Document Vea8D0JM3M0pr6yQmYoko1Qp
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C :\Mass Lynx\P FOA. P RO\pf36k292s .qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Name: pf36k2990, Date: 30-Nov-2006, Tim e: 02:38:16, ID: 930.86.8, Description: 2 0 //g /L
PFOS pf36k2990 Smooth(Mn,2x3) 20 ( jg fl 930.86.8
MRM of 5 ctiannels.ES498.6>98.8
Page 148 of 148
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
8.18 8.18 8.18 9.03
60245313 60245.313 32866.145 51030.070
bb bb bb bb
32866.145 32866.145
32866.145
3 18.331 3 18.331 0 32866.145 3 15.527
19.808 20.621
9.701 20.842
99.0 99.0 97.0 104.2
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0,2 00 6 07:09:11 Mountain Standard Time
Name: pf36k2990, Date: 30-Nov-2006, Tim e: 02:38:16, ID: 930.86.8, Description: 2 0 //g /L
PFOA13C2
pf36k2990 Smooth<Mn.2x1) 20 pg/L 930.86.8
PFOA13C2 MRM of 5 channels,ES-
8.18
414.7 > 369.9
PFOS
pf36k2990 Smooth(Mn.2x3) 20 //g/L 930.86.8
100-,
Page 147 of 14f
PFOS 9.03 51030.07
MRM of 5 channels.ES498.6 > 79.9 1.716e+005
' I "j I I l I J T i l l J :
2.0 4.0
"l 'T' ]i't r r j "
6.0
- r - p r-r-r min
8.0 10.0
Analyst: Steve Cowling
Quantify Sample Report
M a ssLyn x4 .1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2990, Date: 30-Nov-2006, Tim e: 02:38:16, ID: 930.86.8, Description: 20 /jq IL
APFO
pf36k2990 Smooth(Mn,2x1) 20 /jg/L 930.86.8
APFO 6.18
MRM of 5 channels,ES412.7 > 368.9
APFO
pf36k2990 Smooth(Mn,2x1) 2 0 jug/L 930.86.8
Page 146 of 14
APFO 8.18
MRM of 5 channels.ES412.7 >218.9
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Tim e
Name: pf36k2990, Date: 30-Nov-2006, Tim e: 02:38:16, ID: 930.86.8, Description: 20 fjg IL
PFOA pf36k2990 Smooth(Mn,2xl) 20 fjgIL 930.86.8
PFOA 8.1
MRM of 5 channels,ES412.7 > 368.9
PFOA pf36k2990 Smooth(Mn,2x1) 20 //g /L 930.86.8
Page 145 of 148
PFOA 8.18
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2989, Date: 30-Nov-2006, Tim e: 02:25:20, ID: 930.86.7, Description; 1 0 //g /L
PFOS
pf36k2989 Smooth(Mn,2x3) 10 pg/L 930.86.7
MRM of 5 channels,ES498.6>98.8
Page 144 of 14f
1 ,rrvA 5 2APFO
3 PFOA13C2 * 3 8 ^ 4 FFOS
8.18 8.18 8.18 9.06
30274.820 30274.820 33222.512 25785.563
bb bb bb bb
33222.512 ' 33222.512
33222.512
OBegBiifefeergtBB
3 9.113 3 9.113 0 33222.512 3 7.761
9.778 10.180
9.807 10.359
97.8 97.8 98.1 103.6
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C :\MassLynx\PFOA.PRO\pf36k292s.q Id
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Name: pf36k2989, Date: 30-Nov-2006, Time: 02:25:20, ID: 930.86.7, Description: 10 pg/L
PFOA 13C2
pf36k2989 Smooth(Mn,2x1) 10 ^g/L 930.86.7
PFOA 13C2 8.18
MRM of 5 channels.ES414.7 >369.9
PFOS
pf36k2999 Smooth(Mn,2x3) 10//g /L 930.86.7
Page 143 of 148
MRM of 5 channels ES498.6 > 79.9
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2989, Date: 30-Nov-2006, Time: 02:25:20, ID: 930.86.7, Description: 10p g /L
APFO
APFO
Page 142 of 148
Analyst: Steve Cowling
Quantify Sample Report
MMaasssL yn x 44.11
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qId
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Tim e
Name: pf36k2989, Date: 30-Nov-2006, Tim e: 02:25:20, ID: 930.86.7, Description: 1 0 //g /L
PFOA pf36k2989 Smooth(Mn,2x1)
PFOA
MRM of 5 channels.ES-
PFOA
pf36k2989 Smooth(Mn.2x1) 10 jjQtL 930.86.7
;
Page 141 of 148
PFOA 8.18
MRM of 5 channels.ES412.7 > 218 .9
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA_PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2988, Date: 30-Nov-2006, Tim e: 02:12:23, ID: 930.86.6, Description: S /jg /L
PFOS
pf36k2988 Smooth(Mn,2x3) 5 //g/L 930.86.6
MRM of 5 channels,ES498.6>98.8
Page 140 of 148
W igs 1 PFOA 2 APFO 3PFO A 13C 2 4 PFOS
8.18 8.18 9.03
15540.666 15540.666 34709.254 12969.129
bb bb bb bb
34709.254 34709.254
34709.254
3 4.477 3 4.477 0 34709.254 3 3.737
4.755 4.951 10.246 4.966
95.1 95.1 102.5 99.3
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2988, Date: 30-Nov~2006, Time: 02:12:23, ID: 930.86.6, Description: 5 //g /L
PFOA13C2
pf36k2988 Smooth(Mn,2x1) 5 pg/L 930.86.6
PFOA13C2 MRM of 5 chanrtels.ES-
8.18
414.7 > 369.9
PFOS
pf36k2988 Smooth(Mn,2x3) 5 pg/L 930.86.6
'
Page 139 of 148
MRM of 5 channels.ES498.6 > 7 9 .9
p. 10
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2988, Date: 30-Nov-2006, Tim e: 02:12:23, ID: 930.86.6, Description: 5 jjg IL
APFO pf36K2988 Smooth(Mn,2x1) 5 //g/L 930.86.6
APFO 8.18
MRM of 5 Channels,ES412.7 > 368.9
APFO
pf36K2988 Smooth(Mn,2x1) 5 UQIL 930.86.6
Page 138 of 14
APFO 8.20
MRM of 5 charmeIs,ES412.7 > 218.9
p. 11
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Tim e
Name: pf36k2988, Date: 30-Nov-2006, Tim e: 02:12:23, ID: 930.86.6, Description: 5 p g /L
PFOA
pf36k2988 Smooth(Mn,2x1) 5 //g/L 930.86.6
PFOA 8.18
MRM of 5 channels.ES412.7 > 368.9
