Document X8oMdRDD9d48yvaZxj42Lopbd
09/29/- : /:09136
RADIAN A N A L Y
CAL SERVICES
P P A S REPORT
TABLE OP CONTENTS
Client DOW CHEMICAL CO. Facility PLAOUEMIWE, LA_______________ Client Code DOW PIAO
Report Form
Work Order Summary Work Order Comments
Flag Definitions Protocol Summary for Volatile Organics SW8260A Results Summary Initial Calibration
Analysis Batch Summary Results Laboratory Blank Information Laboratory Control Samples Matrix Spikes Calibration Verification
Comments/Narrative
Analytical Batch ID MSMSDA70925181601
vjiny | CLS
'I
Work Order # 97094*^'
Certified By Date
WffiMfAT
Pages
From
To
11 22 33 44 55 6 14 15 15 16 16 17 17 10 18 19 19 20 23 24 24
DO A 049708 CONFTDFNTTAI
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Report RADIAN INTERNATIONAL To P.O.BOX 201099___________ Austin. TX 78720-10B8
Attention HEIDI KRALL___________
Prepared By
Radian International. LLC 14046 Summit Dr.. Bldg. B
P. O. Box 201088________ Austin. TX 78720-1088
CSC DPMAXWBBL
Project Sample ID/ Description
DOW-VP-CI/S-ll-Vl DOW-VP'CLS-11-V2 DOW-VP-CLS-11-V3 DOW'VP-CLS-11-V4 D0W-VP-CLS-11-V5 D0W-VP-CLS-11-V6 DOW-VP-CLS-11-V7 DOW-VP'CLS-11-VS DOW-VP-CLS-11-V9 DOW-VP-CLS-U-VlO DOW-VP-CLS-ll-Vll DOW-VP-CLS-11-V12 DOW-VP-CLS-11-V13 DOW-VP-CLS-11-V14 DOW-VP-CLS-11-V1/V14
WORK ORDER SUMMARY
Client Code DOW FLAP Client DOW CHEMICAL CO. Facility PLAOUEMINE. DA Work ID BIF TRIAL BURNS
Case 8 NA________ SDG 8 N_________ RAS 8 708Q7ADPM
Work Order 8 9709429 Page 1^
RCN 800117.5000
New York ELAP ID 8: 10915
Lab sample ID
01A 02A 03A 04 A 0SA 06A 07A 08A 09A 10A 11A 12A 13A 14A ISA COMPOSITE 15B COMPOSITE
Test Code(s)
COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO COMPVOOO 826SWAVP SPAREBOO
Method Desciption
Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Compositing for GC/MS VOA Volatile Organics by GC/MS Spare Sample
no A 049709 CONFTDFNTTAl
09/29/97 17. .36
WORK ORDRR C^-iMRHTS
The standard Method 8260A surrogate tolerances are laboratory derived from historical data. Project specific tolerances may differ.
Work Order N 970> -- 9 Page 2
DO A 049710 OONFTDFNTTAL
09/29/97 1] 77-:0099?13IK6
AaNnAaLlYyTtIiCcAaLl PpRrOoTtOoCcOoLl SsUuMmMmAaRrYy FLAG DBFIlfITIONS
Work Order tt 9709929 Page 3__
Plog
Definition
c DL NA NC ND NR NS B C E F H X J K M P Q R S T X Y Z
Result less than stated Detection Limit and greater than or equal to zero. Analyte concentration not available for this analysis. RPD and/or % Recovery not calculated. See Narrative for explanation. Not detected. No instrument response for analyte or result less than zero. Not reported. Result greater than or equal to stated Detection Limit and less than specified Reporting Limit. Analyte not spiked. Analyce detected in method blank at concentration greater than the Reporting Limit (and greater than aero). Confirming data obtained using second GC column or GCMS. Analyte concentration exceeded calibration range. Interference or coelution suspected. See Narrative for explanation. Presence of analyte previously confirmed by historical data. Analyte identification suspect. See Narrative for explanation. Result is less than stated Detection Limit but greater than or equal to specified Reporting Limit. Peak did not meet method identification criteria. Analyte not detected on other GC column. Result modified from previous Report. See Narrative for explanation. Analyte not confirmed. Results from primary and secondary GC columns differ by greater than a factor of 3. QC result does not meet tolerance in Protocol Specification. Result reported elsewhere. Analyte concentration obtained using Method of Standard Additions (MSA). Second column confirmational analysis not performed. See Narrative for explanation. See Narrative for explanation. See Narrative for explanation.
