Document VJrYZnN3wo0E01aGYnwmwzVY4

r A M. J- Caprio To: -- 6 A E> 411073 0355 J/AM^C^Jj ^J7m Une.it* j4j-ooTo 411073 0356 W. BENNETT LEWIS MAMACC* * wmtTlNC tCflVt. HARBISON-WALKER REFRACTORIES RECEIVED gZZSZZjW Division of Dresser Iadustfits, he .'UN 17 1985 0/w Gateway Center. Pittsburgh. Pennsylvania 15222 Industrial Hygien June 13, 1985 TfLt*MOM( 412 -942 -6410 Mr. M. J. Caprio Aluminum Company of America Alcoa Building Pittsburgh, PA 15219 J UN 14 1985 PU&C+MSiNu SUBJECT: MATERIAL SAFETY DATA SHEET(S) Dear Mr. Caprio: In response to your recent request, enclosed is(are) the following Material Safety Data Sheet(s): ALAMO S ALUSA BENEZET CALAMO 80 CEMENT PREMIXED WET CORAL PLASTIC H-W ES CASTABLE C GG-10-20 H-W 3-83 HARCHROME G KALA KORUNDAL GUN MIX LOTHERM PHOXBOND H-W SPECIAL MORTAR MIX TYPE B H-W SUPERDUTY MORTAR THERMOLITH / ! Me are presently having a sheet completed for H-W 27-78 Castable, and will forward a copy to you when we receive it from our Committee. Very truly yours, l/J. /A Manager-Marketing Services^ WBL/laj Enclosure! s) ; 3PgB W -.v .' .l-.a M U M . 411073 0357 Material Safety Data Sheet MftW harbisom walker refracto/hss Sinw ti Sfmmr /.Wimps. im.. 1 Stttmtr C*Mir. Hmkmtik. Hmfhm,* IS222 TEL9HONE: (411) 363-6700 TELETYPE: 710-664-4347 ________________________________________________ 10/01/84 DISCLAIMER This data sheet it bated on OSHA FORM 20 but modified to moro adoquatoly suit refractory products. All data aro subject to reasonable variation. This information is supplied in good faith by Harbison-Walker and it applicable to the product as shipped. Your application ef the product may change its characteristics. THE DATA PROVIDED HEREIN ARE BELIEVED CORRECT OR ARE OBTAINED FROM SOURCES BELIEVED TO BE GENERALLY RELIABLE. HARBISON-WALKER SHALL NOT BE LIABLE FOR ANY LOSS OR 0AMAGE DIRECTLY OR INDIRECTLY ARISING FROM THE USE OF THIS PRODUCT, AN0 HARBISON-WALKER ASSUMES NO OBLIGATION OR U ABILITY FOR REUANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is not part of any contract or condition of tale. It is solely supplied as an accomodation to the buyer. Product Tradename: ALAMO S SECTION I PROOUCT IDENTIFICATION Typo ef Refractory:* Fireclay Brick 'For chrome containing refractories, Indicate approximate percentage__________ and chock applicable Mock. Contains chrome ore consisting predominantly of the mineral chromite (MgFo).0.(AIFeCr)^O^ Contains chromium III oxide SEE CHECKED BLOCKS GEN. CHEM. INGREDIENT FORMULA Quartz SiOj SECTION II HAZARDOUS INGREDIENTS C.A.S. NUMBER PERCENTAGE RANGE OSHA P.E.L. 001317794 10 mg/m3 % Respirable Quartz b* CM CM 1 00 rf Ofsfoballte SIOj 14464-44-1 V, Quartz Value Trldymito Fused Silica SiOj SIOj 1346S-32-3 007631869 M Quartz Value NONE Coal Tar Products N/A MXE001SE9 0.2 nig/ Petroleum Pitch N/A MXE032424 NONE Phosphoric Add HjP04 007664312 1.0 mg/m3 (mitt). lime CaO 00I3037BB S.O mg/m3 Sodium Silicate 03-Si .2Na 006E34920 NONE a ACOIH TIV same SAME SAME Use Quartz TLV SAME 5.0 mg/m3 SAME 2.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 75-120 75-120 75-120 75-120 78-107 78-106 NONE NONE NONE SECTION III - PHYSICAL DATA Appearance and Odor: Whitfi tO bU'ff Color; no odor. Specific Gravity* ,2.32 pH: NO Solubility in Water: Soluble Constituents: Other: Insoluble. __________________________________________________________SECTION IV - FIRE AND EXPLOSION DATA UNLESS OTHERWISE NOTED, NONE. Product it a refractory. NOTES: 411073 0358 SEE CHECKED BLOCKS INGREDIENT SECTION V HEALTH HAZARO OATA' EFFECTS OF OVEREXPOSURE d Free Crystallino Sitka Coal Tar Product* 0 Petroleum Pitch Delayed lung fibrosis - silicosis Skin, lung, mucous membrane carcinogen Skin Irritation; photosensitixation (Same as Coal Tar Products) 0 Lime Irritant to skin, eyes, mucous membranes, etc. Phetpharic Acid Primary irritant - skin, eyes, etc Sadivm Silicate a Irritant It tkin, ayat, mucaut mambranat, ate. EXPOSURE REOUIRIO PROLONGED SHORT TERM V V -V V V V EMERGENCY OR FIRST AID PROCEDURES: -- Irritant*: Wash from *kin or flush from eye* using copiou* amounts of water. , Coal Tar Products: Remove from skin by washing with soap and water. DO NOT use solvents. Same for petroleum pitch. . Other: STABILITY: STABLE UNSTABLE Incompafabillty (materials to avoid) Hazardous decomposition products: Hazardous Polymerization: Q may occur SECTION VI REACTIVITY OATA COMMBITS: Q( will not occur SECTION VII. SPHI AND LEAK PROCEDURES. Mot (tfrattofy product* may bo landfilled. However, tinco your application of tbit product may chongo it* chemical characteristics, and sine* disposal procedures may vary with Jocalo and aro iub|ect to change, you should con*ull tho governmental autbority having furisdictiort for di*po*al information.________________________________________________________________________ ___________________ _______________________________ COMMENTS: _______________________________________________ SECTION VIH - SPECIAL PROTECTION INFORMATION_____________________________________ RESPIRATORY PROTECTION (CHECK TYRE); tt Approved Duct Othor (Specify): VENTILATION: Local exhaust ventilation thould bo provided if routine operation generate* dust In excess of allowable limit* PROTECTIVE GLOVES (CHECX TYRE): Add Rnillant Q ImparmaaMa tt Abradan Raddant OtHar (Spadfy): EYE PROTECTION: Approved safety glasses, goggle* or faceshieids should bo used when handling refractory product*. FOOT PROTECTION (CHECK TYPE).-- to Matatarwl toFafy PROTECTIVE CLOTHING (SPECIFY): Imparmaabla 411073 0359 Material Safety Data Sheet RARB/SORWALKER REFRACTORIES Ommm * Ormgmr Iminttm. /.. 2 Sttnur Cammr. PjrrtOvryt. Hmatyhimm 15222 TELEPHONE: (4121 361-6200 TELETYPE: 710-664-4347 __________________________________________________10/01/84 DISCLAIMER This data cheat ii baud on OSHA FORM 20 but modified to mere adequately <uit refractory producti. All data are subject to reatenable variation. This information it supplied in good faith by Harbiton-Walker and it applicable to the product at shipped. Your application of the product may change its characteristics. THE OATA PROVIOED HEREIN ARE BELIEVED CORRECT OR AREOBTAINEO FROM SOURCES BEIIEVEO TO BE GENERALLY RELIABLE. HARBISON-WALKER SH AU NOT BE LIABLE FOR ANY LOSS OR 0AMAGE DIRECTLY OR IN0IRECTIY ARISING FROM THE USE OF THIS PRODUCT, ANO HARBISON-WALKER ASSUMES NO OBLIGATION OR U ABILITY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data it net part of any contract or condition of tale. It it solely supplied at an accomodation to the buyer. SECTION 1 PROOUCT IDENTIFICATION Product Tradename: Typo of Refractory:* ALUSA High Alumina Brick 'hr chrome containing refractories. indicate approximate percenta Contains chrome ere consisting predominantly of the mineral chrornito (MgFo).0.(AIFoCr)^Oj Contains chromium III oxide SEE CHECKED BLOCKS GEN. CHEM. INGREDIENT FORMULA Quarts SiOj SECTION II HAZARDOUS INGREDIENTS CA.S. NUMBER PERCENTAGE RANGE OSHA P.B.L 10 mg/m^ 001317799 % Respirable Quarts *2 d( Crittobalito S*Oj 14464-46-1 0 1 V4 Quarts Value Q Tridymite SiOj 15466-33-3 W Quarts Value Fused Silica SiOj 007631S69 NONE Coal Tar Products N/A MX60015S9 0.2 mg/m* Petroleum Pitch N/A MXE052424 NONE Phosphoric Acid lime w CaO 007664342 001305764 1.0 mg/m3 (mitt) 5.0 mg/m3 Sodium Silicate 03-Si .2Na 006434920 NONE // - / Ud - ' O -- ACOIH TLV9 SAME SAME SAME Ute Quartz TLV SAME 5.0 mg/m3 SAME 3.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 75-120 75-120 75-120 75-120 78-107 78-106 NONE NONE NONE SECTION III - PHYSICAL OATA Appearance and Odor: Buff Color; n0 Odor. pH: NO Solubility in Water: Insoluble Soluble Constituents: Other: __________________________________________________________SECTION IV - FIRE ANO EXPLOSION DATA UNLESS OTHERWISE NOTED, NONE. Product it a rafractery. NOTES: 411073 0360 ^ t `SEE CHOCKED MOCKS INGREDIENT SECTION V HEALTH HAZAEO DATA* EFFECTS Of OVEREXPOSURE df Proo Crystalline Silica Belayed lung fibre*** - tilicotit Coal Tar Products Q PotroUum Pitch Skin, lung, mucous mombrano carcinogen Skin irritation; photosonsitisation (Sam* at Coal Tar Product*) Lime Irritant to skin, eyes, mucous membranes, etc. Phosphoric Acid Primary Irritant tkin, eye*, etc. Sodium Silicato G Irritant ta skin, syos, mucous membranes, etc. EXPOSURE REQUIRED PROLONGED SHORT TERM --v V V V EMERGENCY OR FIRST AID PROCEDURES: Irritants: Wash from stein or flush from eyes using copious amounts of water. Coal Tar Products: Remove from skin by washing with soap and water. DO NOT use solvents. Same for petroleum pitch. ' Other: STABILITY: C* STABLE UNSTABLE fncompatabillty (materials to avoid) Haxardous decomposition products: Hazardous Polymerization: may occur SECTION VI - EEACTIVITY OATA COMMENTS: 8 will not occur _______________________________ _____________________ SECTION VII . SPILL ANO LEAK PROCEDURES Mott nfrocloiy product* may bo landfilled. Howovor, line* your application of this product may change H* chomical diaractorlctic*. and tinea ditpotal procedure* may vary with local* and ar* tubjoct to change, you thould contult tho governmental authority having (uritdlctlen for dicpotal information._______________________________'__________________________________________________________________ COMMENTS: StCTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (CHECK TYPE): & Approved Duct Other (Specify): VENTILATION: Local exhaust ventilation should bo provided if routine operation generates dvH In excess of allowable limits PROTECTIVE GLOVES (CHECK TYPE): Add Resistant Impermeable *3 Abrasion Resistant O Other (Specify): EYE PROTECTION: Approved safety flosses, fofflos or facethieldt should bo usod when handling refractory products. FOOT PROTECTION (CHECK TYPE):' IX Matatanal tafety PROTECTIVE CLOTHING (SPEOPY): O Impermeable 411073 0361 Material Safety Data Sheet SlMsfl* HAR8IS0N-WALKER REFRACTORIES Bmun T Brtum It+ntrim. It.. _L--I Stttwtf Ct*Hr. Pittskmrfh. h*mrrbr*t* till! TRWHONE: (413) 363-6300 TELETYPE: 710-664-4347 10/01/84 This data sheet is basd on OSHA FORM 30 but modified to more adequately suit refractory products. All data are subject to reasonable variation. This information is supplied in good faith by Harbisen-Wallrer and it applicable to the product at shipped. Your application of the product may change its characteristics. THE DATA PROVIDED HEREIN ARE BEUEVED CORRECT OR ARE OBTAINED FROM SOURCES BELIEVED TO BE GENERALLY RELIABLE. HARBISON-WAIKER SHAU. NOT BE UABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INDIRECTLY ARISING FROM THE USE OF THIS PROOUCT, ANO HARBISON-WAIKER ASSUMES NO OBLIGATION OR U ABILITY FOR REU ANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is net part of any contract or condition of tale. It is solely supplied as an accomodation to the buyer. SECTION 1 PROOUCT IDENTIFICATION Product Tradename: Type of Refractory:* BENEZET Fireclay Brick For chrome containing rcfractoriw, indicate approximate personto Contain* chroma ora consisting predominantly of the minora) chrorne (MgFe).O.(AIFeCr^Oj Contain* chromium HI oxide SEE CHECKED BLOCKS GEN. CHEM. INGREDIENT FORMULA Quarts SiOj SECTION II - HAZARDOUS INGREDIENTS CA.S. NUMBER PERCENTAGE RANGE OSHA P.E.L 001317799 10 mg/ % ftetpirabie Quant *2 d! Cristeballte SiOj 14464-46-1 2-42 Vi Quarts Value Tridymito sio2 1546$-33-3 Vi Quartz Value Fused Silica SIOj 007631$69 NONE Coal Tar Products N/A MX$0013$9 0.3 mg/m3 Q Petroleum Pitch N/A MXI053434 NONE Phosphoric Acid lime *V4 CaO 007664303 0013037$$ 1.0 mg/m3 (mist) 3.0 mg/m3 Sodium Silicate 03-Si .3Na 006034930 NONE a ACGIH TLV9 SAME SAME SAME Use Quarts TLV SAME 3.0 mg/m3 SAME 3.