PFOA
pf36k2988 Smooth(Mn,2x1) 5 jqIL 930.86.6
Page 137 of 148
PFOA 8.20
MRM of 5 channels,ES412.7 >218.9
p. 12
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2987, Date: 30-Nov-2006, Time: 01:59:25, ID: 930.86.5, Description: 2 //g /L
PFOS pf36k29S7 Smootn(Mn,2x3)
MRM of 5 channels,ES-
Page 136 of 14
p. 13
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2987, Date: 30-Nov-2006, Tim e: 01:59:25, ID: 930.86.5, Description: 2 //g /L
PFOA 13C2
pf36k2967 Smooth(Mn,2x1) 2 //g/L 930.86.5
PFOA13C2 8.18
MRM of 5 channels,ES4 U .7 > 369.9
PFOS
pf36k2987 Smooth(Mn,2x3) 2 //g/L 930.86.5
Page 135 of 14f
MRM of 5 channels.ES498.6 > 7 9 .9
p. 14
Analyst: Steve Cowling
Quantify Sample Report
M as sL y n x 4 .1
PFOA Analysis
Dataset:
C:VMassLynxVPFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard'Time
Name: pf36k2987, Date: 30-Nov-2006, Tim e: 01:59:25, ID: 930.86.5, Description: 2 j/g /L
APFO pf36k2987 Smooth(Mn,2x1) 2 p Q /l 930.86.5
APPO 8.18
MRM of 5 channels.ES412.7 > 36S.9
APFO
pf36k2987 Smooth(Mn.2x1) 2 //g/L 930.86.5
;
Page 134 of 148
APFO 8.20
MRM of 5 channels.ES412.7 >218.9
p. 15
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2987, Date: 30-Nov-2Q06, Tim e: 01:59:25, ID: 930.86.5, Description: 2 //g /L
PFOA pf36k2987 Smooth(Mn,2x1) 2 //g/L 930.86.5
PFOA 8.18
MRM of 5 channels,ES4 1 2.7> 368.9
PFOA
pf36k2987 Smooth(Mn,2x1) 2 //g/L 930.86.5
Page 133 of 148
PFOA 8.20
MRM of 5 channels,ES412.7 >218.9
p. 16
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4,1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qId
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Name: pf36k2986, Date: 30-Nov-2006, Tim e: 01:46:29, ID: 930.86.4, Description: 1 f/g/L
PFOS
pf36k2986 Smooth(Mn,2x3)
1 f/g/L 930.86.4
MRM of 5 channels,ES498.6>98.8
Page 132 of 148
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
g y g js g j
8.18 8.18 8.15 9.03
3403.384 3403.384 35184.527 2753.079
bb bb bd bb
35184.527 35184.527
35184.527
3 0.967 3 0.967 0 35184.527 3 0.782
0.961... 1.000 10.386 1.024
96.1 96.1 103.9 102.4
Analyst: Steve Cowling
p. 17
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2986, Date: 30-Nov-2006, Tim e: 01:46:29, ID: 930.86.4, Description: 1 //g /L
PFOA13C2
pf36IC2986 Smooth(Mn,2x1) 1 //g/L 930.86.4
PFOA13C2 8.15
MRM of 5 channels,ES414.7 > 369.9
PFOS
pf36k2986 Smooth(Mn,2x3) 1 //g/L 930.86.4
:
Page 131 of 148
MRM of 5 channels.ES498.6 > 79.9
p. 18
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qid
Last Altered: Thursday. November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2986, Date: 30-Nov-2006, Tim e: 01:46:29, ID: 930.86.4, Description: 1 fig lL
AFFO pf36k2986 Smooth(Mn.2x1)
APFO
APFO MRM of 5 channels.ES- pf36k2986 Smooth(Mn.2x1)
:
Page 130 of 14
APFO
MRM of 5 channels.ES-
p. 19
Analyst: Steve Cowling
Quantify Sample Report
M assL yn x4.1
PFOA Analysis
Oataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Time
Name: pf36k2986, Date: 30-Nov-2006, Tim e: 01:46:29, ID: 930.86.4, Description: 1 fjg lL
PFOA pf36k2986 Smooth{Mn,2x1) 1 pg/L 930.86.4
PFOA 8.18
MRM of 5 channels.ES412.7 > 368.9
PFOA
pf36k2986 $mooth(Mn,2x1) 1 //g/L 930.86.4
;
Page 129 of 148
PFOA 8.18
MRM of 5 channels,ES412.7 >218.9
p. 20
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\Massl_ynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Name: pf36k2985, Date: 30-Nov-2006, Tim e: 0 1 :33:32, ID: 930.86.3, D escription: 0,5 #/g/L
PFOS pf36k2985 Smooth(Mn.2x3) 0.5/jgfL 930.86.3
MRM of 5 channels,ES498.6>98.8
Page 128 of 148
1 PFOA" " 2APFO 3 PFOA13C2 4 PFOS
..................8 .1 5 " * * 117726.087
8.15
1726.087
8.15 33514.785
9.03
.1370.478
bb bb bb bb
33514.785 33514.785
33514.785
3 0.515*' 3 0.515 0 33514.785 3 0.409
ilr 0.472
0.492
9.893
0.527
94.5 94.5 98.9 105.4
Analyst: Steve Cowling
p. 21
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Tim e
Name: pf36k2985, Date: 30-Nov-2006, Tim e: 01:33:32, ID: 930.86.3, Description: 0.5 //g /L
PFOA13C2
pf36K2965 Smooth(Mn,2x1) Q.5//g/L 930.66.3
PFOA13C2 8.15
MRM of 5 channels,ES4 U .7 > 369.9
PFOS
pf36k2985 Smooth(Mn,2x3) 0 .5 //g/L 930.86.3
'
Page 127 of 146
MRM of 5 channels,HS498.6 > 7 9 .9
p. 22
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA.PRQ\pf36k292s.qid
Last Altered: Thursday, November 30, 2006 07:08:01 Mountain Standard Time
Printed:
Thursday, November 30, 2006 07:09:11 Mountain Standard Tim e
Name: pf36k2985, Date: 30-Nov-2006, Tim e: 01:33:32, ID: 930.86.3, Description: 0.5 jjg IL
APFO pf36k2985 Smooth(Mn.2xl) 0.5 jug/L 930.86.3
APFO 8.15
MRM of 5 channels.ES412.7 > 368.9
APFO
pf36k2985 Smooth(Mn,2x1) 0 .5 //g /L 930.86.3
;
Page 126 of 14f
APFO 8.15
MRM of 5 channels.ES412.7 >218.9
p. 23
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4 ..
