Document VGZ1dp6K31vdLv6VDG4m76gYp
Charles Hess John Born
C
c
July 26, 1974
Analysis of Vinyl Chloride Personal Monitor Samples
The carbon tube personal monitor samples which arrived on June 28 and July 17, I974 have been analyzed. Corporate Environmental Services Lab has measured each amount of adsorbed vinyl chloride. These samples have been given log numbers of 48 and 77. Please state the log numbers in any inquiry about them.
The attached table gives the results of the analyses. The ppm values are based on the specific air volume sampled. The results have not been extrapolated to 8-hour time-weighted average values. Any inquiries about the sampling details of carbon tube exposures will be referred to you.
cad cc:
A. R. Webber E. B. Katzenmeyer, J. C. McCool L. B. Crider G. D. Schaaf R&D Files
Jr.
)HN W. BORN Dept. 8506
J0OZ9T9Z
6
\
BFG46662
Sample Number
' 32 33 34 35 36 37 38 39 40 41 42 43
54 55 56 57 58 59 60 61 62
Sampling Location
Bldg. 515 Compound Bldg. 512 Bldg. 513 Bldg. 513 Bldg. 513 Bldg. 512 Bldg. 512 Bldg. 512 Bldg. 513 Bldg. 513 Bldg. 513
Bldg. 513 Bldg. 513 Bldg. 513 Bldg. 512 Bldg. 512 Bldg. 512 Bldg. 513 Bldg. 513
Bldg. 513
BFG46663
ZOOZ9T92
1
Job Class
Paste Drier Technician Rover Technician Utility Technician Lead Technician Paste Technician Rover Technician Utility Technician Utility Technician Operator Paste Technician Pearl Technician Rover Technician
Pearl Technician Paste Technician Rover Technician Ope rator Utility Technician Utility Technician Rover Technician
Pearl Technician Paste Technician
* * Sampling Time (min)
250 240
25 245 250 240
24 220 220 245 230 240
240 240 240 235 235 235 245 240 240
Vinyl Chloride Concentration JE5iL
1.6 0. 59 0. 90 0. 85 8. 6 16.
1. 7 2. 9 0. 51 4. 6 4.6 4. 6
2. 6 0. 93 14. 1. 3 14. 26.
29. 5.4^
0. 97 7. 8 8. 0 7. 9
7. 6 10.
3. 4
5.9 8. 6 39. 2. 6 2.3 2.8
13. IS.
5. 6 10. 15. 67.
4. 4 3.9 4.6.^
0^ /* /`f
COVE?. EACH MAJOR PROCESS USTMO A SEPARATE QUESTIONNAIRE
2, Define the number of workers involved in the manufacture of VC or PVC by specific job classification and by nrccess.
Job Classification
jumber
Process
Production Lead technician
Console technician Technician
n
w M
Serviceman
3
2
5 4 12 8
2
1 4
8
Maintenance Mechanics Maintenance supervisor
; 14 2
Supervisor and Sunoort Plant Manacrer Plant Encineer Professional Service Mgr, Area Manager nR
Chemists Lead technicians Technicians Area engineers '
HH
Design engineers
1 1 1 1 ^
3 4 6 3
2
5
Other Technician Technician trainee " **
Serviceman
1 4 4
4
Pearl
Paste Mass
Pearl, paste, mass
Pearl/paste polv
" " drver
* " relief
** Mass
" catalyst
Mass
Pearl/paste, mass
Pearl/paste Mass Laboratory
H
M
Pearl/oaste Mass Engineering
Tank farru ---- Warehouseman
Pearl/mass bagger
KM
M
26163001
Foster D. Snell, Inc,
BFG46664
PEDRICKTOTs^ PLANT
r
Page 10
III. PERSONAL PRCfTECTIVE EOUIP^NT
1. What are vou currently using under the 50 ppm emergency standard and describe the operating conditions?
I. Air-Purifying Respirators A, Combination vinyl service and PVC dust service
Cl) American Optical 5000-R55 Cartridge
a. Cartridge replacement daily or on high exposure.
(2.) Application
a. rise when concentration of VCL in work area is be tween 25 and 50 non and/or dust orotection is needed.
b. Vessel entry as specified in SA-4 Vessel Entry Procedure.
B. PVC dust service
(1.)
American Optical 5000- R 30
American Optical 2000- R 90
MSA Dustfoe 66-
MSA 66
filter filter filter
a. Filter replacement daily or if air-flow becomes restricted.
(2.) Application
a. Pearl/paste and mass resin bagging operations b. Bulk loading and unloading tank cars and trucks c. Dusty housekeeping operations. d. Any excessively dusty area e. Vessel entry as snecified in SA-4 Vessel Entrv Procedure.
