Document VjaVmK2EwZ6r0Zej0MjGY1xBK

Federal Register / Vol, 47. No. 173 / Tuesday. September 7, 1982 / Rule* and Regulations 39199 in rndiUU thf suitability of alternate GC cotaiBiorthioiroeUaftHrtiii dlromciosraphic condition*. on* can employ Ac am overlap the revolution parameter with a apadfic maximum permiiiible value. The use of Gaussian function* to describe rtromatofrepblc iution owe* widaaptead. Howevar. sobs elution curves are hiihly asymmetric ta eaeea where the r.w.piVpttk I* followed by p coalemlnant that hai a 1*adini edge that riaaa sharply but die curve than tails eft It nay be possible to define an effective width for t a "twice the diateoce from the leading edge to perpendicular lint through the ataxia of the contaminant curve, ateaaufed along a perpendicular bisection of that Une.M rioradtiraf fi r111 ttt fnrfhH rtirtittrif GC AsaiyeU Responsibilities ofaudit raperviaor and analyst at the source sampling silt Include the following; / A. The audit supervisor verifies that audit cylinder* are stored in a safe location both before end after tbs audit a prevent vandalismB. At the beginning and conclusion of the audit, the analyst record* each cylinder number and pressure. As audit cylinder is never analysed when the pressure drape below 200 psi. C. During the audit the analyet perform*a minima's of two ooneecutive mslyees of each audit cylinderge*. The audit mutt ba conducted to coincide with the analyais of source teat samples. normally immediately after GC calibration and prior to sample analyses. D. At the end of audit analyses, the audit supervisor requests the calculated concentrations from the analyst and compares the results with the actual audit concentrations. If sech msastired concentration agrees with the respective actual soncastration within 10 percent, be directs the analyst to begin analyzing source samples. Audit supervisor judgment and/or supervisory policy determine action whan agreement is not within 10 percent When a consistent Mas in excess of10 percent is found, it may be possible lo proceed with tha sample analysis, with a corrective factor to be applied to tha mulls at a later time. However, every attempt should be made lo locate the cause of the dissepancy. as it may bs misleading, Hie eadit supervisor records each cylinder number, cylinder pressure (at the end of tbe auditj. and all calculated concentrations. Tbe individual being audited must not under eay circumstance be told eetual audit concentrations until calculated concentrations have been submitted to the. audit supervtscr. Field AuAt Report Pari A.--To ba filled out by organization supplying audit cylinders. 1. Organization supplying audit samplo(i) and shipping addnas 2. Audit supervisor, organization, and pbaae number1 1 Shipping instructions: Nome, Address, Attention . Guaranteed arrival dale for cylinder!--'- I. Planned shipping data for A Details on audit cylinders from laet analytic isesene. Htfi aera PartB^Ta be filled out by audit supervisor. 1. Process sampled....... -- 1 Audit location3. Name ofindividual audit* 4. Audit date & Audit results: ACM Gene. Mm*eW!w------ 1------------ 1----------- in ose. as-eost raw e-aenmi mi FEDERAL EMERGENCY MANAGEMENT AGENCY 44CFR Fart 85 [Docket No. FEMA-tSM] Uet of CommunKle* WHh Special Hazard Areu Under the National Flood tnauraneo Program AOawCY; Federal Emergency Management Agency. Acnosc Final role. OUMMAftv, This rule identifies communities with areas of special flood, mudslide, or erosion hazards as authorized by tbe National Flood Insurance Program. Tbe identification of auch areas la to provide guidance to nnmmunitiaa on tha reduction of property losses by tbe adoption of appropriate flood plain management or other measures to minimize damage. It will amble communities to guide future construction, where practicable, away from locations which are threatened by flood or other hazards, imcnvt dates: The effective data shown at the top right of the table or October 7,1882. whichever Is later. PON TOftTMgft INFORMATION CONTACT: Mr. Richard E. Sanderson, Chief. Natural Hazards Division, (200) 287-0270, S00 C Street Southwest, Donoboe Building, Room 505. Washington DC 20472. 9UFHXMIHTARY INFORMATION: The Flood Disaster Protection Act of 1073 (Pub. L 83-234) requires the purchase of flood Insurance on and after March 2. 1974, as a condition of receiving any form of Federal or federally related financial assistance for acquisition or construction purposes in an identified flood plain tree having special flood hazards that is located within any community participating in the National Flood Insurance Program. One year after the identification of the community aa flood prone, the requirement applies to all identified special flood hazard areas within the United States, so that, after the date, no such financial assistance can legally be provided for acquisition and construction in theta areas ,rr|t-- the community baa entered tits program. The prohibition, however, does not apply in respect to conventional mortgage loans by federally regulated, insured, supervised, or approved lending Institutions. This SO day period does not supersede file statutory requirement that a community, whether or not participating in.the program, be given the opportunity for a period of six months to establish that it Is not seriously flood prone or that such flood hazards as may have . existed have been corrected by floodworka or other flood control methods. The six months period shall be considered to begin 30 days after the date of publication in the Federal ' Register or the affective date of the Flood Hazard Boundary Map. whichever is later. Similarly, toe one year period a community has to enter toe program under section 201(d) of toe Flood Disaster Protection Act of 1973 shall be considered to begin SO days after publication in toe Federal Register or the effective date of the Flood Hazard Boundary Map, whichever is later. This identification is made is accordance with Part 84 ofTitle 44 of the'Code of Federal Regulations as f AP66bd4504 0 *< o w 6-$00 121:0461 ENVIRONMENTAL PROTECTION AGENCY REGULATIONS ON NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS (40 CFR 61; 38 FR 8820, April 6, 1973; Amended u shown la Code o! Federal Regulation, Volume 40, Revised u of July 1, 1978; 43 FR 47692, October 16, 1978; 44 FR 7714, February 7, 1979; 44 FR 55174, September 25, 1979; 44 FR 65399, November 13, 1979; 45 FR 13074, February 28, 1980; 46 FR 27342, May 19,1981; 46 FR 29262, June 1,1981; 46 FR 39422, Inly 31,1981; 46 FR 49853, October 8,1981) PART 41--NATIONAL EMISSION SiApart g National Emliaten Standard far Authority: Sec. U2. 301a>. Clean Air Act STANDARDS FOR HAZARDOUS AIR Mercury as amended (42 U.S.C. 7412. 7601iai). unless POLLUTANTS Subparf tUOtMtil Nevkiene 61.50 Applicability. 6131 Definitions. .61.33 Emission standard. otherwise noted. Source: 38 FR 6826. Apr. 6. 1973. tmletts otherwise noted. See. 61.01 Applicability. 61.0* Definitions. 61.0* Units in* abbreviations. 61.64 Address. 61.69 Prohibited activities. 61.53 Slack sgmplinr. 6134 Sludge sampling. 6135 Emission monitoring. fVUpUfT ^**lHI1V-l-il`l *W->-M- 8 *R8- R*8Wa 18V Vfatyt Otlrrladi Subpart A--Gbnaral Provision* 61.01 Applicability. The provisions of this part apply to the owner or operator of any station 61.66 Determination of constructIon or modification. 61.6T Application for approval of construe* tion or modification. 61.06 Approval by Administrator. 61.60 Applicability. 6131 Definitions. 61.62 Emission standard for ethylene chloride plants. ary source for which a standard Is pre scribed under this part. di* S 61.82 OeflnMone. 61.66 Notification of startup. n'*U?*oa StindIrd Ior vinyl ch,oridB WU* mended * 44 FR J5I74. September 61.10 Source reporting and waiver request. 61.11 Waiver of compliance. 61.18 Emission teeti and monitoring. 61.13 Waiver of emission tests. 61.14 Source lest and analytical methods. 61.18 Availability of information. 61.16 State authority. 61.17 Circumvention. Subport 8 Motional Iwfssfee Standard for AlkMiM 61.20 Applicability. 61.21 Definitions. 61.22 Emission standard. 61.23 Air-deaninr. 61.24 Reporting. 61.23 Waste disposal sites. plants. 26 19791 61.64 Emiaaion standard for polyvinyl chloiWvpbnU. 61.66 Emission standard tor ethylene di- The u1 nra usee Vn this part are Helloed In the Act or in this section as follows: chloride, vinyl chloride and polyrinyl chloride plants. 61.66 Equivalent equipment and proce dures. 6137 Emission tests. 6138 Emission monitoring. 6138 Initial report. 61.70 Semiannual report. 61.71 Recordkeeping. MAct" mtana the Clean Air Act (42 U.S.C. 1857 et seq.). "Administrator" means the Administrator <4 the Environmental Protection Agency or his authorized representative. "Alternative method'1 means any method of sampling end analyzing for an air pollutant which is not a reference or equivalent method but which has besa demonstrated to the Administrator'* satisfaction to. in specific Appendix A--National Emiaaion Standards eases, produce results adequate for his deter* for Hazardous Air Pollutants. CompU- minslion of compliance, ance Status Information. "Commenced' mesas, with respect to the Appendix B--Test Methods. definlttaa of "new source" in section Method 101-Reference method for deter* UltoHJ) of A* Act, that an owner or op* minattan of particulate and gaseous water has undertake! a continuous program mercury emissions from stationary <* construction modification or that an Swhpinl 6 Nsttsnai Ewhiteo Standard far terytfWss sources (air streams). owner or eperator has entered into a coo* Method 102--Reference method for deter* hwtual obligationito undertake and complete, minmtion of pArticulate mud caseous reasonsole cbm, a cootinooui pro- 61.30 Applicability. mercury emissions from stationary construction or modification, 62.31 Definitions. 61.32 Emission standard. sources (hydrogen streams). "Compliance schedule" mesas the date or Method 103--Beryllium screening method, dates by which asourceor categoryof sources 61.33 Stack sampling Method 104--Reference method for deter* la required to comply with the standards of 61.34 Air sampling. mination of beryllium emissions from this part and with any steps toward suck stationary sources. compliance which are set forth in a waiver Method 106--Method for determination of of compliance under 661 11 Subpart P--Metianai ImIssIoh Standard far mercury in wastewater treatment plant "Construettoa" wum fabrication, erec- BerylBum tacbet Metar Briag aewagesiuriget,_ tion, or installation of an affected facility. See. 61.40 Applicability. MsthoA IW--DetcrrnhtotMsafc.Waah. ch)w "Effective date" is the date of promuui* w_ rdLlTe*j*%tiqnwy*o)ircew tion la the Federal Register of an applicable 61.41 61.4* 61.4* Definitions. Emission standard. Emission testing--rocket firing or tantw*3M^Dnu^i|iMiMa>8(\v^yw ehtng standard or other regulation under this part. ridfesA^egeuMiii ajsastwafM samples. "Equivalent method" means any method of and^tunjjt-rhrnrlfb siqpi^-qrpe^ iinxk sampling and analyzing for aa air pollutant propellant disposal. cnMfwfeg rr~irTWnrwM*i TrtV `-tt which has beea demonstrated to the Ad- 61.44 Stack sampling. TVmnf-iriiEi ministrator'i sslitfactloo to have a consistent (See. 81.02) ia.4.t1 Published by THE BUREAU OP NATIONAL APPAJRS. INC.. WASHINGTON. D C. 20037 37 AP00004505 121:0462 FEDERAL REGULATIONS and quantitatively known relationship to tho reference method, under specified conditions. '`Existing source" meant any stationary source which is not a new source. ^Modification'' metw any physical (iiifi te-orchange In tee method of operation ef, a stationary source which increases theamount et any kutrWw air emitted by such aoom.or which remits tn the mnlaeton of any haiardoos air poButant at jrevtenaly anssff Sum Ttbfiie faltering rinll sdle nWMiml a chance In the method ef operation: fa) An incream.jn theproduchea rata, if Ql ClwlK wQ twI VIC9i9 "New source" means any slatiooary source, the construction or modification of which is commenced after the publication in Use Federal Register of proposed national emission standards for hazardous air pol lutants which will be applicable to such source. "Owner or operator" means any person who owns, leases, operates, controls, or supervises a stationary source. ''Reference method' means any method of sampling and analyzing for an air pollutant, as described in Appendix 6 to this part. "Standard" mains a national emission standard for a hazardous air pollutant pro posed or promulgated under this part. "Startup" means the setting In operation of * stationary source for any purpose. "Stationary source'' means any building, structure, fscilityor Installation which emits or may emit any air pollutant which has been designated as hazardous by the Administrator. $11.11 units and abbreviatieae. Used in this part are abbreviations and symbols of units of measure. These are de fined as follows: (a) Syttsm International ISI) unite of measure; Asaznpere (a gram Bfesberta Jsjeuis decree Kelvin kg=fcUogma nfmeubu BtMT IQ-6 mw=mnunersib- meter KgsmagmgramsU1 gram melscmole Rsuewtoti ngsnsnocraasitH gram anenanometers ic* meter MtmpMcai sixsecond Weeolt VsiMt flbUBh 4aiunpaiB ifr* gram <b> Other waits of measure: 'Csdegree Oteha (iwrMgrerte) elmsMade Zee* per mttrate oessooMe osptlnsrter decay 'VsdtpM Mmaheit ffmaquare fee* xtfmeobie feet falagalloa iBslach la HgstnchM of mercury in H,0incheseg w*t* teller inspound 1pmmliterpar artMto milw !<)* UsrnmuiurM Z0-* liter naigspounds per aware inch gage *Sadegree Bcrtelne pollutants for stationary sources locat ed in such State. All information re 4enlmlilselb< titer e/vsvoiume par volume fd'saqoaie yarda yvaytar <e> ChenticaJ nomenclature: quired to be submitted to EPA unier paragraph (a) of this section, must also be submitted to the appropriate State Agency of any State to which this authority has been delegated Be=beryUltun Sgsesueenry %Oamnr (provided, that each specific delega tion may exempt sources from a cer tain federal or State reporting require (d> ICiaoeQaiMOtte: ment). The appropriate mailing ad MtcWtOti Sseaivneslndg*ediameter meter Rasenaal dress for those States whose delega tion request has been approved is as follows: (A) (reserved] OJ>.eteMa dtamster gapiRmt SdsacaBdardi (42 FR 51574, September 29, 1977] (B) State of Alabama, Air Pollution Con trol Division, Air Pollution Control Commisnon. 646 S. McDonough Street, Montgomery, Alabama 36164. U1.M Address. (C) (reserved) [91.04(e) amended by 46 FR 19422. July 21. 1M1) (a> All requests, reports, applies* tions, submittals, and other communi (D) Arizona Marloopa County Department of Health Services. Bureau of Air Pollution Control. 1626 East Roosevelt Street, Phoenix. AZ cations to the Administrator pursuant 16006. to this part shall be submitted in du Pima County Health Department, Air plicate and addressed to the appropri Quality Control District, 161 West Congress, ate Regional Office of the Environ Tueaon, AZ S6T0L mental Protection Agency, to the at tention of the Director, Enforcement Division. The regional offices are as (Ej (reserved] i'-Ciiifomis: follows: (F) California: Region I (Connecticut. Maine. New Hamp shire. Massachusetts. Rhode island. Ver mont). John F. Kennedy Federal Build ing. Boston. Massachusetts 02209. Region XI (New York. New Jersey, Puerto Rico. Virgin Islands!. Federal Office Building, 26 Federal Plaza. (Foiey (6I.04(b)(F) amended by 46 FR 49BS3. Oc tober t, mi) Amador County Air Pollution Control District, P.Q. Box 430,610 Court Street. Jackson. CA 06642 Bay Ares Air Pollution Control District, Square). New York. N.Y. lOOftl. 99 Sills Street Sen Frmadrao. CA 04100. Region III (Delaware. District of Columbia, Pennsylvania. Maryland. Virginia. West Virginia), Curtis Building. Sixth and Walnut Streets. Philadelphia. Pennsyl vania 16106. Region IV (Alabama. Florida, Georgia, Mis sissippi. Kentucky. North Carolina. Butte County Air Pollution Control District. P.O. Box 1219. SIS Neleon Avenue. Orovlile, CA 95968 Celeverfli County Air Pollution Contra] District Government Center. El Domdo Road. Sun Andress. CA 96249 South Carolina. Tennessee). Suite 900. Colusa County Air Pollution Contra) District 1421 Peachtree SireeL, Atlanta. Georgia 90309. Region V (IUinois, Indiana, Minnesota, 751 Fremont Street Colusa, CA 96962 Dei Norte County Air Pollution Control Michigan, Ohio. Wisconsin), 230 South Dear District. 909 Highway lOI North. Crescent born Street. Chicago, Mools (0604. City, CA 9S531 Region VI (Arkansas, Louisiana, New Mexico, Oklahoma. Texas). 1600 Patterson Street, Dallas. Texas 76201. Region VII (Iowa, Kansas, Missouri. , H Dorado Air Pollution Control District. 390 Fair Lunu. Plmerville. CA 9S667 'resno County Air Pollution Control District. Nebraska), 924 East 11th Street, Kanias P.O. Box 11867.1246 L Street, Fresno, CA City, Missouri 64106. 93721 Region VIII (Colorado. Montana, North Dakota, South Dakota, Utah, Wyo ming). 196 Lincoln Towers, I860 Lincoln Street, Denver, Colorado 80202. Region IX (Arizona, California, Hawaii, Glenn County Air Pollution Contra! District. P.O. Box 35L 720 North Colusa Street Willows. CA eseaa Creel Busin Unified Air Pollution Control District. 663 North Main Street Suite 211, Bishop. CA 93514 Nevada, Guam, American Samoa), 100 California Street, San Francisco, Cali fornia 94111. Region X (Washington. Oregon. Idaho, Alaska), 1200 Sixth Avenue, Seattle, Washington 98101. Humboldt County Air Pollution Control Dfatriet. 9600 8. Broadway, Bunks. CA 06961. Imperial County Air Pollution Control District. County Services Budding. 939 West Main Street. Bl Centra. CA 9224S (b) Section 112(d) directs the Admin Kern County Air Foliation Control Dis istrator to delegate to each State, trict, noo Flower Street (P.O, Box 997>, Ba when appropriate, the authority to im kersfield, CA 93302. plement and enforce the national Kings County Air Pollution Control District, emission standards for hazardous air M0 CtraiHis Drive. Hanford. CA 83230 Environment Reporter (See. 61.04(b)] 36 HAZARDOUS EMISSIONS S-9M 121:0463 Lake County Ait PoUutkm CmM DUMct' Yolo-Solano Air Poilutfan Control DUMet J8S North fwtw Street. Laheport CA P.O. Box 1006k 633 Pint Street #*. 