PFOA Analysis
Dataset:
C:\MassLynx\PFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2985, Date: 30-Nov-2006, Tim e: 01:33:32, ID: 930.86.3, Description: 0.5 f/g/L
PFOA
pf3Sk2985 Smooth(Mn,2x1) 0 .5pg/L 930.86.3
PFOA 8.15
MRM of 5 channels.ES412.7 > 368.9
PFOA
pf36k2985 Smooth(Mn,2x1) 0.5 ^g/L 930.86.3
P age 125 of 148
PFOA 8.15
MRM of 5 channels.ES412.7 >218.9
p. 24
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\Ma$sLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2984, Date: 30-Nov-2006, Time: 01:20:35, ID: 930.86.2, Description: 0.2 p g iL
PFOS
pf36k2984 Smooth(Mn,2x3) 0 .2 //g/L 930.86.2
MRM of 5 channels,ES498.6>98.8
Page 124 of 146
4 .|| ?
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
MS 8.18 8.18 8.18 9.03
873.683 873.683 33395.363 553.135
bb bb bb bb
33395.363 33395.363
33395.363
if
i
3 0.262
3 0.262
0 33395.363
3 0.166
0.199 0.207 9.858 0.203
99.5 99.4 98.6 101.6
Analyst: Steve Cowling
p. 25
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset
C:\MassLynx\PFOA.PRO\pf36kL92s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Name: pf36k2984, Date: 30-Nov-2Q06, Time: 01:20:35, ID: 930.86.2, Description: 0.2 pg/L
PFOA13C2 pf36k29S4 Smooth(Mn,2x1)
PFOS PFOA13C2 MRM of 5 channels,ES- pf36k2984 Smooth(Mn,2x3)
Page 123 of 148 MRM of 5 channels,ES-
p. 26
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
CAMassLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2984, Date: 30-Nov-2006, Tim e: 01:20:35, ID: 930.86.2, Description: 0.2 p g lL
APFO
pf36k2984 Smooth(Mn,2x1) 0.2 fjg/L 930.86.2
APPO 8.18
MRM of 5 channels.ES41Z 7 > 368.9
APFO
pf36k2984 Smooth(Mn.2x1 ) 0 .2 /g/L 930.86.2
Page 122 of 148
APFO a. 15
MRM of 5 channels,ES412.7 >218.9
p. 27
Analyst: Steve Cowling
Quantify Sample Report
M a s s L y n x 4 .1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Name: pf36k2984, Date: 30-Nov-2006, Tim e: 01:20:35, ID: 930.86.2, D escription: 0 .2 jug/L
PFOA pf36k2984 SmooUi(Mn,2x1) 0.2 jL/g/U 930.86.2
PFOA 8.18
MRM of 5 channels.ES412.7 > 368.9
PFOA pf36k2984 Smooth(Mn.2x1) 0 .2^g/L 930.86.2
Page 121 of 14
PFOA 8.15
MRM of S channels,ES412.7 >218.9
p. 28
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Name: pf36k2983, Date: 30-Nov-2006, Tim e: 01:07:39, ID: 930.86.1, Description: Blank
PFOS pf36k2983 Smooth(Mn,2x3) Blank 930.66.1
MRM of 5 channels,ES498.6>98.8
Page 120 of 148
>4 . -^ I '
'w'osrivvv ' 1 PFOA
2 APFO
3 PFOA13C2
4 PFOS
MwwwiiK-1
8.15 8.15 8.15
258.814 258.814 37380.000
bbi bbl bd
37380.000 37380.000
37380.000
3 0.069 3 0.069 0 37380.000 3
11.034 110.3
Analyst: Steve Cowling
p. 29
Quantify Sample Report
M assLynx 4.*t
PFOA Analysis
Dataset:
C:VMassLynx\PFOA.PRO\pf36k292s.qId
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0,2 00 6 07:09:11 Mountain Standard Time
Name: pf36k2983, Date: 30-Nov-20Q6, Tim e: 01:07:39, ID: 930.86.1, Description: Blank
PFOA13C2 pf36K2983 Smooth{Mn,2x1) Blank 930.86.1
PFOA13C2 8.15
MRM of 5 ehannels.ES414.7 > 369.9
PFOS pf36k2983 SmootH(Mn,2x3) Blank 930.86.1
:
Page 119 of 148
MRM of 5 channels,ES498.6 > 79.9
p. 30
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFOA Analysis
Dataset:
C:\MassLynxVPFOAPRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Time
Name: pf36k2983, Date: 30-Nov-2006, Tim e: 01:07:39, ID: 930.86.1, Description: Blank
APFO
p(36k2983 Smooth(Mn,2x1) Blank 930.86.1
APFO 8.15
MRM of 5 channels,ES4 1 Z 7 > 368.9
APFO pf36k2983 Smooth(Mn,2x1) Blank 930.86.1
Page 118 of 14
MRM of 5 diannels.ES412.7 >218.9
p. 31
Analyst: Steve Cowling
Quantify Sample Report
MassLynx 4/i
PFOA Analysis
Dataset
C:\MassLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, November 3 0 ,2 0 0 6 07:08:01 Mountain Standard Time
Printed:
