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1152* COPY I
'MONSANTO AISfAACNCOfcFOftATlON / DAYTON LABORATORY / DAYTON. OMO MOT
ESC - DAYTON Win /MCTOtii
ANALYTICAL Tl Ot MfOOl
. won
ACPOATNO.: HDA-413
JOBPAQJCCTNO.: 4S3.5420
OATI: October 27, 1983 ACAIOO COVIAID
"HI ANALYSIS Of LULIHG INCINERATION RESIDUE
RECEIVED
AUTMOAS: B. M. Bushes
NCV 1 1983
^..SANTO-^J.^
ABSTRACT: A staple of nixed DCA heads JnS^Alduc was
analysed for the possible PCB content. The results of the analyses are shown in this report.
Technical Approval:
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Approved by: fCt /- '.jJ
_____________
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Robert P. Ivory 'J
Environmental Sciences Center Service Project Manager
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Approvi 1 date i
<*-7 7- J J
RESTRICTED DISTRIBUTION (see over)
C O M PA N Y CONFIDENTIAL
*MtW*MB4h|iMFN*l* MM
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corvNUMset
1 J. N. Rapko 2 w. B. Bennett 3 R. r. Ivory 4 B. M. Hughes 5 Central rile. e Technical Reports Library
N2B N2B
1250 1250
1250 R2C
ABSTRACT ONLY
P. M. Scott H. A. Nolteraann
021 1250
NOTE:
Distribution of this report is restricted* Requests for additional copies should be made through the principal contact at the Monsanto location involved or the Manager, Environmental Sciences Center, Dayton Laboratory, Oavton, Ohio.
ACKNOWLEDGEMENT
Contributions of the following Dayton Laboratory personnel to this project are gratefully acknowledged:
Analyses:
B. .*1. Hughes D. McKenzie
C. Trang
enmei
r O V P A \ Y CO\F!DE\TIA.
When no longer needed, or upon requeet. return thie report to Centrel Filee. Deylon.
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022659
ANALYSIS REPORT
PATCf Octobor 24. 1903
LOG NUMBER! 1 -83-10-04-02
PROJECT NOl 4S3.54218
TO* Bob Ivorv/St. Lou it (UUa Incinorotion Rotiduo)
FROM*
Eh'ironoontot Scioncot Contor Monsanto Rotoarch Corporation
1515 Nicholas Rood
Dovton. Ohio
45413
Phono No* <S13> 243-3411
Tit to* An I 111 of F'CBt n DC A Hoads (60X) and F*idu Standard SattPlsno riot hod No<>* N/A Standard Etraetior. Mothod No<ti PCEXOI Standard Ar.a t vt i t Mothod No<> ECANO) Final RopoM Fit* No<> A542I8
SAMPLE EXTRACTION! On# taplo labelled AM-148 CCA Hood* C40X> one Residue <40X1 mi extracted in duplicate br elacin* 1.0 in a J4-i Fiore* viol with teflon-lined tidt* seikin* with 40 u I2-dichl or obenzene-C'* and Addin* 10 Alt hexane. Extracts woro thon washed with sulfuric acid a*i eluted through a coluon of tilled tot iAPretnated with eetassiue eeroar.p** ate petattiuA hydroxide and sulfuric ocid nd an activated alunina cetunn. Trr PCB-containino fraction wot olutod with $X oethvlene chlorido in hevar.e tnd concontrotod to 1.0 *1.
SAMPLE ANALYSIS AND RESULTS! Tho above extroct* wort analyzed uin* capillary OC/MS ond cirilUrv OC/EC techniques. Frow GC/MS analysts. on* tatrachlero-biphenyl ioa*r wot dotoctod in tho duplicate taaelet at concentrations of 1*8 and 1.8 us/s. Rocovoriot of CL2-bensena-d4 woro Aoatuftd to bo 14 and 24 X. rotooctivolr. Capillary OC/EC analyses of tno
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Iw'Wtrwtr yUTM valuaeed 9.2 an#
aHIHMarl
>Mf. Tb ilMri ttat eadrecevariee mm mIm mMm< fw Kl limn.
MHrati aaa^vaaa mm alaa mNkM la natch tha Mania vaa 11IM with
ImcIw ISM .at cimmImIImi it 12 lit 24 Uf/|. BecaverJte it triclir
1254 la th*a tM trlktl tablet mm 92 and M * and cencaatratlene if tha
Cll-klilmvl leaner *4 5.0 and 5.2
war* miiwiI. TMmIim tha
value ad 2.0 ua/a CLd-birhanvl leeMr. aaaaurad dren tha OC/HS anatyeea
1* ceneletent vlth tha capillary OC/Cc rtaulta.
Caaillarv OC/EC analvaaa vara canductad with tavala if detection a# 9CB taaaara aarrexlMtely tva ardara ad aaanltude lavar than OC/NS tavala f dataction. Therefore 14 athar cenrenenta. vhlch hava ratantian tmaa
14antica) ta naiar cenrenenta in Araclar 1254. cauld alaa bv nuantlfied. aiiuama CU4-blrhenrl electron cartvre rearenee dactara. Tha fatal cancer.tratlen ad thaaa addltianal cenrenenta vara Matured ta be anrrexiMtelr 14 and 13 X ad tha aajar Cl4-blrhenvl laavar cancantratlan. Thaaa 14
canaananta are alaa thawaht ta be PCB laaaara. but at lavala taa lav ta uneeuivecal l r identify Iran cenrlato Mae arectra. Thav are alaa at lav
eneveh cencentrettana ta that their awantitatian ahauld net be reeulrel dar tha future atudiaa an inctnarttian af thaaa atilt bettene.
