Document V3RdE5oywqqx988v1onnJ9Dno

UNIROYAL Material Safety Data Sheet ( v iP CHEMICAL II Uniroyal Chemical Company, Inc. UNIROYAL Emergency Phone: (203) 723-3670 World Headquarters CHEMTREC Transportation Emergency Phone: 1-800-424-9300 Middlebury, CT 06749 SAFETY DATA Information (203) 573-3303 MSDS No__ 0266001__ Date Issued:------- --------------- Date Revised 8/25/87 R-1 IDENTIFICATION -------------------------------------------------------- Trade Name: NAUGARD 445 CAS Number: 10081-67-1 Chemical Name: 4,4'Di(a,cr - dimethylbenzyl) diphenylamine Chemical Family: Aromatic Amine SPECIAL REGULATORY HAZARDS Ingredient CAS No. Exposure Limit Product 10081-67-1 ND ---------------------------- OSHA (1910.1200) EEC* Not hazardous Not hazardous Hazard assessment based on available data. Transportation: NA PHYSICAL DATA ----------- Appearance and Odor- White to off-white powder; characteristic odor Solubility: Insoluble in water Soluble in most organic compounds Melting Point: 203oF(95C) Boiling Point: Other Data: NA Specific Gravity (H2O = 1): Vapor Pressure @ 20 C. Vapor Density (Air = 1): ^D Volatility @70 F: Low FIRE AND EXPLOSION HAZARD DATA -------------------- FlashPoint: 531 F (276.7C) TCC Autoignition Temp: 569 F (298C) Fire point Extinguishing Media: Water spray, dry chemical Flammable Limits: Special Fire Fighting Procedures: Protect aSainst inhalation of combustion products. Unusual Hazards MaY1orm exPlsive dust-air mixtures. REACTIVITY DATA ------------------------------------------------------ Stability: Stable at ambient temperatures and pressures. Incompatibility: Strong oxidizing agents. Decomposition Products: 0xides of carbon and nitrogen under burning conditions. CONFIDFNtJ NA = Not Applicable ND = Not Determined `European Economic Community Uniroyal makes no representation or warranty with respect to the information in this Material Safety Data Sheet, the information is however, as of this date provided, true and accurate to the best of Uniroyal's knowledge. This list of information is not intended to be all Inclusive. Actual conditions of use and handling may require considerations of information other than, or in addition to, that which is provided herein. SPECIAL PROTECTION INFORMATION ----------------------- Engineering Controls: Sufficient ventilation to minimize dust exposure. Protect closed handling systems against possible dust explosions. Avoid dust accumulation on building or equipment surfaces. Personal Protection Equipment: Avoid all personal contact. Observe good personal hygiene. Impervious gloves and goggles should be worn when handling. In the absence of adequate ventilation, use NIOSHcertified dust cartridge respirator. STORAGE, SPILLS AND DISPOSAL INFORMATION -- Storage. Store away from sources of direct heat in a dry area. Keep containers closed when not in use. Spills: Sweep or vacuum up. Shovel into secure containers for proper disposal. Avoid creating dust. Use personal protective equipment as outlined above. Disposal: In accordance with any applicable local, state, or federal regulation regarding organic waste. Environmental Information' Environmental effects have not been determined. HEALTH RELATED DATA ------------------------------------------- Specific Hazard(s): No acute or chronic health hazards have been identified. There are no known medical conditions aggravated by exposure to this material. Primary Route(s) of Entry: Inhalation, skin absorption. First Aid Procedures: Eye contact: Flush with water for 15 minutes. Skin contact: Wash thoroughly with soap and water Inhalation: Remove to fresh air. Toxicology Information: ra* toxicity: LD50 (rats) - > 10 g/kg Irritation: eye (rabbits) - negative skin (rabbits) - negative Mutagenicity: Ames Salmonella - negative No significant adverse effects have been noted with long-term production and use of this material. Carcinogenic per NTP_______ IARC Y - OSHA---------- None -- NAUSRRDW 445----------------------------------------------------------------------------- DO 0B63&2 OONFIOENTTAL * }, ft*- T VANDERBILT COMPANY , INC* Industria L MineraIs and ChemicaLs ,30 Winfield Street Norwalk* CT 06855 <203) 853-1400 TWX 710~468~2940 Cusflaer:_.I:nai **** MATERIAL * * SAFETY * DATA SHEET * #* Page 1 of 4 Date: 06/17/87 Revised! 