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RESEARCH rg Rot,
AR226-1947
CREECTEIAVED oo OSAPR2S MII: |
3M Company
Analysis of PFOA and PFOS In Water Samples from Oakdale Municipality
\
E05.0243
Exygen Report No. L0004933
"Testing Laboratory
, Exygen Research St3a0te58CoRlelsegesa,rcPhAD1r6iv8e01
Requester
`ManagerG,aErnyvAiroHnomheenntsatleOipnerations EHS Operations Bu3idMinCgo4m2p-a2n6y-27 St. Paul, MN 55106
pastors
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1 Introduction
R(oPsFuOlSs)ainrworaelporstaemdpfiorotshreoacnoailvyesdiosfofExpyagreucnraosorcotqaunocsatlesdb(PyFGOaAr)yaHnadhpeenrsfiuochrooofctSaMneCsoumlpieonnsyt.o T`ahnaetyElxesygqenupraojnectftonruttmhbeaseartmapselseidsg.ned(0the samples Is L0OO4933. Tabl |fatsthotarget Table. TergetAnsfoir Qutenteintson
ammeter Pertuorooctancala Perfuorooctanesuifonste
fromm PFORrC8acd
POS orG8sunt
Fomug CifW000
CFSOF
2 Sample Receipt
.
"Twenty-cn sampleswere receivedatExygenin S00 ml.whi plastnamow-mouthbotfes.At hperreqouessitnaoAftna3cMhi,maeelntsdAampleswereanalyzed. Acopyofalsample log informatioins
"`Tshaempslaemspwleorsewsetorroerdorceofigveerdaotnad03r3o0m0m5.eoTfhetescealmpptluenstwaenreyesh.ipadambient vaUPS. The
3 Met-hAnoalydticsal andPreparatory
`hTheesEaxmyppieonpmreeptehroatdiVonOcOa01n7b8e0fwoeusrusIenSdectotipornap3e.r1eaennddaanssulymzmsatrhyeosfamhpelaensa.lysAissucmomnadrooyfs
canbefoundInSection 32.
.
3.AWater Sample Preparation Fooritdypmihlalseeresxtorfatchtieowne(leSrPsEa)wmpalseuwsaesdfroapnsrioaprerreedth0evaaCl.oyrSsPaEmcpairetsrfiodgreL.TChMeScMarStaingaleywsiass. Veilautlesdanwdianm5yzmeLdoufsi1n0g0e%lmoectrhoaspnroaly.LOAMpSoMrtMoSn.oftheexactwastransferedto aulosampler
Page2068
32 SampleAnalbyyLCsMiSMsS
ItnhrHoougnhPraelsqsuukrtepLhausedchCrhoommaatotgorgarpahpihcyc(oHPrLrC).,aBnasaelduoontothfeeaxfaicnttyIosifnjtehcataednaanldepfaosrstehde schtaartaocrtaerryipshaasmeoIunntioefctoimlei. nForlelolwiengioHPDLeCqsekp!araMtaobnl,emgahsessss,ptahceiaonmaeksypsrooviadienseda foarg afndracacugramteaemnendatndesetfaocdire,adn. ayTahneg i8oWnisecharraancgteeroifstoircgoafn:tcheomcpoomupnodusn.dsM.aorelobesaornceveendiazsendd, quanagaitnstetxteaciedtsanederdds.
