Document Vj12qmJjNepgb8DgZLOJ6x62w

LaboratorRyeportA,nalysiosfFCs inSamplesofChildrenS'esra,May 21,1999 The datasubmitteodn perfluorooctanesulfcoonnattaeinasnalytdiactawhen certaigneneraclonditiohnasvebeenmet. Thesearethatfinaalnalytdiactais availabalned thatifthidsataisa componentofa studya, reporetxisttshat combinesthedataand otherpartsofthestudy.Datathathasnotbeen integratiendtoa reporto,rpilodtata,hasgenerallnyotbeen includeidnthe submission. The attacheidspilodtatashowingresultfsroma limitendumberofhuman blood samples(pediatrsiacmplesfromtheUniversiotfyMinnesota)T.hispilowtas meanttodetermintehattheanalyttiecchniquceouldbe usedon a smallvolume ofserum.Althougfhluorochemicaolncentratiwoenrseabovedetectiolnimits, no conclusiocnasn be drawnfromsucha limitendumberofsamplesT.he plannedstudywilclontairnesultfsromover600 pediatrsiacmples.The samples inthistudywilble runina contracltabusinga differebnltankunderGLP conditionTsh.e planforthistudyhasbeen previoussluybmitteudndercoverof theApri2l1stlettetroEPA. 3M EnvironmentalTechnology and Services PO Box 33331 St.Paul,MN 55133-3331 6127786442 MA T q *mtory RTott AnalysisofFCs inSamples ofChildren'sSera LaboratoryReport No. FACT-GEN-011 W1724 Tesdng Laboratory 3M EnvironmentaTlechnology& SafetyServices 3M EnvirorunentaLlaboratory FluorineAnalyticaClhemistryTeam (FACI) 2-3E-09 935 Bush Avenue, St.Paul,MN 55106 Laboratory Contact KrisHansen,Ph.D. Bldg.2-3E-09 P.O.Box 3331 St.PatiLMN 55133-3331 Phone: (651)778-6018 FAX: (651)778-6176 Requester GearyOlsenand JeanBurris 3M Company OccupationalMedicine 220-3W-05 St.Paul,MN REPORT DATE: 05/21/99 3AI1'.*,VP'I/?OA(LA.IAEBVOTRAAL7r)RY REI'ORTAROF.ilCT-(3EV-011 @.1nir6duetion:. ....................... Samples were armlyzedtoprovidea quantitativdetemiiriatioofnPFOS and PFHS ina mmU number of samplesofseracollectefdrom childrenbetween theages of6 and 12.Additionallys,ampleswere screenedto providequalitatidvaetaon thepresenceof severalotherfluorochertucailnscludingPFDS, PFOSA, PFOSAA, M556, M570, POAA, M463, and M513 (AppendixC conliima lisotfacronyms). Less than 100 pL of serawere availablfeoranalysis.Thissmallsamplevolume posedanalyticarlestrictions and method detectiolnimitfsorthistudyaresipfflamtlyhigherdm reporteidnearlie=rdies. Sem sampleswere extracteudsingan ion-pairinegxtractiopnrocedureT.he extractwsere quantitatively analyzedforPFOS and PFHS usinglugh-pressurleiquidchromatography/elwumray tandem nmo spe=metry KYCIESMR,,4S), and evaluatevdersusan amwted cmt Quahmtivemmbw was conductedby comparingpeak responseinthesamplestodut obtainedfmm s=dgds@when possible.If standardn=nal was notavailablec,ompound identificatwiaosn basedon reasonableIHPLC retentio=ne andpre&cted=ss spectrometerresponse.Am*dcal*Wb',&L@@le inthestudybindermaintainebdy FACT. Despitethematased detectiobnnutsthatresultefdrom thesmallsamplesize,several were detectedind= seramzmlcs. PFOS, PFHS, PFDS, POAA, and M463 were detectedinewh ofthemmples analyzed,fortheseanalytest,heestimatedetectiohnnut is3 ppb. PFOSAA, M556, and NB70 were detectedinsome ofthemniples and thedetectionEn-dtisestimatedtobe approximately5 ppb. PFOSA and M513 were notdetectedinarrysampleabove theestimatedetectiolnimitof8 ppb and 12ppb,respecfively. The averagePFOS concentratiownas 54 ppb,coveringa rangeof31-115ppb. Thesevaluesaresliertly higherthantheaveragevaluesobservedpreviouslfyoradultsand some partofthat(upto lop/om)ay be due touripmvementstothemodifiedmethod usedtoexti= d= samples. The averagePFHS leveldetemiinedinthesesampleswas 35 ppb acrossa rangeof5-100 ppb. Ibisaverage isapproximately10 timeshigherthanthelevelspreviousloybservedina miau setofadultserasamples.In thosesamples,thehighestvaluedctemiin@ ina non-3M workerwas 13ppb. Itisunlikelythattheminor' mochficationmsade tothearmbrbcalmethod couldaccountforthisdramaticdifferencbeetween thetwo groups ofsamples. Althoughrigorousqualitcyontrolnimmm and 3M EnvironmentalLaboratoryStandardOperating Procedureswere followed,theacqtusitioonfdus datawas notnecessarilcyollecteadccordingtoapplicable Good LaboratoryPracticesT.his dataisnotsuitablfeordstnbmon toanygdvenunentagencyindefenseof productsuitabiliotrysafl-tDya.ta presentedhereisthehighestqualitdyataavailablaetft time. ................................................................................................................................................................f...............;..............................................................................................................................................f........................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................... ............................................................................................................................................................................................................................................................................. On 4/27/99,Jean Burrisof3M OccupationalMedicinedeliveresderasamplestotheEnvirorunentaLlab. EnvironmentalLab persoruieilnitiataedchain-of-=ody upon receipotfthesamples. ...................................... .......... 0 )tk. . ........... . ....... ......... There isno holdingtime aiteriassociatewdiththesesamplesforLC/ESMSMS analysis. REPORT DAM: 05t2l/99 EVVIRoVA,11,.'L,@%,41T3.O-RI4LTORY I?FPOI?T,VF(AJC.T.(.;EA(I-Ol M4dh ods.-AnalyticaanldPre@di@atory. Analyticmaelthods ETS-&4.0, Extractionof PotassitunPerfluorooctancsuLfonatocr OtherFluorochcmicalCompounds from Senim or Other FluidforAnalysisUsing HPLC-Electmspray/N4assSpectrometry MODTMD toaccommodate mWI swnplc size.Reagentvolwnes were reducedand aqueousexn= were triplreinsedwith MTBE. These modificationmsay resulitnslightlbyetteranalyterecoveriesthan thoseachievedusingtheorig4W methocl ETS-8-5.0,Analysisof PotassiumPerfluorooctanesulfonaotreOther Fluorocheniicaoln Senun or Other FluidUsing HPLC-Electrospray/Nbw Spe=mctry MOD= forPFHS determinatiobny comparing PFHS samplesresponsetoPFOS curves,asno slvxiardPFHS was available.Tlussubsuwfionislikelytoresultina slighLtTNDER ezmaum of PFHS levels. Sample preparation - aqueous samples, BPLCIESMSMS: ion-pairingextraction Amlyte iswcftwted from-wmnipre matrix with Y"-.g redgw*ueftwtyl==mum hydrogenstiffn (rBA)jm apH-wrilroUeadmmrirnea The catiomrceagenstelectrvdtyargetasmomc Once theaiuori-TBApairisformed,theanalyteisnansfen-edmto a non-polarorgai= sohmt (methyl-tert- butylether)d,ried,and reconstituteidnmethanolforMS analym. BPLC/ESMMS: fordetaijedqualitativweork In BPLC, an aliquotof== isinjecteadnd passedthrougha reversephase liquidchroniatogrdpnc colmnm Based on theaffinitoyf themalyte forthestationarpyhase in thecolu= relativteotheliquid mobile phase,themmlyte isretainefdora dmmctumc amount oftm. For comple, ina standard solutionPFOS may eluteat8.0niimtes. Retentiontimesbetween a zwdard PFOS solutionand the analyteextractedfrom serainthisanalysiswere matched on theBPLC Sys= tovnthm 1*/o. FollowingIHPLC separationE,SMSMS providesa rapidand acmrte means foramlymg a wide rmp of organiccompounds, includingfluorochemicalsE.lecUDspray,an ionizatiotnechniqueused primarilyfor detectionofmolecularions,isgenerallyoperatedatreLUmly mild tmnpw&=. Moleculesareionized, and a primaryioxic,haracteristoifctheanalyte,isselected.This ionisbombarded with high-encru gas; subsequentcoffisonscmge smallersecondaryiomc fragmem unique totheprlmaryion,which are detectecl For example,forPFOS (CSFI7SO3) analysisi,on 499 isselectedas thechmictmisticprimaryion. This ion isfragmentedintootherionssuch as 80 amu (correspondingtoS03), and 230 am (C3F6SO3). Each of thesesecondaryfragmentsisdetectedand can be used todlfferendatPeFOS from odw cornpom& that nugbt have thesame chamcta=c 499 anm prunaryioiib@ut dff=nt chermcalcompositionsand secondaryion fragnmtationpaw=. .. ............................................... ....................................... ............................ ................ 5.1 Calibration For quantitativedeterminations, a niid-level,extracted matrix calibrationcheck standard is analyzed every 5 samplestomorutorinstrumentadlriftCalibratiocnheck=xLv& arecomPUM ifirl@ental responseiswithin+/-10% of theexpectedvalue. Quandtatioonf thetargeatrml)leissbasedon linearregressioanalysi(sweightedI/x)oftwo OcU=ed matrixcurvesbracketinegachgroupofsamples.Quantitatiofneachanalyteisbasedon theresponseof one ormore specifidcaughterionsusingthemultiplreesponse-moritorimnogde ofthedLsV=ent. REPORT DATE: 05/21/91) jAlINVIROA(AIEVT.,II-L4B(.)M7*(JIIY REPORT IV()F.lICT-rJEA(-Ol 5.2 Blanks Two Qxtracfiobnlwks,utiliziwnagterasnmgate matrixa,reextMCtedWitheachbatchofsamples. Additionalltyw,o samplesofblankmatrixor=mgate rmti@@usedforthe&xtractecdalibraticounrves,am e.xtr=edalongwitheachbatchofsamplesand curves. BLviksarecompliantifno targeatnalyteisdetectedabovethelimitofdetectiofnora specifimciakyte.In thistudy,allblvikswem compliant 5.3 Surrogates Tetra-hydropmfluomoctm sulfonaties used as a s=pte in do armlysis.Surrogateresponseis monitoredtoconfirmgrossftLsmuT=W failure. 5.4 Matrix Spikes Duplicatema= spdm malysm uW=g allLmgd am*tm forwluchquantltmm dataisprcserftwdere preparedand ana4-zedforonecontrolamnial Forseraanalysisr,ecoveriewso theacceptable mnge of85-115% @.5 Laboratory Control Samples LaWratoryControlSamplesarenota componentofthisM*. 5.6. Sample Related Comments Due tohmted samplevolume,itwas notpossiblteoconductn=x sp&e ouhes on any ofthesesamples. AlthoughtheanT= understandinogftheanalyticnawlthocisindicattehatmbbitsmm isasuitable mmgate m=x, n=x spicestudlefsordm matrixarerecommendeclStandardniamws forPFDS and M463 were notavailablfeorcompound identificataitotnhefim ofanalysisC.ompound kknfificatiiosn basedon reasonablreetentiotnimeandmm spectradlataconsistewnitthcompound sau=m Despitetheincreasedetectiohnimtsthatresultefdrom theunallsamples=, wveml:fiuorochermcalwsere detecteidntheseseramniplcs.PFOS, PFHS, PFDS, POAA, ard M463 wem dcu=W ineachofthesamples anabrzedf,ortheseanalytmtheestimateddftmm h= is3ppb.PFOSAA, M556, andM570 were detecteidnsome ofthemmples andthedetectiolnimiitsesdnuledto beapproximatel5yppb.PFOSA and M513 werenotdetectedinanysampleabovetheestimatedetectiolnimiotf8 ppb and 12ppb,respec&dy. The averagePFOS concentratiownas 54 ppb,covedm a rangeof31-115ppb.These valuesareslightly lue= dm Ow averagevaluesobsm-vedpreviouslfyoradultsand may be due tounprovemerdstothe modifiedmethodusedto== thesesamples. The averagePFHS levedletermineidnd= sampleswas 35ppbacrossarmp of5-100ppb.7bisaverage isapproxft=ely10finiehsigherthanthelevelpsreviousloybservedina smallsetofadultserasamples.In thesesamplesfromadultst,helughesvtaluedetommed ina non-3M worker was 13 ppb. Itisunlikeltyhat theminormodificationmsade totheanalyticmaelthodcouldaccountforthisdramatlcdifferc= betweenthe two groupsofsamples. Thisreportreflectshemostaccumtedataavailablaetthis6=. .......... .................................................................................................................. ..... Samplesand e=cts willbe retainefdorfun= evaluatiori@fnecessary. REPORT DATE: 0512L/99 JAfEAfVIROiVA4r:,%LTAABLORATR)RY REPORT iVO.FACT-GEV-01I ntents ............ .................................... 