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 73-130 73-130 75-130 75-130 7B-I07 73-106 NONE NONE NONE SECTION IN PHYSICAL DATA Appearance and Odor: Buff tO Orange color; no odor. Specific Gravity: 2.15 pH: ND Solubility in Water: Insoluble Soluble Constituents: Other: SECTION IV - FIRE AND EXPLOSION DATA UNLESS OTHERWISE NOTED, NONE. Product Is a refractory. NOTES: 411073 0362 SEE CHECKED BLOCKS INGREOIENT SECTION V . HEALTH HAZAKO DATA* EFFECTS OF OVEREXPOSURE & Ftm Crystalline Silica Oetayed lung fibratie - tilicecit C Coal Tor Product* Patroloum Pitch Skin, lung, mucous mombrano carcinogon Shin irritation; photetentititatien (Samo as Coal Tar Products) lima Irritant to skin, syos, mucous msmbranos, otc. Phetphoric Acid Primary Irritant thin, tyot. ate Sodium SiUcato Irritant to skin* oyos, mucous msmbranos, otc. 4 EXPOSURE REOUIREO PROLONGED SHORT TERM V ~V-- ~V-- y/ y/ yj CMHGCNCY Off PIRST AID PffOCIDURCS: a Irritant*: Wo*h from thin or flush from oyos using copious amounts of wator. Coal Tar Products: ffomovo from skin by washing with soap and wator. DO HOT wso solvents. Samo for potroloum pitch. D"Othor: STABILITY: (M STABlt a UNSTABU Incompatabillty (matorials to avoid) Hazardous dacamposition products: Hazardous Polymorization: may occur SECTION VI - REACTIVITY DATA COMMENTS: S wilt not occur SECTION VII SHU ANP LEAK PROCEDURES Mott refroctory product* may be landfilled. However, tinea your application aI Ihit product may changa It* chemical charactarittic*, and tinea ditpatal procedural may vary with laeaia and ore tubjeet ta change, yaw theuld cantwlt tha governmental authority having (uritdietian far ditpatal information.__________________________________________________________________ COMMENTS: ________________________________________________SECTION Vlll swa*l PROTECTION INFOPMAHON_____________________________________ RESPIRATORY PROTECTION (CHCCX TYPE): & Approved Dutt Other (Specify): VENTILATION: local exhautt ventilation theuld be provided if routine operation generator dutt in exeat* of allowable limit* PROTECTIVE CLOVES (CHECK TYPE): Acid Rotiitant Impermeable Abratien Retittant Other (Specify): EYE PROTECTION: Approved tafoty glower, goggle* or facethieldi theuld be uted when handling refractory product*. FOOT PROTECTION (CHECK TYPEJ:' A Metatareal tafoty PROTECTIVE CLOTHING (SPEOPY): Impermeable 411073 0363 Material Safety Data Sheet NARBISOH-WAIKER REFRACTORIES Orrmmt a) Crasser Mm ta. 1 Camrsr Cmr. PtnttsryA Amerrbesa* III}} TELEPHONE: (413) 562-4300 TRETYPE: 710-644-4347 ________________________________________________ 10/01/84 DISCLAIMER This data sheet it bated an OSHA FORM 30 but modified ta more adequately toil refractory product*. All data are subject to reasonable variation. This information is supplied in good faith by Harbison-Wolket and is applicable to the product a* shipped. Your application of the product may change its characteristics. THE DATA PROVIOED HEREIN ARE BELIEVED CORRECT OR ARE OBTAINED FROM SOURCES BELIEVED TO BE GENERALLY RELIABLE. HARBISON-WALKER SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INDIRECTLY ARISING FROM THE USE OF THIS PRODUCT. AND HARBISON-WALKER ASSUMES NO OBUGATION OR UABILITY FOR RRIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data it not part of any contract or condition of sale. It is solely supplied at an accomodation to the buyer. Product Tradename: CAtAMO 80 SECTION I PROOUCT IDENTIFICATION Type of Refractory:* Calcined Fireclay For chrome containing refractories, indicate approximate percentage_________ _ and check applicable Meek. Comaim chrome ore consisting predominantly of the mineral chromite (MgFe).0.(AIFeCr)^Dj Contains chromium lil oxide SEE CHECKED BLOCKS GEN. CHIM. INGREDIENT FORMULA Quarts SiO} SECTION II HAZARDOUS INGREDIENTS C.A.S. NUMBER PERCENTAGE RANGE OSHA P.E.L 10 mg/m3 001317799 % ftaspirobJa Quart* +2 CM CM 1 00 d( Crlstoballto SIOj 14444-44-1 H Quarts Value Trfdymit* Fused Silica Si02 sio2 15444-33-3 00763IB49 h Quarts Value NONE Coal Tor Product* N/A MXS00I5B9 0.3 mg/m3 Petroleum Pitch N/A MXB052434 NONE Phosphoric Add w 007444312 1.0 mg/m3 (mitt) lime CaO 00130S7BB S.O mg/m3 Sodium Silicate 03-Si ,3Na 004S34920 NONE ACOIN TLV9 SAME SAM SAM Use Quarts TIV SAME S.O mg/m3 SAME 3.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 73-120 75-120 75-130 75-130 7B-107 71-104 NONE NONE NONE SECTION III PHYSICAL DATA Appearance and Oder: Buff tO gray Color; no odor. Specific Gravity- 1 - 60 pH: ND Solubility in Water: Insoluble. Soluble Censtituents: Other: __________________________________________________________ SECTION IV - FIRE AND EXPLOSION OATA UNLESS OTHERWISE NOTEO, NONE. Product it a refractory. NOTES: 411073 0364 *SEE CHOCXEO HOCKS INGREDIENT SRCTtON V HEALTH HAZARO DATA* EFFECTS OF OVEREXPOSURE 00 free Crystalline Silica Coal Tar Product* Petroleum Pitch Delayed lung fibrosis silicosis Skin, lung, mucous mombrano carcinogon Skin irritation; phetosensitizatien (Samo as Coal Tar Products) iimo Irritant to skin, oyos, mucous mombranos, otc. Phosphoric Acid Sodium Silicate Primary Irritant - skin, oyos, otc Irritant te skin, eyes, mucous membranes, etc. a EXPOSURE REQUIREO PROLONGED SHORT TERM V V V V V V EMERGENCY OR FIRST AIO PROCEDURES: Irritants: Wash from skin er flush from eye* using copious amount* of water. Coal Tar Products: Remove from skin by washing with soap and water. DO NOT use solvents. Sam* for petreleum pitch. G Other: STARIUTY: C* STAN! UNSTAUE Incempotability (materials te avoid) Hazardous decernposition products: Hazardous Polymerization: may occur SECTION VI REACTIVITY DATA COMMENTS: t will not occur SECTION VII - SHU. ANO UAK PtOQDUHB Most refractory products may bo landfilled. However, since your application of this product may change its chemical characteristics, and since disposal procedures may vary with locale and ore subject to change, you should consult the governmental authority having jurisdiction for disposal information.________________________________________________________________________ _________________________________________________________ COMMENTS: SECTION VIII - SPECIAL PtOTICTtON INFOtMATION RESPIRATORY PROTECTION (CHECK TYPE): ti Approved Out! Other (Specify): VENTILATION: Ucal exhaust ventilation should be prevlded If routine eperatlen generate* dust in excess el alleweble limit* PROTECTIVE GLOVES (CHECK TYPE): Add Resistant Impermeable Abrasien Resistant Other (Specify): EYE PROTECTION: Appreved safety-glasses, geggle* er faceshleld* sheuld be used when handling refractory preducts. FOOT PROTECTION (CHECK TYPR): PROTECTIVE CLOTHING (SPRC1FY): d Metatarsal safety Impermeable __________________________________________________________SECTION IX SPROAL PRECAUTIONS___________________________________ If block is checked, preduct contains coal tar products. Worker* sheuld net be exposed to furnace "burn-in" volatile*. Other (Specify): 411073 0365 Material Safety Data Sheet HARBtSOA-WAlKER REFRACTORIES t/Prosser 'nitir i r /sc. 2 Swtrwtf Cmmt. PraivrfS. ^socfAsess If222 TELEPHONE: (41)) 341-4300 TRETYPE: 710-644-4347 DISCLAIMER Rev. 03/06/85 This data sheet it based an OSHA FORM 30 but modified to more adequately wit refractory product*. All data are subfect to reasonable variation. This information is tupplied in good faith by Harbisen-Walker and it applicable to the product as shipped. Your application of the product may change its characteristics. THE DATA PROVIDED HEREIN ARE BELIEVED CORRECT OR ARE OBTAINED FROM SOURCES BELIEVED TO BE GENERALLY RELIABLE. HARBISON-WAIKER SHALL NOT BE LIABLE FOR ANY LOSS OR OAMAGE DIRECTLY OR INDIRECTLY ARISING FROM THE USE OF THIS PROOUCT, ANO HARBISON-WALKER ASSUMES NO OBUGATION OR LIABILITY FOR REUANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is net part of any contract or condition of sale. It is solely wpplied as an accomodation to the buyer. Product Tradename: SECTION I - PROOUCT IDENTIFICATION Type of Refractory:* CEMENT PREMIXED WETAmorphous High Alumina Coating Mix chroma CMltiniiif rafroctoriaa, indlcott approximate p*. -- r and chock appikaWo black* Q Contoint chroma oro consisting prodominonfty of tho minoral chromite (MQFo).<X(AlFoCr)^Dj Contoint chromium M oiidt SEE CHECKED BLOCKS OSN.CHEM. INGREDIENT FORMULA CK Quarts SIOj SECTION II HAZARDOUS INGREOIBNTS CA.S. NUMBER PfRCSNTAOS RANGE OSHA P.E.L. 001317744 10 mg/m3 % RaspirabU Quartz *2 Cristobalito SIOj 14444 44 1 W Quarts Value Tridymite CK Fused Silica 2 SIO, 1344S-33-3 60676-86-0 20 - 25% Vi Quarts Value 20 mppcf Coal Tar Product* N/A MXS00ISB4 0.3 mg/m3 Petroleum Pitch N/A MXB033434 NONE Phosphoric Add lime *v CoO . O074443B3 O0I3O37BB 1.0 mg/m3 (mist) S.O mg/m3 Sodium Silicate 03-SI ,3Na 004B34430 NONE ACGIH TLVO SAMI SAMI SAME Us* Quarts TLV SAME S.O mg/m3 SAME 3.0 mg/m3 NONE NIOSH CRITERIA OOCUMENT NO. 79-130 79-130 79-130 79-130 79-107 79-104 NONE NONE NONE 0 1 b* LIWUW5I ________________________________________________________________SECTION m - PHYSICAL DATA Appearance and Oder: White color; earthy odor. Specific Gravity: pH: ^0 Solubility in Water: Soluble Constituents: Other: NO _____________ _____________________________________________ SECTION IV - FIRE AND EXPLOSION DATA UNLESS OTHERWISE NOTED. NONE. Product is a refractory. NOTES: 411073 0366 SEE CHECKED HOCKS INOEIRXENT SECTION V . HEA1TH HAZARD DATA* EPEECTS OP OVEREXPOSURE & Proa Crystalline Silica CmI Toe Prtducti Petroleum Pitch Lime Belayed hmg fibrosis silicosis Skin, long, muceus membrane carcinogen Skin irritation; phetesensitization (Same as Coal Tar Products) Irritant ta akin, tytt, mixrvt mrrnbraim, tc Chwphirk Add Primary Irritant skin, eyes, etc Sodium Silicate Irritant to skin, eyes, mucous membrane*, etc 3 exposure reiOqUuIiBrCeOd 1 n V V V V EMERGENCY OK flRST AIO PROCEDURES: Irritants: Wash from skin flush from eyes wunf ayim amounts at watar. O Cool Tar Product*: Remove ham skin by washing with and watar. DO NOT ua lohrsntc Soma far petroleum pitch. - Other: STAMITY: CX STASIS UNSTABLE Incompotability (materialt to avoid) Hazardous decomposition products: Hazardous Polymerization: may occur SECTION VI REACTIVITY OATA COMMENTS: dl will not occur tKCTiON VII . SPIU. ANP LEAK PROCEDURES Mast refractory products may be landfilled. However, since your application of this product may thonpo its chemical characteristics, and since disposal procedures may vary with locale and are subject to change, you should consult the governmental authority having jurisdiction for disposal Information.______________________________________________ COMMENTS: ________ section vni. special protection inpormation_________________________________ RESPIRATORY PROTECTION (CHECK TYPE): & Approved Oust O Other (Specify): VENTILATION: local exhaust ventilation should be provided U routine operation generates dust in excess of allowable limits PROTECTIVE GLOVES (CHECK TYPE): Add Resistant a Impermeable Abrasion Resistant Other (Specify): EYE PROTECTION: Approved safety glasses, gaggles or faceehleldt should be used when handling refractory products. POOT PROTECTION (CHECK TYPE):' PROTECTIVE CLOTHING (SPEOPY): d( Metatarsal safety Impermeable _________________________________________________ SECTION IX - SPECIAL PRECAUTIONS____________________________________ If Week is checked, product contains coal tar products. Workers should net be exposed to furnace "bum-in" volatiles. Other (Specify): 411073 0367 Material Safety Data Sheet HARStSQH-WAlKER REFRACTORIES (Mw * Bntm Mwim. !m . 1 Stamtr c--nt. rutvry*. FMtsyhmu 1S221 TELEPHONE: (412) 5*3-6200 TELETYPE: 710-664-4347 _________________________________________________ 10/01/84 DISCLAIMER This dote ihMl it based on OSHA FORM 20 but modified to mere adequately tuit refractory products. All data are subject to reasonable variation. This information is supplied in good faith by Harbison-Wallter and it applicable la the product as shipped. Your application of the product may change its characteristics. THE DATA PROVIDED HEREIN ARE BELIEVED CORRECT OR ARE OBTAINED FROM SOURCES BELIEVED TO BE GENERALLY RELIABLE. HARSJSON-WAUCER SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR IN0IRECTLY ARISING FROM THE USE OF THIS PROOUCT. AND HARBISON-WALKER ASSUMES NO OBLIGATION OR LIABILITY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is net part of any contract or condition of sale. It is solely supplied as an accomodation to the buyer. Product Tradename: SECTION I PROOUCT IDENTIFICATION Type of Refractory:* CORAL PLASTICPhosphate Bonded High Alumina Plastic 'Per chrome containing refractories, indicate approximate percentage_________ _ and check applicable block. Contains chrome ere consisting predominantly of the mineral chromite (Mgfe).0.