Document V32yLYNLZ4x996ZVDJyNKQNwg

) Dow Number 1766772* 17667731766784* 17668241766825* 17669441766948* 17682471768249* 17701871770195* Date 000000 340905 000000 000000 650317 661104 Author Dow Prescott, RF Dow Dow REA W1d1ger, A Johnson, RL Dugan, GF Recipient H* 1770705^ 1770709* O cry 700525 Brady, P Distributees Widlger, A Johnson, RL Dugan, GF Coulter, KE Thurston, D Haberstroh, WH Sauers, RC Wolf, RR Poffenberger, N Goergen, GG Bender, S Louck, A Bailey, CZ Putnam, MS Nielson, WH StaehUng, EC Schmldtke, DJ Haberstroh, WH Page 103 General Subject Matter TCP Process Flow Sheet Manufacture of 245 Trlchlorophenol from 1245 Trlchlorobenzol Diehlorophenol and trlchlorophenol proccess flow sheet 245 Trlchlorphenol operations 804 Building Trlchlorophenol Reactor Cycle Phenol 245 - Trlchloro study of chloracne problem preparation of 245-Tr1chl orophenol from Trichlorobenzene, PL 2064-13 Manufacture of Phenoxy Herbicides )I )I ) Dow Number Date Author Recipient / O an -i )I ; Distributees Williams, L Vogelsang, P Chase, FI Kens1ck1, RF General Subject Matter Page 104 \ V >) ) ) Dow Number 00883470088348* Date 701217 00883490088350* 00886490088650* 701217 590122 0088651 * 00889110088913* 590500 660506 00889140088916* 00889300088962* 00889690088972* 771001 661209 670316 0088973^ 0089003* O cGnO 690515 Author Recipient Dow Hoyle, HR Norris, JM Dow Norris, JM Dow Hoyle, HR McColllster, DD Wolf, MA Dow Dow Hoyle, HR McColllster, DD Olson, KJ Dow Dow Dow Hoyle, HR Olson, KJ Oyen, F Buerge, TE Dow ] D1strlbutees Page 1 General Subject Matter M-3592 (Data sheet of properties, health hazards, and precautions for safe handling of materials) M-32592 (Medical Information) Forron Brush Killer (Data sheet of properties health hazards and pre cautions for safe handling of materials) Forron Brush Killer M-1368, Safety data sheet M-2993 (Data sheet of properties, health hazards, and precautions for safe handling of materials) Tordon 155 Mixture Brush Killer (Material safety data sheet) 2M0-3083-1 (Request for screening or application testing) Tordon 105 Mixture (Data sheet of properties, health hazards, and precautions for safe handling of materials) * Toxicological properties and Industrial handling hazards of > Dow Number Date 00911730091176* 670316 Author Norris, JM Torkelson Buerge, TE Dow Lynn, 6E Olson, K Oyen, F Recipient 00911770091178* 670227 Dow Hoyle, HR Olson, KJ Oyen, F O tn CD - ' 1; Distributees Boundy, RH Dean, P Dow Elshere, D Holder, BB Jones, GD Kagy, JF Kill an, DJ Luce, EN Lynn, GE McIntyre, HH Moss, RD Sheetz, DP Shrader, SA Wilson, AW Wright, N Boundy, RH Dean, P Dow Elshere, D Holder, BB Jones, GD Kagy, JF K1l1an, DJ Luce, EN Lynn, GE McIntyre, HH Moss, RD Sheetz, DP Page 2 General Subject Matter Tordon 225 Mixture herbicide (M-3199X) Toxicological properties and Industrial handling hazards of Tordon 105 Mixture (T2.M031-3132-1) (CRI 123032) i Tordon 105 Mixture data sheet of properties, health hazards, and precautions for safe handling of materials (T2.MO-3132-1) V > )) ) Dow Number Date Author Recipient 02010200201021* 670213 Fletcher, DE Barnes, EB 0201023 * 0201024 * 0201025 * 0201026 * 0201027 * 0201031 * 0201032 * 0201034t-P* 0201035* O CD O 660428 660800 660425 660523 660422 660422 660421 660425 Carlson, R StaehUng, EC BJC 3 Illegible Dow Kennett, W Bosscher, H Anderson, RE Coppage, JS Carlson, RG Key, M Bosscher, H Beck, RH REA Ford, FE Coppage, J Distributees Shrader, SA Wilson, AW Wright, N Bosscher, H Staehling, EC Goergen, GG Dixon, WR Henske, JM Gill Streeter, LE General Subject Matter Page 3 New Tetrachlorobenzene facility Cost of Tetrachlorobenzene expansion Tetrachlorobenzene cost capacity Tetrachlorobenzene economic summary Tetrachlorobenzene expansion Tetrachlorobenzene project scope summary Beginning Tetrachlorobenzene expansion Manpower request Tetrachlorobenzene expansion cost estimate ) Dow Number 0201038- 0201039 0201040 * Date 660315 670529 0201041 * 670529 0201042 * 0201043 * 0201044 * 0201045 * .670700 