DO A 049711 CONFTDFNT T Al
09/29/. *7:09:36
Client DOW CHEMICAL CO,_____________ Facility PLAQUEMINE, LA____________ Client Code DOW PIAQ Method Volatile Organics SW8260A
Project Sample ID/Description DOW-VP-CLS-U-V1/V14
(
ANALYTICAL KOTOCOL SUMMARY
Work Order # 9709429 Page
Lab Sample ID 9709429-15A
Teat Code(a) 8265WAVP
Extraction/Digestion Batch ft
NA
Analysis Batch # MSMSDA70925181601
DO C.OMF
QA971
09/29/97 17.09i36
RESULTS SUMMARY
Method Volatile Organics SW8260A Test Code 826SWAVP
Project Sample ID:
Lab ID. File ID; Date Collected: Date Prepared: Date Analyzed: Dilution Factor: Matrix: Units: Report as: Column: Analyte
Chlorobenzene 1,1,2-Trichloroethane
DOW-VP-CLS-11-V1/V14
9709429-15A COMPOS A0925727 09/17/97
09/26/97 06:05:00 10 Water ug/L
received
Cone.
DL
NO 0,960 ND 1.47
Cone.
DL
Surrogate(s)
l,4-Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8
Recovery \
95 103
98
Recovery %
Work Order ft 9709629 Page 5__
Cone.
DL
Cone.
DL
Recoveryt
Recovery %
00 A 049713 OONFTOFNTTAl.
09/29/97 xr:09x36
Sol'n # ftMS-VOA-STD-6_________________ Method Volatile Organics SW8260A Test Code 826SWAQQ
INITIAL
CALIBRATION
Initial Calibration # MSDA97091700000Q Calibration Date 09/17/97 00;00:00
Work Order # 9709429 Page 6
Instrument MSDA Analyst WER Reviewer APS
Analytes Dichlorodlfluoromethane
Chloromethane SPCC Vinyl chloride CCC Bromomethane
Chloroethane
Trichlorofluoromethane
Acrolein
Acetonitrile
Acetone
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone. ug/L
1,442 0.5
1.589 5
2.554 0.5
2.190 5
1.513 0.5
1,652 5
1.210 0.5
1.251 5
0.902 0,5
1.534 0.5
0,903 5
1.506 5
0,056 2.5
0.062 25
Response Factor
Reference Cone. ug/L
1,752 20
2.200 20
1.719 20
1.329 20
0.895 20
1,616 20
0.064 100
Response Factor
Reference Cone. ug/L
1.876 50
2.253 50
1.804 50
1.400 50
0.912 50
1.667 50
0.061 250
Response Factor
Reference Cone. ug/L
1.996 100
2.373 100
1,915 100
1.454 100
0.983 100
1,783 100
0.063 500
Response
Reference Cone.
Response
Reference Cone.
, Correlation
RF
% RSD
Coefficient
1.73
12.8
2,31
6.60
1.72
8,84
1,33
7.61
0,919
3.95
1.62
6.84
0.0612
5.09
0.999
0.998
lodomethane
1.183 0,5
1.478 5
1.614 20
1.635 50
1.644 100
1.51
12.9
DO A 04971.4 OONFTDFNTTAt
09/29/97 17:09:36
INITIAL
CALIBRATION Ctont'd
Sol'n It ttMS-VOA-STD-6___________________________________________ Method Volatile Organics SW8260A Test Code B26SWA00
Initial Calibration # MSDA970917000000 Calibration Date 09/17/97 00:00:00
Work Order 6 9709929 Page 7.
Instrument MSDA Analyst MER Reviewer APS
Analytes
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone. ug/L
1,1-Dichloroethene CCC
Carbon disulfide
0.911 0.5
3.515 0.5
0.841 5
3.430 5
1,1 * 2-Trichlorotrifluoroethan*s
0.960 0.5
0.865 5
Acrylonitrile
0.270 1
0.240 S
3-Chloropropene
1.684 0.5
1.634 5
Methylene chloride
Response Factor
Reference Cone. ug/L
0.844 20
3.656 20
0.930 20
0.247 20
1.719 20
Response Factor
Reference Cone. ug/L
0.875 50
3.717 50
0.962 50
0.240 50
1.738 50
Response Factor
Reference Cone. ug/L
0.927 100
3.867 100
0.997 100
0.237 100
1.761 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
% RSD
Coefficient
0.680
4.41
3.64
4.71
0.943
5.26
0.247
S.46
1.71
2.91
1.00
trans-l,2-Dichloroethene
Propanenitrile
1,l-Dlchloroethane SPCC Methyl t-butyl ether
0.992 0.5
0.071 2.5
1.618 0.5
1.366 0.5
0.908 5
0.075 25
1.600 5
1.560 5
0.948 20
0.076 100
1.645 20
1.809 20
0.976 50
0.074 250
1.669 50
1.696 50
1.013 100
0.074 500
1.758 100
1.630 100
