Document XOOZoj3p6xONoLQx51b3oJ7ry
BIODEGRADATION
FFiEs=3
TEST SUBSTANCE
Identity:
Perfluorooctanesulfonate, Ammonium salt; may also be referred t1o,1a,s2,P2,F3O,3S,4N,H4,,5",5s,a6l,t 6o,r7,F7C,-89,38.,8-(h1e-pOtacdteacnaefsluulcfroon-i,caamcimdo, nium salt, CAS # 29081-56-9)
Remarks: The test sample is a mixture of the test substance in isopropanol and water (25% test substance, 20% isopropanol, 55% water). No calculations were made to adjust for the actual concentration of the test substance in the test sample.
METHOD
Method: Not noted. Type: Aerobic
GLP: No Year completed: 1974
Contact time: 20 days Inoculum: Not noted
RESULTS
5-day BOD:
10-day BOD: 15-day BOD:
20-day BOD: COD:
232,500 mg/L.
267,500 mg/L 297,500 mg/L
292,500 mg/L 412,000 mg/L.
Remarks: The BOD and COD values are expected to be the result of biodegradation of the isopropanol componentofthe test sample. These values are not expected to be representative of the Perfluorooctanesulfonate, Ammonium salt.
`CONCLUSIONS This testing indicated that some portion of the test substance biodegraded in aerobic environments capable of supporting biodegradation.
Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133
04621
DATA QUALITY
Reliability: listing of test
Kiimisch values.
ranking 4. The original
Summary was created using only a study procedure and raw data were
not
found.
REFERENCES
This study was conducted by the 3M Company, Environmental
Laboratory, Lab Request number 2318, 7/18/74.
OTHER
Last changed: 5/3/00
004622
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MDAATTEARISAHLEETSAFETY
a3m center st. Paul, Minnesota 515-184040--1306040-3577 or (651) 737-6501 (24 hours)
ACoLpLyrriigghhtt,s
1r9e9s9e,rveMdi.nnesCooptyainMginianngd/oarnddMoawnnulofaadcitnugrinogf
Company. this
information for the purpose of properly utilizing 3M products
1i)s tahlelowiendforpmraotviiodnedisthacto:pied in full with no changes unless
2) pnreiiotrheragrteheemecnotpyisnorobttahieneodrigfirnoamlaHi,s arnedsold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: 3M SPECIALTY MATERIALS TRAFDCE-03NAMFEL:UORAD Brand Etching Bath Additive ID9N8-U0M2B1E1R-/0U1.9P2.-C2:. 00-51135-09187-6 98-0211-0201-1 ISSUSPUEERDS:EDEDSe:ceSmebpetrem1b7,er19049,9 1998 DOCUMENT: 10-3795-1
00-51135-09190-6
1. INGREDIENT
G.A.S. NO.
PERCENT
WAAMTMEORN.I.U.M oPeEiRiFiLeUiOeROnAsLiKnYnLseSnUaLsFeONeAsTaEa.a.n.a.n.e.s. 27793028-11-85-656-9
19.0
55.0 - 28.0
AIMSMOOPNRIOUPMYLPAELRCFOLHUOOLROA(LIKPYAL).S.U.L.F.O.N.A.T.E......s.s...e. 66872-6693--007-4 0.1
20.0 - 2.0
AMMONIUM AMMONIUM
PPEERRFFLLUUOORROOAALLKKYYLL
SSUULLFFOONNAATTEE..............
6688225599--0089--56
00..11
-- 22..00
AMMONIUM PERFLUOROALKYL SULFONATE....... 68259-10-9 0.1 = 2.0
TnhoetifciocmaptoineonntsreoqfuirtehimsentpsrodofuctTSCaAr.e iAnLLcomapplpilaincacbeleWitchhetmhiecalchemical EixnigsrteidnigentCsheminictahlisSumbasttearnicaels a(rEeINlECiSs)t,edoronatrheeexEeumrpotpeapnolyImnevresntwohroyseof monomers are listed on EINECS.
2. PHYSICAL DATA
BOILING POINT:......uuennsesnns VAPOR PRESSURE:............eees VAPOR DENSITY:....uuunnasenssns SEOVLAUPBOIRLAITTIYONRINATWEA:T.E.R.:...................... SPPEERCCIEFNITVCOGLRAATVIILTEY::............................ PHI veeeansenneennnnneeeeese
C8. 82 C C3(.In3i4tiaBlA)HQ 08C.alc1..0@A2d0riC. <ca1l.c0. Bu@OA2C0=1C. mcao.der1a.1teWater=t C4. 78 % GOL T
Abbreviations: N/D - Not Determined N/A - Not Applicable
CA - Approximately
004624
MSDS: FC-93 FLUORAD Brand Etching Bath Additive December 17, 1999
PAGE 2
2. PHYSICAL DATA (continued)
(0.1% Aqueous) VISCOSITY: .uvvucunvennnsnnnnns NID MELTINGPOINT:..ovveneeenenees N/A
APPEARANCE AND ODOR: Liquid, Clear amber
solution,
Ammonia,
Isopropyl
Alcohol
odor.