Thursday, November 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Name: pf36k2983, Date: 30-Nov-2006, Tim e: 01:07:39, ID: 930.86.1, Description: Blank
PFOA pf36k2963 Smooth(Mn,2xl) Blank 930.86.1
PFOA 8.15
MRM of 5 channels.ES412.7 > 368.9
PFOA pf36k2963 Smooth(Mn.2x1) Blank 930.86.1
100-1
Page 117 of 148
MRM of 5 channels.ES412.7 > 218.9 2.291e+002 11.55
/
10.94
10.40
ri q i r i i | i i i i
10.0
m in
p. 32
Analyst: Steve Cowling
P. 33:
Quantify Sample Report
M assLynx 4.1
PFO A Analysis
D ata s e t:
C :\M assLynx\PFO A.PRO \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
N am e: p f36k2975, D ate: 29-N o v-2006, T im e: 23:24 :0 2, ID : JJV7E1A A , D escrip tio n : D 6K 160299-5
APFO
pf36K2975 Smooth(Mn,2x1) D6K160299-5 JJV7E1AA
APPO 8.18
MRM of 5 channels,ES412.7 > 368.9
APFO
pf36k2975 Smooth(Mn,2x1) D6K160299-5 JJV7E1AA
Page 86 of 148
APFO 8.18
MRMof5channels.ES412.7 >218.9
Analyst: Steve Cowling
Q u an tify S am ple R ep o rt
M assLynx 4.1
PFO A Analysis
D atas e t:
C:\M assLynxVPFOAPRO \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
N am e: p f36k2975, D ate: 29-N o v-2006, T im e: 2 3:24:02, ID : JJV7E1A A , D escrip tio n : D 6K 160299-5
P FO A 13C 2
PFOS
Page 87 of 148
Analyst: Steve Cowling
Q u an tify S am ple R eport
M assLynx 4.1
PFO A Analysis
D ata s e t:
C:\M assLynx\PFO A.PRO \pf36k292s.qld
Last Altered: Thursday, Novem ber 30, 2006 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
in ' ~ --fO
6.
N am e: p f36k2975, D ate: 29-N o v-2006, T im e: 2 3:24:02, ID : JJV7E1A A , D escrip tio n : D 6K 160299-5
"
PFOS pf36k2975 Smooth(Mn,2x3) D6K160299-5 JJV7E1AA
100-1
PFOS 8.96 1 4845.80
MRM of 5 channets,ES49.e>98.8 1,365e+004
' ---------
Page 88 of 148 ~------------ ------ ------ ---------- ------------------------------------- -
%
Analyst: Steve Cowling
Q u a n tify Sam ple R eport
M assL ynx 4.1
P FO A Analysis
D a ta s e t:
C :\M assLynx\PFO A.PRO \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Brinted:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
N am e: pf36k2976, D ate: 2 9-N o v-2006, T im e: 2 3:36:59, ID : JJV 7F1A A , D escrip tio n : D 6K 160299-6
PFOA pf36k2976 Smoolh(Mn.2x1) D6K160299-6 JJV7F1AA
PFOA 8.15
MRM of 5 channels.ES412.7 > 368.9
PFOA
pf36k2976 Smooth(Mn,2x1) D6K160299-6 JJV7F1AA
Page 89 of 14E
PFOA 8.20
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
Q u antify S am ple R eport
M assLynx 4.1
Page 90 of 148
PFOA Analysis
D ata s e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
hfO=--------------------------------------------------------------------------------------------------------------------------------------------------- ------------------------------------------------------------------------ -------- -- --------- -------- -----------------
.
Nam e: p f36k2976, D ate: 29-N o v-2006, T im e: 2 3:36:59, ID : JJV7F1A A , D escrip tio n : D 6K 160299-6
APFO
pf36k2976 Smooth(Mn,2x1) D6K160299-6 JJV7F1AA
APFO 8.15
M R M of5channels.eS412.7 > 368.9
APFO
pf36k2976 Smooth(Mn,2x1) D6K160299-6 JJV7F1AA
'
APFO 8.20
MRM of 5 channets.ES412.7 >218.9
Analyst: Steve Cowling
Q u an tify Sam ple R ep o rt
M assl_ynx4.1
P FO A Analysis
D atas e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday. Novem ber 30, 2006 07:08:01 Mountain Standard Tim e
Brinted:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 M ountain Standard Tim e
Nam e: p f36k2976, D ate: 29-N o v-2006, T im e: 2 3:36:59, ID : JJV7F1A A , D escrip tio n : D 6K 160299-6
PFO A 13C 2
pf36k2976 Smooth(Mn,2x1) D6K160299-6 JJV7F1AA
PFOA13C2 8.15
MRM of 5 channels.ES414.7 > 369.9
PFOS
pf36k2976 Smooth(Mn.2x3) D6K160299-6 JJV7F1AA
P ag e91o f14
MRM of 5 channels.ES498.6 > 79.9
Analyst: Steve Cowling
p. 39 -Vf 1 w.