9MSS .......... Woodland. CA 0*606 L men Comity Air Folluttoo Control Otatrict, [43 Fit 20986. May 16,19781 ITS Kueeell Avenue. Sueanvilla. CA 06190 Uidn County Air Pollution Control DieMot. IS* W.w------Avanvie. Ukdm, CA mot: MiripaH County Alt Pollution Control District. Ban 8. Mariposa. CA 0693* co>--State of Colorado. Colorado Air PoUutlon Control Divides, 4610 Beat 11th Avaunt, Dram. Colorado 60230. [40 FR S0719. October 31. 1975| <H) State of Connecticut, Departtneul of Xaviroiimental Protection, State offee lrmilnrtnit Cewty Air Pollution Control Bulidinc. Hartford, Connecticut out* District, County Courthouse. Uriah, CA [41 FR 11820, March 22.197*1 NRt Moread County Air Polludoo Control Diatriet, (t) State of Delaware (for aebertaa. beryl Una and mercury only* Delaware Depart P.O. Box 471. MO But lh Street. Merced. ment of Natural Resources and Envtrozv CA 6*940 mental Control, Sdward Tatoal) BuUdJnc. Modoc County Air Pollution.Control DUtriot. Dover. Delaware 16601. 2Ca Waot 4th Stmt. Altnrea. CA 86101 (43 FR 6771. February Id, 1978) Monterey Bay Unified AirPollution Control District 1270 Nttividad Road. Room 106, Sallsai. CA 6SS06 Nevada County Air PoDutioo Control District, H.E.W. Complex. Nevada City. CA 06660 Northern Sonoma County Air Pollution Control DUMot. 1M "AH Avenue, Auburn. CA 05446 (JKK) (mexrod) (I,) state et Georgia, Environmental Pro* taettoa Dlvtdon. Department'of Natural IWounh 610 Washington Street, 3-W, At* lanta, oeorfia aosoa. [41 FR 24885. June 21, I976| (MHO) [reserved) Placer County Air Pollution Control DUbid 114*1 "BT Avenu* Auburn. CA 66601 Ptuzmu Cuuoty Air Pollution Control DUMet P.a Bax 460. Quincy. CA 650T1 (P) State of Zodiaca. Indiana Air Pollu ting centra hoard, 1MO West Michigan etreat. Indian*polls, Indiana 4660#. (41 FR 43148, September 30. 197] Sacramento County Ah Pollution Control t (S> Division of Air Pollution Control, DeDistrict. mi ftueb Crater Hoad. Boom- I pertmani for Natural Resources and Irivt- IBflntO, CA *6661. 1 ronmental protection, DA 187, Frankfort. Sun Butnwdiau County Air Polladon Control Ky. 40401. DUlrid. lM7B-6th. VlctorvtQa. CA 92966 [43 FR 3361, January 25. 1978) Sen Dine County Air Pollution Control (U) Stale of Maine. Department of Envi District, 9iM Chesapeake Drive, Sin Diego, ronmental Protection, Stats Home, Augusta, CA 06166. san Joagufn county Air Pollution Control Maine 04330. 140 FR 59729. December 3a 1 MS] District. 1661 S. --*" Street (P.O. Bos 2600). Stockton. CA *6601. h Luis ObiinoCounty Ait Pollution Control District. PC. Box 637, Baa Lula Obispo. CA (V) Slate of Maryland. Bureau of Air Quality and Noise Control Maryland State Department of Health and Mental Hygiene. 201 West Preston Street. Baltimore, Maryland 63406 21201. Santa Barbara County AirPollution Control District 300 North Saa Antonio Road. [61.04(6)00 added by February 28. 1980) 43 FR 13074. Santa Barbara. CA63110 Shasta County Air Pollution Control District (W) Massachusetts Department of Environmental Quality Engineering, Division of 2630 Hospital Lana. Redding. CA 86001 Air Quality Control. *00 Washington Street, Sierra County Air Pollution Control District Boston, Massachusetts 02111. P.O. Bos 266. DownisxilU. CA 060M Siskiyou County Air Pollution Control District S2S South Foothill Drive. Yreka. GA 96097 South Coast Air Quality Management District 9160 FlairDrive, El Monts, CA 61731 (X) State of Michigan. Air Pollution Con trol Dtviaiea, Michigan Department of Na tural Resources, Stevens T. Muon Building, 8ih Floor. Lansing,Michigan 48926. (Y) Minnesota PoHution Control Agency, Division of Air Quality, 1935 Wert County Road S-2. Roaevifle, Mian. 55113. [43 FR 10, January 3, 1978) Staniolaas CountyAirthjffutionControl (Z) [reserved) District 1000 Scenic Drtvt. Modesto. CA (AA) Missouri Department of Natural 06SSO Resources. Post Office Box 1368, Jefferso* SutterCounty Air Pollution Control District Sutter County Office Building. 146 Garden Highway, Yuba City. CA 66691 Tehama County Airrotation Control District P.a Box 36.1760 Walnut Street. Rad Btuft CA 66060 Trinity County Air PoBatfon Control District City, Missouri 4SI0I. [6l.04(bXAA> added by 46 FR 27342, May 19. 1981) (BB) disco of Montana. Department of Health and Environmental Sciences, Cogswell Building, Helena. Mont 39601. (42 FR 44545. Septarohac 6,1977) P.a Box AX Westerville. CA 06OB3 (CC) Sute of Nebraska, Nebraska Depart Tulare Connty Air Pollution Control District County Civic Center. Visalia. CA 63277 Tuolumne County Air Pollution Control District 9 Nora Washington Street ment of Environmental Control, P.O. Box 94877, State House Station, Lincoln, Nebraska 68309. iul'3^981) adM ** 46 FR 3M22, Booora. CA 88370 Venture CountyAirJtofiutidn Control District 600 Snath Victoria Avenue, Ventura. CA63009 (DD) Nevada: Nevada PeyaiUarat of CnswirvaMnst ra4 Natural Resource*. DMason of Enrtronmsn* tal Protection. 361 South Phil Street. Canon Oty. NV 69110. Clark County County Dlatrlet Health Dopartauat. Air Pollution Control Division. S25 Shadow Lane. Las Vegas. NV 69196. Washoe County District Health Depart ment, Division oi environmental Protection, 10 Kbm Avenue. Rene, KV 66803. [43 FR 20961. May 16.1918) (EX) New Hawpahirt Air Pollution Control Agency, Department el Health and Welfare, State Laboratory Building. Basra Drive, Conoord, New Hampshire 08301. (41 FR 19633. May 13.1976J <yp)~ute ct New Jersey: Now Jersey De partment of xnrironmeatai Protection. John tttoh Pisan, P.O. Xw 3607, Tranton. New jazaay OMan. (42 FR 37387. July 21. 1977] (CG) (restvedj iaaj new York: Now Tik State Dept*** mtat of EavlronmaatAl Conservation. $0 Wolf Hoad. Albany. New York 15336. attention; DivMon of Slr'lMawiia [40 FR 48347, Ocrober 15. 1975| (XI) North Carolina Enviroumontsf W-u. agetneut Commission, Depaitusent ot Natural and Economic Itceoureas. Division of Envi ronmental Management. P.O. Box 3T091. R. letgli. North Carolina 37911. Attention: Air Quality Section. (41 FR 56805, December 30, 1976] <JJ>--Bute af North Dakota, fltato De partment of Health. State Capitol. Bismarck. North Dakota SgSbl. [41 FR 44859, October 13. 1976} [KK) Ohio Montgomery County: Regional Air Pollutioa Control Agency, Montgomery County Combined General Health District. 481 Wert Third Street Dayton. Ohio 45402. Clarita. Darke. Groene, Miami and Preble counties [except for all information required under $61.22(d) and (6)1: Montgomery County Combined General Health District. 491 west Third Street, Dayton, Ohio 4S402. (M.M(bHKK) added by 44PR *S400. Novembw 13, 19791 (LL) [Reserved) (MM) State of Oregon. Department f 2htvironmrata2 Quality. 1334 SW Mor rison Street, Portland, Oregon 97205- (41 FR 7750, February 20, ] 976) (MN) (a) Commonwealth of Pennsylvania (except for City of Philadelphia and Alle gheny Gooncy) Peaaejlvaata Department-of Environmental Heeouroen Bureau of Air Quality and Noise Control. Poet cam Box mi, Harrisburg, Pennsylvania mao. (NNMb) City of Phtiadelphlg. PhlladBlpbta Department of Public Health. Air Management Service*. 601 Arch Street Philadelphia. Pennsylvania 10107. [42 FR 6612, February 4, 1977) (OO) State of Rhode Island, Department of Environmental Management, 68 Park Street. Providence, R.L 92906 (43 FR 47692, October 16, 1973) <PP) state or sooth Carolina, ooee of En vironmental Quality control. Department of Health and Environmental Contra, 3600 Bull Street. Columbia, south Carolina snaoi. [42 FR 4124, January 24, 1977) 18-4-81 [See. S1^4(b)] Published by THE BUREAU OF NATIONAL AFFAIRS. INC.. WASHINGTON. DC 20037 39 AP00004507 121:0484 FEDERAL REGULATIONS (QQj [rsservsd] (RR) Division of Air Pollution Cantrot. Tennessee Department of Public Health, 256 Capitol Hill Building. Naihville, Tenneuee 27219. (6f.04<bXRR) edded by 46 FR 29262, June I, 1911] (88) 8UU of Texas, Tens JUr Oon- trol Board, 8530 Shoal Creek Boule vard, Austin, Texas 78756. Standard Nllfl SiTTll il nee wlttrthisschpati, neeptunderan exemptioo gristed tor tbe President gader lection 113(e)(3) f fee set.. Source*. the construction or modification of which com menced after the publication date of tbe standards proposed to be applicable to auch source, are subject to this prohibition. <b) After the effective date of any' sufficient detail to permit assessment of the validity of such calculations. {41.66 Apgeovai by Adeiinliuetor. () The Administrator wlU, within 60 days of receipt of sufficient informa tion to evaluate an application under 161.07, notify the owner or operator of approval or Intention to deny approval (44 FR 7714, Fetousiy 7. 1979] (TO txewrvstf] Bute of Verawot, Agatov of pavlran. oMtital Protectioa, Bos 4g. UootpeUar, Tarmom 06603. |42 FR 1215. January 6. 1977] <W> Commonwealth of Virginia, Vlrglqi* State Air Pollution Control Board Boom 1106, Moth Street OfflM Buildlag, TUchmcinri, Virginia 33218. (41 PR 5344. February 26. 1976] standard prescribed under tins part, ns owner or operator ahall operate any sew source In violation of each standard ex cept under an exemption granted by the President under section 112(e) (2) of the act. ie> Ninety day* after the effective date of any standard prescribed under this part, no owner or operator than operate any existing stationary source in viola tion of such standard, exoept under a waiver granted by the Administrator iq of construction or modification. (b) If the Administrator determines that a stationary source for which an application pursuant to {61.07 was submitted will, tf properly operated, not cause emissions in violation of a standard, he will approve tbe con struction or modification of such source. fc) Prior to denying any application for approval of construction or modifi (WW> <1> Weahlngton: BUte o Wash aoeordanee with this subpart or under cation pursuant to this section, the ington, Department of SooJogy, Olym- an exemption granted by the President Administrator will notify the owner or rla, Washington 96504. under section 112 (o) <3) of the act. operator making such application of <ii) Northwest Air Pollution Author ity. 307 Pioneer Building, Second and Pine Streets, Mount Vernon, Washing ton 96373. (Ill) Puget Sound Air Pollution Con trol Agency, eio West Harrison Street. Seattle, Washington 96119. (iv> Spokane County Air Pollution Control Authority, North 611 Jefferson, spokaus. Weahlngton 99301. (v> Yakima County Clean Air Author ity, County Courthouse, YUdoa Wash ington 98901. [40 PR 56640, December 18. 1975] (i) Olympic Air Poumion control aotbority, 120 East State Annin, Olympia. Washington 96601. (till Southwest Air Pollution Control Au thority. auite 7B01 B. NX Basal Dali Annul, Vmiwmvtr.WMhlnttta ISMS. (41 FR 4264, January 29, 1970) (XX) (reserved). (TT) Wtaeraaia-- Wisconsin Department at Natural Beaourcee. TJO. BOS 7931, MadtSOC, Niseoaain 65707, [42 FR 16778, March 30, 1977) <ZZ) [retervedl. (d) No owner or operator subject to the provisions of this part shall fail to report, revise reports, or report source test results as required under this part. the Administrator's Intention to issue such denial, together with: (1) Notice of the information and findings on which such intended ! '? * denial is based, and (2) Notice of opportunity for such j^ssa^nssssi- owner or operator to present, within 'such time limit as the Administrator fftll make a determlnatldn WWhether shall specify, additional information actions taken or intended to be tafcett or arguments to the Administrstor By such owner er opnatef Constitute prior to final action mi such applica gMutruction `or- ,raodifie*doirtor the tion. commencement .thereof within the (d) A final determination to deny meaning of this part. The Administra any application for approval will be in tor will within 30 days of receipt of writing and will set forth the specific sufficient information to evaluate an grounds on which such denial Is based. application, notify the owner or opera Such final determination will be made tor of hi* determination. within 80 days of presentation of addi 161.87 Agdikalian for Mgruval, nnietlSB er mflflwliw. tional information or arguments, or 60 days after the final date specified for presentation, if no presentation is (a) The owner or operator of any made. new source to which a standard pre (e) Neither the submission of an ap scribed under this part is applicable plication for approval nor the Admin shall. ftrioi:,to the oon- istrator's granting of approval to con (AAA) (reserved] <BBB1 -- Ceramauwcalth of Puerto Rice: Commeevultb of Puerto Rice SevireomaUl Quality Board. P.0. Boa 117*8, Sasturce. P.R. 00910. .-cructionSr modtfiatoMQs Plaiined to Qemmenee.'e-erfthtn so-neye after the effective dam m ehe a--smog m-tew. mmv thatjalreadyrtMff wammenced gunmiuttleir wrrniudfflcalluh land has struct or modify shall: (1) Relieve an owner or operator of legal responsibility for compliance with any applicable provision of this part or of any other applicable Feder (42 FR 62137. December 9. 1977] 'j&SE&aGSSUtiEl&ig iCCCJ--U.6. Virgin Islands: US. Vir gin Islands Department of Conservation and Cultural Affairs, P.O. Box 578, Char lotte Amalie. St. Thomas, Uff. Virgin *gtval-of --*--tfMtJflliJft WtfHft- mtfjon. A separate application shall be submitted for each stationary source. <b> Each application shall include: al. State, or local requirement, or (2) Prevent the Administrator from Implementing or enforcing this part or taking any other action under the act. Islands 00801. |4I FR 34629, August 16. 1976) (DDD) |reterved|. (1) The name and address of the ap plicant. <2) The location or proposed location of the source. {61.69 Notification of startup. (a) Any owner or operator of a source which has an initial startup (39 FR 37987. October 25, 1974? 40 FR (3> Technical information describing after the effective date of a standard . 18169. April 25. 1972; 40 FR 42195. the proposed nature, size, design, oper prescribed under this part shall fur Scpiemboi 11. 19)6) ating design capacity, and method of nish the Administrator written notifi (SWLOS - PeehmmdeeMWOee. SI After-the tCtagioSsirei ear Canted pmeerlbed nndex -this wart. n wuar or operetnrshall construct or mod ify any gtactenarr ssNg Mhiebt e each operation of the source, including a cation as follows: description of any equipment to be (1) A notification of the anticipated used for control of emissions. Such date of initial startup of the source technical information shall include not more than 60 days nor leas than 30 calculations of emission estimates in days prior to such date. (See. ei.OtUHin Environment Reporter 40 AP00004508 1 HAZARDOUS EMISSIONS 3-500 121:0466 (2) A notification of the actual date (S) A description of interim -- ject to this pert, shall provide or cause of initial startup of the source within control steps which win be taken during to be provided, emission testing facili IS days after such date. the waiver period. ties ss follows: <Ser. 114. Clean Air Act as smsnded <42 UA.C. HU (e> changes In the taibraettea pro (1) Sampling ports adequate for test vided tinder pangraph (a) of this section methods applicable to such source. hell be provided to the Administrator (21 Saf* sampling plsiform<s). g til .10 Sourr* reporting tnd waiver re within 50 days after such change, except (3) Safe access to sampling plat- quest. that 11 changes trill result from modUtaa- form(s). tton of the source, is ****** in 161.02* (4) Utilities for ----r14T,ff and testing (a) The owner or operator of any ex <J), the previsions aC i 6L6T and I 61.03: equipment isting source, or any new source to aro sppUoable. (Sec. 114 of the Qetfi Air Act as amended (42 which a standard prescribed unde** <d> nit format for reporting under US.C.74I4)) this part is applicable which had an initial startup which preceded the ef this section is Included as asper.uUx A at this part. Advice on reporting the status 161.IS elver ofcmlssUm lesta, i i fective date of a standard prescribed under this part shall, within 90 days after the effective date, provide the following information in writing to the of f--p:|*n*f may be obtained Administrator. b* (a) Emission torts may be waived upon written applicative: to the Admin (Sec. 114 of the Clesn Ah Art:as emended (42 UJS.C. 7414)) istrator if, to his Judgment, the source is me*ting the standard, or If the source is operating under awaiver of compliance Administrator f 61.11 ValwreftanpUssM. or has requested a waiver of compliance. < 1) Name and address of the owner or operator. (2) The location of the source. (3) The type of hazardous pollutants emitted by the stationary source. <4j A brief description of the nature, size, design, and method of operation of the stationary source including the operating design capacity of such source. Identify each point of emission for each hazardous pollutant. The average weight per month of the hazardous materials being proc essed by the source, over the last 12 (a) Basedon the information provided in any request under i 61.10, or other top formation, the Administrator may grant a waiver of nwpii*M with a standard for a period not exesedtog a yean from the effective date of such standard. <b) Such waiver win be to writtnr and will: (1> Identify the stationary source covered. . (2) specify tiie termination date of the waiver. The waiver may be termi nated at an earlier date If the conditions specified under paragraph Cb) (3) of this BSfig|B are not met. <b> If application for waiver of the emlwion test Is made, such application hall accompany the information re quired by I eilio. The appropriate form is contained la appendix A to this iiart. <c) Approval of any waiver granted pursuant to this section shall not abro gate the Administrator's authority under the act or in any way prohibit the Ad ministrator from later **nwg such waiver. Such cancellation will be made only after notice Is given to the owner or operator of the source. (Sec. 114 oftbs Cku Air Act si amended (42 U.S.C.7414)) months preceding the date of the (3) Specify dates by which steps to | 61.14 Source test sad analytical meth report. ward ecmpliaaice aro to be taken; and ods. (6) A description of the existing con Impose such additional conditions as the (a) Methods 101,102. and 104 to ap trol equipment for each emission Administrator determines to be necss- pendix B to this part shall be used for point. (U Primary control devicets) for each hazardous pollutant. Ui> Secondary control devlcets) for each, hazardous pollutant. MHt Estimated control rfltateney (per- esnt) for each control device. (7) A statement by the owner or oper ator ei the souses as to whether he oaa oomply with the standards preserved in this past within M days of the effective (b) ' The ownmror operator of an exists sary to assure taatsMstten of the neces sary controls within the waiver period, and te aasun protection of the neaith Oft peyeqng during the waiver period. (e) Frier to denying any request toe a waiver pomuat te this isrtten. tins Admtolfteator will notify the owner or operator making such rsqueet of the Ad- mtDlrtratar'i i*4*ntton to i**!