Document X87x6adek5na7J00MOykmX18B

substance/formula 2,2'-I minodiethanol, see Diethanolamine H79. 5-lndenol TM CgHiQO W*t. DiePOMI uv lACflfK) ttPPA itKM lyibm Pro- PPM caduM ISdeVl/ fmWM3) j Hdttlh PiW. React. Ignit. , Vap. .81. Pt. Tamp. Flam. BP- MJ*. Sol..in Sp. Pan*,; . C C Limits : c C HoO Other Gr. ,(Ailf*=1) tJbP) (F) *% cfi ' ("F) #/i9<i* .Solvents , Misc.-flef, *\ >! 18 L,, 255 (491) 58 (131) sl.sol, ale. ; :. r 550. indium In ggl. Industrial Gas (Liquefied Hydrocarbon Gas) gg2 Iodic Acid HIO3 27k 3 18 - 24b J ;>4 - 3 2 - 2- 7.3 4.63 - -108 (-162) 2000 155 insol. (3632) (311) tIOdec. 286,'8 (230) alo. NTTC 583. Iodine '2 584. Iodine Chloride ICI 12* IQ 21 3 32 4.93 -s 3.18 184 (363) 113 (235) .0320 ale., bz., C$2 97 (207) 14*27 (57-81) dec. V- 8DH, NSC BDH 535. Iodine Pentafluoride IF5 21 3 3 3.75 - 98 9.6 dec. (208) (49) MGB , 586. Iodine Trichloride ICI3 537. (odoacetie Acid C2H3IO2 lodoethane, see Ethyl Iodide iodomethane, see Methyl Iodide **V ' ' '* 3 1 - , kv - "SJV 'mf ' 7' n ( v "S- ^ `I v* Jjjlp ' '/'"V If , V- j "V-, -B .4*. >v Jw ' " - ">' ... ' 3.12 77dec. 101 dec. 41c., bz. BDH (171) (214) , . <816 atm. - dec. 82 sol. 3 ic. (180) *' '""T-, VdSt1 yOtr r.S'v-T'P'.- 1 CMA 045869 SUBSTANCE/FORMULA 3-lodoprOpene, see Ally) Iodide 588. Isoprene CH2C(CH3)CHCH2 Isothiocyanic Acid, see Methyl Isothiocyanate 589a Jet Fuel JP-1 589b Jet Fuel JP*4 589c Jet Fuel JP*5 589d Jet Fuel JP-6 590 Kerosene 591. Ketene ch2co 592. Lactonrtrile CH3CH(OH)CN 593. Lamps, Fluorescent 594. Lanthanum La Waste Dj* posal Pro* cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. (gmt. Vap. FI. Pt. Temp. Flam. B.P, Sp. Dens. C C Limits 6C Gr. (Air=1) <F) (F) % <F) M.P. C <F) Sol. in HtO g/lOOg Other Solvents Misc. R ef 18 2 4 1 .68 2.35 -54 220 34 -147 insol. ale. (-65) (428) (93) (-233) 18 0 2 0 35*63 (95*145) 228 (442) <-46 (<--50) NTTC 18 1 3 0 23*1 M0-30) 242 (468) <-46 K-50) NTTC_ 18 0 2 0 35*63 (95*145) 246 (475) <-46 (<--50) -- NTTC 'f 18 .8 <i 38 224 .6-3.7 121 <-46 NTTC (100) (435) (250) -50) ^i 18 0 2 0 .81 4,5 38*66 229 .7-5 170-300 <-46 (100-150) (444) (338*572) -50) NTTC 1 18 .5 3 1.45 -56 -151 (-69) (-240) dec. dec., ale. > 14 32 .99 2.45 77 (171) 26 - 27k 13 6.15 I82dec. (360) -40 (-40) 06 cs2 3470 (6278) 920 (1688) dec. 1 < K * .w CMA 045870 substance/formula g5. Lacquer Diluent 07 Laurie Acid CH3<CH2)ioCOOH 6g8. Lauroyl Peroxide (Cl1H23c0>202 599. Lead Pfa 600 Lead Acetate Pt>lC2H3O2)2'2H20 601, Lead Araenate PbHAs04 602. Lead Carbonate (PbC03>2 Pb(OH)2 603. Lead Nitrate Pb(NQ3)2 604. Lead Oxide PbO 605. Lead Thiocyanate Pb(SCN)2 606. Ligroio Waste Oispoiat Procedure (See VI) TLV (ACGIH) PPM (mg/M*) NFPA 704M System Health Fire React. 18 3 0 Sp. Gr. .7 26 2 24a 1 .87 22h 0 2 3 27a (.2) 27f 27d (.15) 3 3 3 2 11.3 3.25 7.80 27f 3 61,4 27f 1 0 1 4,53 27f 31 ~9,5 27f 1 1 1 3.82 18 fii l Jj ^ >< FI. Pt. C (F) Igmt. Temp. C (eF) B.P, C lF) M.P. C (F) Sol, in HjO 8/100 Other Solvents -11 232-88 1.2-6 (12) (450-550 88-107 (190-225 ' Miic. Ref 299 (570) - 48 (118) insol. ale., bz. 49 (120) insol. 1744 (3171) 327 (621) insol. 75 (167) 4420 NTTC NFPA 720dec insol. (1328) 400dec. insol. (752) 470dec. 38 (878) ale. 888 insol. (1630) BDH, MCA <22 (<721 - 190dec. insol. (374) BDH 4 .1 PAGE 69 CMA 045871 SUBSTANCE/FORMULA Limonene, see Dipentene see p-Moutha-1,8-Diene 607. Lindane c6h6ci6 608. Liquefied Petroleum Gas (LPG) 609. Lithium Li 610, Lithium Aluminum Hydride LiAIH4 611. Lithium Borohydride L1BH4 612 Lithium Carbonate U2CO3 613. Lithium Hydride *LiH 614. Lutecium Lu 615 2,6-Lutidine (CH3)2C5H3N 616. Magnesium Mg 617. Magnesium Chlorate MgiCI03)2.6H20 Waste Dis posal Pro cedure (See VI) TLV (ACGIHI PPM (mg/M3) NFPA 704M System Health Fire React. Ignit Vap. FI. Pt. Temp, Flam. B.P. Sp. Dens. <*c *C Limits C Gr. (Air^l) 1F> (R % (F) M.P. C (F) Sol. in H2O g/IOOg Other Solvents Misc. R*f 4b (.5) 3 18 1000 3 1.87 - 3 1 1 2 .53 17 3 1 2 .92 17 11 17 (.0251 27k 2 1 .66 | j i1 1 - 1 2.11 ' 1 4 2 | .82 1 2 9.84 - May Ignite Spontan* eousiy 7a 92 3.7 38-46 (100-15) 27a 0 1 2 1.74 12a 2 3 1.80 288 (550) 157 (315) msol. ace., bz. <-46 <<--SO) ISITTC 1337 (2437) 179 dec (354) Al A BDH, NSC 125dec. dec. (257) BDH, NSC 284 (543) dec 1310dec 723 (2390) (1333) si. so). BDH, NSC 680 (1256) dec BDH 3327 (6020) 1652 (3006) 144 (291) -6.6 (20) 00 si. sol., ale. BDH 1107 651 (2025) (1204) deCil00 120dec. (248) 35 (95) 129' ale. AIA CMA 045872 SUBSTANCE/FORMULA gig. Magnesium Chloride MgCl2 Magnesium Nitrate Mg(N03)2 2H2)0 520 Magnesium Oxide MgO 021 Magnesium Perchlorate Mg(Cl04)2 022. Malathion C)0H196pSj 623. Maleic Acid HOOC(CH>2COOH g24 Maleic Anhydride {COCH)2Q 025 Manganese Mn g26 Manganese Sulfate MnS04 627 p'Mentha-l, 8-Diene Clovis Mercaptoacetic Acid, see Thioglycolic Acid 628. 2-Mercaptoethanol HSCH2CH2OH Waste Dis posal Pro cedure ISea VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React, 11 1 Sp. Gr. 2.32 V*p, Dens. lAirsI) FI. Pt. C (*F> Ignit. Temp. C (F) Flam. Limits % B.P. C (F> M.P. C (F) Sol. in H2O g/IOOg 1412 (2574) 708 (1306) 5420 Other Solvents ale. Misc. Ref. 11 1 0 1 2.03 330dec (626) 129 (264) sol. ale 26 115) 2 3 65 3600 -2600 SI.sol (6512) (4712) 12a 1 0 1 2 6 25ldec. (464) 5025 ale 7ta 24a 115) Skin 3 2 1 1 23 1 59 40 156 (313) @ 7mm 135dec (275) 2.9 (37) sl sol ale., bz v. sol ale., ace ether 24a ( 25) 3 1 1 9 3 4 102 477 1.4-7 1 202 58 dec ace (216) (890) (396) (127) AlA, MCA 27a (5)C 2 2 7 2Q 2030 (3686) 1260 (2300) dec 11 2 3 25 850dec. 700 (1562) (1292) 525 ale 18 2 0 3.84 74 45 237 7-6.1 170 <60 inso) (113) (458) (338) l<140> 13 22 1.14 2.69 74oc (165) 157 (315) sol ale PAGE 71 CMA 045873 substance/formula Waste Dis posal Pro cedure (Sm VI) TLV (ACGIH) PPM <mg/M3) NFPA 704M System Health Fire React. 629. Mercuric Chloride HgCI2 630. Mercury Hg 27b 27b Skin 3 3 631. Mercury Compounds (organic) 27b (.01) Skin 3 631a. Mercury Compounds (inorganic) 27b Ignit. Vap. FI. Pt. Temp. Flam. Sp. Dens. C *C Limits Gr. (Air=1) lF) I"F) % 5.44 13.6 B.P, C <F) 304 (579) 357 (674) M.P, C (F) 277 (531) Sol. in HjO j g/lOOg 6920 Other Solvents ale. jj Mtsc. Rtf -39 (-38) insol ! AIA, SDH ! NSC BDH 632. Mercury Fulminate HgC2N202 -----------------------------------------------------------------1 633 Mesityl Oxide CgHioO 27b 18 633a Metal Scraps 26 25 3 3 3 3 4 42 0 .86 3.5 31 (88) 344 (652) exp. si. sol ale. 130 (266) -59 (-74) sol, ale. NSC ! BDH 1 634, #`Methacrylic Acid CH2C(CH3)COOH 635. Methane ch4 636 Methanesulfonic Acid CH4O3S 24a 18 4c 3 2 2 1.02 77oc (171) 158 (316) 16 (61) sol. ale. 1 4 0 .42 .6 537 (999) 5-15 -161 -183 si. sol, (-258) (-297) bz 1.48 167 (333) 20 (68) v. sol ale. Methanethiol, see Methyl Mercaptan 637. Methoxychlor (DMDT) (CH3OCeH4)2CHCCt3 4b (15) 1 12 78 (172) insol. org. sol. 2-Methoxyphenol, see Guaiacoi 4-Methoxy Phenol, see Hydroqumone Monomathy! Ether PAGE 72 CMA 045874 SUHSTANCE/FORMULA 3-(3-Methoxypropoxy)-1propanol, see Dipropylene Glycol Methyl Ether ^^538 Methyl Acetate CH3CO2CH3 Methyl Acetylene, see Propyne 639 Methyl Acrylate CH2CHCOOCH3 Methylal, see Dimethoxymethane 640. Methyl Alcohol CH3OH Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM tmg/M3) NFPA 704M System Health Fire React. 18 200 1 30 18 10 2 3 2 Skin 18 200 1 30 p-Methylaminophenol Sulfate, see 6 Ion 641. Methyl Amyl Alcohol (CH3)2CHCH2CHOHCH3 642 Methyl-n-Amyl Ketone CH3(CH2)4COCH3 N-Methylanitine, see o-Toluidine 2'Methylaziridine, see Propylemmine 643 6-Methyl-l, 2-Benzanthracene CisHiiCH3 18 18 18 25 Skin 100 2 1 Car 2 2 0 0 Igmt. Vap. FI. Ft. Temp. Flam. B.P. Sp. Dens, C C Limits Gr. |Air=1) PF) PFI % PF| M.P. C PF) Sol. in H2O fl/IOOg Other Solvents Mi$c. Ref. 97 2 55 -9 502 3.1-16 57 -99 v. sol. ale. (15) (935) (135) (-146) BDH 95 3.0 --3oc (27) 2 8-25 80 (176) '75 si. sol. (-103) ale CED. MCA 79 Ml 12 (54) 464 (867) 6-36 5 65 (149) -98 (-144) w ale., ace. Al A, BDH, MCA, NSC 80 3.5 Si 3.9 41 (106) 1-5.5 130 (266) <-90 st. sol K-1301 ale. 49oc (120) 533 (991) 151 (304) -35 (-31) si sol. ale. 150 (302) tnsol CS2 PAGE 73 SUBSTANCE/FORMULA Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. 644 10-Methyl-l, 2-Benzanthracene Cl8HnCH3 18 CAR tgnit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C c Limits C Gr. (Air=1) ("Ft ("FI % ("FI M.P. "C ("FI Sol- in M2O 9/10Og Other Solvents Miic. 141 insol (286) ale ace., CS2 645 Methyl Benzoate 18 0 2 0 1.09 4.69 83 C6H5C02CH3 (181) 200 (392) -13 (8.6) insol ale,, MeOh 646 a-Methylbenzyl Alcohol C6H5CH(CH3)QH 18 1 1 0 1.02 4.21 96 (206) 203 (397) 21 (70) si. sol. 647. Methyl Bromide CH3Br $48 2-Methyl-1 -Butene C5H10 649. 2-Methyl-2*Butene c5h10 4b 20C 3 1 0 1.73 3.27 Skin 537 (999) 10-16 4 (40) -95 (-139) msol. ale., CS2 A| A,BDh MCA.MGB 18 2 4 0 .66 2.4 <-7 (<-201 39 (102) -134 (-209) msol. 18 2 30 67 2,4 <-7 l<20) 38 (100) -123 (-189) si sol ale 650. 3*MethyM-Butene C5H10 651 N-Methylbutylamine CH3(CH2)3NHCH3 18 7a 2 4 0 67 2.42 <--7 365 1.5-9.1 20 -63 msol ale. (< 20) (689) (68) (-90) 3 30 74 3.0 l3oe (55) 91 (196) sol. 652 Methyl Butyl Ketone CH3OC(CH2)3CH3 IS 1Q0 2 30 81 3,45 35qc 533 1 2-8 126 -67 (95) (991) (259) (-71) ale. 653 Methyl Butyrate CH3COOC3H7 18 2 3 0 .90 3,53 14 (57) 102 (216) <-97 si sol -- 143) ale. 654. Methyl Cellosolve H3C-0*CH2*CH20H 18 25 2 2 0 .97 2 62 46 288 2.5-14 125 -87 bz 5km (115) (551) (257) (-125) BOH 655 Methyl Cellosolve Acetate CH3COOCH2CH20CH3 18 25 3 Skin 2 1.01 4.07 56 (132) 394 (740) 1,7-8,2 145 (293) -70 (-94) sol PAGE 74 CMA 045876 SUBSTANCE/FORMULA Methyl Chloride CH3CI W Methyl Chloroform, see 1, 1, 1-Tnchloroethane Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM tmg/M3) IWFPA 704M System Health Fire React. 4b 100C 2 4 0 tgn<t. Vap. FI. Pt. Temp. Flam. B.P. Sp* Dens, C Limits C Gr. (Air=1) (F> ("FI % ("FI M.P. *C (F) Sol. in H2O g/100g Other Solvents 0 98 1.8 632 10.7-17.4 "24 (1170) (-11) -98 (-144) S) SO), ale. Misc. Ret. MCA, MGB 557 Methyl Chloroformate CICOOCH3 558 3-Methyl Cholanthrene C21h16 Methyl Cyanide, see Acetonitrile 4b 18 3 CAR 1,24 3.26 1.28 12 (54) 604 (940) 71 (160) 280 (536) p>80mm 180 (356) dec. ale., bz BDH 559. Methyl Cyclohexane c6HnCH3 18 550 (7-Methyl Cyelohexano! CH3C6H10OH 18 56I 2-Methyl Cyclohexanone CH3C5H9CO 18 562 4-Methyl Cyclohexene c6h9ch3 18 663 3>Methy(-4-Dimethy1aminoazoBenzene C15H17N3 8 664 Methylene-Bi-Phenyhsocyanate OCNC6H4CH2C6H4NCO 8 Methylene Chloride, see Dichlorometbane 500 2 100 3 100 Skin . 3 1 CAR 3 2 2 3 0 77 0 92 it0 .92 0 80 3.39 -4 125) 285 (545) 3.93 68 (154) 296 (565) 3,86 48 (118) 3 34 -loc (30) 1 2- 100 (212) -126 (-195) insol. ale 165 (329) -20 (-4) Si. sol ale. 165 (329) insol. elc. 103 (217) -116 (-177) insol. die. 1 19 194-9 (381-901 @> 5mm 37 (99) BOH BDH BDH PAGE 75 CMA 045877 SUBSTANCE/FORMULA Methylene Chlorobromide, see Bromochloromathane Methylene Di-p-Phenylene Isocyanate, see Methylene Biphenyl Isocyanate 665 Methyl Ether CH3OCH3 Waste Oi$* posal Pro cedure (See V|| TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens, 6C C Limits C Gr. (Ar=l) (F) (F) % (F) M.P C (F) Sol. in H2O g/100g Other Solvents Mt$c. 15 3 4 0 66 1.56 -41 350 3.4-18 -24 -139 sol ale MCA (--42) (662) (-11) 1-218) 666. Methyl Ethyl Ether CH3QC2H5 15 24 73 2 07 -37 190 2-10 1 (-351 (374) 11 (52) sol ale. 667. Methyl Ethyl Ketone CH3COCH2CH3 18 668. Methyl Ethyl Ketone Peroxide CH3CO2C2H5 22b 669 Methyl Ethylmtrosocarbamate C4H8N2O3 4a 670. Methyl Formate HCOOCH3 18 671 2-Methyl Furan C5H6O 18 200 100 1 2 CAR 2 2 3 2 4 3 0 81 2 5 -7 515 2-10 BO -87 v. sol ale. bz AlA, BDH, (20) i960) (175) (-124) NTTC, MQa 4 52-93 (125-200) 1 lOexp, (230) sol ale NFPA . 0 99 2.1 -19 456 5.9-20 32 -100 v, sol. ale. (-2) (853) (90) (-148) 1 .92 2.8 -30 (-22) 63 (145) -89 (-128) msol ale BOH 5-Methyl`3-Heptanone, see Ethyl Amyl Ketone 672. Methyl Hydrazine CH3NHNH2 16 .2C Skin 9 1.6 <27 (<80) 87 (189) <-80 (<--112) sol ale. MCA 673 Methyl Iodide CH3I 4b 5 Skin 3 2.28 4 89 43 (109) -67 si. sol. ( -89) ale. BDH PAGE 76 CMA 045878 SUBSTANCE/FORMULA g74. Methyl Isobutyl Ketone CH3COCH2CH<CH3^2 1 675 Methyl Isobutyrate V (Ch3}2CHC02CH3 676. Methyl Isocyanate CH3N=C=0 077 Methyl Isothiocyanate CH3NCS 2-M Ethyllactonitrile, see Acetone Cyanohydrin Waste Dis posal Pro cedure (See VI1 TUV IACGIH) PPM (mg/M3) NFPA 704M System Heelth Fire React. 18 too 2 3 0 Ignit. Vap. FI. Pt. Temp. Flam. B.P, Sp. Dens. C C Limits C Gr. (Air=1) (F) <FI % (F) M.P, C lF) Sol. in HoO g/100g Other Solvents .80 3.5 23 (73) 460 (860) 1 .4-7 5 117 (243) -85 (-12V si. sol ale., b2 18 86 3.5 13oc 482 92 -84 si sol ale (55) (900) (198) (-119) 18 02 Skin 97 44 (1111 63 1.67 19 (246) 36 (97) si sol ale. Misc. Ref. MCA 678 Methyl Mercaptan CH3SH 13 679. Methyl Methacrylate CH2C!CH3)CQOCH3 18 680. 1-Methylnaphthalene C10H7CH3 18 631. 1-Methyl-2-Naphthylamme CH3CioHgNH2 5 682 N-MethyhN-Nitro$oaeetamide C3H6N2O2 6 683 N-Methyl-N-Nitrosoallylamine C4H8N20 6 10C 2 100 2 2 CAR CAR CAR 4 3 2 0 87 1.66 <-18 l<0) 3.9-21.8 7.6 (45) -123 (-189) si. sol. ale MGB 2 94 36 10 421 2.1-12.5 100 -50 si. sol ale. (50) (790) (212) (-58) 80H,MCA 0 1.03 528 (982) 240-3 -22 (464-9) (-7 6) insol. ale. 51 (124) org,solv. 684. N-Methyl-N-NitrosoamUne C6H5N(NO)CH3 6 CAR 1.13 255dec. (491) 15 (59) insol ale. PAGE 77 CMA 045879 substance/formula Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mp/M3) NFPA 704M System Health Fire React. 685 N-Methyl-N-Nitrosobenzyle* min* C3H1QN2O 6 CAR Igntt. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) lF) (F) % (F) M.P. C (F) Sol. in HjO g/100g Other Solvents Misc, R*f 686 1 -Methyl-1 -Nitrosourea H2NCON(NO)CH3 6 CAR 123dec. (253) insoi ale., bz 687 N-Methyl-N-Nitrosovtnylamin* C3H0N2Q 688. Methyl Parathion (Xylene solution) C10H10NO5PS 2-Methyl-2-Propanethiol, see t-Butyl Mercaptan 689 Methyl-n-Propyl Ketone CH3CO(CH2)2CH3 690. 1-Methylpyrrole CH3C4H4N 691 Methyl Salicylate HOC6H4COOCH3 692. a-Methyl Styrene c8h7ch3 693. m.-p-Mathyl Styrene CH2CHC6H4CH3 6 CAR 7b < 1) Skin 4 18 200 2 6 18 1 18 100C 1 18 100 2 3 3 3 1 2 2 3- 46 (115) . 0 SI 3.0 7 505 | 1 6-8.2 102 | -78 si sol ale (45) (941) (216) i ("108} 91 2.8 16 (61) 115 | (239) | insol ale. 0 1.18 5 24 101 454 (214) (8S0) 223 (433) -8,3 (IS) $1 sol ale. 1 92 4.08 54 574 1.9-6.1 167-70 -23 tnsol ale. (129) (1065) (333-8) (--9.4) 0 .39 4,08 57 494 .9 170 -83 (134) (921) (338) (-117) BDH NTTC Methyl Sulfate, see Dimethyl Sulfate Methyl Sulfide, see Dimethyl Sulfide PAGE 78 CMA 045880 substance/formula Methyl Sulfoxide, see Dimethyl Sulfoxide Waste Dis posal Pro* cedure fSee VI) TLV 1ACGIH) PPM (mfl/M3) nfpa 704M System Health Fire React. Ignit* vap, F|. Pt. Temp, Flam, B.P. Sp, Dans. aC C Limits C Or, (Air=1) iF) ("FI % ("FI M.P. C (Fl Sol, m HjO g/IOOg Other Solvents Mik. Rat |sj.Methyl-N'2,4.6-Tetranitro* WT aniline C7H5N5O8 095 Methyl-P'Tolueneeulfonate CH3C6H4SO3CH3 59g Methyl Vinyl Ether H2C=CH-0-CH3 097 Mixed Acids (HNO3+H2SO4I 6 19 15 24b 23 1 57 1.23 6 45 242 4 77 2.0 -51 (-60) None 187exp. 130 (369) (266) msol si. sol 27 (8D msot. bt , ale S -122 (46) (-188) si. sol org, solv None Vanes Vanes MCA 593, Molybdenum Mo 099 Molybdenum Compounds (Insoluble) 27a 26 (15) 1 2 102 5560 2622 (10040) (4751) 700 Molybdenum Compounds (Soluble) 11 (5) 1 701 Monochloroamine NH2CI 19 -66 sol. ale (-87) Monochlorobenzene, see Chlorobenzene 702. Monomethylamme CH3NH2 703. Morpholine C4HgNO 7a 10 3 4 0 11 -10 430 4.9*20.3 -6,3 -94 v. sol. ale. (14) (806) (21) (-137) BDH, MCA, MGB 5 20 2 3 0 99 3.00 38oc 310 Skin (100) (590) 128 (262) -4 9 (23) BO org. solv PAGE 79 CMA. 045881 SUBSTANCE/FORMULA Motor Fuel Antiknock Com pounds, see Tetraethyl Lead Waste Dis posal Pro cedure (See VI) tlv (ACGIH) PPM (mg/M3) NFPA 7Q4M System Health Fjre React. Muriatic Acid, see Hydrochloric Acid Mylone, see Crag 974 Ignit. Vap, FI- Pt, Temp. Flam. B,P. Sp- Dens, C C Limits Q Gr. (Air=1) <F) (F) % lF) M.P, C (F) Sol. in H2O g/IOOg Other Solvents Misc. Rtf 704 Naphtha (Coal Tar) 18 100 2 2 0 87 42 (107) 277 (531) 149-216 (300-421) NTTC Naphtha (Petroleum), see Petroleum Ether 705 Naphtha, Varnish Makers and Painters, 50Fla$h 18 1 3 0 <1 4.1 I 10 ! 232 9-6.7 116-43 . i 150) | (450) (241-89) j I I 706 Naphtha, Varnish Makers and Painters, High Flash 707 Naphtha, Varnish Makers and Painters, Regular 18 18 <11 3 0 4.3 I 29 1 (85) 232 (450) 1-6 139-77 (282-351 )| 1 3 0 <1 -2 (28) 232 (450) ,9-6 100-60 I (212-320)1 70S Naphthalene Cioh8 18 10 2 2 0 1 15 4.42 79 526 .9-5.9 210 80 insol. CS2 MCA (174) (979) (410) (176) ale , bz Naphthalene Ethylene, see Acenaphthene 709. 1-Naphtho! C10H7OH 18 2 1 1.10 288 (550) 96 (205) insol ale., bz. 710 2-Naphthol C10H7OH PAGE 80 18 21 1 22 4.97 153 (307) 295 (563) 123 (253) insol. ale., bz [ CMA 045882 CMA 045883 SUBSTANCE/FORMULA Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) NPPA 704M System Health Fire React. 