
Temp Blank? 0 Y e s
no
Thermometer Q G 87A9170600254
Used:
^EJG87A9155100842
Typ o f Ice: E Ti/Vet I BIue
l~ lN o n e
Dry D M e lte d
Cooler Temp Read rc ): 3 1 ^i[ 2>i0 Cooler Temp Corrected (C): 3 Cl^ 3,, * ^
B io lo g ica l Tissue Frozen? I lYes l~lNo
T'eemm p sho uld be above fre e z in g t o 6C
Correction Factor:
j-fi/e .
Daa'te and Initials of Person Examining Contents: l Y ) f*}
USDA Regulated Soil ( 0 * N /A , w ate r sample)
[ T I n /A S/
Did samples originate in a quarantine zone w ith in th e U nited States: AL, AR, CA, FL, GA, ID, LA, MS,
Did samples originate fro m a foreign source (internationally,
NC, NM , NY, OK, OR, SC, TN, TX o r VA (check maps)?
Yes
I iNo
including Hawaii and Puerto Rico)?
OYes
No
If Yes to e ith e r question, fill out a Regulated S oil Checklist (F-MN-Q-338) and in clu d e with SCUR/COC p a p e rw o rk .
COMMENTS:
Chain o f Custody Present?
V e s No
1.
Chain o f Custody Filled Out?
No
2.
Chain of Custody Relinquished?
, 0 V es N o
3.
Sampler Name a n d /o r Signature on COC?
0 V e s No n /a 4,
Samples Arrived w ith in Hold Time?
Short Hold Time Analysis (<72 hr)? Rush Turn Around Time Requested?
Q V es No
5.
Yes 0 fjo
6.
Y e s ZTnq
7.
Sufficient Volume? Correct Containers Used?
-Pace Containers Used?
0 V es /P^Yes Yes
No
oo
8.
9. P c t/A td
W o$P
S u \^ v < i c c e r t- k i\y iir j
tc /tr< 5 tz 'T c W v r .
Containers Intact?
flY e s No
10.
Filtered Volume Received fo r Dissolved Tests?
No n /a 11. N ote if sed im ent is visible in th e dissolved container
Is su fficie n t info rm atio n available to reconcile the samples to ^ 0 Y e s No
the COC?
M atrix: < A y T
All containers needing acid/base preservation have been checked? All containers needing preservation are fo u n d to be in
J3Ves No
com pliance w ith EPA recom m endation? {H N 0 3, HjS0 4, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide) Exceptions: VOA, C ollform , TOC/DOC Oil and Grease,
/ A 4* * ' {g fy )
DRO/8015 (water) and Dioxin/PFAS
Y e s No
n/a
n/a J 3 n/ a
Headspace In VOA Vials ( >6mm)?
Y e s No 0 n/a
Trip Blank Present?
Yes No 0 N /A
Trip Blank Custody Seals Present?
Yes No - 0 N / A
Pace Trip Blank Lot ft ( if purchased):
12.
13.
ja fiN O s
^
7
S a m p l e _ & 4
ZfHzSOz
. a , ,, u
1
' t
DNaOH
Positive fo r Res Chlorine? Y N
Initial when com pleted: 14, 15,
yyn / \ '
j J Lot tt o f added O
preservative: ^ .
@& J
CLIENT NOTIFICATION/RESOLUTION
Field Data Required? 1 lYes 1 INo
Person Contacted:
Date/Tim e:
C om m ents/Resolution:
Project Manager Review: ___________ ^ ...
v *, _________________
Date: 5/25/18_______________
Note: Whenever there Is a discrepancy affecting North Carolinr|jympliani.ie samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers).