3. FIRE AND EXPLOSION HAZARD DATA
FLASH POINT:...............0... 27 C Setaflash FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, Foam
SPWEeCaIArLfFuIlRlE pFrIoGtHeTcItNiGvePRcOlCoEtDhUiRnEgS,: including helmet, self-contained,
positive pressure or pressure and pants, bands around arms,
demand breathing apparatus, bunker waist and legs, face mask, and
coat
protective covering for exposed areas of the head.
UNSUeSUeALHazFaIrREdouAsNDDEeXcPomLpOoSsIiOtNioHnAZAsReDcSt:ion for products of combustion.
4. REACTIVITY DATA
STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
Not applicable. HAZARDOUS POLYMERIZATION: Hazardous polymerization will mot occur. HAZCAaRrDbOoUnSMDoEnoCxOiMdPeOSIanTdIONCarPbRoOnDUCDTiSo:xide, Oxides of Sulfur, Hydrogen
Fluoride, Ammonia, Toxic Vapors, Gases or Particulates.
04625 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: FC-93 FLUORAD Brand Etching Bath Additive December 17, 1999
PAGE 3
5. ENVIRONMENTAL INFORMATION
SPILL RESPONSE: Refer to other
sections
of
this
MSDS
for
information
regarding
physical personal
and health protective
heaqzuairpdmse,nt.resVpeinrattiolrayteparroetae.ctioEnx,tinvgenutiislhatailoln,
and
ignition sources. from hazard area.
Contain spill. Evacuate unprotected personnel Cover With absorbent material. Cover spill area
with Light Water Brand or other ATC foam usage, contact 3M Fire
APTrCotefcoatmi.on (SFyorstefmusr.t)herCiolnlfeocrtmatuisoinng on
non-sparking tools. Clean up residue with water. Place in an
approved metal container. Seal the container.
RECOMMENDED DISPOSAL: Incinerate in a permitted
hazardous
waste
incinerator.
Combustion
products will include HF.
ENVIRONMENTAL DATA: Contains only "exempt"
solvents
by
"Rule
66
type
regulations;
COD=.41
g/g; BOD20=.29 g/g; 96-Hr. LC50, Fathead Minnow(Pimephales
promelas)=85 mg/L.
REGULATORY Volatile
INFORMATION: Organic Compounds:
220
gas/liter.
VOC Less H20 & Exempt Solvents: N/A.
since regulations before disposal.
vIanryt,hecoenvseunlttofapapnlicuanbcloentrroelglueldatiroenlseasoer
authorities of this
mraetpeorritaalb,lethqeuanutsietry.shoUu.lSd. deEtPeArmHianzeardiofustheWasrteeleaNsuembeqrual=ifiDe00s1 as a
(Ignitable)
This product requirements
is of
in compliance TSCA, EINECS,
with the chemical registration AICS, CDSL, MITI and Korea.
OTHER ENVIRONMENTAL INFORMATION: This product contains one or more
organic
fluorochemicals
that
have
the potential to resist degradation and persist in the environment.
EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: No
REACTIVITY: No
ACUTE: Yes
CHRONIC: Yes
6. SUGGESTED FIRST AID
EYE CONTACT: Immediately
flush
eyes
with
large
amounts
of
water.
Get
immediate
medical attention.
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
04626
MSDS: FC-93 FLUORAD Brand Etching Bath Additive Decenber 17, 1999
PAGE 4
6. SUGGESTED FIRST AID (continued)
SKIFNlusChONTsAkCiTn:with large amounts of water. If irritation persists, get medical attention.
INHIAfLAsTiIgOnNs:/syaptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician.
IFISfWAsLwLaOlWlEoDw:ed, call the instruction of
a a
pphhyyssiicciiaann. imNmeevdeiratgeilvye. aOnnyltyhinigndubcyemvooumtihtitnoganat
unconscious person.
7. PRECAUTIONARY INFORMATION
EYEAvPoRiOdTEeCyTeIOcNo:ntact with vapor, spray, or mist. Wear vented goggles.
SKIANvoiPdROTsEkCiTnIOcNo:ntact. material. A pair of
Wgelaorvesapmpardoeprifartoem
gthleovefsollwohewninghanmdaltienrgialt(hsi)s
are
rpeecrosmomneanldepdr:otecbtuitoynl riutbebmesr.as Unseecesonsearyortmoorperevoefnttheskfinollcoonwtiancgt:
ampardoen,ofcoevietrhaelrlso.f thPerotfeocltliowvienggarmmaetenrtisal(so:ther than gloves) should be
polyethylene/polyvinylidene chloride (Saranex).