Q u an tify S am ple R eport
M assL ynx 4.1
PFO A Analysis
D ata s e t:
C:\M assLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
N am e: p f36k2976, D ate: 29-N o v-2006, T im e: 2 3:36:59, ID: JJV7F1A A , D escrip tio n : D 6K 160299-6
PFOS
pf36k2976 Smooth(Mnt2x3) D6K160299-6 JJV7F1AA
100-,
PFOS 8.96 1 4995-40
MRM of 5 channels,ES498.6>98.8 1.405e+004
%-
- p r I T ' I ' I ' T i'T " I | i',i'lll f |~ Y "
4 bI 1 ` 1 * I 1 1 1 1 1 1 1 1 1 l 1 1 - p - r -
min
2.0 4.0 6.0 8.0 10.0
" llllll
1 pfoa
2PFO 3P FO A 13C 2 4 PFOS
8.15 8.15 8.96
HR 3425.200
3425.200 40320.957
8043.850
bb bb bb bb
40320.957 40320.957
40320.957
5 3 3 0 3
0.849 0.849 40320.957 1.995
0.016 0 .0 1 7 11.902 0.051
119.0
Analyst: Steve Cowling
Page 92 of 146
Q u an tify Sam ple R eport
M assLynx 4.1
PFO A Analysis
D ataset
C :\M assLynx\PFO A.PRO \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 08:00:46 Mountain Standard Tim e
Rsnted:
Thursday, Novem ber 3 0 ,2 0 0 6 08:04:48 Mountain Standard Tim e
M ethod: C :\M assL yn x\P F O A P R O lM eth D B \p a36k29sjn d b 30 N ov 2006 06:57:57 C alib ratio n : 30 Nov 2006 07:08:01
N am e: p f36k2977, D ate: 2 9-N o v-2006, T im e: 2 3:49:57, ID : JJV7G 1A A , D escrip tio n : D 6K 160299-7
PFOA pf36k2977 Smooth(Mn,2x1)
PFOA
PFOA M RM of5channels.ES- pf36k2977 Smooth(Mn,2x1)
Page 1 of 4
PFOA
MRM of 5 channels,ES-
Analyst: Steve Cowling
p .4 1 i
Q u an tify Sam ple R ep o rt
M assLynx 4.1
PFO A Analysis
D atas e t:
C:\M assLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 08:00:46 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 08:04:48 Mountain Standard Tim e
Nam e: p f36k2977, D ate: 29-N o v-2006, T im e: 2 3:49 :5 7, ID : JJV7G 1A A , D escrip tio n : D 6K 160299-7
APFO
pf36k2977 Smooth<Mn.2x1 ) D6K160299-7 JJV7G1AA
APFO 8.15
MRM of 5 channels,ES412.7 > 3 6 8 .9
APFO
pf36k2977 Smooth(Mn,2x1) 06K160299-7 JJV7G1AA
'
Page 2 of 4
APFO 8.13
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
Q u a n tity Sam ple R ep o rt
M assL ynx 4,1
PFO A Analysis
D a ta s e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 08:00:46 Mountain Standard Tim e
fa in te d :
Thursday, Novem ber 30, 2006 08:04:48 Mountain Standard Tim e
N am e: p f36k2977, D ate: 29-N o v-2006, T im e: 23:49 :5 7, ID : JJV 7G 1A A , D escrip tio n : D 6K 160299-7
P FO A 13C 2
pf36k2977 Smooth(Mn.2xl) D6K160299-7 JJV7G1AA
PFOA 13C2 8.13
MRM of 5 channete.ES414.7 > 369.9
PFOS
pf36k2977 Smooth(Mn,2x3) D6K160299-7 JJV7G1AA
Page 3 of 4
MRM of 5 channels,ES498.6 > 79.9
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFO A Analysis
D a ta s e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 08:00:46 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 08:04:48 Mountain Standard Tim e
N am e: p f36k2977, D ate: 29-N o v-2006, T im e: 23:49 :5 7, ID: JJV7G 1A A , D escrip tio n : D 6K 160299-7
PFOS pf36k2977 Smooth(Mn,2x3) D6K160299-7 JJV7G1AA
MRM of 5 channels,ES498.6>96.8
Page 4 of 4
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
8.15 8.15 8.13 8.96
5688.496 5688.496 40399.027 10357.889
bb bb bb bb
40399.027 40399.027
40399.027
3 1.408 3 1.408 0 40399.027 3 2.564
0.029 0.030 11.925 0.067
starts late 119.3
3 0 -N o v -0 6 30-NOV-06
Analyst: Steve Cowling
p. 44
Quantify Sample Report
M assLynx 4.1
PFO A Analysis
D ataset:
C :\M assLynx\PFO A PR O \pf36 k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: pf36k2978, D ate: 30-N o v-2006, T im e: 0 0:02:52, ID : JJV7H 1A A , D escrip tio n : D 6K 160299-8
PFOA pf36k2978 Smooth(Mn,2x1) 06K160299-8 JJV7H1AA
PFOA 8.15
MRM of 5 charoiels.ES412.7 > 368.9
PFOA
pf36k2978 Smooth(Mn,2x1) D6K160299-8 JJV7H1AA
;
Page97of14f
PFOA 8.18
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
Q u a n tify S am ple R ep o rt
M assL ynx4.1
PFO A Analysis
D atas e t:
C :\M assLynx\PFO A.PRO \pf36k292s.qId
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
ftrinted:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: p f36k2978, D ate: 30-N o v-2006, T im e: 0 0:02:52, ID: JJV7H 1A A , D escrip tio n : D 6K 160299-8
APPO
pf36k2978 Smooth(Mn.2xl) D6K160299-8 JJV7H1AA
APFO 8.15
MRM of 5 Channels,ES412.7 > 388.9
APFO
pf36k2978 Smooth(Mn,2x1) D6K160299-8 JJV7H1AA
P ag e98o f14i
APFO 8.18
MRM cf 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
p .4 6
Q u an tify Sam ple R eport
M assLynx 4.1
PFO A Analysis
D atas e t:
C:\M assLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday. Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 30, 2006 07:09:11 Mountain Standard Tim e
Nam e: p f36k2978, D ate: 30-N o v-2006, T im e: 0 0:02:52, ID : JJV7H 1A A , D escrip tio n : D 6K 160299-8
PFOA13C2
pf36k2978 Smooth(Mn,2x1) D6K160299-8 JJV7H1AA.