722a. Nitrate'Nitrite Sait Baths (53% KN03,40%NaN02.7%NaN03) 11 722b. Nitrate-Nitrite Sait Baths (50%KNC>3,50%NaN02) 11 Nitrating Acid, see Mixed Acids 723 Nitric Acid HNO3 24b 2 20 1 724. Nitric Oxide NO 21 25 3 3 gnit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Ar=1) (F> (F) % lF) M.P. C (F> Sol. in H2O g/ioog Other Solvents 140 (285) 220 (428) 1 50 1 34 1 04 86 (187) -42 (-44) <x dec., aic. -153 -164 (-243) (-263) 1 3 ale. t Miic, R,f Jfl NSC ^ NSC ^ "1 Al A, BDH, NTTc MCA ` Al A, MGB ^ -- J 2,2',2"-Nitrilotriethanol, see Triethanolamine 1 725 3 Nitroacetophenone NO2C6H4COCH3 6 202 (396) 81 (178) v sol. ale. 726 m-Nitroanilin# NQ2C6H4NH2 6 31 1 18 306 (583) 114 (237) si. sol. ale., b* MeOH BDH ^ 727. O' Nitroaniime N02CgH4NH2 728. p-Nitroamhne NO2C6H4NH2 729 Nitrobenzene c6h5no2 7 30 0- Nitrobiphenyl c6h5c6H4N02 6 31 1 1.44 168oc 521 284 71 si. sol. ale., bz. BDH ^ (335) (970) (543) (160) 61 Skin 3 1 1 1 44 199 (390) 336 (637) 146 (295) insol ale., MeOH BDH. MCA ^ Al A, Jl 6 1 3 2 0 1 20 4.24 88 482 1 8- 211 5 si. sol. aic., bz. Skin (190) (900) @2000 F. (412) (41) BDH, MCA 1 6 CAR 2 1 0 1.44 6.9S 143 180 (290) (356) 330 (626) 35 (95) tnsoi. ale. P P CMA 045884 SUBSTANCE/FORMULA Nitrochlorobenzene, see Chloronitrobenzene Waste Dispoial Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. Igmt. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F) ("FI % (F) M.P. "C <F| Soi. in HjO g/IOOg Other Solvents Mite. Ref ^V3l Nitroethane CH3CH2N02 732. 2-Nitrofluorene C13H9NO2 733, Nitrogen N2 734, Nitrogen Dioxide N02 735. Nitrogen Fertilizer Solutions 4a 6 26 21 26 100 1 3 CAR 0 5C 3 0 3 1 05 2,58 28 415 3.4- 114 -90 sol. ale. (82) (779) (237) (-130) AIA, BDH 1.25 160 (320) insol. hot bz. -196 -210 (-321) (-346) 2 3 si. sol. ale. CGA 1.49 1.59 20 (68) -11 (12) dec chi,, CS2 AIA, MCA. MG8, NASA <-73 K-100) NTTC Nitrogen Tetroxide, see Nitrogen Dioxide 736. Nitrogen Trifluoride NF3 12a 10 3 3 1,59 -129 -209 (-200) (-344) si. sol 737, Nitrogen Trloxide NO3 738 Nitromethane CH3NO2 739. a-Nitronephthalene Cioh7no2 740. m-Nitrophenol NO2C6H4OH 26 3 1.45 3.5 (38) -102 (-152) eth. MGB 4a 100 1 3 4 1.14 2.11 35 418 7.3- 101 -28 sol. ale- 195) 1785) 1214) (-18) AIA 6 1 1 0 1.14 5.96 164 (327) 304 (579) 60 (140) insol- ale., CS2 63 1.2S 194 (381) <5>70mm 97 (207) si. sol. ale. BDH PAGE 83 CMA 045885 SUBSTANCE/FORMULA 741. o-Ntrophenol NO2C6H4OH 742. p-Nitrophenol NO2C6H4OH 743. 1-Nitropropane CH3CH2CH2NO2 744 2'Nitropropane CH3(N02)CHCH3 745. 4-Nitroquinoiine-N-Oxide NO2C9H6NO 746 N-Nitrosodiethylamine C4H10N2O 747. N-Nftro$odimethylamine C2H6N2O 748. N-Nitroso-N-MethyUniline C6HsN<NO)CH3 749 4'Nitrosomorpholine C4H9N202 750. I-Nitrosopiperaeine C4H9N2O 751. N-Nitrosopiparidine C5H1QN2O 752. Nitrosyl Chloride NOCI Wane Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. 63 Sp. Gr. 1.48 V*p, Dens. (Air=1) FI. Pt. C (F) Ignit Temp. C (F) Flam. Limits % B.P. C <FI 215 (419) M,P, C <FI Sol. m H2O g/IOOg Other Solvents 45 (113) si sol ale. 63 1.48 279 (634) 113 (235) si. sol ale 4a 25 1 2 3 .99 3.06 49oc 421 2.6- 131 -108 si, sol ale (120) (789) (268) (-162) 4a 25 1 2 3 .99 3.06 39oc 428 2.6- 120 -93 si sol. (103) (802) (248) (-135) 6 153 (307) 7a Miic. Rtf, BDH 8DH 7a CAR G 6 1.01 1.13 152 (306) sol. 25$dec (491) 15 (59) insol. ale. ale 6 6 12a 3 1.06 3.0 2.3 217 (423) sol -5.8 (21) -64 (-83) dec. MGB CMA 045886 SUBSTANCE/FORMULA 753. m-Nitrofolugne CH3C6H4NO2 V 754, o-Nitrotoluene ^ CH3C6H4NO2 755 p*Nitrotoluene CH3C6H4NO2 756 Nonyl Phenol C9HT9C6H40H 757. Octacbioronaphthalene CioC'8 758 Octafluoro-2-Butene F3CFOCFCF3 759 Octafluorocyclobutane C4pg (Freon-C3l8) 760 Octafluoropropane C3Fg 761 Octane CH3(CH2)6CH3 762 Octanoic Acid CH3(CH2)6COOH 763. 1-Octanol CH3(CH2)70H 764. 2-Octanol CH30HCH(CH2>5CH3 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) nfpa 704M System Health Fire React. G 52 Skin 2 Ignit. Vip. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Airsl) (F) (F) % ("FI 1 15 4.7 106 (223) 232 (450) M.P. C (F) Sol. <n Other Solvents 15 (59) iftSQl ale., bz Misc, Ref. 6522 1.16 4.72 106 (223) 220 (428) -4.1 (24) insol. ale. BOH 65 2 18 2 3 1.29 4n 106 (223) 0 95 7.6 141 (285) 238 (460) 52 (126) 290-301 (554-74) tnsol ale., bz.. CS2 4b 1 1) 440dec (824) 197 (387) bz. 4b 1.53 1.2 -136 (34) (-213) 26 1.65 --4 -41 eth. (25) (-42) 4b 1.29 -37 -160 (-35) (-256) 18 500 0 3 0 70 3.86 13 220 1.0-4.66 125 -57 msol. si. sol. ale. (56) (428) (257) (-71) 24a 91 5.0 132oc 220 16 $1. to). ate. (270) (428) (61) 18 1 2 0 S3 4.5 81 (178) 194 (381) -17 (1.4) sol ale. 18 1 2 0 .82 4.48 88 (190) 178 (352) -39 (-38) si. sol. ale. PAGE 85 CMA 045887 SUBSTANCE/FORMULA 765 Oil, Cocoanut 766a. Oil, Fuel #1 766b. Oil, Fuel "2 766c Oil, Fuel -4 766d Oil, Fuel *5 766e Oil, Fuel ^6 767 Oil, Lubricating 768 Oil, Mineral Oil Mist 769. Oil, Olive 770 Oil, Peanut 771. Oil, Soybean Oil of Vitroil, see Sulfuric Acid PAGE 86 Waste D,tr posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. Igmt. Vap. FI. Ft. Temp. Flam. B.P. Sp. Deni. C C Limits C Gr. (Air=1) ("Ft (F) % lFI M.P, *C (F) Sol. in HjO g/IOOg Other Solvents Misc. Rff 18 18 18 18 18 18 18 18 (5) IS 18 18 0 0 0 0 0 0 0 0 0 0 0 10 9 2 0 <1 2 0 <i 2 0 <i 2 0 <i 2 0 <1 10 10 .81 10 9 10 9 10 .9 216 (420) 38oc (100) 229 (444) 7-5 38oc (100) 257 (494) 54oc (130) 263 (505) 54oc (130) 71oc (160) 407 (765) >149oc 260*371 0300) (500-700) 193oc (380) 225 (437) 343 (650) 282 (540) 445 (833) 282 (540) 445 (833) 23 (72) <-46 (<-S0) <-46 <<--50) <-46 (<--50) <-46 <<--50) <-46 (<-501 360 (680) <-46 (<-501 360 (680) -6 (21) 3 (37) 22 (72) NTTC NTTC NTTC NTTC NTTC NTTC ,3 ? CMA 045888 SUBSTANCE/FORMULA 772. Oil, Vegetable ^^773, Oleic Acid C17H33COOH Oleum, see Sulfuric Acid 774 Osmium 05 OmOn Oil, see Ally 1 Propyl Disulfide 775 Osmium Tetroxide OSO4 776. Oxalic Acid (COOHI22H2Q 777 Oxalyl Chloride (COCU2 Oxirane, see Ethylene Oxide 778 Oxygen O2 779. Oxygen Difluonde of3 780 Ozone 03 Waste Dis posal Pro cedure (See V|) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React, Igmt. Vap. FI. Pt. Temp. Flam. 9.P. Sp, Dens. C Gr. \Ars=1) (QF) 6C iF) Limits % C (F) M.P. C (F) Sol. in HjO g/IOOg Other | Solvents 1 Misc. Ref 18 0 1 0 <1 321 (610) --9--1 (15-30) NTTC 24a 0 1 0 .89 189 363 360 14 tnsol. ate., bz NTTC (372) (685) (680) (57) 27k _____________ _ 1 2 22 5 -- >6300 (>95721 -- 2700 (4892) msol 27k ( 002) 3 24a (1) la 3 3 491 1 65 1.49 None 130 (266) 41 (106) 5 7'0 ale. 157 (315) 102 (215) 63 (145) -16 (3 2) sol. dec ale. NSC dec , ale. 26 3 0 0 1.43 21 05 1.90 26 1 3 3 2 14 1,7 -183 -218 (-297) (-360) -145 -224 (-229) (-371) -112 -193 1--170) (-315) sol. dec. sol ale CGA AIA. MGB, NASA PAGE 87 CMA. 045889 SUBSTANCE/FORMULA 1__________________________________ 781. Paint 781 a Paladlum 782 Paraffin 783 Paraformaldehyde (HCHO)x 784 Paraldehyde {CH3CHO3 785 Parathion C10H14NO5PS 786 Pentaborane B5H9 787 Pentachloroethane CHCI2CCI3 788 Pantachloronaphthalene C10H3CI5 789 Pentachlorophenol C6CI5OH 790 n-Pentane CH3{CH2}3CH3 791 isO'Pentane (CH3)2CHCH2CH3 792, 1,5`Pentanediol C5Hio<OH)2 Waste Dis posal Pro cedure (See VI) TLV (ACGIHI PPM (mg/M3) NPPA 704M System Health Fire React. | 26 i 3 |3 i ' 27a i , Vap, ! fi. Pt. Sp, Dens, 1 C Gr. (Air=1) | (F) <27 (<80) j 18 j !2 1 j2 0 j1 i r- j 12 1 2 2 j2 1 3! * 99 4.55 199 (3901 70 (158) 36oc (96) Igmt. Temp. 4C (SF) 245 (473) 300 (572) 238 (460) Flam, Limits % B.P. C (F) M.P. C (F) I Sol, in | H20 1 | g/IOOg ( Other Solvents ^ Misc, -36 (-32) i NTTC >370 42-60 (>698) (108*40) 120-170 (248-338) 1,3- 128 (262) 12 v. sol (54) ' BDH,MCA ale ! BDH 7b ! 17 I 4b < 1) Skin 005 4b (,5) Skin 4b ( 5) Skin 4 `1 1 i0 t 1 26 J 1 3 4 |3j 66 2.2 32 1,67 70 30 (86) 3 | ; j 3 i 1 98 ' 375 (707) 61 (43) insol ale,, ace j 4- 58 1 -47 ! dec (136) i (-53) | 1 'i ` 162 (324) -29 (-20) insol, ale AIA, MCA ! NASA, NSC 1 BDH '' 310 (590) 190 $1 sol (374) ale AIA, BDH 18 1000 1 4 0 .63 2,48 -49 309 1,4-8 36 -130 v. sol. ale BDH (-56) (588) (97) (-202) 18 1000 1 4 0 .62 2,48 -51 420 1 4-7.6 28 -161 insol. ale. BDH (-60) (788) (82) (-258) 18 1 1 0 99 3.59 129oc (264) 260 (500) -16 (3.2) sol. ale. CMA 045890 CMA 045891 SU8STANCE/FORMUIA 796. Perchloric Acid Solution HCI04*2H20 Perchloroethylene, see Tetrachloroethylene Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. 312a 3 0 Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F) <F> % (F) 1.70 203 (397) M.P. C <F) Sol. in H2O fl/IQOg Other | Solvents 1 Misc. Ret -18 (0) v. sol. ale. AlA, BDH MCA, NSC 797 Perchloromethyl Mercaptan 13 0,1 3 CISCCI3 1 70 6.4 149 (300) 798 Perchloryl Fluoride CIO3F 799, Petroleum Ethan 21 3 2 2 3 1 43 --47 -146 (-53) (-231) 18 500 1 40 .6 2.50 -57 288 1-6 30-60 <"73 (-70) (550) (86-140) K-ioi) MCA BDH 800 Phenanthrene <C6H4CH)2 18 1 1.18 6.14 340 (644) 101 (214) insol. ale , CS2 801 2-Phenanthreneacetamide c16h13no 802. 3-Phenanthreneacetamide C16H13N 803. Phenol c6h5oh 804 Phenyl Acetate CH3C02CfiH5 20 CAR 20 CAR 18 5 3 Skin 18 1 2 2 0 1.07 3.24 79 715 1.5- 181 40 sol ale,, CS2 BDH. (175) (1319) (358) (104) imttc.mca 0 1 09 4.7 80 (176) 196 (385) si. sol. ale. Phenyl Acetonitrile, see Benzyl Cyanide 8Q5 VPhenylazo-2-Naphthol Cl6H12N20 8 CAR 102-4 (216-19) PAGE 90 CMA 045892 SUBSTANCE/FORMULA Phenylcyclohexane, see Cyclohexylbenzene ^^06 p-Phenylenediamine H2N(C$H4)NH2 307 Phenylethanolamine C6H5NHCH2CH2OH 808 Phenyl Ether c6h5oc6h5 8Q9 Phenyl Ether - Biphenyl Mixture Phenyl Glycidyl Ether, see 1,2- Epoxy-3-Phenoxy propane 810 Phenylhydrszine C6H5NHNH2 811 Phenyl Isocyanate C6H5NCO 812- Phenyi-2-Naphthylamine C10H7NHC6H5 813. o-Phenyl Phenol C6H5C6H4OH Hl4 Phorone 0 CH3(CH3)C=CHC(0)CH= C(CH3)CH3 815 iso-Phorone C9H14O Waste Disposal Pro cedure (See VI) TLV (ACGIH) PPM Img/M3) NFPA 704M System Health Fire React. , tgnit. Vap. FI, Pt. Temp. Flam, B.P. Sp. Dens. C C Limits C Gr. (Air=l) lF| (F) % (F) M.P. C lF) Sol. in H2O g/IOOg Other Solvents Miic. Ret. 5 (.1) 2 52 15 1 15 1 1 3.7 156 (312) 0 1.09 152 (305) 1 09 5.86 96oc. 546 (205) (1195) 1.06 124oc 610 (255) (1130) 267 (513) 140 (284) sol ale 285 (545) 35 4.6TM ale. (95) 258 (496) 27 (81) msol. ale., bz. 257 (494) 12 (54) 16 5 3 Skin 18 5 18 2 18 2 18 2 2 0 1.09 3.7 89 174 (192) (345) 11 2 1.20 1 0 1.21 124 (255) 2 0 .88 48 85 (185) 243dec. (469) 20 (68) sol ale., bz. BDH 165 (329) -30 (-22) dec. dec., ale 400 (752) 108 (226) insol. hot ale. 286 (547) 57 (135) insol. ale., ace, bz. 197 (387) 28 (82) si. sol. ale. 1 0 .93 4.77 96oc 462 .8-3.8 215 -8 si. sol. (205) (864) (419) (16) BDH PAGE 91 CMA 045893 SUBSTANCE/FORMULA 816 Phosdrm C7Hi306P 817, 818 Phosgene COCI2 819 Phosgene Solutions m Benzene 820 Phosphoric Acid H3PO4 821, Phosphoric Anhydride ^05 822. Phosphorus (White & Yellow) P4 823 Phosphorus (Red) P4 824, Phosphorus Oxychloride POCI3 Phosphorus Pentoxide, see Phosphoric Anhydride 825 Phosphorus Pentachloride PCI5 Waste Dis posal Pro cedure (See VI) TLV (ACGIM) PPM (mg/M3) NFPA 704M System Health Fire React. 7b ( 1) Skin 3 Ignit. vap. F|. Pt. Temp. Flam. B.P. Sp. Dens. 6C 6C Limits C Gr. (Air=1) (F) (F) % <*FI 1 23 79oc (175) 107 (225) @1 mm M,P. C <F> Sol. m h2 fl/IOOg Other Solvents Miic. Rf Z7j ,1 3 18 3 224b (1) 24b 3 27c ( 1) 27c 3 0 21 3 _____ 1.39 3.4 8 -128 (46) (-198) dec dec., ale MCA mcb, mgq <22 72) SDH 1 69 .......... 2 2.38 260 (500) 42 (108) v, sol. ale BHD, INITTc 300 sub!, (572) dec. dec,, ale. BOH, MCA 4 42 ! -| 30IS6) 3 1 1 82 j spontaneous 280 44 si, sol. bz ! 1 ignition in dry sir (535) (111) BDH, MCA, NSC 1 1 2.34 4,77 260 (500) 280 590 (1094) @43atm v. sol ale. BDH 1 69 5,30 107 (225) 1.2 (34) dec dec., ale BDH,MCA 21 (1) 3 2 4 65 162 subl. (324) dec. CS2 BDH CMA 045894 substance/formula g26 Phosphorus Pentasulfide ^ ' P2S5 Hf27 Phosphorus Tribromide P4S3 828- Phosphorus Sesqutsulfide PBr3 029 Phosphorus Trichloride PCI3 $30 Phthalic Anhydride CeH4tCO)20 831, Z-Picoline CH3C5H4N 832. 4-Picoline CH3C5H4N 833: Picric Acid (N02)3C(3H20H 834. Pimeiic Acid HOOC(CH2)5COOH 835. Pindona IPIval) C14H14O3 836. 2-Pinene Cio^ie 837 PCi5pHe1ri0dNinHe Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mo/M3) NFPA 7Q4M System Health Fire React. Ignit V*. FI. Ft. Temp. Flam. B.P. Sp. Dans. C C Limits c Gr. <Air=1) lF) (F) % !F) M.P. C (F> Sol. in H2O 8/IOOg Other Solvents Misc. Ref. 21 (1) 3 21 2 21 3 21 .5 3 0 24a 2 2 5 22 5 22 6 (-1) Skin 24a 2 4 18 (.1) 18 1 3 6 23 2 2.03 1 2.03 142 (287) 100 (212) 514 (957) 276 (529) msol. si. sol. CS2 MCA 407 (765) 173* (343) insoi. bz, CS2 2.85 2 1.59 4 75 173 (343) -40 (--40) dec. 75 (167) -112 (-169) dec. dec., ale. SDH bz, CS2 BDH, MCA 0 1 53 5.10 151 584 1,7-10.4 284 131 si. sol. ale. (304) (1083) (544) (268) 0 .95 3.2 39oc 538 (102) (1000) 129 (264) -70 (-94) v. sol ale. 0 .96 3.21 57 (134) 143 (289) 4 (39) aa ale. 4 1.76 79 150 300 (302) (572) 1.33 >300axp (>572) 122 272 (522) 100mm 106 (223) sol. $1. sol. ale. ale. AlA, MCA BDH BDH BDH 0 .86 4.7 33 (91) 3 .86 3.0 16 (61) 109 (228) 156 (313) --55 (-67) $1. sol. ale. 106 (223) -7 (19) so ale., bz. PAGE 93 045895 CMA SUBSTANCE/FORMULA Wane Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (rng/M3) NFPA 704M System Health Fire React. v*p. FI. Pt. Ignit. Temp. Flam. 8.P. Sp. O.ni. C 6C Limits C Gr. (Air=1) (F| <F) % (F) M.P. C <P) Sol. m HjO g/IOOg Other Solvents Misc. 838 Piperylene CH3CH=CHCH*CH2 18 1 3 1 68 2.4 -43 (-45) 2-8.3 42 (108) -141 (-222) insoi ale Pivel, sea Pindone 839. PJatwwm Pt 27a 1.002) 1 0 0 21.5 3827 (69301 1774 (3225) insol. aq rag 840. Polytetrafluoroethylene (F2C'CF2)n 26 1 0 0 2.2 subl >260 (>500) insol. 841 Polyvinyl Acetate Emulsion 18 -36 (-32) acet. NTTC 842 Potassium K 843 Potassium Acetate CH3COOK 844 Potassium Borohydride KBH4 848. Potassium Carbonate k2co3 846. Potassium Chlorate KCIO3 847 Potassium Cyanide KCN 848. Potassium Dichromote K2Cr207 3 3 1 2 .86 1.4 11 1 0 1 8 3.4 17 3 3 2 1.18 1.9 11 3 0 0 2.43 12a 0 2 2.32 14 5 12a (5) 3 3 0 0 1.52 0 0 2.68 774 (1425) 64 (147) dec dec., ale. BHD 292 (558) 353^0 ale., MeOH 500dec. (932) 19^0 si. sol., ale. BDH r ? > dec. 891 (1636) 400dec (752) 368 (694) 635 (1175) <500dec (032) 398 (748) 11220 7,20 ale. 50 si. sol,, ale. 4.90 'JJA! A,BDH i l VSDH I PAGE 94 CMA 045896 SUBSTANCE/FORMULA 049 Potaaium Ferrocyanide K4Fe(CN)6'3H20 g50, Potaaium Fluoride KF 850a. Potaaium Hydride KH 851. Potaaium Hydrogen Difluoride KHF2 Potaaium Hydroxide, see Caustic Potash 852. Potaaium Nitrate KNO3 853. Potaaium Perchlorate KCIO4 354. Potaaium Permanganate KMn04 855. Potaaium Persulfate K2S2O8 856. Potaaium Peroxide k2o2 857. Potaaium Sulfide k2s 858. Praseodymium Pr 859 Propane CH3CH2CH3 Waite Dispoal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. 11 1 0 0 11 (2.5) 3 0 0 17 3 3 ignit, Vap. FI. Pt. T*mp, Ftam. B.P. Sp. Deris. C C Limits C Gr. (Air=1) (F) (F| % CF) M.P. C (F) Sol. in HjO g/IOOg Other Solvents 1 85 2.48 1.43 dec. 70 (158) 27 .a1^ 1505 880 (2741) (1616) v. sol. dec. sol. ace. Miic. Ret. 11 (2.5) 3 0 0 2,37 225dec. (437) 4121 BDH 11 1 0 1 2.11 <400dec 334 (752) (633) 13 12a 1 0 2 2.52 610 (1130) .75 12a 00 1 2.70 <240dec 6.420 dec., ale. l<464) sol., MeOH 12a 1 0 1 2.48 ClOOdBC 1.70 (<212) 22a 3 0 2 - dec. 490 dec., ale (914) 23 2 1 0 1.81 3.8 dust explosive 840 (1544) sol. ale. 27k 1 2 0 6.84 4.9 3127 (5661) 935 (1716) dec. 18 1000 1 4 0 .58 1.56 (-1041 468 2.2-9.5 -45 -187 insol. ale., bz. NTTC (-156) (874) (-49) (-305) PAGE 95 CMA 045897 SUBSTANCE/FORMULA Waite Dis posal Pro* cedure ISee VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. Ignit vp. FI. Ft. Temp. Flam. B.P. Sp. Dans. C C Limit* C Gr. (Air=1) (F) <F) % <F> M.P. C <F) Sol. in H2O g/IQOg Other Solvents Misc. R^f 860. 1,3 Propenediamine NH2(CH3)3NH2 861. 1, 2 * Propanediol CH3CHOHCH2OH 7a 18 2 3 0 86 2.56 24oc (75) 136 (276) -24 (-10) v. so). ale 0 1 0 1.04 2.62 99 371 2.6-12.5 189 -59 w ale. (210) (700) (372) (-74) NTTC n-Propanol, see n-Propyl Alcohol 862 Propargyl Alcohol HC=CCH20H 18 1 23 3 .96 1.93 36 (97) 3.4- 115 -17 sol (239) (1.4) ale. 863 Propargyl Bromide HC=CCH2Br 4b 4 3 4 1.56 4.1 10 324 3.0- 90 -61 (50) (615) (194) (-78) Propene, see Propylene 864. iso-Propenyl Acetate CH3COOCICH3):CH2 ^-Propiolactone, see Hydracryhc Acid-^Lactone 18 2 3 0 .91 345 16 (60) 1.9- 93 -93 si sol. (199) (-135) 865. Propionaldehyde C2H5CHO 2 23 0 .81 2.0 -9-7oc 207 2.9-17 48 -81 sol. ale. BDM (15-19) (405) (120) (-114) 866. Propionic Acid CH3CH2COOH 24a 2 2 0 .99 2.56 54 513 2.9- 141 -22 06 ale BHD (130) (955) (286) (-8) 867 Proptonitrile CH3CH2CN 14 4 3 1 ,77 1.9 2 3.1- 97 -93 v. sol. ale. (36) (207) (-134) 868. Proptonyl Chloride la 3 3 1 1.06 3.2 12 CH3CH2COCI (54) 80 (176) -94 (-137) dec. ale. BDH PAGE 96 CMA 045898 SUBSTANCE/FORMULA Qgo iso-Propyl Acetate CH3COOCH(CH3>2 ^^870 n-Propyl Acetate CH3COOCH2CH2CH3 g7l n-Propyl Alcohol CH3CH2CH2OH 872 iSO'Propyl Alcohol CH3CHOHCH3 g73. Propylamine CH3CH2CH2NH2 874. iso-Propylamine (CH3)2CHNH2 875 Propyl Benzene C3H7C6H5 iso-Propyl Benzene, see Cumene g?6 iso-Propyl Benzoate C6H5COOCH{CH3)2 877 Propyl Bromide CH3CH2CH2Br 878. Propyl Chloride CH3CH2CH2CI n*Propyl Cyanide, see Butyromtnle Waste Dis posal Pro cedure (See VI) TLV (ACGlH) PPM (mg/M3) NFPA 704M System Health Fire React. 