Document VJ28voR2ojvNjpgrMeKQMwvKZ
TO:
Distribution
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Interoffice Communication
FROM: DATE:
SUBJ:
T. G, Grumbles November 12, 1991
EO PERMEATION STUDY
VISTA
The attached report was done to evaluate breakthrough times for garments typically used for emergency response in EO environments. A vapor test and a splash test were run. A full publication of the work is being done, but for now the results table is available.
T. G. Grumbles dlj .335
Attachment
Distribution: Keith Fogg-LCCP, Robert Martin-Austin
WV 000008088
CHEMICAL MANUFACTURERS ASSOCIATION
October 24, 1991
TO: EOIC Industrial Hygiene Task Group RE: Completion and results of permeation study
Please find enclosed one copy of a summary table and individual test reports of the nine selected materials, against ethylene oxide. I hope you find the material useful. If you have any questions or comments, please do not hesitate to contact me at (202)-887-1198.
Sincerely yours
Enel
Robert R. Romano, Ph.D. Associate Director CHEMSTAR Manager, E.O.I.C.
VVV 000008009
J-ftL TRI/Environmental, Inc. A Texas Research International Company
August 26, 1991
Mr. Robert Romano Chemical Manufacturers Association 2501 M. Street NW Washington, DC 20037
Dear Mr. Romano:
We have completed the permeation study of the nine selected materials against ethylene oxide as specified in Amendment No. 2 to the CMA-TRI Contract No. EO-28.0-TRI. Attached are a summary table and individual test reports for each material tested.
We tested each of the nine material to ethylene oxide gas for 8 hours in accordance with ASTM F739. The North G-1510-R PVC coated glove originally specified is no longer produced. Instead we substituted their model number 3112 PVC coated glove which replaces the specified model. We tested Responder Seam twice, since in the initial test, we found one breakthrough within four minutes while in the other replicates there was no breakthrough. When we tested a different lot of Responder Seam, we saw breakthrough times all less than 4 minutes.
As instructed, we tested those materials demonstrating a breakthrough times greater than
60 minutes to liquid ethylene oxide splash exposures. The liquid splash was conducted
for a period of 10 seconds and then removed from the test cell. This test was conducted
for four of the materials: Ansell nitrile glove, 4H glove, Chemrel Max seam, and Responder
seam. The Responder seam was included despite its inconsistent performance against
ethylene oxide gas.
f"W-
Please contact me if you have any questions.
Sincerely,
Jeffrey O. Stull Division Manager Barrier & Materials Technology
JOS:jmm
VVV 000008090
9063 Bee Caves Road -Austin, TX 78733-6201 -(512) 263-2101 -1-800-880-T-E-ST
00000
PERMEATION SUMMARY RESULTS FOR CHEMICAL MANUFACTURERS ASSOCIATION
HATFRIAI
CHECH CAt,
EXPOSES
AriseU Ecfcnont Nitrile Glove (Solvex 37-155) Ansell Ecknont Nitrile Glove (Solvex 37-155) Chernrel Seam
Chemrel Max Seam
Chernrel Max Seam
4-H Glove Seam
4-H Glove Seam
North PVC Coated Glove (Model 3112) North 12 Mil Viton
Pioneer Stanzoil/Milled Neoprene Gloves Responder Seam
Responder Seam
Responder Seam
Silvershield Seam
Ethylene Oxide
Gas
Ethylene Oxide
Splash
Ethylene Oxide
Gas
Ethylene Oxide
Gas
Ethylene
Splash
Oxide
Ethylene ^ Gas
Oxide
1
Ethylene
Splash
Oxide
Ethylene Oxide
Gas
Ethylene Oxide
Gas
Ethylene Oxide
Gas
Ethylene Oxide
Gas
Ethylene Oxide
Gas
Ethylene Oxide
Splash
Ethylene Oxide
Gas
PFRMEAT10N 8REAKTHP0UGH TIMF (minute*)
PERMEATION RATE (Mg/cn<hr)
CELL 1 60
chl 2 68
CELL 3 84
CELL 1 47
CELL 2 42
CELL 3 57
<4 4
4
40 61
180
<4 <4 <4 1.1 .21 .32
NO BT
NO BT
NO BT
N/A
N/A
N/A
NO BT
NO BT
NO BT
N/A
N/A
N/A
NO BT
NO BT
NO BT
N/A
N/A
H/A
NO BT
NO BT
NO BT
N/A
N/A
N/A
8 8 4 120 120 130
28 20 24 77 72 73
36 28 38 70 55 90
NO BT
NO BT
<4
N/A N/A >6.2
<4 <4 <4 1.5 .04 .03
NO BT
NO BT
NO BT
N/A
N/A
N/A
<4 <4 <4 11 .37 2.3
MINIMUM DETrl"TION LIMIT (pciffl)
.09 1 .2 .2 .1 .3 .6 .1 .06 .2 .08 .08 .2 .9
TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No.