II. Scott AirPaks and Air-Line Respirators
- "
A. Use in any area contaminated with:
<U Vinvl chloride
B, Examples of Scott Air Pak or air-line mask usage for vinvl chloride are as follows:
IP
:0 Q C 9 T
(1.) Vessel entrv as snecified in SA-4 Vessel Entrv Procedure
(2.) Building atmosphere above 50 nnm VCL
(3.) Making and breaking connections durina loading and unload
ing operations
(4.) VCL sa^nlina or erauainq (5.) Broakina into vinvl lines or equipment
(6.) Chanoing VCL filters.
BFG46665
PEDRICKTOWN PLANT
r
III. Protective Clothing
A. Daily chances of clothinq will ha provided to all direct employees assigned to production and warehousing operations, and to maintenance emolovees assiqned to jobs in those areas where exposure to vinvl chloride monomer or PVC could occur.
These areas include:
Pearl/paste resin polvmerization Mass resin oolvmerization Resin bagginq Resin drying Tank farm
Clothing contaminated by accidental spills of VCL or PVC will be changed as soon as possible*
B. Protective gloves, suits, and head covers
U.)
Protective gloves will be v?om by workers exposed to VC1 or PVC during routine opedations and excessively wet or dusty operations.
(2.) Protective Tyvek disposable suits will be worn by vrorkers ex posed to excessive dry PVC.
(3*) Protective plastic disposable suits and rubber footwear will be worn by workers exposed to excessive wet PVC.
(4.) Protective head covers will be worn by workers exnosed to excessive wet or dry PVC when hard hats cannot be worn.
Examples of the above are: cleaning autoclaves and nolvs, cleaning accumulated PVC from overhead structures, chancing dustex bags, cleaning in the silo area, cleaning drvers, any excessivelv wet or dustv housekeeping operations, etc.
After the above type of operations, the worker should remove the protective gear and wash his hands and face.
2. What was the purchased cost of this equipment and what are their operation and maintenance costing?
Respiratory protection Supplies (replacement parts,, filters) Maintenance material Work clothing Disposable clothing (and plastic suits)
$21,183/vear $25,800/vear $ 5,000/vear $50,OOO/vear $ 6,OOO/vear
26163003
^G*6666
c
PEDRICKTONN PLANT
r
t'a'ric
3, Vfhat equipment and at what approximate ourchased, oneratinq and maintenance costs would you use assuming best effort to reduce exoosure throucjh other means?
To comply with a 25 ppm (ceiling) limit
Ans.j Canister and air-line mask combination.
"No detectable" limit
Ans.: Not aoolicable.
26163004
BFG46667
ADVANCE COPY
Attachment i
Questionnaire i vinyl chloride (vc) and polyvinyl chloride (pvc) iacilities
(2 t p\ &D4DJI ifl/f. C*
i L-- CoAsi pAr*y^
1, General Plant Layout: a* Is it an outdoor facility?
f/V
b. How long has the plant been in operation?
c Is the equipment corroded?
&
Is the equipment in need of maintenance? NO Specify;
26164001
e Is the housekeeping good? .aspects? '
%JL
Poor?
la which
Where is the control room located?
1 A^O Ay-*-
PfaW 6 f fa/VA^T-1 >u L fLtf
<U Ury-
. g. Other pertinent details re general plant layout; ^
C&7V/V^L-
S-
7) i
LfrPry\ ~T H i
/J? A e /FdKCJZJ> C^-NlC
Lts 'fc
____________________*
BFG46668
Raw Materials
..
a. Indicate the raw.materials: 1/7vV W
. /k CTMD mts'/Z- ,
...
C^/'f l-&f\ \ D
br How are these handled?
T/k^~ t
RM L- TfaiLr*
' ChA.1 & Thru << THu.c.k??, UmL&h-ovzo a <r -A--
L-t> tg i-3>
fL P
c* What provisions is made for^heir storage?
Silo? ________ Tank? _______ Car?
'Bags? ___ Pressure area? ____ Other?
4* What controls are enforced while these materials are In storage?
* '.CthZCK' /AlTO -A.
JtL
fcjr'.FC Pi Fast
pftoc.&e.? - &/%
*3 *> Thh Uj g 7~ 2- 9^</.
e. Is entry to storage facilities accomplished with an air supplied
mask?
X>*i l-- 6/
UrtiltA,
^IAP;^
tr^L
If not, how?
Hov are withdrawals of raw materials controlled? __
Closed system? 1/ &J?
Exhaust system?