0.967
4.22
0.0740
2.53
1.66
3.72
1.61
10.3
DO A 04971.5 CONFTDFNTT Al
09/29/97 .09:36
INITIAL
CALIBRATION Cbnt'd
Sol'n H DMS-VQA-STD-6___________________________________________ Method Volatile Organics 5W8260A Teat Code 826SWA00
initial Calibration # MSDA970917000000 Calibration Date 09/17/97 00:00:00
Work Order 9709929 Page 8
Instrument MSDA Analyst MER Reviewer APS
Analytes Vinyl acetate 2-Chloro-1,3-butadiene 2-Butanone(mek)
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone. ug/L
1,274 0,5
0.910 5
0.765 0,5
0.698 5
Response Factor
Reference Cone. ug/L
1.083 20
0.742 20
Response Factor
Reference Cone. ug/L
0.952 50
0.768 50
Response Factor
Reference Cone. ug/L
0.938 100
0.783 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
4 RSD
Coefficient
1.03
14.6
0.751
4.41
1.00
Tetrahydrofuran
cis-1,2-Dichloroethene 2,2-Dlchloropropane
Bromochloromethane Chloroform CCC 1,1,1-Trichloroethane
1,2-Dichloroethane
0.266 0,5
0.94S 0.5
0,750 0.5
0.621 0.5
1.553 0.5
1.205 0.5
1.105 0.5
0,261 5
0.966 5
0.719 5
0.621 5
1.479 5
1.142 5
1.227 5
0.196 20
0.977 20
0.848 20
0.604 20
1.450 20
1.230 20
1.210 20
0.147 50
0.972 50
0.820 50
0.601 SO
1.457 50
1.250 50
1,215 50
0.131 100
0.980 100
0.761 100
0,597 100
1.526 100
1.301 100
1.228 100
0.200
31.3
0.968
1.44
0.780
6,79
0.609
1,87
1.49
3.00
1.23
4.78
1,20
4.34
DO A 049716 CONFTDFNTTAl
09/29/97 17:09:36
KITIkl
CALIBRATION COnt'd
Sol'n # flMS-VOA-STD-6___________________________________________ Method Volatile Organica SW8260A Test Code B26SWA00
Initial Calibration t) MSDA970917000000 Calibration Date 09/17/97 00:00:00
fork Order a 9709429 Page 2__
Inetrument MSDA Analyst MER Reviewer APS
Analytes 1,1-Dichloropropene Benzene Carbon tetrachloride 2-Hexanone
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone. ug/L
0.328 0.5
0.300 5
1.030 0.5
0.239 0.5
0.986 5
0.232 5
Response Factor
Reference Cone. ug/L
0.310 20
0.982 20
0.242 20
Response Factor
Reference Cone. ug/L
0.325 50
1.009 50
0.249 50
Response Factor
Reference Cone. ug/L
0.332 100
0.998 100
0.240 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
% RSD
Coefficient
0.319
4,23
1.00
1,93
0.240
2.54
1.00
4-Methyl-2-pentanone(MIBK)
1.00
l,2-Dichloropropane
ccc
Trichloroethene
Dibromomethane
Bromodichloromethane
Methyl methacrylate
0.286 0.5
0.235 0.5
0.139 0.5
0.313 0.5
0.278 5
0.240 5
0.145 5
0.304 5
0.283 20
0.243 20
0.143 20
0.307 20
0.292 50
0.258 50
0.143 50
0.311 50
0.280 100
0.260 100
0.137 100
0.312 100
0.284
1.94
0.247
4.52
0,141
2.32
0.309
1.22
1.00
DO A 049717 OONFTDFNTTAl.
09/29/97 *, ;09:36
INITIAL
CALIBRATION Cant'd
Sol'n # flMS-VOA-STD-6_______________________________________________ Method Volatile Organics SW8260A Test Code 826SWA00
Initial Calibration ft MSDA97Q917000000 Calibration Date 09/17/97 00:00:00
Work Order ft 9703329 Page 10
Instrument MSDA Analyst MER Reviewer APS
Analytes 2-Chloroethyl vinyl ether
trans-1,3-Dichloropropene
cis-1,3-Dichloropropene
Toluene ccc 1,1,2-Trichloroethane
Ethyl methacrylate
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone, ug/L
0,112 0.5
0,113 5
0,549 0.5
0.571 5
0.337 0,5
0-318 5
1.661 0.5
1.446 5
0.504 0.5
0.473 5
Response Factor
Reference Cone. ug/L
0.117 20
0.696 20
0.357 20
1.455 20
0.488 20
Response Factor
Reference Cone. ug/L
0.119 50
0.731 50
0.362 50
1.519 50
0.496 50
Response Factor
Reference Cone. ug/L
0.121 100
0.728 100
0.352 100
1.539 100
0.498 100
Response
Reference cone.
Response
Reference Cone.