8.1 Attachment A: QuantitativReesultsof PFOS and PFHS Determination 8.2 Attachment B: QualitativSeummary of FCs identifieidn Samples of Children'sSera 8.3 Attachment C: Table of FACT Acronyms 8.4 Attachment D: Chainof Custody 8.5 Attachment E: AnalyticaDlata forPFOS and PFHS detemiination . .. ...... W4. LisaClemen,Amlyd@ Chemist Date KrisHanseA PILD.,Su* Diromr Date REPORT DATE: 0512IM 6@ SeruDmata &udy ProductNumBa(Ted SuBstn=cY. kfoftix 161cdw"cvuion: A-lytwW EquW- Syst- N-Abwbwmn Sotiswi/Venion: FdenmmR-Squared Value: Slqn Y-imer". Date ofExbwtioWAnslyst: Date ofAnolpie/Anslyst: Dote ofData ReductioWAnslym; Sarnple Dots OEMI I PFOS mid PFHS Exbvdion fimmnam N/A H. Sonam ETS44. wW ETS-8-5.0 Amelia062491 Mmirm 3.2 sw iki% toam rw S" Anacbma" 3a Anadmoa Sao AftadwAnts 04rnM RWW 04r3O/99HOI OS103/99HOJ Fdwmnes Sompla geopw MMM PFOS 043099012-30 NA 0430"032-33 PWS 04309901F.30 NJ 04"M32-33 DUods- in,i/ii./i./i Senm Group Do$@ Sample 0 Edractim VoL Ratio @lethodDik H20 Rik-I 1.0 H20 Bik-2 1.0 Maim Bik RDS04289-Salk.] 1.0 RBS04289-SB[k-2 1.0 QC.250 ppb RBS04229-MS-1 0 RBS04289-MSD-2- I1-.0 GENOI 1 9394 0.3 9395 0.4 9396 0.4 9397 0.4 9398 0.4 93" 0.4 9400 0.4 9401 0.4 9402 0.4 9403 1 0.4 1 Loik OrQuwditmtim (LOQ):PPOS - 4.93nghn[,PFHS - 4.93 ?FOS Ddwtl" Factor 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Pros C~. amfml 0.00 0.0() 0.00 0.00 281 256 1 14.1 19.3 25.5 13.1 12.3 10.7 21.0 15.2 46.3 26.0 1 PFOS Rqwd" mcfal cwm 4ADL <IADL <IIDL 113% 103% 0.0312 0.0357 0.0639 0.0327 0.0352 0.0305 0.0601 0.0310 0.116 0.0744 Average rpm ugiml -*ADL 4ADL 108% 1 0.0537 IPFOS - n RSD gg& Dow. 4ADL 4AM pnm Dihdl" Factor 1 1 1 I PFIIS PFIIS A Cow. Reported me=L _ogfml 0 0.00 0 Or) 0.00 000 0.00 0.00 O.W O.OD 0.(nII 1 NS NS I NS NS --- 1"'7- -6.48 0.0144 1 1&7 00479 1 19.9 0.0498 1 5.23 0.0131 1 1.81 0.0052 1 2.39 0.0068 1 37.6 0.107 14.9 0.0372 50.0 9.17 00229 0.0269'.. 16.4 0.0469 0 16idW DetectionLimk (MDL):PFOS - 2.4rg4n4 PFHS - 2.4r*#nL "M - Pwouambowwmdknds Date EnteFe&By-. Date Valfn& Dr. OSM3/99 LAC ovzitggkjh 0/9'. 1 3M EnvironmentalLab - FluorineAnalyticaClhenistryTeam 4. APPENDIX B Qualitative Summary of FCs identiriedin Children's Sera Samples I Sample # PFOS (ppb) PFH-S (ppb) PFDS POAA M463 PFOSAA M556 ...570 9394 31 14 x x x x x 9395 56 48 x x x x x 9396 64 50 x x x x x 9397 33 13 x x x x 9399 35 5 x x x x 9399 31 7 x x x x x 9400 60 107 x x x x x 9401 39 37 x x x ** f 9402 116 23 x x x x x x 9403 74 47 x x x x x x X detected not detected estimateddetectiolnimitforPFDS, POAA, M463 is3 ppb estimateddetectionlimitforPFOSA is8 ppb estimateddetectiolnimitforPFOSAA, M556, M570 is5 ppb estimateddetectionlindtforM513 is12 ppb 3,NE[nvironmentaLlab -FluorinAenalyticCahlemistryTeam PFS' IFH-S C6Fl3SO3- PFOS C8Fl7SO3- PFOSA C8Fl7SO2NH2 Id PFOSAA C8Fl7SO2N((CH2CH3)(CH2COO))- M556 C-8-Fl7So2N((H)(CH2COO))- M5 70 C8Fl7SO2N((CH3XCHZ.COO))- _.,@,_?Za__CIOF21SO3- PFCA's POAA M513 C7FISC00C9Fl9COO- M463 C8Fl7COO- PFS = perfluorinatesdulfoante PFCA = perfluorinatecdarboxyhcacid no standardmaterialavailablfeorconfirmation; LisaA. Clemen 04127/9904:55 PM EnvironmentalTechnology & Safety Services (651)778-5568 3M Building02-3E-09 PO Box 3331 St Paul,MN 55133-3331 Fax: (651)77M176 To: KrisJ. HanserL/US-Corporate/3MIUS Kari J. Rambo/US-Corporate/3MIUS Grant A. PauVUS-Corporate/3WUS cc: Subject: GEN01 1 Sample Receipt On 04127/99we received10 specialH. samples from Jean BurrisofOcc. Medical.--Thesesamples have been givenproject# FACT-GEN01 1,Lab requestnumber Wi 724. Samples were receivedcoldand have ,.,_loan-storeIdnFreezer 9 at-20..+/1-OC-. Lisa 4le ri 14 EnvironmentalLaboratory 3MRequest Form 3M Environmental Address Laboratory I No. rues Requester Ptw" NO. . 4. Dami Date Received 935 Bush Ave. Building 2-3E-09 Proj#ctDescrOtion (4OChatacftrsMax.) )L 731 Plar4Code St. Paul, MN 55106 Attn: Sample Custodian Phone (612)778-6750 Fax (612)778-6176 (-E,/@)011 @ :)PCL -t.I, It i fi?O A _:x@ /I,(ilo I @'Ip.sM't@rhhi"sUa@'TTTS!CAA 6(d) projw? (See back sideforin5s@tucdons) DW. No.(Main) Su Acci Class/JobfPfoiW No. BE (4-)qI MUST BE CHECKED [:] Yes No .;IA 0.5 @ El 6('*; RCRACC" TSCA CWA El CAA ElSDWA MSDS ,i-t Safety Concefns/SpecialHandling Comments -i'bi J'rI)IfLE !)LtltlbifJ Togs PAR%*od @%,-jt4 SampleNo.(Range0-999) Sample Code (12Charar-teMrax) Sample Date & Time (MWDDNY, HH:MM) 0 Sample DescOption(12CharacterMax) 3M I.D.(iICharacterStock No.) COY"AW-Cak- AvaN. Date BN=to ILI Ftym 10620 P PWO While E nvironrnaniaLlob Archives Pink- Contractor Canary - Disbursentents Copies To: Chain ofCustody Record 3M Environmental Laboratory Foovn 35176 - PWO 3M FacHOV Address Coy. Staie. Zip Code 3M Proloo Tklo 3M FaCiliiy Con[aCt 3M Telephone Ntffnber 1143 1 Sampled By IPFAI) Sampler Signmiure Item Sample Description 2 3 4 5 6 7 8 9 10 Number Containers e ofeach Date Preservatives Date Time Matrix > 3M R*quesist 3M Prolfti Lead E] SamplesSplit Co 12 13 Item Relinquished By/Affiliation Time Date Shipped Via Received By/Affiliation fit study Box N 5@@ e:7a matrix ExtractionWorkshect ETS-8-4.0 SurrogateStd approx. ppm actual/ocippm FC-Mix approx.0.5 ppm actual PPM FC-Mix approx.5 ppm actual PPM FC-Mix approx.50 ppm actual PPM -le-4) Date and Initialfsor Std.or Comments 2- i, -,4j- IV :2,'@x9 q -7- Studv number whe the originalworksheet islocated. I @ank @, h A, Std# -rW-.4-J?9) amount Serum ExtractionMethod Vortex 15 sec. PipettMeatrix Volume /-f) mi PipetteI ml of 0.5M TBA, pH 10.( # - 7-77- Pipette2 mi of 0.25 Na2C-0-3/0.25MNaHCO3 buffer Std. 9!9,,1 -I-r'4e9 Dispens5eml ofmethyl-t-beuthyelr TN-A- 12---j5@-5@ Shake20 min. Centrifug:e20-25 min. 0 --o Centrifutespeed: Z@Lv 0 ML Date & Inidnis 2*&1 Puton NitrogenEvai)omtotrodryness Evaporato0r: Add methanol Volume /0,T) mi Temperature:,7 TN-A- Vortex30 sec. Filteursiniaz3cc B-D svrinecwitha 0.2gm filteirntoa 1.5ml autosamplevial MS/MSDI /-Cont.Checks:Spiked -5 uL of a -@c - ppm std fora finalconcentratioonf e*-1,1:@c, ppm. MS/tvISD usedsample SurrogateStandard:Spiked uL ofa / -. cont.Checks used same matrixas forstdcurve. ppm std toallsamplep,standards.and blanks Attachment A /LOI ETS-8-4.0 Estractioonf PFOS @','/i/.,vl 70am, c/ oo@e eel'* Page 10 of 13 e ton Nit StandardCurv---%--(;);N(IXl)u6man Sera - L)LcaiuSramples) Prep Dotefs): 4r-KM Anslyst(s): RWW SjimpleMatrix: Fluman Sera Method/ttevision: ETS-84 0 -rarxetAnslyte(!i):FC Mix (PFOS. PFOSA. PFO.SAA. ETFOSE. PFOSEA. M556) Study Number. (;E.NOII Equipment Number. FinalSolvent& TN Number McOH Blank Fluid/identifieRra.bbitSem / TN-A-2438 TN-A-2391 FC Mix Std Approx. 0.500 ppm: FC Mix Std Approx. 5.00ppm: FC Mix Std Approx. 50.0ppm: SurrogateSid Approx. 100ppm: 9WI2-29-2 99012-29-1 99012-100 99012-3-24 ActualConcentrationsof Standardsinthe FC Mix & M570. PFOS PFOSA PFOSAA ETFOSE Std Conc. ug/mL Std Conc. ug/mL Std Conc. ug/mL Std Conc. ugtml 0.500 0.500 0.500 0.500 0.500 0.500 0,500 0.500 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 50.0 50.0 50.0 50.0 50.0 50.0 50.0@- 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 PFOSEA Std Conc. ug/mL 0.500 0.500 5.00 5.00 5.00 50.0 50.0 50.0 50.0 M556 Std Conc. ugImL 0.500 0.500 5.00 5.00 5.00 50.0 ---5 500 50.07 FC Mix Am't Spiked mL 0.010 0.020 0.005 0.010 0.020 0.005 ---0.,60 0.015 0.020 All FinalVolume mL 1.015 1.025 1.010 J.0 LS 1.025 1.010 1.015 1.020 1.025 CalculatedConcentrationsof Standards inthe Sample Matrix PFOS FinalConc. ngImL PFOSA FinalConc. ng/mL PFOSAA FinalConc. ng/mL ETFOSE FinalConc. ng/mL 4.93 9.76 24 49..38 4.93 9.76 24.8 49.3 4.93 9.76 24.8 @49.3 4.93 9.76 24.8 49.3 97.6 97.6 97.6 97.6 241 249 248 248 493 493 493 493 735 735 735 735 976 976 976 976 PFOSEA FinalConc. nghal 4.93 9.76 24.9 49.3 97.6 249 493 735 976 Nam FinalConc. ng/mL 4.93 9.76 24.8 49.3 97.6 249 493 735 976 Surrogate Std Conc. ugImL 100 Surrogate FinalConc. ng/mL 500 All ArWt Spiked ML 0.005 ActualConcenuadons of Standardsin theFC Mi)L PFOS Std Conc. ug/mL PFOSA SW Conc. ug/mL PFOSAA Std Cone. ug/mL ms 5.00 MSD 5.00' 5.00 5.00 5.00 5.00 ETFOSE Std Conc. ug/mL 5.00 5.00 PFOSEA SW Conc. ug/mL 5.00 5.00 MI-@.% Std Conc. ugffnl 5.00 5.00 FC Mix AiWt Spiked mL 0.010 0.010 All FinalVolume ML 2.011 2,011 CalculatedConcentrationsof Standardsinthe Rabbit Sem(.09 mi). PFOS PFOSA PFOSAA ETFOSE FinalConc. FinalConc. FinalConc. FinalConc. nt/iqL ng/mL ng/mL ng/mL ms 625.00 625.00 625.00 625.00 MSD 625.00 625.00 625.00 625.00 CalculateCdoncentrationosf StandardsinMethanoRO.2 mi). PFOS PFOSA PFOSAA ETFOSE FinalConc. Final Conc.. FinalConc. FinalConc. ng/mL ng/mL ng/mL ng/mL ms 250.00 '-)50.00 250.00 250.00 MSD 250.00 2SO.00 250.00 250.00 PFOSEA FinalConc. ng/mL 625.00 625.00 M556 FinalConc. ng/mL 625.00 625.00 PFOSEA FinalConc. ngImL 250.00 25000 M556 FinalConc, ng/mL 250.00 250.00 GENO II ion pairshect..<Is Surrogate Std Cone. UZIML 100 Surrogate FinalConc. ngtml 50 Surrogate Std Conc. ug/mL 100 Surrogate FinalConc. ngImL 200 All Am't Spiked mL 0.001 All Aaft Spiked mL 0.001 FACT: DATA RENIEW SUTNINIARI- FORNL Date: Analyst: FACT Study Nundw Matrix 7=4 Points Dilutions? -CIC Ar T Rw L-OQ-W Wo daftset 4 Re.@@ fm,MM tOW? Analyte 4: AcceptableLinearRineI@t_oi:-'y 7 LOQ forthisdataset: Pc-cvguatfoodrdifferr==tp? A)e Aubft 5: T set R*4vabuded fordiffamd r=V? A=4ft 2: Acceptable T Rmpi LOQ forthisdda set Re-cvdwftd for&ffa=t ranp? Awbft 6: le T -in Rxap. LOQ forthisdataset Re-evaluatedfordiffaent r4lP? Analyte3: AcceptableT Rmp@ LOQ ford@s &a set f r-A-F fo7r: got. ri 4 --3-i-z@-isr6AAcr=cpepUtableT-iinew I 4 LOQ f" d@s da ut Re-evali,,,tfWordiff=vw rmgc? Ajd Re or diffemtruge? Jk&4I1f1-t/rompound g..pi. L:;Ed L@st l@d L , "La*sttr@dmod fied: J.ID Cd. SU@ry 144port C@\MASSL.VNX\r&ta2.PPCISanpl*DD\04309961 "on may 03 06:46:38 1092 C: \MMSLYMX\rat*2. MCV"t"9\043099& man may 03 07;33:37 1999 PrLntod: man may 03 07:34:31 1999 Compound 1: PRHS I tj@ ..L.1 4 ',-#--1,4 -1 '#9" .4@ .4 CJ990()9 .4,IJ99()'.Ij @43,j99Oll -j99012 .41,.99()'.3 ;,9.ji: 4 i@,3190: .4 @-',')9,ii _,t' 49c, I 4 991":"@ @,49,::-. 4...99rizi i.39014 -1.990"" :4j-199()2a :9 .43,*,99029 3:. )43099030 , 3. j4309903 3: )43099032 3 3 ',43099033 34 043099034 3! )43099035 '-6 )43099036 37 :43099037 3@ @43099039 3i '.,43099039 '.,43099040 :. 4. ..43-.,99041 4: :43099042 43 )43099043 44 '343099044 4! -)43099045 Samplallat Text GEN011 RBS04209-250 ppb GENOIJ ROS04289-250 ppb HOOM Blank HOOH Blank CE.4011 GEN011 GE4011 GENOII GEN011 GENOII GEN011 GEN011 GENOIJ GENOIJ ASS04209-WBI&nk-I RBSU4289-SBI&nk-I ASS04209-5 ppb-I RBS04289-10 ppb-I RBS04289-25 RBS04209-50 RBS04289-100 RB$04289-250 RBS04289-500 ppb-I ppb-I ppb-I ppb-I ppb-I R8504209 -750 ppb-I HOOH Bl&nK M*OH,Bl,arkk ENO "504209-USI&nk-I GENOII, 9394 10.09 ALL) GENOIJ. 9395 (0.07 OL@ GENOII, 9396 (0.08 ILLI GENOII, 9397 (0-07 ALL) GENOI!, 9390 (0.07 ALI GENOII ROS04289-50 ppb-I H*OH Blank -GENOII RB$04289-KRI&nlt-l GENOIJ. 