PFOA13C2 8.15
M RM of5channels.ES414.7 > 369.9
PFOS
pf36k2978 Smooth{Mn,2x3) D6K16Q299-8 JJV7H1AA
Page 99 of 14
MRM of 5 channels.ES498.6 > 79.9
Analyst: Steve Cowling
Q u a n tify -Sample R eport
M assLynx 4.1
PFOA Analysis
D a ta s e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Rfjnted:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
N am e: p f36k2978, D ate: 30-N o v-2006, T im e : 00:02 :5 2, ID: JJV 7H 1A A , D escrip tio n : D 6K 160299-8
PFOS pf36k2978 Smooth(Mn,2x3) D6K160299-8 JJV7H1AA
MRM of 5 Channels,ES498.6>98.8
Page 100 of 148
1 PFOA 2 APFO 3 PFOA13C2 4 PFO.S
8.15 8.15 8.15 8.96
3029.045 3029.045 40178.684 4351.452
bb bb bb bb
40178.684 40178.684
4 0 1 7 8 .6 8 4
3 0.754 3 0.754 0 40178.684 3 1.083
0.015 0.015 11.860 0.028
118.6
Analyst: Steve Cowling
p. 48
Q u an tify Sam pie R eport
M assLynx 4.1
PFO A Analysis
D atas e t:
C:\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
N am e: pf36k2979, D ate: 30-N o v-2006, T im e: 00:15 :5 1, ID: JJV7X1A A , D escrip tio n : D 6K 160304-1
PFOA
pf36k2979 Smooth(Mn,2x1) D6K160304-1 JJV7X1AA
PFOA 7.93
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2979 Smooth(Mn,2x1) D6K160304-1 JJV7X1AA
page 101 o f 148
PFOA 7.93
M R M of5 channels,ES412.7 >218.9
Analyst: Steve Cowling
Q u antify S am p le R eport
M assLynx 4.1
PFO A Analysis
D atas e t:
C:\M assLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Painted:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: p f36k2979, D ate: 30-N o v-2006, Tim e: 00:15:51, ID : JJV7X1A A , D escrip tio n : D 6K 160304-1
APFO pf36k2979 Smooth(Mn,2x1) D6K160304-1 JJV7X1AA
APFO 7.93
MRM of 5 channels,ES412.7 >368.9
APFO
pf36k2979 Smooth(Mn,2x1) D6K160304-1JJV7X1AA
;
Page 102 of 148
APFO 7.93
MRMof5channels,ES412.7 >218.9
Analyst: Steve Cowling
p. 50
Q u an tify Sam ple R eport
M assLynx 4.1
P FO A Analysis
D a ta s e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
N am e: p f36k2979, D ate: 30-N o v-2006, T im e: 0 0:15:51, ID : JJV7X1A A , D escrip tio n : D 6K 160304-1
P FO A 13C 2
pf36K2979 Smooth(Mn,2x1) D 6K 16 0 3 0 4 -1 JJV7X1AA
PFOA13C2 7.93
MRM Of 5 channels,ES414.7 > 369.9
PFOS
pf36k2979 Smooth(Mn,2x3) D6K16 0 3 0 4 -1 JJV7X1AA
:
Page 103 of 14
PFOS MRM of 5 channels,ES-
8.84
498.6 > 7 9 .9
Analyst: Steve Cowling
Q u antify S am ple R eport
M assL ynx 4.1
PFO A Analysis
D ata s e t:
C:\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 M ountain Standard Tim e
N am e: p f36k2979, D ate: 30-N o v-2006, T im e: 0 0:15:51, ID : JJV7X1A A , D escrip tio n : D 6K 160304-1
PFOS pf36k2979 Smooth{Mn,2x3) D6K160304-1 JJV7X1AA
MRM of 5 channels,ES498.6>98.8
page 104 of 148
Analyst: Steve Cowling
Q u antify Sam ple R ep o rt
M assLynx 4.1
PFO A Analysis
D a ta s e t:
C:\M as$Lynx\PFOA.PRO \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: pf36k2980, D ate: 30-N o v-2006, T im e: 00:28:47, ID : JJV751A A , D escrip tio n : D 6K 160304-2
PFOA
pf36k2980 Smooth(Mn,2x1) D6K160304-2 JJV751AA
PFOA 8.13
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2980 Smooth(Mn.2x1) D6K160304-2 JJV751AA
Page 105 of 148
PFOA ' MRM of S channels,ES-
8.15
412.7 >218.9
Analyst: Steve Cowling
Q u an tify S am ple R ep o rt
M assLynx 4.1
PFO A Analysis
D atas e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
tin te d :
Thursday, Novem ber 30, 2006 07:09:11 Mountain Standard Tim e
N am e: p f36k2980, D ate: 30-N o v-2006, T im e: 0 0:28:47, ID: JJV751A A , D escrip tio n : D 6K 160304-2
APFO pf36k2980 Smooth(Mn.2x1) D6K160304-2 JJV751AA
APFO 8.13
MRM of 5 channels.ES412.7 > 368.9
APFO
pf36k2980 Smooth(Mn,2x1) D6K160304-2 JJV751AA
Page 106 of 14f
APFO 8.15
MRM of 5 channels.ES412.7 >216.9
Analyst: Steve Cowling
p. 54
Q u antify Sam ple R ep o rt
M assLynx 4.1
PFO A Analysis
D atas e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
N am e: pf36k2980, D ate: 30-Nov~2006, T im e: 0 0:28 :4 7, ID : JJV751A A , D escrip tio n : D 6K 160304-2
PFO A 13C 2
pf36k2980 Smooth(Mn,2x1) D6K160304-2 JJV751AA
PFOA13C2 8.15
MRM of 5 channels,ES414.7 > 369.9
PFOS
pf36k2980 Smooth(Mn,2x3) D6K160304-2 JJV751AA
Page 107 of 146
MRM of 5 channels ES498.6 >79.9
Analyst: Steve Cowling
Q u antify S am ple R eport
M assLynx 4.1
PFO A Analysis
D ata s e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
iIoO
"~
'
'' ~
Nam e: p f36k2980, D ate: 3 0-N o v-2006, Tim e: 00:28:47, ID : JJV 751A A , D escrip tio n : D 6K 160304-2
PFOS pf36k2980 Smooth(Mn,2x3) D6K160304-2 JJV751AA
MRM of 5 channels,ES498.6>98.8
'
""
Page 1 08 of 148
~
1 PFOA 2 APFO 3 PFOA13C2 4 PFOS
8.13 8.13 8.15 9.01
4967.577 4967.577 37522.9B0