06/25/86 Supersedes! 11/28/81 I. PRODUCT IDENTIFICATION P14503 | Trade Name! DISPERSED SULFUR Chemica L Name! Su If ur dispersio n i i Synonyms! N/A I Hazardous Ingredients/OSHA! N/A | Hazard! N/A Carcinogenic I ngred i ents/OSHA/NTP/T.ARC 1 N/A II* WARNING STATEMENTS None i III* PHYSICAL AND CHEMICAL DATA j , Appearance and Odor! YelLow aqueous dispersion Density, at 25 deg C, Mg/cu mi 1*51 Solubility in Water! N/A 86363 CONFTDFNTTAI j <# - Registered in US* Patent and Trademark Office) I----------------------------------------------------------------------------------------------------------------------------------------------------- j Inform,ation presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief j but '5 not guaranteed to be so Nothing herein is to be construed as recommending any practice Or any product in violation of any patent or in violation of any law I O' regulation. It is the user's responsibility to determine for himself the suitability of any material for a specific purpose and to adopt such safety precautions as i ma, be necessary. We make no warranty as to the results to be obtained in using any material and. since conditions of use are not under our control we must necessarily disclaim all liability with respect to the use Of any material supplied by us. MSDS! DISPERSED SULFUR Page 2 of 4 IV, FIRE! PROTECTION FLash Point <deg C/deg F) N/A - Product is an aiueous solution* Extinguishing Media! On solids* water Special Firefighting Procedure! SeLf-contained breathing apparatus Unusual Fire Hazard! None known V. REACTIVITY DATA Thermal Stability! Stable Materials to Avoid! Strong oxidizers Hazardous Polymerization! Will not occur Hazardous Decomposition Products! May form suLfur dioxide and hydrogen sulfide when heated VI. HEALTH HAZARD DATA Exposure Limits! None established Effects of Overexposure! Not known DO 086364 CONFIDENTIAL Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief b"t is not guaranteed to be so Nothing herein is to be construed as recommending any practice or any product in violation of any patent or in violation of any law or regulation It is the user's responsibility to determine for himself the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary We make no warranty as to the results to be obtained in using any material and. since conditions of use are not under our control, we must necessary disclaim all liability with respect to the use of any material supplied by us rtsns: dispersed sulfur VII. PHYSIOLOGICAL EFFECTS SUMMARY Not available for product Pag-3 of 4 i i VIII. PRECAUTIONS FOR SAFE HANDLING Keep from freezing DO 086365 CONFIDENTIAL Information presented nerem has been compiled from sources considered to be dependable and is accurate and reliable to the best of our knowledge and belief but is not guaranteed to be so Nothing herein is to be construed as recommending any practice or any product in violation of any patent or in violation of any law 0' regulation It is the user's responsibility to determine for himself the suitability of any material for a specific purpose and to adopt such safety precautions as may be necessary We make no warranty as to the results to be obtained in using any material and. since conditions of use are not under our control, we must necessarily disclaim ail liability with respect