* such deals], together (1) Notice of tbs Information and Wwrifap gg which sm*. Intended ***:*: Is based, and <2) Notice of opportunity for such, all source tests requlnd under this part, unless an equivalent method or an al ternative method has been approved by the Ad^ijnWffitiMti (b) Method 103 to appendix B to this part is hereby approved by the Admin istrator as an alternative method for toufess subject to | Jl,32{*rahdTBr42 <b>. (c) .The Administrator may, after no tice to til* owner or operator, withdraw approval of an alternative method granted under paragraphs (a), (b) or lag source unahie to operate in ccmpllanee with any standard piescrtbsii under Oils part may request a waiver of com owner or operator to present, within such time limit as the Administrator Specifies, nr srpi. (d) of tills section. Whare the test results using an alternative method do net sde-' quetely Indicate whether a source is In pliance with such standard for a period not exceeding 2 yean from the effective meets to the Administrator prior to final action on such request. oompllanc* with a standard, the Admtaisteator nay require the use of the date. Any rcauest shell be in writing and shall Include the following information: aA dsfcriptioe of the controls to be d to comply with the standard. (2) A wmpSane* schedule, including the date each step toward compliance wul be reached. Such ost dull include as e mbusnum the following dates: (1) Date by which eontracts for ends*ton control systems or process modifica tions win be awarded, or date by which orders will be issued far the purchase, of component parts to accomplish emis sion control or protsm modification: <il> Date of initiation of onsite con struction car Installation of ---h--w. oqq. trot equipment or process change: (d) A fell determination to deny any reference method or Its equivalent. request for a waiver will be to writing <dl Method 165 In Appendix B to this ad wlB set forth the specific grounds on part Is hereby approved by the Adminis which Muh dnlil te hAa^. Ama] trator as an alternative method for determination win be mode within so sources subject to 161.93(b). days efter prsscntatlon of additional in (40 FR 48292. October 14. 1975] formation or arguments, or 30 days after 61.tf fraHeHIby of Infer- i.ttae the final date specified lor such presen tation, If ne presentation Is made. t <> The granting pf a waiver unde? this section shag set abrogate the Ad ministrator's authority under section 114 >Ib*.iwaUebUity to tbs pehHo-qt.to* tataarttaa-mvlfled to. or otharwhe ob- by. tbs Administrator<wadar4&U gpg*qfa*fl.he governed by Fast 3 of this of the eel; [41 FR 36913, September 1, 1976| | 61.12 EteUriro tests aad asoaileriag.' (a) Emission - teste and monitoring (Sec. 114 of the Clean All Act u amended (42 U.S.C, 7414)) shall be contacted and reported as set (Ul> Date by which onsite construc tion or imtallatiVin of --* eontroi equipment or process modification Is to be mmDieted; and fiv) Date by which final compliance Is forth to this part and appendix B to this g 61.14 Sum smhority. part. ~'76T The owner or operator of a dnr source subject to this part, and at the (a) The provisions of this part aHaii not be construed in any manner to pre request of the Administrator, the owner elude any State os polltioel subdivision to be achieved. or operator of an existing source sub from: 12-4-SI Published by THE BUREAU OF RATIONAL AFFAIRS, INC., WASHINGTON, D.C. 20037 " 41 AP00004509 121:0466 PEOERAL REGULATIONS (1) Adopting and enforcing toy m||> ehidlag oommerdal asbestos, and tho but act limited to, highways, roads, too limiting regulation mtUeiU* to a im>i*OMlns of this rcentiinalton mto a streets, parking atcas, and driveways.- stationary source, provided that inch ml--ion limiting regulation It not ]e-- stringent then the standards prescribed tinder this pert. (3) "Requiring the owner or operator of a stationary source, other than a sta ttanary source owned or operated hr the product as specttUgm | L22<e). <i> s^Dwnolitton'^mteni the wracking or tektec out of any toad-tupp--ting structural and any --feted re* -mevfcaror shipping of friahls asbestos taatertsO*. <k> "Friable asbestos material" moans any material that t*-***^ more than* (w) "Asb--toe-oo&teinJnf waste mate rial" means any waste which eonfcains oocnmereUl asbestos and is generated by a source subject to tho provisions of this subpart, including asbestos mill tellings, control'device asbestos waste, friable as bestos waste material, pad bags or eon* telners that previously contained oom United states, te obtain permits, or approvals prior to Initiating oenstnaetiom, modification, or owratton of such source. (See. 114 of the dots Air Act as aipmded (43 VAC. 7414.) psrantAibtttos by weight and that oak be ennobled, pulverised, or reduced to merdal asbestos. powder, when dry. taw hand preasur*. (40 FR 48292. October 14.1975] (1> "Control device asbestos waste" (x) "Structural member" T**vry any moans any aabostos<ontalalng waste material that Is ooUeeted In a pollution control devioo. - lead-supporting member, such as beam* and load-supporting walls; or any non- 161,17 QwtewptlHBi " (ml "Renovation" means tbs remov load-supporttog member, tuefi as --ninga No owner or operator subioet to the provisions of this part shall build, erect, install, or two any article. machine, equipment, nrnr--, or method, the use of which conceal* an amission which would otherwise constitute!a violation of aa applicable standard. Such concealment includes, but Is net timttod to, the nee of ing or stripping of friable asbestce ma* terlals used on any pipe, duet, boiler, tahfc, reactor, turttfoe, furnace, or structural member. Operations In which toad-supporting struetural members ore wrecked or taken out are JPangr^h (m) isvtied by 43 FR 26373, Jane and non-load-supporting walls. [42 FR 12127, March 2, 1977] ) 6132 Emission standard. (a) Asbestos mills: There shah be no visible emissions to tho outside sir from any asbestos mill except at provided In paragraph <f> ofthiq section. caseous dilutant* to achieve cempttanee with a visible omi--tons standard, and the piecemeal eanyteg out of an opera tion to avoid coverage hr a standard that applies only te opeqtlcgie taxer than a spectfiedsiie.. . [40 FR 48293, October 14, 1975) Subpart I -Hattons! Emission Standard for Asbestos [39 FR 13936, M*y 3,1974| <n> "Planned xsaovaUca" means a renovation operation, or a number of (It) Roadways; The torfsciag of road such operations, m which the amount of friable asbestos material that will be removed or stripped within a given pe riod of time eon be predieted. Op--tfoua ways with ssUhios tsIUnii or witli u> Ivstoscontslnfaig wasts Dial is pnertted b> sny source Mibiect to paragraphs (c), (db fol or 00. of this section is teat am individually ncsi-enboduled am prohibited. Rteopt for temporary road Included, provided a number of such oiM ways 0C an area of asbestos oro deposits. erattona can bo predicted to occur during The deposition of asbestos teuton er as- 141iO AppUubUKy. The provisions of this suhpart are appUcablo to those sources epociflsd in. IU23. a given periodof timebooed on operating best---containing waste on roadways experience. covered with mow or loo is considered (o) "Emergency renovation" means a "surfacing." -' r--lovatioa operation that results from a (e) Manufacturing: There shall be no udden, unexpected event, and is not a visible emissions to the outadde air, ex | <131 Defialltau. planned reaovatkn. Operations necessi cept as provided in paragraph (f> of this Terms used In this subpart are defined in the act. In sUbpart A of thu part, ox in this section as follows: <*) 'Asbestos'' means actlnoUte, amo- elte, anthophylllte, chrysotlle. eroddollte, tremollte. _ __________ _________ ' tb) "~gAibestos material" means as bestos or any material containing as bestos. (c) `'Particulate asbestos material'* means finely divided parted-- of asbestos materlaL <d) uAsbestos taUlnaa" * any solid waste product of asbestos taming or pinnae operations which contains as bestos. <e> "Outside air" " the air out side buildings stiucture*. % ip "Visible mbdeef any emission* which are visually detectable without the aidof Instruments and which parttaSate asbestos materlaL tated by non-routine failures of equlp- section, from any of Ike following op uwt qr included. erations if they use <yntnomui asb--tea <p> **Adequately wetted" mean* suf or from any straotoxo ta ficiently mixed or coated with water or which such operations are conducted. an aqueous solution to prevent dust (40 FR 41292. October 14. 1975j cmlirions. (a) "Removing" means taking out friable asbestos materials used on any tit The manufacture of dotii eon.' wicks, tubing, tape, twine, rope, thread, pipe, duet; boner, tank, reactor, tur bine, furnace, or structural member from any building, structure, facility, or installation. (r) "Stripping" mean* toting off fri able asbestos materials from any pipe, duet, boflar, tank, reactor, turbine, fur nace. or structural member. jPu^np^lVg sod (r) Kviied by 43 FR 26373, yarn, roving, lap. or ether textile ma terials. , <a> The manufacture of can--it prod ucts. (3) The manufacture of fireproofing mih <bihub| materials. (4) The manufacture of friction products. ' <$> The manufacture of paper, millboard, and felt- <e> The manufacture of floor til*. (a) "Pabrlcating'Mneaxu any prose-- (7> The manufacture of points, coat tag of a manufactured product contain ings, caulks, adhesives, weuants. ing oommerdal asbestos, with tbs ex <8) The manufacture of pi--tw and ception of rriKie--Ing at temporary sites rubber materials. ' '(g) '"Asbestos mil" means any laeUtty for tea oonstvoeUen or restoration of (9) Tim manufacture of chlorine. engaged In the conversion or any Inter* buildings. aUuutuns, fatuities or Instal- <io) The manufacture of shotgun mediate stepm the souvisionof asbestos on into umuueiTlel asbestos. Outside storage of asbestos materials is not con sidered a part of ruch faculty. <fc> "Inactive waste disposal site" means any disposal stte or portion thereof where additions! asbestos con shells. <XI) The manufacture of asphalt con crete. (h) "Coanaarcial asboatos" moans any taining waste mstoriai will not be depos- . (d) DtmcAUio* and renovation. The variety of asbestos which Is produced by tied' and where the surface Is net dls- requirements of this paragraph shall extracting asbestos from asbestos ore. tonbed by vehicular traffic. appte to any owner or operator of a ' (I) "Manufacturing" means the com <u) "Active waste disposal site" means demolition or renovation operation bining of commercial asboatos, or In the any dlmosal site ether than an Inactive who Intends to demolish any Institu case of woven friction products the com site. tional. oommerdal, or Industrial build bining of textiles --commercial (v) "Roadways" means surfaces on ing (Including apartment buildings asbestos, with any other material(s), m- which motor vehicles travel including. having more than four dwelling units), Environment Reporter (fee. <1.22(4)] 42 AP00004510 HAZARDOUS BMISSIONS S-412 121:0473 operator of a source subject to the stand (c) Sludge shall be sampled according shall be retained at the source and made ard ini 6i.S2<b) shin testemissions from to paragraph <c) (1) of this section, available, for Inspection by the Admin that source. Such tests shall be conducted sludge charging rate for the plant *haii istrator, for a wiiwimmw of 2 yearn. la accordance with the procedures set forth either In paraczmph (d) of this section or In i tlit. be determined according to paragraph (c)(2) of this section, and the sledge analysis shall be performed according to (Sec. 114 of the Qeu Air Act ss amended (42 U.S.C.7414)) (2) Method 101 In appendix B to this paragraph (c> <3) of this section. part shall be used to test t<--** as (1) The sludge H*n be sampled after 8 61.53 Eratoion Rtenltering* follows: <i) The test shall be performed withfci 90 days of the effective date of these regulations in the ceee of an existing source or a new source which has an Initial startup date preceding the effec tive date. <U) The test shall be performed within 90 days of startup in the ease of a new source which did sot have an initial startup date preceding the effective date. (3) The Administrator shall be noti fied at least 30 days prior to an emission test, so that he mar at his option observe dewatering and before incineration at drying, at a location that provides a representative sample of the sludge that is charged to the incinerator or dryer. Bight consecutive grab samples shall be obtained at intervals of between 45 and 60 minutes and thoroughly mixed Into one sample. Bach of the eight grab sam ples shall have a volume of at least 290 ml but not more than 400 mL A total of three composite sample* shall be ob tained within an operating period of 24 hours. When the 24-hour operating pe riod is not continuous, the tote! sam (a) Wastewater treatment plantsludge incineration and drying plants. AH such sources for which mercury emissions ex ceed 1600 g/'dey, demonstrated either by stack sampling according to 141.53 o? sludge sampling according to 16144, shall monitor mercury emissions at inter vals of at least one* per year by use of Method 105 of Appendix B, or the proce dures specified in I 41.84(e) and <d). H results of monitoring shall be reported and retained according to 161.63(d) <6> and (6), or * ' *4(1) and (g). the teat (4) Samples shall be taken over such a period or periods as are necessary to dstermlne accurately the emissions which will occur in a 24-hour pling period shall not exceed 12 hours after the first grab sample is obtained. Samples *h*ii not be exposed to any con dition that may result in mercury con (See. 114 of the Qcsa Air Act as amended (42 U.S.C.7414)) SubpaitF1 Nation** Emission Standee# period. No changes shall be made in the tamination or loss. operation which would potentially in (2> The maximum 24-hour period crease emissions above the level deter sludge incineration or drying rate shall ftr Vinyl CMortdi (4! PR 46339, October 21. 1976) mined by the most recent stack test, un be determined by use of a flow rate meas S 61.60 Applicability. til the new emission level has been esti mated by calculation and the results re ported to the Administrator. urement device that can measure the mass rate of sludge charged to the in cinerator or dryer with an accuracy of (a) This subpart applies to plants whichproduce (Si All samples shall be analysed, and mb percent over its operating range. < l) Wpiws dMileridt by reaction of mercury amissions shall be determined Other methods of measuring sludge mass oxygen and hydrogen chloride with within 30 days after the stack test. Each charging rates may be used if they have ethylene, determination shell be reported to the Administrator by a registered letter dis patched before the close of the next busi ness day following such determination. (0) Beeords of emission test results and other data needed to determine total emissions shall be retained at the source and shall be made available, for Inspec tion by the Administrator, for a mum of 3 yean. (Sec. 114 of the Clean Air Act a amended (42 U.S.C 7414)) g 61,54 Sludge sampling. received prior approval by the Adminis (2) Vinyk chloride by any process, trator. and/or (a) The handling, preparation, and <3) One or more polymeia containing* analysis of sludge samples shall be ac an* fnetimtof polymerised- vinyl chi* complished according to Method 10S in ride* ------ - Appendix B of this part. -^*<b) This subpart does nor~aopisi to (d> Tlie mercury emission* shall be f equipment used la research and develop- | determined by use of the following ment If the reactor used, to polymerize I equation: the vinyl chloride processed in the equip- \ where g*-i x io- cQ ment ha* eanajdtgflafr'diP aiere thaw \ C9c ,----*-SMMleuorrddcecuruy*rryycshceoaomlirndgiscsinseigbnoantrrssaai,sttei,go,-no'kdggoay/'fdt.aai(yup.dpgm* )t,aill1:\\p"$n<~6odr1t)c;.a)89p11pS;.l6ey7ct;t6oio16ne.16sq.46a6oip;fm(Satelh.)Sa(is1tS)u;,ss6ue1db.