Method StandardASTM F739-85
Material Log No.
391-152-2
Test Date08-01-91
Analyst '
PERMEATION TEST REPORT
QC Date
Material Name: ANSELL EDMONT NITRILE GLOVE YSOLVEX 37-155)_____________
Prior Conditioning: NONE
Test Duration:8_hours
Challenge Chemical: ETHYLENE OXIDE Concentration:
Chemical Source LINDE CAS No.:75-21 -8
Test Temperature: 27 C 100 %
TEST RESULTS
Breakthrough Time
Permeation R ate
Steady State Maximum
X
Unit Area Weight
Thickness
Units Minutes
Hq/ctt?-min
gms/cn^ mils
Cell 1 60
47
0.0540 16
Cell 2 68
42
0.0594 16
Cell 3 84
57
0.0515 13
Modifications of Method: 1" CELLS
Analytical Technique: CONTINUOUS PHOTOIONIZATIQN... -]
Sampling Frequency: 4 MINUTES
Chemical State: GAS________________________________________________________________________
Type of Contact: CONTINUOUS__________________________________________________________________________________
Collection Medium: NITROGEN
Minimum Detection Limit: .09 ppm_________________________________________________________________________________
Minimum Detectable Rate: .003 ua/cn^*min
Comments:
yVV 000008092
These data are derived from tests performed in accordance with ASTM Standard F739-85. These testa were performed under laboratory conditions and not under actual usage conditions. TRI/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability of material for actual anticipated exposure.
TIME EXPOSED TO ttC M IO .L in m in u t e s
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vw 000008093
TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No..
Method Standard
ASTM F739-85
Material Log No.
391-152-2
Test Date
08-21-91
Analyst
? hi QC Date
PERMEATION TEST REPORT
Material Name: ANSELL EDMONT NITRILE Test Temperature: 27 C Prior Conditioning: NONE Test Duration:8 hours Challenge Chemical: ETHYLENE OXIDE Concentration: Chemical Source LINDE CAS No.:75-21-8
100 %
TEST RESULTS
Breakthrough Time
Permeation R ate
Steady State Maximum
X
Unit Area Weight
Thickness
Units Minutes
^g/crr^-min
gms/cm2 mils
Cell 1 <4
40
.0417 14
Cel! 2 4
61
.0398 14
Cell 3 4
180
.0383 14
Modifications of Method: t" CELLS__________ Analytical Technique: CONTINUOUS PHOTOIONIZATION________________________
-T'f* _ Sampling Frequency: 4 MINUTES
Chemical State: LIQUID
Type of Contact: 10 SEC EXPOSURE Collection Medium: NITROGEN Minimum Detection Limit: 1 ppm
Minimum Detectable Rate: .05 uci/cnf *min
Comments:
VVV 000008094
These data are derived from tests performed in accordance with ASTM Standard F739-85. These tests were performed under laboratory conditions an. not under actual usage conditions. TRI/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed
no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability of material for actual anticipated exposure.
TIME: EXPOSED t o c h e m ic a l . in m in u t e s
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(spuosno'4j_)
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VVV OOOOOBQ95
TRl/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No, Method StandardASTM F739-85 Material Log No. 391-32-4 Test Date07-29-91
Analyst
*
QC Date
PERMEATION TEST REPORT
Material Name: CHEMREL SEAM Test Temperature: 27 *C _
Prior Conditioning: NONE Test Duration:8_hours
Challenge Chemical: ETHYLENE OXIDE Concentration:
100 %
Chemical Source LINDE_____________________________________________ __________ , CAS No.: 75-21-8
TEST RESULTS
Breakthrough Time
Permeation Rate Steady State * Maximum
Unit Area Weight
Thickness
Units Minutes
|! g/cm2-min
gms/cm2 mils
Cell 1 <4
1.1
0.0291 31
Cell 2 <4
.21
0.0298 32
Cell 3 <4
.32
0.0284 25
Modifications of Method: 1" CELLS_______________________ Analytical Technique: CONTINUOUS PHOTOIONIZATION Sampling Frequency: 4 MINUTES_________________________ Chemical State: GAS ______ _____________________________ Type of Contact: CONTINUOUS__________________________ Collection Medium: NITROGEN___________________________ Minimum Detection Limit: .2 pom _______________________ Minimum Detectable Rate: .007 u,a/cm2*min______________ Comments:
VVV 000008096
These data are derived from tests performed in accordance with ASTM Standard F739-B5. These tests were performed under laboratory conditions ano not under actual usage conditions. TRl/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitabilityof material for actual anticipated exposure.