(AIFeCr)^O] Contains chromium HI oxide SEE CHCCKEO BLOCKS GEN.CHEM. INGREDIENT FORMULA & Quarts SX>2 SECTION R HAZARDOUS INGREDIENTS C.A.S. NUMBER PERCENTAGE RANGE OSHA P.E.L. 001317790 Below 1% 10 mg/m3 % ftapirobt* Quartx *2 Cristobalito StOj 14464-46-1 M Quarts Value TridymHt Fused Silica SIO] sio3 1S463-32-3 007631 $69 Quarts Value NONE Coal Tar Products N/A MXE0015E9 0.2 mg/m3 Petroleum Pitch & Phosphoric Add N/A HjP04 MXB032424 007664312 6-7% NONE 1.0 mg/m^ (mitt) lime CoO 00I30S7S3 5.0 mg/m3 Sodium Silicate 03-Si ,2Na 006334920 NONE ACGIH TLV6 SAME SAME SAME Use Quarts TLV SAME 5.0 mg/m3 SAMS 2.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 75-120 75-120 75-120 75-120 73-107 73-106 NONE NONE NON! _______________________________________________________________ SECTION III PHYSICAL OATA Appearance and Oder: Gray Color; odor of phosphoric acid. Specific Oravfty: . 76_________ pH: 2-3 Solubility in Water: About 4% (dry basis) Muble Censrituents: phosphoric aCl'd. __________________________________________________________SECTION IV - FIRE AND EXPLOSION DATA UNLESS OTHERWISE NOTED, NONE. Product Is a refractory. NOTES: 411073 0368 ______________________________ SECTION V . HEALTH HAZARO DATA*.______________________________________________ ____________ $ CHECKBO BLOCKS INGREDIENT EPPCCTS OP OVEREXPOSURE Proa Cryitollin* Silica Deleyed lung fibrosis silicosis | EXPOSURE WQUItH) warn1EMWM! SHORT TER* U VrOQE 1 Ur rrOQVCTl Petroleum Pitch Skin, Ivitfp mucous mombrono carcinogen Skin irritation; photosensitixatien (Same as Coal Tar Products) V..... Lima & Phosphoric Acid Sodium Silicate Irritant to skin, eyes, mucous membranes, etc. Primary Irritant skin, eyes, ate Irritant to skin, eyes, mucous membranes, etc. V V V a CMCROCNCY OX HIST AID PROCROURES: 'Irritants: Wash from thin or flush from eyes using copious amounts of wator. Coal Tar Products: Rornova from skin by washing with soap and wator. DO NOT usa solvents. Sams for potroioum pitch. Other: STABILITY: tS STABLE UNSTABLE Incompatabillty (materials to avoid) Hasardous decomposition products; Haiardout Polymerisation: may occur SECTION VI - REACTIVITY OATA & will not occur COMMB4TS: Store In cool, mgist area. Avoid temperatures in excess of 100F prior to use. SECTION VII . SHU ANO LEAK PROCEDURES: Most refractory products may bo landfilled. However, since your application of this product may change Its chemical characteristics, and since disposal procedures may vary with locale and are subfect to change, you should consult the governmental authority having (urisdiction for disposal information. COMMENTS: ' SECTION VIII - SPECIAL PROTECTION INPORMATtON RESPIRATORY PROTECTION (CHECK TYPE): & Approved Dust Othor (Specify): VENTILATION: local exhaust ventilation should be provided If routine operation generates dust in excess of allowable limits PROTECTIVE GLOVES (CHECK TYPE): tt Add Resistant Impermeable Abrasion Resistant Othor (Specify): EYE PROTECTION: Approved safety glasses, goggles or faceehields should bo used whoa handling refractory products. FOOT PROTECTION (CHECK TYPE): PROTECTIVE CLOTHING (SPECIPY): Q( Metatarsal safety Impermeable _________________________________________________________ SECTION IX SPECIAL PRECAUTIONS___________________________________ If block is checked, product contains coal tar products. Workers should not bo exposed to furnace "burn-in" volatiles. Other (Specify): 411073 0369 Material Safety Data Sheet HARBtSOR-WAlKER REFRACTORIES Omeiee et Qrmeeee leSeetriee. Ime.. I Seamier Ceear. Pmikmrre. feeeeeheeie IS221 TKPHONE: (412) J62-4200 TRETYPE: 710-464-4347 _________________________________________________ 10/01/84 DISCLAIMER Thit data ihoot i bad an OSHA FOAM 20 but modified to mar* adequately suit refractory product*. All data are fubjoct to roaionablo variation, Thit information it tuppliod in good faith by Harbiton-Walkor and it applicable to tho product at thippod. Your application of tho product may change it* characterittici. THC OATA PROVIOED HEREIN ARE BBJEVED CORRECT OR ARE OBTAINED FROM SOURCES BEUEYED TO BE GENERALLY RELIABLE. HARBISON-WALKEISHAU NOT BE UABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INDIRECTLY ARISING FROM THE USE OF THIS PRODUCT, AND HARBISON-WALKER ASSUMES NO OBLIGATION OR UABIUTY FOR REUANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. Thit data it not part of any contract or condition of tala. It it tololy tuppliod at an accomodation to the buyer. Product Tradename: SECTION I - PROOUCT IDENTIFICATION Typo of Refractory:* H-W ES CASTABLE CFireclay Castable "For chrome containing refractorlot, indicate approximate percentage_________ _ and check applicable Mock. Contain* chroma ore consisting predominantly of tho minora! chromite (MgFe).0.(AlFeCr)^Oj O Contains chromium (U oxide SEE CHECKED BLOCKS QEN.CHEM. INGREDIENT FORMULA Quart! d! Crlitobalit* SlOg SlOg SECTION II - HAZARDOUS INGREDIENTS CA.S. NUMBER PCRCSNTAGS RANGE OSHA P.E.L 10 mg/m3 001317799 % Respirable Quarts *2 14464-46-1 10 - 152 Vk Quart! Value Trldymite SlOg 1S46B-32-3 b Quart! Value Futod Silica SlOg 007631169 NONE Coal Tar Product* N/A MXB001SB9 0.2 mg/m3 Petroleum Pitch N/A MXB0S2424 NONE Phetphorlc Acid Ume V4 CaO 0076643S2 00130S7BB 1.0 mg/m3 (mitt) S.O mg/m3 Sodium Silicate 03-Si .2Na 006434920 NONE P ACOIH nve SAMS SAME SAME Ute Quart! TLV SAME S.O mg/m3 SAME 2.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 7S-120 75-120 73-120 75-120 78-107 78-106 NONE NONE NONE StCTtON til - PHYSICAL OATA Appearance and odor: Dark gray color; earthy odor. Specific Gravity: 1.94 pH: ND Solubility In Water: Slightly Soluble. Soluble Conttituentt: Calcium Aluminate Cement _________________________________________________________ SECTION IV - FIRE ANO EXPLOSION OATA UNLESS OTHERWISE NOTED, NONE. Product It a refractory. NOTES: 411073 0370 SEE CHECXEO SLOCKS INCREMENT SECTION V HEALTH HAZARD DATA* EFFECTS OF OVEREXPOSURE M free Crystalline Silica Coal Tar Product! Potroloum Pitch limo Delayed lung fibrosis - silicosis Skin, lung, mucous membrane carcinogen Shin irritation; phofotoncitisation (Same os Coal Tar Products) Irritant to thin* oyos, mucous mombranos, otc. Phosphoric Acid Primary Irritant - skin, eyes, etc. Sodium Silicate Irritant to skin, eyes, mucous membranes, etc EXPOSURE REQUIRED PROLONGED SHORT TERM ----------------------- 1 V --y-- ----------------------- 1 --y-- V V <. EMERGENCY OR FIRST AID PROCEDURES: Irritants: Wash from skin er flush from eye* using copious amount* of wator. Coal Tar Products: Remove from skin by washing with soap and water. DO NOT us* solvent*. Sam* for petroleum pitch. Other: STABIUTY: CX STABLE UNSTABLE Incompatability (materials t* avoid) Hazardous decomposition products: Hazardous Polymerization: may occur SECTION VI REACTIVITY DATA COMMENTS: Store in dry area prior to use. Q will not occur SECTION VII - SPIU. AND LEAK PROCEDURES Molt refractory products may bo landfilled. However, sine* your application of tbit product may change it* chemical characteristics, and cinea dicpocal procedure* may vary with locola and arc tubject ta change, you chould consult the governmental authority having Jurisdiction for disposal information.__________________________________________________________________________________________________ COMMENTS: 1 _________________________________________________ SECTION VIII - SPECIAL PROTECTION INFORMATION______________________________________ RESPIRATORY PROTECTION (CHECK TYPE): 01 Approved Oust Other (Specify): VENTILATION: local exhaust ventilation should bo provided if routine operation generate* dust In oxcoee of allowablo limit* PROTECTIVE CLOVES (CHECK TYPE): Add Rosistant a Impormeable Abrasion Resistant Other (Spodfy): EYE PROTECTION: Approved safety gloss**, gogglos or facoshialds should be used when handling refractory products. FOOT PROTECTION (CHECK TYPE): PROTECTIVE CLOTHING (SPEOPY): A Metatarsal safety Impermeable 411073 0371 Material Safety Data Sheet HAR8IS0N-WAUCER REFRACTOR/E. Onmaa Y Orasaar fwtemt lac. Oaa Gttatnf Caatar. Fittatarfk. Faaatfbaaia IS22 TBJPHONE: (411) 542-4301 TBJTYPE: 710-444-434 DISCLAIMER 4/16/85 This data thaat it bated on OSHA FORM 20 but modified to mare adequately suit refractory product*. All data are (abject to reasonable variation. Thi* information i* supplied in goad faith by Harbiter*-Walker and i* applicable to the product as shipped. Your application of the product may change its characteristics. THE OATA PflOVIORD HHEIN ARE BBJEVED CORRECT OR ARE ORTAINEO FROM SOURCES B&1EVED TO BE GENERALLY RELIABLE. HARBISON-WALKER SHAU NOT BE UABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INOIRECTLY ARISING FROM THE USE OF THIS PRODUCT, ANO HARBISON-WALKER ASSUMES NO OBLIGATION OR UABILITY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is not part of any contract or condition of tala. It is solely supplied as an accomodation ta the buyer. Product Tradename: GG-10-20 SECTION I - PROOUCT IDENTIFICATION____________________________________________________________________ Typo of Refractory:* Amorphous Fused Silica Grain 'For chrome containing refractories, indicate approximate percentage -- , and chad* applicable block. Contain* chrome ere consisting predominantly of the mineral chromite (MgFe).0.(AlFeCr)^Oj Contains chromium III oxide SEE CHECKED BLOCKS GEN. CHEM. INGREMENT FORMULA 16 Quarts & Crittaballta SiO, SiOj SECTION B HAZARDOUS INCREMENTS C.A.S. NUMBER PERCENTAGE RANGE 001317799 0-1% OSHA P.E.L 10 mg/nA % Kttpirabta Quoits *2 14444.44.1 1-2% M Ouartx Value Tridymlte SIO] 13443-32-3 H Quarts Value d Fused Silica SIO] 40474-B4-0 97-99% 20 mppcf 0 Coal Tar Product! N/A MX30013S9 0.2 mg/m3 Petroleum Pitch N/A MXB0S2424 NONE Phosphoric Add h,po4 007444342 1.0 ntf/m3 (mist) lime CaO 0013037S3 S.O mg/m3 Sodium Silicate 03-Si .2Ne 004434920 NONE ACGIH TLV9 SAME SAME SAME Use Quarts TLV SAME 3.0 mg/m3 SAMS 1.0 inf/m^ NONE NIOSH CRITERIA DOCUMENT NO. 7S-120 75-120 7S-I20 73-120 73-107 73-104 NONE NONE NONE Appearance and Oder: Specific Gravity: SECTION III - PHYSICAL OATA White Color; no odor. -Hr 6-8 Solubility in water: Insoluble. Salubl# Cawtlluntt: Other: _______ __________________________________________________ SECTION IV - FIRE ANO EXPLOSION DATA UNLESS OTHERWISE NOTED, NONE. Preduct Is a refractory. NOTES: 411073 0372 't : "SEE CHECKED M.OCXS INGRSOIB4T 8 Fro* Crystalline Sitka SECTION V . HCAITH HAZARD OATA* CFFRCTS OF OVRRCXPOSURI Ooto)od lung fibrosis silicosis Coal Tar Product* Skin. tiNif, mwcMi mmbroA carcinogen Skin irritation; piwtwwiiHiqtiw Fsttoloum Fitch (Same as Coal Tar Products) Lime Irritant to shin, oyoc, mucous membranes, otc. Phosphoric Add Primary Irritant - shin, eyes, etc. Sodium Siikat* Irritant to shin, eyas, mucous membranes, otc. a IXPOSURf REQUIRED PROIONORD SHORT TfRM V VV V V V EMERGENCY 00 FIRST AIO PROCI(XJRRS: Irritants: Wash from shin or flush from eyas using copious amounts of water. Coal-Tar Products: Remevo from shin by washing with soap and watar. DO NOT use solvent*. Same for petroleum pitch. Other: STARIUTY: (tt STASIS UNSTASIS IncompatabHIty (materials to avoid) Hasardaus decomposition products: Haiardaus Polymerlxatien: may occur SRCTION VI - RIACnVITY DATA COMMSNTS: O svill not occur - StCTtON vw . SPIU. ANO HAK PROCSOURSS MM refractory product* may bo landfilled. However, since your application d this product may change its chemical characteristics, and sines disposal procedures may vary with local* and or* subject to change, you should consult tho govornmonted authority haying Jurisdiction ter disposal information.