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* Messrs. J.W. Bowmen - Belvidere A. Cappolia - Stein Hall W. Coble - Newark J. Corley - Clear Lake L. Emge - Houston J. Evans - Stein Ha)) T. Hazelhurst - Greer H. Head - Houston H. Holthausen - Yardley J.W. Lapsley - Charlotte T. Latham - Sayles Biltmore J.G. McLoughlin - Celco J.A. Maher, Esq. ~ New York B. Maurer - -----------' B. Meyer - Bay City J. Sawyer - Bishop P. Stair - Amce1 Ie H. Smith - Rome F. Smith - LouisviIle C. Steinmetz - Charlotte S. Warren - Houston W. Washington - Celriver SUBJECT: Hazardous Materials Regulations As you know, the Water Quality Act of 1970 required that the then FV/QA define hazardous materials so that spills of same could be reported and cleaned up utilizing government money'. The whole designation procedure has become involved in questions as relates what is a hazardous material, as relates to what constitutes a spill, as to whether continuous discharges should be included in the'regulations and as to whether regulations should refer to the Corps, of Engineers Permit Program. Also, there appears a lack of technical expertise on the part of lawyers with EPA in recognizing that the . materials in themselves are not hazardous but become hazardous under certain conditions of release into the environment. tn any event, I attach a list of all those matferials which are now tentatively set to be designated as hazardous. It wi 11'be necessary before a Corp,Permit is obtained to Inventory these materials within the plant and to make sure that none are escaping. This relates to Question 2b on Page 1.2_ of the permit application^ * --' -- 0 EWK/scb Attachment E.W. Kleppinger Vi 010771 Lists of Hazardous Substances Those are materials v/hich arc designated as hazardous in our proposed regulation, 18 CFP Part 618, Designation of Hazardous Substances, l; r !V j ; . . / * V . .* *l * .\ . QJ 0772 Toxic or Heavy Metals- Antimony Arsenic Beryllium Boron Cadmium Chromium : Copper ; Lead Mercury Nickel . Selenium Silver Thallium Zinc ' ' i' |" l , " ' ii 1 Cases or Irritating Substances Brombenzylcyanidc ChloracctophcnoncXylylbromidc Class A Poisons Bromacetone Chlorpicrin Cyanogen Cyanogen Chloride Diphosgene Kexaethyl Tetraphosphace Hydrocyanic Acid Monochloracecone Mustard Gas Nitric Oxide Nitrogen Dioxide Nitrogen Tetroxide Parathion Phenylcarbylamine Chloride Phosgene Tetraethyl Pyrophosphate Tetraethyl Dithio Pyrophosphate Class B Poisons Acetone Cyanohydrin Allyl Alcohol Aniline Barium Cyanide Brucine (dimethoxy Strychnine Calcium Cyanide 4-Chloro-O-Toluidinc Hydrochl Cyanogen Bromide Dinitrobenzol Dinitrochlorbcnzol Dinitrophenol Methyl Bromide Nicotine Hydrochloride Nicotine Salicylate Nicotine Sulfate .Nicotine Tartrate Nitroaniline, Ortho