Correlation
RF
\ RSD
Coefficient
0.116
3,30
0,655
13.5
0.345
5.17
1,52
5.67
0.492
2,43
0.999
1,3-Dichloropropane Dibromochloromethane 1,2-Dibromoethane Tetrachloroethene
0.836 0,5
0.539 0,5
0,465 0.5
0.417 0.5
0.812 5
0.577 5
0.483 5
0.432 5
0.817 20
0.592 20
0.482 20
0.440 20
0,834 50
0.621 50
0.494 50
0.469 50
0.843 100
0.629 100
0.494 100
0.508 100
0.828
1.60
0.592
6.12
0.484
2.46
0.453
7.95
DO A 049718 OONFTDFNTTAl
09/29/97 17:09:36
INITIAL
CALIBRATION Cont'd
Sol'n H 8MS-VOA-STD-6___________________________________________ Method Volatile Organlca SW8260A Test Code 826SWA00
Initial Calibration D MSDA970917000000 calibration Date 09/17/97 00:00:00
Work Order It 9709429 Page 11
Instrument M5DA Analyst MER Reviewer APS
Analytes Chlorobenzene SPCC 1,1,1,2-Tetrachloroethane
1-Chlorohexane
Ethylbenzene
m&p-Xylene
Bromoform SPCC styrene
o-Xylene
trans-l,4-Oichloro-2-butene
1,1,2,2-Tetrachloroethane SPCC
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone. ug/L
1.672 0.5
1.640 5
0.550 0,5
0,519 5
0,731 0.5
0.740 5
0.870 0.5
0.819 5
1.011 1
0.992 10
1,669 0.5
0.978 0.5
0.120 1
0.536 0,5
1.663 5
1.007 5
0.116 5
0.540 5
Response Factor
Reference Cone. ug/L
1.636 20
0.530 20
0,777 20
0.007 20
0.985 40
1.683 20
0.994 20
0.134 20
0.554 20
Response Factor
Reference Cone. ug/L
1.725 50
0.554 50
0.819 50
0.858 50
1.048 100
1.741 so
1.041 50
0.137 50
0.549 50
Response .Factor Reference
Cone. ug/L
1,006 100
0.589 100
0.079 100
0.893 100
1.072 200
1.839 100
1.102 100
0.144 100
0.561 100
Response
Reference Cone. `
Response
Reference Cone.
Correlation
RF
\ RSD
Coefficient
1.70
4.20
0.540
4.90
0,709
7,74
0.849
4,21
1.02
3.65
0.999
1,72
4,30
1.02
4.80
0,130
9.06
0.548
1.06
00 A 049719
conftdfnttai
09/29/97 ,,'09t36
INITIAL
CALIBRATION Oont'd
Sol'n ft ftMS-VOA-STD-6___________________________________________ Method Volatile Organics SW8260A Test Code 926SWAP0
Initial Calibration ft MSDA970917000000 Calibration Date 09/17/97 00:00:00
Work order ft 97lr>29 Page 12
Instrument MSDA Analyst MER Reviewer APS
Analytes 1,2,3-Trichloropropane Isopropylbenzene Bromobenzene 2-Chlorotoluene n-Propylbenzene 4-Chlorotoluene 1,3,5-Trimethylbenzene 1,2,4-Trimethy1benzene tert-Butylbenzene 1,3-Dichlorobenzene
Response Factor
Reference Cone, ug/L
Response Factor
Reference Cone. ug/L
0-365 0,5
0.361 5
2.542 0.5
2.325 5
0.776 0.5
0.759 0.5
0.009 0.5
0-759 0.5
0.802 5
0.731 5
0.791 5
0.770 5
2.629 0.5
2.428 5
2.625 0.5
2.426 5
2.276 0.5
2,188 5
1.471 0.5
1.461 5
Response Factor
Reference Cone. ug/L
0.373 20
2.329 20
0.801 20
0.756 20
0.807 20
0.763 20
2.391 20
2.517 20
2.234 20
1.475 20
Response Factor
Reference Cone. ug/L
0,382 50
2.496 50
0.807 50
0.793 50
0,839 50
0.819 50
2.526 50
2.596 50
2.329 50
1.506 50
Response Factor
Reference Cone. ug/L
0.386 100
2,574 100
0.843 100
0.810 100
0.869 100
0.832 100
2.607 100
2.627 100
2.384 100
1.561 100
Response
Reference Cone.