__________________________ _______________________________________________________________________________________________________ COMMSNTS: __________________________________________________SRCTtON VW - SPRC1A1 PRQTSCTION INFORMATION_______________________________________ RESPIRATORY TOOTKmON (CHKX TYPS): fc Approved Oust Other (Specify>: VINT11ATION: local exhaust ventilation should be provided if routine operation generator dust In excess of allowable limits PROTECTIVE (XOVtS (CttaOC TYrt): ~ a AM Resistant Impormeabie Abrasion Resistant Other (Specify): IYI PROTECTION: Approved safety gfaseec, goggles or focorhlolds should be used whan handling rofractary products. FOOT PROTECTION (CHKX TYFf): PROTECTIVE aOTHINO (SPEQEY): tf Matetarsal safoty Imparmooble 411073 0373 Material Safety Data Sheet HAR8IS0M-WAIKFR REFRACTORIES Smut* ! Anr Itdntrim. !m.. 2 ftnlffyil. AMirAriM ts222 TK&HONE: (411) 342-6200 TELETYPE: 710-664-434 7 _________________________________________________10/01/84 DISCLAIMER This data ihMl ii baud an OSHA FORM 10 but modified to more adoquatoiy uit refractory product*. All data aro aubjoct to reasonable variation. Thi* information is supplied in good faith by Harbiton-Walkar and i* applicabio to tho product as shipped. Your application of the product may change its characteristics. THE DATA PROVIOEO HEREIN ARE BELIEVED CORRECT OR ARE OBTAINED FROM SOURCES BELIEVEO TO BE GENERALLY RELIABLE. HARBISON-WAIKER SHAU. NOT BE UABIE FOR ANY LOSS OR DAMAGE DIRECTLY OR INDIRECTLY ARISING FROM THE USE OF THIS PRODUCT. AND HARBISON-WALKER ASSUMES NO OBLIGATION OR UABIUTY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data it not part of any contract or condition of tale. It it solely supplied at an accomodation to tho buyer. ___________ _______________________________________________ SECTION I - PtOOUCT IDENTIFICATION Product Tradename: Typo of Refractory:* H-W 3-83High Alumina Blocks For chromo containing refractories, indicate approximate percentage and check applicable Week. Contain* chrome ore consisting predominantly of the mineral chromite (MgFe).0.(AlFoCr)^0^ Contains chromium III oxide SEE CHECKED BLOCKS GEN. CHEM. INGREDIENT FORMULA & Quarts SiOg SECTION U - HAZARDOUS INGREDIENTS CA.S. NUMBER PERCENTAGE RANGE OSHA P.S.L. 00131779V 2-4% 10 ing/nt3 % Respirable Quarts 2 d( Criftobaiite Tridymite SiOg sio2 14464-46-1 15466-31-3 1 - 3% Vi Quart! Value Vi Quart! Value Fused Silica SiOj 007631B69 NONE Q Coal Tar Product* N/A MXE001SI9 0.3 mg/m3 Petroleum Pitch N/A MX80S2434 NONE Phosphoric Acid h/o4 007664383 1.0 mg/m^ (mist) lime CoO 001305786 $.0 mg/m3 Sodium Silicate 03-Si INa 006834930 NONE a ACGIH TLV9 SAME SAMS SAME Use Quart! TLV SAME 5.0 mg/m^ SAME 3.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 75-120 75-120 75-120 75-120 78-107 78-106 NONE NONE NONE _______________________________________________________________ StCTlON III - PHYSICAL DATA Appearance and odor: Light gray color; earthy odor. Specific Gravity: _ 2.20 ND Solubility in Water: SI i ght. SalableCenitituent.: Calcium Aluminate Other: ___ ______________________________________________________ SECTION IV - FIRE AND EXPLOSION DATA UNLESS OTHERWISE NOTEO, NONE Product it a refractory. NOTES: 411073 0374 Il4 vl SEE CHECKED MOCKS INGREDIENT ^ -'VKaaH.V. HEALTH HAZABO OATA* EPPECTS OP OVEREXPOSURE & Tree Crystalline Sitka dMqprfhiag fibrosis silicosis Coal Tar Product* Potroloum Pitch Shin, hmg, mucous membrane carcinogen Shin irritation; photosensitiiation (Same as Coal Tar Products) lime Irritant to skin, eyes, mucous membranes, etc. Phosphoric Acid Primary Irritant skin, eyes, etc Sodium Silicate Irritant to skin, eyes, mucous membranes, etc EXPOSURE REOUIREO PROLONGED SHORT TERM V v/ ~~v y/ V V EMERGENCY OR HRST AID PROCEDURES: Q.. Irritants: Wash fram skin or flush from ayas using copious amounts of wator. Coal Tar Products: Remove from skin by washing with soap and wator. DO NOT usa solvents. Santa fair patrolavm pitch. Other: STABILITY: ft STABLE UNSTABLE Incompatability (materials to avoid) Hazardous decomposition products: Hazardous Polymerization: may occur SECTION VI REACTIVITY DATA COMMENTS: fl will net occur SRCTION VII SPHI ANO IRAK PROCRDURRS Most refractory products may bo landfilled. However, since your application of this product may change Its chemical characteristics, and since disposal procedures may vary with locale and are subject to change, you should consult the governmental authority having jurisdiction for disposal information. COMMENTS: ______________________________________________ SRCTION VIII SPECIAL PROTECTION INFORMATION_______________________________________ RESPIRATORY PROTECTION (CHECK TYPE): & Approved Dust Other (Specify): VENTILATION: local exhaust ventilation should be provided if routine operation generates dust In excess of allowable limits PROTECTIVE GLOVES (CHECK TYPE): Add Resistant Impermeable rf Abrasion Resistant Other (Spodfy): EYE PROTECTION: Approved safatp-glasses, goggles or faceshiefds should be used when handling refractory products. POOT PROTECTION (CHKXMfc PROTECTIVE aOTHINO (SPWY^ & Metatarsal safety Impermeable 411073 0375 Material Safety Data Sheet HARBtSQH-WALKER REFRACTORIES Emime ti Crmmr InMim. /at. 1 fsttwtf Ctattt, AwifArMM If222 TRHONI: (417) 567-4700 TELETYPE: 710-664-4347 _______________________________________________ 10/01/84 DISCLAIMER Thit data iknt i bawd on OSHA FORM 30 but modified lo more adequately twit refractory product*. All data are rubject to reasonable variation. Thi* information i* supplied in good faith by Harbison-Walker and i< applicable to the product os shipped. Your application of the product may change its characteristics. THE DATA PROVIDED HEREIN ARE BELIEVED CORRECT OR ARE OBTAINEO FROM SOURCES RELIEVED TO BE OENERAUY RELIABLE. HARBISON-WALKER SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INOIRECTIY ARISING FROM THE USE OF THIS PROOUCT. AND HARBISON-WALKER ASSUMES NO OBLIGATION OR UABIUTY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is not part of any contract or condition of solo. It U solely supplied a* an accomodation to the buyer. _______________________________________________ __________ SECTION I - PROOUCT IDENTIFICATION Product Tradename: Typo of Refractory;* HARCHROME G Chrome Castable `For chroma containing refractories, indicate approximate percentage _Z5lL_, and chock applicable Mack. 3 Contain* chroma or# consisting predominantly of th# min#rol chromite (MgF#).0.(AIF#Cr)jOj Q Conjoint chromium Ul oxide SEE CHECKED BLOCKS OCN.CHBM. INGREDIENT FORMULA Quarts SiOg SECTION II - HAZARDOUS INGREOtRNTS CA.S. NUMBER PfRCSNTAGR RANGE OSHA P.E.L 0013T7799 10 mg/m3 % Respirable Quarts *2 Crlstobalite Tridymita Oj SIOj 14464-46-1 1546B-33-3 M Quarts Value K Quarts Value Fused Silica SiOg 007631169 NONE Coal Tar Products N/A MXI0015B9 0.2 mg/m3 Petroleum Pitch N/A MXB053434 NONE Phosphoric Add Umo V4 CaO 0076643(2 001305711 1.0 mg/m3 (mist) 5.0 mg/m3 Sodium Silicate a a 03-SI ,7Na 006(34930 NONE a ACGiH TIV SAME SAME SAMI Use Quarts TLV SAME S.O mg/m3 SAMI 2.0 mg/m3 NON! 1 | NIOSH CRITERIA OOCUMENT NO. 75-130 75-120 75-120 75-120 7S-107 7S-106 NONE NONE NONE _______________________________________________________________ SgCTlON III * PHYSICAL DATA Appearance and odor: Light gray color; earthy odor. Specific Gravity: - 40 pH. NO Solubility in Water: SI ightly SOI Uble. Soluble Constituents: Calci-um Aluminate Cement SECTION IV - FIRE AND EXPLOSION DATA UNLESS OTHERWISE NOTED, NON!. Product it a refractory. NOTES: 411073 0376 SEE CHEOCSO BLOCHS INGREDIENT SECTION V - HEALTH HAZARD DATA* EFFECTS OF OVEREXPOSURE Froo Crystalliflo Silk# fSlIRd hmg fibrosis silicosis Coal Tor Product! Potrotoum Pitch lung, mucous mombrano carcinogan Stda irritation; phetesensitiiation (Same as Coal Tar Products) Lime Irritant to skin, oyos, mucous mombranos, otc. Phosphoric Acid Primary Irritant skin, eyes, etc. Sodium Silicato Irritant to skin, eyes, mucous membranes, etc. EXPOSURE REQUIRED PROLONGED SHORT TERM V V v-- V V V EMERGENCY OR REST AID PftOCEOURES: Irritants: Wash from skin or flush from oyos using copious amounts of wator. Coal Tar Products: RomoVo from skin by washing with soap and wator. DO NOT uso sohronts. Same for potroloum pitch. Ofhor: STABILITY: rf STABLE UNSTABLE Incampatability (matorials to avoid) Hazardous docomposition products: Hazardous Poiymorization: may occur SECTION VI - REACTIVITY OATA COMMENTS: will not occur Store in dry area prior to use. __________ ____________________________________________SECTION VII SHU. AND LEAK PROCEDURES Matt nlndwy products may bo landfilled. However, sinco your application of tbit product may change its chemical characteristics, and tinea disposal procedures may vary with locals and are subject to change, you should consult the governmental authority having jurisdiction for disposal information. COMMENTS: ____________________________________________SECTION VIII - SPECIAL PROTECTION INFORMATION_______________________________________ RESPIRATORY PROTECTION (CHECK TYPE): tf Approved Oust Other (Specify): VENTILATION: local exhaust ventilation should be provided if routine operation generates dust In excess of allowable limits PROTECTIVE GLOVES (CHECK TYPE): Add Resistant Impermeable Abrasion Resistant Other (Specify): EYE PROTECTION: Approved SEfptp glunss, goggles or faceshieidt should be used when handling refractory products. FOOT PROTECTION (CHEOUMfe. PROTECTIVE CLOTHING (Sf E0Pf)U' CX Metatarsal safety Impermeable _________________________________________________________ SECTION IX SPECIAL PRECAUTIONS___________________________________ If block is checked, product contains coal tar products. Workars should not bo exposed to fumaca "bum-in" volatiles. Other (Specify): 411073 0377 Material Safety Data Sheet HARBtSOH-WAlKER REFRACTORIES Mm Bremer ferheetm. Im.. 2 fMmr Crew. Htutmrft. Awit*w IS222 THJPHONE: (413) 363-6300 TeiTYFl: 710-644.4347 __________________________________________________ 03/19/85 DISCLAIMER- This data theet it bated an OSHA FORM 30 but modified te mere adequately wit refractory preduett. All data are tubject te reateneble variation. Thit information it tupplied in good faith by Harbiton-Walker and it applicable to the product at ihipped. Your application of the product may change itt charocteriitict. THE DATA FROVIOED HBIEIN ARE BSJEVED CORRECT OR ARE OETAINEO FROM SOURCES BBJEVED TO BE GENERALLY RH.IABLE. HARBISON-WALKER SHAU NOT BE LIABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INDIRECTLY ARISING FROM THE USE OF THIS PRODUCT. AND HARBISON-WALKER ASSUMES NO OBLIGATION OR UABIUTY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. Thit data it not part of any contract or condition of tala. It it teiely tupplied at an accomodation to the buyer. SECTION I - PROOUCT IDENTIFICATION Product Tradename: Type of Refractory:* KALAHigh Alumina Brick *For chrome containing refracteriec, indicate approximate p--meg. end check applicable blech. Contaim chrome ore contitting predominantly of th4 mineral chromite (MgFe).0.(AIFeCr)^Oj Contain! chromium 111 oxide SEE CHECKEO BLOCKS OEN. CHUM. INGREDIENT FORMULA Ouartx SlOg SECTION N - HAZARDOUS INOREOISNTS C.A.S. NUMBER POtCSNTAOS RANGE OSHA P.E.L. 0013177PR 10 mg/m3 % tespirade Quortx *2 K) Crlttoballto SlOg 14464-46-1 3 - 5% H Quart! Value Tridymite SiOg 15466-33-3 ft Quart! Value Futod Silica SIOj 00763144* NONE Coal Tar Product! N/A MX4001S4* 0.3 mg/m3 Pttraltgm Pitch N/A MXB053434 NONE Phaephortc Add h,po4 * 007664343 1.0 mg/m3 (mitt) Uma CaO 00130S7B4 3.0 mg/m3 Sodium Silicate 03-Si .3Na 006434*30 NONE a ACGIH TLVP SAME SAMS SAMI Lite Quart! TLV SAME 3.0 mg/m3 SAME 3.