and Para Nitrobenzol Nitrochlorbenzene, Ortho Nitrochlorbenzenc, Meta or Pf Nitroxylol Pe rchlo ro-Me thy1-Mereap tan Phenol Potassium Cyanide Sodium Azide Sodium Cyanide Strychnine Thiopho6gene r JJ10773 PESTICIDES Fungicides Incccticlde9 Captan ' ; Aldrin .. ! Copper Napthenate Dichloronapthoqiiinonc Chlordanc 11 _ ' ; Chloi thion . Ferbara : ' DDD .; Mercury Fungicides . DDT / i Nabam Thiram ' Diazinon . ! t` Dicapthon V, Dieldrin ii r; , Dipterox . : Dibromochloropropanc Herbicides .\ Endrin Guthion ' Ammonium Sulfamate V' I: :: Hcptiicblor 1I ' ;'': 2,4-D Acid 2,4-D Esters 6 Salto ;V\i |'; , l-Isodrin Xelthane .' . _ . CMU Dalapon ' V;. ... Diuron v i.' Lindane \ V V . ; Malaf.h ion : ' Metatystox }! DNEP ' f'l! .'b ' ' Methoxychlor ., . . .'.t-'...;: ;:'j. DNBP (NH^ Salt) Methyl Parathion ' `.V ' Endothal !. 'Nicotine , . ... IPC ' V';," .':.0votran ; ; KCP ,r ' Phenyl Mercuric Acetate . ,I Phosdrin V'. j: Pyrethrum t. . ' ' geson - . ? :Silvex (2,4,5-T) :' .( Rotenone Schxaden V-.-" _ TBA .. i Serin ( i. ' V ; i;: TCA ' . ' V: .'J,'. Simazine H- . 2,4,5-T (Acid, esters, 6alts) '/' Sulfoxide . '>. Systox " 4\ `I i .i i 'i'- l- Others .tepp ;: Thodan 'T.Toxapheno ' V i.- .. -f ::.?enuron \: Kuron V, , ' Omazene -'.-j.-, ' '.^Perthand ; ; Tedion - *'** f: m :*' ,'v* Vapam 1 i' i- Parathion : i' i i ' Ii i i,- ` I I I ^ r v I" v *\ * ; . , , ,, /..* y-H' 010774' Radioactive Isotope Amcricium-241 Antimony-122 Antimony-124 , Antimony-125 Argon-3'/ Arsenic-74 Arsenic-76 Arsenic-77 ... , Barium-131 :' Bariuin-133 Barium-137m Barium-140 Beryllium-7 Bismuth-207 Bismuth-210 Brominb-82 Cadmium-109 Cadmium-115 . Calcium-45 Calcium-47 Carbon-14 Cerium-141 Cerium-144 .. . ... Cesium-131 . Cesium-134 Cesium-137 Chlorine-36 Chromium-51.: Cobalt-57 . Cobalt-58 Cobalt-60 _ Copper-64 Dysprosium-159 Erbium-169 Europium-152 . Europium-154 Europium-155 ' Gadolinium-153 Galliura-68 Gallium-72 Germanium-71 Cold-195 ;; Gold-198 Cold-199 Hafnium-181 Holmium-166 . . Hydrogen-3 " .) V.,-. : Indium-113D Indium-114 . - Iodine-125 : Iodine-125 . Iodine-130 ' Iodine-131 Iridium-192 Iridiuir.-194 l-1.': Iron-55 . 1 / \ * M Iron-59 ; Krypton-85 Lanthanum-140 -:-.Lead-210 Lutetiur-177 ' . Kagncsium-28 y Manganesa-54 ; Kercury-157 Kercury-203 i;olybder.ua-99 Keodyr.iur.-147 I.'..- Keptunium-237 . y. Kickel-63 Kiobium-95 Osmium-151 ' - .v' Palladium-103 ' Palladium-109 `. Phosphorous-32 I.'- .; Plutonium-239 Polonium-210 \ Potassium-42 . Praseodymium-142 . " Praseodymium-143 Praseodymium-144 ; Promethium-147 Protactinium-233 Protactiniua-234 V ' Radium-226 v Rhenium-186 . ' Rhodium-106 Rubidium-86 . : Ruthcniuo-103 -f. Ruthenium-106 Samarium-151 . Samarium-153 ' Scandium-46 _ \ Selenium-75 ' \-\ Silver-110 ' " ' Silver-111 *. ' . ` Sodium-22 Sodium-24 Strcntium-85 . Strontium-67 . Strontium-: ' y : Strer.tium-9C Sulfur-35 Tantalun-lSI Technecium-9 Tellurium-19 Terbium-160 Thallium-204 , ' " Thuliur.