Out of doors? Fv'fi-CuA.rf-it^ O-P-
Other? flPlh/L PiTC^
JX.
<T. `
^ar-
7T
COM--
Ptr-&TlbN br>
T~t> r&c-o\re^
m
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ft a, LDhpsA'3> /*> o n
BFG46669
1
3* Manufacturing Process
a* What process is used?
VCi Direct chlorination?
Oxychlorination?
Other?
_____
-ftFT--
fr-T' THIS PLbrvT-
,, P&frn.
` PVC;
Polymerization?, *Pa 57^
.
a?w p
Wet? ST PeASKt- fl^Ac-nsris 2S
%
Dry? L.lC&toS&D Ua. n tTa -rag.
t xc-r
M
9 PA-ST&ft&AttttKS
fi\g-Aj cif PAs>Ct5?S.
JXhetr- 1 PSK-C^- PiL-ls XL 4~ MtT7>
f> 8^7'
Pvy-y teizAi'zJfiTVdfSg
# b* What Is the method of recycle for the unreacted vinyl chloride?
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P&/}*& D
ftf
t&e-tL&p. ls i ru c&m PA.vtfS's & as A-S
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c. ' In vhat form is the finished product? frfr'l/CL* S/ <g~
Powder?
?.
Af t Pellets?
,f* A
Gas?
/^^TKjTi lS/z_
___________________________ff ftc^S-Z'- 17 &->'>
___
How is it shipped? 'r&titus, .
*3 *
(? *- <-- *r"
r Rfrn-----------
iN3 - --' -' 01
Vhat are the container sizes?
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cv ------------------------ &-
oy $ **--*> / irc>j *+o .jf-
BFG46670
4# . Controls for the Containment of VC and/or Control of Reaction
. Vhafc controls are utilized?
n u, / A& U* A~
-
Describe:
V ti_ rytv s^l o^t-fs/x
A G> ITA r? *- s'
6* ^&<-S> 1 r rn-&- R^cnn^
.. Axe the controls arranged to fall-safe? -
h. Are two sources of supply provided for? Is iB^'S
Cooling water? * P/^f> P id/ &i~4.--?
t
' r r ""
-- " ' "
A*v P S^r^o
' U-/A G9-veL >
Electricity? f^TK.brN'Tla+ --
Compressed air? .
Refrigeration? Are they automatic? Co
P l&f 0 *\ Cotra T/fy i~'$& SyP^^A. _
fboll~T0P hhht fp fk,iiAJ 4 fr~w
PTk fKQy/Yf: *
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,c* Where is the control room/area located?
- * A^t/ /ft/_______ '
p7^/r*\/i t) P l&'iK PT/ a? Q- J\~/Z &- YfP.
Y
is It kt positive pressure with respect to contaminated areas?
Y-Y2.
' P c>? urns ^
p/^ P.<3Szs^^
Is it it least 200 feet from major VC storage or processing?
,,
Are written control/startup/shutdown procedures available to
operating personnel?
l/f
JSV. *D 5z?T~?f1
BFG46671
is:
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3* Ventilation
.*
a* What la the type of ventilation system? Us/svt F /%.
Ayy. Q if/& M
gj? Z7(^zru. /?.
^^
1 *2- ----
iStZi r**
^ -^V *2~c
_______
^/T^rrv 6 S P&n 77t7^~. la it adequate? ________________ ;_______________________ _____________
b. Where Is the air exhausted?
7~~0 ' A~ 7~Ad 6 *5
Is the air treated before exhaustion? A/ *C/
How?
.\
c. ^ Is makeup air introduced In sufficient volume to maintain correct
operation? ' @ P 1Zn_
s Lc>u s B/l _____________________
Where does the makeup air come from? JQ La. ~T~ ^ )Q ^-
Is it treated?
hA "O________ How? _________________
Is It heated in* the winter?
t/e-s
Tfw P&n:
F~ 'AY/?:
d. . Is the entry air to the control room treated?
*
How? _____ __
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BFG46672
i
6. Waste Materials
a. What is the disposition of waste materials? ^Su
P
* ^<p -5
Buried?
_____ Burned?
I't *?*?"?*
, /_g>e-L o.'L AV/vofe
Wnere?
How?
/T!Pf fK&rG-jO
c' ___
]h j=H4AJ
City dump? Describe: _________
Other?
rt
jy'C- p
Treated? How?
Specify*, l/r^ //4- U'PrT# ft- /S
.
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sr^'i _vs' sf 3y*r ^. iS. ^>-
b* Other pertinent specifics relative Waste zoaterials *
; / A5^ 'T'
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v-t>" ^>'Ar*J / Tvfr*. ty'
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^ ^5" TT^A^i _ 0/ & L-oa / A- <-- Fyrre+y^
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BFG46673
261(54006
7 Sanitation
A* What sanitation facilities are provided?