(7pbin0a>;r.traenosd(etoha6)er,1cr.h7t1aahnnadddno (a) As an alternative means for demonstrating compliance with 161.92 (b>, an owner or operator may. usa Method 108 of Appendix B and the proce dures specified in this section. (1) A sludge test shall be conducted (e> Mo changes in the operation of a 1 development if the reactor used to po- \ plant shall be made after a sludge test I Iymerlze the vinyl chloride processed in \ baa been conducted which would poten | the equipment has a capacity of greater l tially increase emissions above the level I .tfNtatftlMRtMftBll.aad no more tharf \ determined by the most recent sludge (jtJtjafcUMrgaift* ____ 1 task until the new emission level has (42 Fit 29006. Jane 7, 1977) within 90 days of the effective date of these regulations In the case of an exist ing source or a new source which has an initial startup date preceding the effec tive date; or (21 A sludge test shall be conducted within 90 days of startup in the ease of a new source which did not have an Initial startup date presiding the affective data. been estimated by calculation sued the results reported to the Administrator. <f> All sludge samples shah be ana lysed for mercury content within 30 days after the sludge sample is collected. Bach determination shall be reported to the Administrator by a registered letter dis patched before the close of the next bull osa day following such determination. Terms used in this subpart are defined in the Act, in subpart A of this part, or in this action as follow*: (a) "Sthylene dichlorlde plant" in- dudes any plant which produces ethyl ene dichlorlde by reaction of oxygen and hydrogen chloride with ethylene. <b) "Vinyl chloride plant" Include* (b> The AdministratorShall be notified (g) Records of sludge sampling, charg any plant which produces vinyl chloride atleast 30 days prior to a sludge sampling ing rata determination and other data by any process. test, so that he may at his option observe needed to determine mercury content coy "Pcigvinytchloride ptaatrmrlmwy the test of wastewater treatment plant sludges MqLRiea^yheu jftot cMoridd atear or* 8-1476 [Sec. 6141(e)) Published by THE BUREAU OF NATIONAL AFFAIRS, INC., WASHINGTON, D.C 20037 M AP0000451f 121:0474 FEDERAL REGULATIONS ' la combtnatton with ether materials is polymerised Into polyvinyl chloride, the product determined tog a dry aoUds Motymsrtae^ err "Rsaetag opening tear;jwss ns the djarif. This requirement applies to day <d) "Blip gauge" means a gauge which necuxring veasel which is used as a reactor or as has a probe that moves through the gas/ liquid Interlace in a storage or transfer vessel end Indlcsatet the level of vinyl iwmaiMos- both a reactor and a stripper. In the : far w sMyy_dftp^thon ta bulk process, the product means the grass product of prepolymerisation and chloride la the vessel by the physical '*!)*(a>. postpolymerisation. state of the material the gauge die* charges. <e) "Type of resin" means the broad classification of realn referring to the basic manufacturing process for produc ing that mam. Including, but not limited to, the suspension, dispersion, latex, bulk, and solution prooeeses. (f)"Grade of resin" means the sub division of resin filaaalflratlon which de scribee it as a unique resin, ie., the most exact description of a resin with no fur ther subdivision. <g> "Dispersion main" miens a resin manufactured in such away as to form fluid dispersions when dispersed In a plasticiser or plastlcizer/diluent mix tures. (h> "Latex resin" means a restn which (*) "Stripper" includes any vessel in which residual vinyl ehlorlde Is moved from polyvinyl chloride main, except bulk resin, in the slurry form by tbs use of heat and/or vacuum. In the cast <4 bulk resin, stripper includes any vessel which is used to remove residual vinyl chloride from polyvinyl ehlorlde resin immediately following the polymeriza tion step in the plantprocess fiov. (t> "Standard temperature" means a temperature of 80* C'ftfi* F>. (u) "Standard pressure" means a pressure of 760 mm of Sg (90.03 In. of Hg). [42 PR 2M06, June 7, 1077] 1 61.63 Emission standard for ethylm* dichloride plants. (3> ilanusl vent valve discharge: Ex cept for an emergency manual vent valve discharge, there Is te ba.no dteeter-- to WMBIMVINB'MfMW MDt --toe -- "-r"ir ~r T~irl-- iiisin i --"--deride capha An emergency manual vent valve discharge means a discharge to the atmosphere which could not have been avoided by taking meas ures to prevent the discharge. Within ID Ja--dt--itoiBlMric --tow atmaapliere %-- any mowed vent vat--, tow'panel WwpmtoTjgf^'teunBa from w--tote pub--ittptheAdtednnnrror a--twrite writing oomatnHtoftoeftumatton tfe te-- oounoe. unk f&d caw-- of tore dteeharga.-'toM date and fttie bftfafi dtoeharpe, tho-appreximate Hfcfl jfmyl chloride lorn during the die- is produced by a polymerisation process (43 FR N00S. June 7, 1977] which initiates from free radical catalyst sites and is sold undried. (a> Ethylene diehlortde purification: U> "Bulk resin' 'means a resin which The concentration of vinyl chloride m is produced by a polymerisation process all exhaust gases discharged to the at in which no water is used. mosphere from any equipment used m <}) "Jnproeess wastewater" means any ethylene dichloride purification to not water which, during manufacturing or to exceed 10 ppm, except as provided In processing, comes into direct contact 161.65(a). This requirement does not with vinyl chloride or polyvinyl chloride apply toequipment that has ben opened, or results from the production or use of is out of operation, and met the require any raw material, intermediate product, ment la 111.65(b) <6) (i) before being finished product, by-product, or waste opened. product containing vinyl chloride or polyvinyl chloride but which hs not bean discharged to a wastewater treat ment process or discharged untreated as wastewater. 'k) "Wastewater treatment process" any process which modifies (b> Oxychlorination reactor: Except as provided tn i 61.65(a), emissions of vinyl chloride to the atmosphere from each oxychlorination reactor sue not to exceed 0.3 g/kg (0.0003 tt>/B of the 100 percent ethylene dichloride produet from the QWBhiorlBtUon process. characteristics such as BOD, COD, TBS. and pH. usually for the purpose of meet 161.(VS EihV-Ior Hwndard* for vinyl ing effluent guidelines and standards; It chloride plant*. does not include any process the purpose of which is to remove vinyl chloride from water to meet ' requirements of this subpart. (It `-in vinyl ehlorlde service" means that a piece of equipment contains or contact* either a liquid that Is at least 10 percent by weight vinyl chloride or a - gas that is at least 10 percent by volume vinyl chloride. <m> "Standard operating procedure" means a formal written procedure offi cially adopted fay the plant owner or operator and available on a routine basis to those persons responsible for carrying An owner or operator of a vinyl chlo ride plant shall comply with the require ments of this section and 141.05. (a> Vinyl chloride formation and puri fication: The concentration of vinyl chloride in all exhaust gases discharged to the atmosphere from any equipment used in vinyl chloride formation and/or purification Is not to exceed 10 ppm, ex cept as provided In 161.65(a). This re quirement does not apply to equipment that has been opened, is out of operation, and met the requirement in 101.63(to' (Oiji before being opened. out the procedure. AAifta niiriey-tggKarfcw oajitown <n> "Run" means the not period of ` *tldsiHl gteftto. time during which an emission sample is collected. An owner or operator of a polyvinyl chloride plant shall comply with the re <o> "Ethylene dlchloride purification" quirements <4 this section and 161.66. Alette, the method used for determining to--vinyl- chloride tees, tew action that # tehecaa suiteat the discharge, and mteMrastetopwg-- proven* future diaAterges. --(-TrlPbufr The concentration of vlflpr chloride in all exhaust gases dis charged to tote atmosphere from each stripper is tobf te 1--1-16 ppm, except as provided in fll.65(a). This require ment does not apply to equipment that has been opened, is out of operation, and met the requirement In I Ol.escb* (6) U> before being opened. <c> tieixlha. tootghlctrfihd holding --ewamete: The concentration of vinyl chloride m all exhaust gases discharged to the atmosphere from each mixing, weighing, or *hmh(wT container In vinyl chloride service which preoedee the stripper lor the reactor if the plant han no stripper) in the plant process flow is teat to exceed 10 pen. except as provided m i BI.65(a>. This requirement does not apply to equipment that has been opened, is out of operation, and met the requirement In 9 61.65(b> (6 (l> before bring opened. rid* MoaorndMooteerr afratem. Tlw concentration of vinyl chloride in all ex haust gases discharged to the atmos phere from each monomer recovery sys tem is Hot to qneeedTD ppm, except as provided In I 6l.4S(a>, This requirement does not apply to equipment that has been opened, is out of operation, and met the requirement In I6148(b><c>(ii be fore bring opened. -- itojuuu fonowtMi4lptaal0per<s>: The tallowing requirements apply to emissions of vinyl chloride to the at mosphere 6bu -ritetea--netion of at) te--loto--ing.^jp stripperit* tor the Includes any part of the process of ethyl ene dtehWide production which follows thylone dlchloride formation and in which finished ethylene dichloride it produced. 49ri Heartsr: The foilowing require ments apply to reactors: Hi The concentration of vinyl Ohio- rtfeln all todmaflfwas--Etoeharited bo tote temosphert from each reactor to not reaetor(s) if the plant has no strip per(a)} in the Plant process flow in cluding but not limited to, centrifuges, concentrators, bland tanks, filters, dry ers. oonveyer air discharges, bagger*, <pt "Vinyl chloride purifiestioc" In -Wo exceed tt ppm, except as provided in storage containers, and inproeess waste- cludes any part of the process of vinyl paragraph <aU2< of this section and water: chloride production which follows vinyl tei.6S(a'. JR) in pnljriuyt chloride plants --tag chloride formation and In which finished <2> ThefeaetaropeningIom from each stripping technology te control vinyl vinyl ehlorlde Is produced. reactor is not to exceed &92 g vinyl Chloride millions, the writhurt average iqi "Reactor" Includes any vessel in jttloride'Kg (6.00002 ft vinyl chloride/ rtelrtml vinyl cblnrida ooneentration in which vinyl ehlorlde Is partially or totally Hb< -of potrriayl rtetrririv product, with tel grades to potnttnyl chloride serin Envi'enmeftt Repe'ter (See. 6lA4(eim] w AP00004512 HAZARDOUS EMISSIONS 121 88 system from which the concentration of concentration of vinyl chloride in the vinyl chloride in the eitiamb gasea deeiA exhaust gases does not exceed IQ pop: noASBeeadltiimto er equivalent as pro or equivalent as provided in I 91.99. vided in 91.69. (3) ingem*; Thirty or un loading operations, the vinyl chloride (U> 48ftpgnB for an other polyvinyl emissions from each slip gauge in vinyl chloride resins, including MlKJMMi chloride service are to be minimised by averaged sepeintely for each type of res ducting any vinyl chloride discharged in; or from the slip gauge through a control (3> Zn polyvinyl chloride p*--con system from which the concentration of trolling vinyl chloride emission* Uh vinyl chloride in tha exhaust casts does Uehfidlficy Rthir thift ijfailiRR or to addition to stripping* ot YtnjI chloride to o** stnsodiin nay oot exceed; set exceed Ifragflif er equivalent as pro vided in 191.9*. <s> isttmi from pmamhseMgossdtt! ail --itiWatoi: thsr* finStjif tor1'roaetor(a) if the ti) Rotating pumps: Vinyl chloride emissions from seals on all rotating plant hex no sCripptrfe) 1 for dfcpenaqRj pumps in vinyl chloride service are to be petyvtoyfMM mat excluding latex mlnimiied by fnztalUng saallaaa oomia resins, with tho preduet determined on a pumps with double mechanical seals, or dry solids haste: equivalent aa provided in < 61.96. If <u> o.r g/tkiijf&rm/m*' priduet freak tfe* WlMps lor reaotor(s> if the plant has so strlpper(e) ] for aft otter polyvinyl oblorlde resins, including Istrir ruins, with the product determined on ediyaoUdeta*.* <6L61t T lull* rse Indfar ****< double mechanical seals arc used, vinyl chloride emission from the seals are to be by maintaining the pres sure between the two seals so that any leak that occurs is into the pump: by ducting any vinyl chloride between the two seals through a control system from which the concentration of vinyl chlo ride in the exhaust gases does not ex ceed Id ppaif or equivalent as provided An owner or operator at an ethylene in 191.96. dlchlortde, vinyl chloride, and/or poly* ill) Reciprocating piauM: Vinyl chlo vinyl chloride plant shall comply with ride emissions from seals on all recipro the requirements of this section. cating pumps in vinyl chloride servlet ra> RoUefraltte <flsd&ar<b: Except for are to be minimized by installing double an emergency relief discharge, there is outboard seals, or equivalent as provldsd <vk Agitato*: Vinyl chloride emissions from seals on all agitators In vinyl chlo ride service are to be minimised by in stalling agitators with double mechani cal seals, or equivalent as provided in 191.99. If double mechanical seals are used, vinyl chloride emissions from the seals are to be minimized by maintaining the pressure between the two seals so that any leak that occurs Is into the agi tated vessel; by ducting any vinyl chlo ride between the two seals through a control system from which the concen tration of vinyl chloride in the exhaust gases does not exceed 16 ppauor equiva lentas provided in f 91.99. (9) leakage from nUeC valve# Vinyl chloride emissions due to leekage from each relief valve on equipment lu vinyl chloride service are to be minimised by installing a rupture disk between the equipment and the relief valve, by con necting the relief valve discharge to a process line or recovery system, or equiv alent ae provided in 191.69, :m 5> Manual venting of gases: Except as provided in 191.64(a) <3>. all gases which are manually vented from equip ment in vinyl chloride service are td be ducted through a control system from which the concentration of vinyl chloride In the exhaust gases does not exceed 19) ppmxor equivalent as provided in i 91.69. <6j Opening of equipment: .Vinyl chloride emissions from opening of to be no drie&mgftto the atmosphere in 161.99. If double outboard seals are equipment (including inaHtng or unload from any relief valve on any equipment used, vinyl chloride emissions from the in vinyl chloride service. An emergency Are to be ii<wimi by wim-i-j-y relief discharge means a discharge which could not have been avoided by taring measures prevent the dtoefcarse. WO* In ie days of any mUM sntHi dNchargg, the' pressure between the two seals so that any leak that occurs is into the pump; by ducting any vinyl chloride be the oDttbr toriratos ot tha court* iron# tween the two seals through a control wtueh the mried vaF*'drie*r*"fla*ug*y system from which tha concentration or shaftatoatokto triw'Ada^lstsatoFAStos vinyl chloride in the exhaust gases does port firwrfttvbliMuadnft tnfbriMami not exceed 19 gam: or equivalent as on the souree, nature and cause of the provldsdlnl 91.967 discharge, the date and time of the dis till) Hean^t*.- mmgestorf: Vinyl charge, the approximate total vinyl chlo chloride emUnions Grom seals on all ro ride loss during the discharge, the meth tating compressors In vinyl chloride od used for determining the vinyl chlo service are to be minimi--a by in*aiung ride loss, the action that was taken to compressors with double mechanical prevent the. discharge, and measure* seals, or equivalent as provided In 191.96. adopted to prevent future discharges, Xf doublemechanical seals are used, vinyl ib) Fugitive emission sources: chloride emissions from the seals are to (1) Loading and unloading Unas: be minimised by t* pres Vinyl chloride anlahoi from *'**" sure between the two seals so that any and unaa m vinyl chloride leak that occurs is into the compresaor; service which are opened to die atmos by ducting any vinyl chloride between phere after each loading erunloading op the two teals through a control system eration are to be *1--1* ae follows; from which the concentration of vinyl (If FR ISMS, Jus 7, 1977] chloride in the exhaust gases does not exceod JBftMtoor equivalent as provided ing lines that are not opened to the at mosphere after each loading or unload ing operation) are to be minimized as follows: il> Begun upilng any equipment for any reason, the quantity of vinyl chlo ride is to be Hdnf so that the equip ment do dsn thaa u peroent by votamevinyl chloride m 6.9606 m* (36, gaiy oCV'riawb. chloride, whichever 1** laiym'dt standard temperature and pressure: and iii) Any rinyr*iTitorirto removed from the equipment in accordance with pare- graph-(b><6Xi) of this section is to be ducted through a control system from which the concentration of vinyl chlo ride in the exhaust gases does not exceed Eftitom, or equivalent as provided in f 91A6T ifEidKPA Unused portion* of sam ples cosueBring at least 19 paresatTbjw weighs- ring* ihbrrktepre to be returned is Uw process, knd sampling techniques are to be such that sample containers in vinyl chloride service are purged into n <i> After each _______ __ in f 91.99. operation and btost* apgnMff A ' erunloadBriBJMi to the atmosphere, the quantity of vinyl chloride in an parts id each loading or line that are to be opened to the atmosphere is to be reduced so that the parts combined con chloride emissions from seals on all re ciprocating compressors in vinyl chloride service are to be minimized by Installing double outboard seals, or equivalent as provided in 191.99. Xf double outboard MUnyb-ihlnsy^e snileiinm due to Stoke. Jiffim, squipmenl.Ia vinyldtioride aaeviee air# tw.tSiHniwbed- by Instituting and . implementing.s farmarxeak: dsteetfem and elimination program* Hwownerof operator abaft- submit a daecription at tain no greater than iWgni`(CvM seels are used, vinyl chloride emissions MMageeDraetoimtim. Adminlstratoe fee of vinyl chloride, at standard tempera from the seals are to be minimised by maintaining the pressure between the attBimOmK&Luwaaitsf.iTInh-4m5 e<isJsahotlot-Mfch* ebfDfecstuivBe- <U> AtoMra5ri3ft35ifiB from two seals so that any leak that occurs is -aatoafcTTiaearsgiilettans; mdses a waitor a loading or unloading line in accord into the compressor: by ducting any ad congil ixaJS granted anrtm I9IJX ance with paragraph- ib>*i) <l> of this vinyl chloride between the two seals If waiver edeempUance ie granted, the faction Is to be ducted through a control through a control system from which the program to. tot be.submitted cc* tt datW 6-18-78 (Sw 91.9S(sK9U Published by THE BUREAU OF NATIONAL AFFAIRS, INC.. WASHINGTON. O.C. 20037 er AP00004513 121:0476 FEDERAL REGULATIONS scheduled tor the Administrator. Ap tori fit swili ini wmi approve use of equipment or procedures proval of a program will be granted toy Mum ji*ntraIw. * atua s leak * ** which have been demonstrated to his the Administrator provided he finds: lt Includes mratisbieaad accurate' wteoA chloride monitormg system far at- hfc'JvvuiSSptoblaeto ttctlsnel major leaks and MenttfieettaB' dhe'bactgv___________ _ satisfaction to be equivalent to terms of reducing vinyl chloride emissions to the !Smm atmosphere to those prescribed lor com the general arm of theptam ofacra m' tolortde tototo-toatototos *m***m** * pliance with a specific paragraph of this 4(nk Is