-170 Tir.-113 Tir.-119n . ' . . .Titanium-44 ' Tur.gsten-lfif Tungsten-107 Uranium-235 Uranium-238 . Xenon-133 Ytterbium-lc ' Yttrium-90 ' . . Yttrium-91 . ; Zinc-65 Zinc-69 : I .... Zirconium-99 010.775 Industrial Element:;. Compounds or Mixtures .Acetaldehyde . Acetic Acid Acetic Anhydride Acetone Acetonitrile . . , Acetophenone Acetyl Bromide ii :i Acrolein Acrylic Acid ' Acrylonitrile Adipic Acid Adiponitrile Allyl Chloride Aluminum Fluoride Aluminum Sulfate Aluminum 'Tricthyl . Amino Ethyl Ethanol Amine Ammonia . ' Ammonium Acetate ; Ammonium Chloride .. ;; Ammonium Hydroxide Ammonium Nitrate *... Ammonium Perchlorate ' Ammonium Phosphate , Ammonium Sulfate N-Amyl Acetate . ; ' V:-` Amyl Alcohol ' " Barium ..-- > ' v' Barium Carbonate -.; . Barium Hydroxide . Benzaldchyde * *;; '..1. Benzene Benzoic Acid - ,. ' : ' Benzoyl Chloride Benzoyl Peroxide : Bismuth /''* Bromine. ' y; N-Butyl Acetate ' :L N-Butyl Acrylate .; Butyl Alcohol r. Butylamine Butyl Benzyl Phthalate 1,3-Butylcne Glycol Butyl Hydroperoxide N-Butyraldehyde Butyric Acid Calcium Carbide Cfelcium Chloride Calcium Hydroxide Calcium Hypochlorite 'Calcium Phosphate (Dibasic;) ! ' ! Calcium Phosphide ` I' Carbon Disulfide Carbon Tetrachloride 1 Chloric Acid , ,-j ' Chlorine y Chlorobenzene ! i Chloroform i Chloroplatinic Acid ' , Ch].orosulfonic Acid :' |'P-Chlorothynol ; : ' | Chlorous Acid Citric Acid /", " M-Cresol . ' O-Crcsol . : ; ' '.p-cresoi ' ' , ,.Crotonaldehyde ; ,;; Cumene ' . ' Cyclohexane ; i ; ! Cyclohexanol . . . -/ * ' ; j'-. I, Cyclohexanone Cyclohexylamine . . y ' P-Cymene t . . ' Decanal 'L-Decene ; 'N-Decyl Alcohol , Diacetone Alcohol V Diamylamine t I'.;,-'. Dibromochloropropane Dibutyl Phthalate i-Dichlorobenzene ; Dichlorodifluoromethane ; > | Dichloroethyl Ether Dichloropropane Dichloropropene ' . . i' Dicyclopentadiene vri.yDiethanolamine Diethylamine . Diethylbenzene - Diethylene Clycol . Diethylene Clycol Monobutyl E- 1 Diethylcne Clycol Monoethyl E Diethylene GlycolMonomethyl :Dicthylenetriamine Diisobutyl Carbinol - .) Diisobutylene ' Diisobutyl Ketone :Diisopropanolamine Diisopropylamine Dimethylamine H)776 .. Dioctyl Phthalatc ; Dioxanc ' ; ' ; -.r.';. Hypochlorous Acid '; Ir.on ; Dipcntcno ' Isoamyl Acetate ' . Dipropylcne Glycol l|.' '. Isobutyl Acetate ' Dodccanol r |i ' ' Isobutyl Acrylate L-Dodeccnc l Isobutyl Alcohol Dodecylbenzene -.Isobutyl Mercaptan Dodccyl Mercaptan .,. Isobutyralcehydc ' Epichlorohydrin . Isodecaldehyce Ethoxy Triglycol ".-[/ ' Isodecyl Alcohol ' Ethyl Acetate '!. Isooctyl Alcohol Ethyl Acrylate jj / , Isooctylaldohyde Ethyl Alcohol- ij- Isopentaldehydc Ethylaminc ' :i ;.,,-.y Isopliorone Etliyl Benzene Ethyl Butanol *'4\ (. Isopvcne Isopropyl Acetate . 