Page 52 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00062
^ / / .,,-FaceAnalytical
Document Name: Sample Condition Upon Receipt Form
Document No.: F-MN-L-213-rev.23
Document Revised: 02May20lB
1
Page 2 of 2
Issuing Authority:
j
Pace Minnesota Quality Office
|
SCUR Exceptions:______________________________Workorder #:
Issue
Sample ID
Container Type/#
Sample ID
5 / n u j - 11
H P " Z. P a c p /?' H & ' l
pH Adjustment Log for Preserved Samples
Type of Preservative
pH Upon Receipt
Date Preservation
Adjusted
Time Preservation
Adjusted
Amount of Additional Preservative
Added
>6
5 / x s j \ % l S cj
s
11
11
I >0 m l-
Lot it of Preservative
Added
11
n
V
II
h
1.6 m l
* 1
pH After Adjustment
1 -0
l 0
\.o
Initials
/n%
m l)
mb
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 53 of 58
ED 002061 00090997-00063
Sierra Club v. EPA 18cv3472 NDCA
^ a c e A n a ly tic a l
0 10432831 W # : CHAIN-OF-CUSTODY /Analytical Request Boa
The Chain-of-Custody Is a LE G A L DOCUMENT. All relevant fields must be completed ac
10432831
Section A Required Client Information:
Company: NewFields
Section B Required Project Information:
ReportTo: dtooke@newfields.com
Section C invoice Information:
Attention: Donna McCammon
10432831
ACdress: 700 SW Higgins, Suite 15
Missoula, MT 59803
Email Tor David Tooke
Phone: 406-549-8270
Fax:
Requested Due Date/TAT:
Standard (except where noted)
CopyTo: ajotinson@newfields.com; ksitler@newfields.com Company Name: NewFields
Address: Same
Purchase Order No.:
Project Name: Frenchtown Mill Project Number 350.0065.001 Phase 15
Pace Ouote Reference: Pace Project Manager
Pace Profite #:
Kang K h an g
32634
REGULATORY AGENCY r NPDES F GROUND WATER
r UST
r RCRA
Site Location
i'
STATE:
Requested A n alysis Filtered (Y/N)
DRINKING W ATER OTHER
[
Section D Required Client information
S A M P L E ID
(A -Z, 0-9 /
Sample IDs MUST BE UNIQUE
Valid Matrix Codes
M A TR IX
CODE
DRINKING WATER CM
WATER
WT
WASTE WATER WW
PRODUCT
P
SOIL/SOUD
SL
OIL
QL
AWJR,P E
wA Rp
OTHER
OT
t is s u e
ts
UJ L
1
CFR-1
2
CFR-2
3
SMW-11
4
H P -1 3 A P on d
5
CFR-H P-13A (48-hr TAT)
6
HP-2 Pond
7
CFR-HB-1
3
SW -D U P
9
ERB
M ATRIX CO D E (see valid codes toleft)
a. 5
8
0 CD
6
t
1 < w
WT G WT G
WT G
WT G WT G WT G WT G WT G wt G
COLLECTED
COMPOSITE START
Z
Q
COMPOSITE END/GRAB
8
d O 0
S Cl
DATE
TIME
DATE
5
1
TIME S
05/23/18
19:10
05/23/18 05/23/18 05/23/18
05/23/18
05/23/13 05/23/13 05/23/18
17:40 15:40 16:15 16:40 18:40 19:50
_,,
05/23/18
2 :5 5
# O F CONTAINERS
U n p r e s e r v e d 1
Preservatives
1
1
1NaOH
OH 1
d
Pf O
O
2
C
XX
;z
4 XXX 5. X X X 4 XXX 5 XX X 4 XXX 4 XXX 4 XX X 4 XXX 6 XXX
1Methanol
|
Other
3
J CL
Oo CO $ S lco
Pace Project NoJ Lab I.D. QC>{
1D
11
12 AOOiTiONAL COMMENTS
' 60l0:Ca, Mg, Na, K
'602:A!, V, Cr, Fe, Mn, Co, Zn, As, Se, Ag?Cd, Sb, Ba, T, Pb
RELINQUISHED BY/AFFILIATION Heather G notbo/NewFleIds
DATE
5/24/18 - & .
A CCEPTED B Y / AFFILIATION
ce.
DATE
s 3 S it R o O S A
3 -0
SAMPLE CONDITIONS
Z. r
Ls
U-
Please See attached project table for reference.
Tier 10
ED 002061 00090997-00064
"00)
cn
PRINT Name of SAMPLER:: H|-E|FAATTHHEERR GROTBO_______
SIGNATURE of SAMPLER:
_
DATE Signed
J L z J > (MM/DD/YY):
cono
Mmportaril Note: BysigningthisformyouareacceptingPace'sNET30daypaymenttermsandagreeingtolatechargesof1.5%permonth foraIrrylnvoicesnotpaidwll^in30day.
5/24/18
il
fi
sp
F -AL L-Q-020rev .08 , 12-0ct-2007
-FaceAnalytics!
