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/ AR 286 0848 BIODEGRADATION (BOD/COD) IESTSuBSTANCE Identity: ArefmeirxrteudretocaonstPaiFnOiSng, pFeCr-f9l5u,oroorocatsanaescuolmfponoanteen,twhoficFhC-m6a0y3EaFl.so (b1e- Octanesulfonic acid) (CAS # 2795-39-3). FRCe-m6a0r3kEsF:. CuTrhreen3tMinpfroordmuacttiioonnilnodtincautmebseirt isisanomtixntoutreed.ofT1h.e30te%stPsFaOmSp,le10is% dpireotphaynleesnuelgtloynceolfobuatmyelr,et5he%r,A5lk4y.l1e5th%erwastuelrf,at2e,2.05.%1%etNh-y(l3e-ne glycol, 2.6% tCrhileotrhoaanlollyalm)ihneex,aamnindi0um.0c5hl%ortiodley, t0ri.a9zo%leX.anthan gum, 0.9% starch, 1.0% The following summary applies a mixture with incompletely rcehfalreaccttdeergirzaeddactoinocnenotfrtahteifolnusoorfocimhpeumriictailesc.omDpaotanemnatyonfottheactceusrtastaemlpyle. MEQ. TMyepteh:odA:erMoobdiicfied CBOD test GLP: No Year completed: 1996 CIonnotcaucltumt:imeP:ol2ys8edeady-sNX Lo#t A306, Polybac Corp., Bethelem, PA. peSOYS Chemical Oxygen Demand (COD): Biochemical Oxygen Demand (BOD): 5Day: 10-Day: 20.Day: oS 28-Day: 740,000 mg/kg 216,189 mghkg 110,163 mg/kg (duplicate) 376,258 mg/kg 434255,,697546 mmggl/kkgg (duplicate) 438,632 mg/kg (duplicate) 361071.,960170 mmgg//kkgg (duplicate) Remarks: Testing was conducted on the mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not the fluorochemical proportion alone. conclusions 00 002229 No conclusions given. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 D0 ATAQ0 UAL0 TY 0000000000 Reliability: Kiimisch ranking 3. Study lacks description and records of the method followed. The inoculum was not properly characterized. Sample purity was not properly characterized and the study lacks analytical confirmation of the amountoffluorochemical proportion in the solution. R0 EFER0 ENC0 ES 000000000 `This study was conducted by the 3M Company, Environmental Laboratory, St. Paul, MN, Lab Request number P2581, 1996. oTWeR Last changed: 6/26/00 0000000000 OOO00 002230 SECOND RUN BEST COPY AVAILABLE ' Modified CBOD Test 5,10,20 & 28 Day Analyses P3551 Date_ 1=2!2 Ge Analyst_T\eS Sample Description FC c3CF = Concentration of stock solution__2 1% mo__\_L pH Stock Solution__&-& Polysesd NX Lotn__B\3CL Le dii xeERLE aEc e elRe SaETR nS e eE e st| S CageC R SiSSE E Ra Ea SA e i@a B W gee Ena oEnoCooeendniseu e nae LB h l R Se a IAReGa e S SRERs Lan i eR ot TR RRR RN RC OF Te Saye BEST COPY AVAILABLE Modified CBOD Test LR# Date 1s i : yl ie TE ET [aoJo: T[ H sus| [r2ac[ory | [as[ol T9949[su | |i2>se[55| Pot] aneLee | |pare[05 | [oe [~ 01 i adel pans 3 |s|[ + 994| [ao[soTauy | [ao[s[= T4av| [ar[wo]= Hay| |500 [p|a6sw| [ae[volv= [994 | Soil CasTea] 0[403 | Bri [so 2a] rc [9aq| |01s |@vop[Tera] Sin S0d0eiFeress oe[sEeer [890 Sih lees Tk agin i i TE RS eet SE Caen RUSE SRan Beit ie or Sr 5 ihakd 2 Modified BOD Test 5, 10, 20, & 28 Day Analyses Sample Description BEST COPYAvaILAgy EY Date : Lf [alo marTy |wmnat)[|vamansy ]| man [[oose[Too|l T[aoims To39uq|} [oerrse[uons]| [selo [49+[540] [[esor[[ s[T Tuaaq r|| [[seoo[[as||T To ar s] s| [[oCere[[wwoo]]= [9w0aar | | [[55s3t4[moawg][oown || be tas Teo =[a7] ro [se[20][99g| a |5Tacsarees ]| 17 5 [Ceafaa] [war] i [Loo[ocalo] Io70 azauive]tires Bo iia RUSK i oh Ey " RE ie iri : SES3 Tio PE W Ptraogdiuicetd TCeas0tDingTes Poser FOSOEF 2 CO a Sl E 5 3 @ 5102,8Da2yAn0aly8ses ae . =33 = crov|ou e[5o00nm|[F[p+emam0a0n|| ESO EEERETE ] 2 [coo| men ore | ome|Ema ec] 8&Zz CI CoCsNi I 2 Tae Tous OT J SshE eayl 43 bcs EmmFoesoTssoTT ooryTse] pie. Coho : aa ane w [Craaosb osrao]rsTeRtaEoTo s sr oTHeeae r]of i eel e slee ages f= 5 ER # avIeEasaYlR2saC rrTaeO s{s6A sororT olaol B se suo l nau | cesa[rC[ [Teersazrsossfvsoeslsss TTeieToeesesss nns [[7sslas|e [s7als2oe5TToo[ooe2lsoo4lTerrso oosevroooascdd] [ --vcooss o ecouo d l r ieuad)l srin) : [as[ [sasi u tlazos TTses rfr iases5 rnea sssn estotTs eoa osusse sTooool T --ovei o-- d ees anoes r 2rws00 A. . corerof FT SetosvetsaA assoC e TsIeoCOToaocr oRCAnF) f --CeYti is l salmees5or ;& COS Ra Tha 89Dep PAT 7Co na) 1 XBR ata GSreIs0Treaso aredatae with una2cc0eprtableaynygen concao0 ns: Final D0mursobo80A5mdg atnd COD. Ei 1 oe | EEE MProoddiuicetdTeCsBtOiDngTest wy 510,2&206 Oay Analyses 3 P2581 FC.S00EF Oupicate = Sa oe n k Se Too|[Sommee5e0 0n% |iSa s2 ma | age Co rm emeo]ee on r Loy ed = tGBo,aekSiaon a> CColoaTasseles[soosTtaaoesst]Tssuar t Fae n Te Sg = [[sBeEmTisE[1NTsT7TRsEETTsWA[RaToYrR]Evn:) Fo Tne n Ts rl Era tv e]a y ona Esme an ETEuEl awo| [FarrinasesrrisoTToiTreer[sTssoLal st] i a a o ES= La [ssleoToslee[il oToineCooalSoi : [T[ EzszTss oslEvs EolrNseTEm esTsET|Bs sC5I17Rl s2C5TT|Ma oT2o0R.rA8[o RrsaYoo]]l ||EEaoTnoidM s woat ue l om Tn es #; samen [ [TCaragasszrsf[soeoserss[Trm rsssi1lszl5vsa0eaoTToooootslolserToooiysonool s reoeab r s <aid oorenrol SiSg oTe HE 4 sa[vrsastarseottesesTr Teo sss Tooooe roTolllo et so a 13 gx CE r+[ [ThurrsaG0oasprPiAs TtTeroiae t[l siCsoeelsos oy)Tzie 1oe%oesr15o0sl5su00nlmolts asoisassS1aga 3 x| SGITipyroost rorg nni cronos0n F40G0m3a1t9h8 3h05sToaa CCD 43 BEST COPY AVAILABLE Modified CBOD Test a5,c10b,at2a0, & 28 Day Analyses LRe 0258), P395, PaqsE ADnaatleyssTtaeT0ed3111v-2e1 9s DesScarrioprteion [Mediom Bank DiTsosrottvaed|| DlsFsiaimved emaav)e || Omnavain TT4, | | aa |Bn| [SessEesTmn-- TTv75] [Retswcea Ts 5| [[rfeoxtsCniewoeeLenFPZT T| 61 r537 47 | [PCiraaaagzeeTotano] |saev s | |[1i2 o|a2 e6gs5% e [Tox checxtAr -- T50 Toesavn] Days [MediumBlank Ti [[MSesdecieusmBgloannek 11 12 3]| CAEN poteTen | RIES PN CTI [Rots cea Ts) [[pfoexsGrwecereLao pasT ar is 17]| [ToxCheck LAWpze5p| 18 | (fox Creextms------T 20] [o sr aTThaarese[rReess || |osTTianSawcs]| sewTT= = Day 10. a i s > [SeededBlank Daye [MediumBlank [Medium Blank [SeededBlane [SeededBiank 123} 25 MN 126} 157] 26} [MediumBlank F3 E[[SMeefondamiduemaBmlaannek [SeededBian 125} 35,0 T57 } : :Sz SIEer BfR ica A |wos pase av} 5 i wks ise . Bl:[Erie Tes | | voc Tiar Sea s |Gao Taz9e 1s | 4 siai [|s2a1sd"T[mio2a00vve[ier=seoos| ARNEPEeRhe a sic 17aveg Tes| nhyi mo AEE dR AgeTer Ba IEE CM EEa S aESd A BEST COPY AVAILABLE ModinfieandeCeBODosTeGsotp Anspeen E2a we fasl ced Amat 25 > rier Fim owe| wintiwar. aatmetaiterosnnd||| d"iotesmvaootusvn.d||| imm"Fatirintaaylr.||| seF`wimsanrcaor PST KA) [i igoni ) [Medium Blank | [TTee e e ow] | 2 ear | eis| 034| | aTear 722 | ros | 41 eas |747 | 09s | [12s] |_o008| I I I meanscka 112| [Retswcea TT 206 | 15 | sas | sea | 261 | 149 J (Rol. Std. GGA [7326176| sar| 572 | 275 | 163| [Tox_Check LAP2S8T[ 51000| 17 | 647 | 017 | 630 | 7.18 | [1x00Cr0a0seo avsl 1000ToorToss7a 30] [ToxCheckLAsPoose 1000|10| 844 | 013 | sar | 710 [MediumBank] [MediumBian} 2000 ac [SeededBank | Lmsnsore vee] [20T sac 1 813 | 033 | 21 sar | 612 |o3s J | 22| sar | 66s | 1.2| | 231 sas | ese |19 J a scr] [eo] [MegiomBlank] [MediumBlank} Cor Teoh 135) [2T sac | sos [| oss | | 2s| ear| e0e | oar| 7 |sce]. To Got cn st Bt sr vn hi 18m ti cin 0 IR 20 oy aC [MediumBlank] [MediumBlane | [SeededBlank | (So Cont Facto bo _ [meanSCF= 224 | [26Teac 1781 | oes | |20| ear| 78 |oes | f=s0| sar | 530 | 3.7 | 3 |sce] La ETE NY ET osi me SCF a 3:2n 4 | 2% esd Cartcton Facor (9m SeBaandkDeOOdop i fA Z ynso tin(eS58aBar l RnyoBrEen prs 5 CL EAR ;i fo Fong Ri ii ASRl EsRL BC oes BA R i Beiioghn R AREA orE R hlLoa LEE tSn d SH CL EERIE BERR