A`snarmHpPl1oe100xsysatfeomrcqIunetntatraatcsoend. 10anApplied BlosysemsAPI4000wasusedtoangiothe
I2s.o1mteormsepxeSraatmiconawnes.obiTahienesduumsionfgthaegrIsaodmeenrtseui oranpooruedgh8a&TshgelrmvoaFlluueopfhoareseaRcPhc,f60thxe analytes The folowing gradientwasperformed:
MoMboibolPehPahsee((s88s)) 2MmeiMenAdlmmoAcsnatkabniWetnar
Ti00ma
5&
2
1890
2&%
37s
110100
28
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180
&
3%
"Thefolowingparameterswere sedfor peratnofthe isspectrometer:
T onizatonMog E `Becrosprey
pTarratnsyionsMontored
41N3eg5a3i6ve9(PFOA),498-590(POS),
Gas Temperature
415c5370 (C-PFOA,surogetsspke)
Dring Gas(82)
ZoUmn
4 Analysis 41 Calibration
PFAOTA-p,oPntFcOaSlbarnadt"inCcPurFvOevAa.Tshaencaallybzreatdiionnptoilntasnwderthorporuogphaoruatdtahe0a,n2s5l,yl5c0a,l1s0e0q,u2e5n0,c5e0fo,r a`snadme1S0P00Enpolr(oopt)cfuosraeLddfOoruSsaSmrpalneeasl.ysTish.e"iCasltiburmateinontsrtoa3npdoanrsdssverrosupsrtohpeecroendcuesnitnrgehtoen Wasplfoorsatchpsain. Using insarregressionwin 1 welhing,the sope,yniaroopt
Paceacrs
27
--_--
2ntdycoficintofdtom(i)nwwaeettaominned. Acalcurtveiraccaspaoie n> FIonrethreorwedseuasIenpAoaricehdhmareen, tcalbratonrerewere mel.Thecalbraoncurvesarsincuded
42 Surrogates
wSaCamsPpaiFdnOdgA.ed(IinCtohFe[uhflooa"Cm,IpFlay"sCsaJamOmpOplHle)eaincsdounsqaeuhdaetarysscba@esnfukoomrloebgtaahttesebfsoowrtehssewwfeoelraerss0aem8mvp1loemsh.efC ePdFfnOogA with Bosample C PFOArverios canbo oundhnAtachment8.
4.3 Laboratory Control Spikes
oLfabPorFaOtoAry,c"onPtFrOoAsp,i0knedsPnFthO aIonaaslssatwoeroogeprsg.arLadbyaalcsgooaressoowsnbcsoencearmirasstion
sw1si3sl0ei%snostahrmcetihohodoeadlpatcoaaurrrebajaceniycgt.aeed.T.hFeolrahboararlooruytcsonrieroplosrpeidkhessm,ushet ancorwsreicooyvecroines bespthweenv7r0s
44 FloldMatrixSpikes
D`O0nocmmapi ssaimkawecsoprmepearrei dfor veFryowatterssapieneth fol.Compoundswer addeedSto
Tssopclcckooevpsatraearinoeburesatnewgdeet,eon7a0s-s1e2ss0m%.etFhoordtahccruorawcyrienptohretemdathreirxe.,Thhe eamatrisxpsipeiskwesasrheoauildt shrows
4.5 SampleRelated Comments
AhlewsaamrplsearmpelaetswhenrAaacocliehcteednI5n. dupa, Duplicatesample osuls reepovind songwih
3 Data Summary
PpieaarssaspoorebAtoanch(manngt)foorr PadFeOaAiaenddlPiFgSo,f he natsresus,Theroarsreasred
razors
6 StatoefmAcecunratcy Bapoinskieeso,nsurrsocgooartaascoypffiokreaPsbaFunOsdSifairnedcdmoPnaFtOrolAxssrppiekasesst,sf8hoorwoeadstarimepcolaveeskrIise,.s2wa3in0id%h.sAhulemasobegorreaatntgsaeoesky.eos,orho `Speci sample ecoveres 76given InAschment8.
7 Data/SamplaRetention rH`eaSiarmdopovloaepstywediamtebadairsataaornedmdhfatorrodacSmMoip6nyi0rmedupamoyrsotafsffaevreryesinaarolsr.depTIohrntedicnaig.etAnftlowliedlleebrcestnrmooatnnfciioeitdn3ae0idsdbaaryycshEpixovyuegdreo1nn5. ho posalofhardcodaptey.
8 Attachments
81 AtacA:tAnamlytanlRnestts 82 tachSpmikeeRecnovertyDa:ta 83 AtachmenCt: ChofCuastoi dy Fn orms 84 AtaDc:RhawmAnaeytanlDatta
9 Signatures
:
bs
PrincipalTvesigaior
Hp la
--
-- fob
aaEsors 29
Section A
EXys SEARCH
"Summary of PFOA and PFOS In Water Samplos E05-0243
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'0-W2-208463
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nl.adthe ink
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Section B
_
32
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_--
XYgen..