to the use of any material supplied by us, ftSDS J DISPERSED SULFUR Page 4 of 4 IX PROTECTION AND CONTROL MEASURES l --------------------------------------------------------------------------------------------- Protective Equipment! Goggl.es, rubber gloves Respiratory Protection* N/A Ventilation, Effective ventilation to draw fumes and vapors away from workers to prevent routine inhaLation X. EMERGENCY AND FIRST AID PROCEDURES Eye Contactl Flush eyes with water for at least 15 minutes Skin Contact! Wash affected area with soap and water InhaLation! Remove to fresh air. Keep warm and iuiet, Ingestion! Seek medica l attention immedia teLy XI, SPILL AND DISPOSAL PROCEDURES Spill or Leakage Procedure! Absorb on inert material. Transfer to a closed container for disposaL* Waste DisposaL! Not an RCRA waste. As for organic chemicals according to applicable government regulations. For Additional. Information Contact! Environmental Affairs R, T, VANDERBILT CO,, INC. 30 WinfieLd Street P,0. Box 5150 Norwalk, CT 06856 Tel, No,! <203) 853-1400 00 086366 --------------------------------------------------------------------------------------------------------------------------------CONFIDENTIAL. ______ Information presented herein has been compiled from sources considered to be dependable and is accurate and reliable to the best of Our knowledge and belief but is not guaranteed to be so. Nothing herein is to be construed as recommending any practice or any product in violation of any patent or in violation of any law or regulation it is the user's responsibility to determine for himself the suitability of any material for a specific purpcse and to adopt Such safety precautions a$ may be necessary We make no warranty as to the results to be obtained in using any material and, since conditions of use are not under our control, we must necessaniy disclaim all liability with respect to the use of any material supplied by us UNIROYAL CHEMICAL ' 'U>1 Material Safety Data Sheet Uniroyal Chemical Company, Inc. UNIROYAL Emergency Phone: (203) 723-3670 World Headquarters CHEMTREC Transportation Emergency Phone: 1-800-424-9300 Middlebury, CT 06749 SAFETY DATA Information (203) 573-3303 MSDS No___ 0269004 IDENTIFICATION --------- Trade Name: NAUGARD BHT Date Issued:_____9/12/85 Date Revised: 5/22/89 CAS Number: 128-37-0 R-1 Chemical Name: 2,6-di-tert-butyl-p-cresol Chemical Family: Cresol SPECIAL REGULATORY HAZARDS Ingredient CAS No. Exposure Limit Product 128-37-0 10 mg/m3 (OSHA, ACGIH) OSHA (1910.1200) Not hazardous EEC* Not hazardous Hazard assessment based on available data. Transportation: NA PHYSICAL DATA Appearance and Odor: White crystal; characteristic (cresylic) odor Solubility: Solubility in water: 0.4 mg/liter Specific Gravity (H20 - 1): 105 So1^ Ko ^rbn S0'VentS Melting Point: 156 F (69.4 C) Boiling Point: 509F(265C) Other Data: NA Vapor Pressure @ 20 C. 0.01 mm Hg Vapor Density (Air = 1): 7- Volatility @70 F: Low FIRE AND EXPLOSION HAZARD DATA --------------------- Flash Point: 261F (130C) CC Autoignition Temp: 878F (470C) dust cloud Extinguishing Media: Water spray, dry chemical Flammable Limits: -2 oz./ft3 Special Fire Fighting Procedures: Protect against inhalation of combustion products. Unusual Hazards: Mayform explosive dust-air mixtures. REACTIVITY DATA -------------------------- Stability: Stable at ambient temperatures and pressures. Incompatibility: Strong oxidizing agents. Decomposition Products: Oxides of carbon under burning conditions. DO Co l\lpr 0s636? XNTT6L NA = Not Applicable ND = Not Determined `European Economic Community Uniroyal makes no representation or warranty with respect to the information in this Material Safety Data Sheet. The information is however, as of this date provided, true and accurate to the best of Uniroyal s