18 250 1 30 18 200 1 30 18 200 1 30 18 400 1 30 7a 5 3 3 0 7a 5 3 4 0 18 2 3 0 Ignit. Vap, FI. Ft. Temp. Flam, B.F. Sp. Dens. C C Limits C Gr. <Ait=1) (F) (F) % (F> M.P. C <F> Sol, m H7O fl/IOOg Other Solvents .87 3.52 4 (40) 460 (860) 1 8-7.8 93 (199) -73 (-99) sol. ale. .89 3.5 14 (58) 450 (842) 2-8 102 -95 (216) (-139) si. sol ale .78 2.07 25 (77) 433 (812) 2.1-13.5 97 -127 (207) (-197) V. sol. ale., bz. 79 2.07 12 (53) 399 2.3-12.7 (750) 82 -89 (180) (-128) 00 ale. .72 2.0 -37 318 2.0-10.4 49 -83 sol. ale. (-35) (604) (120) (-116) .69 2.03 --37oc 402 2.3-10.4 32 -101 w (-35) (756) (90) (-150) ale. .86 4.14 30 (86) 450 (842) 0 8-6 159 -100 (318) (-148) msol. ale., bz. Misc. Raf BDH SDH BDH BDH, MCA SDH BDH. NTTC, MCA 18 1 1 0 1.01 5.67 99 (210) 218 (424) -26 (-15) insol. ale. 4b 2 3 0 1.35 4.3 490 71 -110 si. sol. ale. BDH (914) (160) (-166) 4b 2 3 0 .89 2.71 <-18 520 2.6-11.1 47 -123 $1. sol. ale. BDH 0 (968) (117) (-189) PAGE 97 CMA 045899 SUBSTANCE/FORMULA 879. Propylene c3h6 880. Propylene Carbonate C3H6C03 Propylene Dichloride, see 1,2-Dichloropropane Waste Dis posal Pro cedure (See VI) TLV (ACGIM) PPM (mg/M3) NFPA 704M System Health Fire React. 18 4000 1 41 18 1 1 0 Ignit, Vap- FI. Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=1) (F) (FI % (F) M.P. C (FI Sol. in HjO g/IOOg Other Solvents ,51 1.5 -108 460 2-11 1 -48 -185 v. sol. ale (-162) (860) (-54) (-301) 1.21 3.5 l35oc (275) 242 (468) -49 (-56) v. sol bz. 881. Propylene Disulfate CjHgSjOg Propylene Glycol, see 1,2-Propanediol 882. Propylene tmine C3H6NH 4b CAR 7a 2 2 2 2 Skm 2.0 63 (145) Propylene Oxide, see 1,2-Epoxy-Propane 883 t$o-Propyl Ether [(CH3)2CH]20 15 500 2 3 1 72 3.5 -28 443 1.4-7.9 69 -60 si. sol. ale (-18) (830) (155) (-76) 884. n-Propyl Formate C3H7OOCH 18 2 3 0 .91 3.03 -3 455 2.3- 81 -93 si. sol. ale. 127) (851) (178) (-135) 885. iso-propyl formate (CH3)2CHOOCH 18 2 3 0 .88 3.0 -6 485 (22) (905) 68 (154) si. sol. ale. 886. iso-propyl glycidyl ether 15 50 3 H3C0CH2CH2*0-HC{CH3l2 .92 4.15 137 (279) 887. propyl nitrate CH3CH2CH2N03 4a 25 2 3 3 1.06 20 (68) 177 (350) 2-100 111 <-100 si. sol. (232) -148> ale. s r-Mik, R,t r-MCA ; f f MCA PAGE 98 CMA 045900 substance/formula j$o-propyl toluene, see cymene W 888. Propyne w HC-CCH3 889 Propyne-allene mixture (MAPP) 890. Pyrethrum 891. Pyridine C5H5N 892 Pyrogallic acid C6H3<OH)3 893. Pyrrolidine C4H9N 894. Pyruvic acid CH3COCOOH Quicklime, see Calcium oxide 895 Quinaldine CH3C6H3NCHCHCH 896. Quinoline C6H4NCHCHCH 897. 8'Quinolinol HOC6H3NCHCHCH Waste Dis posal Pro cedure (See V)) TLV (ACGIH) PPM Img/M3) NFPA 704M System Health Fire React, Ignit. Vap. FI. Pt, Temp. Flam. B.P, Sp. Dens. C C Limits C Gr. (Air=1) <FI (FI % (F) M,P. C <f) Sol. in Hz0 g/IQOg Other Solvents Mtsc. Ref. 18 1000 2 4 2 0.68 1.38 18 1000 2 4 2 >1 26 (5) 2 1 0 >1 1.7 -23 -105 si. sol. (-9) (-157) forms expl. with Cu & Ag ale. 5 5 2 3 0 .99 2.7 20 482 1.8-12.4 115 -42 w ale. (68) (900) (240) (-43) 24a 3 1 0 1.45 4.4 309 (588) 133 (271) v. sol. ale. 7a 2 3 1 .85 2.45 3 (37) 89 (192) --63 (-81) ale. 24a 1.23 3.0 165 14 ale. (329) (57) BDH. NSC BDH 5 3 1 0 1.06 4.9 247 (477) -2 (28) msol. ether 5 2 1 0 1.09 4.45 480 1.2 238 -20 sol. ale., CSj BDH (896) (460) (-4) 5 210 267 (513) 76 (169) insol. ale. PAGE 99 CMA 045901 substance/formula 898 Qumone OC6H4O Rad fuming nitric acid, see nitric acid, anhydrous 899, Refrigerant gasas 900. Resins 901. Resorcinol C6H4(OH)2 902. Rhodium Rh 8 8 3 3c h ci o ps903. Ronnel 904. Rotenone C23H22O6 905. Rubber (tubing, etc,) 906. Rubidium Rb Ru907 Ruthenium Waste Dis posal Pro cedure (See VI) TLV (ACGIH! PPM (mg/M3) 18 ,1 NFPA 704M System Health Fire React. SpGr. r 3 ! 1.32 _____ __________ Vap. Dens. (Airasl) FI. Pt. C (F) 293 (560) Ignit. Temp, 6C (F) Flam. %Limits B.P. C lFI M.P. C fcF) Sol. in H2O g/IOOg Other Solvents 116subl. (241) si. sol. ale. Misc. Ref, | ' I- " 26 26 18 2 Z7 (.1) 7b (15) 18 (5) 2 26 27k 2 27k 1 2 1 3 2 <38 100) NTTC ( }~~ 1.27 3.79 127 (261) 12.4 j ___ 1___ 1 27 1.53 12.30 608 1.4(1126) @392F 281 (538) 110 (230) 3707 (6705) 1985 (3605) 41 (106) 210-20 (410*28) @5mm 163 (325) Ignites in air 700 (1292) 38 (102) (47155002) (24445420) sol. ale. insol '1 'r org, soiv. ____ _ -\ insol. org. solv. ,1 dec. dec. ale. insol. 'k * >1 ! .> ri 908. Salicylaldehyde HOC5H4CHO 2 2 0 1.15 78 (172) 197 (387) -10 (14) si sol. ale. r * CMA 045902 SUBSTANCE/FORMULA 909. Salicylic acid _ HOC6H4COOH Samarium Sm 911, Salanicacid H2SBO4 912. Sslanium Sc 913, Selenium dioxide Se02 914 Selenium Hexafluoride SeFg 915 Selenium oxychloride SeOCl2 Selenous acid, see selenium dioxide 916. Savin C12H11NO2 917. Silane SiH4 918. Silica (cristobalite) Si02 919. Silica (free) S1O2 Waste Dis posal Pro cedure (See VII TLV (ACGIH! PPM (mg/M3) NFPA 704M System Health Fire React. 24a 1 1 Ignit. Vap. FI. Pt. Temp. Flam. B.P, Sp. Dens. C C Limits C Gr. (Air=1) (F) (F) % <F) M.P. C (F) Sol. in HjO g/lOOg Other Solvents Misc. Ref. 1.44 4.8 157 (315) 545 (1013) 211 (412) 159 (318) si. sol. alc.r ace. 27k 2 7.54 '""150 1900 1072 msoi. (302) (3462) (1962) 27e 3 2 3.0 260dec. (500) 58 (136) w dec. ale. AIA. BDH 27e 1.2) 3 2 "'"4.5 688 (1270) 217 (423) insol chi. AIA, NSC 27e (.2) 3 3.95 315subl. (599) 3814 ale., bz AIA, BDH 27e 05 3 3.25 --46 $ubl. (-51) dec. NSC 27e (.2) 3 2.42 - 176 9 dec. bz., CS2 AiA, NSC (349) (48) 14 (5) 17 3 26 250 2 (%Si07fSI 26 2 3 .68 2.32 Sponta neously -112 -185 flammat le in air (-170) (-301) insol. 2230 (4046) 1715 (3119) tnsol. - MGS PAGE 101 CMA 045903 SUBSTANCE/FORMULA 920. Silica {quartz) S1O2 921. Silica (amorphous) Si02 922, Silica gal H2SjQ3 Silicic acid, see silica gel 923 Silicon tetrachloride S1CI4 924. Silicon tetrafluorida S1F4 925. Silver Ag 926 Silver Nitrate AgNQ3 927. Sodium Na 928. Sodium acetate NaQOCCH3 929. Sodium amide NaNH2 930. Sodium azide NaN3 PAGE 102 Waste Oiv polel Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React, 26 250 2 I%Si02+6 26 20 2 26 1 Ignit. Vap. FI. Ft. Temp. Flam. B.P, Sp. Dens. "C C Limits C Gr. (Air^l) (F) (F) % (F) M,P. <flF| Sol. in g/ltS* Other Solvents 2.64 2230 (4046) 1610 (2930) insol. 2.19 2230 (4046) tnsoi. 150dec. (302) insol Mik. 1b - 3 21 3 1.48 97 4,67 27a (.01) 1 2 10.5 27k (.01) 1 0 1 4 35 3 312 .97 11 1.53 19 3 2 83 2.85 58 (136) -70 (-94) dec. dec. ale. -65 -90 (-85) (-130) 5>181 Omrr @13l8mrT dec. 2212 (4014) 961 (1762) insol. ale. BDH MGB 444dec. (831) 212 (414) >115 (239) spontaneous ignition in dry air 892 (1638) 607 (1125) 98 (208) 324 (615) i22o dec 1199 eth. dec. ale si. sol. ale. SDH. MCA, NSC 400 (752) dec. 210 (410) dec. - 4217 si. sol. ale. BDH BDH CMA 045904 SUBSTANCE/FORMULA g3l. Sodium benzoate NaQQCCgHg $32 Sodium bicarbonate NaHC03 933 Sodium bisulfate NaHSO* 934, Sodium bisulfite NaHS03 935, Sodium borohydride NaBH4 936 Sodium carbonate Na2CQ3 937 Sodium chlorate NaCl03 938, Sodium chloride NaCI 939. Sodium chlorite NaCIC>2 940. Sodium chromate Na2Cr04 941 Sodium cyanide NaCN 942. Sodium dichromate Na2Cr207 Waste Dis posal Pro cedure (See VI) TLV IACGIH) PPM (mg/M3) NFPA 704M System Health Fire React, 11 0 Ignit. Vap. FI, Ft. Temp, Flam. B.P. Sp. Dens. C C Limits C G, (Air=1) lF> lP> % (F) j M.P, C (F| Sol. m h2 g/IOOg Other Solvents Mise. Ref. 662 si sol ale, 11 2.16 12a 2 12b 2.44 1 48 ! 17 2 2 1.07 11 2 2 53 12a 1 0 2 2 49 11 0 2 17 12a 1 1 2 12a 3 14 (5) 2 0 0 12a 3 none 270 (518) !>315dec (599) dec j6 9 si, sol ale, 1 i j29^5 si sot ale. ! v sol si sol ale | i | none ! >400 1 <>7521 55^5 | ale . MeOH i1 dec. 851 j 7 10 1 si sol, ale 1 | U564) j ! i i 7T- AlA, SDH ' 300dec, I 248 79 1 ale A1A, 1572) (478) | ! SDH, MCA 1413 (2575) 801 (1474) 175dec. (347) 36 39l7 iisi, sol ale. , --------------------- 1------------------------- 792 (1458) sol 1496 (2725) 560 (1040) 4810 si sol. ale MCA BDH, MCA 120 (2481 sol MCA PAGE 103 CMA 045905 SUBSTANCE/FORMULA 943. Sodium ethoxide NaOC2H5-2C2H5OH 944 Sodium fluoride NaF 945 Sodium fluoroacetate CH2FCOONa 946 Sodium formate NaOOCH Waste Dis posal Pro cedure (See VI) TLV (ACGIh: PPM (mg/M3) NFPA 704M System Health Fire React. 3 3 3' Sp. Gr. 11 3 4b ( 05) Skin ii 3 3 I' 2,56 i 1 - ,1.92 Vap. Dens. (Air=1) FI. Pt. C (F) Igmt. Temp. C (CF) Flam. Limits % B.P. C ("Ft M.P. C (F) Sol. m H2O g/IQQg dec 200 dec. (392) 1700 (3092) 980-97 (1796- 1827) 4.2'S 200 (392) 1112S 253 (487) 9720 : Other Solvents Misc, Ref. ale. 8DH j j ~~~ si. sol. ale. sl. sol. ale 947 Sodium hydride MaH 948. Sodium hydrogen difluonde NaF-HF Sodium hydroxide, see caustic soda 949. Sodium hypochlorite NaOCI 17 11 12a 3 !2 2 .92 Explodes with w iter j2,08 i \....... ......-..., __________ 1__________ - SQOdec. (1472) dec dec. NSC BDH BOH 950. Sodium iodide Nal 11 2 3.67 (1204)1304 (2379) 651 18425 ale., ace 951 Sodium methoxide Na0CH3'2CH30H 952 Sodium nitrate NaN03 3 n 1 0 2 2.26 dec. dec. MeOH BDH 380dec. (716) 307 (585) 9225 ale., MeOH 953. Sodium nitrite NaNC2 12b 3 2 2.17 (1000)538exp. 320dec. (608) 271 (520) 81'5 $1. sol. ale. PAGE 104 CMA 04590$ SUBSTANCE/FORMULA 954. Sodium pentachlorophenate CgCIgONa Waste ! Dis- 1 tLV posal '(ACGIHI Pro PPM cedure (mg/M3) (See VI) NFPA 704M System Health Fire React. 4b (,5) 3 Igmt. Vap. FI. Ft. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=l) (F) (F) % (F) M.P. C !F) Sol. m H2O g/IOOg Other Solvents 1 Mse, Ref, Sodium perchlorate NaCl04 12a 2 0 2 2 02 956 Sodium peroxide Na202 22a 957, Sodium -phosphate Na2HPQ4 7H20 958, Sodium-potassium alloys NaK 959 Sodium propionate NaOOCC2H5 11 3 !- j! 11 , 960 Sodium silicate (water glass) Na20.xSi02 11 961 Sodium sulfide Na2S 23 3 |3 ii t [ 2 ! 0 2 281 1,68 ;3 ' ! 2| l 1; ' ;i 1 |o 1 ! 1.86 | ignite in air ! 1 i i 962 Sodium sulfite Na2S03 963. Sodium tetraborate Na2B4C>7 12b 11 2 3 2.63 - 2.37 964. Sodium thiocyanate NaSCN 11 3 965. Sodium thiosulfate Na2S203 12b | ! 1 1.67 482dec. (900) sol ale 460dec (860) sol dec ale 48 (118) 104`W jsol. ale. BOH sot. NTTC 1180 (2156) isio si. sol. ale. dec. 120 si sot ale. BDH 157dec. 741 (2867) (1366) 1.06 287 (649) 1392' ale., ace 48 (118) 50 PAGE 105 CMA 045907 SUBSTANCE/FORMULA 366. Stannic Chloride SnCl4 Stannic Chloride hydrate Waste Dis posal Pro cedure (See VI) TLV (ACG1H) PPM (mg/M3) 1b 11 NFPA 704M System jHealth Fire React. 13 1 Vap. Sp. Dens. Gr. <Air=11 2 23 1 FI. Pt. C <F| Igmt. Temp. C (F) Flam. Limits % B.P. 6C (F) 114 (237) M.P. "C (SF) Sol, m H2O g/TOOg Other Solvents 1 Misc. Ref, -33 (-27) sol eth j BDH 1 1 967 Stearic acid C, 7H35CQOH 24a 1 0 95 9,8 196 395 (385) (743) 358-83 69 (676-721) (156) msol CS2 I NTTC 968. Stibme SbH3 969 4-stibenamme C14HT4 970 Stoddard solvent 971 Strontium Sr 972 Strontium carbonate SrC03 973, Strontium nitrate Sr<N03)2 974. Strontium peroxide SrO2 975, Strychnine C21H23N203 976. Styrene (C6H5CHCH2)n 27d ,1 3 1 2 5 30 -17 (1,4) -88 (-126) 4o CS3 !5 , | 18 j 1 1 27h | 27h 27h ----- ---------- 1 27h 5 18 500 ( 15) I jCAR 1 2, - | 1.0 j2 2i - ! 26 :| - 3.7 : 10; ; 1 i 2 99 j ; 90 ! (194) !--______________ 38-43 227-60 (100-110) (441-500) .8-5 220-300 (428-572) -; -i ! j - -1 i i 1384 j 752 ' (2523) f (1386) ' dec ale 1 1340 ' si sol ' ! j| (3444) : (27271 j t i 1 @69atm. t __________ i__________ _____________________ ______________ ___________________ -! - 645 1 570 ! 7118 si sol ale. ! 11193) (10581 ' 1 ; j1 0 j____ 3 _L ... j- j [ 1 4,56 | ........ 1____________ !____________ - 1.36 -- 23 909 3.6 31 (88) 490 (914) 215dee si. sol. ale j (419) j 270 (518) @5mm 268 1 si sol 1514) ] __________ 1__________ chi | 1.1-6 1 146 (295) -33 insol. (-27) ale., CS2 AIA. BDH,NTTC 977 Styrene monomer C6H5CHCH2 18 100C 2 3 2 905 31 (88) 490 (914) 1 1-6.1 145 (293) -31 msol. (-23) ale.. CS2 BDH, NTTC, MCA PAGE 106 CMA 045908 SUBSTANCE/FORMULA d7g Succinic Acid ^ COOH{CH2}2COOH Succmic Anhydride TM C4H4O3 gsQ Sucemonitrile NCCH2CH2CN qgOa Sulfamic Acid so2<nh2ioh 931 Sulfamide S02(NH2>2 gg2 Sulfur Ss g83 Sulfur Decafluonde S2F10 984. Sulfur Dichloride sci2 g85 Sulfur Dioxide S02 986 Sulfur Hexafluoride sf6 987 Sulfuric Acid H2$C>4 988 Sulfur Monochlonde S2CI2 989. Sulfur Tnoxide S03 Waste Dis> posal Pro cedure (See VI) TLV (ACGlH) PPM (mg/M3) NFPA 704M System Health Fire React. 24a 2 1 24a 2 1 14 3 1 19 2 3 19 . 26 2 1 0 1 21 j 21 3 32 ( 12b 5 3 0 0 j 21 1000 24b m 3 0 1 21 1 24b 21 3 1 Ignit Vap. FI. Pt. Temp, Flam. B,P,, Sp. Dens. C C Limits C Gr. (Air=1) lF) (F| % (FJ M.P. C lF) Sol. m H2O g/IOOg Other | Solvents j Mise. Ret 1.57 235dec. (455) 185 (365) $1. sot. ale , MeOH | 1.10 261 (502) 120 (248) insol. ale 98 2 03 2.76 132 (270) 266 (511) dec 58 (136) 200 v sol. dec, ale., b* 1 1 1 1.61 2.07 | 3.08 j 1 62 J 11 3.6 1 4 2.3 1,67 62 1.84 2.3 1.69 2.75 207 (405) 232 (450) 250dec (482) 92 (198) sol. ale 444 (832) 119 ! insol. ; 12461 ] 1 CS2 29 ' -92 ; (84) | (-134) i - - ' NTTC. ; MCA, NSC j ! None 118 (245) 234 (453) 59dec J --78 (138) | (-108) -10 (14) -76 1-105) | bz 23 ! ale . -64subli Sl. sol (-83) | ate. None 338 (640) 10 (50) OO dec., ale 136 (277) -80 (-112) dec. bz,,CS2 j BOH, MCA AIA, MCA CGA AJA, BDH, NTTC, MCA BDH, MCA 45 (113) 17 (63) dec MCA PAGE 107 CMA 045909 SUBSTANCE/FORMULA 990 Sulfury! Chloride SO2CI2 991 Sulfuryl Fluoride SO2F2 992. Systox (C2H50)2PS0C2H4SC2H5 993. Tall OH (Liquid Rosin) 994 Tallow 995, Tannic Acid C76H526 996 Tantalum Ta 997. Tar, Liquid Waste Dis posal Pro* cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. 21 3 Sp. Gr. 1 67 Vap. Dens. (Air=1) FI. Pt. C lF) Igmt. Temp, C <F) Flam. Limits % 47 B.P, C (F) 69 (156) M.P. *C ("FI Sol. m M2 g/IOOg Other Solvents -54 (-65) dec. bz 21 5 3 3.72 -55 -137 (-67) (-215) 109 ale 7b (.1) 3 134 (273) 18 1 182 (360) 18 0 1 0 .895 265 (509) 32 (90) 24a 27a (5) 2 1 2 16.7 199oc. 527 (390) (980) 210dec. (410) sol. ale., ace 5425 (9797) 2997 (5300) insol. 26 3 2 >93 15^001 49 (120) Misc. BDH NTTC NTTC NTTC TEDP, see Tetraethyl Dithionopyrophosphate 998. Tellurium Te 999 Tellurium Hexafluoride TeF TEPP, see Tetraethyl Pyrophosphate 27e < 1) 2 27e 0.02 2 2 6 25 1.18 1390 (2534) 452 (846) insol. 35 (95) -36 (-33) dec. PAGE 108 CMA 045910 SUBSTANCE/FORMULA 1000, Terbium Tb BfoOl m-Terphenyl 018*14 Waste Dis posal Pro cedure (See VI) j TLV ! (ACGIH! "m3 I (mg/M )j 27k IS 1C nfpa 704M System ! 1 1 | Health Fire React, j Sp. Gr. ! 2 j - ! 8,77 ! i0 1 1,16 Vap. Dens. (Air=1) i! 1 1 FI. Pt. "C ("F| 135oc (275) Ignit. Temp, *C ("F| Flam. Limits % B.P. "C ("FI 2800 (5072) 365 (689) M.P. C <F) Soi. tn HjO g/lOOg 1356 (2473) msol. 87 (189) msol. Other Solvents ale., bz. Misc. Ref. 1002 o-Terphenyl Ci8H14 1003, p-Terphenyl Ci8H14 1004 Tetrabromoethane BrjCHCH &<2 18 1C 18 1C 26 1 3 1 0 1 14 11 I 1 24 1 01 2.97 7.9 l63oc, (325) 332 (630) 57 (135) msol. bz., MeOH 405 (761) 213 (415) 239dec. (374) *1 (30) msoi ale. BDH 1005 1,2,4,5-Tetrachiorobenzene C6*2Cl4 4b 1 0 1,86 155 (311) 243 (469) 139 (282) msol. bi,,CS2 1006 1,1,1.2-Tetrachloro-1,1* Difluoro Ethane F2CCI CCI3 26 500 2 1.64 7,03 92 (198) 41 (106) msol ale. 1007. 1,l,2,2'Tetrachloro*1,2, Difluoro Ethane O2FCCFCI2 26 500 1.64 7.03 93 (199) 25 (77) msol ale. 1008. 1,1,2,2-Tetrachloroethane CI2HCCHCI2 4b 5 Skin 3 1 59 5.8 None 146 (295) -43 (-45) sl. sol ale. A|A BDH, MCA 1009. Tetrachloroethylene Cl2C=CCl2 1010 Tetrachioronaphthelene CioHgCU 4b 100 3 6 (21 2 Skin 1.62 5.8 None 121 (250) -24 (-11) msoi 182 (360) ale , bz. AIA,BDH. NTTC, MCA 1011. Tetradecane Cl4H30 IS 1 0 .76 6.8 100 202 .5- 254 6 msol. ale. (212) (396) (489) (43) PAGE 109 CMA 045911 SUBSTANCE/FORMULA 1012. TetraethyIdithionopyro phosphate (C2H5O)4P20$2 .- Tetraethylenepentamine 1U1J H9N(CH2CH2NH)3 CH2CH2NH2 1014. Tetraethyl Lead Pb(C2H5)4 1015. Tetraethyl Pyrophosphate (C2H50)4P203 1016 Tetrahydrofuran C4HgO 3,4,7,7a*Tetrahydro-4,7Methanoindene, sea Dicyclopentadiene 1017, Tetrahydronaphthalene C10H12 Waste Dis posal Pro cedure (See VI) TLV (ACGlHi PPM (mg/M3) NFPA 704M System Health Fire React. Sp. Gr. j7b 3i 1 19 7a 2 1 0 99 Vap. Dens. <Air=1) FI. Pt. C (F) Ignu, Temp, C lsF) Flam. Limits 163oc (325) B.P. C (FI 138 1280) 333 (631) M.P. C (F) Sol. in HjO > Other g/IOOg | Solvents 1 Mi$c. Rat. msoi ! ale - 1 . 4b 1.075) 1 3 Skin 2 3 i 1 66 S6 93 (206) 170exp. -137 (338) (-215) insol ale bz MCA 7b 18 200 i3 21 3 1 !, 1 20 89 ] 155 (311) 1] ; 25 -14 ' 321 2-11.8 65 | (6) | (610) | (151) qo 1 ale ace -65 (-85) v sol ' org , sol i SDH i i > i1 : !1 i1 18 1 12 10 1 .97 i 455 1 71 384 .8-5 207 -30 msol j itlc 1I j (160) (723) @302 F (405) (-22) 1018. Terralin, see Tetrahydronaphthalene 1019 N, N,NJ. N'-Tetramethy1-3,3'* Dimethoxybenzidine CiSh2402^2 N,N,N',N'Tetramethylethy020 lenediamine (CH3)2NCH= CHN(CH3)2 1021. Tetramethyl Lead Pb(CH3)4 i j 6 6 i ; CAR ii ' ; : 2 .78 4b ( 075) 3 Skin 3 3 1.99 6.5 38 (100) 121 (250) sol. 110 (230) -28 (-18) insol. ale., bz. 1022 Tetramethyl Silane S.(CH3)4 26 3 65 27 (81) eth. PAGE 110 CMA 045912 SUBSTANCE/FOBMULA Waste 1 D's- j TLV posal Pro cedure (See VI) (ACGIH! PPM (mg/M3) NFPA 704M System Health Fire React. Vap. Sp. Dens. Gr. (Air=1) 1023 ^1024 Tetramethyl Succinomtrile NCC(CH3)2C(CH3)2CN Tetramethylthiuram Disulfide (Thiram) (H2NCSCH3)452 j i i! 14 j 1 5)3 - 1' 1 - ! 1.30 1 1 ' 13 * (51 2 , ( 1,3 1i!:1! __________ _____________________ i__________ l______________ ____________ 1 q26 Tetramtromethane CIN02M 4a 1 |3 )3 !- 11! 1 64 | FI, Pt. C lF) ignit. Temp. C (F) Flam. Limits % B.P. G !F> 1 M.P. *C (F) Sol. in HjHD g/1OOg Other j Solvents j Misc, Ref. 190subl (374) 5) SOl ' !' 70 (158) ------------------ ---------------- 126 I (259) | 13 (551 insol sf sol , <i!cm ! ------------ 1 ' ale | - - Tetryi, see N-Methyl'N-2, 4,6-Tetramtroariiiine 1026 Thallium Tl j 11) J ' js| j1 ! i'| !1^ 27k | ; Skin I 3 ; ,- 11,9 I1 - iMl1!1 :- 1- ! 