Field Matrix Spike Recovery Summary for PFOAand PFOS In Water E08-0243
\_ simple
SampoleeceRraAccoauvpatrrsodnRecovery|RinSameplCe1.sRueAcfonvotonresdOReSecovery
SWDEeecTptTenSp
: po) gmt) gh gly ager
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or | om ome ss | cow om nm
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Surrogate
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Sumfmor"aC-rPFyOA
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0055 o0u4nx &5 10 103 103
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005s oodsse %2 of ooes 7
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0055 oassme TM2 10 102 102
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Phone: 814-272-103 Fa`xa:x: 814-821341--213.1-1580
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Proijedt Po0o0s0890 Company Name: 3M
Login Group: L0004933 CCoonnfofrmorm CCOOCC: Samia TTiede
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Conform Request: True
SOtasrttoedSwt 0Ti0e2005
ROeecelDavteed: Date: 0043038022000055
Recoived By. Ammerman, Mark
ESLxapbyregetaedn
Sample:
SOPL:
Risha, Karen
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`Conform Notes
fEarcha--ce
CoCnotmgeioresr$ cose comers cameos comer comm comers comes commen come comers cosas comms comms
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ReDcueoiDavleed:Dale: 004313008212000055
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CONTRAC3TMLENVAIRBONOMENRTWAAOLRLTKAOBORODRERARTOBYRYYSAMPLE `Contract Lab): EXYQEN.
Page 10f3
Requester: Hohensteln,Gary Department: $3071
A
(0042.02E-27)
PrDoajtaecRteNceuimvbeed:r:3020/222060784449
`ProjectDescription: Oakdale MunicipalWall FC IV
`PCroomjpelcetLteiaond:DKaesn:tLindstrom P`hEoanniel NAuddmrbeesrs:, k65r1l.i77n8d.5e3r5o2m@rmconmm
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Comments: Pace field sulin.
3 Sample Number __ Sampled Date __ Sample Description
E05.0243.31103 Asal Code
32005 owns
AustcalMitte
Comvenents
PFOA
PFOA
PFOA
FF--_O--S
PFOS by ESMS.
PROS
E05-0243-81104 AnaisCade PFOA Pr_o--s
3292005 0-W1.208462 Duo
AuirtialMethod PFOA
Campsoms PFOA
`PROSby ESMS
rrOS
B05.0243-81105 AsPFiOmA Code Pr--o_--s
32972005 AustadMethod
O-W1-2084620.) PE Capen
Soike
PrOA
FFOA
PROS by BSMS
Pros
E05.0243-41106 Austr Code PFOA r_o--s
9200S O-wa208463
Auttial PFOA
Mothod
PCOomAona
PROS by ESMS.
PROS
E05.0243:81107 PAuFlOuAsCode PF--O_--S
3092005 0-W2.208463 Duo.
APmFlOviAcalMethod PCFomOmAamat
PFOS by ESMS
EOS
E05-0243-81108 Analy Code PPOA P_OS--.
An3t2i2c0aS]Mood 0-W2Co2m0p0.a1n8PePn4BS6oi3ke
PFOA
PrOA
PFOS by ESMS
Pros
voit
4A20u2a00lD5ayaDiatae t42e02e003s 4A12u02s00D8iyevDeiig 42e020s08 A4u2e0r200D5usDate t42e02m00s5 4A2u02a00bD5uaeDlatas t42e02e005s 4A0n20s05DiosvDolty v420e 2005s 4A201s200D5lueDiats e420s 2005
_--
39005
CONTRAC3TELNAVBIORROANTMOERNYTWALOLRAKOORRADTEROBRYYSAMPLE.
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anonoos
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PFOS by ESMS
PFOS
'
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= PFOS frPFoOSsbwyeESwMsS
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000 e42w0020s05
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Auabvils Code
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Components
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PFFrOoA
Pe PFrOOASw byESMe S pPrFoOsA
34220070200088
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rans `AsalvilaDyeDate
= e-- sos mPrOoS-- bymESMess PreOo s, anus
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CONTRACSTMELNAVBIORROANTMOERNYTAWLOLRAKBOORARTOBDRYYSEAMPRLE
Page3ot3
Project: BES0243 (cont).
.
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3SimpleNumber __ Sampled Date _ Sample Devription
Bosassiial oes owsasisrs
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3M Company
Analysisof PFOA and PFOS In Water Samples from HastingsMunicipality
:
[E05-0186
Exygen Report No. L0004709
Testing Laboratory
Exygen Ressarch
3058 Research Drive
`State College, PA 16801
Requester
Manager,GaErnyviAr.oHnomheenntsatleOipnerations E3HMS OCpoemraptainonys. Building 42-26-27
St. Paul, MN 55106
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1 Introduction
Re(sPFuOtSs)ain wraetcrsratmdpfloorstrheeacnaavleydsaistoEfxpyegfoonroasocrteaqunecsatieedb(PyFGOaAr)yaHnodhpaenrsfioornooofc3iManCeosmupfeornyte.