RECIfOMMexEhNaDuEsDtVEvNeTnItLiAlTaItOiNo:n is not adequate, use appropriate respiratory pcroontceecnttiroant.ionsPrboevliodwe vreenctoimlmaetnidoend eaxdpeoqsuuartee tloimictosntraonld/ovrapocrontrol spray or mist.
RE`SAPvIoRiAdTObRrYeatPhRiOnTgECToIfONa:irborne material. Select one of the following NcIoOnStHamianpapnrtosvedandreisnpiraactcoorrsdanbcaesedWitohn OaiSrHbAorrneegulcaotnicoennst:ratiHoanlf-ofmask organic vapor respirator with dust/mist prefilter.
PREVENTION OF Do not eat,
AdCrCiInkDENorTALsmoIkNeGESwThIeOnN:using
this
product.
Wash
exposed
abreefaosretehaotrionugg.hly With soap and Water. Hash hands after handling and
RECSOtMoMreENDaEwDaySTfOrRoAmGEa:reas where product may come into contact with food osrunlpihgahrtm.aceuKteiecpalcso.ntaiSnteorrecalwoasyedfwrohmenhenaott. inStuoser.e oKuteepofcdoinrteacitner in
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
0462or7
MDSeDcSe:mbeFrC-9137, FL1U9O9R9AD Brand Etching Bath Additive
PAGE 5
7. PRECAUTIONARY INFORMATION (continued)
well-ventilated area.
FIRKaEeweaApyNDcfrooEnnXtPaLihOenaSetIr,ONtisAgpVhaOrtIklDsy,ANcCloEop:seend.flamFel,ammaanbdleothleirquisdouracndesvaopfori.gnitKieoenp.
OTHNcEooRntsamPomRkiEinCnaAgtU:iToInSOmNoAokfRiYntghIeNwFhOtiRolMbeAaTcIcuOosNi:nagndt/hoirs sprrookdeucatndcalneadrestuolttheinformation oDfatathesechtaizoanrdooufsthdiescomMSpDoSs.ition products mentioned in the Reactivity
HMIS HAZARD RATINGS: HPEEARLSTOHN:AL2PRFOLTAEMCMTAIBOINL:ITXY:(S3ee RpErAeCcTaIuVtIiToYn:s, 0section 7.)
EXPOSURE LIMITS
INGREDIENT
VALUE UNIT TYPE AUTH SKIN
WAAMTMEORN.IU.M..P.EeRiFuLvUuOsReOsAeLnKsYiLiiSeUeLeFeOeNaAiTnEi.i.e.s. N0O.1NE ~NMOGN/EM3 IISSOOPPRROOPPYYLL AALLCCOOHHOOLL ((IIPPAA))............................ 450000 PPPPMH IISSOOPPRROOPPYYLL AALLCCOOHHOOLL ((IIPPAA))............................ 450000 PPPPMM AAMMMMOONNIIUUMM PPEERRFFLLUUOORROOAALLKKYYLL SSUULLFFOONNAATTEE........ ~ 00..11 ~MMGG//MM33 AAMYMMOONNIIUUMM PPEERRFFLLUUOORROOAALLKKYYLL SSUULLFFOONNAATTEE........ ~ 00..11 MMGG//MM3
TNOWNAE N3OMNE Y TSHTEAL AACCGGIIHH TSTHEAL OOSSHHAA TTWWAA aoMH Y TTWWAA G3MM Y
thSeKIpNotNeOnTtAiTaIlONc:ontrLiisbtuetdionsutbostatnhceesoveirnadlilcateexdpowsiutrhe b'yY' thuendecrutSaKnIeoNusrefreoruteto ibnyclduidriencgt mcuocnotuasctmewmibtrhanteheansdubsetyae,ncee.itheVrehibcyleasirbcoarnnealotre,r smkorien paabrstoircputliaornl.y,
SOURCE 3M:
OFaMEXPROeScUoRmEmenLdIeMdITEDxApToAs:ure
Guidelines
AOCSGHAI:H: OAmcecruipcaatnionCaolnfeSraefnectey aofndGoHveearltnhmenAdtmailniIsntdruasttiroinal Hygienists
- NONE: None Established
8. HEALTH HAZARD DATA
EYEWiClOdNTEAyCeT:Irritation: signs/syaptoms can include redness, swelling, pain, and tearing.
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
04628
MSDS: FC-93 FLUORAD Brand Etching Bath Additive December 17, 1999
PAGE 6
8. HEALTH HAZARD DATA (continued)
SKIMNildCONSTkAiCnT:Irritation (after prolonged or repeated contact): signs/syaptons can include redness, swelling, and itching.