1460 ; 304 ! insol. i 1 ; 12660) ' (579) J I - j! | 1027, Thallium, soluble compounds j ; ! 27k ' (,1) i Skin 1 3- ! 1 j J 1 1028, Thellous Sulfate 1! J 27k i ,3; '1 i- j 6,77 1 j , , ti2so4 111>[' I! _________________________________________ i__________ i__________ _____________________ L______ :__________ ,__________ ________ : j1029 Thioacetamide 13 1 2 . !- . ,. . ch3csnh2 j; ''1 ,, - 1030 2,2'-Thiodiethanol (CH2CH2OH)2S 1031, Thioglycolhc Acid hsch2-cooh 1032 Thionyl Chloride SOCI2 1033, Thionyl Fluoride SOF2 I 13 j 13 |1 ! Is 1 ! | 3 j21 ` - 11i 21 1 i 3 i- |j 1 0 ; 1,1a 1 4.2 ;1 1 35 ' i 1,64 2.93 16Qdc. (320) 1 ' ] . 1 ) i 1 , 1 1 1 dec, ! i. ! 632 (1170) 115 (239) 20 4,9 j ! v sol j ale. 1 t 28 (82) -11 (12) w 105 (221) >11 rtlm -17 (1) 76 ~1Q5 (169) (-157) 00 dec. ale ale bz. BDH BDH -44 1-47) -110 (-166) dec bz., ace. PAGE 111 CMA 0459X3 SUBSTANCE/FORMULA 1034. Thiophene C4H4S 1035. Thiourea NH2CSNH2 Tbiram, see Tetramethyl Thigram Disulfide 1036 Thorium Th 1037 Thorium Nitrate Th(N03)4 1038. Tin Sn 1039. Tin, Inorganic compounds 1040 Tin, Organic compounds 1041. Titanium Ti 1042 Titanium Dioxide (rutile! T1O2 1043 Titanium Tetrachloride T1CI4 1044. Toluene CeH5CH3 PAGE 112 Waste Dis posal Pro cedure (See VI! tlv (acgihi PPM Img/M3) 13 NFPA 704M System Health 2 Fire React. 1 3! Sp. Gr. 1.06 Vap. Dens. (Air=1) FI. Pt. C (F) Ignit. Temp. <* Flam. Limits % 29 -1 (30) B.P. C (FI 84 (183) M.P. C lF) Sol. in H2O g/lOOg Other i Solvents Misc, Ref, -38 (-36) org , sol ] BDH 13 1 1.41 1 dec. 181 (358) sol. ale -.M i I vJ 11 If27k 2 ;117 | j j 4500 { (8100) 1827 (3321) in$ol AIA U__________ !___________ 1________ _1 27k 0 1 ' 11 27a (2) 0 1 i- 5.75 ! - j i j! 11 (2) variable, oxides toxic 26 i.i) 3 ' j' i - ! I! 500dec, (932) v sol ale. 2260 (4100) 232 (450) insol, ! 1 most soluble 1n1** 27a (15) 0 26 (15! 1b 5 30 18 200 23 45 4,26 700-800 (12921472) 3262 (5432) 1800 (3146) insol. ''-2700 (4890) 1840 (3344) msol. AIA I* 1 1.73 136 (277) -30 (-22) sol. ale BDH, NSC il J I0 87 3.1 4.4 (40) 536 (997 1.4-6.7 111 (231) -95 (-139) msol ale., bz., cs2 AIA, BDH,NTTC MCA J CMA 045914 substance/fohmula 1045 Toluene-2i4'dii$ocysnate CH3C6H3|NCO)2 Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M*1) NFPA 7Q4M System Health Fire React. 6 ,02C 2 1 2 Ignit. Vap. FI. Ft. Temp. Flam. B.P. Sp. Dens. C c Limits C Gr. (A.r=1) (F) <F) % lF) l 2 60 132 I270)oc 9-9.5 251 (484) M,P. C lF) Sol. m HjO g/IOOg Other | Solvents j Misc. Ret, 20 (68) A|A, MCA Q-Toluenethiol. see Benzyl Mercaptan 1046 l'O-Tolylazo'2-Naphthol C17H14N2O 8 CAR Totylene Dusocyanate, see Toluene-2,4-Diisocyanate o-Tolyl Phosphate, see Tritolyl Phosphate ! 1047, m-Toluidine CH3C6H4-NH2 5 3 2 0 99 3.9 86 482 (1871 (900) 203 (398) -31 S). 501 (-24) ale. BDH,MCA 1048. o-Toluidme CH3-C6H4-NH2 5 53 2 0 1 004 37 85 482 Skin (185) (900) 200 (392) -16 (3) sl. sol. ale. BDH. MCA 1049. p'Toluidine CH3C6H4-NH2 1049a. Transite Toxaphene, see Chlorinated Camphene 5 26 3 2 0 1.046 | 3.9 87 482 (189) (900) I | 200 (392) 44 (111) si. sol. ale. BDH.MCA 1050, Tremolite Ca2Mg5Si8024H2 1051 Triamyiamine (CsH1l)3N Tribromomethane, see Bromoform 26 7a 2 1 0 .8 7.8 102 (215) 232 (450) ale., ace. PAGE 113 CMA 045915 substance/formula 1052 Tri-n-Bufyl Amine (C^^N *053, Tnbutylchlorotm C^2H27SnCI 1054. Tributyl Phosphate (C4H9O3 PO 1055 Trichloroacetic Acid C CI3COOH Trichloroacetaldehyde, see Chloral 1056. Tnchloroacetortitrde CCI3CN 1057. Trichloroacetyl Chloride CCl3COCI 1058 1,2,4-Trichlorobenzene C6H3CI3 1059, 1,1,1-Trichloroethane CH3CCI3 1060. Trichloroethylene ClCHCCfg Trichiorofluoromethane, see Fiuorotrichloromethane Waite 1 NFPA Oil- j TLV 704M System Ignit. posal Pro cedure (See VI! (ACGIHI PPM (mg/M3) Health 7a 2 4b Fire , 1 1 ! !!2 React, i ; 0| ; Vap. Sp. Dens. Gr. (Air=1) 1 .8 1 6.38 FI. Pt. C (F) 86 (187) Temp, C (F) Flem. Limits % -; - - 1;1 B.P. C (F) 216 (421) 174 (345) M.P C (F) -70 (-94) 30 (86) Sol. in HjO Other g/1Q0g Solvents Mtsc. Ret, !1 si. sol. 1 ale. ! 11 80H 7b IS) 2| 1 0 1 .97 1 9.2 [ 146 1 S 292 ; <-80 sol. ale . bz., 15581 j (<-112) 1 csj I1!!! j jt29S> 1_____________________ 1 j 1 i ! !| |4c | !3 - - | 1.63 j -| 198 58 v. sol, ale. BDH i(388) i (136) j! j| 1l i !1 j i i | j | j1 1 :- 1 j - ! j . . i14 1 1.44 - ! i - !1 i I l ][la 3 1.63 _ L_ ;_ , 1. 04b 1.45 6.3 99 ' 1 2 (2101 III' 85 -44 (185) i (-471 1 1 118 (244) dec, dec., ale. 214 (417) 17 (63) msol. si. sol., ale 26 350 2 1.34 4.6 none 74 (165) -38 (-36) m$ol ale. AIA, NTTC. MCA 4b 100 2 1 1.46 4.54 32 (90) 410 (770) 12.5-90 87 (188) -73 ('99) si. sol, ale. AIA, BDH. NTTC. MCA, NSC Trichloromethanethiol, see PerchJoromethyl Mercaptan PAGE 114 CMA 045916 SUBSTANCE/FORMULA 1061 Trichloronaphthalene Cl0H5Cl3 W Tricbloronitromethane, w see Chloropicrin Waste Dijr posel Pro cedure (See VI) TLV IACGIH] PPM (mg/M3) NFPA 704M System Health Fire React. 4b (5) 2 Skin Ignit. Vap. FI. Pt. Temp. Flam. S.P. Sp. Dens. C C Limits "c Gr. (A.r=1) (F) <F) % (F| ! M.P. C (F) Sol. in H2O fl/IOOg Other Solvents ! [ 1 { j Misc. Ref. 133 (271) alc.h 1062- 2,4,5'Trichlorophenoxy Acetic Acid CI3C2H2OCH2COOH 4c ve 1063, 1,2,3-Trichloropropane C3H5CI3 4b 50 1064, 1,1,2-Trichloro-1,2,2-Trifluoro Ethane CI2FCC Cl F2 26 1000 Tricresy! Phosphate, see Tritolyl Phosphate 1065, Tridecanol CH3(CH2)iiCH2OH 1066, Tnethyl Aluminum <C2HS)3AI 18 3 3 3 2 0 j 1.39 5.0 - ! 1.56 1 ____ _____, | i ,82 6,9 167 (315) 1 82 <180)OC 304 3,2-12.6 (579) 156 (313) -- 15 (5) si .sol si. sol. ale. 680 (1256) 48 (118) -36 (-33) msol ale., bz. 121 (250) 274 (525) 31 (88) insol. ale. ,84 <-53 <-53 194 -53 exp.H20 (<--63) K-63] (381) (-63) AIA 1067. Triethyl Amine <c2h6i3n 7a 25 2 3 0 .73 3.48 <-7 l<--20)oc 1.2-8,0 89 (192) -115 (-175) sol. ale. BDH 1068. Triethanolamine ICH20HCH2)3N 7a 1 1 1 1,13 179 (355) 360 (680) 20 (68) 06 ale. 1069. Triethylene Glycol Triethy (CH2OCH2CH2OH)2 18 1 1 0 1.13 5.17 177 371 ,9-9.2 276 -4 03 ale. (350) (700) (529) (25) 1070. Triethylene-Tetramine H2NCH2(CH2NHCH2)2CH2 nh2 7a 3 1 0 ,98 136 (275) 338 (640) 267 (513) 12 (54) sol. ale. BDH PAGE 115 CMA 045917 SUBSTANCE/FORMULA 1071. Triethyl o* Formate (C2HS0)3CH *1072. Trifluoroacetic Acid CF3COOH 1073. Trifluoromathane chf3 1074, Triisobutyl Aluminum {C4H9>3AI 1075. Tnmethyl Amine (ch3)3n Waste Dis posal Pro cedure (See VI) TLV (ACGIH) PPM (mg/M3) NFPA 704M System Health Fire React. 18 3 2 Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dans. C C Limits C Gr. (Air=1) (F) <F| % (F) .89 5.1 30 (86) 146 (295) M.P, c (F) Sol. in H7O g/lOOg Other Solvents dec ale 4c 3 1.54 3 92 72 (162) -15 (5) sol. 26 2 1.52 -84 (-119) -163 (-261) si. sol. sic. 3 33 .79 <0 <4 114 4 {< 32) K39) (237) (39) 7a 3 4 0 66 2,0 -13--8 190 2-11,6 4 -117 V. sol. ale., bz. (8-18) (374) (39) (-179) Misc. Rat, BDH BDH AlA BDH, MCA, MGS 7076. 5,9,10-TrimethyM,2-Benzanthracene (^3)30^8^3 IS CAR 1077. 6,9,10-Trimethyl-l .2-Benzan thracene (^3)30^8^3 18 CAR 1078 Irimethyl Borate B(OCH3)3 18 2 3 1 .92 3.6 <27 80) 67 (153) -29 (-20) dec. MeOH 3,5,5-Tnmethyl-2-Cyclohexe* none, see iso-Phorone 1079. 2,2,4-Trimethyl Pentane (CH3)3CCH2CH(CH3)2 1080. 2,4,4-Trimethyl-2-Pentane {CH3)2C=CHC(CH3i3 1081. 1,3,5-Trinitrobenzene CeH3(N02)3 18 18 6 2 3 0 .69 3.9 -12 418 1.1-6.0 99 -107 insol. si. sol., BDH (10) (784) (210) (-161) ale- - 3 0 .72 3.9 2 (35) 112 (234) -107 (-161) insol. 2 4 4 1.69 exp. 121 (250) si. sol. ace., bz. PAGE 116 CMA 045918 SUBSTANCE/FORMULA Trinitrophenoi, $ee Picric Acid Hb82. 2,4,6-Trinitrotoluene W CH3C6H31M02}3 1083. 1,3,5-Tnoxane OCH2OCH2OCH2 1084 Triphenvt Phosphate IC6H5D)3PO 1085 Triphenyl Phosphine (C6H5I3P 1086. Tripropylamine <C3h7*3 N ]087, Trisodium Phosphate Na3PQ4'12H20 Triton, see Trinitrotoluene 1088. Tritolyl Phosphate {CH3C6H4)3P04 1089. Turpentine ClOH16 1090. Unsymrnetrioal Dimethyl Hydrazine (CH3)2NNH2 1091. Uranium U Wu Du- 1 TLV poul Pro* cedure (See VI) (ACGIHI PPM (mg/M3) IMFPA 704M System Health Fire React. Ignit. vap* PI. Pt. Temp. Flam. S.P. Sp. Dent. C C limits c Gr. (Air=1) (fiF) (F) % (F) M.P. C (9F) Sol. in HjO g/IOOg Other Solvents Mi$c. Ret 6 (1.5) 2 4 4 1.65 Skin exp. 240exp 81 (464) (178) insol, ace., bz. 18 2 2 0 1.17 7b (31 2 1 0 1.21 45 (113)oc 414 (777) 3 6-29 115 (239) 62 (144) 220 (428) 245 (473) @11 mm 49 (120) v. sol. ale., bz 2 insol ale., bz 7b 32 1.19 180 (356)oc >360 (680) 80 (176) insol. ale., bz. 7a 2 2 0 .75 4.9 41 (1Q6)oc 11 2 1.62 156 (313) -94 (-137) si. sol. ale. 74dec. si. sot. (165) 7b 2 1 0 1.17 12.7 225 386 410 11 (437) (725) (770) (52) AlA, BDH 18 100 1 3 0 .87 4.6 35-39 253 .8- 153-75 (95*1021 (487) (307-47) AIA 16 .5 3 3 1 .79 1,94 '''-15 249 2-95 63 -58 v. so). ale., MeQh MCA r-5> (480) (145) (-72) 27k (.05) 3 3 19.05 3818 (6905) 1130 (2066) insol. AIA PAGE 117 CMA 045919 t SUBSTANCE/FORMULA Waite Dis posal Pro cedure (See VI) TLV (ACGIM) PPM (mg/M3) NFPA 704M System Health Fire React. 1092 Uranium, Insoluble Compound* 27k ,25 3 Ignit. Vap. FI. Pt. Temp. Flam. B.P. Sp. Dens, C C Limits C Gr. (Air=1) PF) PF) % m M.P. C PF) Sol. in h2o g/IOOg Other | Solvents 1 Mist Rgf insol, 1093 Uranium, Soluble Compounds 1094 Uranium, Nitrate UQ2(NQ3>2 6H2O 27k 27k (.05) (.05) 3 1 0 2.81 1095 Urea H2NCONH2 1096 Valeraldehyde CH3CH2CH2CH2CHO 26 |2 | 0 1.32 .81 1097 Valeric Acid C4H9COOH 24a - 1 ,94 1098, Vanadium Oichlonde vci2 27L 3 3.23 1099 Vanadium Oxytrichloride VOCI3 1100 Vanadium Pentoxide V205 1100a. Vanadyl Sulfate VOSO4 27i (.1) - ---------------27i ( 1) ; - I 27i 2 1 83 :1 2 - 336 'i 1101 Varnish 18 3 0 1102 Vinyl Acetate CH3COQCHCH2 18 2 3 2 .94 Vinyl Bromide, see Bromoethylene Vinyl Butyl Ether see Butyl Vinyl Ether i \ 118 (244) 59 (138) sol 00 dec. 133 v, sol. ale,, ace, j ale. NTTC 3.0 12 (54) 3,5 96 (205)oc 102 -92 sl. sol (217) (-134) ale 186 (367) 35 ! sol (-31) ! ale. i dec ! ale j NTTC ! 1! 127 -77 (261) (-107) dec ] 1750dec,j 690 j sl, sol, 1 (3182) ; (1274) , ] ale 1 I 176-248 | 3.0 -8 427 2 6-13 4 73 -100 insol. (18) (800) (163) (-148) NTTC org. sol. NTTC, MCA PAGE 118 CMA 045920 SUBSTANCE/FORMULA 03. Vinyl Chloride ' CH2CHCI Vinyl Cyanide, ^ see Acrylonitrite 1104 Vinyl Ether CH2CHQCHCH2 1105' Vmylidene Chloride CH2CCI2 Vinyl Toluene, see Methyl Styrene 1106. Warfarin C19H16O4 1107, Xenon Xe Xenylamme, see 4-Biphenylamme 1108. m-Xylene C6H4(CH3)2 1109. o-Xylene C6H4(CH3)2 1110 p-Xylene C6H4(CH3l2 1111. Xylenol C6H3(CH3)2 0H Waste Dis posal Procedure (See VI! TLV 1 IACGIH): PPM i (mg/M3) j NFPA 704M System Health Fire React. 4b 500C 2 4: 21 Vap. Sp, Deni. Gr, (Air=1) ,91 ; 2 15 FI. Pt. C (F) -78 (-108) Ignit. Temp, C (F) 472 (882) I-]! lil! Flam. Limits % 4-22 B.P, C (F) -14 (7) l 15 2 3| 2 | .77 2 4 <-30 | 360 1.7.27 i 39 (<--221 (6801 (102) M,P, C (F) Sol. in H2O g/IOOg Other Solvents ' Mi$e, Ref, -- 154 si. sol. (-245) ale. MCA ale. ace. 4b 5 2 4 2 1.3 3 4 -15oc' 458 5.6-11.4! 37 -122 msol. (5) (856) (99) (-188) MCA 18 (,1) 26 !! 5 ! !_LJ ' 0 5.89 i ! -- ---------------- 161 (322) msol ale., ace. -108 -112 (-162) (-170) 240 18 100 2 3 0 .87 29 (84) 528 (982) 1.1*7,0 139 (282) -48 (-54) insol. org, sol Al A BOH, NTTC, MCA 18 100 2 3 0 .90 11 32 464 1.0-6.0 144 -26 insol. org. sol Al A (90) (867) (291) (-15) BDH. NTTC. MCA 18 100 2 3 0 .86 27 (81) 529 1.1-7.0 (984) 138 (280) 13 (55) insol. org. sol. Al A BDH, NTTC. MCA 18 3 218 (424) 75 (167) si. sol. ale. BDH PAGE 119 CMA 045921 SUBSTANCE/FORMULA 1112. Xylidin C6H3(CH3)2NH2 1113. Yttrium Y 1114. Zinc Zn 1115. Zinc Acetate Zn(C2H302)2 1116. Zinc Chlorate Zn{CI03)2'4H20 1117. Zinc Chloride Zn Cl2 1118. Zinc Oxide ZnO 1119. Zirconium Zr 1120. Zirconium Compounds 1121 Zirconium Hafnium Powder Waste Die* pose! Pro' cedure (See vi) TLV (ACG)H) PPM (mg/M3) NPPA 704M System Health Fire React. 55 3 1 0 Sk/n Ignit, Vap. FI, Pt. Temp. Flam. B.P. Sp. Dens. C C Limits C Gr. (Air=l) (F) (F) % <F| M.P. C lF| Sol. in HjO g/IOOg i Other Solvents Misc. Ref, .99 4,2 97 (206) 224 (435) <-15 5) si. sol ale. 8DH 26 m 2 4,34 2927 (5300) 1500 (2732) si. dec. 27a (15) 11 12a 0 1 1 7,14 ii 0 1 - I 1 84 | 2j ! 0| i 2 \ 2,15 i 905 (1661) 419 (787) insol. 2P0dec. 30J0 (392) ale. 60dec. 26220 j ale., ace. (140) AIA 11 (1) 2 0 2 { 2.91 26 (5) 3 5.47 732 (1350) 283 (541) 43225 1975 (3587) sol. ale. 26 (5) 1 4 1 6.5 260 (500) 3578 (5252) 1850 (3362) insol. AIA, NSC 11 (5) 1 26 (5) 1 4 1 20 (68) insol. MCA. NSC PAGE 120 CMA 045922 section VI. WASTE DISPOSAL CM& 045923 --------------------------------------DISPOSAL PROCEDURE ORGANIC ACID HALIDES Wear: Rubber gloves, self-contained breathing apparatus (or work in an effective fume hood with full face shield), laboratory coat. Spills : Cover with sodium bicarbonate. If a small quantity is involved, scoop the mixture into a large beaker of water and let stand for a few minutes. Slowly pour into the drain with copious amounts of water. If a large quantity is involved, scoop the resulting bi carbonate mixture into a plastic bag, cardboard box or small fiber drum. This material can then be burned in an incinerator or spread on the ground and flooded with water. The site of the spill should be washed with soapy water. Package lots: Slowly sift or pour into a large glass or plastic vessel containing a layer of sodium bicarbonate. Mix thoroughly and add slowly to a large container of water with stirring. Slowly pour this mix down the drain with copious amounts of water. Examples Acetyl bromide Acetyl chloride Benzene sulfonyl chloride Benzoyl chloride Butyryl chloride Chloroacetyl chloride 3-Chloropropionyl chloride o-Chlorobenzoyl chloride Crotonyl chloride Dichloroacetyl chloride Oxalyl chloride Propionyl chloride Trichloroacetyl chloride CMA 045924 1b INORGANIC HALIDES Wear: Rubber gloves, self-contained breath ing apparatus (or work in fume hood), laboratory coat. For the more active compounds work from behind a body shield. Spills : Cover with excess sodium bicarbonate. If a small quantity is involved, scoop the mixture into a large beaker of water and let stand for a few minutes. Slowly pour into the drain with copious amounts of water. If a large quantity is involved, scoop the resulting bi carbonate mixture into a plastic bag, cardboard box or small fiber drum. This material can then be burned in an incinerator or spread on the ground and flooded with water. The site of the spill should be washed with soapy water. Package lots: Sift or pour onto a dry layer of sodium bicarbonate in a large evaporating dish. After mixing thoroughly spray with 6M-NH.1OH while stirring. Cover with a layer of crushed ice and stir. Con tinue spraying with 6M-NH.,OH. When the smoke of NH^CI has partly sub sided add iced water and stir. Dump this slurry into a large container. Re peat until all has been treated. Neu tralize* and slowly siphon the sus pension into the drain with excess running water. * If excess of 6M-NH,OH has been used, neutralize with 6M-HCI (use litmus paper indicator), if acidic, neutralize with 6M-NH,OH. Examples: Aluminum bromide, anhydrous Aluminum chloride, anhydrous Chlorosulfonic acid Ferric chloride, hexahydrate Germanium tetrachloride Silicon tetrachloride Stannic chloride Tin tetrachloride Titanium tetrachloride PAGE 124--DISPOSAL PROCEDURE lb INORGANIC HALIDES CMA 045925 DISPOSAL PROCEDURE Wear: Rubber gloves, self-contained breathing apparatus, laboratory coat. SpillS : Eliminate all sources of ignition and flammables. Small--Absorb on paper towel. Evapo rate in fume hood and burn the paper. Large--Cover with sodium bisulfite (NaHSO:i). Add small amount of water and mix. Scoop into large beaker. After one hour wash down the drain with a large excess of water. Wash site with soap solution. Package lots: (CHOICE OF PROCEDURES) 1 Absorb on vermiculite. Burn in an open pit or open incinerator, 2 Dissolve in a flammable solvent (such as acetone or benzene). Spray into the fire-box of an incinerator equipped with an afterburner. Examples Acetaldehyde Acrolein Acrolein dimer o-Anisaldehyde Benzaldehyde Butyraldehyde Caprylaldehyde Chloral Chloralhydrate Chloroacetaldehyde Cinnamaldehyde Crotonaldehyde iso-Decaldehyde 2-Ethyl-3-propylacrolein Formaldehyde Formalin (MeOH free) Formalin (15% MeOFI) Furfural Glutaraldehyde Gfyoxal Paraformaldehyde Paraldehyde Propionaldehyde Salicylaldehyde Valeraldehyde ALDEHYDES DISPOSAL PROCEDURE 2--PAGE 125 CMA 045926 ^ DISPOSAL PROCEDURE----------------------------------------- ^ ALKALI AND ALKALINE EARTH METALS, METAL ALKYLS, AND ALKOXIDES Wear: Leather gloves, large face shield, labo ratory coat. (Class D fire extinguisher should be available) SpiUS : Small--Cover with excess dry soda ash or sodium bicarbonate. Mix and add slowly to butyl alcohol. After 24 hours dilute and add to drain with large excess of water. Package lots: OR Large spill--Mix with dry soda ash or sodium bicarbonate. Scoop into a dry bucket. In a remote area spread onto a large iron pan. Cover with scrap wood, paper and ignite with an excelsior train. OR--Burn in an open pit incinerator. OR--Direct "dry" steam onto the waste, spread on an iron pan. Beware of splatter. Examples: Aluminum alkyls Aluminum ethoxide n-Butyllithium Calcium Chlorodiethylaluminum Diethyl zinc Lithium Potassium Sodium Sodium ethoxide Sodium methoxide Sodium-potassium alloys Triethyl aluminum Triisobutyl aluminum WARNING: Possible Violent Reaction with Water PAGE 126--DISPOSAL PROCEDURE 3 ALKALI AND ALKALINE EARTH METALS, METAL ALKYLS, AND ALKOXIDES CMA 045927 ------------------------------------DISPOSAL PROCEDURE CHLOROHYDRINS, NITROPARAFFINS Neoprene gloves, plastic laboratory coat, self-contained breathing appara tus. Provide good ventilation. Spills : Eliminate all sources of ignition. On skin--Wash immediately with soap solution. Rinse thoroughly. On clothing--Remove clothing immedi ately and place in a fume hood. Wash clothing before wearing again. Shoes are difficult to decontaminate and may have to be discarded and burned. On bench and floor--Cover with soda ash. Mix and spray with water. Scoop into a bucket of water. Let stand two hours. Neutralize* and wash into sewer with large excess of water. Wash site with soap solution. * Neutralize with 6M-HCI, Package lots: (CHOICE OF PROCEDURES) 1 Pour or sift over soda ash. Mix and wash slowly into large tank. Neu tralize and pass to sewer with excess water. 