TahneteExsyqgenuprajenctftnorutamhbeseiroamesessdig.nedto thesamplesisLOOOA7O8, Table | fists thetarget
Tatke |. TargetAnfora Quarts iton
Parameter Perfuoroctamonts
aconm PFOAOrCBlocid
Eom CFC00
Parfuoroocianesufonate PROSorCBslonats
CiFuSO;
2 Sample Receipt reFqouuresstofa3Mm,woopf rsaelmrpolceeaiswvseedraot aEnxayhgzoendi.n A5c0o0pmyio.fwalhslampplalsetigcinnarfoowrmmaotuihobniostipreess.oAniledthe AtacrmenAt `TshaempslaemspwleersewsatorreedrreecferiivgeedroatnedfOr3oD1mItDSm. oTfhreoscaampptuinotswaensrhesskhsp.podambientvia UPS. The
3 Methods -AnalayndtPreipacraatorly TshulefEonxayteoe(nPFmOaSi)n,ePderfeunctreodo,ct"aMnesishuofdonoyfiAamnitdee(sPFfOoSrtAh),eDnetderPmeirnfautairoonocotfanPoaariueo(rPoOaAcAi)sns suWamtmera,r"ymoodfftiheedsfaompilseopmreerpseeractairoantocna,nwbaesfuosuenddtion Sporcetpoanre3a.n1daenndehzeemtohdeFsaemdpineasy.s.A `cononsfoisomer separationcanbe oundinSecton 32.
34 WaterSample Preparation SFoolritdypmhialsleeresxtorfactthieowna(lSePrEs)awmapsleuwsaesdfforparnesipoamreedth1e0 awaCt.eursSaPmEplceastifdogre.LCTMheSMceSrkaincagleyswiess. wa10s0h%emdewlitfha5nmc.LoAfpao4r0t%nomeffthhaenecxta6c0t%wwaasterawnasstha.reTdhetocaarutfodsgaemwpleesrevkalesdawnidhan5almyLzoefd using electosprey LOMSIMS.
racerces
--
32 Sample Analysis by LC/MS/MS
ItnhHroiugghhP2rolsisquuirde-LpihqausiedCCvhoommaatlooggrreappihcyco(lHuPmLnC.),aBnaseqduoonttohfeexatfriancttiyosfnehcotaendaantdepfaosrstehde scthaatriaocntaerryispthicaasmeoiunntthoefcoileu.mnFrol@oiwvieng10HtPhLeCsqeupiadrmatoiboln,ampahassses,petchteraonmaeytlrey pIrsorveimdiensedafroapida 2fndracacugramteeamnnedatdnestefeocdtre,da.nahTzihneg i@ownisdechraarnagcieoerfisoircgoanfictchoemcpoomupnodusn.dMs eereeobcsaetrrevikendieazansdd, quaangaints!exitrasctedtstaendadrds.
A`snamHpPl1ee10x0stysftroermqaiuanntcteirttfataicsoend.toanAppiiedBiosystemsAPI4000wasused fo ansyzsthe
I2s1ommemrsexpaSryamtcioonlwumans.obTiahienseduumsionfgthageriasdoimeenrtsaiksroenporrtoeudgahs aaTsihnegrlmeovFailuuoefpohraseeaRchPo,f5t0hax nates.