Document Name: Sample Condition Upon Receipt Form
Docum ent No.: F-MN-l.-213-rev.23
D o cu m e n t Revised: 02Mfay2018 Page 1 o f 2
Issuing A utho rity: Pace M inn esota Q uality O ffice
Project #: UOtt: 1 0 4 3 2 8 3 1
C ourier:
J T f e d E-
ups
I ICom mereiai
I Pace
SpeeDee
Tracking Number: 7 */ 7 S
6 7 i>
Custody Seal on C oole r/B oit Present?
^QVes
O usps Q Other:
clie n t
PM: KSK1
D u e Date: 05/30/18
CLIENT: 11 N e u f ieIds
Seals intact? 0 Y e s D no j 0pilo"al: Proj-DueDate: ^ Name:
Packing Material: ^ 'B u b b le W ra p B u b b le Bags f l N o n e o t h e r :
Temp Blank? PYes
QNo
Thermometer Q G87A9170600254
Used:
^ T g87A9 155100842
3 Cooler Temp Read (C):
< ^
T e m p should be above fre e z in g to 6C
Type of ice: ^ H 'Wet Qlue Qlslone Qory OMelted
Cooler Temp Corrected (C): 3 * Cf ^ 3 * &
Biological Tissue Frozen? Yes No
Correction Factor: ~ f r ;
Date and Initiais o f Person Examining Contents: V f ]
0N/A
USDA Regulated Soil ( 0 T J /A , w ate r sample)
Did samples originate in a quarantine zone w ith in the U nited States: AL, AR, CA, FL, GA, ID, LA. MS,
Did samples originate from a foreign source (internationally,
NC, N M , NY, OK, OR, SC, TN, TX or VA (check maps)?
Yes
I |No
including Hawaii and Puerto Rico)?
DYes
D no
If Yes to e ith e r question, fill out a Regulated Soil Checklist (F -M N -0 -3 3 8 ) and include w ith SCUR/COC paperwork.
COMMENTS:
Chain of Custody Present? Chain o f Custody Filled Out? Chain of Custody Relinquished? Sam pler Name and/or Signature on COC?
PfYes
o
1.
No
2.
>0 Ves No
3.
0 Yes
o
n / a 4.
Sam p le s Arrived within Hold Time?
Short Hold Tim e Analysis (<72 hr)? Rush Turn Around Tim e Requested?
Su fficien t Volume? Correct Containers Used?
-Pace Containers Used?
OVes Yes
- Yes
0 Yes
No
Zfao
No No No No
5 .'
6.
7.
8.
g u w -f r e - S . Q,
s o b o Vs
- ^ -
Containers Intact?
Yes No
10.
Filtered Volume Received for Dissolved Tests?
Is sufficient information available to reconcile the samples to
the COC?
M atrix: lA S T
All containers needing acid/base preservation have been
checked?
All containers needing preservation are found to be in
com pliance with EPA recommendation?
(H N 0 3, HjSCh, <2pH, NaOH >9 Sulfide, NaOH>12 Cyanide)
Exceptions: VOA, Coliform, TOC/DOC Oil and Grease,
DRO/SQ15 (water) and Dioxin/PFAS
6 Headspace in VOA Vials ( > mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
Pace T rip Blank Lot ft (If purchased):
jE JY e s
^ 0 Yes
^Pf/es
^Zfves Yes Yes Yes HVes
No No
n /a
11. Note if sedim ent is visible in the dissolved container
12,
No
n /a
13.
0HNO3
S a m p le # /; 7^
o
n/a
No No No No
0 /A ,0N /A JHfo/A ..PTry/f,
Initial when completed: 14. 15.
><
Lot ff of added preservative:
CLIENT N O TIFICA TiO N /R ESG LU llO hi Person Contacted:
D ate/Tim e:
Field D ata R equ ired ? [~~lYes Q k f o
Com merits/Resolution:
\ ?
Project M anager Review:
N o te : W h e n e v e r t h e r e is a d is c r e p a n c y a f f e c t in g N o r t h C a r o t i n a ^ | m p l i a n c ^ j n p l e s , a c o p y o f t h is f o r m i h o ld , in c o rre c t p re se rva tive , o u t o f te m p , in c o rre c t c o n ta in e rs ).