2 Absorb on vermiculite. Mix and shovel into paper boxes. Drop into incinerator with afterburner and scrubber. Examples: iso-Amyl nitrate iso-Amyl nitrite 1-Chloro-l-mtropropane Chloropicrin Cyc Ionite 1,1-Dichloro-l-nitroethane EPN Ethylene chlorohydrm Ethylene nitrate Ethyl nitrite Methyl ethylmtrosocarbamate Nitroethane Nitromethane Nitropropanes Propyl nitrate Tetranitromethane CMA 045928 DISPOSAL PROCEDURE_______________________ ORGANIC HALOGEN AND RELATED COMPOUNDS Wear: Rubber gloves, self-contained breath ing apparatus, laboratory coat. Spills : Eliminate all sources of ignition. Ab sorb on paper towels or with vermiculite. Place on an iron, glass or plastic dish in a hood. Allow to evaporate. Burn the paper or vermiculite. Wash site with soap solution. Package lots: (CHOICE OF PROCEDURES) 1 Pour onto vermiculite, sodium bi carbonate or a sand-soda ash mixture (90-10). (If a fluoride is present, add slaked lime to the mixture.) Mix and shovel into paper boxes. Place in an open incinerator. Cover with scrap wood and paper. Ignite with an excelsior train; stay on upwind side. Or dump into a closed incinerator with afterburner. 2 Dissolve in a flammable solvent. Spray into the fire box of an inciner ator equipped with afterburner and scrubber (alkali). Examples: Aldrin Allyl bromide Allyl chloride Allyl chloroformate Allyl iodide Amyl bromide Benzal chloride Benzotrichloride Benzotrifluoride Benzyl bromide Benzyl chloride Benzyl chloroformate Bromobenzene Bromoethane Bromoethylene o-Bromotoluene n-Butyl bromide n-Butyl chloride t-Butyl chloride Chlordane Chloroacetophenone Chlorobenzene Chlorocresols Chlorodiphenyl 2-Chloro-2-methyl propene Chloronaphthalene PAGE 128--DISPOSAL PROCEDURE 4b CMA 045929 -----------------------------------DISPOSAL PROCEDURE EXAMPLES--Continued Chioroprene Chlorotrifluoroethylene Dibutyf dichlorotin 1,4-Dichlorobutane 1, 3-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethylene 1,2-Dichloropropane 1,3-Dichloropropene Dieldrin Diethyl aluminum chloride Diethyl sulfate Dimethyl sulfate Dimethyl sulfoxide Dodecyl sodium sulfate Epichlorohydrin Ethyl bromoacetate Ethyl chloride Ethyl chloroacetate Ethyl chloroformate Ethylene dibromide Ethylene dichloride Ethyl fluoride Ethyl fluoroacetate Ethyl iodide Fluoroethylene Heptachlor Hexachlorobenzene Hexachloronaphthalene Lindane Methoxychlor Methyl bromide Methyl chloride Methyl chloroformate Methyl iodide Octachloronaphthalene Octafluoro-2-butene Octafluoropropane Pentachloroethane Pentachloronaphthalene Pentachlorophenol Propargyl bromide Propyl bromide Propyl chloride Propylene disulfate Sodium fluoroacetate Sodium pentachlorophenate 1,2, 4, 5-Tetrachlorobenzene Tetrachloroethane Tetrachloroethylene Tetraethyl lead Tetramethy! lead Tributyl chlorotin 1,2, 4-Trichlorobenzene Trichloroethylene Trichloronaphthalene 1,2,3-Trichloropropane Vinyl chloride Vinylidene chloride CMA 045930 4c SUBSTITUTED ORGANIC ACIDS Wear: Rubber gloves, self-contained breath ing apparatus or all-purpose canister respirator, laboratory coat. Spills : Eliminate all sources of ignition. Turn on the fume hood if acid is volatile. Cover the spill on bench and floor with excess sodium bicarbonate and vermiculite. Mix and scoop into a large beaker of water. When reaction is com plete, pour down the drain with a large excess of water. Wash site with soap solution. Package lots: (CHOICE OF PROCEDURES) 1 Pour onto excess sodium bicarbo nate. Mix and scoop into a bucket. Dump into a 55-gal. drum and fill with water. After 24 hours slowly pour into drain with large excess of water. 2 Pour onto vermiculite in an open incinerator. Cover with scrap wood and paper. Pour waste alcohol over all and ignite with an excelsior train. Stay on upwind side. 3 Dissolve in a flammable solvent such as waste alcohol. Spray into an incinerator with an afterburner and scrubber. Examples: Benzene sulfonic acid Bromoacetic acid Chloroacetic acid Dichloroacetic acid Ethylenediamine tetracetrc acid (EDTA Fluoroacetic acid lodoacetic acid Methanesulfonic acid Trichloroacetic acid 2,4, 5-tnchlorophenoxy acetic acid Trifluoroacetic acid CMA 045931 -------------------------------------------DISPOSAL PROCEDURE AROMATIC AMINES Butyl rubber gloves, plastic laboratory coat, self-contained breathing appara tus. Spills: On skin and clothing--Wash skin with strong soap solution immediately. Rinse thoroughly. Contaminated cloth ing should be removed, dried, and washed with strong soap solution--or destroyed. It may be necessary to de stroy shoes by burning. Small spills--Absorb liquids on paper towels. Brush solids onto paper. Place in an iron pan and allow evaporation in the fume hood. Add crumpled paper and burn. Wash site with strong soap solution. Large spills--Cover large spills with sand and soda ash mixture (90-10). Mix and shovel into a cardboard box. Pack with much excess crumpled paper. Burn in an open pit or in an incinerator with afterburners and scrubber. Package lots: (CHOICE OF PROCEDURES) 1 Pour or sift onto a thick layer of sand and soda ash mixture (90-10). Mix and shovel into a heavy paper box with much paper packing. Burn in incinerator. Fire may be augmented by adding excelsior and scrap wood. Stay on upwind side. 2 Waste may be dissolved in flam mable solvent (alcohols, benzene, etc.) and sprayed into fire box of an inciner ator with afterburner and scrubber. Examples: Acridine 2-aminodiphenylene oxide 2-aminopyridine Aniline Anisidines 2-anthramine Auramine Aziridine Benzidine* Benzyl amine N-4-biphenyl acetohydroxamic acid 2-biphenyl amine Chloroanilines 1,2, 5,6Dibenzacridine 1,2, 7,8Dibenzacridine 1,2, 5,6Dibenzcarbazole 3,4,5,6Dibenzcarbazole ibenzyl amine Carcinogenic N, N-diethyl aniline 3,3'-dimethoxy benzidine* N, N-dimethyl aniline Diphenyl amine N-ethyl aniline Ethyl morpholine l-methyl- 2-naphthylamine Morpholine 1- naphthylamine 2- naphthylamine* Nicotine p-phenylenediamine Phenylethanolamine Phenyl- 2-napththylamine Picolines Pyridine Quinaldine Quinoline 8-Quinolinol 4-Stilbenamine Strychnine Toluidines Xylidines AROMATIC AMINES DISPOSAL PROCEDURE 5--PAGE 131 CMA 045932 JL DISPOSAL PROCEDURE----------------------------------------- AROMATIC HALOGENATED AMINES and NITRO COMPOUNDS Wear: Butyl rubber gloves, protective labora tory coat, self-contained breathing apparatus, protective shoes. Spills: On skin--Wash with strong soap solu tion immediately. Rinse well. Contaminated gloves, clothing, shoes-- Remove and clean at once or destroy by burning. Small spills on tables or floor--Absorb liquid spills on paper towels or vermiculite; sweep solid spills onto paper. Put on an iron pan in the fume hood and allow to evaporate. Burn the paper or vermiculite in the absence of other flammables. Wash the site thoroughly with strong soap solution. Large spills--Absorb or mix with ver miculite, sodium bicarbonate or sand. Package this in a paper carton and burn in an open pit. Use fuel such as crumpled paper and wood splinters. Wash site thoroughly as above. Package lots; (CHOICE OF PROCEDURES) 1 Pour or sift onto sodium bicarbo nate or a sand-soda ash mixture (90-10). M ix and package in heavy paper cartons with plenty of paper packing to serve as fuel. Burn in an incinerator. Fire may be augmented with scrap wood. 2 The packages of #1 may be burned more effectively in an incinerator with afterburner and scrubber (alkaline). 3 The waste may be mixed with a flammable solvent (alcohol, benzene, etc.) and sprayed into the fire cham ber of an incinerator with afterburners and scrubber. Examples: Brucine Carbazole 1- Chloro-2.4-dinitrobenzene Chloro-2-naphthylamine Chloro-nitroanilmes Chloro-mtrobenzene Chlorophenols 2.6- Dibromo-N-chloro-p-benzoquinonimine 2, 5-Dichloroaniline Dichlorobenzene 3, 3'-Dichlorobenzidine* 1, 3-Dichloro 5, 5-dimethylhydantoin 2,4-Dichlorophenol 2- Dimethylammofluorene 9,10-Dimethyl-l, 2-benzanthracene N, N-Dimethyl-4-biphenylamme Dinitroaniline m-Dinitrobenzene** o-Dinitrobenzene** p-Dinitrobenzene** 4.6- Dinitro-o-cresol 2, 7-Dinitrofluorene 2, 4-Dinitrophenol** * Carcinogenic. ** Explosive. Other nitro compounds may also be unstable. PAGE 132--DISPOSAL PROCEDURE 6 AROMATIC HALOGENATED AMINES and NITRO COMPOUNDS CMA 045933 EXAMPLES--Continued 1,4-Dinitropiperazine k2,4-Dinitrotoluene** 'Elon Endrin 4-Ethoxy-2-nitroaniline N-2-Fluorenylacetamide 4-Fluoro-4-biphenylamine 2'-Fluoro-4'-phenylacetanilide 4'"-Fluoro-4'-phenylacetanilide Methylene bis-phenylisocyanate Methyl isothiocyanate N-methyl-N-nitrosoacetamide N-methyl-N-nitrosoallylamine N-methyl-N-nitrosoaniline N-methyl-N-nitrosobenzylamine DISPOSAL PROCEDURE 1-Methyl-l-nitrosourea N-Methyl-N-nitrosovinylamine 1-Methyl pyrole N-Methyl-N-2,4, 6-tetranitroaniline 3-Nitroacetophenone m, 0-, p-Nitroanilines Nitrobenzene Nitrobiphenyl 2-Nitrofluorene cc-Nitronaphthalene Nitrophenols 4-Nitroquinoline-N-oxide N-Nitroso-N-methylaniline 4-Nitrosomorpholine 1-Nitrosopiperazine N-Nitrosopiperidine m-t o-, p-Nitrotoluenes Picric acid** Piperidine Tetrachloronaphthalene N, N, N', N'-tetramethyI-3, 3'-dimethoxy benzidine N, N, N', N'-tetramethylenediamine Toluene-2,4-di isocyanate Trinitrobenzene** Trinitrotoluene** ** Explosive. Other nitro compounds may also be unstable. DISPOSAL PROCEDURE 6--PAGE 133 i CMA 045934 7a is ALIPHATIC AMINES Wear: Butyl rubber gloves, face shield or all purpose canister respirator, laboratory coat. Spills. Liquid or solid--Cover with sodium bi sulfate. Spray with water and wash into drain with large excess of water. Package lots: (CHOICE OF PROCEDURES) 1 Add the contaminated amine to a layer of sodium bisulfate in a large evaporating dish. Spray with water. Make neutral and wash into the drain with large excess of water. 2 Dissolve in a flammable solvent (e.g., waste alcohols). Burn in an open pit by means of an excelsior train. Stay on the upwind side. 3 Solution of #2 may be sprayed into the fire box of an incinerator with afterburner and scrubber. Examples. Allyl amine Amyl amine Aminoethylethanola- mine Butyl amine iso-Buty! amine Tert-Butyl amine Cyclohexylamme Dibutyl amine Dicyclohexylamine Diethanolamine Diethylamine 2-Diethyl aminoethanol Diethylenetriamine Diisopropylamine Dimethylamine Ethanolamine Ethylamine Ethylene diamine N-Ethyl-N-nitrosoN-butylamine N-Ethyl-N-N nitrosovinylamine n-Heptylamine Hexamethylenetetra mine 1-6-Hexanediamine Hydroxylamine Hydroxylamine hydrochloride Lutidine N-Methylbutylamine Monomethylamine N-Nitrosodiethanola- mine N-Nitrosodimethyla- mme* 1, 3-Propanediamine Propyl amines Propylene imine Pyrrolidine Tetraethylenepenta- mine Triamylamine Tri-n-butylamine Tri-ethylamine Triethanolamine Triethylene tetramine Trimethylamine Tripropylamine * Carcinogenic. PAGE 134-DISPOSAL PROCEDURE 7a ALIPHATIC AMINES ft S3 f ,'t CMA 045935 _DISPOSAL PROCEDURE ORGANIC PHOSPHATES AND RELATED COMPOUNDS Wear: Rubber gloves, self-contained breath ing apparatus, laboratory coat. SpillS: Absorb with vermiculite or paper towels. Scoop the mixture into a plastic bag. Take bag outside to incinerator or pad and burn. If an incinerator is not avail able, set the bag in a pan of waste flammable solvent and burn. Package lots: (CHOICE OF PROCEDURES) 1 Take packages to an open incin erator. Stay on upwind side and mix with equal parts of sand and pulverized limestone. Wet down with a flammable solvent (benzene or alcohol). Ignite from a safe distance with an excelsior train. 2 Shovel mixture of #1 into a paper box and drop into an incinerator with an efficient afterburner. Alkaline scrub bing will prevent escape of any oxides of phosphorous and arsenic. Examples: 0-Chlorophenyl diphenyl phosphate Oibutyl phosphate Dibutyl phosphite Dichlorophenyl phosphine Diethyl ethyl phosphate Diisopropyl fluorophosphate Dimethyl-1,2-dibromo-2, 2-dichloro-ethyl phosphate Grain fumigants Hydroxy dimethyl arsine oxide Malathion Methyl parathion 1-Naphthyl isothiocyanate Parathion Phosdrin Ronnel Systox Tetra ethyl dithiono pyrophosphate Tetra ethyl pyrophosphate Tributyl phosphate Triphenyl phosphate Triphenyl phosphine Tritolyl phosphate s ORGANIC PHOSPHATES AND RELATED COMPOUNDS DISPOSAL PROCEDURE 7b--PAGE 135 CMA 045936 O DISPOSAL PROCEDURE O AZIDES and AZO-COMPOUNDS The organic azides and heavy metal azides are explosive. Alkali and alka line earth azides are not considered ex plosive under normal laboratory con ditions. Keep stock of all azides very low. Stamp date and receipt on package. Wear.- Leather gloves, heavy face shield, labo ratory coat. Work from behind a barri cade (body shield or wall). Avoid un necessary heat, friction or impact. Small spills : Absorb the liquid on paper or with vermiculite. If it is a solid, dampen and brush onto paper with great care. Place in plastic bag and take outside for burning. OR Sponge up with water, followed by de contamination with a 10% ceric am monium nitrate solution. Large spills or Package lots.- (CHOICE OF PROCEDURES) 1 Dissolve alkali or alkaline earth azides in a large volume of water. Wash into drain with a large volume of water. 2 Transfer organic azides and azo compounds, and azides of heavy metals to an open pit, preferably on an iron pan. Add paper and wood for fuel. Ignite by means of a long excelsior train. 3 "Kill" in a greater-tha n- stoichiometric amount of ceric am monium nitrate solution with agitation sufficient to provide suspension of all solids. Examples: 2,2'-A2onaphthalene Azoxybenzene Diazo methane Dimethyl amino azo benzene-2-naphthalene 2,3-Dimethyl-azo benzene Hydrazoic acid 3-Methyl-4-dimethyl ammo-azobenzene l-Phenylazo-2-naphthol l-Ortho-tolylazo-2-naphthol Sodium azide PAGE 136--DISPOSAL PROCEDURE 8 AZIDES and AZO-COMPOUNDS CMA 045937 DISPOSAL PROCEDURE CARBON DISULFIDE Wear: Rubber gloves, safety glasses, labora tory coat. If hood is not available wear self-contained breathing apparatus. Carbon dioxide fire extinguisher should be available. Spills: Eliminate flammables and all sources of ignition. Allow to evaporate or ab sorb with paper towels and evaporate in hood on an iron pan or glass dish. Bum the paper. Package lots: All equipment or contact surfaces should be grounded to avoid ignition by static charge. Absorb on vermiculite, sand, or ashes and cover with water. Transfer under water in buckets to an open area. Ignite from a distance with an excelsior train. If quantity is large, carbon disulfide may be recovered by distillation and repackaged for use. CARBON DISULFIDE DISPOSAL PROCEDURE 9--PAGE 137 CMA 045938 10 CAUSTIC ALKALI AND AMMONIA Wear: Rubber gloves, large face shield (wear all-purpose or special canister respira tor for Laboratory coat. Package lots: Pour into large tank of water and neu tralize. Transfer to sewer with large excess of water. Spills: Solid--Sweep up, dilute and neutralize with 6M-HCI in a large bucket. Wash down drain with large excess of water. Solution--Neutralize and mop up--or use water-vac. Discharge to sewer with large excess of water. Examples: Ammonia, anhydrous Ammonia, aqua Calcium hydroxide (slaked lime) Calcium oxide (quick lime) Potassium hydroxide (caustic potash) Sodium hydroxide (caustic soda) PAGE 138--DISPOSAL PROCEDURE 10 CAUSTIC ALKALI AND AMMONIA CMA 045939 DISPOSAL PROCEDURE INORGANIC SALTS Rubber gloves, safety glasses, labora tory coat. 1 Solutions--Cover with soda ash, mix and scoop into a beaker of water. Neutralize with 6M-HCI and wash down drain with excess water. 