located. Avinyl chlmtoewwnitor- subpart. For an existing source, any re eii wsuni maim m Stovtae wtooa ototato quest for using an equivalent method as tr samples vem ana or morepetott on - -- itotoe the initial measure of control Is to be M eenttnomaf osmueiaf bteB end aati- submitted to the Administrator within Vyiis the mmifim ertoh vs tfhtvenetng- 39 days of ttaa affective date. For a new ngOWMito --nai iy source, any request for using an equiva earnas ttana all hydrocarbons cisasiaert lent method is to be submitted to the ora vinyl eblnide, with mfrpzedotdisC Administrator with the application for photometry flame too deicetoon, brj approval of construction or modification weutaalent or alternative method?' required by | 9147. i il >jfitoctnifca axsttofclwoid afetimto ntoHftolnetobsn rSbttoehr to find ride emissions to the atmespbora from 6jiil;l6toltoBlMto vtot tos major leaks tnproceas waatawatar are to be reduced (a) Unless a-waivsrf emission testing vmylchterfcle as fallows; is obtained under i 91.13, the owner, or portable hydmcectoen (i> Hie concentration of vinyl able- operator of a source to which this sub- ^device which meaeurea. hydieraikom*' ride In each inprocesa wwtoewasir tifauato Ppart applies shall test emissions from with a sensitivity -yt at-toastTM pp*n iMitotuTin tveatto-TStosei-m aa wtayt' the source. and to of each mingii sit rim ritH4i-can tmiwdtetely || |t <1) Within 90 days of the effective date tow used toMsuuaetooliihiiiilsid* leaves a piece of equipment and before to the case of an existing source or a -toed points. being mixed with any other inprocess new source which has an initial startup >iii) it pieeldseferdhtoieasptatoieBea- wastewater stream is to be Mriioafitoato date preceding the effective date, or hratten and natoUhaaobweliedule for more thenlgppmhf titoghtbifiei bekig (2) Within 90 days of startup in the thevinyl shluilii mountains system end deni TrlTli snj nther InrmnnM TToitrtrs case ef a new source. startup of portable fcydraceabea risteeter.Tor tow *Vimrt chloride moottoriad amam. nifttily ^apan dwet la. to he canducted with a ^cwioentration of vinyl- chlorine nqnal to Che concentration defined asto-leek m- tor earearn which contains leu than 10 ppm vinyl chloride; before being exposed to the atmosphere, before being dis charged to a wastewater treatment proc ess: or before being discharged untreated as a wastewater. Thi* paragraph Raise which occurs after the affective date. <b> The owner or operator shall pro vide the Administrator at least 89 days prior notice of an emission test to afford the Administrator the opportunity to have an observer present during the test. eording loesmmih'tMtoKvto of this fibffiy tomaaer wafidhtoattod to fitspiaee section. Ibe catibrattcri- to to be dene totoyi eblertoe-JremwQBipascnt before * vt%)**!fe5B!ibmtton iu mixture pre jto opeMfi'to tou atomspham to nemsdemi Hh tn44<siii tor. paragraph pend from the gases specified to sections (*) oftola aeottoautori Raw not apply 5.2.1 and SIJ of Ttost Method 106 and saa water whtoMeuoad to wash out equlp- in aoeordaaoa with section 7.1 of Test ment after .tha equipment has abaady Me(Bth>oda10e6s.OoUr mtion gaa oy.itotdm stand toeen epehed to''the efenospbsra to Oetoerdance vMi retMtsMp or para ard containing the appropriate concen graph ib> (f) of this section. tration of vinyl ehloride. The gas earn- <li* Any vinyl chloride removed from position of the calibration gas cylinder the toproeeas wastewater in aeoordaacc standard is to have been certified by the with paragraph (b) (9) U) of this section manufacturer. Tbs manufacturer most Is to be ducted through a control system have recommended a maximum shelf life from which the concentration of vinyl for each cylinder so that the oonoentra- chloride to the exhaust gases does not don does not change greater than *5 exceed ttwpaa, or equivalent as provided percent from the certified value. The date to < 91.99. of gas -cylinder preparation, certified (c) The requirements to paragraphs vinyl chloride ooneentratlon and reoom- (bi(H. (b)(2). <b><9>, (b)(0), (b)(7) mended maximum shelf life must have and <b> (9) id this section arej$ be in been affixed to the cylinder before ship corporated into a MUnT' ojinuUni ment from the manufacturer to lha swtodiai anr mada available upon re buyer. If a gas chromatograph to need as the vinyl chloride monitoring eyetem. quest for inspection by the Admlnistratig. Pm etonrlerd opmaliug grceidme is these gas mixtures may be directly need AtetoeitoRrto'b'riefi-- tor mssnirtog fibs to prepare a chromatograph calibration totogt diifffi'linirtiliM totsidn* curve as described to section 7.8 of Teat . ijr^ew mm* Method 1M. The requirements to sec mmmsKm^piumtDt m^Lmmriwy (c> Any emission test is to be con ducted while tbs equipment being tested is operating at the maximum production rate at which the equipment will be op erated find under other relevant condi tions as may be specified by the Adminis trator based on representative perform ance of the source. <d> (Reserved) (e) When at all possible, each sample is to be analysed within 34 hours, but to no ease to excess of 73 hours of sample eoHecticm. Vinyl chloride emissions are to be determined within 30 days after the emission test. The owner or operator shall report the determinations to the Administrator by a registered,letter dis patched before the dose of the next busi ness day following the determination. [43 Fit UOOI, Juat 7. 1977) if) The owner or operator shall retain at the plant and make available, upon request, for inspection by the Adminis trator, for a minimum of 2 yean records of emission test results and other data BiaSsd to determine amissions. <g> Unless otherwise specified, the ojcw^nneroo*rtoopAeprpaetonrdisxnhsaaulltoustheistepsat rtTi efosrt tion 8,34.1 and 84.84 of Test Method 109 for certification of eyftoder stand (e fmresmndtotev^MiM mtogTori Method 199, a pdrtatoehydro- ards and for establishment and verifiestien of calibration standard* are to be followed. (42 FR 29005. June 7, I977| Tec 'ah equities*nu*l- ' The method of meas urement is to meet the requirements to I 91.97(g) (*))(A) or (g> ((8> (1) <B>. uvrvtoa loeatfciv miatofivto patoto , 141 FR 53017, December 3, 1976] each test as required by paarnaggraphs <g)u>, (g)(3). (xxs>, (g)(4), ai nd (g> <#> of this section, unless an equiva lent method or an alternative method has been approved by the Administrator. Xf the Administrator. finds reasonable grounds to dispute the results obtained by an equivalent or alternative method, top be laijiiltnisd toad totoufieiusvm 'ef he may require the use of a reference dtomltostog MwMriaff tor to the bragnm method. If the results of the reference >e aeisytabls when ttisy ate isaiiparaii Sth the naaanar of tomis nf equftxDSDt vtoyl cfclerUs eervto* end towtoss and utohyetoallayattoaf tow Meat. | 91.94 Eqaivalrul equipment and pro cedure*. Upon written application from an own er or operator, the Administrator may and equivalent or alternative methods do not agree, the results obtained by the reference method prevail, and the Ad ministrator may notify the owner or Environment Reporter [See. AP00004514 HAZARDOUS EMISSIONS S-412 131:0477 operator that approval of tbo mithad previously oonsldsrod to ho equivalent or alternative la withdrawn. < rmniywi dotormina thr* froo mm ltehlriim>aaNmi.W( or <b I *1.68(0), or || 4144(a) (1), (b>, (e>, or id). or from any control system to which reactor --<--!-- an remind to bo ducted In I ilMW 48) or to which fugi tive omlsoloas an required to bo ducted in |ti.cs(b>(i>(U>, (b)(9), (b)(5), (b> <*><U),cr<b><9> (U>. (1) Far eaeh run, one --la to bo collected. The sampling elte to to be at but two stack or duet lUsmtenrs downtream and one hall diameter upetream from any flow disturbance eueb u a bend, expansion. contraction, or vtelbte flame. Per a rectangular btoh section an equivalent dlameler la to be determined from the following eolation-. <v|iiivukut dtaiMtrr>t (length) (width) iength-hVkffli * The sampling point in the duet is to be at the centroid of the cross' The sample le to be extracted at a rate proportional to the gas Telocity at the sampling point, th# mpi u_ta he token a mlnfamf* at anm hB,.r r.H le ta wmtaln a minimum eoluine of so ittors wnraeton to The aovnerage Is to be . LweiaBtea easin (111) Foe gas atreamieentauung i than to percent oxygen the concontea tkm el vinyl chloride as detennlned by Tbit Method 1M la to be corrected to* 10 percent unseen <dxy bade) for ibbnuU nation of sttUssloru by uring the follow* .tag equation: Cn^to^-C1* 20.9--peioeni 6, 4-here: eoeeentratlon of vtoyi emoiida in theexhaust gum, corrected to KVpercrat oxygen. C*-Th nmstnuoe at vtnyTchloride as measured by Test Method 100. 80.9m Percent oxygen in the ambient air at stendeed soodltiona. 10.9MPereeat oxygen in the ambient air at standard condUtona, minus the 10.0-percent oxygen to which the correction it being made. Percent Oi^Pmoi xygew is the exhaust gu * measured by Refers enoe Method g tn Appendix A of Fart 04 of this chapter. (It) For thoee emlselan eonrooe where the wnimkn limit le preoevibed in tone of mass rather than eaneentrattan. maee emlwrlnrw in kg/100 kg produet are tn be determined by using tbo foQowtnf tqga* ttea: CacMkg vinyl ehloride/lOO kg prod* uct C#The eeneentratloa at vinyl chlo ride as measured by Teat Method 105. 8.54m Density of viayl chloride sc one atmosphere tad 2CP C In kg/m?. QmVolumetric flew rate ia m*/hr as determined by Reference Method 2 of Appendix A to Part 60 of this chapter. iO~*MCoavenloa factor for ppm. ZMj>rodaction rate (kg/hr). (48 PR 89005, Joat 7,1977} <9) Test Method 107 Is to be used to determine the concentration of vinyl chloride in each inprocese wastewater stream for which an "(--limit Is proacribed la 161.05(b) (6) U>. O) When) a stripping operation Is used to attain the emiuloa limit In f 61.64(e), omleston* sure tn bo determined using Test Method 107 as follows: (I) Tho number of stripporo and sam ples and the types and grades of resin to bo --M to bo determined by tho Administrator for each individual plant at tho time of the test based on tho plant's operation (II) SaOh sample Is to bs taken imme diately following the stripping operation. (III) Tho corresponding quantity of material processed by each stripper is to bo determined on a dry solids basis and by a method submitted to and approved by Alto,tnUtobm, <lv> At tho prior request of the Ad ministrator, the owner or operator shall provide duplicates of tho samples re quired in paragraph (g) (9> (1) of this section. (4) Where control technology other than <w in addition tn a stripping opera tion Is used to attain the emission limit in 101.04(e), emissions are to bo deter mined as follows; (1) Tset Method 100 le to be used to determine atmospheric emtmtons from all of tho proo-- equipment simultane ously. 17m requirements erf pangraph (g) (1) of this section arc to bo met. ^ (UV1^ Method!^to^ ehleridm m eeolt inpeaemn-wastewater stroafohiest tubeemission limitaooF serttoad togtofiteke The mass of vtnyi chloride Oi kg/100 kg product in oaeh in process wastewater stream lo to bo do* tcnnJned by using tho following equa tion: c JlEJZU2S51 rTw*; C*Cm',--Utmt veionuyel eMUtenrllidorn. tmwvltxuyrnl cdfeemd.tut u naunta) by TtoM*tou41W. R-wr flowate liil/w, MwadueS in twrerdsiwe lib SKiiwe vMith tot ton nbniHtc te SSeknoeeBan nta ifinr), ddawliwd tn amd. a. i1M1 `attrt--s--muud vfntref--k basbeenMJmSnid (5) Tho reactoropening loss far which an omleeion limit te prescribed In f sing (a)(S> te te be determined. The number of reactors fox which the determination is to be made le to be specified by tbo administrator for each individual plant at too tone of- tbo determination based on the plant's operation. For a reactor that te ateo used as a stripper, toe doterditnaticn may bo made immediately fol lowing the tertypteg- epsraMon, (1) Stoop* as provided in paragraph <5><6><h) of this section, too reactor opening loos te to bo determined using the following equation: W (2.54) (10-) (Ct) " YZ MU" Cm Is vlny1eMof4enMsei/kcproCiKl. r< aiuettyeitiwieactwinTal. wa- l)tndt)re^vlayllilMe at Uimipli*r itd CppsTihnirmrtcvflTw*iyttoitfavoantertaii^a_aitnwo_otd_mii*al_c.Mrvbtiaeii yMiluecrBMse.atvwpudulwddrmen*uMmbhClCirmMakrnvteniiurctalIMimibiCMeabBny Kwaiuciklpr*TMteuadlwttTtitayoeegC (atot mlenesut r1wAapi eliaK. ' Aiv-paariuitshec.uio-difntUtaoDetmtaoeMinMptdtmoaiAlioyMiavtoripnaatyo(tmlbraaea.tbaatbepafbCaaMafi*pt.cruotdWucrendcpiaarr (A) if Method 106 is used to deter mine the concentration at vinyl chloride <Cb>, tho sample Is to bo withdrawn at a constant rate with a probe of su&cient length to reach the vessel bottom from tbo manhole. Samples are to be taken for 5 minutes within 6 inches of the ves sel bottom, 5 minutes near the vessel center, aud 5 minutes near tho vessel top. <B) If a portable hydrocarbon detec tor te used to determine tho concentra tion of vinyl chloride (Cb). a probe of sufficient length to reach toe vessel bot tom from the manhole is to bo used to make the measurements. One measure ment will be made within 6 Inches of the veesel bottom, one near the vessel center tnd one near tho vessel top. Measuremenu are to be made at each location until the reading te stabilised. AO hydro carbons measured are to bo assumed to bo vinyl chloride. <C> The production rate of polyvinyl chloride (Z) te to bo determined by a method submitted te and approved by the Administrator. (ii> A eofttdaDBftbased OB too numbed^ ofhsiibIIiMB IlM ioi miniMvblved. tnd^ too vtotonoof ago ia thoyeagtow tehemtas atfmuod.&3t togAfinWrtrmtte axonal* temalted aaftoqg/or determining reac tor opening Tderzor pos(polymerization reactors in the manufacture of bulk resin*. (Sec. 114 erfth Ctesa Ak Act u amended <42 U&C. 7414)) iHitloo ' `SW'Afrtort- rtHBridg nwritoUng o tototegg qg we* to monitor own eowtf tonsaan-bari* tog emhsinng front- Use-' aoawoaamrwiueB main hmltearopi*-' eetoaffitoLtXJXd) and (b). i41.53(a), and i 61.64ia)(l), (b). (e>,and (d).and for any control system to which reactor ,mlsdna sic leqaiied to be ducted in 61.64(0 (2) or to which fugitive emhdoai ue required to bs ducted hi 61.65 (b) (1) gj.(ud (b) (2), (b) (5), (b) (|) (b), aad (b) (41 PR 33417. December 1,1976| b) TlMTfdyfeftforfdojnmdtmtagtyfI2nft|g moWto maoktha raqntnasnt to rtowgroftora^-od tom aoettoi te to into whkto etodrm nlr sompolr from ecir-'flit~ft(W-'pe(fito-ito w eenratowS eaqatoitelbesii aad analrsaothe sampto oroporow ateomsa iw*grMI hydrocarw bonr mubl'**~aio vtnyk ehteckto,..witb [8m aigflfb)] >178 PaMhhsd by THE BUREAU OF NATIONAL AFFAIRS, INC.. WASHINGTON, D.C. 20037 St AP000045I5 121:0478 FEDERAL REGULATIONS infrared' mimi naiinHiwiiyrtiatoo Iff <1) In the case ef a new source which in fit L63(n> e>Hb), | oiaks) . did not have an toHtsl startup dote pre art* 6L64<t)(&),<b)r<e),or (d>,erfer IhifWiWafMi --Hinr ceding the effective date, the statement any control ajst--i to which reactor tttoitMinaiitiBMtni iwnGraanti is to be submitted within 06 days ef the emhrien* are -quMty be ducted Ip < -taMLlK>(Da) BkHtdtaiii- initial startup date. f eiA4(a) (S> er a which fugitive mk- ' the roqubWMBto aftidsecetian. <o> The statement fc to oontato the Cons are required to be dupted In 161JO <e> A Saif tttiti AMOk-fs to be eon- followinff information: (b) (lXU), (b)(3), (b)(6), (b)(6)(ID, or ducked for each vinyle chloride monitor <1) A Uft of the equipment installed (b)(6) (ID. The emissions a--lobe meas- ing system used. war all ef the emitaion for compUanea, umd la aeeerdance with I tlAfi. sources listed In paragraph (a) o( this section, except the one for which aa emis sion limit Is ptemilbfd In I 61.f2(b), the dally --aa ehetir ts to-babendneted erttt -arsnnmtioh-- of vtoyl chloride *qhe) ( A deeeripttcn ef the physical and functional characteristics of each pises of equipment. <3) A fiasrilpiioo of the methods which have been incorporated into the <t> In polyvinyl chloride r*--ti for which a stripping eparathn le need te attain the omlalsnn level preaedbed in 5EWS5S aa l wan Wvt the --|tm source tor standard operating procedures for mens- the pelyilLul which an smtorton limit is prescribed in urtng or ealeulattac the ----*** for imhrtHjaiB..Tme-ireMinAfiWtttrvfteatoobe I 61.63<b), the daily span check Is tnbe which emission limits are prescribed in thed to determine vinyl chloride content conducted with a ccntenttatlon of vinyl 1161.66 (b> <DO) and (b)(6) <l). aafoUows: ehlorble vhldi la --termined to be (4> A eminent that each pieoe of equlnlaat to the emksioo toft for that equipment is Inetaned and that each net bend ee the emarine act tequfaed by 1,67. Tbs calibration k to be done whh piece ef equipment and each procedure la being used. ther: [41 FA 53017, December 3.1976) 4^g^Mr90WHMKVhti* fng the completion of the stripptaropcration. and identified by resin type and <!