Response
Reference Cone.
correlation
RF
% RSD
Coefficient
0.373
2.86
2.45
4.83
K>
to
00
0.806
0.770
4.09
0.823
3.77
0.789
4.34
2.52
4.19
2.56
3.37
2.28
3.38
1.49
2,72
DO A 0497P0
CDNFTDFNTTAL
09/29/97 17:09:36
INITIAL
CALIBRATION Oont'd
Sol'n # ttMS-VOA-STD-6___________________________________________ Method Volatile Organics SW8260A Teat Code 826SWA00
Initial Calibration It MSDA9709noooooQ Calibration Date 09/17/97 00:00:00
Work Order ft 9709429 Page 13
Instrument MSDA Analyst MER Reviewer APS
Analytes sec-Butylbenzene
1,4-Dichlorobenzene
Response Factor
Reference Cone, ug/L
Response Factor
Reference Cone. ug/L
3.383 O.S
3.086 5
Response Factor
Reference Cone. ug/L
3.100 20
Response Factor
Reference Cone. ug/L
3.334 50
Response Factor
Reference Cone. ug/L
3.391 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
1 RSD
Coefficient
3.26
4.69
1.00
p-Isopropyltoluene 1,2-Dichlorobenzene n-Butylbenzene l,2-Dibromo-3-chloropropane 1,2,4-Trichlorobenzene Naphthalene 1,2,3-Trichlorobenzene Hexachlorobutadiene
2,676 0.5
1.317 0,5
2,654 0.5
0.081 2
0.805 0.5
1,481 0.5
0.639 O.S
0.377 0.5
2.462 5
1,340 S
2.462 5
0.076 5
0.758 5
1.539 5
0.682 5
0.301 5
2.473 20
1.341 20
2.487 20
0.095 20
0.791 20
1.610 20
0.718 20
0.313 20
2.624 50
1.413 50
2.595 50
0.098 50
0.834 50
1.658 50
0.739 50
0,337 50
2.744 100
1.447 100
2.684 100
0.098 100
0.858 100
1.665 100
0.752 100
0,350 100
2.60
4.60
1.37
4.05
2.58
3,83
0.0896
11.6
0.809
4.77
1.59
4.98
0.706
6.50
0.336
8.98
00 A 049771 OONFTOFNTTAl
09/29/97 ...09:36
Sol'n ft ftMS-VOA-STP-6________________ Method Volatile Organics SWB260A Teat Code 826SWAOO
INITIAL
CALIBRATION Coat'd
Initial Calibration ft MSDA970917000000 Calibration Date 09/17/97 00;00:00
Work Order It 970^9 Page 1*
Instrument MSDA Analyst MER Reviewer APS
Analytes l-Bromo-2-chloroethane
Response Factor
Reference Cone. ug/L
Response Factor
Reference Cone. ug/L
0,297 0.5
0.325 5
Response Factor
Reference Cone. ug/L
0.321 20
Response Factor
Reference Cone. ug/L
0.323 50
Response Factor
Reference Cone. ug/L
0.311 100
Response
Reference Cone.
Response
Reference Cone.
Correlation
RF
t RSD
Coefficient
0.315
3.68
DO A 0497?? CONFTOFNTTAl
05/29/97 17:09:36
Method Volatile Organics SW8260A Test Code 826SWA00 Initial Calibration # MSDA970917000000 Calibration Date 09/17/97
ANALYSIS BATCH S0NMARY Analysis Batch ft MSMSDA709251B1601
Analysis Start Date/Time 09/25/97 18:16:00 Analysis Stop Date/Time 09/26/97 06:05:00
Work Order ft 9709429 Page 15
Instrument MSDA Analyst MER Reviewer APS
Sequence/Analysis Time
1 09/25/97 17:48:00 2 09/25/97 18:16:00 3 09/25/97 18:16:00 4 09/25/97 18:44:00 5 09/25/97 19:13:00 6 09/25/97 19:41:00 7 09/25/97 20:09:00 8 09/25/97 20:37:00 9 09/25/97 21:06:00 10 09/25/97 21:34:00 11 09/25/97 22:02:00 12 09/25/97 22:30:00 13 09/25/97 22:59:00 14 09/25/97 23:27:00 15 09/25/97 23:55:00 16 09/26/97 00:24:00 17 09/26/97 00:52:00 18 09/26/97 01:20:00 19 09/26/97 01:48:00 20 09/26/97 02:17:00 21 09/26/97 02:45:00 22 09/26/97 03:13:00 23 09/26/97 03:41:00 24 09/26/97 04:10:00 25 09/26/97 04:38:00 26 09/26/97 05:06:00 27 09/26/97 05:35:00 28 09/26/97 06:05:00
Project Sample ID DOW-VP-CLS-11-V1/V14
Lab Sample ID Sample Type
SB BFB VSTDCAL LCS976894 LCSD976895 BLK973847 9709346-01A 9709346-Q2A 9709346-03A 9709346-04A 9709356-01B 9709353'01A 9709353-02A 97093S3-03A 9709366-01A 9709366-02A 9709366-03A 9709366-04A 9709366-05A 9709366-06A 9709395-03A 9709395-01A 9709395-02A 9709449-18A 9709455-18A 9709454-18A 9709444-18A 9709429-15A