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VVV 000008097
Mm IVOWUl .-4w* f
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TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON. DC 20037
Customer P.O. No.
Method StandardASTM F739-85
Material Log No. 91-543-2-9
Test Date
07-25-91
PERMEATION TEST REPORT
Material Name: CHEMREL MAX SEAM. Test Temperature: 27 `C Prior Conditioning: NONE Test Duration:8 hours Challenge Chemical: ETHYLENE OXIDE Concentration: 100 Chemical Source LINDE CAS No.:
%______ 75-21-8
TEST RESULTS
Breakthrough Time
Permeation Rate Steady State Maximum
Unit Area Weight
Thickness
Units Minutes
l-l g/cm2-min
gms/cm2 mils
Cell 1 NO BT
N/A
0.0599 73
Cell 2 NO BT
N/A
0.0590 73
Cell 3 NO BT
N/A
0.0594 73
Modifications of Method: 1 * CELLS_____________________ Analytical Technique: CONTINUOUS PHOTOIONIZATION
*T' Sampling Frequency: 4 MINUTES______________________
Chemical State: GAS__________________________________
Type of Contact: CONTINUOUS________________________
Collection Medium: NITROGEN_________________________ Minimum Detection Limit: .1 ppm_______________________
Minimum Detectable Rate: .1 Hg/cm2*min______________
Comments:
000008098
.These data are derived from tests performed in accordance with ASTM Standard F739-85. These tests were performed under laboratory conditions ar>w not under actual usage conditions. TRI/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed
no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitabiiityof material for actual anticipated exposure.
TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512} 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No.
Method Standard
ASTM F739-85
Material Loa No. 391-32-4
Test Date
08-21-91
,2 .
Analyst
(ps/2i '
QC Date
PERMEATION TEST REPORT
Material Name: CHEMREL MAX SEAM Prior Conditioninq: NONE Challenne Chemical: ETHYLENE OXIDE Chemical Source LINDE
Test Temoerature: 27 C
Test Duration:
8 hours
Concentration: 100 %
CAS No.:
75-21-8
TEST RESULTS
Breakthrough Time
Permeation R ate Steady State Maximum
Unit Area Weight
Thickness
Units Minutes
^g/crr^-min
gms/crr^ mils
Cell 1 NO BT
N/A
.0147 11
Cell 2 NO BT
N/A
.0136 9
Cell 3 NO BT
N/A
.0138 10
Modifications of Method: 1" CELLS___________________________
Analytical Technique: CONTINUOUS PHOTOIONIZATION
Sampling Frequency: 4 MINUTES_____________________________
Chemical State: LIQUID______________________________________
Type of Contact: 10 SEC EXPOSURE_________________________
Collection Medium: NITROGEN_______________________________
Minimum Detection Limit: ,2 oom______________________________
Minimum Detectable Rate: .008 ua/cm2*min
Comments:
VVV 000008099
These data are derived from tests performed in accordance with ASTM Standard F739-85. These tests were performed under laboratory conditions and not under actual usage conditions. TRI/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability of material for actual anticipated exposure.
TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No.__________________
Method StandardASTM F739-85
Material Log No.