> A eellbratton gas ntrin pre- () ins owner or opetator ef any grade and the date and time the batch parad from the gates specified In tactions source to which title subpertappUe* shall la completed. The corresponding quan 6.3.1 and B-2-* of Teat Method 106 and submit to the Administrator on h0tm: tity of material processed in each strip In aoeotdanea with section 7.1 of Tsat 6fftiiWlflb*m(slATWir>nport per hatch la to be recorded and identi Method 106. or In writing oaitahting the Infcraaticn fied by resin type and grade and the (43 PR 31001, Jme T, 1077} (3) A caUfcrattcn aba cyttader stand ard poptaming the appropriate concen tration of vinyl chloride. The caa cosn- required by this section. The first cent>miii*i Murt k to be submitted riv--tag tbefirstfull 6 month--porting period after the inittalrepost la submitted. date and time the batch h completed. (42 FR 20006, Jme 7, 1077) poamoe of the calibration cat cylinder (41 PR 53017, December 3,1976) standard la to have been certified by the manufacturer, The manufacturer muat have a wmtmiim shelf life for each cylinder eo that the ooneec- tration does not chance greater than, 5 percent from the oertlfled value. The date of caa cylinderpreparation, oartifled vinyl chloride concentration and reeom- pnwiirf maximum shelf life must have been affixed to the cylinder bafoct ship ment men Che maaufaetuiw to the buyer. XI a fas chromatograph la used aa the vinyl chloride monitoring system, these gas mixtures may be directly used to Drapers a chromatograph calibration (bXl) Inthe ease ofanexisting seuree or a new source which hat aa tatttal startup date preceding the effective data, the first iawi Is to be submitted within 160 days of the effective date, wnlsm a waiver of oompUanot is granted under *6101. V a waiver ef scenfiRanee le granted, the first report is to be ah* nutted en a date scheduled by the Ad ministrator. <9> an the ease ef new eeuree which did net have an initial startup date pre ceding the effective date, the tint report la to be submitted within 166 days of the Initial startup date. wf.polyvinyl staga* 3 te fie he taken fee each prooseeed srAt t--reals eanh gmis tfihhqmA 6i beta*pn rtsi agent. The sample is to betaken as the reshi flowa out of tbs stripper and iden tified by resin type and grade and tbe date and time the sample was takas. Tbs eorraspondlng quantity of material pyaemia by each atripper ever tbe time pwiod i--isamtsii by the aamtfo during tiie eight hour period, Is to be recorded and identified by recta type and grade and tiie date and time it represent*. curve aa d--crlbed In section IS of Tost Method 100. The requirements tn see* tkms 6S4.1 and 3.34.1 ef Tsat Method 106 for certification of cylinder stand* ards and for establishment and verifica tion ef calibration standards are to be followed. (Sec. 114 ofthe Osm Ak Act as amended (42 U.S.C. 7414)) 43 FR 30006, Joaa T, 1077] <e) Truism otherwise --oefflod. the owner or operator shall use the Tsat Methods m Appendix B to this part to conduct omimton taste aa required by paragraphs (0(3) and (e)(3) ef this seotion, tmlaea an equivalent or an alter native method has been approved by the Administrator. If tits Administrator finds rosammin grounds to disputo the result* obtained by an equivalent or al ternative method, be amy require the use (Hi) Yhe quantife et mmtorfal procfitied by the stripper Is te be determined on a dry edm batia end by n method submitted to and approved by the Ad ministrator. <lv> At fibs peter nqawt of the Ad ministrator, the owner or operator ibeD provide thMttatoa of the samrtet re quired In paragraphs (e)(3) ti) and <c> (3) (tt) of this section. <a) an owner or' operator ef any source to which tide subpart-appbas shall .ih--ri g ststenint tn writing notifying of a raferenoe method, if the remits of the reference and equivalent er altemattve'metbods do not agree, the results obtained by the lefwwioe msrtinrt pre (v>4Bttp.ttnve to tiie Administrator by the owner or operatorriTtigInetude earn the Administrator that the equipment and procedural specifications in II Cl-66 (bXl), <bX3), <b><3>, <b>(4), <b><>. (b) <6>, (b) (7). and <b><fi> are belnc vail. and the Administrator may notify the owner or operator that approval ef the method previously oontodorod to be equivalent er alternative is' withdrawn. by pa--graphs (e)(3) -mm fitofifeh. aver aged separately for each type of resin, implemented. <b)(I> in the case Of aa existing KBbfnEjlSSftSaSr over each co1stdir day and weighted according to the quantity ef each grade source or a new source which has an Initial startup date rraraltnf the effeetire date, the statement la to be submit 0..BB6P .Kveugsa .over m of resin prac--sed by tha strlpper(i) 'S&2Z that calendar day, according to the fol lowing equation: ted within`06 days of the effective date, unleu a waiver of is granted under 161.11. along with the informa 2h-W>*s, P*M*,+P#,Mc,+ .. . +Pe.*, tion required tmdu f 61.16. If a waiver of rompHsiure Is panted, the statement Ar*m-------- ------------ " '"8r, h to be submitted on a date scheduled by the SilmlnletTsinr Environment Reporter [Isa 61.70W12M*)] to AP00004516 HAZARDOUS EMISSIONS 5412 121:047* tobem; AwathoT mnfi eoueeatrstloa of typa Tt ratoe la ppm (dir weight bufert. Q--Tolel produetioa at type f, rwln ovtt the 34*hoar period, in kg. 7\Type of neis; i-1,] . . . m where m it total number of mein typee produced daring the 24hour period. UCoeMQtntkn d vinyl chloride in one temple of grade <7* rata, in ppm. of each leak detected with tho poriablo hydrocarbon detector, the date and tlmo of the Mak, and say notion taken to eHmlnato than leek. (tt rn pm, Jam 7, itnj operating record fee bride rsseftf end tempwehires (tt FA 3M0I. Jobs 7. 1*7?) (tt fr mass, jms 7, uni (Sec. 114 of tba dam Alt Act as amsudsd (42 U.S.C. 7414) JMfttI A Mled Wtila Itoahifs Hr Sin Hie Air ailiMt toltu sutm lafcraattm !* Production of gride <7 reetn repraeented by the temple, in kg- Grade of rata; e*, 9y <7* end fj. Total nunoer of grades of rarin produced during the 24-hour period. ***** wt ISSTSUCTtDMI 0WIH w WWkUrt af. towns X kuariut stlUUiU mjaet te tt* KHIsmI Mufaa liMdrM Hr Hatartaat Air SaHuimts an famitraS ta mWl Ui lafMMtfea aaaUlaaS 1 Setie IUO wnriwiU. Cwtrwmatal PrstxtlM fwaer Am tow) flfflea kritr te ft Says after W< affscMM Sw sf ujr iuadHi or asseta*ru Mlel rmlN ua ueiwle tf twi tnr.futlet (41 Fit 19001, June 7, 1>77| A Hit af arrises is frt*14(4 ia H1.M. . <vt> Thn owner or operator shall re tain at the eouroe and make available for inmeetion hy thn Administrator for n mtafcmm of > poor* rsosnft of an data noednd to fundalr the information re quired by paragraph <c> <*) <v) of tfedo section: The reoords are to contain the <oUMdBf Information: (A) TtevhskotaMdooMtonMeuad tB on the ssmpUe required In paragrapha (e> (S) (1) end (c> (D Oi> of this section. Identified fey the reein type end grade end the time and date of the sample, end A. uMC linwaiiM 1. Taiir>cHwAot.tin . lastula tie ami u4 Mm if uct sswee* i *. ISjTc fC&i Imi,1 isandtor u**`*i> irti tr TSnT "IS ksUli W ir* Itfwt iii usutie h >mu A *i------------- srirsa------------- M ruft: <B> Tha corresponding. guiiitHy <4 potyvtayt BhlfVtc resin proocceed by tht atrtppor(s). ldentlfled fey the reein type and tllf Him wH ifala it represents. ( The owner or speeder shall in clude In tba report a record of theomh* tony from eoeh rnilrf igonlng ter* which am omhsfen Mari* ft muibwt hr* 1 ttA4(a> <*. Bmtaelone are to be deter mined in aeeordanoe with | i,7(g) (4), except that missions for e*h reeetoc ere tobe determined. For e reactor tootle 8# MS tnirtt y iji rtsBrP wt 1* tr 41 4 *M* tt4fe ri------------------------------------------- ft tkraJf <7--BetF--n ir also used as a stripper, tbs determination mar bo made Immediately following tho stripping operation. (Sec 114 of the Clem Ah Act as warned (42U.&C. 7414) i^W r lucfiptlsa SI.......... ....... CSati'iSf -------- '- J> ft is a lacaiiM Mritrsm tku tkat spulfise aim. (a> Tho ownm dr opsrator of any mures to which this safapart nppBos shall retain the following Infcciaatlon at the eouroe end mafce tt available (or tacpecRon fey the Administrator for hmsflt a>4l Hf Ml (1--t3afi^itfa*k V Ik AeUf------- ft W Sap MS si--~ city--"" a 'Tm? si n> n w s* fwalifact St|(iif - tka aafwfau I-- Ola *--- m ----t --a WBBBTSStttlw uataiaaS ia tta Sstiaul tSttituTEuSw* aa tr srlkf to SS aura after irfKtiN Sata C a-gp sii-Cam tr iaar.4au M(A fajilra to* uSalalM af a-U iatonadu, required by | gusto) (g). toriadlng tbs uontentretIsms of vinyl ohlorida as msssursd. aaalyasd. and racordsd fey the vinyl chloride detector, tbs location of each measurement and tba data and ap proximate Mm* of each **"*--*"rii a <a^Amosr*mto)safc*deteefe94W> ftmxammaarnnitortoywtaittiapetmSs hydsueaihcB item-- as*, thft nttM* toksm tw repsto'tftO'leokBj'aa isdMMt fey ! 61AUb) tt), tt^uding a brief state ment --phLimwy (he locatton and causa ir afaW. w-iw amitl Bll>, . amaaiau m tat du aauSa tnaia liaiii taf v m-invi aHaatos StaMrss far Huiraeu Air fallauau, tfcs iwu uU la la vtaiattu M SMJw*to rcsarkl wfarmmt isklwi utoas oHt.*S a uiaar af eawiiwra h vm MMsUtratar af tka U.S. tartiwanal fewtaetiaa *|iary TN tafaiauia* aaaSU far sack ufawa 1* littoS is SaeUu 1 af tfcls farm, I, fkBtcss Tk*OSWTiflw. P*rt Italt ka ewiinf laaKsta*/ far hS> plx af kEHMUMil4*alaNr.laRWlfSJT&MTWU k-UutMU (:** suhjack to 11.310) to mil (to Mi II-ft 1 iTTl SEMI Raf ir sis (AppsadtgAl ft17fl PutiUihad fey THE BUREAU OP NATIONAL AFFAIRS. INC. WASHINGTON, D.C 20037 AP00004517 1, Pollutant Enittad m Indicate tha typo f baxardm pollutant ewltted by the proem. indicate "M* for UMittii W for beryUlia, or "HQ" for Mrcury. 92 39 fiTISFant 31 "" Regulation ------------- a r EC 2. Process Description - Frovfda o brief description ef each rrocesi (a.g., Mrogw and Eoh1 te a nertwry chler-alkall plant. "grinding mchtaa* in a berylllM mcMm shop). IIm additional tkaoti if rm*i!M7. 60 process Description tip 1-18 1 15 a 21 nW 5b 51 Dtp Ml 52 ir^t 81 ------------- 79 8D 5b 51------------30 ! iwm m +mm vmimi vhmii nnv piw< previous twelve nonthi of operation). 75 IT Oup 1-18 83 15 a n---------------------- TT if w Control Devices T, indicate the typa of pellutfen control devices. If any. asad to reduce tha emissions mi tha proents (e.f. vontnrl scrubber, btQhewe, not cyclone) and tiw estlnated percent ef the-pollutant which the device runouts fron the process pas strtm. 9UP 1-18 8 8, 15--2b 21 PMimr CORTWL DEVICES --O an rrtanry Rfice nun 88 70 n Percent fteaevai fl n 0 to Mi c s IT 20 SEcomur comm. devices: 21--------------------------------------------------------------- f | v secondary Devtce'lUe t erne. 64 88 ID r 7b Percent Renewal Efficiency b. Asbestos Emission Central levlcet Only I. If e baghout* Is specified In Itea 4a, give tha following InforMtlon: w Tha air flow permabllity In cwMc feet per nfnute per sdaara foot of fifirlc area. Mr flew Mmeebfllty ________ ea/ft2 The pressere drop In Inches water gawge ecnjjs the filter at tdileh the baglwn* is operated. Operating grosser* drop Inches w.g. If the bsghouse mterlal contains synthetic fill yum, cheek whether this Mterlal Is / / span / / or not spun. If tha beghousa wtlllzes a fatted fabric, give the utataM thickness In Inches and tha density In oances per square yard. Thickness -laches Density ____________________/jd* II. If a wat collection device is specified In Itan 4a, give the designed unit contacting energy la Inches water gauge. Ualt contacting energy -inches u.g. C. lISfOSAL Of ASDESTOS-cowramnc HASTES. Part C should be toileted separately for each asbestos-containing waste geSeratlan operation arising fro* sources Mdijact ts 161.22(a). (<), (e), and (h). *'-u w-n 00 17--n 5 15 Tf ITS 15 ST HEDSXIar CS SIP A I,A Pollutant Negumtan 4b 15 EC FEDERAL REGULATIONS AP00004518 i AP00004519 1 thsto hwwrtw - PcovMa a ftrtef Voscriptfoa f each proem tint generates asdofcwtatnlin w>t lltpoaal of control MeUKtu). sr 2. mcooa mcrlptiw' T - Mad Up average Darerttigt asbestos content 1^Ja tl wmiHiwMn*. p 4S____ , sJ ar 3, /Uowt of tales - Irttcato Wo norm wtoht of aatatrtconUla1ns wastes aiipMM lit WHVK fa M/rtf* Dip Ml 27 I, Cnatml Hrtho* . Jrtlcata tfca ortsslon control nethrts usrt fn *11 stages or waste otspoiau fna aHactlaa* processing* art packaging to transporting art rtposltlat. Prtopiy Control Hathad IT TJ ----------------------- Dap 1-1S < O 2T ST "75 8 *. tat#)* Dug 1-11 <5 lI"Tb XT vr TVfg y SITE: S3 35 -- W TO NMI U_<2b H" Brtl-W ,IfIT 20 sr YT *-**** sr LWATWIfc AT TP 1. rtSTE disposal SITES. Port I staid bo cenpletrt HparsUV fr each estate! waste Olfpotal lit* subject to Mrtlw SKn(1). pup M3 00 S it--re 17--ft it ar tbt 2f r sr 7T NCOS X Hof C$ SIP s*' SC hfoUtlon Pollutant If fC haste msposal site -a BET 1* 0*scHot<i . provide brief tacHptton of tbo site, fneloAog tta slxo conflgiratlea.-art trt distance to wo closest dtp or tom* ctooott residence^ art closest prtnefy sort. PPM* i5Ua _______ SITEDBCilWlOW t sr ----------------------- sr --75 IV aESlBEOCEt 4T 77^5 t* sr --a t trK aN s--M--MQt TS 71 ------- 75 121:0U1 HAZARDOUS EMISSIONS 121:0483 2 Inactivity - Aftertbe site It iMCtlfttad. Indicate the uathederuattorf* km it toili Mill ttw itinM M mM a list of the actions tint Mill to mdnrteton to noloUIn tin Inactivated site. MS sr^itCiai % SlTt: R ST * w Bap 1-1 it0--17n sm sr ~n si Rvor/m-- w Oato of initiation of on-site cam Unction or Installation of orioslan control oqripnat or praeoso ctongo. Hup MS -S2 7 17-------I* sm Date by which m-olto canitruetlan or tostalUttaa of anfsalon control Ullpnat or process mdlflcatlen If'to to ouploted. if. mira stflutsis A. wren or ctowmcc. Cwom on eparetars of sorco< mabio to mti In couplluwa with too MIomI Mn1 Standards for Iuii4m Air Pollutants prior to 90 days oftor tho orfMtlvo 1tt< of My standard! or amndmats wOilcti ns*1n Do MoltilN.nf well Inftmtln ay mount a waiter of comIIoom Iron no Mrtnlitntir of tha B.S. bwInnonUI Protection Aphncy for tho tlm period nacossory to Install appropriate control devices or mta edifications to acMava ckpIImc*. tha AMnlstrator any gnat o waiter of CMpllanco with no standard for o period not axeoodlng two wars Iron tho'effoctlte dote of tha hazardous pollotaat standards! if ho finds that such porfad la nacoasary far tha Installation of controls and that staos Hilt ba tafcao daring tto period of tha waiver to essnm Mat tha fcaeltn of parsoM trill ba protected fron tmlnent endangenant. The report Informeioo praridad In Section t Hast aeeanpMy this application. Applications should bo soot to tho appropriate BA ragicnel offleo. o 1. Processes lavatvad - Indicate tho proeass ar meossao aaltting hazardous pollutants to which uatuloa controls art to bo appllod 3 2. Controls nBuy 037 it-- o sr Tb i mm/m--r w late fay which final cn^llance Is to ba achieved. Dm 1-1* 170--*--7-IT sm es------------ Rt 1--ID7IV7R---- & w I. MAlVEh OP PIISSI0H TESTS. A waiver ef enfsilwi tostlny my ho granted to owners or operators oriourcos of borylllwa or narcunr pollutants If* fn tho Jadgiwnt of tin Adalolstrutor of tho, Earirommtal Protection Agency the missions fraa tin source eogly rith the appropriate standard or if the owners or operators of the source have requested a waiver ef caqrtlute or tore bean granted a waiver of cewpl lance. This application should eccenpany tin report laformtlon provided in Section I. 1. toason - -Statu the reasons for requesting a-waiver of mission testing. If the reosen stated is that tin erissfent frm tin source ore within the prescribed Units, desmantattoo of tMs condition oust to attached. a. Ptseriho thu prapotad typo f control device to ha addal %r uodiflcatlm to m mdi to tha process to raduca the eulisloM of hazardous pollutants to an acceptable level. (Isa pddfttaaif i ahoata If nacoaaary.) b. Describe tha aaaaaras that rill ba taken drring tha waiter period to assnru that tho haaltb of parson rill bo protected fro* Meant andangaimnt. (Use additional stoats If pacassaiy.) 'Can Signature of- Me owner or worator 3. laaiumntn of Proaress i Specify tho dates by which tin fallowtup Mur--nto of pragmas Mill to aaC. [40 FR 48292, October 14,19791 lute by rhlch contrueto far oulsslcn control aystans or procosa mdlflcatkps Mill ba awardadt ar date by which orders rill ba Itswad far tha purchase of the ceeponset parts to actengllih cariislan control or procoss Modification. FEDERAL REGULATIONS AP00004520 t HAZARDOUS EMISSIONS 121 yisnw iti. .imm ra Mniimuntfit or vtuvtT nr wiirmm iwuncarr hamt KW*M BMM 1. rr*neipu~ mod ojtpUaabUitf. Ms> eipie--A weighed portion of the iswage ludge ample X dlgegted in aqua regia fa I minutes it 96*0, followed by oxidation with .peteeclum permanganate Matoary la the digested sample M then measured toy toe conventional toeeteopbetemeter com vapor technique. An alternative digestion Involving the un of an autoclave Irdeecrlbed in para graph itJ of this method. 14 Appliability--This *< U eppU- obi* for tut determtnuaoB of total oginje and lnogaaie mercury eontent ta wni* aludgee, sella. sediments, sad bottom-type materials. Tba normal range of *> method ta 64 to B %/%. The range may toe extended above ee below toe normal image by inereee- ing or deereaalag aample sine and through in strument and recorder control. 9. Apparatus. a.l dnatyna-rffhe conven tions! eold vapor technique(5) ta used to analyce the sample. ajA Atomic Absorption Spectrophoto meter *--Any atomic absorption unit baling an open petavatetion area in which to mount the absorption cell ta sultab]*.*In- atruaant settings by the par ticular manufacturer ehould be fallowed. * 1.11 Mercury Hollow Cathode Ump-- WactlnghouM WL-83347, argon Ailed, or equivalent. 34 4 Recorder--Any multirange, variable- speed recorder that la compatible with toe OT detection system is suitable. 3.1.4 Absorption Call--Standard apoeoophotometer cells 10 am long, having quarts and windows may bo used. Suitable oells may be constructed from plexiglass tubing, 24 cmO-D. x 11.4 cm <oa.. 1" OB. x 4#"), The onds axe ground perpendicular to toe longi tudinal axis, and quarts windows jti cm diameter x O.id cm thickness (on. l" x tie" thlckneu) I are cemented in place. Oas inlet and outlet porta [also of plexiglass but on cm OJ3. (oa. %" on.) \ axe attached approximately 14 cm tram each and. The cell ta strapped to a burner fa support and aligned in 'toe light beam to give the maximum transmittance. NOTK: Two 5.1 cm x B.l cm (ca. 3" c 3") -card* with 24 cm (ea. 1") diameter holee may be placed ova each end of the cell to amist in positioning the cell for maximum transmittance. 2.14 Air Pump--Any peristaltic pomp capable of delivering l liter of air par minute may he used. A Meaterflex pump with elec tronic speed control has been found to be satisfactory. (Begulatad compressed air can be used in an open one-pern system.) 2.1.4 Flowmeter capable of measuring an air Sow of 1 liter per minAte. * -3.1/1 Aeration Tubing--Tygon tubing la used for passage of tbs msreury vapor from the ssmpli bottle to toe abeofptton oell and return. Straight glass tubing tensmating in a coatee porous frit la used tor sparging air into toe aample. 3.14 Drying Tube--15 cm tong x 14 cm diameter tea. 4" long 14" diameter) tube containing to grains of toe dcelaeaat mag nesium perchlorate. The apparatus is assem bled as shown in Figure 105-1. Si plus of tot magnethim perchlorate drying tube, * smell reading lamp with MW bulb may be used to 1 instruments designed specifically fa toe measurement of mercury using toe eold vapor technique are ooamerclally available and may be eutoetituted fa the atomic absorption ipectropbotflcieter. prevent eeodensaUen of moisture imlitr toe eefi. The lamp Is positioned so as notto interfen with the measurement and to tolna ea paraturn about 4`C above ambient. 