Blank, System GC/MS tune files Continuing Calibration Verification Lab Control Sample Lab control sample Duplicate Blank, Method Sample Matrix Spike Matrix Spike Duplicate Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample Sample
Analysis File (t
A0925701 A0925702 A0925702 A0925703 A0925704 A0925705 A0925706 A0925707 A0925708 A0925709 A092S710 A0925711 A0925712 A0925713 A0925714 A0925715 A0925716 A0925717 A092S718 A092S719 A0925720 A0925721 A0925722 A0925723 A0925724 A0925725 A092S726 A0925727
DO A 04^7^3 CONFIDFNTTAl
09/29/:. *7:09:36
Extraction Batch # Analysis Batch
lllli. f S MSMSDA70925181601
Work Order 970942? Page 16
Project Sample ID D0W-VP-CLS-11-V1/V14 Lab Sample ID 9709429-15A COMPOS File II A092S727 Method Volatile Organics 5W8260A Test Code B26SWAVP
Date Collected 09/17/97
Date Received 09/19/97
Date Prepared
________
Date Analyzed09/26/97 06:05:00
Instrument MSDA
Column
Analyst MER
Reviewer
APS
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor
10
Analyte
Chlorobenzene 1,1,2-TrIchloroethane
CAS #
108-90-7 79-00-5
Measured Concentration ug/L
ND ND
Reporting Subset spikes Subset ___ Specs Subset ____
Matrix H Report As received % Moisture _________
Detection Limit ug/L
0.968 1.47
Reporting Limit ug/L
0 0
Surrogate(s)
1,4-Bromofluorobenzene 112-Dichloroethanej-d4 Toluene-d8
CAS ft
460-00-4 17060-07-0 2037-26-6
Spiked Cone. ug/L
167 167 167
Measured Concentration ug/L
159 171 164
Recovery %
95 103
98
Specification Limits
Low %
High %
77 117 61 143 87 113
DO A 049724 GONFTDFNTTAt
09/29/97 17:09:36
LABORATORY BLANK INFORMATION
Extraction Batch 9 Analysis Batch 9 msmsda70925181601
Work Order 9 9709429 Page 17_
tjih fiamole TD BLK973847 Pile # A092570S Method Volatile Oroanics SW8260A Test Code 826SWAVP
Date Prepared Date Analyzed Q?/2S/J7 19:41:00
Instrument MSDA Column Analyst MER Reviewer APS
Reporting Subset Spikes Subset specs Subset ____
Matrix W
Aliquot Mass/Volume
15.0 (mL)
Extract/Digestate Volume
15.0 (mL)
Dilution Factor
1
Analyte
Measured Cone. ug/L
Detection Limit ug/L
Reporting Limit ug/L
Chlorobenzene 1,1,2-Trichloroethane
ND 0.0968
0
ND
0.147
0
Surrogate(s)
1,4-Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8
Spiked Cone. ug/L
16.7 16.7 16.7
Measured Cone. ug/L
16.3 16.9 16.7
Recovery %
98 101 100
Specification Limits
Low %
High t
77 117 61 143 87 113
09/29/97 17'.. .36
LABORATORY CON i'A OL SAMPLE Extraction Batch (t Analysis Batch # MSMSDA70925181601
Work Order * 970929 Page 18
Method Volatile Oraanics SW8260A Test Code 826SWAVP
Date Prepared Date Analyzed 09/25/97 19:13:00
Instrument MSDA Column Analyst MER Reviewer APS
Reoortinq Subset SDikea Subset Specs Subset __ ____
Matrix w Renort Aa received % Moisture Aliquot Mass or Vol Extract Maas or Vol
15.0 (mL> 15.0 (mL)
Control Std, ft LCS1 LCS2
Vol. Added
5.0
UL
S.O uL
Surrogate Sol'n ft 1.2-DCA-d4 Toluene-d8 1.4-BFB
Vol. Added 1 uL 1 uL 1 uL
Analyte
Chlorobenzene 1,1,2-Trichloroethane
>,
LCS Lab Sample ID
LCS976894 Pile II> A0925703
Spiked Cone. ug/L
Measured Cone. ug/L
20.0 20.0
20.7 20.4
LCS Duplicate Lab Sample ID
LCSD976895 File II) A0925704
Rec. %
Spiked Cone. ug/L
Measured Cone. ug/L
103 20.0 102 20.0
21.1 21.2
Recovery Spec.