Shower?
i Vashroom?
LfJZS.
Change room? Lunchroom?
,L-~Cc/\t
Individual lockers? ____fiL&_
~ Drinking fountains?
Toilets?
iAfy&'T
4'Ll3 <SS
b* Comment on location, accessibility, adequacy, utilization.
condition, etc. of pertinent sanitation facilities:
t.
/
AD \7 v? T7i.T. '->*/ 4.-
%w* -nJ> -- -'j*
8* Exposure to VC
a* la which activities is there a potential for exposure to VC? _____
fh)
kTK<cyfir?
S' t'2-
% <O
_____________________
How many employees are involved in each activity?
What is the length of the potential exposure time?
fYP, f
-
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"P .t~UUL~ 3}-/] fZ''T~
b.Are the activity areas regulated?
A'T' ft ItfaUt-hnTZ>
Indicate which; /^tfR XpM p udw ^ &S
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huV ftfZ.$fi/AfirTT)P>
J
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Give the rationale for establishing these;
n> 7~
.t'Wjnxu.fiG, to
]/'* &*_______________________________
Are all employees generally aware--of the hazards presented by VC or PVC?
To what extent is labeling or posting of signs used to appropriate!:
inform or warn employees?
S^/ (S W S?
Asp
gyj-TV^/^
ik
hn6fr? ,
BFG46675
-ADVANCE COPY
9. Protective Clothing and Equipment*.
*
*
4* What articles of protective clothing and equipment are the
employees provided? ^
PS
PKOV\D&>
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fc t-OV-JZ. ft* A W> r/t*< //y ' T)?/<3
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Are they required to wear or use these? '
Do they wear or use these? Specify L/ fz^{s
b* Do employees change into work clothes upon arrival at the plant and back into street clothes before departing? - W
C.^Do they shower at the end of the day? L/ a-^x^a ?____________
/**
'. Do they wash hands and face before eating lunch?
1^3 .
VherA do they eat lunch? L~/x W c-rt' Floods, P&ftC^/yrKZO
How are clothing and equipment articles cared for? Cc>i-t-.ticTTP
* lUt^,__________________________
BFG46676
(1) How often cleaned?
%? Pr l
.
1 How? A-lx~r Q / P > C^t>
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. Where?
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ftf r* *
(2) ' Are they decontaminated after use? 7VCT~ 3 f*/*-.
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.
TlfS^ /
Which use?
2S161009
When?
Where?
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L
ADVANCE copy
9# Protective Clothing and Equipment*-*Continued
g. How often are the articles replaced?
fey
i'
`
t
9l/zfjE? L- i4f/L p^r *>
___________________________________________
What determines replacement?
V^lC A Jgv-g.
Us Hyrt h 6
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: * Respiratory protection devices are covered in question 10--omit here.
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BFG46677
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10* Rcap:tratory Protection
' . .,
a* What kiud of respiratory protection devices are provided? /# --
/^> SooTf ft iR pftctcs .
7^
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S&rci
C'A^r/zT6 pK'$?PiAr^r-ans c^mt~
r>g^r, A^f < 1/ &F > --P^r C2~*ri*~i-/K\VC
&M.
<fr<K. 1? US V~ 0L$ 9 A^1 5-
ft??> ~PU.Zf~
Arc the respirators provided specific for protection from VC or
?VC? yj?s.
0 d~n+
Explain:
<3 PftCtFt ftJ>
C ft (U>M C^nttmog.
ftft ft >
A- } g ft /**
ftl -J>- Py tf.A-v-$yiS ftr? . 7--
*yo tk o'v\ pgp ,~
- :*
What respirators are utilized by the employees? TaP- 'M3PV&
__6 ___________________
b* Is-there a training program for.employees which includes the
,\ proper wearing of respiratory protection devices? L/
fari--l-- tiflw
p i~oy ?S. AW > ^ 15- X3 ^ 1
`Jaj
How often are the respiratory protection devices 'checked, for
efficiency and effectiveness? ft l ft-if
If applicable, how often are cartridges or cannisters replaced?.
P/rt L-i? /hS A ppx- l CA Ol~&-
/
Other comments: v&-/7? ft> /<? T
//^ C-,fEASI ,
/ ''<'/?&.