9399 CO.07 aL) GENOII, 9400 (0.07 UL) OFNOJI, 9401 10.08 UL) GENOIJ, 9402 10.08 aL) GEN011, 94003 AL) GEN011 PZS 428(90--5007 ppb-I GENOII -GEN011 GEN011 PLB504209-250 R8304209-250 RBS04289-50 Ppk), KS ppb. MSD ppb-I HOOK ank GENO,!lRB304269-WBI&nk-2 GENOII GEN011 GEN011 GENOII GENOLI GENOII GEN011 GENOII GENOII RBS04269-SBI&nk-2 RBS04209-5 ppb-2 RBS04209-10 RBS04299-25 RBS04209-50 RES04289-100 ppb-2 ppb-2 ppb-2 ppb-2 RBS04209-250 RBS04209-500 RDS04289-750 ppb-2 ppb-2 ppb-2 PageI Type Analyto Analyto Anslyto Analyto Analyto Analyto Standard Standard Standard Standard Standard Standard Standard Standard Analyt* Analyto Analyto Arialyto Analyto Analyto Artalyto Analyto oc Analyt* Analyto Analyto Analyte Analyto Analyto Analyt* oc Analyto Analyt* oc Analyte Analyt* Analyte Standard Standard stan"rd Stan" rd Standard Standard Standard Standard std cone ItT 4.735 4.720 4.93 9.76 24.60 49.30 -97.60 248.00 493.00 735.00 4.691 4.697 4 .491 4.677 4 .. 699 4 Goo 4.486 49.30 4.689 4..677 4 $02 4.406 4.483 4.705 49.30 49.30 4.705 4.689 4.696 4.693 4.695 4.697 4..696 4 $91 4.706 4.93 9.76 24.80 49.30 97.60 246.00, 493.00 735.00 4.699 4.702 4.706 4.697 4.694 4..614 4 701 Ace& 473 521 conc. 199.93 220.14 riage bb bb ID&V 26 8.35 m -14 so 23.01 m -1 126 51.29 M 4 225 09.51 bb -8 613 259.77 MN 5 1107 4')0.97 M -4 1724 735.29 MM 0 216 $9.73 M $37 226.99 bb 634 --26"1 bb 177 73.01 M 70 27.10 14K 239 36.93 m 15 30 10.61 m Is 35.00 M Ilse 505.91 mm 479 202.49 M 300 125.96 bb 527 222.75 M '130 52.97 M 7 679 208.14 MM 651 276.12 M 243 59.43 M 19 35 12.27 MN 26 60 23.21 bb -6 127 51.86 M14 5 243 101.25 M 4 543 222.05 NK -7 1279 501.72 MM 2 1774 756.56 NK 3 6wt vs A-61&4 062499: "@iood and quantitated by haj 5/3/99 Ou@nt&fy Compound S%M@RY ROPOCT S&Apie Lisftk: : WOt @dL ad thod: -La.1 M*dLfL*d: i.r, Code C:\MASSLYNX\rata2.pm\smWleDskC43092&1 HO "&y 03 04:40:30 1999 C:\KUZLYWX\rat&2.PRO\MothDS\043099& Mon May 03 07:33:57 1999 Pr,,.Lod. "on may 03 07:34:31 1999 Compound 0 N@ 2. PFOS i-. .'4 '..1 4 :4 4"..l ;431.491j.@9 - @4J:,199t; 1.1 1 -43 99,j',@ -3 -43-j99013 .4 *.43rj99014 )4 3-)990*.5 )43099016 )430990!7 6 '343099018 19 1)43099019 20 043099020 21 043099021 22 043099022 23 043099023 24 043099024 121@:043a"025)43099r,26 .43.)990,17 43-'99@*29 1 4 3..*49--,@3 4;;.:@9@: S'. ')9-3: 4 99-.23 3,i .4 JC-99C.j4 43 )9@.3-4 -."99.@3,i 4 3.."99,@3:,3.:99@ 3i z '.43.,'99@29 : 143099,j4O "43rj99C,4'. '.43C)99()42 41 '43099043 4.; ')43099044 45 3,309904.- SampleliSt Text jENOI; RBS,j4289-250 ppb ;ENO'. RBS-;4209-250 ppb HOOH Blank M*OH Blank GENOII ROS04209-WBlank-I GENOII RBS04289-381&nk-I GENOII GENOII RBS04289-5 ppb-I RBS04289-10 ppb-I GE0011 ASS04289-25 ppb-I GENOII RBS04289-50 ppb-I C E N 0 11. RR:S042::- 100 ppb-I GENOII GENOII GENOIJ S042 -250 RBS04289-500 RBS04269-750 ppb-I ppb-I ppb-I HOOK Blank NEOM Blank GEN011 RBS04209-WBlank-I GZN011, 9394 (0.09 ML) GEMOII, 9395 10.07 &L) GZN011, GEN011, 9396 9397 10.08 oLL) 10.07 &L) GEN011, 9396 (0.07 aLL) GENOII RRS04209-50 ppb-I NOW Blank GENOII RBS04209-WBI&nk-l-,GENOIL. 9399 10.07 nkL) GEN011, 940C (0.07 oLL) GENOIJ, 9401 40.08 aL) GENOII 941)2 @0-087 mL) GENO 11: 94 03 0.0 mL) GENOI: RBS04289-50 GENOII RBS04299-250 @3ENO 11. RBS0421g-250 ppb-1 ppb, MS ppb. NSD GENOI! RBS04299-50 ppb-I MOOK,B@,;nk ENO BS04209-WB!ank-2 GENDII RBS04269-Salank-2 GENOII FLBS04299-5 ppb-2 GEtiOl! RBS04209-10 ppb-2 GEN011 R8504289-25 GEN011 RBS04209-50 ppb-2 ppb-Z GENOII RBS04209-100 ppb-2 GEN011 ROS04289-250 ppb-2 GEN011 RBS04209-500 ppb-2 GEN011 RBS04289-7SO ppb-2 Page 2 Type Anslyto Anslyto Analyto Analyt* Analyto Analyto Standard Standard Standard Standard Standard Standard Standard Standard Analyto An&lyto Analyto Analyto Amlyto Analyto Analyto Analyto oc Analyte Analyto Analyto Analyto Analyto Analyt Analyt* oc Analyte A"lyt* oc Analyto Analyto Analyto Standard Standard Standard Standard Standard Standard Standard Standard Std Cone ItT 5.283 5.267 4.93 9.76 24.00 49.30 97.60 240.00 493.00 735.00 S.254 5.237 5.244 5.239 5.249 5.259 5.250 S.255 49.30 5.201 5.240 'S.249 5.250 5.233 5.259 5.251 49.30 49.30 5.256 5.239 5.244 5.240 5.245 3.248 3.246 5.236 S.256 4.93 9.76 24.80 49.30 97.60 246.00 493.00 735.00 5.250 5.240 5.252 5.252 5.265 5.245 S.253 5.249 Ar" 5941 6144 Cone. 186.42 196.10 rlags bb bb ridev lit 314 819 1551 2995 6950 12095 19202 4.71 bb 9.61 bb 25.76 bb 49.17 bb 95.39 bb 221.89 bbX 412.06 bbX 613.79 bbX 24 453 623 oil 423'- 399 1459 0.33 MM 14.06 bb 19.48 bb 25.51 bb r3.09 bb 12.33 bb 46.24 bb 347 $71 489 1461 027 1591 7594 6928 2600 10.60 bb 21.04 bb 15.21 bb 46.32 bb 26.04 bb 50.46 bb 242.50 bb 221.18 bb 50.75 bb -4 -2 4 0 -2 -11 -16 -16 - -6 2 3 176 319 765 1554 3135 6634 13256 19100 5.19 bb 9.77 bb 24.03 bb 49.20 bb 99.86 bb 218.18 bbX 423.61 bbX 610.79 bbX 5 0 -3 0 2 -12 -14 -17 LAL -lia 062498: Revio-ed and quantitated by h*3 3/3/99 QuantLfy C*W4MUnd SU@RY PAPOCR gmgle List: c;\MASSLYNX\C&t*2, pw\smpl&DB\043099&1 L.St @d&ftod: Man WAY 03 0, :49:36 1999 me thod: C: \rASSIVM\C&tg2. VM\iftthD\043099& L.St @d, fted: men May 03 07:33:57 1999 job Cod&: Prtnt.d. Man may 03 07:34:31 1999 C@@wound N 3 PROS 4,- 494)(11 41,)990,)9 0 --43'j9901@ .3 -,43099013 .4 IJ43099014 t -143099015 IJ43099016 043099011 ii C-43099010 9 )43(j99019 @,43099020 (,43099021 @2 )43099022 3 )443099023 ,'4 0 3099024 2r$,,ti*7099M- 26 ')43099024 )43099021 :@430990@'$ 430990290 43,,99"3 17 -1,9031 cS,,'32 4 '--')9,,33 ;j,.99C,34 99C.35 @991;36 ,421 99-('3' ,i 43'".,99031 19 @.t3,@9-@39 4, 143' 99040 4 1. C,43'.919041 4: @43'1,99042 13 )43099043 44 ')43099044 45 043099045 samplolist Text ILNOI! PBS.,4Z49-250 ppb ZLN-J'.*F.kB.--4:v9-250 ppb " anx "m:'OH:*',ank GEN-)II RBS,)4209-WBiank-I GEN011 ROS04299-SBI&nk-I GENOIJ ASS04289-5 ppb-I GENOIJ RBS04289-10 ppb-I GENOIL RBS04299-25 ppb-I GEN011 FLBS04299-50 Ppb-I GEHOJJ RW04289-100 ppb-1 GEN011 RBS04289-250 ppb-I GENOIJ RBS04289-500 ppb-I GENOJI [kBS042$9-750 ppb-I MOON Blank MOOH Blank GENOII RDS04299-WBI&nk-I GENOII, GENOIL, GEROII, 2394 (0.09 SL) 9395 (0.07 aL) 9396 (0.04 mL) GEROJI, 9397 90.07 ML) GENOIJ, 9398 (0.07 UL) GEMO 1 1IRBS 04229-30 ppb-I mook 2 ank 'GENOIJ RB$04229-WBlank-I GENOIL, 9399 (0.07 &Li GENOIJ. 9400 (0.07 ILL) GEN011, 9401 (0.00 ALI @EN01i 9402 (0.070 ALL) @EMOll: 9403 tO.0 EL, GE)1011 ASS04299-SO ppb-I GENOI! RBS04289-250 ppb, KS GENOII RBS04289-250 ppb, KSD GENOJI RBS04289-50 ppb-I Meog,!l&nk GEN RBsO4289-Mblank-2 GENOII RBS04289-501&nk-2 GEN011 RBS04289-5 ppb-2 SENOIJ FtOS04289-10 ppb-2 GENOII GEN011 GENOIJ ROS04299-25 ppb-2 ROS04289-50 ppb-2 P.BS04209-100 ppb-2 GENOII RBS04209-250 ppb-2 GENOIJ R8504299-500 Ppb-2 GZNOJI RBS04209-750 ppb-2 Type Analyto Analyto AA lyt: An:lyt Anslyto Analyt* Standard Standard Standard tandard Standard Standard Standard Standard Analyt: Anslyt Analyt Analyt: Analyt* Analyto Analyto Analyto orAnalyt* Analyto Analyto Analyto Analyto Analytis Analyto ac Anslyt Paalyto QC Analyto An&Lyte Analyto Standard Standard Standard Standard Standard Standard Standard Standard std cone R? 5.459 5.641 4.93 9.76 24.60 49.30 97.60 248.00 493.00 735.00 41.10 5.553 5.590 5.644 5.654 5.626 5.632 5.703 3.479 S.491 5.627 5.649 .31:131 929 49.30 49.30 5.480 5.614 5.643 S.617 5.641 5.647 5.639 4.93 9.76 24.00 49.30 97.60 248.00 493.00 735.00 5.626 5.639 S-590 5.648 5.525 Are1&2 23 conc. flags %DOV 65.74 bb 342.31 bb 10 6.72 bb 13 07.16 mm 21 4'y.01 bb 19 249.53 bb 29 499.12 bb 34 632.03 M 50 1030.72 bb 16 174.76 m 4 0.00 bb 26 428.39 bb 20 --241-.-40 bb 1440.50 bb 6: 0.00 m 6 0.00 m 1 0.00 bb 23 .344.15 bb id 178.86 bb 22 320.33 bb 46 943.73 bb 23 341.64 bb IS 140.95 bb -is 77 -52 1 I -14 -100 16 174.77 bbX 255 13 106.26 M 9 23 35S.64 M 43 28 473.47 M -4 39 762.37 M 4 Page 3 lia 062490: Reviewed and quantitated by hal 5/3/09 Quantkfy CA&Lbration RSP*rt Cal&bratL@ : C:\K'4&SLYNX\CatS2.PIRO\Curv*D\043099& at modtftod: Mon may 03 07:34:03 1999 m@ may 03 07:36:44 1999 Compound I name:PFHS Coefficienotf Determination:0.998313 Calibratiocnurve:2.33693 * x + 6.12110 Response type:ExternalStd,Area Curve type:Linear,Origin:Exclude,Weighting:1/x,Axis buns:None 1.77e3 Page 25.7 %Conc -14.4 0.0 100.0 200.0 A"Lka 062499: Revis@ed and quantitated by haj S/3/99 306.0 400.C 56b.0 600.0 Conc 700.0 Q-u@-n-LLCCY&Lgbrat&on Report CaLLbrat,on: C@\NMSLYNX\rat 2.VW\curveDE\043099& l@at W@JLCLSO; "On ms, 03 01:3::C$ 19 PrLnEed non May 03 07:36:44 19 Compound2 name:PFOS Coefficienotf Determination:0.998987 Calibratiocnurve:31.2623 * x + 13.4094 Response type:ExternalStd,Area Curve type:Linear,Origin:Exclude,Weighting:I/x,Axis transN:one 2.3Oe4 Paqe 2 0 5.26. %Conc -16.90.0 100.0 200.0 AWAIL& 062490: Revie.ed and quant.Ltated by he) 5/3/99 300.0 400.0 506.0 600.0 Conc 700.0 Qu..V.,Ey CALLbration ROPOct cal'bratl@ : t w@dit,od@ IPr-:.td C:U",Lyllx\;st&2.PRO\Curv*03\043099S "an Ka., 03 0 :34:03 1999 mn may 03 07;36:44 1999 Compound3 name:PFDS Coetlicienotf Determination0:.955785 Calibratiocnurve:0.0390723 * x + 9.30435 Responisetype:ExternalStd,Area Curve type:Linear,Origin:Exclude,Weighting:1/x,Axis transN:one 39.1 Pa3ge Respmmf z " 01 255, %Conc -64.8.0.0 100.0 Amelia 062499; PAv&owed and quantltatod 200.0 by hol 5/3/99 300.0 400.0 --7'506.0 600.0 Conc 700.0 ou&,,tity Compound (cf-7 Summary Report S@PL. Li,;t@ : C:\ ""SLYWX'\rat&2.Pno\ wp eos\043099al L..'.@l L-J men Kay 03 06:46:39 19:9 I th-I C: \M"SLYNX\rat&2. PM\HathDB\04300a L.aa t wad, fked: mon Kay 03 07:33:57 1999 I-ob Code iPrLnted; Mon 14&y 03 07!40:Sg 1999 Compound 1: PRHS I N@ 4 $1 :)91)001 4 4 1 4 31)19"9,"J.14 4),)99u 5 .j j.443l-V).919)OU960(07) 4 3:@ 990 8 9 1143 99009 Ili @43099010 .43(,99011 2 ',43-)9901.,' ;2 .41-,9191)13 1.4 4 ii,)@9-)14 4 @,9clu15 43.1491*1"ti .i 4"!.99ul - 4 1 -99,)19 2-'- , 4 3- 0 9 C,2 0 1: :43:,99021 j.' .43,..-99,)22 ti @41-.,49,323 .4 .43 99024 -a!r-@4@*, t-, 2i *4-:99,j-"6 2@ :4;099021 21 431)::0299 29 30 43;)990%3)02 0430 31 043099031 32 043099031 33 N3099033 34 )43099034 35 )430:903S 36 0430 90 36 37 -@43099037 30 043099038 39 )43099039 40 )43099040 41 43099041 42 ',43099042 43 43099043 44 )4'3099044 45 43099045 Samplelint Text GEN011 ABS042a9-2SO ppb GEN011 ROS04209-250 ppb "*ON Blank m ON Blank G;mo GtNoll GENOIJ RBS04209-WOI&nk-I R :042:9-9 lank-I R: 042 9-Sappb-1 GEN011 RBS04209-10 GEN011 RBS04299-2S GENOII ROS04299-SO GENCII RBS04299-100 GENOII RBS04209-250 GENOII ABS042a9-500 GEN011 RBS04289-'750 m:OH :lank N OH lank ppb-I ppb-I ppb-I ppb-I ppb-1 ppb-1 ppb-1 GENOII GENOII, GEN011, GENOIJ, GENOII, RBS04289-WBI&nk-I 9394 (0.09 &L) 9395 (0.07 OL) 9396 10.00 nL) 9391 40.07 AL) GEIIOII. EL) GENQII R995,::.;,9:'s'Cppb-I MOOK Blank GENOII RBS042B9-WBI&nk-I GENOII, 9399 (0.07 aLL) GEtGll, 9400 tO.07 &L) GENOII , :,4,002",.0:*: t, GGEENNOOIIII, 1403 ICI.007 MMLL) GENOII RBS04219-SO ppb-I GENOII GEN011 RBS04289-250 RBS04289-2SO ppb, NS ppb, NSD GEN011 RBS04289-50 ppb-I M*OH,Bl,ank ENO ILBS04289-WBI&nk-2 GEN011 IkBS04289-SBlank-2 GFN011 FtB$04289-5 ppb-2 GEN011 GEN011 ROS04289-10 RBS04289-2S ppb-2 ppb-2 GEN011 RDS04289-50 ppb-2 GEN011 RBS04209-100 R)b-2 GEN011 GEN011 RBS04209-2SO ASS04209-500 ppb-2 ppb-2 GEN011 RBS04209-7SO ppb-2 Type Analyto Analyto Anslyto Analyto Analyto An&lyto Standard Standard Standard Standard Standard Standard Standard Standard Analyt: Analyt Analyto Analyto An&iyto Analyto Analyto Anslyto ac Analyto Analyto Analyto Analyto Analyt: Analyt Analyt* oc Analyto Analyt* ac Analyto Analyto Std Cone RT 4.73S 4.720 4.93 9.76 24.90 49.30 97.60 248.00 493.00 735.00 4.691 4.697 4.691 4.611 4.619 4.600 4.686 49.30 .4.689 4. 67'7 4.642 4.416 4.685 4.705 4. 644-- - 49.30. 