Limits
RPD
Rec. %
Low High Result
%%
%
Spec. Limit
t
105 77 129 106 67 135
1.9 14 3.8 17
Surrogate(s)
1,4-Bromofluorobenzene 1,2-Dichloroethane-d4 Toluene-d8
16.7 16.7 16.7
15.9 16.4 17.2
95 16.7 98 16.7 103 16.7
16.2 16.6 17.0
97 77 117 100 61 143 102 87 113
DO A 049776 GONFTDFNTTAI
09/29/97 17:09:36
MATRIX SPIKB(S) Extraction Batch S ___________________________
Analysis Batch # MSMSDA70925181601
Work Order # 9709929 Page 19.
Project Sample ID ___________________ Method Volatile Organics SW8260A Test Code 826SWAMS
Date Collected Date Received Date Prepared Date Analyzed
09/17/97 09/18/97
_______ 09/25/9721:06:00
Instrument MSDA Column Analyst MER
Reviewer APS
Reporting Subset Spikes Subset Specs Subset
Matrix W Report As received % Moisture __________
Spike Sol'n If LCS1 LCS2
Vol. Added 1^. uL S. 0 uL
Surrogate Sol'n 1,2-DCA-d4 Toluene-d8 1.4-BFB
vol. Added 1 uL 1____ _ uL 1 uL
Sample
Lab Sample ID
9709346-01A
File A0925706
Aliquot Mass/Vol
15.0
(mL)
Extract Mass/Vol
15.0
(mL)
Dil Fact.
1
Spiked Sample
Lab Sample ID
9709346-02A MS
File It A0925707
Aliquot Mass/Vol
15.0
(mL)
Extract Mass/Vol
15.0
(mL)
Dil Fact.
1
Spiked Sample Dup
Lab Sample ID
9709346-Q3A MSD
File ft A0925708
Aliquot Mass/Vol
15.0
(mL)
Extract Mass/Vol
15.0
(mL)
Dil Fact.
1
Recovery Specification Limits
RPD
Analyte
Spike sol'n Cone.
ug/L
Measured Cone. ug/L
Spiked Cone. ug/L
Measured Cone. ug/L
Rec. %
Spiked Cone. ug/L
Measured Cone, ug/L
Rec. %
Low High %%
Result %
Specification
Limit %
Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene
200000 200000 200000 200000 200000
NO ND ND ND 3.06
20.0 20.0 20.0 20.0 20.0
21.6 21.0 24.3 21.8 25.2
108 105 122 109 111
20.0 20.0 20.0 20.0 20.0
22.6 21.7 26.0 22.2 26 * 9
113 71 108 77 130 47 111 70 119 71
133 129 175 132 129
4.5 2.8 6.4 1.8 7.0
17 14 25 17 17
Surrogate(s)
1.4-Bromofluorobenzene 1,2-Dichloroethane-d< Toluene-da
250000 250000 250000
15.7 17.3 16.4
16.7 16.7 16.7
15.2 16,3 16,7
91
16.7
15.5
98
16.7
16.3
100
16.7
17.0
93 77 98 61 102 87
117 143 113
00 A 049777 CONFTOFNTTAl
09/29/If ,:09:36
COHTIHOIHQ<OR DA . .. T ) CALIBRATION VERIFICATION
Analysis Batch tt MSMSDA7092S1B1601 Initial Calibration tt MSDA970917000000
Work Order If 9709429 page 20
y
Lab sample ID VSTDCAL
Date Analyzed 09/25/97 18:16:00
File It A0925702___________
Method Volatile Organics SW8260A
Test Code 826SWA00
Reporting Subset ____ Spikes Subset -----Specs Subset ------
Instrument MSDA Analyst MER Reviewer APS
Analyte
Measured Concentration
ug/L
Reference Concentration
ug/L
Recovery %
Recovery Specification
Limits
Low t
High %
Acetone Acetonitrile Acrolein Acrylonitrile Benzene 1 -Bromo-2 'chloroethane Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone(MEK) n-Butylbenzene sec-Butylbenzene tert'Butylbenzene Carbon disulfide Carbon tetrachloride 2-chloro-l,3-butadiene Chlorobenzene Chloroethane 2-Chloroethyl vinyl ether Chloroform 1-Chlorohexane Chloromethane 3-Chloropropene
18,3 88.8 91.4 20.9 21.0 20.3 22.0 19-6 21.0 17.0 17.1 19.6 20,9 21,5 22.7 20.3 21.1 20,7 21.0 18.0 13.2 20.8 20-3 14.4 21.6
20.0 100 100 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
92 89 91 104 105 102 110 98 105 85 86 98 105 108 113 102 105 104 105 90 66 104 102 72 108
80 120
0497?^
DO A DfrMTf AV.