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fo rsps* - Af-fW c&^y?. *Tftftft&7V . R_1/hS
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BFG46678
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11. Maintenance and Decontamination Activities a* What procedures are established for maintenance and decontamination
OU'TPZ' '
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A9 y~ &
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p /Hfi CLL-oatf
Are there periodic inspections for-the: Ventilation system7
^
^ - -- FACic-i"^
AS'Are^T
Process equipment? Up R i - '~~J`------------------- 21------------ &/<
Piping and fittings? ^9 a- 7 L~ w 3 v > ^ A
Other?
hi What transpires when leakage occurs? Tfiy TZ> S'TX> P ' A-
\ #
_______
s\., o
~TS t~.
l-f/)L
bFG46679
c. What provisions are there for the protection of employees in
cleanup of leaks or spills; maintenance or repair operations r- '
- on Contaminated systems or-equipment? A'PfKoT^
. r.c.'b'rvcnmC' h^s>- pnh
_________________
What protective clothing and equipment are utilized?
. i
* .Air ^supplied suits?
/(/ V>
^
Gloves?
,
^*
&
O
Respirators? ly
'*
5" ' Others? <r^lT-, Z U
)/ >Af
Stc77.
d. How "axe employees decontaminated after work is completed? ^
- QMfiusi??
err
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11* Maintenance and Decontamination Activities--Continued e* Are maintenance repair cleanup crews available during all shifts?
-ty, (Z. *> ;----------------- -- ,, ____;___;_____ _______
/
26164013
g^G46680
VANCE COPE
.12 Tire Protection
prL--
fWhat provisions are made for fire protection? As P
ih/fiKh
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Who approves the fire protection plan? /N //A hyp^^ VJLO r
h. Who conducts fire inspections?
What is the frequency of the inspections? A/l &7Y
L- _______
`'
: f 4- >*T>U/t.>.
-C* Are there fire insurance engineers? F{/}- T^rv & 9 --Thfl^L j/S
Give, particulars *
-______
**'
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!$ Employer * 'e ^
a, What fr the r;
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sacrXms? .^
ft) fay f C~ ^ (X^Q /*?r+ULA7/y
jftrr^PL- i~6 ft^p: ^JT/ - yfy py^o^An ,'> _ .
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t> "!,^V'i . -u-. ip.u ;; -,. ` -
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How?
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Ace c `i sinuous maples taken? r<j'3
t
___How? (PfkkA A'TVZ^rLy
Tpj T/r^ hy
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. *1 se .s TS a.-; a u:i*idf whev:e are they located? *t # /tvi/^P a-7--
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b* Are p -sanal samples taken? Xf
#^ * HoW? Xte(s\s< f-'-A/P 1 "Tor'how xong? *
V
'
' t Vbat it .lie sampling r.'te-l
i. ` /- Li ? & P
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/** Cc T'g.
What _i; . of activity a*-' the *emp.: - ees In when'monitored? A'aft/W'^
\! What ^erceutagu of employe^. j^xe irov.-tored in each area? 2-P? ^
What i 1 tho frequency' of monitoring? ^/QT~ WfPl f?TA73*-/$H.
What sa. * hod >.a used to analyse -the samples collected in the
,? CtiM- (**<- W0**- ******Cc%%
monlto !.n'i program;
Whht i t .%,'. u s: tlvf'- tl
' Aty } ffW .
WKht i
CC-if *
i# Whit 1 the f{&9t
o* the "results of sample analyses.?
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fitt* -?!>? f." ^Z> &S-T& G*~< 5 H A C^>7\ r
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Bp046682
26161015
advance copy
Employer Monitoring--`Continued
Are the employees Informed?
Axe .the results recorded.? Where are the records kept? LocAl-'--V /A7 0ffL@z-
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Hqw long are records of the results maintained?- T^O 72^ ^>
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Are the results available at all times to thee employees?
BFG46683 26164016
14# Medical Program
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a. What does the in-house medical pregram consist of?
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Are physical examinations of - employees required? if
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Periodical?
What does the physical examination include?
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Is there a medical surveillance program in effect? j&l
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Does the employee have access to his medical records?
Is there a physician and mursejhn duty at all tim^s? //o
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- Hbw many employees are trained in first aid?
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hi. What*satellite-support'medical facilities are readily available? -
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.Is there a contract or working agreement in forc;ee^j^yith^this facility? CpM.TK4-c.-T. t^.lcrVh-. .PA-K^r PrQ
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BFG46684
26164017
15* Emergency
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In the event an emergency should occur for any. reason within the.
operation whereby employees are involved, what plan would be
implemented?
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a* Is there an evacuation plan?
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b* Are there definite emergency procedures' established to include. ^
authorization for individual control of assigned"personnel?-
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c* .Is there a mutual support plan for outside assistance in 'the event . df a catastrophic incident such as fire,' explosion/massive 'spill?
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