knowledge. This list of information is not intended to be all inclusive. Actual conditions of use and handling may require considerations of information other than, or in addition to, that which is provided herein. SPECIAL PROTECTION INFORMATION ------------------------ Engineering Controls: Sufficient ventilation to minimize dust and/or vapor exposure. Protect closed dust handling systems against possible dust explosions. Avoid dust accumulation on building or equipment surfaces. Personal Protection Equipment: Avoid all personal contact. Observe good personal hygiene. Impervious gloves and goggles should be worn when handling. In the absence of adequate ventilation, use NIOSHcertified respiratory protection for dust and/or organic vapors. STORAGE, SPILLS AND DISPOSAL INFORMATION -------- Storage: Store away from sources of direct heat and moisture. Keep containers closed when not in use. Spills: Sweep or vacuum up. Shovel into secure containers for proper disposal. Avoid creating dust. Use personal protective equipment as outlined above. Disposal: ln accordance with any applicable local, state, or federal regulation regarding organic waste. Environmental Information: Environmental effects have not been determined. HEALTH RELATED DATA --------------------------------------------- Specific Hazard(s): Contact with eyes or skin may cause irritation. Repeated minimal contact with skin may cause sensitization. Primary Route(s) of Entry: specific route. First Aid Procedures: Eye contact: Flush with water for 15 minutes. Get medical attention. Skin contact: Wash thoroughly with soap and water Inhalation: Remove to fresh air. Toxicology Information: *oxlcl*y: 1*^50 (rats) - >2 g/kg Irritation: eye (rabbits) - slight skin (rabbits) - slight Sensitization: skin - slightly positive based on human experience Mutagenicity: Ames Salmonella - negative Chronic: The feeding to rats and mice of 3000 or 6000 ppm for two years did not produce an increased tumor incidence. Teratogenicity: The feeding to pregnant mice of up to 800 mg/kg/day from day 6*13 of gestation did not produce teratogenicity. Carcinogenic per NTP ______ IARC _______ OSHA---------- None NAUGARD BHT DO 0S>3F>8 CONFTCENTTAt MATERIAL SAFETY DATA SHEET ? " HSACULSS (Approved by ll.S. Depertment of Labor at "Esaentlelly Similar" to Form 0SHA-20) \ PAGE 1 of 3 1. PRODUCT IDENTIFICATION CHEMICAL NAME AND SYNONYMS CHEMICAL FAMILY FORMULA TRADE NAME AND SYNONYMS Dlcumvl peroxide supported, on precipitated calcium carbonate Organic peroxide KA di-cup<*>4oc REGULAR TELEPHONE NO. 302-576-5000 EMERGENCY TELEPHONE NO. 302-995-3000* CAS NO. 80-43-3 and 471-34-1 MOLECULAR WEIGHT -- II. HAZARDOUS INGREDIENTS MATERIAL TLV-TWA VALUES ADOPTED BY ACGIH 1981 Dicumyl peroxide 40 Not established I. PHYSICAL DATA BOILING POINT, 760 mm Hg NA - Decomposes PREE2ING POINT NA VAPOR PRESSURE Not determined BULK DENSITY 418 kg/m3 (26 lb/ft^) VAPOR DENSITY (AIR-1) NA SOLUBILITY IN WATER. % BY WEIGHT Negligible APPEARANCE ANO ODOR: Free-flowing, offwhite oowder: acrid. frultv odor. PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE (BUTYL ACETATE-1) pH Negligible at 20*C(68#F) <1 NA IV. FIRE AND EXPLOSION HAZARD DATA FLASH POINT 120C (225F) SETA-CC (TEST METHOD) AUTOIGNITION Not determined TEMPERATURE FLAMMABLE LIMITS IN AIR PERCENT BY VOLUME LOWER Not determined UPPER Not determined EXTINGUISHING MEDIA: Water spray, dry chemical, foam, or carbon dioxide. SPECIAL FIRE-FIGHTING PROCEDURES: None UNUSUAL FIRE AND EXPLOSION HAZAROS: Flammable dust when finely divided and suspended In air. See SECTION VI - REACTIVITY DATA. NOTES: This product In flberboard containers of up to 100 lbs. each maximum can be considered as a Class V Peroxide in accordance with Factory Mutual Loss Prevention Data Sheets 7-80. Class V Peroxides