OONF T
09/29/97 17:09:36
CONTINUING (OR DAILY) CALIBRATION VERIFICATION (Coat'd)
Analysis Batch MSMSDA70925181601 Initial Calibration MSDA970917000000
Work Order * 9709429 Page 21,
Lab Sample ID VSTDCAL
Date Analyzed 09/25/97 18:16:00
File H A092S702___________
Method Volatile Organics SW9260A
Test Code 826SWA00
Reporting Subset Spikes Subset ___ Specs Subset __
Instrument MSDA Analyst MER Reviewer APS
Analyte
Measured Concentration
ug/L
Reference Concentration
ug/L
Recovery %
Recovery Specification
Limits
Low %
High %
2-Chlorotoluene 4 * Chlorotoluene 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dlbromoetharte Dibromomethane trans-l,4-Dichloro-2-butene 1,2'Dichlorobenzene 1,3-Dichlorobenzene l,4-Dichlorobenzene Dichlorodifluorome thane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene ciB-l,2-Dichloroethene trans-l,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-l,3-Dichloropropene Ethyl methacrylate Ethylbenzene Hexachlorobutadlene
22.3 22.0 17.2 19.8 14.3 21.1 13.7 21.6 21.4 20.6 11.3 21.3 21.2 21.7 20,1 19.5 20.9 19.5 23.3 22.7 16.5 18.0 21.6 20.3 21.0
20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0
ill 110
86 99 71 105 68 108 107 103 57 106 106 109 101 97 105 98 117 114 82 90 108 102 105
80 120 80 120
80 120
HO A 049779 OONFTDFNTTAl.
09/29/9 r r7:09:36
CONTINUING (OR DAILY) CALIBRATION VERIFICATION (Cont'd)
Analysis Batch I MSMSDA7092S181601 Initial Calibration * MSDA970917000000
Work Order # 9709429 Page 22
Lab Sample ID VSTDCAL
Date Analyzed 09/2S/97 18:16:00
File ft A09257Q2
Method Volatile Oraanlca SW8260A
Test code 826SWA00
Reporting Subset Spikes Subset ___ Specs Subset ___
Instrument MSDA Analyst MER Reviewer APS
Analyte
Measured Concentration
ug/L
Reference Concentration
ug/L
Recovery %
Recovery Specification
Limits
Low %
High t
2-Hexanone Iodomethane Isopropylbenzene p-Isopropyltoluene Methyl methacrylate Methyl t-butyl ether 4-Methyl-2-pentanone(MIBK) Methylene chloride Naphthalene Propanenitrile n-Propylbenzene Styrene 1,1, l,2-Tetrachloroethane 1,1,2a 2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trlchloroethane 1,1,2-Trlchloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,1,2-Trichlorotriluoroethane
16.2 17.0 19.6 20.3 21.8 19.6 18.1 19,2 20,1
103 21.1 19.6 19.2 21.1 22.3 18.5 21.7 22.1 21.6 21.1 22.0 21,5 20.0 20,1 21.0
20.0 20.0 20.0 20.0 20.0 20,0 20.0 20.0 20.0 100 20.0 20.0 20,0 20.0 20.0 20,0 20.0 20.0 20.0 20.0 20,0 20,0 20.0 20.0 20.0
81 85 99 102 109 98 91 96 101 103 105 98 96 106 111 92 108 110 108 106 110 108 100 101 105
80 120
D0 A 049730 CONFTDFNTTAL
09/29/97 17:09:36
CONTINUING (OR DAILY) CALIBRATION VERIFICATION (COnt'd)
Analysis Batch It MSMSDA70925181601 Initial Calibration 8 MSDA970917000000
Work Order * 9709429 Page 23_
Lab Sample ID VSTDCAL Pile 8 A0925702___________ Method Volatile Organics SW8260A Test Code 826SWA00
Date Analyzed
09/25/97 18:16:00
Reporting Subset Spikes Subset ___ Specs Subset ____
Instrument MSDA Analyst MER Reviewer APS
Analyte
Measured Concentration
ug/L
Reference Concentration
ug/L
Recovery %
Recovery Specification
Limits
Low %
High t
1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate vinyl chloride m&p-Xylene o-Xylene
21*9 22.9 26.0 17,0 41.3 20.5
20.0 20.0 20.0 20.0 40.0 20.0
109 115 130
85 80 120 103 102
Surrogate(s)
1,4-Bromofluorobenzene 1,2-Dlchloroethane-d4 Toluene-d8
15.8 16.3 16,9
16.7 16.7 16.7
95 77 117 97 61 143 101 87 113
D0 A 049731 CONFTOFNTTAl
09/29/97 17. j6
Method Volatile Organics SW8260A Specification#
Lab Sample ID File ID
Project Sample ID/Description
Analyte
ANALYTICAL l-OTOCOL SUMMARY COMMBNTS/NARRATIVB
Work Order I) -y /09429 Page 24.
Flag Comment/Narrative
Corrective Action
DO A 04973? OONFTDFNTTAl