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 73-130 73-130 73-130 73-130 76107 76106 NONE NONE NONE .'Fjes-'j nun SECTION HI PHYSICAL DATA Appearance and Odor: Dark buff color; no odor. Otavity* 0 c 43 pH: ND Salability In Water: Soluble Conetltueatt: Other: Insoluble. _________________________________________________ SECTION IV - FIRE AND EXPLOSION DATA UNLESS OTHERWISE NOTEO, NONE. Product it a refractory. NOTH: 411073 0378 dl nm SEE CHECKED MOCKS INORSDIBNT & Free Crystalline Silica Cm! Tar Products ' Potrolovm Pitch SECTION V HEALTH HAZARD OATA* EFFECTS OF OVEREXPOSURE Mhperi'hsng fibrosis silicosis lung,Mm mucous membrane carcinogen SUsi irritation; phetesensitisatien (Same as Coal Tar Products) a lime Irritant to skin, eyes, mucous membranes, etc. Phosphoric Acid Primacy Irritant - skin, eyes, etc Sodium Silicate Irritant to skin, eyes, mucous membranes, etc A' EXPOSURE REQUIRED PROLONORO SHORT TERM V V ~^7 V V V EMERGENCY Ot FIRST AID PROCEDURES: Irritants: Wash from skin or flush from eyes using copious amounts of watar. Coal Tar Products: Remove from skin by washing with soap and water. DO NOT use solvents. Same for petroleum pitch. Q Other: STARHITY: d( STASIS O UNSTARU Incempotability (materials to avoid) Hazardous decomposition products: Hazardous Polymerisation: may occur SECTION VI - REACTIVITY DATA COMMENTS: 09 will net occur SRCTION VII SPILL ANO IRAK PROCEDURES. Most refractory products may bo landfilled. However, since your application of this product may change its chemical characteristics, and since disposal procedures may vary with locale and are subject to change, you should consult the governmental authority having Jurisdiction for disposal Information.' COMMENTS: __________________________________________________SECTION VW SPECIAL PROTECTION INFORMATION_______________________________________ RESPIRATORY PROTECTION (CHECK TYPE): til Approved Dust Other (Specify): VENTILATION: local exhaust ventilation should b provided if routine operation generates dust in excess of allowable limits PROTECTIVE GLOVES (CHECK TYPE): Add Resistant Impermeable b Abrasion Resistant Other (Specify): EYE PROTECTION: Approved safajy glasses, goggles or facashioMt should be used when handling refractory products. TOOT PROTECTION (CHECK PROTECTIVE CIOTMINO <SPEM*|- (X Metatarsal safety Impermeable 411073 0379 Material Safety Data Sheet RARB/SOR-WAIKCR REFRACTORIES Omm* / trmmr Ittntrm. /or.. 2 Sattmtf Crrrer. Pirrste/y*. Pumiyhrtnu 15222 TB.EPHONE: (411) 161-4100 TRETYPE: 710-664.4347 ____________________________________________ 10/01/84 DISCLAIMER Thit data sheet it bated an OSHA FORM 10 but modified to more adequately suit refractory product*. All data are subject to reasonable variation. Thit information it supplied in good faith by Harbiton-Walker and it applicable to the product at shipped. Your application of the product may change itt characteristics. THE 0ATA PROVIDED HEREIN ARE BR.IEVE0 CORRECT OR ARE OBTAINEO FROM SOURCES BELIEVED TO BE GENERALLY RELIABLE. HARBISON-WALKER SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR IN0IRECTIY ARISING FROM THE USE OF THIS PROOUCT. ANO HARBISON.WALKER ASSUMES NO OBLIGATION OR LIABILITY FOR RBJANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data it not part of any contract or condition of tale. It is solely supplied as an accomodation to the buyer. Product Tradename: KORUNDAL GUN MIX SECTION I - PROOUCT IDENTIHCATION Typo of Refractory:* High Alumina Gun Mix *For chrome containing refractories, indkato approximate percentage __f and check applkable block. Contains chrome ore consisting predominantly of the mineral chromite (Mg^e).0.(AIFeCr)^O^ Contains chromium Ml oxide SEE CHECKED BLOCXS GEN.CHEM. INGREDIENT FORMULA d( Quarts SIOj SECTION . HAZARDOUS INGREDIENTS CA S. NUMBER PERCBNTAGfl RANGE OSHA P.E.L 10 mg/m3 001317744 1 - 2% % Respirable Quarts +2 Crktoballto SIO] 14464-46-1 M Quarts Value Tridymite Fused Silica SIOj sio2 13463-31-3 007631B64 M Quarts Value NONE Coal Tar Products N/A MXB001334 0.2 mg/m3 Petroleum Pitch N/A MXS0S1414 NONE Phesphoric Acid h,po4 0076643E1 1.0 mg/m3 (mitt) Ume CaO 00130S7BB S.O mg/m3 Sodium Silicate 03-SI .INa 006034430 NONE ACGIH TLV4 SAME SAME SAME Use Quarts TLV SAME 5.0 mg/m3 SAME 3.0 mg/m3 NONE NIOSH CRITERIA OOCUMENT NO. 73-120 75-120 75-120 75-110 78-107 78-106 NONE NONE NONE _______________________________________________________________ SfCTtON III - PHYSICAI DATA Appearance and odor: White color; earthy odor. Specific Gravity: ^.56_________ pH: NO Solubility in Water: Slightly Soluble. uW.Constituents: Ca1cium Alu(I,inate Cement _________________________________________________________ SECTION IV - FIRE ANO EXPLOSION OATA UNLESS OTHERWISE NOTEO, NONE. Product it a refractory. NOTES: 411073 0380 ^P**-*`r'" WCnON V HBAITH HAZARD DATA* * chbocbo blocks-_____________________ | expqsubb wtoma INORBNBfT EFFECTS OF OVEREXPOSURE Kl Ftm Crystalline Sitka U WOOl far rTOaUCTl Q fatralaum Pitch DsEapod lung fibrosis silicosis SMn, lung, mucous membrane carcinogen Sfcht Irritation; photosensitixation (Sam* as Coal Tar Products) lime Irritant to skin, eyes, mucous membranes, etc. G Phosphoric Acid Primary Irritant skin, ayos, ate Sodium Sillcat* Irritant to skin, eyes, mucous membranes, etc. a M SHORT TERM! in l V V V i. a EMERGENCY O* FIRST AID FROCSOURIS: Irritant*-. Wash from (kin or flush from eyo* using copious amounts of wator. Coal Tar Products: Remove from skin by washing with soap and wator. DO NOT uso solvent*. Sam* for potrolowm pitch. Other: STABIUTY: til STABLE O UNSTABLE Incompatability (materials to avoid) Haxardeu* decernposition products: Hazardous Polymorixatien: G may occur SECTION VI - REACTIVITY DATA COMMBfTS: Store In dry area prior to use. O will not occur SECTION VII. sm AND IRAK PROCEDURES Mott refractory products may b* landfillod. However, tines your application of tbit product may change Us chomical characteristics, and tinea disposal procedures may vary with local* and or* iub|*ct to chango, you should consult fh* govommontal authority having jurisdiction for disposal information. COMMENTS: _________________________________________ SECTION VIII - SPECIAL PROTECTION INFORMATION_______________________________________ RESPIRATORY PROTECTION (CHECK TYPR): tf Approved Dust Other (Specify): VENTILATION: local exhaust ventilation should bo provided if routine operation generaft dust in excess of allowable limits PROTECTIVE GLOVES (CHCCX TYPE): G Add Resistant Impormoabi* G Abrasion Resistant O Other (Specify): EYE PROTECTION: Approved safety glasses, goggle* or facoshieldt should bo used when handling refractory products. FOOT PROTECTION (CHICK BjMfc PROTECTIVE aOTHINO (SFfHPY): & Mstatarsal safoty G Imparmaabls _________________________________________________________ SECTION IX - SPECIAL PRECAUTIONS___________________________________ If block it chocked, product contains coal tar product*. Workers should not be exposod to furnace "bum-in" volatiles. Other (Specify): 411073 0381 Material Safety Data Sheet urc--11IB| HARBtSOM-WALKER REFRACTORIES Oiritmt t Itmmm tsobsmbs. Im.. 2 (merry Cfttr. fmtmrit. fnttrlntit IS222 T&PHONI: (415) 543-4200 TRETYPE: 710-444-4347 __________________________________________________10/01/84 DISCLAIMER Thit data sheet it bated on OSHA FORM SO but modified ta mere adequately tuit refractory products. All data are subject to reasonable variation. This information is supplied in good faith by Harbiton-Walker and is applicable to the product as shipped. Your application ef the product may change its characteristics. THE DATA PROVIDED HEREIN ARE B&IEVEO CORRECT OR ARE OBTAINED FROM SOURCES BELIEVED TO BE GENERALLY RRIABIE. HARBISON-WALKER SHAU NOT BE LIABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INDIRECTLY ARISING FROM THE USE OF THIS PROOUCT, AND HARBISON-WALKER ASSUMES NO OBLIGATION OR UABILITY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS OATA SHEET. This data is not part of any contract or condition of sale. It is solely supplied as an accomodation to the buyer. Product Tradename: LOTHERM SECTION I . PROOUCT lOENTINCATION Typo of Refractory:* Insulating Fireclay Brick 'For chrome containing refractories. Indicate approximate percentage__________ and check applicable Mock. Contains chrome ore consisting predominantly of the mineral chromite (MgFo).0.(AIFoCr)^3j Contains chromium III oxide SEE CHECKED BLOCKS GEN. CHEM. INGREDIENT FORMULA Quartz SIOj SECTION 11 - HAZARDOUS INGREDIENTS C.A.S. NUMBER PHCXNTAGf RANGE OSHA P.E.L. 10 rng/rn^ 001317799 % Rotpirobi# Quarts +2 & Cristobalito SiO? 14444-44-1 5 - 10* Quarts Value Tridymite SIOj 1544B-33-3 Vi Quartz Value Fused Silica SiOj 00743IB49 NONE Cm! Tor Product* N/A MXB001SB9 0.2 mg/m3 Potralovm Pitch N/A MXBOS3424 NONE Phosphoric Add h,po4 0074443(3 1.0 mg/m3 (mist) lime CaO 0013037(4 9.0 mg/m3 O Sodium Silicate 03-Si .3Na 004(34930 NONE a ACOIH TLV9 SAME SAME SAME Use Quartz TLV SAME 5.0 mg/m3 SAME 2.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 7S-130 75-120 75-120 75-130 7B-I07 73-104 NONE NONE NONE SECTION III PHYSICAL DATA Appsoranc* and Odor: Buff to orange color; no odor. Specific Gravity: ^ .44 pH: ND Solubility in Wcrtor: Insoluble. Soluble Constituents: Other: _________________________________________________________ SECTION IV FIRE ANO EXPLOSION DATA UNLESS OTHERWISE NOTED, NONE. Product is a refractory. NOTES: 411073 0382 -H- *SM CHECKED BLOCKS INGREDIENT ; SECTION V . HEALTH HAZARD OATA* EFFECTS OF OVEREXPOSURE H Proa Crystalline Silica Deiafod lung fibre*Is - silicosis Coal Tar Product* Ptrolum Pitch Skill, king, mucous membrane carcinogen Skin irritation; photesonsitixatien (Sam* as Coal Tar Products) Urn* Irritant to skin, eyas, mucous membranes, etc Phosphoric Acid Primary Irritant - skin, eyes, etc Sodium Silicate Irritant to skin, eyes, mucous membranes, etc ^ EXPOSURE MQtXRSO PROLONGED SHORT TERM V V -V-- V V V EMERGENCY OR FIRST AID PROCEDURES: Irritants: Wash from skin or flush from eyas using copious amounts of water. Coal Tar Products: Remove from skin by washing with soap and water. DO NOT use solvent*. Sam* for petroleum pitch. Othor: STABILITY: tt STABLE UNSTABLE lncompotability (material* to avoid) Hazardous decomposition products: Hazardous Polymorixation: may occur SECTION VI REACTIVITY DATA COMMENTS: (X will not occur SECTION VII . SHU AND LEAK FEOCEDURRS Most refractory products may b iondlilltd. However, sine* your application tf Hite product may change its chemical characteristics, and sine* disposal procedures may vary with locale and are sub|ect to change, you should consult the governmental authority having jurisdiction for disposal information. COMMENTS: _________________________________________________ SECTION VIII . SPECIAL PROTECTION INFORMATION______________________________________ RESPIRATORY PtOTECTlON (CHECK TYPE): (X Approved Dust Other (Specify): VENTILATION: Local exhaust vent!lotion should be provided if routine operation generates dust In excess ef allowable limits PROTECTIVE GLOVES (CHECK TYPE): Add Resistant Impermeable & Abrasion Resistant Other (Specify): EYE PROTECTION: Approved safaty.glasses, goggle* or faceshields should bo used whan handling refractory products. FOOT PROTECTION (CHECK. PROTECTIVE CLOTHING (M M Metatarsal safety Impermeable _________________________________________________________ SECTION IX SPECIAL PRECAUTIONS___________________________________ If biedt is checked, product contains coal tar products. Workers should net be exposed t* furnace "bum-ln" volatile*. Other (Specify): 411073 0383 Material Safety . Data Sheet HAHB/SOH-WAIKCH REFRACTORIES Ofrmmt ef Rrsesar fsiksnus /.. 2 Gttwmty Cutr, MtxieryA Hmrhfis 1S222 TELEPHONE: <412) 362-6200 TELETYPE: 710-644-4347 DISCLAIMER 10/01/84 This data sh is based on OSHA FORM 20 but modified to more adequately suit refractory products. All data are subject to reasonable variation. This information is supplied in good faith by Harbison-Walker and is applicable to the product as shipped. Your application of the product may change its characteristics. THE DATA PROVIDED HEREIN ARE BELIEVED CORRECT OR ARE OBTAINED FROM SOURCES BELIEYEO TO BE GENERALLY RELIABLE HARBISON-WALKER SHAU NOT BE LIABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INOIRECTIY ARISING FROM THE USE OF THIS PROOUCT, AND HARBISON-WALKER ASSUMES NO OBLIGATION OR UABIUTY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is not part of any contract or condition of sale. It is solely supplied as an accomodation to the buyer. SECTION I PROOUCT IDENTIFICATION Product Tradename: Type of Refractory:* PH0XB0NPPhosphate Bonded High Alumina Mortar For chrome containing refractories. Indicate approximate pe<vem.ige and check applicable Modi. Contains chromo ora consisting predominantly of the minorol chromito (Mgfa).0.