207217
bb bb bb bb
37522.980 37522.980
37522.980
3 1.324 3 1.324 0 37522.980 3 0.055
0.026 0.028 11.076
0.001
110.8
Analyst: Steve Cowling
p. 56
Q u antify S am ple R eport
M assLynx 4.1
PFO A Analysis
D a ta s e t:
C :\M assLynx\PFO A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 30, 2006 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: p f36k2981, D ate: 30-N o v-2006, T im e: 0 0:41:44, ID : JJV791A A , D escrip tio n : D 6K 160304-3
PFOA
pf36k2981 Smooth(Mn,2x1) D6K160304-3 JJV791AA
PFOA 8.18
MRM of 5 channels,ES412.7 > 368.9
PFOA
pf36k2981 Smooth(Mn,2x1) D6K160304-3 JJV791AA
Page 109 of 14
PFOA 8.18
MRM of 5 channels,ES412.7 >218.9
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFO A Analysis
D a ta s e t:
C :\M assLynx\PFO A.PRO \pf36k292s.qld
Last Altered: Thursday, Novem ber 30, 2006 07:08:01 Mountain Standard Tim e
g lin te d :
Thursday, Novem ber 30, 2006 07:09:11 Mountain Standard Tim e
N am e: p f36k2981, Date: 30-N o v-2006, T im e: 0 0:41:44, ID : JJV 791A A , D escrip tio n : D 6K 160304-3
APFO pf36k2981 Smooth(Mn,2x1) 06K160304-3 JJV791AA
APFO 8.18
MRM of 5 channels,ES412.7 > 368.9
APFO
pf36k2981 Smooth(Mn,2x1) D6K160304-3 JJV791AA
Page 110 of 148
APFO 8.18
MRM of 5 oharmels.ES412.7 > 218.9
Analyst: Steve Cowling
p. 58
Q u antify Sam ple R ep o rt
M assLynx 4.1
PFOA Analysis
D ata s e t:
C :\M assL yn xV P F O A .P R O \p f36k292s.q ld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: pf36k2981, D ate: 30-N o v-2006, T im e: 00:41:44, ID : JJV791A A , D escrip tio n : D 6K 160304-3
PFOA 13C2
pf36k2981 Smooth(Mn.2x1) D6K160304-3 JJV791AA
PFOA13C2 8.15
MRM of 5 channels,ES414.7 > 369.9
PFOS
pf36k2981 Smooth(Mn,2x3) D6K160304-3 JJV791AA
Page m of 148
MRM of 5 channels,ES498.6 >79.9
Analyst: Steve Cowling
Quantify Sample Report
M assLynx 4.1
PFO A Analysis
D atas e t:
C:\M assLynx\PFO A.PRO \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
gptinted:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
N am e: p f36k2981, D ate: 30-N o v-2006, T im e: 0 0:41:44, ID: JJV 791A A , D escrip tio n : D 6K 160304-3
PFOS pf36(c2981 Smooth(Mn.2x3) D6K160304-3 JJV791AA
100-1
MRM of S channels,ES-
498.6>98.8
8.93
1.646e+002
Page 112 of 146
1 PFOA S-yfiSMt 2A P FO ^ J j | 3PFOA13C2
4 PFOS
8.18 8.18 8.15
943.854 943.854 34410.773
bb bb bb
mmm
34410.773 34410.773
34410.773
mm
3
0274
3 0.274
0 34410.773
3
0.004 0.004 10.157
101.6
Analyst: Steve Cowling
p. 60
Q u antify Sam ple R ep o rt
M assLynx 4.1
PFOA Analysis
D atas e t:
C :\M assLynx\PFQ A PR O \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: pf36k2982, Date: 30-N ov-2006, T im e: 00:54:40,- ID : JJV8E1A A , D escrip tio n : D 6K 160304-4
PFOA
pf36k2982 Smooth(Mn,2x1) D6K16034-4 JJV8E1AA
PFOA 8.13
MRM of 5 channels.ES412.7 > 368.9
PFOA pf36k2982 Smooth(Mn,2x1) D6K160304-4 JJV8E1AA
Page 113 of 148
PFOA 8.15
MRM of 5 channels.ES412.7 > 218.9
Analyst: Steve Cowling
p. 61
Q u antify S am ple R ep o rt
M assLynx 4.1
PFO A Analysis
D a ta s e t:
C:\M assLynx\PFOA-PRO\pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: p f36k2982, D ate: 30-N o v-2006, T im e: 00:54 :4 0, ID : JJV8E1A A , D escrip tio n : D 6K 160304-4
APFO
p(36k2982 Smooth(Mn.2xl) D6K160304-4 JJV8E1AA
APPO 8.13
MRM of 5 channels.ES412.7 > 368.9
APFO
pf36k2982 Smooth(Mn,2x1) D6K160304-4 JJV8E1AA
Page 114 of 146
APFO 8.15
MRM of 5 channels ES412.7 >218.9
Analyst: Steve Cowling
Q u an tify S am ple R eport
M assLynx 4.1
PFO A Analysis
D a ta s e t:
C:\M assLynx\PFO A.PRO \pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
(Mprinted:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: p f36k2982, D ate: 30-N o v-2006, T im e: 0 0:54:40, ID : JJV8E1A A , D escrip tio n : D'6K160304-4
P FO A 13C 2
p<36k2982 Smooth(Mn.2x1) D6K160304-4 JJV8E1AA
PFOA13C2 MRM of 5 channels,ES8.13 414.7 > 369 .9
PFOS
pf36K2982 Smooth(Mn,2x3) D6K160304-4 JJV8E1AA
:
Page 115 of 14*
M RM af5channels,ES498.6 > 79.9
Analyst: Steve Cowling
Quantify Sample Report
M a ssLyn x4 .1
PFOA Analysis
D ataset
C:\M assLynx\PFOA.PRO\pf36k292s.qld
Last Altered: Thursday, Novem ber 3 0 ,2 0 0 6 07:08:01 Mountain Standard Tim e
Printed:
Thursday, Novem ber 3 0 ,2 0 0 6 07:09:11 Mountain Standard Tim e
Nam e: pf36k2982, Date: 30-N o v-2006, T im e: 00:54:40, ID: JJV 8E 1A A , D escrip tio n : D 6K 160304-4
PFOS pf36k2982 Smooth(Mn.2x3) D6K160304-4 JJV8E1AA
MRW of 5 channels.ES498.6>98.8
Page 116 of 146
p. 63
Analyst: Steve Cowling
Attachment B
JXNITEDSTATES DISTRICT COWRvT
P lS T R C f O F jE k $ D A
EMERALD 0OAS D TU tlES
A D T H O R T i'y,
T iain H ffi
v.