49.30 4.IOS 4.689 4.696 4.693 4.69S 4.697 4.696 4.691 4.706 ASnt&alndyta*rd Standard Stan"rd Standard Standard Standard Stan"rd Standard 4.93 9.76 24.80 49.30 97.60 248.00 493.00 735.00 4.699 4.702 4.704 4.697 4.694 4.664 4.701 Ar" 473 521 Conc. 199.93 220.14 riag& bb bb IDOV 26 60 126 215 613 1107 1724 8.35 mm 23.01 NK 31.29 NK 89.Sl bb 259.77 M 470.97 MN 735.29 M -14 -1 4 -0 -4 0 216 09.73 m 337 226.99 bb 636@.- 2".Sl bb 17 73.02 M 70 27.16 M 139 54.93 M is 50 18.91 NK as 3S.00 M iiss SOS.91 m 479 202.49 NK 300 12S.96 bb 527 222.75 M 130 S2.97 M 7 679 289.14 MK 451 276.12 M 143 SO.43 NK 19 35 12.27 MN 26 60 23.21 bb -6 127 Si.86 NK 5 243 101.25 NK 4 543 229.95 M 1179 SOI.72 NK 2 1774 7S6.56 M 3 Page Amol&a 062490: Reviewed and quantitated by hoi 3/3/99 @Y3(-i7 f-i :,vW*.nd Summary R.P*tt LL;t. . C:\M"SLYNX%rat.2.pno%SamplooB\043099&l Last malt &ad Man Key 03 06:41:39 1999 Method C:\KUNLYNX\rats2.PRDV%thD*\C43O29a Last @@d&fL*d' Job rod.. Mon May 03 07:33:57 1999 PrLnted Mon May 03 07:40:56 1999 Compound 2: PFOS 01 PIWA : ..,4 );;790-jI 3 n 4) 99002 43r)990,)3 4 43fj99Ou4 S .)43.j99005 -i .)431)99006 .43r,990t)7 ,@4*j.l)q900: 9 43 9,40,) j j43,,99010 i: j,4@-' 9:,J*,I '.I 43-,9 )12 13 )43r,99013 14 -)43.'j99014 15 :4*--.-99015 '.43r.99016 @41(.490111 )43,,9913 fj .43.99-..19 2-1 !,43,;99020 2. 4 3-.99,)21 2, 43@99i)22 3 :4.@-99023 24,.,@@ZL-! ".. 44.11:t 'e 4z '49@126 @43,@99029 3C )43-@99030 31 '.-43j99031 32 043099032 33 043099033 34 043099034 35 00 430:9035 36 430 9036 37 343099037 38 043099038 39 043099039 40 043-)99040 41 1?43099041 4; .)43099042 4 43099043 44 CP43099044 45 )43099045 Smpielxat T4kxt GENOll RES04289-250 ppb GE Oll ARS04289-250 ppb M :OH 3,lank ON Ian GENCII RES04289-WBI&nk-I GEN011 RBSO:2:::5351&nk-I GENOII RBSO 2 ppb-I GEHOJI ROS04289-10 ppb-1 GEMOII RaS04289-2S ppb-I GENOII RBS04209-50 ppb-I GE140111 GEN01 R:SS042:9-100 ppb-l R 042 9-250 ppb-1 GENOII R3304209-500 X6-1 GEN011 RBS04209-750 ppb-I "*ON Blank M*OM Blank GENOII ROS04299-VB1&nk-I GFNOII, 9394 (0.09 KLI GENOII, 9395 (0.07 iLL) GWOII, 9396 (0.08 &L) GENCIL, 9397 10.07 &L) GENOII. 9398 (0.07 aL) GFN011 P.BS04209-50 ppb-I HOOM Blank GENOII R5304289-MBlank-I GENOII, 9399 10.01 aL) GEN011, 9400 10.0'7 aLl GENOI., 9401 10.00 EL) GENOII, 9402 (0.08 AL) GEN011, 9403 10.07 &L) GEN011 RBS04209-50 ppb-I GVX011 RBS04299-250 ppb, US GEHOII RRS04209-250 ppb, NSD GENOII RDS04299-50 ppb-1 M*OHIBI1&rLk GENO RBS04289-WBI&nk-2 GEN011 RES04289-Sblank-2 GEN011 GEN011 RBS04299-5 ppb-2 ROS04219-10 ppb-2 GEN011 "S04209-25 ppb-2 GZNOII RBS042::-5:oppb-2 ppb-2 GENO 11 RBS042 -1 GEN011 RRS04289-2SO ppb-2 GENOII RBS04289-500 ppb-2 GEN011 RBS04209-7SO ppb-2 Type Analyto Analyto An ly An:lyt Analyt: Anslyt Standard Standard Standard Standard Standard Standard Standard Standard Analyto Analyto Analyto Analyto Analyto Anglyto Analyto Analyto oca An lyto Analyto Analyto Analyto Analyt* Analyto Analyt* oc Analytt Analyto oc An&lyt Analyt* Analyt* Standard Standard St&D"rd tandard :t-ndard Standard Standard Standard Stci Cone RT 5.203 5. 2 6'1 4.93 9.76 24.80 49.30 91.60 248.00 493.00 735.00 5.254 5.237 5.244 5.230 5.249 5.259 5.250 5.255 5.281 .5.240 5.246 5.250 5.233 5.256 4@l,:k!_ 5.251 49.30 49.30 5.256 5.239 5.244 5.240 5.245 5.240 5.246 5.230 5.256 4.93 9.76 24.80 19,1:3* Go 240.00 493.00 735.00 5.250 5.248 5.251 15 :212 265 5.245 5..253 5 249 AV" 5841 6144 Cone. 215.01 227.13 riago bb bb %Dov 161 314 019 1551 2995 6950 12$95 19202 3.29 bb 9.02 bb 21.91 bb 55.29 bb 109.34 bb 257.30 bb 419.71 bb 715.64 bb 24 0.00 MK 453 14.23 bb 623 20.57 bb III--- 2?.Sl bb 423 13.09 bb 399 12.21 bb 51.06 bb 347 671 489 1461 827 1591 7594 6928 1600 10.27 bb 22.38 bb 15.57 bb 51.95 bb 28.23 bb 56.80 bb 291.40 bb 256.46 bb 57.14 bb -33 :3 12 12 4 -3 -3 3 I 176 319 745 1151 313S 6834 13256 19108 3.05 bb 9.21 bb 25.19 bb 1 35:12 bb 57 14 bb 252.96 bb 493.22 bb 712.14 bb -22 -6 4 12 17 2 0 -3 Page 2 LAL A@I&A 062490: Rovio@ed and quantitated by he) 5/3/99 Qu&nt.Lt,/Compound Summry ftport S.Pple L,st C:\MASSLYN \r t:2.PltO\SmWleDB\C43O99Bl L:gt wAxiLfLd: Mon May 03X*ga 3 1999 t.t,W , C:\MA53LYMX\rat4.2.::,@\NethDB\043099a La r.mod ftod: t4onKey 03 07:33:37 1999 'Job Code Printed Mon May 03 07:40:56 1999 Compound 3: PRDS t @a" r)44:lu')90201 2 ..,j4rj.91990.) 4 1)41"9191'00.00.43 043" 5 6 -j43 29006 7 -4!1.1 @l9@lu) :4 .43 9 u09 .43-'-99010 1' 4 1 ')9012 1.3 0431,99013 14 u43rj99014 1 c -)430:9015 .6 )431;90 6 l'? ,j43IJ9901'7 14 )4 19 ',433"';999aqO!9 2, )43-@99020 .43.;119021 @43 '991.,2,' 4J ',99-)23 4i :6 43"990,i z- , '6 43.99QZC29 "4,. 91)29 3 4 3,,99-@30 3. 43(,99031 32 .,,3099u32 33 )43099033 34 (J4301111034 35 043099035 36 043099036 37 043099037 30 043099030 39 043099039 40 043099040 41 0443099041 42 0 3099042 43 043099043 44 1343099044 45 043099045 Samplelist T"t GENOII ROS04269-250 ppb GENOIJ ROS04289-250 ppb Mm:OOHH 1.n.k" GEN Oll Rt:SS042:9:WBla,nnkk:lI GENOII 042 9 SOi GENOII ROS04209-5 ppb-I GENOII ROS04299-10 ppb-I GENOII R9504209-25 ppb-I ROS04289-50 ppb-I GGEENN0O1J1I RBS04299-100 ppb-I GEN011 RBS04289-250 ppb-I GENOJJ IkBS04209-500 ppb-I GENOIJ RDS04209-750 ppb-I M:OH :1:,nk ON 1 ic GENOII RBS04209-walank-I GEN011, 9394 90.09 aLl GEMOII, 9395 tO.0-1OL) GEN011, 9396 tO.08 OLL) GENOIJ, 9397 10.0'7ML) GENOIII 9399 (0.01 "1 GEIJOII RU04269-50 ppb-I M*OH Blank GEN011 RBS04299-WBlank-I GENOII, 9399 10-07 ML) GENOII, 9400 40.07 AL) GE O0 ll: 9401 0.0: SLI1 GEN" 11 9402 1.0.0 3LL GEN011, 9403 10.07 SLL) GEN011 GENOII GENOII ROS04299-50 ppb-I P.BS04209-250 PPb, NS R3504299-250 ppb, NSD GENO'll P.BS042:9-SO.Ippb-I MOOM Blank GENOII ItBS042 9-KB ank-2 GENOIJ ItBS04209-351&nk-2 GWOII ABS04289-5 ppb-2 GENOIJ RBS04289-10 ppb-2 GEN011 RBS04209-2S ppb-2 GEHOJI GENO 11 GENOII GENOIJ GEN011 RRS04289-50 ppb-2 RBS04289-100 Ppb-2 ILBS04289-250 ppb-2 RBS04289-500 ppb-2 RBS04299-750 ppb-2 Type Analyto Analyto Analyt: Analyt Analyt* Anal St:nYdtarod SSt nd ard t ,nndard st dard Standard Standard Standard Standard Analyto Analyte Analytt Analyt* Analyte Analyt: Analyt Aocn&lyt Analyt Analyto Analyto Analyto An lyt An&&Iyt : Analyto QC Analyto Analyte oc Analyto Analyt* Analyto Standard Standard Standard Standard Standard Standard Standard Standard Std cone 4.93 9.76 49:0300 4 97.60 246.00 4!13.00 735.00 49@.3LO 49.30 49.30 4.93 9.76 24.60 49.30 97.60 24$.00 493.00 735.00 5.459 5.641 1:113 5 590 5.644 5.654 5.626 5.632 703 -3.679 3.491 5.627 5.649 5.632 5:6529 44- 5.400 5.614 3.843 S.617 5.641 5.647 5.639 5.626 5.639 5.598 5.649 5.625 Area 12 23 Conc. 71&98 IDOV 65.74 bb 342.31 bb 130 1:72 bb 1 16 m 11 47.01 bb 19 249.53 bb 29 499.12 bb 34 632.03 M So 1030.72 bb 15 178.76 NK 4 0.00 bb 26-- 4Z$.39 bb 20 262.40 bb 46 1440.50 bb 0:0000 M m 6 0.00 bb 23 344.15 bb 16 176.$6 bb 22 329.33 bb 46 943.73 bb 23 341.04 bb 15 140.95 bb 65 -52 1 1 -14 -100 14 274.77 bbX 255 13 106.26 M 9 23 355.64 NK 43 29 473.47 M -4 39 762.37 M 4 Page 3 Iia 062499: Revxo.ed and quant&tated by he) 3/3/*9 Quantify t:aL&bratLon Report Caltbrap@Lo"n.- LAt pr&nt'd-I &ed: C; \KUSLYIAX\rats2. PW\CurveoB\0430998 "on may 03 07;40:38 Itto "on may 03 07:40:30 1999 page Compound Iname:PFHS Coef*ticiconft Determination:0.998313 Calibratiocnurve:2.33693 * x + 6.12110 Response type:ExternalStd,Area Curve type:Linear,Origin:Exclude,Weighting:I/x,Axis transN:one 1.77e3 0 25.7 %Conc -14.4 0.0 100.0 Amelia 062498: PA@xe-ed and quant&tatod 200.0 by haj S/3/99 300.0 400.0 566.0 600.0 Conc 700.0 Quant&fy ealtbc&tlon Re"ct C&Ltbr&tLan C: \H"SLT"X\rat&2. PW\Cu~5\0430$ga f,.a: Pion May 03 07:4::3: 1::: LParsnte@d-d' man may 03 07:4 :5 1 Compound 2 name: PFOS Coctlicienotf Determination0:.998238 Calibratiocnurve:26.7298 * x + 72.7186Response type:Extemal Std,Area Curve type:Linear,Origin:Exclude,Weighting:I/x,Axis bam: None 1.97e4 P&9* 2 -plo-n-s-e- 0 17.4- %Conc -33.21 0.0 100.0 200.0 AM*IL& 062498: PAVLOwOd and quantitated by hol 5/3/09 306.0 4'00.0' 500.0 600.0 Conc 700.0 -4. C: \?&"$LYNX'. rat32. PPO\MethDB\0430994.mft M, Mon May UJ 9)'7:13:S@ L9991. L : PRHS Non May t)3 0*1:53:34 1999 )Un' , I conc. ,J::r t TRACO: standards: Fd tor: tinco. factor: P"S lftne) TIC Conc. A 1.0000000, Disabled ..00000 2.000 ent Tj I! i n a* min3): 4 Enaab&led 0:40".:0 D& bled 0.584 Nearest ponst, ripd: :&--Lbri.'.-onCurves lynomi&l Type: PlOoint at Origin:. fit Neghting; -XXts -4m*odotmwtion: Concentration units: Extaernal Are s Linear zxclude I/X None Peak-to-p*&k amplitude: Smoocr, Smooth;.nq: Window SIZO (3C&AS): NUMber Zf SMOO th3: Smocr:!@.-.qmethod: Base.;nes j:@n -;&.-eytrireshold; .ko,a,zzreeak CaLling: ika.se --aze.ine maximum: *:a . s.'al@ threshold: ,1,14,d.rs: tn a hold: 71.resnld Re'-Atlve height: Absol;;t: height: lt*l ar ..o"ltuvt. r:::- 206 Disabled 3 2 20.00 50.00 5.00 10 00 Di.abl*d 40 00 1.50. Disabled 0.00, Disabled 2:000.: ll:&blod 0 DL &bled Aftic, IAC,i)5L311'-i C:\KASSLYNX\EaCS2.PRO\MethDB\043099&.vAb Non may 4)3 01133:57 1999. 2: Pros Pf Ln' @-1: 14on May 03 07:53:34 1999 t !*, ce: .;tanclards: Pros I#one TIC Cone. A User 'I.L.O: eea,. Factor: ULn(20. Factor: 1.000000. 1.000000 2.000 Disabled PESK L_O_n @*'tIe-ne, .(om"LnT3i)m:e: .@ns, E.106. Znabl*d 'J.000. Disabled 0.390 Nearest ':a.@crat.on Curves Polynomial Type: Point of Origin: Fit Wei-g-hRt-ing: ax -a a Concentration Unit:: Nois POAK-@o-peak aoqlitude: Smoot.'% thing: SWoionodow size (scans): Number of 3WA)Qths: Smooth tnq method: Baselines @oi n 4&:.ey threshold: .k:l.;=*peak taling: R ;st m&ximum: Ext:rnal Are s Linoar ILKCUde I/X Man* 218 D12abled 3 2 20.00 50.00 5.00 :cA@ ver:.Za. zhresnold,. Sr.z,-aer tn:eshold: pcnst 7hreshold ReLat.v: Abso P*s lut Relative Absolute height: height: area: area: Disabled 40.00 1.50, 0.00, 2.00, 0.00, Disabled Disabled Disabled Disabled 2 L4 -4 t:. i C:%XASSLYNX%rats2.PRO\MethDB\043099a.mdb ?4on May IJJ 1)7-.33:571999, 3: Pros PC . 161 Mon Kay 03 07:53:34 1999 'm @j..m :nt I .;t..,aards: PrDs lmonal lic Cone. A @nteqir@4to wincia- ractor; 1.000 00, Disabled 1.0000.00 2.000 Peak ;.ocattan -.Me :sins): ketvrtion Time: m:ns,: 5.573, Znabled 0.000, Disabled ).220 4@arejt p Fk 77pe: Ca.*.tra'..os:iurves ppo lin-mial Type: Eo'iitnVtt-ig'n'tiringgx:n: Concentration units: Noise Peak-t-.-peak amplitude: smooth smo tning: Winodow size lscans): Number of smooths: r'nooth@ ng method: Base..nes Joi-I vAk :y threshold: .qeduce -=:"k Ca'-Iing: ikaist @. .1:%e Maximum: pe4,:El--.:-ion threshold: :,e-tz- ircL;:ciers: t.,ireshoid: Ext:rnal Are a Lin*ar txcludt I/X Mon* so Disabled 3 2 200.00 5 .00 5.00 10.00 Disabled 40.00 FL* c Ab; Ab; 1 h:-qnt: '.i iqnr: a A.@ea: area: 1.50, Disabled 0.00, Disabled 2.00, Disabled 0.00, Disabled C)1,22qi2 LA --------------------------------------- -- - Q@" i,yCmg, ., mpar, 0=-:Il lko&&n sera I (lk&alltativeCCOPOU" Cb"k Smolo L.Lat: [Amt ditie4: method: "A modified: JobtC*do - C: %XUSLYNXN FACT- 1. PW%BAMIOMN 0503 ggb ow Way 03 16:01:10 1999 c:%K&"LTM%FACT -plko%nothm%oso3otb we may at 11:06:51 1999 Printed: ?me may 04 11:19:20 1999 - - ------------------- -- - ---------------------Page CCEWaUJ34 1: to" wa@ 050399006 2 D05SO)9;007 3 039 06 4 0$0399009 5 OS0399010 1 050399011 7 OS0399012 9 050399013 9 050399014 10 050399015 11 050399016 12 050399017 13 050399019 145 050399019 1 OS0399020 16 050399021 17 050399022 11 050399023 19 OS039:024 20 05039 025 22 050399027 23 050399028 24 050399029 2: 00503::0301 2 503 03 27 050399032 28 050399033 29 050399014 30 050399035 31 05039:00376 32 05039 3 33 050399039 34 050399039 35 050399040 36 050399041 3? 