391-111-5
Test Date07-26-91
rj~-. e.. (Pd?I
Analyst
* QC Date
PERMEATION TEST REPORT
Material Name: 4 H GLOVE SEAM Test Temperature: 27 *C
Prior Conditioning: NONE Test Duration:8_hours
Challenge Chemical: ETHYLENE OXIDE Concentration: 100
%
Chemical Source LINDE
CAS No.:_________________________________________________________75-21-8
TEST RESULTS
Breakthrough Time
Permeation Hate Steady State Maximum
Unit Area Weight
Thickness
Units Minutes
|_Lg/cm2-min
gms/cm2 mils
Cell 1 NO BT
N/A
0.0116 15
Cell 2 NO BT
N/A
0.0108 15
Cell 3 NO BT
N/A
0.0111 15
Modifications of Method: 1" CELLS Analytical Technique: CONTINUOUS PHOTOIONIZATION
_______________ _______________________________
Sampling Frequency: 4 MINUTES_____________________ ______________________________________________________
Chemical State: GAS Type of Contact: CONTINUOUS Collection Medium: NITROGEN Minimum Detection Limit: .3 ppm
Minimum Detectable Rate: .01 lla/cm2*min_________________________________________________________________
Comments:
WV 000008X00
These data are derived from tests performed in accordance with ASTM Standard F739-65. These tests were performed under laboratory conditions a. not under actual usage conditions. TRI/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability for use of this materia) with the chemical tested. The user should determine the applicability of test conditions when assessing surtabilityof material for actual anticipated exposure.
TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No.
Method StandardASTM F739-85
Material Log No. 391-111-5
Test Date
08-20-91
PERMEATION TEST REPORT
Material Name: 4-H GLOVE SEAM Prior Conditioning: NONE_____________ Challenge Chemical: ETHYLENE OXIDE Chemical Source LINDE_____________
Test Temperature: 27 C
Test Duration:8 hours
Concentration: 100 %
CAS No.:
75-21-8
TEST RESULTS
Breakthrough Time
Permeation Rate Steady State Maximum
Unit Area Weight
Thickness
Units Minutes
^g/crT^-min
gms/crr^ mils
Cell 1 NO BT
N/A
.009 3
Cell 2 NO BT
N/A
.007 3
Cell 3 NO BT
N/A
.009 3
Modifications of Method: 1" CELLS_____________________________________________________________________
Analytical Technique: CONTINUOUS PHOTOIONIZATION_____________________ __________________________
Sampling Frequency: 4 MINUTES______________________________________________________________________
Chemical State: LIQUID_______________________________________________________________________________
Type of Contact: SPLASH______________________________________________________________________________
Collection Medium: NITROGEN________________________________________________________________________
Minimum Detection Limit: .6 ppm________________________________________________________________________
Minimum Detectable Rate: .02 ua/crr^*min_____________________________________________________________
Comments:
00000Sl01
These data are derived from tests performed in accordance with ASTM Standard F739-65. These tests were performed under laboratory conditions and not under actual usage conditions. TRI/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability
of material for actual anticipated exposure.
TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET. NW WASHINGTON. DC 20037
Customer P.O. No.
Method Standard
ASTM F739-RR
Material Loq No.
391-154-1
Test Date
08-14-91
Csb&fae K Analyst
Mif J'QC
Date
PERMEATION TEST REPORT
Material Name: NORTH PVC COATED GLOVE (MODEL 31121____________________
Prior Conditioning: NONE
Test Duration:8 hours
Challenge Chemical: ETHYLENE OXIDE Concentration: 100
Chemical Source LINDE CAS No.:75-21 -8
Test Temperature: 27 C %
TEST RESULTS
Breakthrough Time
Permeation R ate
Steady State Maximum
X
Unit Area Weight
Thickness
Units Minutes
/ig/crrf-min
gms/cnf mils
Cell 1 8
120
0.1255 47
Cell 2 8
120
0.1374 52
Cell 3 4
130
0.1371 51
Modifications of Method: 1" CELLS_______________ ____
Analytical Technique: CONTINUOUS PHOTOIONIZATION ^:
Sampling Frequency: 4 MINUTES_______
_
Chemical State: GAS_____________ .
Type of Contact: CONTINUOUS
Collection Medium: NITROGEN
Minimum Detection Limit: .1 pom..
Minimum Detectable Rate: .005 ua/crrF*min
Comments:
________ __
________ vvv 000003i02
These data are derived from tests performed in accordance with ASTM Standard F739-B5. These tests were performed under laboratory conditions and not under actual usage conditions. TRI/Errvfronmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability of material for actual anticipated exposure.
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VVV 000008103
TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No.
Method StandardASTM F739-85
Material Log No.