3M CDMEANY*'et ai.,
& E N O .i
Defendants*I,3
*$HW f<ji|lp\*:$:
I, IMi .overtbege of.eigSteffttfern.
7am wmpetentandauthorizediowakethi3'I5elaratoa^d $iomttorssontalned thetcinarewithinmypersonalknowiedgeanii-trueand powect.
1-amjnsnftgprtfn
Healthaftd'Sa^^eriiorts rt'JM
Company) Ih ave hothahacheiior of^clepDeand wnsterspfspiepeedpgree In civil
engineering, M y master^ theslSciipmed IhjprpovSi.ofcoohnawahts^onx pubHe
dridlciiig'WSter systems,
3. As part ofmy wsponsihilUtes atSMCpfApshy,1hvc hf JrivlVedn :thcopTdliitont)fthedhstaltationofsystems deSgiied iori'riQvc perfluordoeiane sulfonate (PFO),:perfluoroctiiote'(3PFOA), and h&mo'idgohs perfluoritiated compunds.flromdrinkingwater system's, .la sodoing; LhaVebecome familiar with
EMRAt? COASrOTTI#
A i/T H O a iy ,
P ia ln H rn
V.
3M OMANY, et ai.,
Defendants123
NO.
% iy H e h 'e is ^ to w ^ ^ l^ ^ ^ H ^ v ^ ^ ^ s
1, My^aO30is<3aiyH^cnspftirt^ 1*m averSie-ge ofelgbtoetteaffi.
1sm Qiapetiit an atho^z4^ wal iW i ^ a r ^ ^ ^ d jtW^ftefeiaUiine
Jhetin ar wltWnmy;personal kndw|edge^an;tpuc!nd GTtect
2. T-aift.a
aviHtettlal, Health and'^fety^ettioas ttf3M
Company? Ipave bothafeacbefor of^i.enoeafld masicjsdfseineedegree in civil
rgttHfertagi Musser^ tbelscnrned thvfapoval/QobtaBMts^i> public
drriKtatg'M te r systems,
3, As port oftny responsibilUtesa't^M'Copany/1 bvebe ihvlVedfo
sulfonate PFQS), peffluoroct^te'iPFOA), and-bmoigous pffltthated compounds.from drinking water systems. 4n sodding, Ih'aVe become famlli&r wHh
1
p. 67
thetcosts asSoc.ia.tedwith the design, installation, maintenance,and operation of-sueh systems.
4. I ihaye reviewed ihe complaint filed bythe-Emerald Coast utilities Authority ( `E C U A 1") in the above-referenced matter, in particular,-I have reviewed
EQUA's demand formal!-necessary funds" to-design, oansiruet, instdil'i operate,,and maintain the IreatmeiH facilities end equipment necessary to remove ?EOA and PEGS to m the drinking water it supplies tothe public.
5. in .our expetience, (5AC is the tfeehnology o fChoice and the'rttost ousteffective headdress the presence o fPFCs in large scale, irriuriiclpal dflnkirig water
spppiyscettdriQS. 6. Thegfanular activatedcarbon (GACjtf'eatmChtsystem installed to
treat BECsjb & e 3 $ 'b ? Oakdale,iM fatf& dttcosfwctb than $2.hil8ii3il SBfi dptlgn
<Btsw*ttei#2.;$O'0 Jratehsper
h^SeSted hi
0akdnl6,,ftfliMy.foailahfe-.atM p ^ *S.
.412Bg5BqAecaVa70.PDF. Thisvtgure does nptJncrlude ppe.ratihg-eo.sit?! which iJ);5P0S
exceeded
,?v 1hayereviewedlhe 2 W iffincheial repojt-for'iO iJA ) publiciyayaiiahle abv^.ectfa.crc/nat/haC08.Pdh Which Indicates on page 7Jt that E C yA is 2008 supply
rate was l2,'l'9 million gallons, which 1s ip excessoFiSfiQO gallons-per minute,
neatjy 4Q iitnesihe rafe o fthe.Oakdale, MlnhesotasyStCm.- The reportalso indicates
thatEGUA served more than:S9;OOQ customers.
S. Although lam awareof-ho evidenceto suppori-theailcgafron'that
Pf'GS ftnd.pFpA are present in the EOUA water-supply, I haye assumed for the purpose ofthis declaration (and solely forthat purpose) that, asalleged in the
2
p. 68
Complaint {hose substances have been detected "at varying amounts and at vary ing times,1' Complaint, paragraph 43. I also note.that, jn addition -to the costs of installing a system capable ofremovingtheSe PFOA and P FC ^E laintlffseeks damages for (be cost o finvestigating and monitoring the alleged presence o f "PFOA
3nd/br;BFQSCoipplainij paragraph <3. Based uponm y training, daoatlori, mid
experience with treatment systems o f the Bud sought by'EC U A 'here, it is my.opinion to a reasonable degree o fscientific certahtfy that "ail accessary fttnds*' needed to destgn, cg,i)sirue.t, install, Operate, and maintaln a freatmerit system capabieOf .rempving'iPFOA and FFO$ for an authority with a-fioifate the size 0f.BOCiA',i would exceed $75,00.0,, A system for treating even a few w etls offhts average s izeo f those in the'EGlJA system would exceed $75,000.
Bated: August 14,200$
3