present a low or negligible fire hazard. With these peroxides combustible packing materials may present a greater hazard than the peroxide itself. NA - NOT APPLICABLE no 08333^ rnNFTOENT' T Al- CONI* *UM thl. margmcy number only after normal bualnaaa hour* end only for emergencies Involving ufery and health. W cannot antidpatg all conditions under which this information and our products, or tha products of other manufacturers in combina tion with our products,' may ba used. Wa accept no responsibility for results obtained by tha application of this information or the safety and suitability of our products, either alone or in combination with other products. Users are advised to make their own tests to determine the safety and suitability of each such product or produet combination for their own purposes. Unless otherwise agreed In writing, we sell the products without warranty, and buyers and users assume all responsibility and liability for lose or damage arising from the hendling and use of our products, whether used alone or in combinetlon with other products. HERCULES INCORPORATED WILMINGTON, DELAWARE 19899 Mta 14440 Riv 9.79 Itt PftIMTtO IN U.8.4 MSDS OR 616A DATE 3/29/83 V. HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: Not established. See Section II. PAQG 2 of 3 EFFECTS OR OVEREXPOSURE: Mild eye, skin, and respiratory irritation. Decomposition products "* fumes from vulcanization and crosslinking operations may cause eye. skin, and respiratory irritation and be skin sensitizers. See Hercules Bulletin ORC-204 for summary of toxlocologlcal investigations. EMERGENCY AND FIRST AID PROCEDURES: EYES: In case of contact. Immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. SKIN: Wash thoroughly with soap and running water. Nash clothing before reuse. INHALATION: Remove to fresh air and, if indicated, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. Treat symptomatl--lly. STABILITY UNSTABLE STABLE VI. REACTIVITY DATA CONDITIONS TO AVOID: Stable at room temperatures. Avoid temperatures above 55C (131F) or contact with materials listed below. X Higher temperatures or contact with listed materials promote exothermic decomposition. INCOMPATIBILITY (MATERIALS TO AVOID): Adda and acidic-type materials such as FriedelCrafts catalysts, strong oxidizing and reducing agents, and oxidation catalysts. Copper, copper alloys, lead and iron. HAZARDOUS DECOMPOSITION PRODUCTS: Acetephehone, ciunyl alcohol, a-methyl styrene, methane, and ethane. Under acidic decomposition conditions, phenols may also be formed. Combustion products include CO, CO2, and generation of smoke. HAZARDOUS MAY OCCUR CONDITIONS TO AVOID: POLYMERIZATION WILL NOT OCCUR l VII. SPILL OR LEAK PROCEDURES None STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: If material is not contaminated, scoop into clean containers for use. If contaminated, scoop into clean containers for disposal. WASTE DISPOSAL METHOO: Dispose of in accordance with local, state, and Federal regulations. VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION Nuisance dust respirator approved by NIOSH/MSHA if airborne (SPECIFYTYPE) dust is not adequately controlled. Use self-contained breathing apparatus in excessive fumes from product decomposition. VENTILATION LOCAL EXHAUST -- MECHANICAL (GENERAL) PROTECTIVE GLOVES: Chemical resistant OTHER PROTECTIVE EQUIPMENT: -- SPECIAL OTHER Use adequate ventilation EYE PRO!rECTION: Safety glasses DO 086370 CONFIDENTIAL MSDS OR 616A DATE 3/29/83 V. HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: Not established. See Section IZ. PAGE 2 of 3 EFFECTS OF OVEREXPOSURE: Mild eye, skin, and respiratory irritation. Decomposition products fumes from vulcanization and crosslinking operations may cause eye. skin, and respiratory irritation and be skin