050399042 S&Aplelist Text N*OH Blank X*OHIBI1&nk CENO RDS04259-WBlank-I GCNOll oguoll GzNoll CZNOII GENOJJ GzNoll R&SO4289-S@Iank-I RAS04289-5 vpb-I RAS04289-10 ppb-1 RBS04289-2S ppb-I R&SO4289-50 ppb-1 ReSO4289-100 ppb-I X&OR Blank X&OR Blank GENOIJ RBS04289-WBI&nk-1 GENOIJ, 939oL (0.09 nL) CCHOIJ, 9395 CO.07 nL) 0=1011, G=011, 9396 (0.08 OkL) 9397 40.07 mL) 0=011, 9398 CO.07 OL) G=Cll RSS04289-50 PPB-I MWW,Iilank OM I RB504289-WBlan)L-1 G=011, 9399 9400 (0.07 aL) (0.07 =L) GMOII. 9401 (0-08 OL) 0=0 11. 9402 (0-08 UL) C4DMLl,R93403 07 nL) CZNOLI SO4i28(9a:50 ppb- I Gmoll "SO4209-2SO ppb. US Gzmoll RBS04209-2SO ppb. NSD Gzmoll RIS04289-SO PPB-I Me= Blank CZN IL RDS04209-walank-2 zm:IL R3904239-Sal&nk-2 GzNoll Gumoll czxoll CaMoll RDS04209-5 "SO42S9-10 "SO4289-25 RBS04289-50 ppb-2 ppb-2 ppb-2 ppb-Z GeNoll RBS04289-100 ppb-2 Type A@lyto Analyto Analyto Analyto Standard Standard Standard Standard Standard Analyto ilnalyto Analyto Analyto Analyto Analyto Analyto Analyto QC Analyt* Analyto Analyto Analyto Analyto Analyto Analyte QC Analyto Analyto QC AnslytO Analyto Analyt, Standard st--A-rd Standard Standard standard std conc 4.93 9.76 24.80 49.30 97.60 49.30 -- 49.30 49.30 4.93 9.76 26.80 49.30 97.60 AT 5.112 S. 1202 S. 5.1074' S.030 5.039 5.016 S.041 S.029 5.097 5.04 6 S.019 5.012 S.019 3.019 5.020 5.042 5.039 5.013 S.022 5.034 5 01 3 5:023 5.017 5.020 5.043 S.L2 0 5.034 5.045 5.050 5.030 S-014 5.034 5.020 Di.. 29 1 22 1 3: 1 3 1 61 1 so 1 45 1 Go 1 86 1 28 1 cow 0.0 0.00 0.000 0. a 43.69 12.23 0.00 65.90 120.18 0.00 riaca MM mm mm mm MM NK mm mm PCK m %Dow 786 25 -100 34 23 39 1 0.00 UK 98 1 155.38 bb loo 1 162.84 bb 111 1 202.02 137 1 273.88 bb 124 1- 213.37 bb as 1 117.39 M 138 42 1 0.00 UK 1 134.42 bb 203 1 473.43 bb 127 1 243.87 bb 111 1 19S.93 bb 168 1 365.67 bb es 1 116.98 bb 137 130 1 251.12 bb 201 1 166.53 bb 51 1 21.61 NK -56 20 1 0.00 nu 30 1 0.00 mm 61 1 43.72 Mg 38 1 0.00 mm -100 47 1 2.51 NK -74 49 1 7.88 MM -68 56 1 20.58 M -42 06 1 119.72 NK 23 Soup 020199: ou&ntltated &" printed by drb 05/04199 IL ------ ----------------------------------------------------------------------------- Quantit,y Compound mmmb"T Report OM-01 Human "C& I Qualitative Compound Cho" sample L.Itst: : C. %N&ASL.YNX%rACT-I.IPRO%SMWIGCS%05039gb Led mLe^t*htod:modi Non May 03 ls:Oltlo 199, C- %KUSIY=%FAICT-1. IPRO%..b=%OS039$b Page 2 ".t modified: TUG may 04 11:06:51 I'll Of,-,IS Printed: io co" Tug way 04 11:19:20 I'll Compound 2: M443 2 3 4 5 6 7 : 10 11 12 13 14 15 167 1 1: 10 2 @ll 22 23 2 211, 2 27 20 29 30 31 32 33 34 3S 36 37 190" BaMl:liot Text 050399006 moo lank 050399007 N*OHH Blank 05003990008 9 0550 39:(,100 0 39 CGZNOL1 'SHOLI CENO xi RBS04269-WBI&nk-I RDS0042::-Salank-I 42 Ra " -5 . -b-11 050399011 GENOII =042 - ppb-I 0(15003::012 GaENOII RBS04289-25 ppb-I .5503 ...Oil G Moll "SO 0:2:: -10.ppkl-l 3 14 ENOII RBS 2 - 0 ppb-1 05003:901S N*OH Balank 3 9016 N*OK lank 0OS5O032 GG =Oll . RBS0,4289t-oWBI&nk-I 3 oil ZU4) 11 93 4 .09 &L) OS0399019 99020 0503 GZMOII, amil 9395 (0.07 nL) 93;71 1"0.0078 055003990g21 GMII: . 93 9@ (0:07 ELL 3 022 0a5003919023 055, 19 902,1 3 9,25 CMIJ 13 11 "304289-50 Blank Me" OLI Mb-I GMII RBS04289-IMI&zLk-I f5V"9C2t-V=11, 1319 (0.07 nL) 05039:,0027 0503 28 CZKOII. OMIL, 9400 (0.07 mL) 1401 (0.04 =L) 50399029 10503:9030 1 0503 903 GENCII DMJI: 94'1*0'3 (00 0'7 28 :50 OL 0503 032 G=Cll RRMASLOS&2&89-2950 pppbpb-.1 KS 050399033 GRZENNOOII11 "SO&289-250 ppb. NSD 0503,9034 GVJOII "SO4239-50 ppb-1 05039903S K*ON Blank O0 S0399036 GrEMOll RU04281-Valank-2 50399037 ZNOII "SO&261-Salank-2 05039903: CZW 11 RDS04289-S ppb-2 05039903 Ginooll RBS04289-10 ppb-2 OS0399040 050399041 990 0503 42 CENOII GEND11 Gzmoll RDS042:99-25 so RDS042 "304239-200 ppb-2 ppb-2 ppb-2 TY" Analyto Analyto Analyto Analyto Standard standard Standard Standard Standard Analyto Analyto Analyto Analyto Analyto Analyt Amlyt: ac Awayto Analyt: Analyt Analyto Analyto Anglyt Analyt: oc Analyto Analyto QC Analy'to Analirt Analyt: Standard Standard t&ndard :tandard st andard Btd Cow *r 4.93 9.76 24.80 49.30 17.60 41.30 S.259 3.279 1,:2:: 2 5.20, -- 41.30 49.30 5.280 5.291 1 :1741 25 5.256 5.287 4.93 9.76 24.80 30 979:60 Area bi.. cone. Flags %Dow 21 1 mi 20 1 NKI 22 1 un 34 1 mm 48 4- mz I mm is I =a 20 1 3= 47 1 am 47 1 N= 17 1 I= 17 1 mi L4L SOUP020119: Quantitated &" printed by ftb 05/04/99 ------ ------- Qu@t LeIy compound sun-&jry Report OMX-ol ULI&M Sorl@ I (N&&LLtative Compound Ck"k somio LLst: : C:%K"SLT=%FACT-L rw%:amiom%oso3ggb Last moalcied ma may 03 1420&:L; lot C: %KILSSLVM%VAM-I.VRC%mathM%03039gb "thod: Last @dltied: Tue 3gay 04 11:09:51 1999 b Code: jPovLntod* Tue may 04 11:12:20 1999 CC.00m" 3: *513 x@ 912 05003,10.1 05 399007 T"t MOOM 81L:nnkk 3 050399008 GENOII RD 42:9-WB1&rLk-I 050399009 GENOLI RDSSo0 2 9-SBIank-I 5 OS0399010 1 6 OSO)9901 7 OS0399012 3 0503990 1 GCNOI0J GEN 11 GEN011 0 RBBSS0442::-S Lo ppb-I 0 2 - ppb-I RBS042:9-25 ppb-l RBS 050399011 CGEZNNO1111 ROS0044228:--ISOoQPppbpb--IL 10 OS0399015 moom Blank 11 050399016 12 d05SO399017 13 0399018 14 050399019 050399020 OS0. 319021 17 05 0399022 is OS0399023 X&OH $lank Gzuoll.RZS,04289-tWoBlagLk-I GENOIL 0 lxoii GZKCII 93 93 996: 93 cCol,.0o71l ==LL; . ML) GENOII. 9397 (0.07 =L) 0=011. 9392 (0.07 mL) 0=11 RDS04289-50 ppb-1 391024 NOW 3.B1lank 219. 0,5,00319025 GZNO RU04281-WRI&Ikk-I ---7r-@geog*TgVV21--CNXOJI. 9399 (0.07 =L) 22 OS0399027 23 OS0399028 45 050399029 a 2 05039903 276 503:9031 2 01503 9032 ' 28 050329033 29 050399034 30 050399035 31 0OS5O03:90036 32 3 9 37 33 050399039 34 050399039 35 050399040 36 050399041 37 050399042 GZNCII, 9400 (0.07 mL) GZUOII, azuoii GZUOII: 9401 402 :603 (0-08 =L) :0.:: mL) AL) 0. 0=011 RW:42::-I:Oppb-I CM011 Gzmoll RDS 42 RaSO4289-250 ppb. MS Vpb. XSD GM11 RRSO&281-50 ppb-I maox Blank ozuoll RBSO&2:9-Walank-2 Mo G=Cll &2 9-SBlank-2 GZNOLI RBS04289-5 ppb-2 GENOIJ R"04239-10 Ppb-2 GZMOLI RDS04289-25 ppb-2 GZMOII R35042S9-50 ppb,-2 cinoll R3304289-100 Mb-2 0 cC C C, 2y Std Case AT Analyt .,y .,Yt t: Standard standa r d andard Stta.n.ddarrdd Analyt* Analyto Analyt* Analyt Analyto Analyto Analyto Analyto QC Analyto Analyto Analyto Analyto Analyto ASL&Iyt: Anslyt oc Analyto Analyto QC Anslyto Analyto Analyto Standard standard Standard standard Standard 3 :7 24 *806 49 '300 97'6 49.30 41.30 49.30 4.93 9.76 24.00 49.30 97.60 Area OL.. @on rigus %mv oti) hiD@ ttlLt44 6 ID -ri pag3 e Soup 020119: gu&ntit&to4 and VrLDtod 3py dxb 05104/19 Oman icy c=mpound ouma"T Report --------------------------------------------------------------------------------- mu-011 KUMAN sera / Qualitative compound check Is List: : C:%MUSLy"X%TAM-I.pmo%aaMle=%*5039gb go" find moo way 03 16:OL:lo 1999 h"-. C.-%KUSLTM%FACT- 1. Plko%ustbw% 0503 gob L.t.t dified: ?us May 04 11:06'-St1999 Job Code! Printed: TIAO MAY 04 11:19:20 ---- ------ 1999 Convou" A.-surr 21 3 4 5 i 7 I1 10 11 12 13 14 is 16 17 Is 19 20 --21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 99006 005S0O3399007 oSSOo39 9:00,I 0 3 0010 OS03990 OS0399011 050399012 OS00399013 os 399014 05039901S 050399016 050399017 OS0399019 OS039901, OS0399020 OS0391021 OS0399022 0503,9023 05 039:024 5039 023 -'f 43' OS0319027 050391028 050319029 0503:90,30 1 0503 03 050399032 050399033 OS0399034 050399035 00:0399036 0399037 OS0399038 050399039 050399040 050319041 OS0399042 SSMI:li&t TILKT MOOH H "*o 2 11&@n*k CZNOLJ R350042:9-Wolanka-I c zwoil guoll Gem 11 Gemo oil Ru 042 899-Ssal rLk-I Rjks 42 - pp b-1 RBS04289-10 ppb-I R"04289-25 ppb-I cG zN 11 RSSO&0 2:9-50o1ppb-I gno0ll RBS 42 9- 0 ppb-I moon Blank MOON Blank CCUOII RBS04239-WBI&nk-I cluoll, 9394 (0.09 AL) Gamoll. 9395 (0.07 AL) axwoll, 1396 (0-09 mL) GZKCIII GEROXI, 1397 (0.07 ML) 1318 (0.07 nL) Czeroll RU04289-50 ppb-I MACM Blank amil R"04289-wala"-l --OMO II I't99 (0-07 mL) OMIJ, 9400 (0.07 aL) GXK011. 1401 (0-08 RL) OXXO11, 9402 (0.08 =L) GZMOII. 9403 (0.07 mL) OXWOL 02 ppb-I GZKOLII RRSISS0442:'-95-02SO ppb. KS amoll RDS04289-250 ppb. M= CM(Oll RDSO&281-SO ppb-I X*OU Blank Gzmoll ]tBSO&2:9-walank-2 CIXOII RBSO&2 9-Salank-2 ammoll R"04201-5 ppb-2 GENOIL R"04289-10 ppb -2 GZKCll GEN011 GENOII RDS04289-25 RBS04289-50 RBS04289-100 ppb-2 ppb-2 ppb-2 TYPO Analy Alyt tAnalyt* Analyto an"rd :ptandard standard standard Standard Analyto knoxyto Analyto Analyto Analyta Analyt* Analyto Analyte QC Analyto ArAlyto Analyto AzL&lyto AnalytO Analyt* Analyto oc @l@o . Anslyto oc Analyto Analyt* Analyt* standard standard standard Standard standard std cow RT 1.000 1.0 1.00 1.00 i.oo 5.016 5.008 :0.220, 5.009 5.005 5.022 L.00 S.010 5.012 5.004 5.012 S.012 3.012 5.006 S.032 -%@ 5.006 S.015 4.9090: 1.00 S. 5.016 5.010 S.013 i.oc 5.007 L.00 1.00 1.00 1.00 1.00 5.026 5.003 5.011 5.023 5.006 5.027 5.013 Area OL.. conc. lpl&gs %Dow 1624 0.01 bb -19 0.91 bb -9 11573691 1. 0.88 bb -L2 1 1 0.93 bb --7 17931 1 0.789 bb 11 15 5 1 . i bb 24 1891 1 0.94 bb -6 1813 3937 4524 4072 4241 3633 1792 1 0.94 bb 1 2.96 bb 1 2.2$ bb 1 2.03 bb 1 2.12 bb 1__ L.81 bb 1 0.89 bb 2179 1 --.*2N-- 1 6844 1 $032 1 4315 1 7774 1 197, 1 4326 1 3993 1 2442 1 1.08 bb 2.12 bb 2.41 bb 2.50 bb 2.19 bb 3.87 bb 0.90 bb 2.IS bb 1.99 bb 1.21 bb 1891 1 2227 1 2203 1 2L62 I 2241 1 2449 1 2114 1 0.94 bb 1.11 bb 1.10 bb L.07 bb 1.11 bb 1.22 bb 1.09 bb -6 96 128 103 112 $I -11 a 112 141 ISO L19 297 -2 115 99 21 -6 11 10 7 11 22 9 Soup 020199: Quantitated and printed by drb 05/04/11 Method Report Method filet Last modified Compound- Printed; C.-%KASSL.YUX%FACT-I.PRO%KethDB%OS0399b.mdb Tue May Ot 11106:51 1999 1: POAA TU* May Ot 14.11,29 1999 COMPOU igt rnI:@d, .O.t 'y ;:!Ce, Conc. of Standards; U :r R,,:.Val0: U: r k IP@ctor. Integrate Windw Factor: POAK IN*n*l TIC Conc. A 1.000000, Disabled 1.000000 2.000 ion Time (ains)i ::t:lotivn*o on ionITimes Tin1** Ilind,.(t.tin.) Peek Selection- 4.1)76. tmbled Disabled :::pon::,Tyge, pon gxternal Areas Polynomial Type: Point of origin. Fit Weighting: Axis Transformation: Linear amiude I/X None Units: ftak-to-pook amplitudet 230 Smoothing; wirwlowBig* (scans): mu"er Of smooth Smooth ng method: Disabled I Join valley threshold: Refteo peak tailing: Raise bmseline m"i@, 20.00 100.00 0.00 Draw vertical threshold: Detect should*rss Shoulder threshold: 10.00 Disabled 40.00 Relative height, Absolute height: nel:tiv* are&: Abe lute or*&: 1.50. Disabled 0.00. Disabled 2.00. Disabled $0.00, anabl*d tA!L Method Report Method file. Lost modified: Compounds Printed- Ct %KASSLYNX%rACT-1. PRO%KethD]N%OSO199b.mft Tue May 04 11.06:Sl IL999 2: W463 TUg Kay 04 14.11:29 1999 Compound N@, Internal Ref.: ou&ntily TcoceCom. of Standards: User RF Value: User lpookFactor: Integrate Window Factor: N&63 (Non*) TIC Conc. A 1.000000, 1.000000 2.000 Disabled ::t:p-n!ion Time loins): I &we Retention Time: T'LM Window (sins$: ftek Selection; S. 102. Znabled 0.000, Disabled 0.188 Nearest Response Types Response; txterns IL Are&* lpolrnamial Type. IP*intof origin: Pit Weighting: Axis Transfor@timt Lia*ar gxcludo I/X Won* Units: Peak-to-pank amplitude. 114 Smioothingi Window tire (scent): number of smooths: gowthing method: Disabled 3 2 Join valley threshold: Reduce peak tailings Raise baseline m"i@: 20.00 100.00 0.00 Draw iertical threshold: Detect shoulders: Shoulder threshold- 10.00 Disabled 40.00 Relative height; Abe lute height: Rel tive area: Abs:lute area: I.SO, Disabled 0.00, Disabled 2.00, Disabled 80.00. gnabled Method Report A. method file, Lost modified: C.