89-543-10-4
Test Date07-25-91
y**"*v
Analyst
PERMEATION TEST REPORT
Material Name: NORTH 12 MILVITON Test Temperature: 27 C Prior Conditioning: NONE Test Duration:8 hours Challenge Chemical: ETHYLENE OXIDE Concentration: Chemical Source LINDE CAS No.:
QC Date
100 % 75-21-8
TEST RESULTS
Breakthrough Time
Permeation R ate
Steady State Maximum
X
Unit Area Weight
Thickness
Units Minutes
Aig/cnrf-min
gms/crr? mils
Cell 1 28
77
0.1077 17
Cell 2 20
72
0.1101 17
Cell 3 24
73
0.1084 17
Modifications of Method: 1" CELLS_______________________ Analytical Technique: CONTINUOUS PHOTOIONIZATION Sampling Frequency: 4 MINUTES_____________________ _ Chemical State: GAS____________________________________
A
Type of Contact: CONTINUOUS_________________________ Collection Medium: NITROGEN__________________________ Minimum Detection Limit: .06 ppm________________________ Minimum Detectable Rate: .002 ua/crrf *min______________ Comments: MATERIAL SWELLED.
VVV 000008104
These data are derived from tests performed in accordance with ASTM Standard F739*85. These tests were performed under laboratory conditions ai*. not under actual usage conditions. TRI/Environmental, inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability far use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability of material for actual anticipated exposure.
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TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No.
Method Standard
ASTM F739-85
Material Log No.
391 -152-1
Test Date_____________ 08-01-91
Analyst
PERMEATION TEST REPORT
' QC Date
Material Name: PIONEER STANZOIL/MILLED NEOPRENE GLOVES______________ Prior Conditioning: NONE Test Duration:S_hours Challenge Chemical: ETHYLENE OXIDE Concentration: Chemical Source LINDECAS No.:75-21-8
Test Temperature: 27 C 100 %
TEST RESULTS
Units
Breakthrough Time
Minutes
Permeation R ate
Steady State Maximum
X
^g/crr^-min
Unit Area Weight
gms/crr^
Thickness
mils
Cell 1 36
70
0.1728 35
Cell 2 28
55
0.1770 35
Cell 3 38
90
0.1745 35
Modifications of Method: V CELLS Analytical Technique: CONTINUOUS PHOTOIONIZATION: Sampling Frequency: 4 MINUTES] Chemical State: GAS Type of Contact: CONTINUOUS Collection Medium: NITROGEN Minimum Detection Limit: .2 ppm Minimum Detectable Rate: .006 ua/crrf *min Comments:
VVV 000008106
These data are derived from tests performed in accordance with ASTM Standard F739-85. These tests were performed under laboratory conditions. not under actual usage conditions. TRt/Environmentai, Inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability of material for actual anticipated exposure.
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TRl/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No. Method StandardASTM F739-85 Material Log No._______ 391-75-2
Test Date08-14-91
Analyst
PERMEATION TEST REPORT
Material Name: RESPONDER SEAM Test Temperature:
Prior Conditioning: NONE
Test Duration:8_hours
Challenge Chemical: ETHYLENE OXIDE Concentration:
Chemical Source: LINDE_______________ CAS No.:
' QC Date
27 C 99.9 % 75-21-8
TEST RESULTS
Breakthrough Time
Permeation R ate
Steady State
Maximum
X
Unit Area Weight
Thickness
Units Minutes
ug/crrf-min
gms/cnf mils
Cell 1 NO BT
N/A
.0635 50
Cell 2 NO BT
N/A
.0624 52
Cell 3 <4
>6.2
.0600 46
Modifications of Method: 1" CELLS_______________________
Analytical Technique: CONTINUOUS PHOTOIONIZATION _
Sampling Frequency: 4 MINUTES____________________ __
Chemical State: GAS__________________________
___
Type of Contact: CONTINUOUS_________________________
Collection Medium: NITROGEN__________________________
Minimum Detection Limit: .08 ppm_______________________ Minimum Detectable Rate: .003 ua/cnrf *min______________
Comments:
VVV 000008108
These data are derived from tests performed in accordance with ASTM Standard F739-85. These tests were performed under laboratory conditions a not under actual usage conditions. TRl/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability of material for actual anticipated exposure.
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TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No.
Method Standard Material Loa No.