! b e s e n t ta th e N o rth C a ro lin a DEHNR C e rtific a tio n O ffic e { i.e o u t o f
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 55 of 58
ED 002061_00090997-00065
Table 11
Groundwater Sample Methods, Containers and Preservatives 2018 and 2019 Groundwater Monitoring Plan
Frenchtown Mill Site, Missoula County, Montana
Parameter Group
Analytical Method & Parameters
Number of Containers
Container Type
Preservative / A dditive
Hold Time
Field Parameters
Flow Cell / In Field; pH, conductivity, DO, ORP, tem perature, turbidity
D io x in s /F u ra n s
8290; congeners PCDD/F (CI4-CI8) 2005 WHO
Total and Dissolved M e tals
6020; Ag, Al, As, Ba, Cd, Cr, Co, Cu, Fe, Pb, Mn, Ni, Sb, Se,TI,V, 7471B; Hg
6010;Ca, Mg, Na, K
Volatile Organic Compounds (VOCs)
82 60; See FSP Table D-5
Semi-Volatile Organic Compounds (SVOCs) 8270; See FSP Table D-5
Polychlorinated Biphenyls (PCBs) Nutrients
Ions
8082; PCBs (Aroclors)
353.2; N itrate+N Itrite SM 4500-P-E; Phosphate SM 5310C; TOC 300.0; S04, Cl, F SM2320B; Alkalinity SM 2540-C; TDS Electrode; Conductivity, pH
0
...
...
...
Store a t <6C, or low er, in the dark.
Extract within 30 days and analyze
2
1-liter amber glass bottle Cool to 6C, sodium within 45 days of extraction.
thiosulfate
Analyze withing 1 year if sample
extracts stored in the dark at < -
lOoC.
Cool to 6C; n itric acid
250-mL HOPE bottle
to pH <2; water to be 6 months w ith th e exception o f
1
(Dissolved, Field-Filtered) sampled fo r dissolved mercury (28 days).
metals m ust be field-
filtered,
3
40m LVO Avial
Cool to 6C; hydrochloric acid to pH<2; Sodium Thiosulfate (Na2S20 3) if
14 days.
Cl present
2
1-lite r amber glass bottle Cool to 6C
Extract within 7 days after sample collection. Analyze w ith in 40 days
o f extraction.
Extract within 1 year of sample
2
1-liter amber glass bottle Cool to 6C but above collection. Analyze w ith in 40 days
freezing
o f extraction.
1
250-mL HOPE bottle
Cool to 6C, sulfuric acid 28 days to pH <2
1
500-mL HOPE bottle
Cool to 6C
All analytes 28 days except TDS (7 days).
Notes:
- n o t applicable
Hg - mercury
Ag - silver AI - aluminum As - arsenic Ba - barium Ca - calcium Cd - cadmium Cl - chloride Co - cobalt Cr - chromium
K - potassium Mg - magnesium mL - m illiliter mn - manganese Na - sodium Ni - nickel ORP - oxidation reduction potential Pb - lead Se - selenium
Cu - copper
S 0 4 - sulfate
C - degrees Celsius DO - dissolved oxygen
TDS - total dissolved solids Tl - thallium
Fe - iron
HOPE - high density polyethylene
T O C - total organic carbon V - vanadium
Zn - zinc
FSP - NewFlelds 2015, Field Sampling Plan, Appendix D o f the Remedial Investlgation W o rk Plan, Novem ber 2 0 15
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
Page 56 of 58
ED 002061 00090997-00066
Friday. M ay 25. 2018 12:10:48 PU
FMT-ALL-C-002rev.00 24March2009
Page 57 of 58
/ ' -FaceAnalytical'
D o c u > r:e n i N a rv a . S a m p le C o n d itio n U p o n R e x e ip t F o rm
D ocum ent No F -V M -C -Q 0 .l-R e v .1 0
D o c u rn e n f R e v v e d : ? S R R a r70 ?6
Page 1 o f 1
Is s u in g A u th o r ity : P ace V irg in ia , M in n e s o ta Q u a n te O ffic e
C lie n t N am e:
Ai .
/V '\ !\ /
Project if:
C o u rie r: T ra c k in g N u m b e r:
L J r e d Ex i iC o m m e re ia i
I JUPS F P ace
[__ U S P S
j L O t h e r :
r ia ie n t _____________
WO#'1 2 1 0 9 1 7 3
12109173
C u s to d y Seni o n C o o le r/B c x P re s e n t?