2 Solids--Collect m a beaker, Dis solve in large amount of water. Add soda ash, mix and treat as above. If spill contains a fluoride, add slaked lime in addition to the above treatment. INORGANIC SALTS Package lots: Examples Add slowly to a large container of water. Alums Stir in slight excess of soda ash. If fluoride is present add slaked lime also, Let stand 24 hours. Decant or siphon Aluminum chloride, hydrate Aluminum nitrate, hydrate into another container and neutralize with 6M-HCI before washing down drain with large excess of water. The sludge may be added to land fill. Aluminum sulfate, hydrate Ammonium fluoride Ammonium nitrate Ammonium thiocyanate Borax Calcium chloride Chromic (III) salts, hydrates Cobaltous nitrate Copper nitrate Cuprous chloride Ferrous Ammonium sulfate Ferrous chloride Ferrous sulfate Lithium carbonate Magnesium chloride Magnesium nitrate Manganese sulfate Molybdenum compounds (sol.) Nickel nitrate Nickel sulfate Potassium acetate Potassium carbonate Potassium ferrocyamde Potassium fluoride Potassium hydrogen difluoride Potassium nitrate Sodium acetate Sodium benzoate Sodium bicarbonate Sodi .Ti carbonate Sodium chloride Sodium fluoride Sodium formate Sodium hydrogen difluoride Sodium iodide Sodium nitrate Sodium phosphates Sodium propionate Sodium silicate Sodium tetraborate Stannic chloride, hydrate Trisodium phosphate Zinc acetate Zinc chloride DISPOSAL PROCEDURE 11--PAGE 139 1 CMA 045940 DISPOSAL PROCEDURE OXIDIZING AGENTS Wear: Rubber gloves, face shield, laboratory coat. Body shield should be available for the more active agents. Replace face shield with self-contained breath ing apparatus for such agents as chlo rine and bromine. Spills : 1 Gas leak: If the valve is leaking because it cannot be closed (a common occurrence), the gas can be bubbled through a reducer (sodium sulfite) and excess sodium bicarbonate solution. Be sure to include a trap in the line to prevent the solution being sucked back into the cylinder. If this cannot be done, the cylinder should be placed in or adjacent to a fume hood and left to bleed off. If the leak is in the valve assembly, a plastic bag can be fastened over the head of the cylinder which can then be taken outside or to a fume hood. PAGE 140-DISPOSAL PROCEDURE 12a 2 If the oxidizer is a liquid or a solid--Cover with a reducer (hypo, a bisulfite, or a ferrous salt but not car bon, sulfur or strong reducing agents). Mix well and spray with water, A sulfite or a ferrous salt will require addition of some 3M-H_S04 to promote rapid reduction. Scoop slurry into a con tainer of water and neutralize with soda ash. Wash down the drain with excess water. Wash site thoroughly with a soap solution containing some reducer. Package lots: Add to a large volume of concentrated solution of reducer (hypo, a bisulfite or a ferrous salt and acidify with 3M-H...SOJ. When reduction is com plete add soda ash or dilute hydro chloric acid to neutralize the solution. Wash into drain with large excess of water. Examples Ammonium dichromate Ammonium perchlorate Ammonium persulfate Barium chlorate Bromic acid Bromine tert.-ButyI chromate Bromic acid Bromine Calcium chlorate Calcium hypochlorite Chloric acid Chlorine Chlorine dioxide Cleaning solution (acid dichromate) Chromium oxide Chromium oxychloride Cleaning solution (acid dichromate) Fluorine Iodine Magnesium chlorate Magnesium perchlorate Nitrogen trifluoride Nitrosyl chloride Peracetic acid Perchloric acid Potassium and sodium perchlorates, chlorates, chlorites, dichromates, hypochlorites, per manganates, persulfates Zinc chlorate OXIDIZING AGENTS J f f A 3 CMA 045941 DISPOSAL PROCEDURE 12bREDUCING SUBSTANCES Wear: Rubber gloves, safety glasses, labora tory coat. Work in hood or wear a respirator. Spills. Gas leak: Eliminate all sources of igni tion. If the valve is leaking because it cannot be closed, the gas can be bubbled through a calcium hypo chlorite solution. Be sure to include a trap in the line to prevent the solution being sucked back into the cylinder. Solid: Cover spill with soda ash or sodium bicarbonate. Mix and spray with water. If effervescent wait until reaction is complete. Scoop into a large beaker and cautiously add equal volume of calcium hypochlorite (reac tion may be vigorous). Add more water, stir, and allow to stand for one hour. Dilute and neutralize* the oxidized so lution and transfer to the drain with excess of water. Package lots: If a gas,** bubble into soda ash solu tion. If a solid, mix with equal volume of soda ash and add water to form a slurry in a large container. In either case add calcium hypochlorite. Add more water if necessary and let stand two hours. Neutralize* the oxidized solution. Wash down drain with large excess of water. Examples. Chromous salts Sodium bisulfite Sodium nitrite Sodium sulfite Sodium thiosulfate Stannous chloride Sulfur dioxide k Test with litmus. Neutralize with 6M-HCI or 6M-NaOH as required. * If a tank of reducing gas has developed a perma nent leak lower it upside down into a drum filled with water. Add a mixture of soda ash and cal cium hypochlorite. Continue the treatment until the tank i$ empty and the drum contains a solu tion of stable element or compound. REDUCING SUBSTANCES DISPOSAL PROCEDURE 12b--PAGE 141 CMA 045942 DISPOSAL PROCEDURE________________________ MERCAPTANS--and organic sulfides Wear.- Rubber gloves, self-contained breath ing apparatus, laboratory coat. Spills : Eliminate all sources of ignition. Cover with calcium hypochlorite and mix. Scoop into a large beaker. After 12 hours, neutralize* if necessary. Wash to sewer with excess water. Wash site of spill with strong soap solution to which has been added some hypochlo rite. Package lots: 1 As for spills. 2 Dissolve in waste alcohol or other flammable solvent. Burn in an inciner ator with an afterburner and scrubber to neutralize the S02. Allyl propyl disulfide Amyl mercaptan Benzyl mercaptan Butyl mercaptan Carbonyl sulfide** Crag 974 Dimethyl sulfide Diphenyl sulfide Ethanethiol Ferbam 2-Mercaptoethanol Methyl mercaptan'* Perchloromethyl mercaptan Thioacetamide 2, 2-Thiodiethanol Thioglycolic acid Thiophene Thiourea Tetramethylthiuram disulfide (Thiram) * Test with litmus. Neutralize with 6M-HCI or SM'NH^OH as required, ** If quantity Is large, seal and return container to the supplier, if small, allow it to dissipate in a fume hood. PAGE 142--DISPOSAL PROCEDURE 13 MERCAPTANS--and ORGANIC SULFIDES CMA 045943 DISPOSAL PROCEDURE CYANIDES AND NITRILES Long rubber gloves, self-contained breathing apparatus, laboratory apron or coat. Evacuate the laboratory and isolate the area during decontamination. Spills : Eliminate all sources of ignition and flammables. 1 General treatment: (a) Absorb liquid with vermiculite or on paper towel {sweep solid onto paper). Place on an iron or glass dish m a hood. Evaporate and burn paper. (b) On skin--Wash away immediately with much soap and water. 2 Hydrocyanic acid (HCN) leak:* Turn on fume hood. Allow gas to leak into a container of sodium hydroxide solution while stopping leak. Add ex cess calcium hypochlorite to the alkali cyanide. Discharge the cyanate into the drain with excess water 3 Cyanides: (a) Scoop into a larger beaker and make alkaline with sodium hydrox ide solution. Add to the slurry an excess of ferrous sulfate solution. After one hour, flush down the drain with excess water. OR (b) Add excess sulfur to the alkaline slurry of the cyanide. Heat to con vert to thiocyanate. Flush down drain with excess water. 4 Nitriles: Add excess of strong calcium hypochlo rite solution to produce a cyanate. Scoop slurry into a large beaker. After one hour flush down the drain with excess water. Wash site with soap solu tion containing some hypochlorite. CYANIDES AND NITRILES * If the leak cannot be stopped set the tank upside down in a drum filled with a strong solution of sodium hydroxide and calcium hypochlorite. Con- tmue the treatment until the tank is empty. (Continued on next page) DISPOSAL PROCEDURE 14--PAGE 143 CMA 045944 Package lots: (CHOICE OF PROCEDURES) 1 Add with stirring to strong alkaline solution of calcium hypochlorite. Let stand 24 hours. Flush the cyanate down drain with large excess of water. 2 Liquid nitrile can be mixed with a flamable solvent and sprayed into an incinerator equipped with an after burner and scrubber. Examples .* Acetone cyanohydrin Acetonitrile Adiponitrile Benzonitrile Benzyl cyanide Butyl nitrile n-Butyromtrile Calcium cyanide Chloroacetonltrile Crotononitrile Cuprous cyanide Cyanamide Cyanoacetamide Cyanogen Cyanogen chloride Ethyl cyanoacetate Hydrocyanic acid Lactonitrile Potassium cyanide Propiomtrile Sevin Sodium cyanide Succinonitrile Tetramethyl-succ i nonitrile Trichloroacetonitrile PAGE 144--DISPOSAL PROCEDURE 14 CYANIDES AND NITRILES I I !i I I I I * CYANIDES AND NITRILES | CMA 045945 DISPOSAL PROCEDURE Wear: Rubber gloves, large heavy face shield (if in doubt use body shield also). Selfcontained breathing apparatus. Spills: Eliminate all sources of ignition and flammables. Absorb on paper towel. Evaporate from an iron pan in a hood. Allow time for vapors to completely escape the hood vents, then burn the paper. If large spill, absorb on much more paper or vermiculite and allow com plete evaporation from all surfaces. Use same precaution before burning paper. Package lots: 1 Pour on ground in open area. Allow evaporation or ignite from a dis tance by means of a long fuse or excel sior train. 2 Dissolve waste in higher alcohol (e.g., butyl), benzene, or petroleum ether. Incinerate. 3 PEROXIDE FORMATION. (See MCA Data Sheet SD-29 ethyl ether.) Ether of long standing in contact with air and exposed to light may contain peroxides, especially if stored in clear glass. Explosions have occurred when caps or stoppers were turned. (See MCA Accident Case History No. 603.) Transport cans or bottles to an isolated area (e.g,, deserted quarry). Each con tainer should be wrapped in padding material or packed in sawdust. At site uncover containers and arrange an ex celsior train. From a safe distance puncture the cans near bottom with rifle fire. Ignite excelsior train. Local regulations must be observed. Examples: Allyl glycidyl ether n-Amyl ether Anisole n-Butyl glycidyl ether Butyl vinyl ether Di-n-butyl ether Chloromethyl ether 2,2-Dichloroethyl ether 1.1-Diethoxyethane Diethylene glycol monoethyl `^her Diglycidyl ether Diisopropyl ether Dimethoxy ethane Dimethoxy methane Dimethoxy propane Dipropylene glycol methyl ether 1, 2-Epoxy-3-phenoxy- propane 1.2-Epoxy-propane Ethoxy acetylene Ethyl ether Ethyl vinyl ether Ethylene oxide Glycidol Guaiacol Hydroquinone monomethyl ether Methyl ether Methyl ethyl ether Methyl vinyl ether Phenyl ether Phenyl etherbiphenyl mixture iso-Propyl ether iso- Propyl glycidyl ether Vinyl ether ETHERS DISPOSAL PROCEDURE 15--PAGE 145 CMA 045946 Wear: Rubber gloves, self-contained breath ing apparatus. Impervious clothing recommended. Body shield should be available. Spills : Eliminate all sources of ignition and flammables. 1 On skin or clothing--Wash skin immediately. Remove contaminated clothing at once. 2 Absorb liquid with vermiculite or paper towels. Scoop mixture, paper or solids into a plastic bag and take to a burning pit or incinerator for burning. 3 Large spills--Collect the liquid with an aspirator such as used for re covering spilled mercury. Empty into a large beaker and neutralize with dilute sulfuric acid. Wash to drain with excess water. Wash ' site with soap and water. Package lots: (CHOICE OF PROCEDURES) 1 Dilute to at least 40% and neu tralize with dilute sulfuric acid. Flush to sewer with excess water. OR 2 Dissolve in large volume of waste alcohol or other flammable solvent and burn in an open pit. Ignite from a dis tance with an excelsior train. PAGE 146--DISPOSAL PROCEDURE 16 HYDRAZINES Examples 1,1-Dimethyl hydrazine (UDMH) Hydrazine Hydrazine salts Methyl hydrazine Phenyl hydrazine HYDRAZINES CMA 045947 HYDRIDES DISPOSAL PROCEDURE Wear: Rubber gloves, fire proof clothing, face shield. Work from behind body shield where possible. Keep available pulver ized dolomite or dry graphite for fire fighting. Spills : Eliminate all sources of ignition. Scoop in dry plastic bag which has first been purged to inert gas. Remove to the outside for burning. Flood the burned residues with water to ensure complete destruction of hydrides. Package lots: (CHOICE OF PROCEDURES) 1 Mix with dry sand to avoid or stop fire. Scoop into bucket and remove to open area. Slowly spray with dry butyl alcohol. Later add water by fogging until last of hydride is destroyed. Scoop the solid into a large container. Neutralize* with 6M-HCI. Let settle. Decant and flush to sewer with excess of water. Send sand residue to land fill. If the hydride is a gas (e.g. diborane, silane, germanium hydride), dispose of it by controlled burning. 2 Burn in iron pan or in open pit. Examples: Aluminum borohydride Calcium cyanide Decaborane Diborane Germanium hydride Lithium aluminum hydride Lithium borohydride Lithium hydride Pentaborane Potassium borohydride Potassium hydride Silane Sodium borohydride Sodium hydride 0 HYDRIDES * Test with litmus-- neutralise with 6M HCI if necessary. DISPOSAL PROCEDURE 17--PAGE 147 I CMA 045948 DISPOSAL PROCEDURE HYDROCARBONS, ALCOHOLS, KETONES, and ESTERS Wear: Rubber gloves, face shield, laboratory coat. Have all-purpose canister mask available. SpH/S: Eliminate all sources of ignition and flammables. 1 A gas leak from a faulty tank-- Keep concentration of gas below the explosive mixture range by forced ven tilation, Remove tank to an open area and allow dissipation to the atmos phere, Attempt to cap the valve outlet and return tank to the supplier. 2 A liquid--Absorb on paper. Evapo rate on an iron pan in a hood. Burn the paper. 3 A solid--Sweep onto paper and place in an iron pan in the hood. Burn the paper and compound. Package lots 1 A gas--Pipe the gas into the incin erator. Or lower into a pit and allow it to burn away. 2 A liquid--Atomize into an incinera tor. Combustion may be improved by mixing with a more flammable solvent. 3 A solid--Make up packages in paper or other flammable material. Burn in the incinerator. Or the solid may be dissolved in a flammable sol vent and sprayed into the fire chamber. I Examples Acenaphthene Acetone Acetylene Alizarin dye Allene Ally) acetate Allyl alcohol n-Amyl acetate iso-Amyl acetate sec-Amyl-acetate n-Amyl-alcohol iso-Amyl alcohol tert-Amyl alcohol Amylene iso-Amyl formate Anthracene Anthraquinone 1, 2-Benzanthracene Benzene Benzyl acetate Benzyl alcohol Benzyl benzoate Biphenyl Borneol Butadiene n-Butane iso-Butane 1-Butene 2-Butene n-Butyl acetate iso-Butyl acetate sec-Butyl acetate tert-Butyl acetate n-Butyl alcohol iso-Butyl alcohol sec-Butyl alcohol tert-Butyl alcohol Butyl cellosolve n-Butyl formate iso-Butyl formate Butyl methacrylate iso-Butyl methyl ketone p-tert-Sutyl toluene 1-Butyne 2-Butyrolactone Camphor Carbon monoxide Cellosolve Cellosolve acetate Cresols Creosote Croton oil Crude oil Cumene Cycloheptanone Cyclohexane Cyclohexanol Cyclohexanone Cyclohexene Cyclohexyl benzene Cyclopentadiene Cyclopentane Cyclopentanone Cyclopropane p-Cymene PAGE 148--DISPOSAL PROCEDURE 18 HYDROCARBONS, ALCOHOLS, KETONES, and ESTERS CMA 045949 EXAMPLES--Continued Decahydronaphthalene n-Decane n-Decyl alcohol Diacetone alcohol 1, 2, 5, 6-Dibenzanthracene 1, 2, 5, 6-Dibenzofluorene 1, 2, 3, 4-Dibenzophenanthrene 3, 4, 8, 9-Dibenzpyrene Dibutyl tin diluarate Dibutyl oxalate Dibutyl phthalate Dicyclopentadiene Diethyl adipate Diethyl carbonate Diethylene glycol Diethyl ketone Diethyl malonate Diethyl phthalate 3, 4-Dihydropyran Diisobutyl ketone 2, 2-Dimethyl butane Dimethyl carbonate 1, 2 Dimethyl chrysene Dimethyl fumarate Dimethyl naphthalene Dimethyl propane Dimethyl phthalate Di-n-octyl phthalate Di-sec-octyl phthalate 1, 4-Dioxane Dipentene Dipentene monoxide Diphenyl methane Dodecane Ethane Ethanol Ethyl acetate Ethyl acetoacetate EtM^crjdate^^--_ Ethyl alcohol Ethyl-sec-amyl ketone Ethyl benzene Ethyl benzoate Ethyl butyl ketone Ethyl butyrate Ethyl crotonate Ethylene Ethylene glycol Ethyl formate 2-Ethyl hexanol Ethyl lactate Ethyl oxalate p-Ethyl phenol Ethyl silicate Furan Furfuryl alcohol Gasoline Glycerol Greases Heptane Hexane n-Hexano! 1- Hexene 2- Hexene sec-Hexyl acetate p-Hydroquinone 5-indanol Industrial gases (LHG) Isoprene Jet fuels Kerosene Ketene Lacquer diluent Ligroin Liquefied petroleum gas p-Mentha-1, 8-diene Mesityl oxide Methane Methyl acetate Methyl acrylate HYDROCARBONS, ALCOHOLS, KETONES, and ESTERS Methyl alcohol Methyl amyl alcohol Methyl-m-amyl ketone 6 Methyl-1, 2-benzanthra cene 10 Methyl, 1, 2-benzanthra cene Methyl benzoate Methyl benzyl alcohol 2-Methyl-l-butene 2- Methyl-2-butene 3- Methyl-l-butene Methyl butyl ketone Methyl butyrate Methyl cellosolve Methyl cellosolve acetate 3- Methyl cholanthrene Methyl cyclohexane 2-Methyl cyclohexanol 2-Methyl cyclohexanone 4- Methyl cyclohexene Methyl ethyl ketone Methyl formate 2-Methyl furan Methyl isobutyl ketone Methyl isobutyrate Methyl isocyanate Methyl methacrylate 1-Methyl naphthalene Methyl-n-propyl ketone Methyl salicylate Methyl styrenes Methyl-toluene sulfonate Naphthas Naphthalene 1- Naphthol 2- Naphthol Natural gas Nickel carbonyl Nonyl phenol Octane 1-ctano1_______________________ 2-Octanol Oil, cocoanut Oil, fuel Oil, lubricating Oil, mineral mist Oil, olive Oil, peanut Oil, soybean Oil, vegetable Paraffin n-Pentane iso-Pentane 1. 