(AIF#Cr)^O^ Contains chromium III oxide SEE CHECKED BLOCKS GEN.CHEM. INGREOIENT FORMULA Quarts SiOj SECTION 11 - HAZARDOUS INGREDIENTS C.A.S. NUMBER PERCENTAGE RANOI OSHA P EL 10 mg/m3 001317799 % Respirable Quarts +2 Cittobalilt Si2 14464-46-1 Vi Quarts Value Tridymite SiOj 1S46S-32-3 Vi Quarts Value Fused Silica Coal Tar Products SiOj N/A 007631(69 MXB0015B9 NONE 0.2 mg/m3 Petroleum Pitch lH Phosphoric Acid lima N/A v CaO MXB0S2424 0076643(2 00130S7BB 0 1 cn NONE 1.0 mg/m3 (mitt) S.O mg/m3 Sodium Silicate 03-Si .2Na 006434920 NONE a ACGIH TLV9 SAME SAME SAME Use Quarts TLV SAME S.O mg/m3 SAME 3.0 mg/m3 NONE NIOSH CRITERIA OOCUMENT NO. 75-120 73-120 75-120 75-120 7B-107 7(-106 NONE NONE NONE _______________________________________________________________ $tCTIOM III - PHYSICAL OATA Appearance and odor: Gray color; odor of phosphoric acid. Specific Gravity: 2-58_________ pH: 2-3 Solubility in Water: AbOUt 12% (dry basis) Soluble Constituents: , other: Phosphoric acid. _____________________________________________________ SECTION IV - HER ANO EXPLOSION OATA UNLESS OTHERWISE NOTED. NONE. Product is a refractory. NOTES: 411073 0384 SEE CHEOaO MOB tNEREWBMT 2dHE&temQN-7- HEALTH HAZARO DATA* ~ " -- EFFECTS OF OVREXPOSURE Free Crystalline Siiie* . Jm^pirfdbng fibrosis . silicosis Coal Tar Products Otk hmg, mucous mombrano carcinogen Skin irritation; photosensitization Petroleum Pitch (Some as Coal Tar Products) Q Un X) Phosphoric Acid Irritant to skin, oyos, mucous membranes, ate. Primary Irritant skin, oyos, ate. Sodium Siikoto Irritant to skin, oyos, mucous mombrano*, etc. / r'S':* v 40 > * ' CT" tst-- EXPOSURE REQUIRED PEOION6EO SHORT TERM V ~T~~ --v-- V V V EMERGENCY OR FIRST AID PROCEDURES: ft Irritant*: Wash from shin or Audi from *yo* using copious amount* of watar. Coal Tar Product*: Romovo from skin by washing with soap and water. OO NOT u*a solvents. Sam* far potroloum pitch. Othor: STABILITY: A STABLE UNSTABLE IncompataMllty (material* to avoid) Hazardous decomposition products: Hazardous Polymerization: may occur SECTION VI REACTIVITY OATA I) will not occur COMMENTS: Store in cool.area. Avoid temperatures in excess of 100 F prior to use. SRCTION VII SPtU AND IRAK PROCEDURES Most rofractory products may bo landfilled. Howovar, sine* your application of this product may chang* its chomical diaroctoristics, and sine* disposal procedure* may vary with local* and are subject to change, you should consult th* govornmontol authority having jurisdiction for ______' disposal information._____________________________________________________________________________________________________ __________________________________ _______________SRCTION VIII - SPROAt PROTiCTION INFORMATION_______________________________ RESPIRATORY PROTECTION (CHECK TYPE): tt Approved Oust D Othor (Spocify): VENTILATION: local exhaust ventilation should bo provided If routine operation generates dust in oxcess of allowable limits PROTECTIVE GLOVES (CHECK TYPE): EYE PROTECTION: Approvedodb^glassos. Resistant Impormoabl* Abrasion Resistant Othor (Spocify): las or focoshiold* should bo usod whan handling rofractory product*. FOOT PROTECTION (' PROTECTIVE CLOTHING d Metatarsal safety Impormoabl* ________ SECTION IX SPECIAL PRECAUTIONS___________________________________ P If Mock is chocked, product contains coal tar product*. Workers should not b* exposed to fumac* "bum-in" volatile*. Other (Spocify): 411073 0385 Material Safety Data Sheet HARB/SOfi-hVAlKER REFRACTORIES tt Orm--r /MtotriM. tmt.. I Stttwtr Cnur. Httttarft. Ptmittrbrfit IS222 DISCLAIMER TREPHONI: (412) 562-4200 TELETYPE: 710-664-4347 10/01/84 This data sheet is baud on OSHA FORM 20 but modified to more adequately suit refractory products. All data are subject to reasonable variation. This information is supplied in good faith by Harbison-Walkor and is applicable to the product as shipped. Your application of the product may change its characteristics. THE DATA PROVIDEO HEREIN ARE BELIEVED CORRECT OR ARE OBTAINED FROM SOURCES BELIEVED TO BE GENERALLY RELIABLE. HAR8ISON-WALKER SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE 0IRECTIY OR INOIRECTLY ARISING FROM THE USE OF THIS PRODUCT, ANO HARBISON-WALKER ASSUMES NO OBLIGATION OR U ABILITY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is net part ef any contract er condition of tale. It it solely supplied as an accomodatien to the buyer. SECTION I - PEOOUCT IDENTIFICATION Product Tradename: Type of Refractory:* H-W SPECIAL MORTAR MIX TYPE B______________________ Fireclay Mortar chrome containing rafrodoriti, indicat# approximate p#rc#ntog, and ch#dt appikabi# block. Q Contains chrom# or# consisting predominantly of th# mineral chromite (Mgp#).0.(AIF#Cr)^Oj Contains chromium ill oxid# SEE CHECKED BLOCKS GEN. CHEM. INGREDIENT FORMULA d Quarts SlOg SECTION II HAZARDOUS INCREMENTS CA.S. NUMBER PERCENTAGE RANGE OSHA P.E.L 001317799 3-5? 10 mg/m3 % Respirable Quarts *2 d Cristobollte SlOg 14464-46-1 12 - 15? Vi Quartz Value .Tridymit# SI02 1546B-32-3 Vi Quart! Value Fused Silico sio2 007631*69 NONE Coal Tar Products N/A MXE001SB9 0.2 mg/m3 Petroleum Pitch N/A MXB0S3424 NONE Phosphoric Acid Lim# w CaO 0076643(2 00130S7BB 1.0 mg/(mist) 3.0 mg/m3 Sodium Silicate 03-SI ,2Na .004(34930 NONE a ACGIH TIV SAME SAME SAME Use Quart! TLV SAME 3.0 mg/m3 SAME 2.0 mg/m^ NONE NIOSH CRITERIA DOCUMENT NO. 73-120 75-120 75-120 75-120 7*-107 7B-106 NONE NONE NONE __________________________________________________________ SfCTtOW III - PHYSICAL DATA Appearance and Oder: Light gray to buff color; earthy odor. Specific Gravity: ^ -10 pH: NP Solubility in Water: Slightly Soluble. Soluble Constituents: riju Other: L ** __________________________________________________________SECTION IV - FIRE AND EXPLOSION DATA UNLESS OTHERWISE NOTED, NONE. Product it a refractory. NOTES: 411073 0386 'SSECHECXeO HOCKS INGREDIENT SECTION V - HEALTH HAZARD DATA* EFFECTS OF OVEREXPOSURE Free Crystalline Silka Coal Tar Products Petroleum Pitch OWgad hang fibred* diked* Skin, lung, mucous membrane carcinogen Skin irritation; pheteseasitixatien (Same as Coal Tar Products) 0 lime Irritant to skin, eyes, mucous membranes, etc. Phosphoric Acid Primary Irritant - skin, eyes, etc Sodium Silicate a a Irritant to skin, eyes, mucous membranes, etc. EXPOSURE REQUIRED PROLONGED SHORT TERM V V V V y/ V EMERGENCY OR FIRST AID PROCEDURES: Irritants: Wash from skin er flush from eyes using copious amounts of water. O Coal Tar Products: Remove from skin by washing with soap and water. DO NOT use solvents. San 'v petroleum pitch. .Other: STABILITY: K) STABLE UNSTABLE incompatability (materials to avoid) Hasardews decomposition products: Hasardeut Polymerisation: may occur SECTION VI REACTIVITY DATA COMMENTS: will not occur SECTION VII - 5PM. AND LEAK PROCEDURES Moat refractory product* may bo landfillod. However, dnc* your application of thil product may chango it* chomicat characteristic*. and ainc* diapoaal procedure* may vary with local* and ar* aubjoct to chango, you thouid contult tho govornmontal authority having juriadictian for diapocal information. COMMENTS: ~ ________________________________________________SECTION VIII - SPECIAL PtOTECTION INFORMATION_____________________________ RESPIRATORY PROTECTION (CHECK TYPE): ti Approved Dual Other (Specify): VENTILATION: local exhaust ventilation ahould bo provided if routine operation gonarato* duct in oxcoss of allowable limit* PROTECTIVE GLOVES (CHECK TYPE): Add Rodatant Impormoabla Abrasion Rotiatant Other (Specify): EYE PROTECTION: Approved safety glasses, goggle* or fac**hi*ld* thouid bo used whan handling refractory product*. FOOT PROTECTION (CHECK TYPE): PROTECTIVE aOTHINO (SPEO^fn tt Motatonal tafoty Impormoabla _______________________________________________________ SECTION IX SPECIAL PRECAUTIONS__________________________________ If block i* checked, product contains coal tor products. Workers should not bo exposed to furnace "burn-in" volatiles. Q Other (Specify): 411073 0387 . Material Safety Data Sheet HARBtSQR-WALKCR RCfRACTQRtCS imam eT Oimmr It*mm. /at. I Stamtr Cttttf. Fmsttrjt Htnrltttt IS222 TELEPHONE: (411) 561-4100 THJTYPE: 710-664-4347 .________________________________________ 10/01/84 DISCLAIMER This data sheet is based on OSHA FORM 10 but modified to more adequately tuit refractory products. All data are subject to reasonable variation. This information is supplied in peed faith by Harbisen-Walker and is applicable to the product as shipped. Your application of the product may change its characteristics. THE OATA PROVIDED HEREIN ARE BBJEVEO CORRECT OR ARE OBTAINED FROM SOURCES BEUEVEO TO 8E GENERALLY RELIABLE. HAR8ISON-WAIKER SHAU NOT BE LIABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INOIRECTIY ARISING FROM THE USE OF THIS PROOUCT. AND HARBISON-WALKER ASSUMES NO OBLIGATION OR LIABILITY FOR RELIANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is net part of any contract or cenditlen of sale. It is solely supplied as an accomodation to the buyer. Product Tradename: SECTION I - PROOUCT IDENTIFICATION Type of Refractory:* H-W SUPERDUTY MORTARFireclay Mortar `For chrome containing refractories, indicate approximate percentage.-- ___ and check applicable Week. Contains chrome ere consisting predominantly of the mineral chromite (MgFe).0.(AlFeCr)^Oj Contains chromium III oxide SEE CHECKED BLOCKS GEN. CHEM. INGREOIENT FORMULA C3 Quarts SiOj SECTION N HAZARDOUS INGREDIENTS C.A.S. NUMBER PfRCSNTAGfl RANGE OSHA P.E.L. 10 mg/m3 001317790 20 - 30% % ItMpirobic Quartz *2 Crittoballt* SiO] 14464-46-1 M Quarts Value Tridymit* SIOj 1546B-31-3 Vi Quarts Value Fused Silica SiOj 007631E69 NONE O C*al Tor Products N/A MXB001SB9 0.2 mg/m3 PtroUum Pitch N/A MXB0S1424 NONE Phosphoric Acid HjP04 - 007664331 1.0 mg/m3 (mist) lime CaO 001305733 S.O mg/m3 Sodium Silicate 03-SI .INa 006334920 NONE a ACOiH TLVa SAME SAMI SAME Use Quarts TLV SAME S.O mg/m3 SAME 2.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 75-120 75-120 75-120 75-120 78-107 73-106 NONE NONE NONE _______________________________________________________________ SECTION III PHYSICAL DATA Appearance and Oder: Gray COlOT; earthy OdOr. Specific Gravity: ^ ` ^________ pH: ________________ Solubility in Water: Slightly Soluble. *.ub.. Constituents: Mreclay> _______________________________________ SECTION IV - FIRE AND EXPLOSION DATA UNLESS OTHERWISE NOTEO, NONE. Product Is a refractory. NOTES: 411073 0388 'SEE CHECKED BLOCKS INGREDIENT SECTION V HEALTH HAZARD DATA* EFFECTS OF OVEREXPOSURE 6 free Crystalline Silica Delayed lung fibrosis - silicosis O Petroleum Pitch Skin, lung, mucous membrone carcinogen Skin irritation; phetosensitixotion (Same as Coal Tar Products) Lime Irritant to skin, eyes, mucous membranes, etc. Phosphoric Acid Primary Irritant - tkin, oyot, otc. O Sodium Silicate a Irritant to skin, eyes, mucous membranes, etc. a EXPOSURE REQUIRED PROLONGED SHORT TERM V ~V~ --y?---------- V V V EMERGENCY OR FIRST AIO PROCEDURES: Irritant*: Wath (ram tkin ar (lush (ram oyo* using ccpiaut amount* o( watar. Coal Tar Product*: Ramava (ram tkin by wahing with *aap and watar. DO NOT u*a Mhront*. Sam* for patrolaum pitch. Other: STABILITY: <8 STABLE UNSTABLE Incompatability (materials to avoid) Hazardous decomposition products: Hazardous Polymerisation: may occur SECTION VI REACTIVITY DATA COMMENTS: 09 will not occur SECTION VII - SPIU. ANO IRAK PROCEDURES; Matt refractory product* may be landfilled. However, tinea your application of thi* product may change it* chemical charactarittic*. and tine* di*pe*al procedure* may vary with local* and ar* tubjact to change, you thouid consult the governmental authority having jurisdiction (ar disposal information. COMMENTS: __________________________________________________SECTION VIII - SPECIAL PROTECTION INFORMATION_______________________________________ RESPIRATORY PROTECTION (CHECK TYPE): A Approved Oust O Other (Specify): VENTILATION: Local exhaust ventilation should bo provided if routine operation generates dust In excess of allowable limits PROTECTIVE GLOVES (CHECK TYPE): Acid Resistant Impermeable Abrasion Resistant Other (Specify): EYE PROTECTION: Approved safety glasses, goggles or faceshields should be used when handling refractory products. FOOT PROTECTION (CHECK TYPE): PROTECTIVE aOTHING (SPECIFY): d Motatarsal safety Impormoabl* _________________________________________________________ SECTION IX SPECIAL PRECAUTIONS___________________________________ If block is checked, product contains cool tar products. Workers should not bo exposed to furnace "bum*in" volatiles. Other (Specify): 4A1073 0389 Material Safety Data Sheet HAR8IS0M-WAIKER REFRACTORIES Oknmt tf Orttmr /t+ttrmt. lac. 2 Stttwtf CsKttr. pfnyWrye, AmrAwa 1S222 TEl&HONE: (412] 142-6200 TELETYPE: 710-664-4347 ______________________________________________ ____10/01/84 DISCLAIMER This data sheet is batad on OSHA FORM 20 but modified lo more adequately suit refractory product*. All data are tubjocl to roatonablo variation. Thi* information i* iuppliod in good faith by HarbUon-Wallcor and i* applicable to the product as shipped. Your application of I he product may change its characteristic*. THE DATA PROVIDED HEREIN ARE BELIEVED CORRECT OR ARE OBTAINED FROM SOURCES BELIEVED TO BE GENERALLY RELIABLE. HARBISON-WALKER SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE DIRECTLY OR INDIRECTLY ARISING FROM THE USE OF THIS PRODUCT. AND HARBISON-WALKER ASSUMES NO OBUGATION OR UABIUTY FOR REUANCE ON THE INFORMATION CONTAINED IN THIS DATA SHEET. This data is not part of any contract or condition of sale. It it solely supplied a* an accomodation to the buyer. SECTION I - PROOUCT IDENTIFICATION Product Tradename: Typo of Refractory:* THERMOLITH Chrome Refractory Mortar *For chrome containing refractories, indicate approximate percerilage^Hl, and check applicable block. tjC Contains chrome ore consisting predominantly of the mineral chromite (MgFe).0.