-%KASSLYKX%PACT-I.PRO%HethDONOS0399b.odb T%ie May 04 11:06:Sl 1999 Ccapmnd, 1. US13 Printedt Tue May 04 l4sllt29 1999 Compound 1;:ternal antity Conc. of Me" Rot.: Tracet Standardat Volu U::Ir ::.h Factors Integrate Window Factors M513 (MGM) TIC Com A 1.066006, 1.000000 2.000 Disabled Retention Time (mins)z Relative Retention Times Time Win&jw fains)1 took Selections Response Types Response: Polynomial Types Point of Origin; Fit Weighting: Axis Transforiution: 8.324. gnabled 0.000. Disabled 0.724 woorest Rxternal Areas Linear gxclud* I/X None units: Peak-to-pook &Wlitudes smoothing$ WirAlow size 4sconsl Number of amootba. smoothing methods lid Disabled 3 2 J In valley threshold: A = ce peak tailings Raise baseline maximms Draw vertical thresholds Detect shoulders: Shoulder threshold: Relative Absolute Relative Absolute height: height: area: area: 20.00 100.00 0.00 10.00 Disabled 40.00 1.50. Disabled 0.00. Disabled 2.00. Disabled 80.06. tmbled method Report Method file: tast modified- C: XMASSLYNX%FACT-2. PRO%NethDB%05039b.ndb rue may ot 11:06.-Sl1999 Compound: 4! surr Printed: Tue May 06 16-11:29 IL999 CompoNu@n:d Intenrnal Ref.: 0 u::tify Trace: Co of Standards: surr won* TIC Fixed U R,:Ovkalu - U: c rector: Integrate Window Factor: 1.000000. 1.000000 2.000 Disabled ::tention Tim fains); Retention Timat TiIm&etiwvl= (sins): Peak Selection: 4.925. 0.000. 0.348 Knabled Disabled Nearest Response Type: Response: External Areas Polynomial Type: Point of origin: Pit Weighting: Axis Transfor@tion: Linear twlude I/X None units- Peak-to-pask &Wlitude- lid Smoothing; Window size iscans)- Wawber of smooth$: Smoothing method: Disabled 3 2 J in valley thresholdR:Iuce peak tailing. Raise baseline P&xi&Am- 20.00 100.00 0.00 Draw vertical threshold3 Detect Shoulders; Shoulder threshold: 10.00 Disabled 40.00 Itelative heightt absolute beight3 Relative are&: Absolute arms- I.SO, Disabled 0.00, Disabled 2.00. Disabled 90.00, Enabled 9C)IAP ------------ y compowid swomerv Jkevoct a=-OL Mown Seca / Qualitative C=Wou" - C3b*ek ZZ smople Li;,t,: Last @dL ad. .th"; x.&stoo"fiod; Job Co": C: %Mao FACT-1. vw%mamla=% me way 03 Is 43:0& 3 It 9 0 $0399C C: %NUSLYM%F:ACT- PW'%Mmtb=%0503904 U" May 03 09:33:35 1999 PrLut.4; wod Kay 09 10:03:17 ltt!l COOIDOUnd I- PFOSA u@ ll 050399043 2 005500339999004,15 3 & 0500399:0476 5 05 3 04 6 OS0399048 7 05039904L9 a 0503990so 9 050399051 1 050399052 l@0 050 3990S 3 12 0OS5O0399034 L3 3 99055 14 OS0399OSS 15 OS0399057 16 0503990SO 17 050399059 18 050399060 19 050399061 20 050299062 22 050399064 23 050399065 2 0503990066 214 .50399 67 26 050399068 27 050399069 28 050399070 29 050399071 30 050399072 31 050399073 32 050399074 33 050399075 34 050399076 35 050399077 36 050399078 37 050399079 samisilat Taut moom Blank MoOH,Sl,artk GENO RBS04289-WSI&nk-I GaEMOLI R&SO042:99:SSZ1&nk-I smoil Ras 42 vpb-I 42:99-105 gob-I GGEENROOIlLl "RSBo$042 -2 ppb -1 GENOII "504289-50 ppb-I GENOLL RDS04289-100 ppb-I K*Om :lank K*OH lank GXN011 , RBS0428(9-"Iank-I GZKOII 9394 0.09 OL) GMX011. 9395 (0.07 &L) GZNCII, 9396 10-08 =L) GUOIJ, 9397 (0.07 mL) clxoll. 9398 (0.07 nL) GZMOII RBS04219-50 ppb-I KEOR Blank --mll XW04399-Vblank-I 9399 (0.07 =L) GUOLL. 9400 (0.07 mL) GZKOLI. 9401 (0-08 nL) ro.lOollll: "901'03 '.00:*'07"EL)) GSUOII RU04289-50 vpb-I GEWOII RBSO&289-250 vpb, Xg GZKOII RBSD&259-250 a*. XSD GMII RSSO&289-50 Zpb@l K&OR Blank GZNCll RZSO&239-WBlank-2 GMCII RIS04289-Salank-2 GZKOII RDS042S9-5 ppb-2 G=Oll RBS04209-10 vpb-2 GMOII RBS04289-25 gob-2 GZMCII RBS04239-50 Vpb-2 GEND11 RDS04239-100 ppb-2 -------------------------------- ------- Type Analyto melyto Analyto Analyto Standard t-ndard Standard standard 'Standard AnalYto Analyt* Analyto Aa&lyte Analyto Anglyto Anslyto Analyto QC Ana]Lyto Analyto Ag&alyte Analyto Analyto A"Iyte Analyto QC Analyto Analyto oc Analyto Analyto Analyto tandard :t--l-rd Standard Standard Standard std Conc 4.93 9.76 24.830 49. 0 97.60 49.30 -- 49.30 49.30 4.03 9.76 24.80 49.30 97.60 RT 6.123 6 1:3 :1 :.1115 6.065 6.059 66 .062 .062 6.066 6.107 6.146 6.147 6.107 6.103 6.115 6.142 6.106 6.062 6.131 6.149 I 6.141 4.144 6.142 6.104 6.061 6.OS9 6.058 6.082 6.14$ 6.148 6.141 6.0 0 6.0:1 6.061 6.064 6.046 Are Di- 23&9 1:6 1 1 1629 1 729 1 1340 1 3103 1 6126 1 12048 1 207 1 216 1 179 1 IS6 1 138 1 161 1 143 1 170 -I- 5913 1 206 1 194 1 1 158 1 14$ 1 129 1 ill 1 5190 1 24445 1 22905 1 6123 1 240 1 116 1 161 1 7426 1 127 1 3078 1 6119 1 ll$09 1 Cone. Flags %0" 0.85 bb 0.42 bb 0.&241 bb 6.91 bb a 9.97 bb 2 24.57 bb -1 49. 0 bb 1 98.64 bb I 0.59 bb 0.66 bb 0.34 bb 0.17 bb 0.02 bb 0.21 NK 0.06 bb -.0.29 bb 47.01 bb -5 O.Sl bb 0.48 bb 0.15 m 0.19 m 0.10 m 0.00 bb 0.00 bb 41.85 bb -15 201.30 bb 188.54 bb 49.38 bb 1 0.86 bb 0.57 m 0.21 bb -91:07 1 3 44 bb 3 24.37 bb -2 49.S& bb 0 96.66 bb -1 Page (AIlk 020 g'; o@48nia," a" P'lot.."Y 0!",Os",, ---- ---------- - ---- -------- QU&AtitYI COEPWAghd SUMMSVY Refort Gem-01 mu@ for& / (NL&Iitative Convou" Ch*ck XX &Mlo List: : "st @dLELed method: Last modified: Job Code: C:%KUfLym%rACT-I.PW%SaNPIOM%OS*3!lga 100 WAY 03 LS;43:03 1999 C: %KIL"LYM% FACT- 1. FW%N*tW=% @SO 3 YOC U" N&Y 05 09:55:55 1999 Printed; Ned N&Y 05 10-.03:17 1999 comipound 2- PFOSAA m@ 201 050,,999,0403" 050 3 99045 samistimt To= MOON lank K*OM 11 I"k 3 3 ..... 1 0503 5 050399047 GrZNO . Zmo GZNGLI "SOII:9-WBI&rLk-I Rlks.,28:-:Blam-l RBS042 - ppb-I 67 O05S03:9048 g GrZNOLI RU04289-10 pob-I 39:0OSO ZNGLI RBS04289-25 ppb-I a OS03 9 050399051 10 050399CS2 GZNCII R2204249-SO RDS04289-100 GZ"03,1 NGOH lank ppb-I ppb-1 11 050399OS3 K*GH :lank 12 OS0399054 czwoii RSS04219-Wbl&nk-I 13 0503990$S 14 050399990O5S67 is OS03 GMIII GM011,11, alxo 9394 9395 9396 0.09 UL) (0a.07 =L) .08 =L) 16 050399058 CM21, 9397 (0.07 =L) 17 050399059 G=011. 9398 (0.07 oW IS 050199060 GZKOII RBSO&209-SO ppb-I 19 050399061 Me= I&" 20 OS0399062 G=9011 12SO4289-WBI&nk-I 21 0503990:3 OS03990 i 22 GZKOII: GWOLL :19: 40 tl::0071) 7 m&L) OSrj"VWF-IMDMII. 94901 (0.06 ML) 24 OS0399066 ' 11, 9402 (0.06 RL) 2S OS0399067 GZNOII. 9403 (0.07 mL) 2_1, *1039900:98 2 OS0399 ' Ll RBS04289-30 0=011 RU04289-250 ppb-1 ppb, NS 2: O:g39:007! GZKOII RW:42:9:2:0 ppbi MD 2 0 O0SO 39 90772 3 39 0=011 BlaRnDkS 42 9 5 ppbNo= 31 050399)0g7(3,74, OXMII 32 0503 GMII RIS042:9-WSI&nk-2 RISO 42 9-531&nk-2 33 05039907: 34 05039907 3S 050399077 G=Cll GENOIJ GINOJI RBS04209-S RU04289-10 RBS04269-2S ppb-2 ppb-2 ppb-2 36 OS0399078 GIN011 RaSO4289-50 ppb-2 37 OS0399079 GaNoll RBSO&289-100 ppb-2 5 Type Analyto Analyto Anslyto Analyto Standard Standard Standard Standard Standard Analyto Analyto Analyto Analyto Analyto Analyto Analyt: An&2yt oc Analyto Analyto Analyt Analyto Analyto Analyto Analyto oc AcLalyto Analyto oc Analyt* Anslyt Amlyt* tandard :tandard Standard Standard Standard Btd COW *t 4.93 9.76 2:.380 4& . 0 97.60 5.649 S.698 5.6:0 5.6 7 5.691 S.646 5.687 S.6ss 19.30 5.63a 49.30 49.30 5.44S 5.487 5.445 5.64, S.664 5.647 4.93 9.76 24.80 49.30 97.60 5 616 5:190 5.64S 5.649 5.175 Azoa OL.. Cone. Flags %Dev 35 1 4.14 m Ila 1 10.42 bb 277 1 26 .28 bb S17 I So .30 bb 948 1 93.37 bb -16 7 6 2 -4 29 1 33 1 29 1 1.54 NK 1.94 m 1.56 m sis I-- SO..13 bb 2 0.02 36 1 2.23 NK 6si 1 43.72 bb 29 2217 1 220.16 bb 2102 1 200.65 bb 529 1 51.16 bb 4 31 1 1.80 m 62 1 4.587 M -1 109 1 9. 7 bb -2 273 1 2S.91 bb 539 1 52.51 bb 7 969 1 95.40 m -2 tA Page 2 "uP 020199: Nantitated and printed by drb OS/05/99 ---------- Qu"tity compound ounimsy Report am-all mulma "9& / goalitativa C=Wou" Check ZZ Smiole LLst: I..t W41fied: ::at .dilLd: Job Code: c.-%MANLY=% rwr- 1. pw% sawleoa% mm *my 03 14:43,03 Isis C: %mooLv3m%rAm-,. rw%mothm% Md May 05 09*SS:55 1999 0503 ggc 0503 too .,Latod: wed may OS 10.-03-17 1999 3 C6 carapound 3: M570 9 U4@ 1 050399043 2 OS039904A 3 05039904S 4 050399046 5 050399047 6 050399048 7 OS0399049 8 050399050 9 050399051 10 050399OS2 11 030399053 12 010399051 13 050399055 id 050399CS6 15 050399057 16 050399059 17 050399059 1: 005503990060 1 0399 61 20 050399062 22 OS0399064 23 050399065 24 050399066 25 050399:00:7 26 0503 a 27 050399069 28 OS0399070 29 OS0399071 30 OS0399072 31 050399073 32 05039990970475 33 050 3 34 050399076 3S 050399077 36 OS0399078 37 050399079 Bawl*lLst TdLxt HOOH &lank NOOK ZI&AK G=Oll R9504289-"Iank-I GIXOll RBS04289-531&nk-I GMOLI RSSO&289-5 ppb-I GMOLI RILSO&289-10 gpb-I GZUOLJ RBS04289-25 ppb-L GIXCII RSS04209-50 GKKOLI RDS04239-100 HOOR Blank PPB-I VPb-1 XEOH slank RIKOIII RDS04289-Wbl&nk-I GIXOII, 9394 (0.09 UL) GZNOIL, 9395 (0.07 oLL) GWOLI, 9396 (0.08 RL) GUOLI, 9397 (0.07 nL) 9=011, 9398 (0.07 &Ll 0 M 11 lRaDnSk04289-SO Mb-I MOCE 911 RZS*4289C-401&nk-I 9399 0.07 mL) 11, 9400 (0.07 &L) GMII. 9401 11, 9402 (0.04 EL) (0.09 RL) oxwoi'i11'US9D&&02389:S Co 070 IpLpLb)-I CMIJ RWO&289-250 ob. NS GMI I RWO&289-230 OPOI I Roso&289-SO Vpb. USD vvb-I MACE alazkk GMCJJ RBSO&289-Walank-2 G=Oll RBSOt2:9-SnlasLk-2 GUOIJ RDS042 9-5 ppb-2 GMOII RS504289-10 ppb-2 GZ3Mll ReSO4280-25 ppb-2 G=Oll RSSO&289-50 ppb-2 0=011 nSO6299-100 Ppb-2 Type Std Cone RT Artalyto AnalytO Analyt* Analyto Standard 4.93 Standard standard 9.76 24.80 Standard 49.30 Standard 97.60 Analyt* Analyto Analyto Analyto Analyto Analyto Analyto Analyto oc AgLalyto A"Iyt A"ay,: 49.30 Amlyto Analyto Analyto ASL&lyte QC Analyto Analyt* oc Analyt* Analyto 49.30 49.30 Analyto Standard standard standard Standard standard 4.93 9.76 24.80 49.30 97.60 Area Di.. conc. Flags %Dov LAG SOUP020199: ou@titated and vrLate6 by 6rb 03/05/99 QCu=a-ntitIy CCWVou" duon"y Report oi K@ @era / cra&litati" C=wou" Ch-k xx $awls &lot: Last mw"fied: thed: M.a.set N"LfLod: Job Code: C:%KUOZ.T=\TACT-I.MW%BMWIODD\OS0399C am lay 03 Is-43: 03 isto C:\K%NSLTNZ\YACT-,L.M*\NatMM\OS0399C U" my as 09153-35 2999 Printed,. w" may 05 10:03.17 1999 CcoVam" 4: KSSS s@ I2 0OS5O0399043 1990 a 1 050399045 45 0500339:0:6 9 07 6 050399048 7 050399049 0 OS039;OSO S 39 051 10 050399052 11 OOSSO03::053 54 12 30 13 050399055 it OS0399056 1: ::.03::0:7 1 3 0,: 17 0503990 la 050399060 19 030399061 20 050399042 21 5039:0043 22 :3039 64 24 050399044 25 050399067 267 OS503:9068 9 2 2.9 *1051000319 9070 39 2 :071 30 050399072 31 050399073 32 OS0399074 33 050399075 34 050399074 35 OS0399077 36 050399078 37 050399079 Sanplel:Lot Text HOOR :1 nk moon 1= G=Oll RBSO&289-WS1&nk-I CZNOIL 0=011 Camoll USO:2:9-Sglank-I RBSO 2 9-5 ppb-I RDS04289-10 ppb-I GZNOII GM11 GMII RiKS04209-25 ppb-I RBSOO&2:9-!Ooppb-I n$ 42 9- 0 ppb-I NOCM Blank K&Om,bl1ank GXNO RDS04209-WBlank-I GRUOI1, 9394 (0-09 aL) GZKOIJ. 