5-Pentanediol 2, 4-Pentanedione 2-Pentanol Petroleum ether Phenanthrene Phenol Phenyl acetate Phenyl isocyanate o-Phenyl phenol Phorone iso-Phorone Phosgene solutions in benzene 2-Pinene Piperylene Pival Polyvinyl acetate emulsion Propane 1, 2-Propanediol Propargyl alcohol iso-Propenyl acetate iso-Propyl acetate n-Propyl acetate n-Propyl alcohol iso-Propyl alcohol Propyl benzene iso-Propyl benzoate Propylene Propylene carbonate 18 Propyl formate iso-Propyl formate Propyne Propyne-allene mixture Quinone Resorcinol Rotenone Stoddard solvent Styrene Tall oil Tallow Terphenyls Tetradecane Tetrahydrofuran Tetrahydronaphthalene 1-Tetralone Toluene Tridecanol Triethylene glycol Triethyl-ortho-formate 5, 9, 10-Trimethyl-l, 2-benzanthracene 6, 9,10-Trimethyl-l, 2-benzanthracene Trimethyl borate 2, 2, 4-Trimethyl pentane 2,4, 4-Trimethy!-2-pentane 1, 3, 5-Trioxane Turpentine Varnish Vinyl acetate Warfarin Xylenes Xylenols DISPOSAL PROCEDURE 18--PAGE 149 i CMA 045950 DISPOSAL PROCEDURE_______________________ INORGANIC AMIDES and Derivatives Wear: Rubber gloves, large face shield, pro tective laboratory coat. A large body shield should be available. Spills: Eliminate all sources of ignition. Sweep up solid amide onto dry paper. Cau tiously add to cold water in small por tions with agitation. Neutralize* and discharge into drain with large excess of water. Package lots.- Sift slowly into a large container of cold water, with agitation. When all has reacted, neutralize* and pour into drain with large excess of water. Examples Ammonium sulfamate Monochloroamine Sodium amide Sulfamic acid Sulfamide Test with litmus. Neutralize with 3M-HCI or SM'NHtOH as required. PAGE 150--DISPOSAL PROCEDURE 19 INORGANIC AMIDES and DERIVATIVES CMA 045951 DISPOSAL PROCEDURE ORGANIC AMIDES Wear.- Rubber gloves, safety glasses, laboratory coat. Spills : Scoop into a plastic bag or onto a paper towel. Remove to the outside, add alcohol and burn in a safe place, Package lots: Add to a flammable solvent (alcohol or benzene). Pour into an iron pan in an open pit. Ignite. OR Spray into an incinerator. Oxides of nitrogen may be scrubbed out with alkaline solution. Examples Acetamide Chloroacetamide N, N-Dimethylacetamiae Dimethylformamide Ethyl Acetanilide Formarrnde 2-Phenanthreneacetamide 3-Phenanthreneacetamide ORGANIC AMIDES DISPOSAL PROCEDURE 20--PAGE 151 CMA 045952 DISPOSAL PROCEDURE-----------------------------------INTER NON-METALLIC COMPOUNDS Wear.- Long rubber gloves, safety glasses or goggles, self-contained breathing ap paratus, laboratory coat. Recommended that work be done in an effective hood from behind a body shield or in an open barricaded area out of doors. NOTE--Some suppliers will collect unwanted cylinders of com pressed gases on request. Spills : Eliminate all sources of ignition. Gas leak (e.g., boron trichloride, chlo rine trifluoride). Allow gas to flow into a mixed solution of caustic soda and slaked lime, If possible, keep in a hood until cylinder is emptied. Liquid or solid--Cover with vermiculite, sodium bicarbonate or a mixture of soda ash and slaked lime (50-50). Mix and spray water cautiously from an atomizer. Scoop up and add slowly to a large container of water (if too active continue spraying). When reaction is complete neutralize* and wash down the drain with a large excess of water. Wash site with soap solution. Package lots: Sprinkle or sift onto a thick layer of mixed dry soda ash and slaked lime (50-50) from behind a body shield. Mix and spray water cautiously with an atomizer, Scoop up and sift cautiously into a large volume of water. Neutral ize* and wash down the drain with large excess of water. Examples: Boron fluoride-ethyl ether complex Boron tribromide * Make litmus test Neutralize with 6M*NHtOH or SM-HCi as required. Boron trichloride Boron trifluoride Boron trifluoride complexes with acetic acid and methanol Bromine pentafluoride Bromine trifluoride Carbonyl fluoride Chlorine trifluoride Iodine chloride Iodine pentafluoride Iodine trichloride Nitric oxide Nitrogen dioxide Oxygen difluoride Perchloryl fluoride Phosphorus oxychloride Phosphorus pentachloride Phosphorus pentasulfide Phosphorus sesquisulfide Phosphorus tribromide Phophorus trichloride Silicon tetrafluoride Sulfur decafluoride Sulfur dichloride Sulfur hexafluoride Sulfur monochloride Sulfuryl chloride Sulfuryl fluoride Thionyl chloride Thionyl fluoride PAGE 152--DISPOSAL PROCEDURE 21 INTER NON-METALLIC COMPOUNDS CMA 045953 DISPOSAL PROCEDURE PEROXIDES, INORGANIC Wear: Rubber gloves, large face shield, labo ratory coat. A body shield should be available. Package lots: Use the above method for the encrusted impure peroxide. Repackage any recov ered pure granular peroxide in glass containers with rubber stoppers. SpHlS : Cover with at least double volume of sand-soda ash mixture (90%-10%). Mix thoroughly and break up any lumps of peroxide. With a plastic scoop add slowly to a large beaker of sodium sul fite solution (3 or 4 liters) with stirring. Neutralize with dilute sulfuric acid. When settled decant the sulfate solu tion into drain with excess water. The sand can be sent to the landfill. Hydrogen Peroxide (spill or package lots): Dilute and wash down drain with excess of water. Examples: Hydrogen peroxide (3% to 90%) Potassium peroxide Sodium peroxide PEROXIDES, INORGANIC DISPOSAL PROCEDURE 22a--PAGE 153 CMA 045954 DISPOSAL PROCEDURE PEROXIDES, ORGANIC CAUTION: Keep stock low and date each container as received. Never transfer to glass stoppered containers or screw cap bottles which can cause dangerous friction. See Procedure 15. Wear: Rubber gloves, large heavy face shield, laboratory coat. Work from behind heavy body shield in hood. NaOH, Burn the original cartons and bags. 2 Solid peroxide spills should be mixed with a large volume of vermiculite or sand. Cautiously transfer as above and burn. 3 A very small quantity of #1 or #2 may be destroyed by adding 10 vol umes of 20% NaOH. After 24 hours, neutralize* and pass into drain with large excess of water. Examples .* Acetyl peroxide Benzoyl peroxide Butyl hydroperoxide tert.-Butyl peracetate tert.-Butyl perbenzoate Butyl peroxy pivalate Cumene hydro peroxide 3,4-dichlorobenzoyl peroxide Dibutyl peroxide Diisopropyl peroxy dicarbonate Lauroyl peroxide Methyl ethyl ketone peroxide Spills : Eliminate all sources of ignition. 1 Liquid peroxide spills may be ab sorbed in large quantity of vermiculite or sand. Using a soft plastic scoop, carefully place the mixture in a plastic container. Spread on a steel pan or in a deep pit. Ignite from a distance with an excelsior train or a long torch. Wash the scoop and container with 20% Package lots: Absorb or mix in small portions on ver miculite or sand. Wet down with 10% NaOH. Scoop up with plastic scoops and take to open-incinerator pit. When dry, ignite from a distance with an ex celsior train. * Neutralize with 6M-HCI. PAGE 154--DISPOSAL PROCEDURE 22b PEROXIDES, ORGANIC CMA 045955 DISPOSAL PROCEDURE SULFIDES, INORGANIC Wear: Rubber gloves, safety glasses. Work in hood or wear self-contained breathing apparatus, laboratory coat. Spills : Eliminate all sources of ignition. Add FeCI3 solution. Stir until FeS formation is complete. Add slight excess of soda ash. Scoop up and wash into drain with excess water. Wash site with soap solution. OR Absorb with vermiculite or sodium bi carbonate and scoop into plastic bag or wide-mouthed glass jar. Close tightly, remove to safe place outside and add FeCI:) solution. Stir until reaction is complete. Add slight excess sodium bicarbonate and wash into drain with excess water. Package lots: Add to a large volume of FeCIi solution with stirring. Add more FeCU if neces sary, Add soda ash with stirring until neutral. Scoop up and wash down the drain with excess water. Note; If a gas (e.g., H ,S), seal the cylin der and return to supplier. If the valve is leaking the gas can be bubbled through a FeCl.t solution. Be sure to include a trap in the line to prevent the solution being sucked back into the cylinder. If this cannot be done, the cylinder should be placed in or ad jacent to a fume hood and left to bleed off. Examples Ammonium polysulfide Ammonium sulfide Calcium sulfide Hydrogen sulfide Potassium sulfide Sodium sulfide a SULFIDES, INORGANIC DISPOSAL PROCEDURE 23--PAGE 155 CMA 045956 24a DISPOSAL PROCEDURE. ACIDS, ORGANIC (Limited to C, H, and 0 Compositions) Wear: Rubber gloves, face shield, laboratory coat. Body shield and self-contained breathing apparatus should be avail able. SpHlS : Eliminate all sources of ignition, 1 Cover contaminated surfaces with soda ash or sodium bicarbonate. Mix and add water if necessary. Scoop up slurry and wash neutral* waste down drain with excess water. Wash site with soda ash solution. Package lots: (CHOICE OF PROCEDURES) 1 Liquid acid may be injected at base of incinerator or after mixing with a flammable solvent. Afterburner is suggested for complete combustion, 2 A solid add may be dissolved in a flammable solvent and burned as above. 3 Solid acid may be packaged in paper or other flammable material and burned in an incinerator. Examples Acetic acid Acetic anhydride Acrylic acid Adipic acid Benzoic acid n-Butyric acid iso-Butyric acid n-Butyric anhydride Caproic acid Citraccnic anhydride Citric acid Formic acid Fumaric acid Gallic acid Glutaric anhydride Glycolic acid Hydracrylic acid-B-lactone* Laurie acid Maleic acid Maleic anhydride Methacrylic acid Octanoic acid Oleic acid Oxalic acid Phthalic anhydride Pimelic acid Propionic acid Pyrogallic acid Pyruvic acid Salicylic acid Stearic acid Succinic acid Succinic anhydride Tannic acid Valeric Acid * Make l<tmus test. Neutralize with 6M-NH<OH or 6M-HCI as required. PAGE 156--DISPOSAL PROCEDURE 24a * Carcinogenic. ACIDS, ORGANIC CMA 045957 DISPOSAL PROCEDURE ACIDS, INORGANIC Wear: Rubber gloves, self contained breath ing apparatus, laboratory coat. Have body shield available. SpillS : 1 Cover the contaminated surface with sodium bicarbonate or a soda ash--slaked lime mixture (50-50). Mix and add water if necessary to form a slurry. Scoop up slurry and wash down the drain with excess water. Wash site with soda ash solution. Package lots: Add slowly to large volume of agitated solution of soda ash and slaked lime. Add neutralized solution to excess run ning water. As an added precaution, the sink can be lined with protective matting and filled with coarse chipped marble. Examples: Boric acid Boron oxide Fluoroboric acid Fluorosilicic acid Hydriodic acid Hydrobromic acid Hydrochloric acid Hydrofluoric acid Iodic acid Mixed acids Nitric acid Phosphoric acid Phosphoric anhydride Sulfuric acid Sulfur trioxide ACIDS, INORGANIC DISPOSAL PROCEDURE 24b--PAGE 157 CMA 045950 DISPOSAL PROCEDURE Wear: Rubber gloves, safety glasses, labora tory coat. SpillS: Cover with dry vermiculite, scoop into a dry bucket or plastic bag and trans fer to a safe open area. Dispose of the material cautiously by adding it slowly to a large volume of water. Burn the hydrocarbon gas using a pilot burner. Allow to stand for 24 hours and run to sewer with excess water. Package lots.- Take to a safe open area and add slowly to a large container of water. Burn off the hydrocarbon gas with a pilot flame. Allow to stand for 24 hours. Siphon off the liquid and transfer the precipitate to a landfill. Examples .* Aluminum carbide Calcium carbide PAGE 158--DISPOSAL PROCEDURE 25 CARBIDES CMA 045959 DISPOSAL PROCEDURE WASTES TO BE DUMPED INTO LANDFILLS OR RELEASED TO AIR Wear: Heavy work gloves, safety glasses. Properly assembled waste ready for pick-up trucks may be used as fill in reclaiming low areas or may be dumped into a landfill. Examples Argon Asphalt Batteries, dry cell Boron Bromochloromethane Bromoform Bromotrlfluoromethane Calcium carbonate Calcium oxide Carbon black Chlorobromomethane 1-Chloro-l, 1-difluoroethane Chloroform Chloropentafluoroethane Chlorotrifluoroethylene Chromium Crude lime 1, 2-Dibromotetrafluoromethane Dichlorodifluoromethane Dichloromethane Dichloromonofluoromethane Dichlorotetrafluoroethane Epoxy resin systems Ferrosi I icon Ferrovanadium dust Fluorotrichloromethane Helium Hexachloroethane Hexafluoroethane Hydrogen Lamp bulbs Latex Magnesium oxide Metal scrab Molybdenum, insoluble compounds Neon Nitrogen Nitrogen fertilizers Nitrogen trioxide Octafluorocyclobutane Osmium tetroxide Oxygen Ozone Paint Pyrethrum Resins Rubber Scrap glass Scrap stoneware Silica Sludges Stone, alberine Sulfur Tar Tetrabromoethane WASTES TO BE DUMPED INTO LANDFILLS OR RELEASED TO AIR 1. 1,1.2-Tetrachloro-2, 2-difluoroethane i, 1, 2, 2-Tetrachloro-l. 2-difluoroethane Tetramethyi silane Transite Tin, organic compounds Titanium oxide Tremohte 1, 1, 1-Trichloroethane 1,1, 2-Trich loro-1. 2, 2-trifluoroethane Trifluoromethane Urea Xenon Yttrium Zinc oxide Zirconium Zirconium-hafnium powders DISPOSAL PROCEDURE 26--PAGE 159 CMA 045960 27a DISPOSAL PROCEDURE. RECOVERY Scrap metal in the form of sheets, rods, wire, tubes I Wear: Heavy gloves, safety glasses, laboratory coat. 1 Larger pieces of less expensive metals can be salvaged profitably for use in local shops, or can be sold as scrap metal--e.g., aluminum, copper, brass. 2 The more expensive metals are worth salvaging, even in small pieces-- e.g., platinum wire, silver foil. Metal should be sorted, classified, and placed in boxes, properly labelled. Turnings, shot, cuttings of the cheaper metals may be assigned to landfill. (See 26.) PAGE 160--DISPOSAL PROCEDURE 27a Examples: Sheet, rods, wire, tubes, foil, etc. Aluminum Antimony Batteries, wet cells Beryllium Bismuth Bronze Cadmium Cobalt Copper Gold Lead Magnesium Manganese Molybdenum Nickel Paiadium Platinum Rhodium Silver Steel, carbon Steel, stainless Tantalum Tin Titanium Zinc t > RECOVERY--SCRAP METAL CMA 045961 DISPOSAL PROCEDURE RECOVERY*--MERCURY Wear: Rubber gloves, self-contained breath ing apparatus, laboratory coat. CAUTION: The toxicity of mercury is such that the element and its com pounds should not be allowed to con taminate air or water. * In procedures 27b to 27m, recovery is essential because of high toxicity of all elements and com pounds--e.g. the American Conference of Govern mental Industrial Hygienists' threshold limit values (1968) expressed as mg/MJ (milligrams per meter cubed) for mercury 0,1, for arsenic ^ 0.5, anti mony 0.5, selenium ^ 0.2, beryllium 0,002, lead 0.2, cadmium 0.2, barium 0 5, uranium 0.05, vanadium 0,1--as opposed to hydrogen cyanide 11, and hydrogen sulfide 15. Spills and package lots: Metal--Collect all droplets and pools at once by means of suction pump and aspirator bottle with a long capillary tube. Cover fine droplets in nonaccessible cracks with calcium poly sulfide and excess sulfur. Combine all contaminated mercury in a tightly stoppered bottle. Hold it for purifica tion or sale. Compounds--Dissolve all water soluble contaminated compounds. Convert other contaminated compounds to the soluble nitrates. Adjust the acidity and precipitate as mercuric sulfide. Wash and dry the precipitate. Ship to the supplier. Examples: Mercuric nitrate, chloride and thiocyanate Mercurous nitrate and chloride Mercury Mercury fulminate Organic mercury compounds RECOVERY*--MERCURY DISPOSAL PROCEDURE 27b--PAGE 161 CMA 045962 DISPOSAL PROCEDURE---------------------------- RECOVERY-PHOSPHORUS YELLOW AND RED Wear: Rubber gloves, large face shield. YELLOW PHOSPHORUS Spills: Cover with wet sand. Spray with water to keep sand wet. Scoop into a bucket of water. After standing overnight, re cover and repackage. OR If quantity is very small (e.g., frag ments of sticks of yellow phosphorus), cover with water and remove to an open area. Pour onto the ground or a steel pan. The water will evaporate and dry yellow phosphorus will ignite spontane ously in air and burn away. RED PHOSPHORUS Spills: Sweep up and burn on an iron pan in the hood. Defective package Repackage and return to the shelf--or to the supplier. PAGE 162--DISPOSAL PROCEDURE 27c Defective package Submerge defective package in a large container of water. Repackage under water and return to the suppliers. RECOVERY-PHOSPHORUS CMA 045963 DISPOSAL PROCEDURE 27dRECOVERY--ARSENIC, ANTIMONY and bismuth* Rubber gloves, safety glasses, respira tor, laboratory coat. Work in fume hood. Waste: Dissolve in minimum hydrochloric acid (concentrated, reagent). Filter if neces sary, Dilute with water until white pre cipitates form (SbOCI and BiOCI). Add just enough 6M-MCI to redissolve. Saturate with hydrogen sulfide. Filter, wash the precipitate, dry, package and ship to the supplier. OR If the waste is of very little value, use Procedure 11. Examples j Antimony pentasulfide Antimony trioxide Arsenic acid Arsenic trichloride Arsenic trioxide Arsenous acid Calcium arsenate Lead arsenate Metals (arsenic, antimony and bismuth) Nitrates and chlorides of arsenic, antimony and bismuth Stibine 7 'Although bismuth is much less toxic than arsenic or antimony it is included here because the recov ery procedure is similar. RECOVERY--ARSENIC, ANTIMONY AND BISMUTH DISPOSAL PROCEDURE 