Tha raaulta rarer tad abava are far ana ainala tearIa turrlied I. Or. .*ahn Bari a in it. Leuie. Thaaa raaulta indicate that, baaed uran tnia ana anelvtii. tha Lulina veite can be treated at oat cantamine dtfi lurca the total PCB content la lata than SO vr/el. Navavar if ther* It vide variabilit. of tha dCB cancantratiana in athar lata af diclU' > analma haada and reiidrei. the actual aanrla ta be incinerated M.
a'<a:h or even a tat) tha 50 ua/e critanan. Tnaradara it it var . inr.rtant ta datarama PCB cantant for tha headi and raaiduaa vhich vi l' ct'.all. ta mcinaratad to aaau'd that thie incir.aratad aanrla la ml I balov tha 5*> ua/a total PCb concantration rarviranant.
BfOiL-JTii h. n. MuGedEi. C. nClCNUE AhC C. IMHO
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Th* tallawln* ptMl MicrIW StwMrd Extraction Htht an* StaaMri Analytic mihtii uaad tar till rrojact.
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ESC StaMar* Extractlan Hatha* ISEHI
TITLE> Nil tn Variava Hatrlcaa
hatmiixi.icesh
Still tattaai. loili. beat fat Leaf larva, wtiala allk, baaf facai
ESC Stan*ar* Extracttan Hatha* Mai PCEX01
TYPICAL SAMPLE
SIZE (a)
TYPICAL EXTAACT VOLUME
(at I
0.5 - 5.0
I
TYP?CAl"anALVTEirociprl 15557
* ~~ESC~$tan*a7*~Anai7ii~fWthai"Nal7
1241. 1254. 1260. 1262. tnchtara-
ECANOI. ECAN02
I iicmm drouth octochlorolr*f. .1
IN?(MCKC^Cf ( Aii. l<trA c*tgr in?
*{>
th#
t ric-r.
tr t<Mor<-M*h**t I it(>ari threw*
<><t;Mretir.v*
rvPtCAc U**OGATC*
rv*iC*C x
r.# cht er et#ra;r># ^.4.ri(htro*
?/ - |?6 T*A - HO
AMMATV? AMD nATE*!*Lt
h*4l{^ *n# v4<l<r. h.Mi ***:*
Mth.Uriv (hliriO For
# trti.*o#
(fnontntfi tultuMt <il **r >mU 4irtin or orlt clon-v.
SlhCt ! <vlv*if iftrrffMttJ with rotonvo 0vrm**9++ to* lulfvrtc 4CI4*
*M rotttftiv* h.4rc*4o.
A<ttvt#4 fcttic lvir<.
DtlMUtU vl>irr.
LIMITATIONS*
Mht oilv to Mt*ut wKuk 4o not contain nn*Av4ro-
tisftHo oloctroh <triM
in th# trtchlorofriohon*1 throw* eto-
<Merofctohoh. 1 rotention tlot rttitr..
SAFETY PAECAUTJONSi 5 PCD Hontlino nr*to<et tn Utorotor* o#ot* hkmI.
DATES or FCTHOO CREATION AND UPDATES tO/29/83
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CSC Stan4ar4 Analvalt Math#4 ISA") TITLE! PCS* in Salvanta
ESC St ECANOI
tatlnla Natkaa Nai
ANALYTICAL INSTRUMENT AND NOOE OF OPERATION! HP-9880 CaallU/v OC/EC iatarta an HP-3396-LAS Lakaratarv Data Svatan
TYPICAL
analyte
TYPICAL INSTRUMENT level OF rCTECTI ON (LOO)
(aa/nll
Trichlaraaianan.1 IIMan tnrawah
actacMarabiPhanrl itaa*ra
O.Ol
TYPICAL PRECISION 10* LOO
(XI
30
TYPICAL ACCURACY 101 LOO
(X)
30
interferences amt- limitations* a*. aiact/a* caaturm* #(!#> i* tn# rtA*
tlr. tin* raaian t) lri(klrti*hn<l iaa*ara dirwak xtacklarakirkan.l
a*
lMr
C.att ratantian tiwi * mi! tikaW PCS utMri
(an S* abtlina4 if#a lk anal.lit F Araclar 1249. A/o<lr 1254 ar Rracltr
12*0 (Yl<liai.>,
OWNATOOAAPHIC COLUMN! JW t>S-S 10.rs M) cn Fu>4 >111(4 i4a Sara 10. ?:*>
COLiam TEWERATURE PROGRAM! 130(11/4/300
IN.CCTION TYPE! Slitl*>>
CAlISAATION AND STANDARDIZATION* Uta intarnal >tm4ar4 awaMitatian lack*!*... a*4 (aliarata matruPant raaaanaa Factan Fran autnantic PCS taaaar atan4ar4>.
CALCULATION! PCS laaaar canctntratian fiaanar ar)/( i>a*ar RAF) wnarai RAF ia tha ralativa raaaanaa Facta/ Far tha annrarrlat PCS iaaaar.
SAFETY PRECAUTIONSI Saa PCS hantlina aratacala in labaratarv aaFatr aanaal. OATES Of'mETHOO CREATION ANd"mETMOO'UPDATES! 10/29/83
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