sensitizers. See Hercules Bulletin ORC-204 for summary of toxlocological investigations. EMERGENCY AND FIRST AID PROCEDURES: EYES: In case of contact. Immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. SKIN: Wash thoroughly with soap and running water. Wash clothing before reuse. INHALATION: Remove to fresh air and, if Indicated, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. Treat symptomatic -liy. STABILITY UNSTABLE STABLE VI. REACTIVITY DATA CONDITIONS TO AVOID: Stable at room temperatures. Avoid temperatures above 55C (131"F) or contact with materials listed below. X Higher temperatures or contact with listed materials promote exothermic decomposition. incompatibility (MATERIALS TO AVOID): Acids and acidic-type materials such as FrledelCrafts catalysts, strong oxidizing and reducing agents, and oxidation catalysts. Copper, copper alloys, lead and iron. HAZARDOUS DECOMPOSITION PRODUCTS: Acetephehone, cumyl alcohol, a-methyl styrene, methane, and ethane. Under acidic decomposition conditions, phenols may also be formed. Combustion products include CO, C02, and generation of smoke. HAZARDOUS MAY OCCUR POLYMERIZATION WILL NOT OCCUR CONDITIONS TO AVOID: VII. SPILL OR LEAK PROCEDURES None STEPS TO BE taken IF MATERIAL IS RELEASED OR SPILLED: If material is not contaminated, scoop into clean containers for use. If contaminated, scoop into dean containers for disposal. WASTE DISPOSAL METHOO: Dispose of in accordance with local, state, and Federal regulations. VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION Nuisance dust respirator approved by NIOSH/MSHA if airborne (SPECIFYTYPE) dust is not adequately controlled. Use self-contained breathing apparatus in excessive fumes from product decomposition. VENTILATION LOCAL EXHAUST -- MECHANICAL (GENERAL) PROTECTIVE GLOVES: Chemical resistant OTHER PROTECTIVE EQUIPMENT: SPECIAL -- OTHER Use adequate ventilation EYE PRO!rEdTlON: Safety glasses DO 086371 CONFIDENTIAL ( rRADE NAME DI-CUF 40C MATERIAL SAFETY DATA SHEET MSDS OR 616A DATE 3/29/83 PAGE 3 of 3 IX SPECIAL PRECAUTIONS PRECAUTIONARY LABELING danger: HEAT OR CONTAMINATION MAT CAUSE HAZARDOUS DECOMPOSITION. PRODUCT MAY CAUSE EYE, SKIN, AND RESPIRATORY IRRITATION. DECOMPOSITION PRODUCTS MAY CAUSE EYE, SKIN AND RESPIRATORY IRRITATION AND MAY BE SKIN SENSITIZERS. * FLAMMABLE DUST WHEN FINELY DIVIDED AND SUSPENDED IN AIR. Do not heat above 55C ( 131F) or permit contact with acids and addle-type materials such as Friedel-Crafts catalysts, strong oxidizing and reducing agents, or oxidation catalysts. Higher temperatures or contact with these materials . promote exothermic decomposition. Avoid contact with copper, copper alloy, lead, and Iron as contact with these metals accelerates decomposition. Avoid contact with eyes, skin, and clothing. Avoid breathing dust or vapors of decomposition products Use with adequate ventilation. Wash thoroughly with soap and water after handling. Keep away from heat, sparks, and open flame. Clean spills promptly. FIRST AID; EYES - In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. SKIN - Wash thoroughly with soap and running water. Wash clothing before reuse. INHALATION - Remove to fresh air and, if Indicated, give artificial respiration, preferably mouth-to-mouth. If breathing is difficult, give oxygen. Call a physician. Treat symptomatically. STORAGE: Store below 35*C (95F) In original containers In a ventilated area out of direct sunlight and away from heat sources. Storage at higher tempera tures risks melting of the Dl-Cup and the formation of lumps and cakes. SPILLS: If material is not contaminated, scoop into clean containers for use. If contaminated, scoop Into clean containers for disposal. Disposal must be in accordance with local, state, and Federal regulations. DO 08637? CONFIDENTIAL