27d-PAGE 163 CMA 045964 -SELENIUM AND TELLURIUM Wear: Rubber gloves, safety glasses, respira tor (or work in hood), laboratory coat. SpillS: Absorb on paper and place in wide mouth stoppered bottle for later recov ery, Wash site with soap solution. Package lots and recovered spills: Liquid or solid --Make a solution strongly acidic with hydrochloric acid. Slowly add sodium sulfite to the cold solution with stirring, thus producing sulfur dioxide, the reducer. Upon heating dark grey selenium and black tellurium form. Let stand over night. Filter and dry. Ship to supplier. Examples Hydrogen selenide Selenium hexafluoride Selenium oxides Selenium oxychloride Selenium tetrachloride Tellurium hexafluoride Tellurium oxides PAGE 164--DISPOSAL PROCEDURE 27e RECOVERY--SELENIUM AND TELLURIUM CMA 045965 DISPOSAL PROCEDURE 27fRECOVERY- LEAD AND CADMIUM COMPOUNDS Wear: Rubber gloves, safety glasses, respira tor (or work in hood). Package lots and recovered spills: Convert to nitrates with a minimum of nitric acid (concentrated, reagent). Evaporate in a fume hood to a thin paste. Add about 500 ml. water and saturate with hydrogen sulfide. Filter, wash, and dry the precipitate. Package and ship to the supplier. OR If the waste is of small volume, use Procedure 11. Examples: Cadmium oxide Cadmium salts Lead oxides Lead salts 1 RECOVERY--LEAD AND CADMIUM COMPOUNDS DISPOSAL PROCEDURE 27f-PAGE 165 CMA 045966 DISPOSAL PROCEDURE-------------------------- RECOVERYBERYLLIUM COMPOUNDS Wear: Rubber gloves, self-contained respira tor, laboratory coat (wash after each job). Spills : Absorb on paper towels and place in large stoppered wide-mouth bottle. Save for recovery. Wash site with soap solution. Package lots and recovered spills: Dissolve in minimum of 6M-HCI. Filter and treat filtrate with slight excess of 6M-NH4OH (use litmus). Boil and allow coagulated precipitate to settle for about 12 hours. Filter and dry. Pack age and ship to the supplier. Examples: Beryllium salts PAGE 166--DISPOSAL PROCEDURE 27g RECOVERY--BERYLLIUM COMPOUNDS CMA 045967 DISPOSAL PROCEDURE f 27hRECOVERY-STRONTIUM AND BARIUM COMPOUNDS Wear: Rubber gloves, safety glasses, labora tory coat. Package lots and recovered spills. Dissolve waste in 6M-HCI and filter. Neutralize the filtrate with 6M-NH4OH (use litmus) and precipitate with ex cess sodium carbonate. Filter, wash, and dry the precipitate. Package and ship to the supplier. OR If the waste is of small volume, use Procedure 11, Examples Oxides and salts of strontium and barium ! RECOVERY--STRONTIUM AND BARIUM COMPOUNDS DISPOSAL PROCEDURE 27h--PAGE 167 CMA 045968 DISPOSAL PROCEDURE---------------------------RECOVERY--VANADIUM COMPOUNDS Rubber gloves, large face shield, labo ratory coat. (Wear self-contained respi rator if spill is large.) Cover with powdered ammonium carbonate. Add a layer of crushed ice and spray with 6M-NH4OH while stirring. Scoop slurry into a wide mouth bottle, save for salvage. Wash site with soap water. (Work in a fume hood). Add (e.g., VOCI,) slowly to a thick layer of powdered ammonium carbo nate m a large evaporating dish. Spray with 6M-NH4OH while stirring. Add a layer of crushed ice and continue stirring and spraying. Add more 6M-NH.,0H if necessary. May add more waste vanadium compound with stirring. Pour info large beaker and let stand over night. Filter off the crude ammonium vanadate, dry and package for shipment to supplier for reprocessing. Ammonium vanadate Sodium vanadate Vanadium chlorides Vanadium oxychlorides Vanadyl sulfate PAGE 168--DISPOSAL PROCEDURE 27i RECOVERY--VANADIUM COMPOUNDS CMA 045969 T DISPOSAL PROCEDURE RECOVERY-- Carbon Tetrachloride, Carbon Tetrabromid , Carbon Tetrafluoride* and Phosgene* Rubber gloves, self-contained respirator (or work in hood), laboratory coat. Absorb on paper towels and allow to evaporate in the fume hood. Burn the paper. Wash site with soap solution. The toxic liquid compounds concerned here are insoluble in water and cannot be burned. Purify the contaminated liquids by distillation and place the pure distillate back on the shelf. UK Return to the supplier, 4 The phosgene or carbon tetrafluoride container should be sealed and returned to the supplier. If the cylinder has developed a permanent leak it may be necessary to dissipate the leak in a strong-draft fume hood The supplier may be called to cap the cylinder and haul it away. RECOVERY--CARBON TETRACHLORIDE, CARBON TETRABROMIDE AND PHOSGENE DISPOSAL PROCEDURE 27]--PAGE 169 CMA 045970 DISPOSAL PROCEDURE-----------------------RECOVERY-MISCELLANEOUS The elements and their compounds listed below should be dealt with sepa rately. If the quantity justifies recovery get in touch with the supplier for spe cial instructions. These materials as well as all other naturally radioactive materials, elements or substances must be disposed of m accordance with regulations of the u.S. Atomic Energy Commission or those of the local or state departments of health. This may usually be done by turning them over to the radiation safety officer or a commercial disposal agency handling radioactive materials. Examples.* Deuterium Erbium Gadolinium Gallium Germanium Germanium dioxide Hafnium Holmium Indium Lanthanum Lutecium Niobium Osmium Osmium oxide Praseodymium Rubidium Ruthenium Samarium Silver nitrate Terbium Thallium Thallous sulfate Thorium* Uranium* f PAGE 170--DISPOSAL PROCEDURE-27k RECOVERY-MISCELLANEOUS CMA 045971 DISPOSAL PROCEDURE 28CELLULOSE NITRATE, COLLODION, CELLULOID Rubber gloves and face shield. Note: Outside disposal is preferred but can be done in the hood. Spills : CELLULOSE NITRATE Eliminate all sources of ignition. Gather up the nitrocellulose and dampen with an alcohol. Spread out in a thin layer (2 inches deep max.) in an outside open area on top of papers or other combustible material. Ignite from a distance with an excelsior train or a long torch. When disposal by burn ing must be done in a hood, the quan tity of nitrocellulose burned at any one time should be limited to 250 ml or less. This small quantity of nitrocellu lose can be placed in a shallow pyrex dish and ignited after it has been dampened with an alcohol. OR Eliminate all sources of ignition. Gather up the nitrocellulose and dampen with water. Squeeze out ex cess water and place nitrocellulose (250 ml or less) in a large stainless steel beaker (2500 ml or larger), and place beaker in a large pyrex dish. Add an equal amount of 10% caustic (no stronger) to the beaker. Most of the nitrocellulose should be consumed in 20 minutes. Remove beaker (Cau tion: beaker will be hot from the heat of reaction) and pour remaining con tents into drain with large excess of water. Spills. COLLODION (Nitrocellulose Lacquer) Eliminate sources of ignition. Wipe up spilled material with paper towels or rags. Remove to an outside open area, spread on the ground and ignite with an excelsior train or a long torch. Package lots. Small quantities of collodion (250 ml or less) may be disposed of in a hood by igniting it in a pyrex dish. Larger quantities should be disposed of in an outside open area by pouring into a steel pan and igniting with an excelsior train or a long torch. CELLULOID (Nitrocellulose Plastic) Celluloid disposal should be done out side in an open area, Eliminate sources of ignition. Spread the waste celluloid on top of paper or other combustible material. Ignite from a distance with an excelsior train or a long torch. WARNING: Whenever cellulose nitrate, collodion or celluloid is burned or decomposed, oxides of nitrogen are released. Avoid direct breathing of vapors. DEEP BURIAL DISPOSAL PROCEDURE 28--PAGE 171 CMA 045972 DISPOSAL PROCEDURE-----------------------------DIRECT BURNING Wear: Heavy leather gloves, safety glasses. Disposal: Materials should be properly packed for safe handling, and placed in a pre scribed site for daily pick-up. Burning can be done in an open or closed incin erator with afterburners. Examples Materials: Bags, paper and cloth Biological wastes--animal remains, bedding, feed wastes Clothing, discarded or contaminated Excelsior Paper wastes, packing boxes, etc. Wood scraps, packing boxes, etc. Bags, paper and cloth PAGE 172--DISPOSAL PROCEDURE 29 DIRECT BURNING CMA O45973 SECTION VII Disposal Ma terials--Minimum Requiremen ts (a) CHEMICALS Acetone, waste (2 gal.) Alcohol, butyl (2 gal.) Alcohol, denatured (waste) (2 gal.) 'Ammonium hydroxide (concentrated, Reagent) (2 liters) Ammonium hydroxide (6M) (4 liters) Ammonium carbonate (2 x 1 lb.) Benzene, waste (2 gal.) Calcium hypochlorite (2 x lb.) "Calcium polysulfide (2 x 1 liter) Excelsior (box) Fuels -- scrap wood paper organic flammable solvents Ferrous sulfate (2 x 1 lb.) Ferrous sulfate, 30% (4 x 1 liter) Ferric chloride (2 x 1 lb.) Graphite powder (5 lb.) Hydrochloric acid (concentrated, Reagent) (2 liters) '"Hydrochloric acid, (6M) (4 liters) Hydrogen sulfide (small cylinder) Ice, chipped Kaolin (2x5 lb.) Kaolin -- Soda ash (50-50) (2 x5 lb.) Limestone, pulverized (2x5 lb.) Litmus paper, red and blue (1 doz. vials each) Marble chips (2x5 lb.) Nitric acid (centrated, Reagent) (2 liters) Paper boxes, waste Potassium iodide, 10% (peroxide test) Sand, dry (2x10 lb.) Sand-Soda ash (90-10) (2x10 lb.) Slaked lime (calcium hydroxide) (2x5 lb.) Soap power (6 x 1 lb.) Soda ash (sodium carbonate) (2x5 lb.) Soda ash-Slaked lime (50-50) (2 x 10 lb.) Sodium bicarbonate (2x5 lb.) Sodium hydroxide, 10% (4 liters) Sodium hydroxide, 20% (4 liters) Sodium bisulfite (5 lb.) Sodium sulfite (5 lb.) Sodium thiosulfate (hypo) (2x5 lb.) Sulfur, sublimed (2 x 1 lb.) Sulfuric acid (concentrated, Reagent) (2 liters) ""Sulfuric acid (3M) (4 liters) Towels, paper (1 doz. rolls) Vermiculite (or Oil-Dri, Sol-Speedi-Dri, etc.) (10 lb ) Requires approximately 400 ml. of concentrated reagent grade per liter of solution. Saturate one hter of concentrated lime water with hydrogen Add excess sublimed sulfur. Shake, Requires 516 ml. of concentrated HCI per liter of solution. '**336 ml. of concentrated reagent H.SO* per hter of solution NHOH sulfide ______________________ (See over tor EQUIPMENT listing) PAGE 173 si CMA 045974 SECTION VII continued T Disposal Materials--Minimum Requirements (b) EQUIPMENT Aspirator bottle (mercury collector) (2) Atomizer spray bottle (2) Beakers, 3 or 4 liter size (2) Brush, hand (6) Brush, small paint Bucket, plastic (3 gal.) Burners, Bunsen Condenser, Liebig Dish, evaporating, 12" (2) Extinguisher (Class D fires) (30 lb. size) Extinguisher (CO_.) (10 1b. size) Flask, Distilling -- 1 liter (2) Gloves, heavy work Gloves, leather Gloves, neoprene Gloves, butyl rubber Iron pan (for fume hood) (approx. 18" x 24") Laboratory coat, cloth Laboratory coat, plastic Matting, open mesh, rubber, to fit sink Mop and bucket Pipettes 10 ml. (peroxide test) (4) Respirator, canisters (1 of each) Respirator (self-contained breathing apparatus) Safety glasses or goggles (2 prs.) Scoop, plastic Shield, body Shield, face, large and heavy, 0.050", to cover ears and neck Spray jar (insecticide type), stainless steel Suction pump (mercury collector) Tank (oil drum, 55 gal.) Tools -- hammer pliers wrench, crescent screwdrivers Water-vac PAGE 174 CMA 045975 SECTION VIII BIBLIOGRAPHY ACGIH--''Threshold Limit Values," American Conference of Govern mental Industrial Hygienists, 1014 Broadway Cincinnati Ohio 45202 AlA--"Nitroparaffins and their hazards. Report --12 and "Chemical Hazards Bulletin, 1 American Insurance Association 35 John St . New York N Y, 10038 A$TM--"Fire and Explosion Hazards ol Peroxy Compounds, ' Tech. Bui. =394. American Society for Testing and Materials, 1916 Race St., Philadelphia. Pa 19103 Audrieth. L. F & Ogg, BA,--"The Chemistry of Hydrazine," John Wiley & Sons Inc , 605 3rd Ave,, New York, N.Y. 10016 BDH--"Spillages of Hazardous Chemicals," British Drug Houses Ltd , Poole, Dorset, England Also available from Gallard-Schlesmger Chemical Mfg Corp 584 Mineola Ave., Carle Place. Long Island, New York, NY 11514 or from British Drug Houses (Canada) Ltd.. Barclay Ave., Toronto 18, Ontario, Canada Brookes and Alyea--"Poisons," Van Nostrand Reinhold Corripany, 430 Park Avenue. New York, N.Y, 10022 Campbell, Neil--"Schmidts Organic Chemistry," Oliver and Boyd Ltd,, Edinburgh, Scotland CGA--"Safe Handling of Compressed Gases" Pamphlet P-1. Com pressed Gas Association Inc., 500 5th Ave , New York, N Y. 10036 cioyd, D. R. & Murphy, W. J.--"Handling Hazardous Materials--N.A.S.A. SP-5032," National Aeronautics and Space Administration, Washing ton, D. C. 20546 Elkins, H, B,--"Chemistry of Industrial Toxicology," 1963, John Wiley & Sons. 605 3rd Ave., New York, N Y. 10016 Fairhall L. T--"Industrial Toxicology," Williams and Wilkins Balti more, Md, Gaston, P J-- The care, handling and disposal of dangerous chem icals," 1965. Institute of Science Technology. Northern Publishers (Aberdeen Ltd,). Aberdeen, Scotland Gonzales Vance Helpern--"Legal Medicine and Toxicology," 1940, Appleton-Century Trade Books. 250 Park Ave,, New York N Y 10017 Hurd--"Chemistry of Hydrides," 1952, John Wiley & Sons Inc , 605 3rd Ave , New York, N.Y. 10016 IBM--"Freon" solvent data book, IBM Corp . Yorktown Heights New York 10598 Kirk Si Othmer--"Encyclopedia of Chemical Technology," Vol 8. p 489 2nd Ed,, Wiley-lnterscience, 605 3rd Ave , New York, N Y 10016 Los Angeles Fire Dept.--"Dangerous Chemicals Code," 1951. Parker & Son, Inc., Los Angeles, Calif. McElroy, F. E.--"Accident Prevention Manual for Industrial Operations." 5th Ed., National Safety Council, 425 No, Michigan Ave.. Chicago, III 60611 MCA--"Chemical Safety Data Sheets." "Safety Guides 1 and "ChemCard Manual," Manufacturing Chemists Association, 1825 Connecti cut Ave., Washington, D. C. 20009 PAGE 175 CMA 045976 MCB--"Safety Procedures. Laboratory Chemical Catalog,' pp, 9-31, Matheson. Coleman & Bell 2909 Highland Ave.. Norwood, Ohio 45212 MGB-- 'Gas Data Book.'' The Matheson Co , Inc , P.O. Box 85, East Rutherford, N J 07073 N.F,P,A.--No. 49, "Hazardous Chemicals Data"; No. 325, "Fire Hazard Properties of Flammable Liquids, Gases and Volatile Solids", No 491, "Manual of Hazardous Chemical Reactions ' No 704M, "Fire Hazards of Materials," National Fire Protection Association, 60 Batterymarch St,, Boston. Mass 02110 Nat'l Research Council--"Evaluation of the Hazard of Bulk Water Transportation of Industrial Chemicals," 1966, National Academy of Science, 2101 Constitution Ave , N W,, Washington, D. C, 20418 Nicholson, H. Page--"Pesticide Pollution Control," Science 158, 871 (Nov, 17, 1967) Noller, D. C. & Bolton. D. F--"Sate Handling and Storage of Organic Peroxides in the Laboratory," Anal Chem 35, 887 (June 1963). NSC--"Chemical Safety References," National Safety News 97, 47 (Apr. 1968), and "Industrial Safety Data Sheets," National Safety Council, 425 No Michigan Avenue, Chicago, III. 60611 NTTC--"Commodity and Equipment Data Sheets," National Tank Truck Carriers, Inc., 1616 P St., N.W., Washington, D, C, 20006 O'Brien, Richard D.--"Toxic Phosphorous Esters," 1960, Academic Press Inc., Ill 5th Ave., New York, N.Y. 10003 Patty, Frank A.--"Industrial Hygiene and Toxicology," Vol. II, 1963, Wiley-lnterscience, 605 3rd Ave., New York, N.Y. 10016 Pennsylvania Department of Health--"Short Term Limits for Exposure to Airborne Contaminants," "Hygienic Information Guides." "Indus trial Waste Manual," Division of Sanitary Engineering, Harrisburg, Pa. Pennsylvania Department of Revenue--1"Highway Transportation of Hazardous Substances," 1968, Hazardous Substances Transportation Board, Harrisburg, Pa. 17127 fRemy, H.--"Treatise on Inorganic Chemistry," Vo! I & II, 1956, Ameri can Elsevier Publishing Co.. 52 Vanderbilt Ave., New York, N.Y. IOQ17 Ross, R, D--"Industrial Waste Disposal," Van Nostrand Reinhold Com pany, 430 Park Avenue, New York, N.Y, 10022 Sax, N I,--"Dangerous Properties of Industrial Materials." 1963, Van Nostrand Reinhold Company, 430 Park Avenue, New York, N Y. 10022 Sidgwick--"Chemical Elements and their Compounds," Vol, I & II, 195Q, Oxford University Press, Inc., 200 Madison Ave., New York, N.Y, 10016 f f f Sittig, Marshall--"Sodium, its manufacture, properties and uses," 1955 Van Nostrand Reinhold Company, 430 Park Avenue, New York, N Y, 10022 Steere, N. V,--"Handbook at Laboratory Safety," Waste disposal pp 34-40, 1967, Chemical Rubber Co,. 18901 Cranwood Parkway, Cleve land, Ohio 44128 Voeglein, Joseph F--"Storage and Disposal ot Dangerous Chemicals," J. Chem. Educ. 43, A151 (Feb. 1966) Walsh, John--"Pollution--The Wake of the Torrey Canyon" (news comment), Science 160, 167 (April 12, 1968) Weast, R, C, & Selby, S. M.--"Handbook of Chemistry and Physics," 1967, Chemical Rubber Co., 18901 Cranwood Parkway, Cleveland, Ohio 44128 World Health Organization--"Treatment and Disposal of Wastes," WHO Tech. Report Series No, 367 (1967) PAGE 176 CMA 045977 Price: $3 50 per copy Discount: 10 to 99 copies--10%, 100 or more copies--20% Order from Publications Department MANUFACTURING CHEMISTS ASSOCIATION 1825 Connecticut Ave., Washington, D. C. 20009 045978 CMA ! CMA 045979