2-Ethylbutyraledehyde , ' , Isopropyl Acetone ' Ethyl Chloride Ethylene ' \ :/ ; [ y.]. Isopropyl Alcohol Isopropylamine 'Ethylene Cyanohydrin ; ';* ' :,;V. " .Isopropyl Ether Ethylcncdiamine Echylone Dibromide ' Ethylene Dichloride ' j; ,!'';. Latic Acid f v-; 'i-: Lanthanum Acetate ," i Lithium Sulfate; .. Ethylene Glycol Magnesium "Ethylene Glycol Monobutyl .Ether Magnesium Sulfate .Ethylene Glycol Monoethyl Ether Maleic Anydride Ethylene Glycol Monoethyl Ether Acetate Mesityl Oxide Ethylene Glycol Monomethyl Ether- ... . Ethyleneimine , Methanol v. Methoxy Triglycol Ethylene Oxide Ethyl Ether :, ' 'J Methyl Acetate . 1\.: Methyl Acrylate Ethyl Formate ' {.'4:.".*, Methylal 2-Ethyl Hexaldehyde Methylamine 2-Ethyl Hexyl Acrylate' . Methyl Amyl Acetate 2-Ethyl-3-Propylacrolein . Ferrous Sulfate ; ; A! r-.Ar... Methyl Methyl Amyl Alcohol Butyraldehyce Fluorine Methyl Chloride yFormaldehyde^> ;; . ;' Methylene Chloride ~Formic~Acid . :r'i Methyl Ethyl Ketone Fumarlc Acid v^;;V 2-Methyl-5-Ethyl Pyridin 'Furfural -'y:y' .Methyl Isobutyl Ketone Furfuryl Alcohol ' ... Methyl Methacrylate Glycerol (Glycerine) . . . v Molasses (Sucrose) . Clycol Diacetatc ... '.. .... Molybdenum Glyoxal . j- f`V; Monochlorodifluoromethen Heptane , ' ...... Monoethanolamine Heptanol V- ..... MonoisopropanoIamine 3-Hep tone '. : '. ' * f Morpholine Hexamethylenediamine Naphthalene .> .Hexane 2-NaphthyIamine ' Hexjnol Nitric Acid L-Hexcne .' ''; .' Nitrophenol Hexylene Glycol ' 2-Nitropropane Hydrochloric Acid Nitrous Acid . Hydrofluoric Acid' .' v . Nitrous Oxide Hydrogen Peroxide Nonane , Hydrogen Sulfide .* NonanoT - -010777 I > I- I r; 1 iI r i ' l i *t ' *. !; a ". : I . . f; ; i f i: i I 1-Honcne .. ' Nonyl Phenol Nitrilotriacctic Acid (NTA) Octa'nol . 1-Octenc ' : Oleic Acid Oxalic Acid t* . : Pentachlorophcnol Pentane Pentadccanol 1-Pentene ' Perchloric Acid Perchloroethylone ir Phosphoric Acid Phosphorous ii. Phosphorus Oxychloride 'j "Phosphorus Pentasulfide / ',y'.. M Phosphorus Trichloride ' i. Phthalic Anhydride _ Polychlorinated Biphenyls (?CB) i Polypropylene Glycol Methyl Ether ; ; Potassium Hydroxide Potassium Iodide "I , ! I.... Potassium Pyrophosphate j _ 'J ,.' Potassium Sulfate ' Propane ' B-Propiolactone ' . j''.'.' '.v\va Propionaldehydc }:'[ \ ' h. Propionic Acid . Propionic Anhydride : Propyl Acetate N-Propy 1 Alcohol .' C. ''.V.'