9395 (0.07 mL) 0=011 RMOLI, amaii CMIOIL : 1931,:76 93 a 11.17 RWO4299-50 OL: MIL) ppb-I NOW Blank 9 11 amaii 4=9011: R3304289-WSlank-I 1319 1, :::7 ml; 9400 7 =L 9401 (0.08 EL) GZUOII, GMOII, 9402 9403 CO-08 2&U) (0.07 =L) eG mmoil RZSO&289-50 ppb-I &2:9-2!50C, ppb ms 1 *MCI, RUO .42 S: -2 ppb: XSD G=Mollll RUASSOL2 -50 ppb-1 meor Blank GEN011 RBS04289-WBLLnk-2 CMIJ R&SO4289-Salmk-2 0=11 RIS04289-5 ppb-2 azwoll RaSO4239-10 ppb-2 OxNall RIS04289-25 ppb-2 GZNOll RIS04289-50 "b-2 G=Cll RU04289-100 Vpb-2 Type AnalytO AnalytO Analyto Analyto Standard Standard tandard :tend r tand:rdd Analyte Analyt Analyto Analyto Analyt: Anal Yt Analyto Analyto QC Analyto Analyto Analyto Analyto Analyte Analyt: Analyt ac Analyto Analyt* QC Analyto Anglyto Analyto Standard st Standard Standard Standard std Cone av 4.93 9.76 24.80 479.30 9 .60 S.588 S.540 5.544 S5.55&3 45 49.30 5.543 -- 49.30 49.30 5.542 5 49937 5& 5.552 4.93 9.76 24.80 49.30 97.60 5.595 5.543 5.592 S.544 5.529 AC" DL.. Flags %Dew 41 1 81 1 4.33 NK 9.92 M 223 1 29.23 bb 388 1 51.60 bb 726 1 97.90 bb -12 1 is 5 339 1 45.08 bb -9 -- 358 1 47..61 M -3 2L21 2:::l87 bb 1985 12 7 bb 389 1 SI.86 bb 5 as 1 5.29 M 72 1 2.52 Mg ISO 1 23.27 bb 403 1 S3.72 bb 661 1 89.03 NK 7 -13 -6 9 -9 LA Page 4 BOUD020199: Quantitated mA printed by dvb 05/05/99 ---------- wantity I compowd Summ"T Aftort am-al *Am" &or& I Qualitative compwaad cb"IL xx Is List: modified: shod: M.O.tt00"fL*d: Job Code: Um May 03 16:43:03 1999 C:%KUBZvm%rACT-1 PW%.tb=%03039tc Wod May 05 09.55:5; 1999 ftinted: Wed May 09 10:03:17 1999 Corwound 5: surr K@ 0503999004,3& S=WLOIL&T T4bxt H"&&OOHR gSll:,nkk 2 3 0500399900445 A 539 6 GENO 11 IMS0044283:-Walank-I 0=011 M 2 -SSI&nk-I 5 050399047 GZKCII RBS04289-S ppb-I 76 055003:90044: GZNOll RU04289-10 ppb-I a aoso 3 ,9 050 azuoii RaSO4289-25 ppb-I 39 Gzuoll RDS04289-SO ppb-I 9 0503990si czucll RSSC&289-100 ppb-I 10 050399052 11 050399053 K*OH :I:nk X&OH I nk 12 005500399:0054 13 3 SS OAXOtl , RBS3042$91 -WBI&nk-I 0=11 9 94 0.09 aL) :S,13::0571 15 5 3 05 r-amoll 39S 1(0 07 nL)t 1.9*011: :396 0:08 AL 16 0503:9053,8 Quoll, 9397 (0.07 &L) 117, 3 90 is 050399060 0=011. 9398 (0.07 =L) 0=011 RSSO&289-50 ppb-I 19 050399061 X*= Blank 20 050399OG2 21 050399043 22 050399064 GMMII , RBSO&92989-(WSI&nk-1 G=Oll . :43 0. .*.:017 mL) Gzxoli . 7 ") -0540004"---G=Oll 940L (0.06 ML) 24 050399066 GMOLI. 9402 (0.02 nL) 25 050399067 26 OS0399068 0=011. 9403 (0.07 =L) GZKOL1 "SO4289-50 pob-I 27 05039:006: 05039 7 28 29 050399071 GMOLI 0=011 RBSO,42:9-250 ypb xs RDSO 2 9-2SO ppb: MD GMIIOII RDS04289-50 ppb-I 30 050399072 M40H Blank 31 050399073 CM11 RBS04289-Wblank-2 32 0503990741 33 O0SS003:9107S 03fUOll RSS04289-SSI&nk-2 0=011 RBS0042:9-5appb-2 34 3 076 G=Oll RES 42 9-1 ppb-2 35 050399077 36 050399079 ORM011 9=011 RDS04289-2S RDS04209-50 ppb-2 ppb-2 37 050399079 GZNCII RBS04239-100 ppb-2 Type Analyto Analyto Analyto Analyto Standard Standard andard :ttandard Standard Analyto std case R? 1.00 i.oo 1.0a0 1. 0 1.00 4.994 4.998 4.997 5.035 4.996 4.9,6 4.999 Analyt* Analyt* Analyt* Analyto Analyto Analyto AzL&Iyto oc Analyto Analyte 1.00 4.995 4.999 4.992 4.994 4.990 4.997 4.993 4.996 Aaalyt* Analrto - Anslyto Analyto Analyto -- 4.995 4.091 4.994 4.994 oc Analyto Analyto oc Analyto Azialyto Analyto t,,A,@d :tandard Standard Standard Standard 1.00 1.00 1.00 00 1. 1.00 1.00 1.00 4.994 4.992 4.992 4.998 4.997 4.992 4 9994 4:9 5 4.992 4.997 4.903 *4bae S el%510c-5 AV" Di.. 2041 1 2299 1 2055 1 21S3 1 20003 1 I'm 1 igas 1 1986 1 4144 1 4751 1 4225 1 4496 1 1691 1 1730 1 1964 1 4095 1 4606 1 1 4196 1 8708 1 2756 1 4008 1 4109 1 2293 1 1920 1 2064 1 2028 1 1931 1 2202 1 2260 1 2071 1 Cosa. P2&gs %Dwv 1.01 bb 1.13 bb 1.01 bb 1.06 bb '0 :'8'3 ' bb 0.98 bb 0.98 bb 2.03 bb 2.33 bb 2.07 kkb 2.21 bb 1.81 bb 0.$S bb 0.94 bb 2.01 bb 2.29 bb 2.41 bb 2.04 bb 4.27 bb 1.35 bb 1.97 bb 2.02 bb 1.13 bb 0.95 bb 1.01 bb 1.00 bb 0.95 bb 1.03 bb 1.11 bb 1.02 bb I 13 1 6 - -2 17 -2 -2 103 133 107 121 It -is -4 101 126 141 106 327 35 97 102 13 -5 I 0 -S 111 2 L4c, &Oug OZOL99t Quantitated &ad printed by dtb 05/05/99 -------------- OwantitY I Callbration Inert ..-Ol M@ sera I VA&Iitatlve CompauDd callbrati@: L"t modified: Priated: C:%ML"LTM%VACT-L.V=%CUrvo=%05039ga Wed May 05 09:56.L2 1929 Wed my 05 49:56:44 1999 Cbeck ZZ Compound I name: PFOSA Coefficienotf Determination0:.999781 Calibratiocnurve:120.761 * x + 135.834 Response type:ExternalStcLArea Curve qW: Linear,Origin:Exclude,Weighting:I/x,Axis trans:None 1.20e4- Page I Response- 2.87- %Conc- -3.25 0.0 . 10.0 20.0 .3.0...0....40 0 ftuv 020192: an@titatod ow priated by dcb os/os/99 50.0 60.0 70.0 80.0 90.0 Conc QM.Cll callbeation Rwart M@ Nor& / Q"Iit&tLVO COMOC*AD CbGC3& ZI C&Iibration: t'amtE:Lfiod: printed: C:%MSSLTMNTAM-L.vw%curve=%os*3tc wad X&Y 05 og:$G:12 lost wed may 05 09:36:44 1999 Compound2 name:PFOSAA Coefficienotf Determination0:.996430 Calibratiocnurve:10.0108 * x + 13.4359 Response type:ExternalStd,Area Curve type:Linear,Origin:Exclude,Weighting:Ilx,Axis transN:one 990- Page2 Response- 0- . . ....... 6.81- x x %Conc' -16.0 0.0 10.0 20.0 30.0 "up 020109: queatitated A" Printed bv drb 05/05199 40.0 50.0 6.0..0.....7.0.0 80.0 90.0 Conc oantify Calibratioa Report am-all wamn Seca / awaltatlvs Calibration: "at modified: Fr&atod: C: UWNLT=%FACT-I.PW%CUXVOM%OS03990 U" N&Y 05 09:36:12 Wed KW 05 09:56:44 compwand 1999 1999 cb"k zz Compound 3 name: M570 Coefficienotf Determination0:.000000 Calibratiocnurve:0 * x + 0 Response type:ExternalStd,Area Curve type:Linear,Origin:Exclude,Weighting:I/x,Axis transN:one 100- - ----------- page 3 Responst- I(Y ............ I- i-/%-Conc- ............. I0-. ""nConc 0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 2@p 020199: Qu=tit4ktod &ad Printed by dcb 03/05129 gum&tlgIy CalLbration 3Leport 0=-Cl Ru@ft 80CA I Oumlit&tlwe CONPDWbd Cheak ZZ -ILbration: Last mo"ft*M PrL&tod: c C: %nuoLTMNFACT-I.IPSO%CuzvsM%030399C wed mar 03 09:54:12 1929 lftd WAY 05 09:34-.44 lot$ Compound 4 name: M556 coefficienotf Determination0:.988614 Calibratiocnurve:7.32086 * x + 9.47847 Response type:ExternalStd,Area Curve type:Linear,Origin:Exclude,Weighting:I/x,Axis transN:one 726- pa" 4 x Responsex 17.9- x x x x %Conc x x -12.7 x7 0.0 SOUP030199: QuantLtated . 10.0 20.0 30 0 asbd 9cieLted kpy drb 05105ttO . 40 0 x . . . . . . . .. . . . . . . . . . . ....... ... ......C.onc 50 0 60 0 70 0 80 0 90.0 QuantifyCalibratioMnooort cl=.Ollft@ "we / Q"LitativeCMWM-- CMak 22 Cal&bc&tioa: C:%MUM&=% FWf- 1.VW%Cmxvo=%05039ge Z."%modLgia4:U" way 05 09:34:121999 lprijkted3 U" sw 05 09-55:44 lost Compoun5dnames:urr Response Factor:2036.99 Response type:Extemal Std,Area Curve type:RF 2.26e3- Response- - ---- --- -------- Page s x xx x 0- 10.9- x x x x x %Conc' -17.4 ).0 84OUP 020199-. Qn"tit&ted 0 1 0.2 0.3 &" 3prl&%Od by drb 05/oSI99 0 .4 0.5_0.6 0 1 Conc 0.7 .8 0.9 .0 method Report K*thod file: Last modified: compound: Print": Cc NHASSLYNX%FACT-1.PltO\MethDB\OS0399c.mkdb Wed May OS 09.55@SS 1999 1, PPOSA W" My OS lOtO2t8S 1999 C - nd Name, Internal Rot., Quantity Trace: Conc. of Standardmi Us:r RF Val *1 Us c Peak Factor: Integrate Window Factor: PPOSA ING") TIC Com. A 1.000000. 1.000000 2.000 Disabled Retention Tim* (mins)t Relative Retention Times Tim Window (ninsis Peak Selection: Response Types Responses ftlynmial Types Point of Origin: Fit Weighting; Axis Tronsformationt units[ roak-to-pe&k amplitudes Smoothing, wiraw size (scans)t Mimber of smooths: s@thing method: 6.06S. 0.000. 0.296 S"bled Disabled Nearest Ext*rnal Areas 16ineor twiude I/X None 230 Disabled 3 2 Join valley thr*sbold: Reduce peak tailings Raise baseline m"i@: Draw vertical thresholdi Detect :bouldtrst Shmld* threshold; Relative h*ightAbsolute heightRelative or*&Absolute area: 20.00 100.00 0.00 10.00 Disabled 40.00 1.50. Disabled 0.00, Disabled 2.00. Disabled 80-00. B"bled LAC,C).Sli)slgg f moth" Report method file, Lost modified: CoogaundPrinted; C.%KUSLYNX%FACT-I.PRO%MethDONOS0399c.ndb W" Kay 05 09,SS;SS 1999 2. IPVOSJLA Wad May OS lOtO2:09 1999 CONpmnd 1;:tarn anti C.. Has*: I Rot., ;y Traceof Standardes U of RIP Values U:er Peak Factor: Integrate Window Factors PIPOSAA Imomi TIC Conc. A 1.000000. 1.0:00000 2.0 Disabled Retention Rtlmtiv Time Wi= Time (sins), Retention (min&) Times Peak Selection, S.&SO. 0.000. 0.424 ftabl*d Disabled noar*st Response Response, Types aktarnal Areas Poly @ tol Type; Point of origin: Fit Weighting: Axis Transfo @ tion: Linear axclude I/K None units: fta,L-to-peak amplitude: 114 Smmthing: Window *amber Smoothing size (scans)t of s@oths. methods Disabled 3 2 Join valley thr*sboldi Reduce Peak tailings Raise baseline N"i@: 20.00 100.00 0.00 Draw vertical threshold- Detect ghould*rs. Shoulder threshold; Relative AI=Olut* Relative Absolute heights heights age&. area. 10.00 Disabled 40.00 I.SO. 0.00, 2.00. 00.00. Disabled Disabled Disabled Snabled A. LAf, 9f Method Report Meth.od file. Las m@odified C.-%KASSLYNX%rACT-I.PRO%NethDB%OS0399c.odb Wed May 05 09,55:55 1999 Compound: 5, surr Printed: Wed Kay OS 10;02;09 1999 DL4 Compound N@: 1;:ternalRof.: antify Trace: Cone. of Standards: Burr inonel Tic Fixed Us:r RP Values us c Peak Factors In,*grate Window Factors 1.000000. Disabled 1.000000 2.000 Retention Ti@ gnins)j R!Iative Retention Time. TLme Window (mins): Peak Selection- Response Type: Response; Polynomial TypePoint of Origint Pit Weighting. Axis Transto@tiont 4.913. znabled 0.000. Disabled 0.637 Nearest gxternal Areas Linear txclude I/X *one units. Peak-to-peak aMILtud*: 114 SmoothingWindow miss (sconsi: Number of amoothat Smoothing wathod: Disabled 3 2 Join valley thresholdi Reduce peak tailings Raise baseline m"immt 20.00 100.00 0.00 Draw vertical thresholdDetect shoulders: Shoulder threshold: 10.00 Disabled 40.00 Relative height: Absolute heights Relative areas Absolute area: 1.50. Disabled 0.00. Disabled 2.00. Disabled 80.00. anabl*d LAt-I)SJZ>s-I?P 3 M -ENVIRONrvilENTAL LABORATORY Note to File 3M ET&SS LaboratoryStudyNo. _6ENOIJ AssociatedStudy Number: POAA V4eXs '2 t4 0 m 5 1 N. R'S 4,j-L5,ky&*TAATV tc_. [S -of-L.It V M55 11 ot 0(1111c,@eid,.rv@@ cazn@u I Recorded By: Date Quant&fy CampomW sumary R*Wrt Rat Urtne Method De"lopment, 999 Saample LA;t: Last modi led Method; Last modified: Job Code: S: \TACT- 1.MW\NmWleDB\05039ft Mon May 03 16:01:10 1999 S:\FACT- 1.PM\NothD\03032gb ?" May 04 11.109:51 1999 Pr&nted: Fri May 21 11:34:44 1999 Campoww 1; POM a1 "11-0"399006 2 050399007 3 050399008 4 050399009 5 050399010 6 050399011 7 050399012 05039:013 05039 014 10 0503::015 11 0503 016 12 050399017 13 050399018 14 0503::0109 15 0503 02 16 050399021 17 050399022 11 050399023 19 050399024 20 0,103,9025 21 0503,9026 22 050391027 24 050399021 25 050399030 26 050399031 27 0503:9032 24 0503 1033 21 050399034 30 050399035 31 050399036 32 050311037 33 0503::03: 34 0503 03 35 050391040 36 050399041 37 050399042 sampleliat Text MOOH Slak NOON Blank GUOII R9304289-WBI&nk-I GLUOII RBS04299-SBI&nk-I GZNOII M04299-5 ppb-I GZN011 R9304209-10 ppb-I GENOII RBS04209-25 ppb-I GZNOII RBSO:2:::500ppb-I GEMOII RESO 2 10 ppb-I HOOM :I:nk eOH 1 k GZN011 R3504299-WBlank-I GFN011, 9394 (0.09 UL) GEN4)11: :3:: 100:07 "1 GRXOII 3 Ot aL GENOIJ, 9397 (0.07 aL) GENOIJ, 9398 (0.07 mL) GENCII RS304289-30 ppb-I NOW Blank GENOII,RILS:4219-WBI&nk-I GZMII 93 1 0.07 UL) GENCII. 