(AIFeCr)^Oj Contain* chromium III outdo SEE CHECKE0 BLOCKS GEN. CHEM. INGREDIENT FORMULA d( Quarts SiOg SECTION II HAZARDOUS INGREDIENTS CA.S. NUMBER PERCENTAGE RANGE OSHA P.E.L 10 mg/m3 0 1 ** 001317790 % Ratpirabla Quarts *2 Cristoballte SiOg 14464-46-1 Vt Quarts Valua Trldymite SiOg 1J44B-32-3 H Quarts Value O Fu*od Silica SiOg 007631869 NONE Coal Tar Products N/A MXEOOISE9 0.2 mg/m3 Petroleum Pitch N/A MXB0S2424 NONE Phosphoric Acid Umo w CaO 007664342 0013057B4 1.0 mp/m^ (mitt) S.O mg/m3 o 1 CO if] Sodium Silicate 03-Si 2Na 006434920 NONE O ACGIH TLVa SAME SAME SAME Use Quarts TLV SAME S.O mg/m3 SAME 2.0 mg/m3 NONE NIOSH CRITERIA DOCUMENT NO. 75-120 73-120 75-120 7S-120 74-107 74-106 NONE NONE NONE SICTION III * PHYSICAL DATA Appaaran id Odor: Dark gray color; odor of sodium silicate. Specific Gravity: 1-92 _pHu:. ND Solubility in Water: SI ightly SOl Ubl e. other*c#n****u*n,*: Sodium Silicate, amber powder (gum) __________________________________________________________SECTION IV - FIRE ANO EXPLOSION DATA UNLESS OTHERWISE NOTED, NONE. Product is a refractory. NOTES: 411073 0390 SEE CHECKED BLOCKS INGREDIENT SECTION V . HEALTH HAZARO OATA* EFFECTS OF OVEREXPOSURE Froo Crystalline Silica Cool Tor frodvKlt Petroleum Pitch timo Delayed lung fibres!* - silicosis Skin, lung, mucous membrane carcinogen Skin irritation; photosonsitisotion (Sam# as Coal Tar Products) Irritant to skin, oyos. mucous membranes, otc. Phosphoric Acid Primary Irritant - skin* oyos, otc d( Sodium Silicate Irritant to skin, eyes, mucous membranes, etc. EXPOSUEE ESQUIBED PROLONGED SHORT TERM V V V V V V EMERGENCY OR FIRST AID PROCEDURES: CX Irritants: Wash from shin or flush from ayes using copious amounts of water. Cool Tor Products: Remove from skin by washing with soap and water. DO NOT use solvents. Sam* *or petroleum pitch. Other: STABILITY: cK STABLE UNSTABLE Incempatability (materials to avoid) Hazardous decomposition products: Hazardous Polymerization: may occur SECTION VI - REACTIVITY OATA COMMENTS: A will not occur - SECTION VII - SPIU AND LEAK PROCEDURES Mttt refractory product* may bo landflllod. Hewever, tinea your application of Ihit product may change it* chemical characteristic*, and tinea disposal procedute* may vary with locale and are subject to change, you should consult the governmental authority having jurisdiction for disposal information.___________________________________________________________________________________________________ COMMENTS: ________________________________________________SECTION VIII SPECIAL PROTECTION INFORMATION_____________________________ RESPIRATORY PROTECTION (CHECK TYPE): ft Approved Dust Other (Specify): VENTILATION: Local eshaust ventilation should bo provided if routine operation generate* dust in escett of allowable limits cX PreventPROTECTIVE CLOVES (CHECK TYPE): Add Resistant Impermeable Abrasion Resistant Other (Specify): EYE PROTECTION: Approved safety glasses, goggle* or facethields should be used when handling refractory products. d i rpr t FOOT PROTECTION (CHECK TYPE): PROTECTIVE CLOTHING (SPECIFY): K) Metatarsal safety Impermeable skin contact. _______________________________________________________ SECTION IX - SPECIAL PRECAUTIONS__________________________________ If block is checked, product contain* coal tar product*. Workart should not bo exposed to furnace "burn-in" volatile*. Other (Specify): 411073 0391 MATERIAL SAFETY DATA SHEET MC-X-01046 MSOS NUMBER I________________________ PROOUCT IDENTIFICATION 4338 TRADE NAME GENERIC NAME Molten Metal MARINITECalcium Silicate/Asbestos MANUFACTURER'S NAME CAS NUMBER Manville Products Corporation ADDRESS (STREET) PHONE NUMBER P. 0. Box 5108 303/978-3120 CITY STATE ZIP CHEMICAL STRUCTURE Denver Colorado 80217 Board I . PROOUCT INGREDIENTS MATERIAL Amosite asbestos fiber (encapsulated) Calcium Silicate CAS NUMBER % 1332-21-4----- 40 -.60 TLV 2 f/cc 5 mo/m^ respirable dust Cutting, drilling, or otherwise abraiding this product will release asbestos fiber -- see health hazard information below. II PHYSICAL DATA BOILING POINT NA SPECIFIC GRAVITY 0.6 SOLUBILITY IN WATER Negligible PERCENT VOLATILE APPEARANCE ANO ODOR Solid brownish sheet - no odor III FIRE AND EXPLOSION DATA FLASH POINT ,LEL FLAMMABLE LIMITS Nonflammable_________________________________________________ EXTINGUISHING MEOIA -HA-___________________________________________________________________ SPECIAL FIREFIGHTING PROCEDURES -None______________________________________________________________________________________________ UNUSUAL FIRE OR EXPLOSION HAZAROS None IV HEALTH HAZARD INFORMATION _r HAZARD BY ROUTES OF EXPOSURE (Indicate chronic or acute) inhalation Excessive exposure to^bigh concentrations of airborne asbestos fiber can cause chronic pulmonary disease and cancer. Product is a known human carcinogen. ,N#|im53!ift?fia?uS!iilsiluiAsthih?S|eili88 82t^i|&f^tfliSSi8sSiiel!aeen fiber found in environmental and current occupational situations. EYE As with any dust, excessive exposures can cause transient irritation. Fibers can become imbedded m skin and m some cases SKIN ABSORPTION None SIGNS AND SYMPTOMS ASSOCIATED WITH EXPOSURE OVER TLV There are no acute signs or symptoms associated with result in ZZ asbes'bos. asbestos corns". The diseases associated with overexposure are chronic, generally taking from 10 to 40 years to become apparent. HEALTH HAZARD INFORMATION CONTINUED ON BACK 411073 0394 V HEALTH HAZARD INFORMATION (Continued) __________________________________________________________________ FIRST AID_____________________________ INHALATION Remove to fresh air. Avoid inhalation of tobacco smoke. INGESTION NA EVE CONTACT Flush with copious quantities of water.____________________ SKIN CONTACT Wash or shower thoroughly using soap and warm water. SKIN ABSORPTION NA VI CONDITIONS FOR SAFE USE (When over TLV) RESPIRATORY PROTECTION Pse respirators approved for protection against pneumoconioai'producinqr dusts EYE PROTECTION Goggles are recommended when using power cutting tools. PROTECTIVE GLOVES Not normally required.; other protective clothing/equipment Use special clothing as required by OSHA Standard for Exposure to Asbestos Dust 29 CFR 1910.1001(d). ventilation requirements Control with mechanical dust collection equipment to within TLV. (See American National Standards Institute booklet Z9.2 - 1971). VII . REACTIVITY DATA IS MATERIAL STABLE? Yes INCOMPATIBILITY NA HAZARDOUS DECOMPOSITION PRODUCTS None WILL HAZARDOUS POLYMERIZATION OCCUR? No CONDITIONS TO AVOIO NA VIII SPILL OR LEAK PROCEDURES issteps to be taken if mateial spilled or released Vacuum clean spillage and dust created during fabrication. If sweeping is necessary, wet down spillage. Use approved respiratory eguipment when reguired. WASTE DISPOSAL METHOD LABELING REQUIRED? NO RCRA REGULATED? DOT REGULATED? RCRA NUMBER OOT NUMBER IX SPECIAL PRECAUTIONS SPECIAL PRECAUTIONS FOR HANOLING AND STORAGE Store flat. OTHER PRECAUTIONS Smoking greatly increases the chance for asbestos-related lung disease. If you work with asbestos, DO NOT SMOKE. PREPARED BY Kenneth A. Roberts .DATE 6/1/84 .TITLE Mgr., En tal Services While the information and recommendations set forth herein are believed to be accurate as of the date hereof, THE MANUFACTURER MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM REUANCE-TMgREON. ~ -___ MATERIAL SAFETY DATA SHEET MC-x-onm___________________________ _ MSOS NUMBER PRODUCT IDENTIFICATION TRADE NAME MARINITE C MANUFACTURER'S NAME Manville Buildinq Materials Corporation ADDRESS (STREET) P. 0. Box 5108 CITY Denver STATE Colorado ZIP 80217 GENERIC NAME Calcium Silicate Board CAS NUMBER PHONE NUMBER (303) 978-3120 CHEMICAL STRUCTURE I PRODUCT INGREDIENTS MATERIAL Calcium silicate matrix Calcium silicate reinforcinq filler Natural oroanic fiber Fibrous Glass CAS NUMBER % 1344-95-2 50 10101-39-0. -.40 65996-61-4v^ ^4-6 65997-17-3 4-6 TLV 5 mq/mJ respirable BOILING POINT N/A SOLUBILITY IN WATER Negligible APPEARANCE ANO OOOR Gray board - no odor FLASH POINT Nonflammable EXTINGUISHING MEDIA N/A . SPECIAL FIREFIGHTING PROCEDURES UNUSUAL FIRE OR EXPLOSION HAZARDS II PHYSICAL DATA SPECIFIC GRAVITY 0.7 PERCENT VOLATILE III FIRE AND EXPLOSION DATA FLAMMABLE LIMITS r IV HEALTH HAZARD INFORMATION ________________________________ HAZARD BY ROUTES OF EXPOSURE (Indicate chronic or acute) INHALATION Nuisance dust - no known acute or chronic health hazards. INGESTION None__________________________________________________________________________________ EYE Transient mechanical irritant.__________________________________________ SKIN CONTACT None__________________________________________________________________________________ SKIN ABSORPTION None SIGNS ANO SYMPTOMS ASSOCIATED WITH EXPOSURE OVER TLV Inhalation - excessive exposures to product dust may cause upper respiratory irritation. Eye - temporary irritation or inf lamination. ______ - - - HEALTH HAZARO INFORMATION CONTINUED ON BACK 4 ~ *' ' . 411073 0396 MMMMMPIRr V HEALTH HAZARD INFORMATION (Continued) FIRST AID INHALATION Remove to fresh air. INGESTION JiZ&_______ EYE CONTACT Flush with CQPioua quantities of water. SKIN CONTACT JiZfi___________ SKIN ABSORPTION 1UL VI CONOmOHS FOR SAFE USE (Whan over TLV) respiratory protection At areas of dust generation, use a respirator^snltable for protection against nuisance dusts. ________________ EYE PROTECTION Use goggles when cutting/ drilling, abraiding with power equipment. PROTECTIVE GLOVES Recommended when carrying and installing product.____________________________________ OTHER PROTECTIVE CLOTHING/EOUIPMENT Hot normally required. VENTILATION REQUIREMENTS JJse^^local^xhaus^ventilatior^n jjjower fabrication VII REACTIVITY DATA IS MATERIAL STABLE? WILL HAZARDOUS POLYMERIZATION OCCUR? Yes INCOMPATIBILITY No CONDITIONS TO AVOIO Hone in designed use_____________ ______________ HAZARDOUS DECOMPOSITION PROOUCTS vm SPILL OR LEAK PROCEDURES Steps to be taken if mateial is spilled or released Wet sweep or vacuum dust and scrap resulting from fabrication. WASTE DISPOSAL METHOO Comply with local, state and federal regulations covering nonhazardous LABELING REQUIRED? Ho RCRA REGULATED? No DOT REGULATED? RCRA NUMBER OOT NUMBER IX SPECIAL PRECAUTIONS SPECIAL PRECAUTIONS FOR HANOUNG ANO STORAGE Do not drop. OTHER PRECAUTIONS PREPAREO BY Kenneth A. Roberts DATE 6/29/84 Vrrr**- ihtal Services WhMetheJrrformation and recommendations sat forth heroin are believed to be accurate aa of .the date jjMAKES tW yVARRANTY VyiTH RESPECT l^ER^TO AND DISCLAIMS ALL LIABILITY^FROM I,-THE MANUFACTURER ^FFMERtSDN.------ MATERIAL SAFETY DATA SHEET MC-X-0I046 MSDS NUMBER 3013 PRODUCT IDENTIFICATION TRADE name SUPEREX 2000 MANUFACTURER'S NAME Manville Building Materials Corporation ADDRESS (STREET) P. 0. Box 5108 CITY Denver STATE Colorado ZIP 80217 GENERIC NAME Thermal Insulation CAS NUMBER PHONE NUMBER (303) 978-3120 CHEMICAL STRUCTURE - Calcium Silicate Diatomaceous earth Clay Reinforcina fiber MATERIAL I PRODUCT INGREDIENTS CAS NUMBER 1344-95-2. 