.j Propylene Propylene Glycol \ ' y .'i Propylene Oxide \ / ;i Pyridine ' ' Sec-Butyl Acetate . Skatole '. ^ Sludge, Chemical, (resulting from water or waste treatment plant operation) Sludge, Digested Sewage ' .. Sludge, Raw, Undigested Sewage Sodium Sodium Acetate `` . I Sodium Carbonate Sodium Chlorate : Sodium Dodecyl Benzene Sulfonate (ABS) . Sodium Fcrricyanide Sodium Fcrrocyanide Sodium Fluoride " Sodium Fluosilicate Sodium Hydrosulfite t Sodium Hydroxide Sodium Methylate Sodium Phosphate Sodium Silicate : Sodium Sulfate Sodium Sulfide Sodium Sulfite Sodium Thiocyanate Sorbitol ' ' Stannous Chloride. Styrene Sulfolane ' . Sulfur Dioxicc Sulfuric Acid Sulfurous Acid . Supcrphosphaie Tetradecanol 1-Tctradecer.e Tetraethylcr.e Glycol . Tetraethyler.e Pentaninc . Tetrahydronaphthalene --'Thioglycolic Acid Toluene -Trichlorobeniene I-. Trichloroc thane Trichloroethylene : Trichlorophenol .. Tridecanol 1-Tridecene .Triethanolamine. Triethylamir.e : Triethylbenzene V Triethylene Glycol ; Triethylenetetraroinei ; 2-Undecanol "1-Undecene j Urea ; AN-Valeraldehyde 'Vanadyl Sulfate '. Vinyl Acetate . 'Vinyl Chloride Vinylidene. Chloride Vinyl Toluene 0-Xylene M-Xylene V- P-Xylene >"Boric Acid Chromic ACid Sodium Borace Sodium Chromate v Sodium Dichromate Sulfur Calcium Fluoride ' ''m Arsenate , 010778 t i Ji I r rI i t j. i Calcium Nitrate Copper Sulfate Nickel Sulfate Zinc Sulfate , ' Zinc Acetate l... Zinc Chloride ' Lead Arsenate .. v. Silver Nitrate /. Silver Cyanide Vinyl Ether Propylamine Divinyl 3cnzene Trichloro Fluoro Methane Chloromechane . .. Prppylene Dichloride Lauroyl Peroxide Tetraethyl Lead . I,'.'- Tetraracthyl Lead ,'^-V i ' ij '\\ ' ). i J i .Jt l. I'* . V' 'r;' t. -i y * it t.; i i.n> p i ul!+'.pqu1 ,1 OIL SPILL DISPERSANTS 'y !'. Aiken 0. S. D.'v,- ; Hoil-Chen 06*22 ' ! Aneroid Aqtiancx HC :'V.- '/V.::'} Igepal CO-430 . Ifiepal CO-530 ' ': . Bacto-Zymc . . '.! Isoxal 265 b&b 2021-s B&B 2023 : . Jansolv-60 6 60 .H . r! ' . ' . , ' ' ''; YYv LLCP-12 . ' 'Y * ' Becco B-51-DT- 'I:'- } ` Nagic Power v' BescoD-Emulsion No. 100 ` Magnus . . Beeco Slick - 440 iv-'-VJi v; ' Met Aquadene 100 ' . 'Blitz . Y; ,;v.;, od - 2 \: BP ~ 1002 *' BP - 1100 v :: /. ` / ; : ' ' Casoi : . -w- N.::- -! '.>YOil Spill Ersdicator X-l-11 (Pecrolite) W-.1439 (Pecrolite) -VF-30 " Colloid ~ 88 .V-n.'- , . Polyclene (Koltoklar) Corcxit 7664 ;'. ; Y ' ;.v.; Poly complex A-ll & A-ll D Corexit 8666. 'i A "V;4< Di-Chera 320 '' ' y/yy-y.'-'Ridziik ; : . ' . Seaculso B Disporae-Oil ^Y i. '``Skanex S-102 ; Dispersol OS M',-Y Jitjv'-'sii*- ' ' F. 0. 300-B " y: vVyy'V:* :: Spill - X . ^ P. O. 300-H r Surflo RD 282. Foilzoil r . Talent (Gamlcn) D. Solvent . /. : . , r.. >r . : : ' .'i' : Camosol TEOC 444 .TEOC 777 , ;` Gold Crew '. Tyfosol 80 '* `.-i Uenco No. 2 (Wyandotte) Spill Recover B ';.;: V V\ 010780 section u . Actuuol .. Actusol T-776 . ; '!; Clock 06139 7 t COB afco 1/5250 : ' Acccmul '- . i . : ` "O- . 1; '..1`IW.; . . , .-C oldclcan ji -.'