9400 10.07 aL) GENOXI, 1401 (0.08 aL) GEN011, 1402 (0.04 aL) GZNOII, 9403 (0.07 &L) GENOII R9304219-50 ppb-I GENOII RDS04281-250 ppbl m UNOII RS304289-230 ppb, MD GENOII RBS04289-50 ppb-I HOOH Blank MNOII RBS04289-MBI&nk-2 GZNOll R3304209-3Blank-2 GENOII R33042::-Soppb-2 GENOII RS3042 -1 ppb-2 GENOII RBS04209-25 ppb-2 GZN011 RBS04289-50 ppb-2 GENOII R3304209-100 ppb-2 ftge I Type Analyto Analyto Malyto Analyto Standard Standard Standard Standard Standard Analyto Analyto Malyto Analyto Analyt: Analyt Analyte Aztalyto QC Analyto Anslyto Anslyto AnaLyt: Analyt Analyto Analyto cc Analyt* Analyto ac Analyto AzL&lyt* Analyt* Standard Standard Standard Standard Standard Std Cone 4.93 9.76 24.00 49.30 97.60 RT 5.112 5.102 5.023 5.074 5.030 5.039 5.016 5.041 5.029 5.097 Area 29 22 34 30 11 50 45 Go 86 29 5.046 39 5.019 90 022 100 , ais 113 5.019 137 5.'020 124 49.30 5.042 05 49.30 49.30 4.13 9.76 24.80 41.30 97.60 5.039 5.043 --IL0013-@--2 22 5.034 5.013 5.023 5.017 3.020 5.043 5.120 5.034 5.045 5.050 3.030 5.014 5.034 5.020 42 .91 3 1207 ill is@ Is 130 101 53 20 30 11 30 47 49 56 86 Response 29.033 22.095 33.979 39.037 60.545 50.106 44.822 67.951 85.999 27.504 39.225 97.701 1*@03 :1012 1 29 137.099 123.430 M.069 42.226 90.731 203 445 127:121 111.183 167.617 94.935 129.533 101.407 53.226 19.637 29.864 60.576 37.194 46.876 40.660 55.542 05.044 Cone. 0.00 0.00 0.00 0.00 30.62 0.00 0.00 67.77 159.54 0.00 riage mm m m m M mm mm M MN m %Dev 521 -100 -100 37 42 0.00 m 217.39 bb 2259:317 1 29 9 M 41S.S4 bb 347.$0 bb 153.96 M 212 0.00 m 182.34 bb 7495 22 bb 36 :36 bb 283.20 bb 569.03 bb 153.19 bb 377.49 bb 236.03 bb 0.00 m 0.00 NK 0.00 m 30.48 M 0.00 "M 0.00 MM 0.00 ma 3.36 MM 157.76 NU 211 -100 -100 -100 -100 -01 62 soup 020199: :quantitated and printed by swb guanti6fy Coopound ou@ry PAMpart Rat Urine Method DaveloPmnt, Stt Sim*le Lk;t: : s:\rACT-I.P%O\:M1.WLADB\o 399b L&ft modl led men Way 03 IS: .10 lots Method: $:\rACT-I.PRO\IftthDB\Q$O::gb Last modified: Tue May 04 11:06:51 1999 Job Code- Printed: rri May 21 11:54:44 1999 Compoi-nd 2: M463 mam 91 050399006 2 050399007 3 050399006 4 050399009 5 050399010 4 030399011 7 050399012 0 050399013 9 050399014 10 050399015 11 050399016 12 050399017 13 050399010 14 050399019 15 050399020 if 050399:0021 1 0503 22 19 050399023 19 050399024 20 050399025 21 050399026 22 050399027 -93-&SVYMA. 24 050399029 25 050399030 24 050399031 27 050399032 2$ 050399033 29 050399034 30 050399035 31 050399036 32 050399037 33 050399030 34 050399039 35 050359040 36 050399041 37 050399042 gnpielist T"t MOON Blank M*OK Blank GUOII GMOII GMCIJ RBS04289-WBI&nk-I PZ$042$9-SBI&nk-I ROS04289-5 ppb-I G=Oll R9304209-10 ppb-I GEN011 RBS04209-25 ppb-I GZNCI1 RBS04219-50 ppb-I GWOII P.BS04209-100 ppb-I HOOK Blank MOON Blank GMOII RBS04209-WBlank-I GWO 11, 9394 (0.09 aL) GUO 11, 9395 (0.07 mL) GMJI, 9396 (0.08 aL) Gwo 11: :3:1 1::0*1 aL: GUCII 30 7 aL GINOII RDS04209-50 ppb-I NoW Blank GMII R9304249-IMI&nk-I GUOII, 9399 (0.07 aLl Gamoll .:400 (0.07 &L) GENOII: 401 (0.08 OL) GM011, 9402 10.06 aL) GENOII, 9403 (0.07 ML) GEMOLI "304209-50 ppb-1 GZN011 R3304209-250 ppbo MS GZNOII R9304209-250 ppb, KSO GUOII RS304209-50 ppb-I MoOll Blank GENOll RDS04289-*Blank-2 GENOIL ROS04209-SBI&nk-2 GENOIX RBS04289-5 ppb-2 GEN011 R3S04289-10 ppb-2 GENDII R3304299-25 ppb-2 GENOIJ ROS04269-50 ppb-2 GEN011 RBS04289-100 ppb-2 Page 2 Type Analyto Analyto Analyto Analyto Standard Standard Standard Standard Standard Analyto Anslyto Analyto Analyto Analyto AAMlYt@ Analyto Analyto ac Analyt* Analyto Analyto Analyto Analyto Analyto Analyto oc Analyto Analyto oc Analyto Analyto An&Lyrte Standard Standard Standard Standard St&rA&rd Std Cone RT 4.93 9.76 24.60 49.30 97.60 49.30 5.259 5.279 5.285 5.259 5.289 5.310 -,@@O 5.291 S.275 5.254 49.30 5.256 5.287 49.30 4.93 9.76 24.00 49.30 97.60 Area PAsponse Conc. rl&gs %Dav 21 20.904 NMI 20 20.379 NMI 22 22.269 mi 34 34.007 NMI 48 48.086 mi 20 20.260 17.984 20 20.376 mi 47 47.425 mmi 47 47.000 NMI 17 17.200 mi 17 16.612 mi 8cuP 020199:: quantitated and printed by L.;.@@ Quantity compound su@ry Report Rat Urine method D@LOP@nt. 899 ga"le Lt;t: : S:\rACT-I.PW\SAMPLOD:\,05039gb Last m*dL &ad Mattkod: Last mod&fiod: man may 03 14:01:10 1 9 S: \rACT-1. PW\MothDS@030399b Tue Stay 04 11:09:51 1999 Job Code: Printed: rri bfty 21 11:34:44 1999 Compound 3: M313 m@ 1I OS0399006 2 050399001 3 05039:001 4 0503:9009 5 0503 010 OS0399011 17 OS0399012 a 050399013 9 050399014 10 050399015 11 050399016 12 050399017 13 050399010 14 0503:"19 15 0503 9020 If OS0399021 17 050399022 10 050399023 19 050399024 20 050399025 21 050399026 22 050399027 24 05039"29 25 050399030 26 050399031 27 05039:032 28 05039 033 29 050399034 30 050399035 31 050399036 32 030399031 33 0503::03: 34 0503 03 35 050399040 36 050399041 37 050399042 S&API;IiOt T*Zt HO(M larlk N*OH Blank UMWNO0J1I1 RRBBSSOO:22:9S-_WSBsI:lnkn-kI-I MW011 R3504289-S ppb-I GEMOII ROS042:::10 ppb-I GZNO 11 RBSO 42 2S ppb-I GEMOII RBS04299-SO ppb-I GEKOII R8304299-100 ppb-I MOOM Blank X&OR Blank GZNOI1 RILS04289-WBlank-I GENOIL, 9394 (0.09 iLL) GENOII, GZNOII. GZN011, GEN011, GUOII 9395 40.07 9396 40.08 9397 10.07 9398 (0.07 A3304289-50 aLl aLl aL) aL) ppb-I N*M Blank GENOII RBS04289-931&nk-I GEMOLL, GEN011, 9399 9400 10.07 &L) 10.07 aL) GtNO11, 9401 10.08 aL) GEN011, 9402 (0.00 &L) GEMOII, 9403 (0.07 aL) GEN011 RBS04219-50 ppb-I GER011 RBS04209-250 ppb, KS GZNOI1 RBS04289-230 ppb, KSO GER011 RBS04209-50 ppb-I HEOR Blank GENOII RS504209-WBlank-2 GWOII RBS04289-Slklank-2 GZWMOOIIII RBS0428" ppb-2 RBS04299-10 ppb-2 GENOII GENOII GEN011 R3304299-25 RBS04269-SO RBS04299-100 ppb-2 ppb-2 ppb-2 ViLgo 3 Type Std Cono AT Anaiyt* Analyto An lyt An:lyt: Standard 4.93 9.76 Standard Standard Standard Analyto Analyto 24.10 49.30 97.60 Analyto Analyto Analyto Analyto Analyto Analyto QC Analyt* Analyto 49.30 Analyt* ..Analyto Analyto Analyt* Analyto oc Anslyto Anslyto oc Analyto Analyto Analyto Standard Standard Standard Standard Standard 49.30 49.30 4.93 9.76 24.80 49.30 97.60 Area Reopen@* Cona. Flags ODOV SOUP 020199:;quantLtatod and printed by QuantLEy Camp*wW S@ry Report Rat Ur&ne Method Do"lopmnt. egg 2mvIe LL*t: Last modlfted: method: Last wAdLfxod: Job Code: 2: \rACT-1. PW"amploDS\OS039gb NDn May 03 16:01:10 1999 2:\FACT-I.P=\NothDB\030399b Tue May 04 11:04:31 1999 PCLnted: rri May 21 11:34:44 1999 Comgxmnd 4: surc I Now 1 050399006 2 050399007 3 050399008 4 050399009 5 05039901D 1 050399011 7 050399012 a 050399013 9 050399014 10 050399015 11 050399016 12 050399017 L3 050399010 14 050399019 15 050399020 16 050399021 17 050399022 18 050399023 19 050399024 20 050399025 21 050399026 22 050399027 4 050399029 25 050399030 26 050399031 27 050399032 20 050399033 29 050399034 30 050399035 31 050399036 32 050399037 33 050399039 34 050399039 35 050399040 36 050399041 37 050399042 Samplallat Tazt HOON Blank N*M Blank GMOII ASS04209-NDIank-I GENOII R3304289-321&nk-I GENOZI R9304289-5 ppb-I GENOII RRS04289-10 ppb-I GtWOll R3504209-25 ppb-I GENOII RU04209-50 ppb-I CM011 RBS04289-100 ppb-I M*OX Blank M*OH Blank GENOII RAS04289-WBlank-I GEN011, 9394 10.09 UL) GZUCII, 9395 (0.07 nL) GENCII, 9396 40.00 &L) GENOII, 9397 JO.07 &L) GEMOII, 9399 (0.07 aLL) GENOII RBS04229-50 ppb-1 Ke(M Blank GENOII RBS042$9-WRI&nk-I GENOII, 9399 (0.07 aL) GEMOLI. 9400 (0.07 &L) GENOII. 9401 10.09 =L) GZNOII, 9402 (0.00 aL) GENO11, 9403 (0.07 aLL) MN011 R8304209-50 ppb-I MMOLI P3304269-250 ppb, ms GCNOII ASS04289-250 ppb, Nso =UCI1 R35042S9-30 ppb-I mook Blank GZNOII RDS04209-MBI&nk-2 GZNOII RU04209-SBlank-2 =Mll RBS04289-5 ppb-2 GINOII RRS04289-10 ppb-2 GEUOII R3304209-25 ppb-2 GZNOII GEMOZI RDS04219-50 RBS04289-100 ppb-2 ppb-2 Type Analyto Analyto Analyte Analyto Standard Standard Standard Standard Standard Analyto Analyto Analyte. Analyt* ArLalyto An&Lyt* Analyto Analyto oc Analyto Analyto Analyto Anglyt Analyt: Analyto Analyto oc Analyto Analyto oc Analyto Analyto Analyto Standard Standard Standard Standard Standard Std Cona RT Area Response 1.00 1.00 1.00 1.00 1.00 5.016 5.008 5.022 5.002 5.009 5.005 5.022 1624 1839 1749 1075 1791 1535 1091 1624.026 1939.452 1769.444 1675.130 1790.796 1535.177 le90.$29 1.00 5.010 5.012 S.004 5.012 5.012 5.012 5.006 1393 3937 4504 4072 4269 3433 1702 5.032 2179 5.001 4258 6-_@_-AIL" ----rbolS 5032 4.994 4395 1.00 5.006 3.016 7774 1979 5.010 4326 5.013 3993 1.00 5.007 2442 1.00 1.00 1.00 1.00 1.00 5.026 5.009 5.014 5.023 5.006 3.027 5.013 1896 2227 2203 2162 2241 2449 2194 1493.356 3937.170 4583.925 4072.485 4269.604 3633.260 __174-1.350 2179.290 4257.904 4043.063 5032.063 43$4.549 7774.321 1970.790 4326.159 3993.073 2442.139 1996.270 2226.930 2202.940 2161.525 2241.125 2448.654 2194.037 Cone. rlago toov 0.01 bb 0.91 bb 0.60 bb 0.93 bb 0.99 bb 0.76 bb 0.94 bb -19 -9 -12 -7 -11 -24 -6 0.94 bb 1.96 bb 2.28 bb 2.03 bb 2.12 bb 1.81 bb 0.$9 bb 1.08 bb 2.12 bb 2.41 bb 2.50 bb 2.19 bb 3.87 bb 0.99 bb 2.15 bb 1.99 bb 1.21 bb 0.94 bb 1.11 bb 1.10 bb 1.07 bb 1.11 bb 2.22 bb 1.09 bb -6 96 128 103 112 el -11 a 112 141 150 119 287 -2 115 99 21 -6 12 10 7 11 22 9 soup 020199: :quan"t&tod and pr&nted by Quantaty Compound 3@ry Report R&t Uc&fts "OthOd 9)svslDF@t. SZZ SMVIG L4;t: : 9:%rACT-I.MkO\SMWIODS%GS039gc Last soft Led Man May 03 16:43:03 1999 method: S:\TACT-I.MW\Noth0m\OS03990 ,.at Modified: Fri May 21 12:01:34 1999 Job Code: Pr&nted: rcL Hey 21 12:04:05 1999 Compound 2: PTOL%A N01-.199043 2 050399044 3 050329045 4 050399044 5 050399047 6 050399048 7 OS0399049 1 050399050 9 050399051 10 050399052 11 050399033 12 050399054 13 050399055 145 050399056 1 OS0399057 16 050399054 17 050399059 10 050399060 19 OS0399061 20 050399062 21 050399063 22 050399044 24 OS0399066 25 050399067 26 050399060 27 05039"109 20 0303,90 29 050399071 30 050399072 31 050399073 32 050399074 33 050399075 34 050399076 35 050399077 36 050399078 37 050399079 amwimilat Text MOOM almk HOOK Blank GZNOII RBS04209-WBI&nk-I GrXOll RBS04209-SBiank-I GENCII RW04219-5 ppb-I GENOII R8304219-10 ppb-I GENOII RBS04289,-25 ppb-I GENOLI RS304259-50 ppb-I GENOII RBS04209-100 ppb-1 M*OH Blank Me(M Blank GENOII RDS04209-USlank-I GENOII, 9394 10.09 iLL) GZNOII, 9395 (0.07 3LL) GENOII, 9394 40.09 iLL) GZNOII, 9397 10.07 aLL) CMNDII, 9391 (0.07 aL) GZNOII RBS042$9-50 ppb-I M*M Blank =UOll AN04209-*Blank-I GENOLI, 9399 (0.07 aL) GZNOII, 9400 (00:07 UL) GZXOII, 9401 f 00 &L) GENOII, 9402 (0.01 aL) GEMOLI, 9403 10.07 aL) GENOII RS304219-50 ppb-I GZNOII RBS04289-250 ppb, NS GENOLI RAS04289-250 ppb, NSD GMOII R3304209-50 ppb-I NOOK Blank GZNOII RDS04289-VBI&nk-2 GENOII R3304289-SBlank-2 GENOII RgS04209-5 ppb-2 GEN012 RBS04289-10 ppb-2 GEUOII RS304269-25 ppb-2 GEN012 RBS04289-50 ppb-2 GEN011 PJSS04299-100 ppb-2 page 2 TY" Analyte Analyto Analyt* Analyto Standard Standard Standard Standard Standard Analyto Analyt* An4lyt*' Analyto Analyto Anslyto Anslyto Analyto QC Analyto Analyto Analyte An&IYtt Analyt* Analyto Analyto oc Analylts Analylts cc Analyto Analyto Analyt* Standard Standard Standard Standard Standard Stcl Cone itT 4.93 9.76 24.80 49.30 97.60 5.649 5.688 5.690 5.647 5.691 5.649 5.487 5.650 49.30 5.499 -,.@@83 49.30 49.30 5.565 5.645 5.947 5.645 5.144 5.664 5.647 4.93 9.76 24.00 49.30 97.60 5.646 S.690 5.645 5.649 5.675 Area Response Cone. rlaga %Dev 55 54.972 4.14 M -16 111 117.791 10.42 bb 7 277 276.567 26.20 bb 6 517 516.974 50.30 bb 2 948 94B.112 93.3) bb -4 29 20.854 1.54 MM 33 32.863 1.94 MN 29 29.018 1.56 mm 515 5LB.321 30.13 bb 2 13.654 0.02 M is 15.192 0.2S M 34 35.720 2.23 M 431 551.303 63.72 bb 29 2217 2217.426 220.16 bb 2102 2102.170 208.65 bb 529 528.553 51.46 bb 4 31 31.433 1.80 mm 62 62.194 4.97 MN -1 109 109.232 9.57 bb -2 273 272.800 25.91 bb 4 539 539.138 52.51 bb 7 969 968.504 95.40 M -2 soup 020199::quantAtated and printed by me*-4043~