ASTM F739-85 39-75-2
Test Date
08-14-91
PERMEATION TEST REPORT
Material Name: RESPONDER SEAM' Test Temperature: 27 'C Prior Conditioning: NONE Test Duration:8 hours Challenge Chemical: ETHYLENE OXIDE Concentration: 100 Chemical Source LINDE CAS No.:
Analyst
' QC Date
%______ 75-21-8
TEST RESULTS
Breakthrough Time
Permeation Rate Steady State x Maximum
Unit Area Weight
Thickness
Units Minutes
H.g/cm2-min
gms/cm2 mils
Cell 1 <4
1.5
0.0631 51
Cell 2 <4
.04
0.0642 53
Cell 3 <4
.03
0.0653 55
Modifications of Method: 1" CELLS_________________________________________________________________ _________
Analytical Technique: CONTINUOUS PHOTOIONIZATION:
Sampling Frequency: 4 MINUTES^
Chemical State: GAS
Type of Contact: CONTINUOUS
Collection Medium: NITROGEN
Minimum Detection Limit: .08 ppm________________________________________________________________________ __
Minimum Detectable Rate: .003 Lla/cm2*min_____________________________________________________________ ___
Comments:
VVV 00000811G
These data are derived from tests performed in accordance with ASTM Standard F739-85. These tests were performed under laboratory conditions a. not under actual usage conditions. TRI/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitabilityof material for actual anticipated exposure.
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TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON. DC 20037
Customer P.0. No.
Method Standard
ASTM F739-85
Material Loa No. 391-75-2
Test Date
08-20-91
Ccub***.
Analyst 9 QC Date
PERMEATION TEST REPORT
Material Name: RESPONDER SEAM Prior Conditionina: NONE Ohallenne Chemical- FTHYLENE OXIDE Chemical Source LINDE
Test TemDerature: 27 C
Test Duration:
8 hours
Concentration: 100 %
CAS No.:
75-21-8
TEST RESULTS
Breakthrough Time
Permeation R ate Steady State Maximum
Unit Area Weight
Thickness
Units Minutes
pg/crr^-min
gms/crrf mils
Ceil 1 NO BT
N/A
.0629 35
Cell 2 NO BT
N/A
.0612 31
Cell 3 NO BT
N/A
.0621 31
Modifications of Method: 1" CELLS_______________________ Analytical Technique: CONTINUOUS PHOTOIONIZATION Sampling Frequency: 4 MINUTES________________________ Chemical State: LIQUID_________________________________ Type of Contact: 10 SEC EXPOSURE____________________ Collection Medium: NITROGEN__________________________ Minimum Detection Limit: 2 ppm__________________________ Minimum Detectable Rate: .07 tiQ/crrf*min_______________ Comments:
vvv 000008112
These data are derived from tests performed in accordance with ASTM Standard F739-85. These tests were performed under laboratory conditions an,, not under actual usage conditions. TRI/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed
no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability of material for actual anticipated exposure.
TRI/Environmental, Inc 9063 Bee Caves Road Austin, TX 78733 Phone: (512) 263 2101
CHEMICAL MANUFACTURERS ASSOCIATION 2501 M. STREET, NW WASHINGTON, DC 20037
Customer P.O. No. Method StandardASTM F739-85 Material Log No. 91-543-18-4 Test Date______________07-29-91
Analyst
QC
PERMEATION TEST REPORT
Material Name: S1LVERSHIELD SEAM Test Temperature:_27_lC Prior Conditioning: NONE____________________________________________ ________ ___
Test Duration:8 hours
Challenge Chemical: ETHYLENE OXIDE Concentration: 100 %
Chemical Source LINDE CAS No.:
75-21-8
Date
TEST RESULTS
Breakthrough Time
Permeation Rate
Steady State
Maximum
x
Unit Area Weight
Thickness
Units Minutes
|lg/cm2-min
gms/cm2 mils
Cell 1 <4
11
0.0157 26
Cell 2 <4
.37
0.0159 26
Cell 3 <4
2.3
0.0165 26
Modifications of Method: 1" CELLS________________________________________________________________________ Analytical Technique: CONTINUOUS PHOTOIONIZATION: Sampling Frequency: 4 MINUTES;
Chemical State: GAS_______________________________________________ _________________
Type of Contact: CONTINUOUS
Collection Medium: NITROGEN_______ _______ __
Minimum Detection Limit: .9 ppm
_________
Minimum Detectable Rate: .03 Ua/cm2*min__
Comments:
VW 000008113
These data are derived from tests performed in accordance with ASTM Standard F739-85. These tests were performed under laboratory conditions and
not under actual usage conditions. TRI/Environmental, Inc. makes no warranties or other guarantees concerning protection by this material and assumed
no liability for use of this material with the chemical tested. The user should determine the applicability of test conditions when assessing suitability
of material for actual anticipated exposure.
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