> ` < ; ij'- 1 " i ; . .Compound Kichonagc YLA Actcmul U. C. " Ameroid Drewclean 522 . ' ' .if ', .. . :: ' ;. - ..Conco Emuloificr 700 ' .. Con-O-1571 Amvay Industroclcan * jj '.Anti-Oil TS 3 ' : . ;v !-'. r'p:: ;::y .C-Reiniger Cronax (Oil Spill) . Anti-oil xs^5.: V.i ...: CW Solvent Aquanix \ J\`"j ' Dart DBC Plus , . '' Aquatreat . V'\i)' '' *': Deck Glo . ., Ascal Super 7-11. i' > Degreaser 60 C . Atlas 1901 .. 4 Automatic Tank Waeh-'y ' ''v * -v Y . ~ 1 \ . . t .:yV J >- "* /;Degreco .;~-y ;.-'.Dermol '' .' Baroid Slix-5 7 D. G. 0A ' ' <' . fj' ":r* . Basic-H v. V ;] . . 1..-.. .' Di-Chen; 322 . 6Basal AD. "S,ty "./V' .'*#; i'-'* ;-V/.--" ' '* '* A-. ' v*'v 'j `i`- ^ ;*-. D-Chem 325 BD"30 ; Di-Chem 400 ...'.. Bersen Big Red ., ceseo ' Cejer APC -= '!;.! r' -V . v'-' \ PpP':-. ' Diepersite 110. . : -1 . /.av:,P' ''' 'pp- Dispersal Disolvol Dissolvo .... , *i r - ' i.. Cirrasol -j'( Drew-SC 96 Chevron HI-0 V/.: Cleanosol^ /-. Cleaner - '8671 ; r;:-v'-' y.-*''- :Drew Tank Cleaner No. 4 * .V ;Dunham D-166 * . Elimax .' ' . ' i;:" '/ r; ,J-i 0T0781 I' r Sinking Agents AP-10 Fuel Oil No. 5 Calidria Asbestos Grade R-G444 " 'Fuel Oil No. 6 - Bunker C. . Mcqsite !^ ; 1 Crude Light (Grand Isle Mix; His cron Vapor . i,: Louisiana) Omya Nautcx H ; / ... Crude Medium : Sol-Specdi-Dri zorb-Aii ' -.v. i Crude Heavy (Loganillas) J?-4 ji>-5 , . . : ... Gasoline ; ' -C-o- m- bustioni Pi rioimoti e1 r' s-- ' .i|. ' .-V 5 ,| Tallov; -Coconut Oil . '' '' \ : Cab-O-Sil ST-2-0 '! : Turpentine ' .' . V Capillardiamin ,! < : NSFO :/; .. \ Ekoperl Pyraxon >: 'j.=` ;:'r, . Asphalt Cutting Oil : : ! Sea Bead . ' ' . 1 "; Cas Oils h.'.VvFish Oil.' ' . Biological Degrading Agents DBC P3.ua ^ "'i' Gelling Agents ' . ' ; J.-y : Spill-Away Strickite C'-;- '" '-Vr : v'.'V .'w.'V.-; -Tv; Collection Agents ' Shell Herder Hiecellanous Unclassified Emery 15298 Emcal 42 ` -'.Vy f. Oils Diesel Fuel No. 1-D Diesel Fuel No. 2-D Diesel Fuel No, 4-D Fuel `bil No. 1 Fuel Oil No. 2 Fuel Oil No. 4 j. 010782 IirfEfu'IAL LETTERHEAD ronuacN-ss ncv. 7-6s v y "Vo **na .^/See Below "VAOvt (Nwn n*J LoOitJon) A/ E.W. Kleopinqer 7$9 4- Messrs. J.W. Bowman - Belvidere A. Cappolla - Stein Hall W. Coble - Newark J. Corley - Clear Lake L. Emge - Houston J. Evans - Stein Hall T. Hazelhurst - Greer H. Head - Houston H. Holthausen - Yardley J.W. Lapsley - Charlotte T. Latham - Sayles Eiltmore ACT. NO. EWX-72-08 VI I. i ` Oil. ACf. NO. EWK-73-123 DATE Janyigxv. j.?, 1372- J.G. McLoughlin - Celcp^ R.H. Maurer - CCTC W.T. Meyer - Bay City J. Sawyer - Bishop P. Stair - Amcelle H. Smith - Rome F.G. Smith - Louisville C. Steinmetz - Charlotte L. Susser, Esq. - New York W, Washington - Celriver S. Warren - Houston SUBJECT: Hazardous Materials Regulations Attached are what are probably the final regulations. Please be prepared to comply. EWK/scb Attachments E.w. Kleppi^r 016783