Mtahyosebecaaubsseodrbebdy tihnrhoaulgahtiotnheansdki/noranidngepsrtoidounc.e effects similiar to
INHALATION: single overexposure,
above
recommended
guidelines,
may
cause:
Cheeandtarcahle,NedrivzozusineSsyss,temdroDwespirneessssi,on:inscoiogrndsi/nsaytaipotno,mssclaonwedincrleuadcetion time, slurred speech, giddiness and unconsciousness.
Isrorrietnaetsisonof(tuhpepernosreespainrdattohrryo)a:t, sciogungsh/isnygmptaonmdsscnaeneziinngc.lude
IFAnSiHAmLaLlOWsEtDu:dies conducted on organic Tluorochemicals which are present ilnosst,hislospsrodoufctappientdiitcea,teleetfhfaercgtys, ianncdludnienugrolloigviecrald,istpuarnbcarnecaetsi,c,weight aedfrfeencatls afnrdomheamnattiocliopgaitcedefefxepcotssu.reThteoretheasree noorgaknniocwnfhluumoarnochheemalitchals when used as intended and instructed.
tIhlilsnesmsatemraiyalr.esult from a single swallowing of a moderate quantity of
Iparirni,tatvioomnitionfg,GasatbrdooimnitneasltitneanlderTniessssu,es:naussiegan,s/sbylaopodtoaisn cvoamnitiunsc,ludaend blood in feces.
Cheenadtarcahle,NerdviozuzsineSsyss,temdroDwespirneessssi,on:mussciuglnas/rswyeaapktnoemsss,caninicnoocrlduidneation, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions.
Ingestion may cause:
Adsipfifriactuilotny Pbrneeautmhoinnigt,is:wheseizginnsg/,syacpotuogmhsingcanupibnlcolouddeancdougphnienugm,onia, which can be fatal.
OTHAERPrHodEuAcLtTHToHxAiZcAiRtDyINSFuOmRmMaArTyIOSNh:eet is available.
This product contains one or more organic fluorochemicals that have tohfetipmoet,enetiitahlertoasbethaebsoprabreednt anmdolerceumlaeinorinatshemebtoabdoyliftoers,lonagnd pemraiyods accumulate with repeated exposures. There are no known human health
04629
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
#80S: FC-93 FLUORAD Brand Etching Bath Additive December 17, 1999
PAGE 7
5. HEALTH HAZARD DATA (continued)
ewhfefnectussefdroams ainntteincdiepdateadndexipnosstururcetetdo. these organic fluorochemicals Tphoepulparteisoennceandofsoubrpgoapnuilcatfilounosr,ochseumchicaalsswoirnketrhse, blhoaosdbeofenthpeublgiesnheeradl dwaotriknegrsbaicnkdictaotetsheno197a0d'vse.rseGM'esffeecptisd.emiological study of its own
SECTION CHANGE DATES
PRECAUTIONARY INFO. SECTION CHANGED SINCE September 04, 1998 ISSUE
Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
TbheeciornrfeocrtmataisonofinthtehidsatMeatiesrsuieadl.Sa3feMtyMAKDEaStaNSOheWeAtRRA(NMTSIDESS), isEXPbReElSiSeEveDdOtRo
MIEMRPCLIHEADN,TABIINLCILTUDYINOGR, FBIUTTNENSOSTFLORIMAITEPDARTTOI,CUALNARY PIUMRPPLOISEED OWRARRCAONUTRSYEOFOF
wPhEeRtFhOeRrMANtChEe SOMR pUrSAoGdEuctOFiTsRAfDiEt. forUsaerpairstirceuslpaornsipbulreposfeoradndetesrumiitnaibnlge for
ucsaenr'asffemcetthotdheofuseuseandoraapppplliiccaattiioonn.of Gai3vMenprtohdeucvta,riestoymeofoffawchticohrsatrheat
uniquely the user
weivtahliunatethetheuse3rM'sprkodnuocwtledtgoe daentdermcionnterowlh,ethiterisit esissenfittialforthaat
particular purpose and suitable for user's method of use or application.
aDMueptroovtihdeesreimnoftoermaptoisosnibiilniteylectthartonieclefcotrrmoniacs tarasnesrfveicremtaoy hiatvsecursetsoumletresd.
irneperrersoernst,atioomnisssiaosnstooritsalctoemrpalteiotnesnesisn otrhisacciunrfaocrym.atioInn, ad3dMitmiaokne,s no
iinnffoorrmmaattiioonn
ionbtatihenedMSDfSromavaaildaatbalbeasdeirmeacytlynotfrobme
as current aM.
as
the
04630