Thefolgradoienwtwasipernformged:
MMoodlleePPhhaa((ssA8ee: 2MmeMtAanmomloniumAsstaieinWater
T0mo 285A
3258
8100
28
735
11000 2&5
75 35
180
5
3
`Thefollowing paramelorswereused foroperationofthemassspectromelsr:
TFoanrizaamteotnaMrode, PTorlanasttyions Montorea DrGyaisnTgeGmapesra(tNu2)re
`SeEfefcionsgpray 4Ne1g3a5ti3v0e9(PFOA),499-380(PFOS). 4381065C.370 (*C-PFOA,sumogtospike) 70Urmin
4 Analysis 44 Calibration
PAFO7A-p,aiPntFOcaSlabnradio"nCcPuFvOeAw.aTsheancaallyizxeadtiionnpaollasnwdertehrporuogphaoruetdtshte0,a2na5l,y5ti0c,al1s0e0,q2u5e0n,ce50f0o,r wesanasdmpe10Sl0P0EofGpoIrtLroce(etaodpcuih)repfeooudriseL.dCU/fsMoirSn/sgMamSpailnveasel.r"yrseiTgshr.eesCisoinlosbnkwruamitehnotns1/rixeawsnepdioagnrhsdiesnvgae,rretshpuesrteshplaeopcreoe,ndcyue.snrtiirneagrtciteohpnet
pacesans
_--
0a5n8dc5o'eficientof elerinaion (1)weredetermined. AcalcuvbeIsrcepatabole n2 nForhthrearewsduolttas irneApotratecdhhamreen,cCta.lbatonceaweremet.Thecalcburversaraeioncunded 42 Surrogates wsCaamsplPaidFngdO.eAd(ICan0FtwthlFe"leCdmI,pFt{ly"lCssIaamOmpOpllHee)caIonsundtsqaeiudnaaeysrcsobanetsfurorarreogttahiteeefbsoowrtatirheeeswlweadtreer1ssea8mvpolek10sa.nheerfCcofPl!FnOoeAr it vesample. G PFOAocacnboofouvnd ion Atrachemenst .
43 Laboratory Control Spikes
Laborslonycon spiesintheanalyteslwerspreparedbyadding knownconcanttion o15f350P8%F5Oo5ArM,teh"lodoC adPtFaaOcAsi.reaejnccdyt.PeTF.hOFeSolrIabolovraeabrtoeorrasytuocrsoyneretpaogsreneptdks.ehesrL e,mtua setsab hboocwo eorntterr ocylocsova pnritikot selbsseapto riwekeeuser snweedy 7rt0.eo witinhe eccepiraanigee.
4.4 Field Matrix Spikes
f`AdCloomwfpaoornusndadmaspiwhnieggrh.emaMadtaidleisdspipioikkewheseearerempupriseypasaarm0epadlswesicohentsthmaeisnteahrolsdbeesafooonruersaachyembpinloerheemspawlieasrt.desTehnttehimfoattkhreix 5S95kkeess swehroaudiiShnow2reacocwceraiepsibaorbawniegoenT0-130%. For faresusrepos hes, he max 45 Sample Related Comments TAhteawcarlmoernsta.mpies werocoocted induplicate, Duplicatesamplerasulsareroporadby
5 Data Summary PlpeaarstasspeoeAltiaocnh(m1o5n/tmL8 ffoorPadFOaAlaendPtRnOoSf.th anaylcaross.Theresareueptorised
Pacesces
-------- es ---- ------ -- ------ -------- ------ ----
6 Statement ofAccuracy
BaSaprsioeeisdc,aoalnnsdrcbeaoseducsmyoaffiolrasbForiOaStsoraySncdhooPnwFteoOdlrAsecrpoeavsesru,isefsew53im0na%t.iLeasabpnosgrsea., ancdosnuvogspebtesss,hers,otohe Speci samperecoveriesars given nAtachmentB.
7 Data/SampieRetention
SrHoaatrpidiocoaepbnyiweciamltabadeirsooarmneded aoc1r03cMo6y0mrudaemypsosfatvteaeyfsroisee.grTihinnagcie.naA towdlorbl samoaitc aeian3f0dso dboayrrcsEhpin vasedo1n5n he disofphacoopsycael.
8 Attachments
74 AnachmenAtAnasRosuts 72 Asacnmanta: SpeRecovseyDua 73 AtachmentC. Cran Custody Forms 74 AtscrmentD: Row Anaicsaln
9 Signatures
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- SECTION A
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`Summaryof PFOA and PFOS in Water Samples E05-0186
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SECTION B
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Field Matrix SpikeRecovery Summary for PFOA and PFOS in Water E0S-0186
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`Surrogate Spike Recovery Summaryfor"C-PFOA In Water E0S-0188
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2282005
Project: 50186
CONTRAC5TMLEANBVOIRROANTMOERNYTAWLORLKABOORRDAETROBRYYSAMPLE Conroct Lab(s, EXYGEN
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DReeqpueesmteecr:t:H$3o071heGarnyAs(004e2-0n26:,27) DPursojRcetcNeuimvbeedr::22050722206075645 ProjctDescription:HastingsMusicipalWellCs 1.
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Comments:
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