3. Reagents. 9.1 Analysis. I.U Aqua Begia--Prepare Immediately baface use by earerully adding three volumes of ooaoentrated SCI to one volume of eon- taper, precaution must he taken to avoid its inhalation., Therefore, a bypam ehwild be included to toe analysts system to cltoa van* toe maroury vapa into an exhaust hood a pea the vapa through anao absorbing medttsuch aa* (a) equal volumes of 04NKMNO sad 10% eaatcated HNO- 344' Sulfuric Acid, OAJ^-DUute ids mi of concentrated sulfuric acid to 14 liter. 344 Stannous Sulfite Add 33 g stan nous sulfate to 350 ml of 64V sulfuric acid. This mixture la a rapeoalon tad should be ttlnWA rtnflnr St----ni .(b) 045% todintln a 1% Kl motion. A Specially treated ehaieoel that will absorb mercury vapa to also available from Bob-- beyond Cheney, R. nth Are. and Noth Cattidy St. Columbus, Ohio 4*210. Catalog No. KO-UvHaUMV chloride may be usad laplace of toe stanaons sulfate. 4A1 Trassfw 0, 04, 14,34,54 add to ml 9.1.4 Sodium Chloride--Hytiroxylamint Uquote of tbe waking mercury eolation Sulfate Solution.--Dissolve 13 grains of so ooctAlnlhg 0 to 14 ag eg mercury to a mrlrn dium chloride and 13 grama of hydroxylamina of MO-mi BOO bcMlie. Add enough dls- sulfate m distilled water and dilute to ioo ti&ad vw to seen bottle to make n total ml. Hydroxyiamine hydrochloride mav be volume of to ml. Add! ml of aqua regln and used in plaoe of the hydroxylamine aulfate. heat 9 minutes la a water bathat 36*c. Allow 34.5 Potassium Permanganate--4% aoltt- ton mmple to ood and add M ml distilled Uob, w,*v. Dissolve 5 grams of potassium per water and if ml of EUnO, eolation to each manganate in 100 ml of distilled water. bottle and return to the water beto fa so 1.14 Stock Mercury Solution--Dissolve mfmltee Cool end add 4 ml of sodium able- 64344 grams of reagent grade xaercurle chlo rlilc Tifil(HiyTainlnn aulfate solution to re ride (Assay >65%) m ? mi. of distsuc* duce the exove* nermanganalo. Add 50 ml-of water. Add 10 ml of eoneentrated nitric acid dimmed water. Tfcaatiag mob bottle individ and adjust the volume to 4004 ml. 1 ml * 1 ually. add I ml ef etannous sulfate solution mgBg. and tmmartially attach the bottle to the *4.7 Working Mercury Solution--Mali* aeration apparatus. At tola point, the --r** successive dilutions of the stock mercury solution to obtain b waking standard' con ta allowed to stand quitely without agitation. The etaeutotlng pump, which hie taining 04 || pa ml. This waking standard pravieutiy been adjusted to a into of 1 liter and too dilutions of too stock msreury solu pa minute; is allowed to run continuously. tion should be prepared fresh dally. Acidity The aheetbanee, as erhlbltad ettba on toa of the waking standard should be main woctrophotomater a too recorder, will t&tained at 0.15% nittie acid. This acid should nriaee and reeflh maximum withln_po aco- be added to the fiask aa naadad before toe onde. As soon aa toe reeorder pen levels off. addition.of toe aliquot Mercuric solutions approximately 1 minute, open- the bypam should not he prepared in plastic oo&Ulnsr*; valve and oontlnne the aeration until tba 4. Procedures. Samples fa msreury analy aheorbauoo returns to ite minimum value. sis 'are subject to contamination from a Clloac the bypaaa valve, remove the fritted variety of sonnet. Extreme earn must be tubing from the BOD bottle and continue taken to prevent contamination. Certain In- the potation. Proceed with the standards and 'terfbrvaees may occur during the aaaly< conjunct a standard curve by plotting peak praeeduree. Bxtrsm* wvttm must l*c take'' height nnui minrograme of memuy. to avoid inhalation of mercury. 44 Sample Fantiling and Freeervatlou. 44 Analysta. 444 Because of toe extreme sensitivity 44.1 Weigh triplicate 04g040l g por of toe analytical procedure and the om tions of dry sample end place m bottom ef nipresence of mercury, care must be taken a BOD bottle. Add 6 ml a distilled water to avoid extraneous contamination. Sam and 4 ml of aqua regia- Seat 9 minutes in a pling dsvloes, sample containers, and re water bath a* 66-0. Cool and add to ml dis agents should be ascertained to be free of tilled Bata and 16 ml potassium paP' significant amounts of uwruuryi the aample mangawato aolutlon So each sample bottle. should not be exposed to anx condition in Mix thoroughly and place in the water bath the laboratory that may reault In contact i*r fv to mlnutM at 86-C. Oool and add e ml of airborne msreury contamination, gamble aodluw chloride-hydroxylamina sulfate to re oontainart to be used tor eoQcottan and ship duce the excise permanganate. Add 69 ml of ment of mercury camples should be properly distilled water. Treating each bottle indi cleaned betas use. Those should be. rln -'l vidually, add B ml ef ateumoua sulfate and with at toast Wt > BWO, .followed by Immediately attach the hotel* to the sue- du>tilled water. that appezatua. With each aample. oontlnne 444 While the mmple may be aarlyrc*l as described In paragraph AAl of tola tritoout drying, it hat been found to be more method. convenient to analyse n dry aample. Moisture 444 An alternative digestIon procedure may bo driyen off la a drying oven at a tem using aa autoclave may also be weed. In title perature of 40`C. No aigniflcaat msreury method 6 ml of oonoantrated K60t and 2 ml losses bate been observed by using this dry cf concentrated HNO. ere added to toe 04 ing sup, Tba dry sample should be pulver gram* of sample. $ mh-of.saturated XMnO, ised and thoroughly mixed before toe aliquot aolutlon are added and the bottle la covered is weighed. with a plea of aluminum foQ. The aarnplaa , 44 Interferences. are autoclaved at 121'C and 34 kg/csn* (ea. 44.1 Interference! that may occur in 1* paig) fa 16 mlnutee. Ood. &ak> up to a Nudge samples are aulfldta, high copper, high voUuoa a 100 ml with vrater, and Chlorides; etc, A discussion of possible in add 6 ml of --tt" oUortde-hydroxylamtne terferences and cunetted preventative meas aulfate solution to reduce th* exsea per ures to be taken lt-given in Reference (4) (7), manganate. Purge the dead ata apaee and 444 Volatile outerlaic which absorb at the 353.7 nm will cause a positive laterfer- oontinue aa described In paiagiaph 4.lt ef tola method. anoe. Xa orda to remove sap Interfering volatile materiel*. toe dead Air epees in the BOD bottle should ha purged with nltaogen. before ton addition a etannous sulfate. 44 Handling mmple Mercury 'topers After Analyta. Mention of wad* names a f**1** prod ucts docs not eonetiteite endorsement by too Environmental Protection Agency. [Appendix BJ M4-7 Pidiltahed by THE BUREAU OF NATIONAL AFFAIRS, 1NCL, WASHWGTOK, T>JC. 2003? 87 AP6b6b452i 121:0600 FEDERAL REGULATIONS b. cuoviaoen. Al mw ttw yut A /ater/ereneee. iootaniaftyfla. which ean 485 ghermmuetei Awnrele to one (ta height cf tte unknown from the chart ml oeeur in oome vinyl chloride wiuun, eU in pe* eratogred*, to nieeimi temperature el reed the aereury value (rn 11m standard terfere`with the vinyl chloride peek from heated aomple loop at time of aampto idRc- cum. the Ohromaewti 108 * column, gee eeotto-- den. M CtlwliW tbi nuriniTT oonoentmrioa 488 and 58. if reecluttcd eg the vinyl 4.58 Seremeter Acceietetotmaartg. %o in tto sample by me formula: 4l|lBthflll40flt U Bsport mercury eonaantretloae ee fal low*: Balov 0.1 *g/gs bstwven 54 and 1 *g/g, to the uiMt obi jg/g; between 1 and 10 ag/g. to nearest 0.1 eg: shove 10 ag/g. to nearest *f. 0. Freclrioa end ceeuraep. 54 Aowrdttf to tbo provisional method In referenoo Bun* bar 0, tbc following etandard davlahona on rvpueate sediment maples 'him boon to* corded at the Indicated level*: 088 *g/g5.0l egd 085 *g/f OJ>*. BiMTiry of mercury e* tne*e level*. added aa methyl odniu cbloride, vaa 07 and 04%. raspeetlvely. 7. Jte/orenoM. 1. Bishop; J. K. Hiwurr in adtesanta.'* Ontario Water tiaww <Vwmn, Itroato, Ontario. Canada, 1971. a. Balaa. X. Private oommunlratlaa. SPA Oal/Mev BMln Odea Alameda, California. 8. Haleb, W.B., >ad Ott. W.*. `^otaimtoatlon of gub-Utcrognm Quantities cd Hereury by' Atomic Absorption SpoBtropbfltwaetry," Asa.Cbein. 40, MBS uM). 4. Bradenberger, S. ana Bader, H. TW DeterminesIon of Hanofrws Levels of Mer cury in solution by a wamaleaa Atnenta Ab- ,nerpttaa Technique," Atomic Abeeepttoa newsletter 0 101 (1007). A Analytical Quality Control Libcratery chloride peak M atm net BBtUfaototy (or a particular aampte. than chmenalcigreph peraaeetera can he farther altered with prior approval ec the AflininktiaMr. if alteration eg the chromatograph peremrtera fella 40 raoolve the vinyl ehtaride peak, then rapplemantel eonflrmattm of the vinyl tolorida peek through en absolute analytical tech nique. each m mom epectreaeopy, mnot he performed. (41 PR 89005, Asw 7, 1977] 44 Seiupllng (Pigmy 104-1), 44.1 rmtia gtatniw Steel, pyiwr glam, or Teflon tubing aeoerdlng 4e (tack temper ature, web equipped with A glue wool plug to remove perttcuJAMmAMr. 418 Sample line--TBtom. 04 mm fartalli wwnttWf, gf nAciMU Mgth to oanaeet probe to beg. A new unuapd pteee le employed fmeaahewleaof begeampleathetecpetitutae mnemimloeiteet. C1J Male (t) and famaie (8) atalalaaa teal qulok-conneeta. with ball cheoka (ana without) kcatad a* abon in Figure (48 FR 88000. Jus* 7. 1877) 4.14 Bedlir bege; BBO Hter dBpdDttp-To oantaia mmpla. TWan bags are not accept able. Ahimlnlaad.Mylar baga may bo need, provided that the aamplee are analysed within M houit of collection. 448 Rigid leakproof poptainwe for 44.4, awaaurt a&iwnpharle praaaura around gaa ebjenuno^aph diving aomple analyria. *.7 Fninp-' teek-Xree. Mlnlnwm capac ity UO aal/mm. 4.4 Calibration. 4.44 Tubing Teflon, 54 mm outside diameur, separate ptoom minted for each eellbaatlca cenaeatretton. 488 Tedlar begs Metsea Inrh equaxv alM. otparate bag atorkad fer aaeh eallbra- toon oonoeatzatiaa. 488. dyrings--88 aed, gda tight. 488 Syringe *5sL gaa tight. 845 Flaw ttittor RotgiMtar ^pa, 0 to loot ml/mta range aoeueata to ml*, to mater aitragen m ptsparatme cf standard gaa mistime. 444 Stop watch--cc tom imuim), to time gea Sow to pi,*Jtllmi eg etandard gas ainuw A BMgB&ta xa to naenmary that all ma genta to eg ilmnnaHiQiaiililn grade. Al Analyala g.Li Helium gaa or totregaa gaa--zero grade, for Ohrcmategraphto cartlar gaa. A18 Hydrogen gaa Serp grad*. 5.18 Oiygeii gas. or Air, aa required by the detector--Sera grade. AS CBUbroHon. Oto one eg tbo toUowtag optloBt: either 98.1 and 588, er 588. AAl Tbigf ehionn, 948+ percent. Fort vmyl chloride gaa awtlflad by the aaanufaeturar to sontain a *>|-- at MJ pereaat vinyl ahloclda fer uae in tha preparetlon of (AQOL), BnvtronmtBtol riotecbou Agency, with cowing to protect ooatenu from run- atandan' gaa mlzturaa to section 74. Xf tha Cincinnati. Ohio, "Mercury in Sediment (Cold Toper Technique),* Provisional Method, April 1078. f. Kopp. J. F. Longtetcam, BL C. and Lobring, L. s. "Cold Taper Method for De termining Mercury," Journal AWWA* 04, 1 (1018), pp. 80-15. 7. "Manual of for Chemical Anal- yala of Water and WiftH.* Snelmninanlel light. 4.18 Woedie valve--To ad)u*t (ample Sow rate. 44.7 Finnp toeb-free. Mlalraw nepec- ity g pun per minute. 448 .Chafnpal 'tub*--To prawot admla- Mon of'vtoyl cntcrlda to atmoephere In riolnity of MTTinleiv 448 Pww meter--For obetrvlag aomple gaa manufaeturar malntalna a bulk cylinder rappiy of *98+ percent nay! eniceide. tb* eertlSBatlnn aaaiyria atay have been per formed on tola supply rotbar than on aaeh gaa cylinder ptepsrod from thto bulk rappiy. The data of gw cylinder preparation and tho oartlflod aaMytoa muat nave bean atosad to tha cylinder before ahlpmant from tha pi awnnfaenaer to the buyer. Protection Ageney, . HTA-OM/O-TO-OM, pp. 110-184. flow rate; oafiihte of measuring a flow range 588 jrttrope* res. Ewe grade, for prapa- fnn 0.10 tv180 liter per minute. tatton of -*-1---H gaa iidilmaa 140 FR 46292, October 14,1975) 44.10 Owwacrtag fsbfng. Teflon, g.4 ASB Cylinder etondorde (5). Oaa Bals mm eutelde dl*xpetarK go amemtale aomple am* vtaadBidB (M, 10, nod 5 ppm -vinyl nmnif Sovatiao (41 FR 46S59, October 11.1976] tram (Figure ioa-s). (48 FR MOOS. June 7. 1077] 4441 Mtot tube--TypeS (or equivalent), iniaonucinin attached to the probe ao that the aaeipuiig performance of thla aaothed abould not bo Attempted by panona ---- with the operation of a geo etoanteptph, ner by thoee who ere erith source -*** pllng. ae there are many detail* that are beyond the eeope ef thle preawtatton. Oare muet be esereteed to prevent otpecure of -f'y pectennel to vinyichibride, a eer- Mnogwi. Maw rata ean he feghteted preperttoaal to ra* ataeb gee velocity. 48 Sample ivnurery. 484 Tubing--Teflon, 4.4 asm eutaSde diameter, to ooaneet hag to gee chromato graph sample loop. A new unuaed piece is employed fer each eeriee eg bag ----pi-- that eenatltuteo an --teet, and la to be dis carded upon concluetoa of anatyaifl of thoee ehieride in nUingon syUnban) for which the gaa eumptniucB bee been ewllflij by the manufsctuzvr. Ths mamtfaotum moat have rewaimended a --w--" abrii wo for -- oyhndor ao that tha eeaeestoetlea dbaa ao* bang* greater than 5 percent from too ow uaed value. The data of gw cylinderpevp- avatira, ewtlfled vinyl chloride eenoentoatoon and recommended maximum abeU Ufa muot have been afflrvl is the ayunder bafera shipmeat from toe gaa manufaeturar to too bujwr. Thsae gaa mlstura etandard* may bo dlncuy need to ptapaia-a chramatograph aaltoratoon eurva aadaaarlbod la motion 78. 1. Waelfb and ApplloabUlty. >854 flpunder ecimdard* eerNScoHen. u An integrated bag sample of etaek gar containing vinyl ehieride (ehlevoethane) la (objected to chromatographic analyst*. uei-y *wu ianiaatlon detector. (48 FR 80000, Jaw 7. 1*77) IB The method te opposable to toe meas uremente< wnyl chlorida in atncfc gaoeo Bom ethylene dlchleride, vinyl ehieride and poly vinyl manufacturing ppaaemie. ex- oept wbooo the vinyl ehioride. la aofldnmod St particulate matter. A Saage and flwatUvity. The lover ttmit of detection win vary ao* aordlng to tha ehaamatograph uaed. Taluea repeated tostude 1 X-18-* mg and 4 X 10-* mg. 48.1 AM M8walui7t|^ 9l(lb fcsnra amaeHMa. daaeobor, potenUometric atrip cbsrt noerder end 18 to AO ml heated cam pling loop to automatic mmple valve, 488 CHromatoffhptHc oohima, BtaMlma oteeLS mx88 nun, ccwtainiBg m/ioo aaaoh Chramaamb 108. A aaoondary wfnrm cf Od SF-OB, M percent on BO/M mettlWObum Barb Ft italniM ttaai, t mxAl mm or Forapk T 00/100 maatt Btalnlaaa ata. l mXAS mm la reqghed If4oeta)d*byde to prevent, tf need, aaecendaiyjmuma to Macao IW tbo Bhrcimaaorb la oolumn. ni oemblMd eelumaoabould tbca be operated at in* a [48 FR 89000, Jbdb 7, 1977} 488 Flaw matora (7) SiHanialM type. The ccncestratloa cf vinyl ehieride In nitro gen In each cylinder moat have been carUfled by tha manufacturer by a direct analysis cf each cylinder using an aaalytteal procedure toot too manufaeturar had caUVatsd on too1 dha--y of cylinder analysts. Tho calibration of have uiniaad a three point eeiibrattsn eurva. It la tv ecnitu ended toe* tha manufaeturar maintain two calltranom Btandarda-and um tooaa Btandarda to the foueariag way; (1) a high eeenentretten etandard (between 50 and 100 ppm) tor preparation of a oaUbratlca curve by aa appropriate dtttrttoa tvehalqut; (I) a lew oencentraticn etandard (between and 10 ppm) tor wtsoattoa of toe dilution technique need. * Mentlen of trade namee on cpeetflq'pnducta dooa net eonatltute endeiaemrat Mr tiw Barironmental Protection Agency. 0-to 100 >11/7010 eepedty, with flow eoncent ealeae. 488 Oao regulatora For, required g-- egundara 888 ' SelcbKfhmewl and v tguullua of oabbrorioa etandard*. The ehoratratlcn of ee*h eeUbratlon waadard muet have tow mtahuehod by the manufaeturar uatng [Appendix ) Efivlranmen) Reporter 68 v r AP00004522 ZStOOOOdV eg teoo;a7a<NoioNiHsvA,oNi`svivdiV'EVMOuvNdonv3YneaHi^'p*tmiqni ( KIPUMOV) %l+z* do?* irmwifTt UamVtpiMmw|ritmiiyw m oo oimdmi M Mhai nrarti H <TM>'oairuqn** leitap n*~' to,IBWMHHIjM'MTdMMUdMWNtMMIMatHq IM* JqjRMIpBI --------mi jo ~nM'fftdana mmiimm* m*n MMM U>IJ pnCrnv HiNmmniinNma4UMu<u-iHr e-ear nnBK v**-Ty>j rX'rf*0 v iMenotn^omiM -mo mm wtf nmm oqt at opaodns W* O jo oniBA oqt loop* <#*oq *T4 aoRMt w poquooop anno BoptMqnao Bqt mu fnoBonovM opuoiqa tfou re MmR MmtMMoBmHiMnioMqx*m--*vr MR good qdnm*SJ)-y _ l-BOT aonm&s ty*Y-T o ** VR otdono n WRMig rp 'ntitiliwiW *tm mmoipm xmo mi a* nwdh *oq oqt bora mb cam rrim at Jouwoioi quo MBnu'`eaaa otoBMAs Tonq dMd qt pm >oq oqt Ri*lR oBn-ar ntratRi 'a m|d fjiii|i4uaO' pt>w m at Soq. i[teii OBOO 4Q* (T|W1 MIMtPTO Soq MtTOP P 'iqSraaio poor M mam Po OTI 'T *-t a o*h n ai-S 0 *oq oqt MtnuMd at R poqiata qooqo nt OABBuatlB trr :om> 'mwv vmt at n*i > aaaw pifu oqt mom one "mor b- Mfaipai- nsramni j*m* oqt bt tans ooBidnp ft wnma1 m an pmi at mrt 'fo*H i *-6) o'k mb oi-t oi tvq oqt Mtma Hid pm aiomamM m a 9000000 `qooqo m>l ax `oanoj ** RfB*i dotwop tea pip tag mtu iro'm pm MtlT m Swq 01 pl ponnutd oq it ipqt pooupB orb n It'm J*q 01 toonbaaqiN poipibw *1 aenooo *tm JO omoMojad onq* `awip not Yk llUl 'L Otnr `MOW Mi ) imalwo WOW ! 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MMUIMHi t. amm. o. w, ley, M. W. and atophui- M, U. B. 'Vinyl Chloride Ifnattering Xw the s. r. oooanaa obanneal Ooranany m LonMvtUe, *oaekj." *etV XV, 04 BiV- mwtn tawtsrtiop j|i>ip guTvmntans M AntayoM Btikka. Athena, aw|l>, Mm Aim. S. `"valuation erf A ObOmUm ia< AhalyReal riBMinW foe Tlayi fftalcrtOe ta Alt,* by O. D. oayton ud dosortatta. Baa--(bar U, 1P4. BA Owkeet Me, ta W ttta. Ttak Crtar Wo.*. VABMoll. W-TOUd. A "gVswgsriMmiHa .r wtuy J--w UMBUaAtwVttflOb--,"Ryma. wt ii--A Mum, vn. ba Ontaet Mo, ii-ta IWATeAt--srMs.V. M a irte a i fcanmp: , mm vnm. flMrwma OueauiT^ar 'mifBRl CkE--t MbK* A--b VB (41 FA 46559, October 20,1976) MOaucp-- Me-- e( thb MeOnd AmiM apt be attempted bf persons *ia Be operation ol i pt ctarTTBatogfoph. --r by those be ere ------- with sampling. ae. there ere amat entile tkn ere mm thr oope erf this pwtntttlBa care hub be nsetaaa bo prevent eipaeure of sampling: perennael te vinyl ohlcridt, a earotaogen. 