7631-86-9' 1302-78-9 % 15 73 10 2 TLV 2.7 ma/m3* Total dust This TLV recocrnizes the combined Dresence of approximately 2% cristobalite and 5* free crystalline silica. BOILING POINT gQLjJBIUTY IN WATER II PHYSICAL DATA SPECIFIC GRAVITY 0.4 PERCENT VOLATILE APPEARANCE AND ODOR Dense solid block - no odor. FLASH POINT Nonflammable EXTINGUISHING MEDIA Ill FIRE AND EXPLOSION DATA LEL FLAMMABLE UMITS SPECIAL FIREFIGHTING PROCEDURES UNUSUAL FIRE OR EXPLOSION HAZARDS UEL IV HEALTH HAZARD INFORMATION HAZARD BY ROUTES OF EXPOSURE (Indicate chronic or acute) inhalation prolonged exposure to dust generated during installation or removal may cause chronic pulmonary disease. INGESTION None EYE Transient mechanical irritant. SKIN CONTACT None SKIN ABSORPTION None SIGNS AND SYMPTOMS ASSOCIATED WITH EXPOSURE OVER TLV ` Inhalation -- excessive exposures to product dust may cause -upper respiratory irritation.__________________________________________________ ____________ Eve - temporary irritation or inflammation. HEALTH HAZARD INFORMATION CONTINUED ON BACK 411073 0398 r -- INHALATION Remove to fresh air. INGESTION V HEALTH HAZARO INFORMATION (Continued) FIRST AID EYE CONTACT Flush with copious quantities of water. SKIN CONTACT SKIN ABSORPTION VI CONDITIONS FOR SAFE USE (When over TLV) RESPIRATORY PROTECTION NIOSH approved respirator EYE PROTECTION Not normally required. PROTECTIVE GLOVES for protection against pneumoconiosis-producing dusts. OTHER PROTECTIVE CLOTHING/EQUIPMENT VENTILATION REQUIREMENTS _Recommgidgd_at==areasss!of=me32afi^4] VII REACTIVITY DATA IS MATERIAL STABLE? Yes INCOMPATIBILITY Hydrofluoric acid HAZARDOUS DECOMPOSITION PRODUCTS WILL HAZARDOUS POLYMERIZATION OCCUR? No CONDITIONS TO AVOIO VIII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATEIAL IS SPILLED OR RELEASED When sweeping, use a dust suppressant. Vacuum clean fine dust. WASTE DISPOSAL METHOD Comply with local, state & federal regulations. L^EUNG REOUIRED? DOT REGULATED? ^pRA REGULATED? RCRA NUMBER DOT NUMBER IX . SPECIAL PRECAUTIONS SPECIAL PRECAUTIONS FOR HANDLING AND STORAGE Avoid creating dust.________________ other precautions See caution label on carton. PREPARED BY , Kenneth A. Roberts_________________ DATE | 6/10/83 , .TITLE |Mgr., Envli^nmental Services While the information and recommendations set forth herein are believed to be accurate as of the date hereof, THE MANUFACTURER MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. MATERIAL SAFETY DATA SHEET MC-X-0KM6__________________ ' __________ MSOS NUMBER 3014 PROOUCT IDENTIFICATION TRADE NAME GENERIC NAME Calcium SUPEREX 1600_________________________________________________ Silicate Thermal Insulation MANUFACTURER'S NAME CAS NUMBER Manville Building Materials Corporation ADORESS (STREET) P. 0. Box 5108 PHONE NUMBER (303) 978-3120 CITY Denver STATE Colorado ZIP 80217 CHEMICAL STRUCTURE I PROOUCT INGREDIENTS Calcium Silicate Glass Fiber Orqanic Fiber MATERIAL CAS NUMBER % 1344-95-2 $5 65997-17-3 3 - . .. 2 TLV 5 mCT/mJ respirable dust II PHYSICAL DATA BOILING POINT N/A SOLUBILITY IN WATER Nil APPEARANCE AND OOOR White odorless solid - pipe covering SPECIFIC GRAVITY 0.21 PERCENT VOLATILE H?0 12% or block. HI FIRE ANO EXPLOSION OATA FLASH POINT Nonflammable .LEL FLAMMABLE LIMITS 1 EXTINGUISHING MEDIA N/A SPECIAL FIREFIGHTING PROCEDURES N/A UNUSUAL FIRE OR EXPLOSION HAZAROS N/A________________________ _________________________________________________ ,UEL _J______ IV HEALTH HAZARD INFORMATION _____________ _________ HAZARD BY ROUTES OF EXPOSURE (Indicate chronic of acute)____________ inhalation Dust created during installation is considered a nuisance dust. No known acute or chronic health hazards._______________________________ INGESTION None EYE Transient mechanical irritant._______________________________________________________ SKIN CONTACT None ______________________________________________________________________________________ SKIN ABSORPTION None ______________________________________________________________________________________ signs ano symptoms associated with EXPOSURE over tlv Inhalation - excessive exposures to product dust may cause upper respiratory irritation. Eyes - temporary irritation or inflammation. HEALTH HAZARD INFORMATION 'CONTINUED ON BACK V . HEALTH HAZARD INFORMATION (Continued) RflSUO^N. IFICA f ION INHALATION Remove to freah air.______________________ INGESTION N/A_______________ - i.________________ EYE CONTACT Flush with copious quantities of water. SKIN CONTACT N/A ________________________________________________ SKIN ABSORPTION N/A VI CONDITIONS FOR SAFE USE (When ever TLV) - --------- respiratory-protection JHhen using mechanical cutting or abraiding equipment, you should use a respirator suitable for protection aaainst nuisance dusts. EYE PROTECTION Not normally required. PROTECTIVE GLOVES -- OTHER PROTECTIVE CLOTHING/EQUIPMENT -- VENTILATION REQUIREMENTS Recommended at fabrication sites. -e* * VII REACTIVITY DATA IS MATERIAL STABLE? Yes INCOMPATIBILITY Strong acid HAZARDOUS DECOMPOSITION PROOUCTS WILL HAZARDOUS POLYMERIZATION OCCUR? No CONDITIONS TO AVOfO VHI SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATEIAL IS SPILLED OR RELEASED Vacuum clean spillage. If sweeping is necessary, use a dust suppressant. waste disposal methoo Dispose in closed containers, comply with all .Local, state, and federal regulations. k*EUNG REQUIRED? OOT REGULATED? DOT NUMBER RCRA REGULATED? No RCRA NUMBER * *- IX SPECIAL PRECAUTIONS SPECIAL PRECAUTIONS FOR HANDLING AND STORAGE Avoid creating dust. Keep material dry. OTHER PRECAUTIONS PREPARED BY Kenneth A. Roberts IOATS 9/27/83 il.TllILTSLE -- I Mgr.,Environmental Services WWM the Information arKlrecommendationa aet forth herein are believed to be accurate as of the date hereof. THE MANUFACTURER MAKES*<^A9R(ANTYtWITH .RESRECT .THERETO AND DISCLAIMS ALL UA8IUTY FROM RELIANCE THEREON. 411073 0401 MATERIAL SAFETY DATA SHEET MC-X-01046 MSOS NUMBER 3310 PROOUCT IDENTIFICATION traoe name Insulating Fire Brick manufacturer s name Manville Building Materials Corporation ADDRESS (STREET) P. 0. Box 5108 CITY STATE ZIP Denver Colorado 80217 GENERIC NAME Insulating Fire Brick CAS NUMBER PHONE NUMBER (303) 978-3120 CHEMICAL STRUCTURE I PRODUCT INGREDIENTS MATERIAL Inert ceramic matrix i.e., Mullite. corundum, anthorite CAS NUMBER % 70-90 TLV This refractory Droduct also may contain free crystalline auartz and cristobalite which will vary in cruantitv with degree of firing both prior to and during service;for TLV refer to CFR 1910.1000, Table Z-3 "Mineral Dusts". II PHYSICAL DATA BOILING POINT SOLUBILITY IN WATER Nil APPEARANCE AND OOOR Solid off white to pinkish brick - no odor SPECIFIC GRAVITY 0.5 PERCENT VOLATILE III FIRE AND EXPLOSION OATA FLASH POINT Non flammable EXTINGUISHING MEDIA N/A SPECIAL FIREFIGHTING PROCEDURES .LEL FLAMMABLE LIMITS UNUSUAL FIRE-OR EXPLOSION HAZARDS UEL 1 IV HEALTH HAZARD INFORMATION HAZARD BY ROUTES OF EXPOSURE (Indicate chronic or acute)_____________________________ inhalation Prolonged exposure to excessive concentrations of dust generated during installation or tear-out may cause chronic pulmonary disease. INGESTION None EYE Transient jreshgnicfll., irritant SKIN CONTACT none SKIN ABSORPTION _____________________________________________________________________________________ SIGNS AND SYMPTOMS ASSOCIATED WITH EXPOSURE OVER TLV : v- ' , Inhalation - Excessive exposure may cause upper respiratory irritation. Eye - Temporary irritation or inflammation_________________ _____________________ HEALTH HAZARD INFORMATION CONTINUED ON BACK 411073 0402 V HEALTH HAZARO INFORMATION (Continued) FIRST AID INHALATION Remove to fresh air; INGESTION N/A_______________________________________________________________________ EYE CONTACT Flush with copious quantities of water SKIN CONTACT N/A^ SKIN ABSORPTION N/A VI CONDITIONS FOR SAFE USE (When over TLV) RESPIRATORY PROTECTION ! NIOSH approved respirator for protection against pneumoocnlosis-producincr dus ts. EYE PROTECTION Goggles recommended during cutting, chipping, and breakup operations PROTECTIVE GLOVES OTHER PROTECTIVE CLOTHING/EQUIPMENT VENTILATION REQUIREMENTS _Reco^ended_at_cutting_locaiions^2i_4MiB3_Sg^U; VII REACTIVITY DATA IS MATERIAL STABLE? Yes______________ INCOMPATIBILITY WILL HAZARDOUS POLYMERIZATION OCCUR? _N2______________________________ CONDITIONS TO AVOID HAZARDOUS DECOMPOSITION PRODUCTS VIII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATEIAL IS SPILLED OR RELEASED ' Vacuum clean dust generated during installation and tear-out. If sweeping is necessary, use a WASTE DISPOSAL METHOO Dispose in closed containers. I.ABEUING REQUIRED? Yes RCRA REGULATED? No Comply with local, state Si federal regulations. DOT REGULATED? DOT NUMBER RCRA NUMBER IX . SPECIAL PRECAUTIONS SPECIAL PRECAUTIONS FOR HANDLING AND STORAGE OTHER PRECAUTIONS See caution on product packaging. PREPARED BY DATE .TITLE .?/*;.r Kenneth A. Roberts| 6/17/83|Mgr., Environmental Services While the information and recommendations set forth herein are believed to be accurate as of the date hereof. THE MANUFACTURER - MAKES NO-WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREQN. MATERIAL SAFETY DATA SHEET MC-X-01048 MSDS NUMBER IP 3211 t PROOUCTIDENTIFICATION TRADE NAME ____ _ 460 Cement MANUFACTURER'S NAME Manville Buildincr Materials ADORESS (STREET) P. 0. Box 5108 CITY STATE Denver. Colorado Corp. ZIP 80217 GENERIC NAME ^1 Insulating Cement CAS NUMBER PHONE NUMBER 303/978-3120 CHEMICAL STRUCTURE I PROOUCT INGREDIENTS MATERIAL Mineral Wool Clav PyroDhvllite Natural diatomaceous earth CAS NUMBER 65997-17-3 1302-78-9 None 7631-86-9 % '55 25 10 10 TLV 30 mppcf o 10 mg/M3 total dust 20 moocf BOIUNG POINT SOLUBILITY IN WATER Slight APPEARANCE ANO OOOR Gray powder - no odor FLASH POINT Nonflammable______________ EXTINGUISHING MEDIA SPECIAL FIREFIGHTING PROCEDURES UNUSUAL FIRE OR EXPLOSION HAZARDS II . PHYSICAL DATA SPECIFIC GRAVITY PERCENT VOLATILE III FIRE ANO EXPLOSION DATA FLAMMABLE LIMITS |LEL r IV HEALTH HAZARD INFORMATION HAZARD BY ROUTES OF EXPOSURE (Indicate chronic or acute) INHALATION Nuisance dust. INGESTION No known acute or chronic health hazards. None EYE Transient mechanical irritant. skin contact None SKIN ABSORPTION None SIGNS AND SYMPTOMS ASSOCIATED WITH EXPOSURE OVER TLV Inhalation - excessive exposures may cause upper respiratory irritation. Eyes - temporary irritation or inflammation. _____________________________ HEALTH HAZARD INFORMATION CONTINUED ON BACK 411073 0404 V HEALTH HAZARD INFORMATION (Continued) FIRST AID INHALATION ______ Remove to fresh.air. INGESTION NA EYE CONTACT Flush with copious quantities of water. SKIN CONTACT NA SKIN ABSORPTION NA VT CONDITIONS FOR SAFE USE (When over TLV) RESPIRATORY PROTECTION Use a respirator suitable for protection against nuisance dusts. EYE PROTECTION Not normally required._______________________________________________________ 1________ PROTECTIVE GLOVES OTHER PROTECTIVE CLOTHING/EQUIPMENT VENTILATION REQUIREMENTS Recommended at baa openi.no stations. VII REACTIVITY OATA IS MATERIAL STABLE? Yes INCOMPATIBILITY Hydrofluoric acid HAZARDOUS DECOMPOSITION PRODUCTS WILL HAZARDOUS POLYMERIZATION OCCUR? No CONDITIONS TO AVOID VIII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATEIAL IS SPILLEO OR RELEASED Vacuum clean spillage. If sweeping is necessary, use a dust suppressant. Repair all baas._______________________________________________________________________________ waste disposalmethoo Dispose in closed containers. Comply with all local, state and federal regulations. LABELING REQUIRED? NO DOT REGULATED? DOT NUMBER RCRA REGULATED? NO RCRA NUMBER IX SPECIAL PRECAUTIONS SPECIAL PRECAUTIONS FOR HANDLING AND STORAGE Avoid creating dust. Repair all broken bags. Keep material dry. OTHER PRECAUTIONS PREPARED BY Kenneth A. Roberts DATE ! 5/4/83 .TITLE hgr. EnvitfOnatental Services While the information and recommendations set forth herein are believed to be accurate as of the date hereof, THE MANUFACTURER MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCEJMEREON___ ______