[ jY es
J no
S e a ls I n ta c t 7 Q V e s
C jN o
O p tio n a l: P ro f. D ue C a te :
f 7r o f . N a m e
P a c k in g M a te ria l: L J B u b b le W ra p
[f/IB u b b le Sags
|__ I N o n e
[ jO in e m
T e m p B la n k ?
t f j Yes
jjN o
T h e r m o m e t e r U s e d : 1 / jT 140792808
T y p e o f Ic e :
C o o le r T e m p R e a d 'C :
A 1J
T s r n p s h o u l d b e a b o v e f r e e z i n g t n 6 :' C
C o o le r T e m p C o rre c te d *C
C o rre c tio n F a c to i _
7
| W e t
[ j B lu e
LjN o n e
f^Sampifcs on ice, cooling process has b e g u n
c B io lo g ic a l T is s u e F ro z e n ?
D a te a n d in itia ls o f P e rs o n E x a m in in g C o n te n ts :
j Iv e s
; N o 1/Y N A
C,-v % fS Q
C o m m e n ts:
C h a in o f C u s to d y P re s e n t7 C h a in o f C u s to d y P iiie d O u t 7 C h a in o f C u s to d y R e lin q u is h e d ? S a m p le r N a m e and S ig n a tu re on CO C7
Y g s........ [ > c I I c V ......... b e
S
no
Yes
no
n /A 1
n /A s.
n/a
7
[J N /A
A.
.S a m p le s A rriv e d w ith in H o ld T im e 7 S h o rt H o ld T im e A n a ly s is (<??. h r}? R ush T u rn A ro u n d T im e R e q u e s te d ? S u ffic ie n t V o lu m e ?
?es ves ves LJves
[J N C i I
,-- , ,
H m/ a . J N /A
n /a
S. If Fecah [_ ]< g b o o rs [ J >8. <2? h o u rs U M x ! h o u rs ? 7.
g.
C o rre c t C o n ta in e rs u s e d 7 Pace C o n ta in e rs U s e d 7
C o n ta in e rs in ta c t? F ilte re d v o lu m e R e c e iv e d fo r D is s o lv e d T e s ts 7
Yes L J Yes [jY e s M Ves
hio uc no
n/a [JN /A n /A n /A
9
10. 11. N o te if s e d im e n t is v is ib le m th e d is s o lv e d c o n ta in e rs .
S a m p le L ab els M a tc h C O C?
ves
no
n/A 12
-in c lu d e s D a te /T im e /iD /A n a ly s is M a trix
A ll c o n ta in e rs n e e d in g a c id /b a s e p re s e rv a tio n w ill he c h e c k e d and d o c u m e n te d in th e pH lo g b o o k
ves
CU No
---tie a d -S p 3 ce --iri--M e .tA -v-!Jyf w :e u r,v-C M iA o 4 a fttr-------------------------------- - . Y e s ......... H h c
n/a
S e e p H lo g f o r r e s u lts a n d a d d it io n a l p r e s e r v a t io n d o c u m e n ta tio n
.... Q n /a .... - 1 3 - .... -.......... - - - ................ ............... - ........ ...........................................................- ...........................- ........
H e a d s p a c e m V O A V ia ls ( > 6 m m )? T rip B la n k P re s e n t? T r ip B la n k C u s to d y S e a ls P re s e n t?
Pace Trip Biank Lot S (if purchased):
Ves ves Yes
LJN L.J no
N /A
L ,,j N /A
IS
n/a
C L IE N T NOTIFICATION/RESOLUTION
P e rso n C o n ta c te d : C orn m e n ls /R e s o lu tio n
O a te /T im e :
F ie ld D a ta R e q u ire d ? F jY e s O n o
FECAL WAIVER ON FILE Y N
TEMPERATURE WAIVER ON FILE Y N
P r o j e c t M a n a g e r R e v i e w : Y ? 7 c f L < W W m R ________________________
D a te :
5 /2 9 /1 8
oi N o t e W h e n e v e r t h e r e is a d is c r e p a n c y a f f e c t in g N o r t h C a ro lin a c o m p lia n c e s a m p le s , a c o p y t in s t e r m w ill b e s e n t t o ; b e N o r t h C a r o lin a O E H N R C e r t if ic a t io n O ff ic e h e o u t o i
h o ld , in c o rre c t p re s e rv a tiv e , o u t o f te m p , in c o rre c t c o n ta in e rs )
Page 58 of 58
Sierra Club v. EPA 18cv3472 NDCA
Tier 10
ED 002061 00090997-00068