1. Ptlaeipie a-- AppUeabtttty. la Ibe bub tee this method mates to the rmpee eqmubrtam which M vstabUahed be--t RVdrf. rva rosin. --, and Mr rtn a tlaaad intia. It hat been damonstistetf that the BVCU in a rvo mein will squillbrate la a dosed eeeetl quite rapidly, pro-. Tided that tba tempereture or the PTC nsta* ia maintained abort the gla transition; temperature orf that apeolAe -- 1.8 Thla ptwjoduro is ealtatala tor deter- iM"t the vtnyi ohorfds monoiosr (VCH) eoateut erf iaprcoses waste-- samples, end the realmill rlayt ehlerlde monom* (KTcK) oontent of polyvinyl ehioride two) rsaiaa, wwt safes, slurry, and lata ssmpiss. It canned ba used ter puijiiisr ta fused forms, sueh -as sheet or oabea. If resolution of the flay) ehlerlde peek M-jata satisfactory for a particular tampTs too* chromatograph parameters may be altered provided that the prwMalea sod reproduci bility of the analysis of fiayt chloride eylta- dsr standards are sot Impaired. If there is reason to believe that aome other hydro carbon with sa identical retention time la prestut la the sample, then supplemental eoafirmatio*. cC the vinyl ohlerM* psafe through as absolute analytical technique, sueh as moss spseaustopy. Should be per- (49 FH MOM, JbM 7, MTTJ 1. Bange and activity. The lower that* orf dpteotto he fiagt-moo- ride wen fair ossrirding la ihe Ohio--to- goh wmd. 'slats itprtti Inetuds IXHH ag aad 4xto* mg. antfe r------------- ---"" -- BBDwllnlt -- bees a. Jieulaian and Meprod--htUtf. An latartabcratoty comparison tdow seres laboratories orf three re-- ssiwplis, eeeh spilt Into three parts, yielded a etodmd deviation of 3A>% for a sample with a aisaa orf *40 ppm. ult tor a sample with a mesa orf l.M ppm, and 140% for a eampie with a mean erfM44 ppm. Oateq, Oo not release vinyl ihlartta to the labors tory etmeepheredurlsg preperfottdnsrf sessdarde. Venting or puicwg with VaM/asraattfuns must be bald to a i--llmnm. When they are required, the taper --at be routed be outside atr. Vinyl chloride, area at lew ppm levels, must asear be muted inside the ieboratcry. At-- vlale have beau aaaJysd. the pt-- within ttavlai sun-ta waul prior to ibaineal from tfea tnstroment tarntable. tub must be rmiiod tsn ta aotitstsd ehsreoal tube tatag a hypodsRDls mifle OK prevent reloase orf vtayt chlortd# into -the laboratory atnmepti--. Ihs -tdwtaodl -- be aoplaosd prior ta vinyl --do tasak- g.14 Tlsla-gonaiaypo-vteitf --Udwttfe Tbfica taaed Itfd-- dhos for wntsr mm plea. Ui taectrtosl toe or -equivalent, ta prevent loosening orf tattle tog*. M Sample recovery. 141 Vials 'With oasis and caps, tartanUmar carporation Mo. loe-onc, m equiva lent. 44 Analyttasl hatsuoe- CbpeMf of weighing to 49401 gram. 44. byrtage, lOO pt T--slno tanas Me. oiaou, m ---- S4A vial gisin. rrmn vurrr Mo. lag0104 or equivalent. .44 `Anaiystf. 14.1 fin ehrometourenh Perils Tlmd Ootpcratlon Modal tadAtaad^aos ana* lyaer, Mo. I0e-0001, or equivsleot. 44 ffliifwtbrqiMi eelueiw. gieinlsta steel, I m x 14 nun, aontainlnj o.o percent Osztawan 1100 an Otriwpih A. tarkin-blmer oorporation Me. 104-01It, or equivelent. Ositapak O can ba used la place et CaAopsk A. It methanol and/br aesasldahyde Is pree. ent ta the sample, a pair orf Peropait Q oolumna la serin (I m X 04 mm followed by IbX ii bus) with provision for bsckflush orf the diet eolumn tae been shown te pro vide adequate separation of vinyl otateride. [tt nt MOM. Jm 7,1977] 44 Thame--ter--O ta 100* e. aoeurate to M0.1* a Pemn-Sbner M0. 100-0100 or OQtilvais&t. t44 taasple hay thermostat ejslem tarkm-Bhaer Mo. lot OIOS, r equivalent A Apparatus. U gampUag. aaa aottlss ao ad M ea). with waned lined sore* tags, ter BO samples. "Vfsnimn rrf bids aamm en spsumn lonil mots dose aot-eoastfCata endeceeseearf by Ota BvtwumsntR Vratastiaa Agamy. Enviremneni Roparter {Appendix B] 60 HAZARDOUS EMISSIONS 8-391 121:0003 gJ.B Septs Bsndwlch type. for auto mate dosing, is Ban, Perkm-nmar No. M4loot, or iqiiinint 4.4 Integrator - recorder -- Hewlett PieUrt iiodoi asaOA, or equivalent. 82.T Filter drior saaembly ()--PmkinBaser No. S3M11T, or equivalent. UJ Boap Sts florasUr--Hewlett Fuk> lid Mo. 0101-0114, or ifilfBlni 4.4 calibration. B.42 Maculatoca ter koquired gaa oyindan. 4. Macront*. 4.1 Analyaia. U.1 ZfdMfM car owe ptdt. 40.4 Nitrogen gas pare grads. 4.24 Air" ottograflo. 44 Calibration. (41 FR 300B, Juna 7, 1477] 44.1 Cylinder atondmfli (4). Oaa mixture standards (40,800,4,000, and 4,000 ppm vinyl shloridq in nitrogen cylinders) for which tha gaa composition has boon oartiflod by tbs manufacturer. tower concentration stand ards should bs Attained If lower oanoantrationa of vinyl chloride samples an expected, as tha muot is to bracket ths (ample eonoontratteas with standards. Tha manufac turer must bars recommended a maximum half Ufa for sash cylinder so that the eonaootratlon doaa not obangs graator than ns percent from tha certified value. Tha data of eat cylinder preparation, certified vinyl ablorida eoaoantratlon and recommended maxtramflTfchelf life must have baan afised to tha cylinder before Shipment from the manufacturer to the buyer. 6.2.1.1 Cyttnder standard* ocrttjteoriofi. The ooneeatratton of elnyl chloride in nitro gen in each eyllndsr must have been osrtl- fled by tbs manufacturer by a direct analysis of aaeh cylinder using an analytical proce dure that the manufacturer had calibrated on the day of cylinder analysis. Tbs calibra tion of the analytical procedure shall, a* a minimum, &av utlUssd a three-point cali bration curve, It la recommended that the manufacturer maintain two calibration standards aod us* Mines standards in the fonowbax way. (l> a bigb concentration standard (between 4,000 and 8.000'ppm) for preparatloD of a calibration curve by an ap propriate dilution technique; (3) a low con centration standard (between Ad and 800 ppm) for verification of the dilution tech nique used. 44.12 fltfabftsbinent end eriflostfox of eetibrerion ttan&ardm. The ootwentratlea of aeh calibration standard must have baan established by the manufacturer using reli able procedures. Additionally, eaab calibra tion standard must have baan verified by the manufacturer by one of the following proeodurw, and the agreement between the ini tially determined eoneauCratlea value and the verification concentration value must be within usB percent: (1) verification value de termined toy eempaxiaen with a gaa mixture standard generated la a similar manner to the procedure described la section 7,1 of Method 104 for preparing gaa mixture stand ards using N8i percent vinyl ehlonde. c <S) verification value obtained by having tbs eaUbretlOB standard analysed by tbs Nation al Bureau of Standards. All calibration stand ards must be renewed on a ttxns interval consistent with the shelf Ufe ef tha cylinder T. Procedure. 74 Sampling. TAJ V4B sampling--Allow tbs resin er slurry to flow from a tap on the tank or-alio until the tap line has besn well purged. *x- and a #mraM0fe4(4l4e under tha tap, AH, 72.4 and Immediately tightly a* tha bottle, wrap Using a turn rial (Including ,,< electrical tap* around tha sap and bottle to aluminnm eap) quickly add approximately prevent the tap from loosening. place an x oe ot water uing a ~niniia oruppar. flaal identifying label on each bottle, and record tho vial as soon os possible. Determine the date, time, and sample location both on sample weight aecoate to 420X gram. Con the bottles and in a leg book. dition the vial for two hours at M*C la tha 7JJ iMtfuempUhg--Frier to use. tho analyser. Uk-tot-WMIs - (without the dm) must be 74 Analysis. earned with aluminum foil sad muffled at 404*0 few at least"One hour to dsetrby cr 72.1 rnpaiatlon of gaa chromatograph-- Install ** j**iimBii'|wpB i Min-,- mm, . remora' any organic matter that could is* ditlon overnight at 184*0. Do not -ytmrvt the terfere with analytic. At the --mpit^g loca tion fla the vials bobble-free, to overflowing so that a convex maniseua forms at tbs top. Tha excess water te dUplaoed as the --**-g cdt and of the column to the fletaetog while bmiHIMaiiIm, 72.1.1 Wwr rote adjustments--Adjust RfMP fttM B| ftttlMM* disc Is carefully placed. Teflon 4di down, on tha opening of tbs TlaL place tbs aluminum seal over the disc and the neck of the vial and crimp Into jdaoe. Affix an Identifying label on tha bottle, and resort tha date, time, and sample location both on the vials and in.a log book,, ait samples must be kept re frigerated until analysed. 72 Bsmpiorecovery.BfliHuVm xftwfhetwa. wrtMn 44 buiira 72J Mann tempim The weight of the msm used must be between 0.1 and 4A grams. An exact weight must be obtained (^O.ooi gram) for each aamplv. Xn the cam ot mupension reams a volumetric eup can be pre pared which will bold the required amount of sample. Tbs sample bottle la opened, and the cup volume of resin is added to the tared cample vial (including, septum and alumi num sap). The vial is Unswdiately sealed and ths exact sample weight is than obtained. Meport this value on tbs data sheet as It M required for calculation f MUCK. Za the a. Nitrogen carrier gas--gat emulator an cylinder to mad 40 paig. flat regulator on chromatograph to 24 kg/cm*. Normal flows at this pressure should bo 28 to 40 oe/alnmta. Check with bubble flow asstar. b. Burner air supply got regulator aa cyl inder to mod 40 peig. get regulator on chromatograph to supply air to burner at a rate between 980 and 800 ec/mlnute. tilth bubble flowtneter. 4. Hydrogen supply- Bat regulator on cyl* todm to mad 40 pslg. Bat regulator on chromatograph to supply approximately 45+8 oc/minute. Optbalas hydrogen flew to yield ths most sensitive detector response without extinguishing the flame. Check flew with bubble meter and record this flow 72.12 Tbmpemtom adjustments flit temperature* aa follows: a Oven (chromatographic opiums), go* C. b. Dosing line, 140' C. . Injection block. 140* C. saae of relatively dry resin Tf*T'-- (watar A. flampla ohamber, watar temperature. content <0J weight %), 100 >1 of distilled 40* C12* C. water must be injected into at vial, after aeaUag and weighing, using a 104 *1 syringe. 2n the case'of dlspenlen resins, the cup cannot be used. The sample is i nitsad weighed approximately in an dish, transferred td the tared vial and weighed accurately in the vial. The sample is than 72.12 Ignition of flam# Ionisation detec tor--Ignite tha detector acocedlng to ths manufacturer's instructions. 72.J .4 Amplifier balance--Balance the amplifier aceoidifig to the manufacturer's Instructions. placed in the Perkin-Emar head space ana 722 Programming the chromatograph-- lyser (or equivalent) and conditioned for one -Program the chromatograph bi follows; beer at M-c. a. I--DflUns time- 'The normal seating ia Mots: Boms aluminum vial caps have a 2 aeconds. canter saclion which must be removed prior b. A--Anal?*U time--The normal setting to placing into sample tray. If not removed, is a minutes. Certain types of aamplee con oerious damage to the Injection needle will tain high boiling materials which ean cause occur. ... interference whb the vinyl ehlorlde peak on 722 BuapeMicMeerin irony and wetoaks subsequent analyses. Xn these eaeee the sanmtoe--Slurry most be* filtered using a nmlyels time must be adjusted to eliminate small Buchner funnel with vacuum to yield the Interference. Aa automated baekfluah wet cake. The filtering prooeee must be con system can also be used to solve this prob tinued only as long as a steady stream of water la exiting from the funnal. Excessive filtration time could* rcdult in mu lose of VCM. The wet cake sample (0.10 te tfi grama) la added to a tared Vial (including septum lem. o. B--Flushing--The normal setting is 02 minutes. d. W--atsMUaetkm time--The nnmei set ting is 02 minutes, and aluminum cap) and Immediately aealed. e. X--Number of analyses per mmpiw--The Sample weight la than determined to S deci normal setting is l. mal places. The temple la then placed in the 722 Preparation of sample turntable--Be- Mas In Ttixai bond spaas aualjms <r equiva lore placing any sample Into turntable, be lent) and conditioned for one hour at M*C. certain that the center section of the alu A sample of wet cake is need to determine minum cap baa been removed. The numbered TS (total solids). This Is required for calcu sample bottle* should be placed in the cor lating the MVCM. responding numbered pceitio&a in the turn 722 -OripetelM imstt .Ttampla*,-- table. Insert --al* In the followInc order: This material should set be Altered. Sample Positions t h 2--Old 8000 ppm standards must be thoroughly mixed. Using a Waeed- for conditioning. These ere neeeasary only ST-XIncluding septum and aluminum cap) after the analyser haa not boas used for 34 add approximately 4 drupe (428 to 028 hours or longer. gnuna) of slutyy or latex utng a medicine Position s--w ppm etaadart. freshly pre droppar. This should be done mmsa<eaiy pared. after mixing, Baal tha vial as soon aa possible. Position 4--800 ppm standard, freebly pre Determine sample weight accurate te 0202 pared. grama. Total sample weight must not exeeed Position 8--2000 ppm standard, freshly 440 grains. Condition ths vial for one hour prepared. at po*0 in the analyser. Determine the TS Position 6--4000 ppm standard, freshly pre on the Blurry sample (Section 724). pared. 3-34-78 [Appendix B) PuMifhrt by THE BUREAU OF NATIONAL AFFAIRS, INC., WASHINGTON, D.C. 20037 gj I AP00004525 121:0604 FEDERAL REGULATIONS Factum 7--sample No. 7 (nic u th# am mmI* at tb* dy, tat N glean ulteta* eonMotent with fee turntable cad th* integrator printout.) Alter *U MimplCi tart barn poBttouod. in- mat th* OOOObd Mt or so, coo. aooo, and 4000 ppm standard* Bamplm, IUMIk tonal* node auat Be miidill--gBa-teotatb or W 0 foe 1 boor (act to iwni A Bean). 7J4 Start ckromttcnpli - umyia-- When ou samples. taciuding sUTidarti. bn boon oosdltionod at 90* O ter i boor, otort tto uutai program according to tbo nui* lecturers* instruction*. That* taatraetlona BWt bo carefully toUawt when iWntB| tnd itopptai program to prevent damago to the dodsg utambiy. 744 Determination e tot*] solids <TB>. For not oak*. slurry, rasla solution, end PVC latex tempioo. dotennis* TS for eceB ample by accurately weighing approtim- otoly to 4 mu or nayb is *n aluminum poa bofor* and *ft*r placing la * draco ovon {IOC to 110* C). ttaplM nutt b* dried to constant weight. Altos am weighing rotom Om poa to tbo owa for abort poMod at time cad than rsvMgb to verify mb* put* diynoao. TB it tboa u tbo anal aomplt weight dloldad by Initial aam- pie vd|bt 9. OaUbrauon. tfteratton it tohrpmlui--wodboight- <Aor ported-wMb tfco'lnstrumsat It-Mood. Been flay, prior to running tbo ooi- nm mould bo ooadltiobod by running two of tbo previous dip 0000 ppm BJ preparation or standards. Calibration ataridarda im poopaiod by in* tag tbo vials with tbo Tl&yl ehlorlda/nltro- Ctd lUSdVKl, rapidly anting tbo aopeum ond aoallag with tbo aluminum oop. Uao *aintaa atooi bat from tbo oyuadtr to tta: tUL DO SOt um rubbor or tygoa tubing, no sample Has tMOC tbo cylinder matt *be purged (into hoed) for several mlwiitee prior to fillag slab. Aftor pinging. raduoo tbo flaw lo to approximately 000-1000 oo/mln, Float ond of cubing Into viol (ant bottom) and aftor on* minute olowfy rwiti tubing. Ptooo aoptum la viol *a soon ao pommi* to mini- auoa wuimg air with sample. Aftor tbo etead- ord title ora eealed, tajeet 100jd of distilled water. r M Fiupuraugg of thremategraph taUbtatlm turn. TNporo fwo 80 ppm, two 006 ppm. two 9000 ppm, and two 4000 ppm standard samples. Iran tbo oaUbrattm samples fa exactly tbo tamo uug at ngular r1** Fist A, tta integrator oraa .oetmtt tor oaob otaadard sample n c* tbo weapontrauun of vinyl chloride la Meb otaadard sample. Draw unt of Mttnt through tta potato. 9. Calculations. 91 fftotcc* From tbo eoUbratloa cum dtaolbod la flection-gJ. abort, select tta value of C. ttat eorroapandi to,A> for oaeb oompl*. Com pute tbo ratpoato factor, Br. for oaeb maple, ao follow*: Equation 107-1 90 Botldml vinyl chloride moaemot ooaoantrtttoa. or vlyl chloride'moBcmw oonomtratiob.' Calculate Cm at foUowt; Equation 107-2 then: C,M-- Concentration of vinyl chloride in the ttnple, tn pom. Pm--Laboratory atmosphere pw euro, xnm Eg. Ru Room temperature. *KMolecular weight of VCM (82.5). l'i<aTohime of vapor photo (vial volume lets cample volume), ti"Weight of cample, gram*. RwOm constant [63,380 (eo-ina- mole-degreet Kelvin)] ff--Henry'H Law constant. For VCM in PVC at 0* C, K--0.52X 10-*-K For VCM In 1 ee (approximate) wastewater cample at 00* C, K-6.0X10-*-JCT*" Equilibration temperature, *K. If the following condition* are mot, Equation 107--2 can be simplified a* fouowo: l. r.-22*C f298*K) 8. Ti-00* C (383* K) 3. P--750 min Hg. 4. K<-K.-2i_23,6~|L where r,--VUd volume, ee (23.5). 5. Semple contains less than 0.0 percent water. '(4.197 X10-+B-a8^~~<) Equation 107-3 The foDowing general equation eon bo used for any aaraple which contains VCM, FVC and water. Equation 107-4 where: TS--Total solids. Norc: Kw must be doteraiaed for sam ples with a vapor volume to liquid volume ratio other than 22.5 to 1. Tbit ratio can be obtained by adjusting the sample weight through giving consideration to the total solids ana density of the FVC. ' Results calculated using Equation 107-4 represent oemoeatration based on the total rumple. To obtain reaulta bated on dryi PVC content, divide by TS. ' For a 1-ce wastewater sample (that it, 22.5 to 1 vapor volume to liquid volume ratio), Kw is 5.0X10-*. Thus, Equation 107-4 eqn be simplified to the following: c;,,"^[^gH2+C2.oxio-.)] [48 FR 39006, Jam 7,19771 Equation 107-5 ip. Bofsrtnom. t r-,K--1 vinyl bfonemm Don- teas of Felyvlnyl OhlcrMe lHa and teat Cake gemplm. B. F. Ooodrleb Chsmleal 00. Btendaid Tast proeadure No. 1006-T. B. F. Oeedrlta Toctaical otnttr. Avon Lok*. Ohio. ITaauaiy W, 1979. t. Bmaiw. A. "Tb* SolablUly of Vinyl Chlocld* In Fulyrtnyl outrider Aoe-DM* dm of FiJymar Chemistry, Folyinw Froprtete JA (I) 1197,1974. 8. Bwaaa. A. B.. "Tho fiurualan of vinyl OhleeMa t Foiyviayl ebtoelda,** A0B4Mt> alea at Mraw otoubUr, Mymer Froprlate ff (3): 10a, 1974. 4. Barant, 41,1.4Crldw, 0, 9.Toaianak and J. II. wumay. Anaiyaia ter Vtnyt Obierldo la FVC Fuellii by Boad-Hpoo* 0*0 Obroeoatography,- to Bo pubUatad, x Environmont Report** (Appendix B] 42 AP00004526