670622 670608 670608 Author Anderson, RE Comer, WL Recipient Carlson, R StaehUng, EC Bosscher, H EBB CBB BJC Carlson, R Staellng, EC BJC Dow Woodward, EE Bosscher, H Nummy, WR Barnes, EB Barnes, EB 0201046201048* tP o CD 0201049201050* |)0^ 670526 670531 Anderson, RE Baltusls, M Carlson, RG Bosscher, ) Distributees Page 4 General Subject Matter Tetrachlorobenzene plot plan Capital authorization for Tetra chlorobenzene expansion Bosscher, H Staehllng, EC Carlson, RG Dixon, WR Expense, authorization for Tetrachlorobenzene expansion Tetrachlorobenzene expansion Economic summary for Tetra chlorobenzene expansion Tetrachlorobenzene expansion Tetrachlorobenzene expansion Tetrachlorobenzene project scope summary Tectrachlorobenzene expansion Dow Number 0201051- 201052* 0201053 * 0201054 * 0201055201056* 02010570201058 0201080 * Date 670531 660421 670526 670526 660315 670000 Author Tacey, WJ Recipient Carlson, RG Beck, RH Coppage, J Brauer, AR Wappenhensch, 0 Brauer, AR Wappenhensch, 0 Anderson, RE Anderson, RE Comer, WL Dow 0201081 * 0201082 * 0201083 * 670418 670501 670412 StaehUng, EC Goergen, GG Bosscher, H B J .C Bosscher, H Barnes, EB Lueck, AF Bosscher, H 0201084 CD tO 670320 Wehn, WE O.A.W. ) Distributees Streeter, LE StaehUng, EC Putnam, MS Goergen, GG StaehUng, EC Putnam, MS Page 5 General Subject Matter Tetrachlorobenzene capacity Manpower request Tetrachlorobenzene expansion cost estimate Tetrachlorobenzene expansion expense estimate Tetrachlorobenzene plot plan 245-Tr1chlorophenol (Board of D1r. agenda) (authorization request M-32063A) 245-Tr1chlorophenol 804-7 Bldgs, production facilities 245-Tr1chlorophenol plant return : of funds (authorization M-32063A)? 245-Tr1chlorophenol plant 245-Tr1chlorophenol plant 804-7 Bldg, cost estimate )) I ) Dow Number Date Author Jacobs, CE 0201085 * 670320 Wehn, WE Jacobs, CE O.A.W. 0201086 * 000000 Dow Recipient 0201087 650000 W.C.T. 0201088 * 02010890201090* 0201091 * ri* O' m 651006 651021 651020 Hutchenreuther, C Goergen, GG Bosscher, H M.K. B.J.C. Bosscher, H Timm, WC Dixon, WR Key, M f ) Distributees Goergen, GG Bosscher, H Leuck, AF Staehllng, EC Lueck, AF Putnam, MS Goergen, GG Bosscher, H Staehllng, EC Lueck, AF Bosscher, H Putnam, MS Goergen, GG General Subject Matter Page 6 245-Trichlorophenol plant 804-7 Bldg, cost estimate - changes and alterations 245-Tr1chlorophenol authorized spent, differences capital New 245-Trichlorophenol (Dow Bd. of D1r. authorization request M-32063) 245-Trichlorophenol additional funds Bosscher, H Henske, JM PI etcher , DE Review of Trichlorophenol job v Position on the Midland division Trichlorophenol plant ) ) Dow Number 0201092 * 0201093 * 02010940201097* 0201098 * 02010990201101* 02011020201104* Date 651011 651027 651027 650707 651021 650927 0201105 * 02011060201107* 651007 651004 0201108 * 651001 Author Bosscher, H Recipient Key, M Goergen, G Wehn, WE Goergen, G Bosscher, H Branch, CB Delisle, NG Wappenhensch, OA Stuart, GA Goergen, GG Goergen, GG Bosscher, H Vanarsdale, JD T1mm, W Dlmmlck, D Doedens, J Hutchenreuther StaehUng, E G111, W Perry, R Goergen, G Lundqulst, J Saphler, L Vanarsdale, JD Goergen, GG 14064 DI strlbutees Key, M Page 7 General Subject Matter New 245-Tr1chlorophenol plant M-32063 245 Trlchlorophenol plant 660000 Trlchlorophenol plant cost reduction New Trlchlorophenol plant Trlchlorophenol authorization New 245-Tr1chlorophenol plant project scope summary (job 50175) 245-Tr1chlorophenol 245-Tr1chlorophenol expansion Delisle, NG Domlck, D Trlchlorophenol requirements  Dow Number 0201109 * 02011100201111* Date 650929 651012 Author Taylor, N Recipient Del Isle, NG Churchman, JW Bosscher, H 0201112 * 02011130201114* 0201115 * 0201116 * 0201117 * 0201118 * 02783850278390* 02783900278392* o (Sh. 651018 651000 000000 650526 650608 650622 540106 531230 Churchman, JW Wehn, WE Wappenhensch, 0 H.A.S. Churchman, JW Bosscher, H Branch, CB Henske, JM Doedens, JD Dow Wolf, MA Branch, CB J Distributees Hutchenreuther, C Timm, WC Goergen, GG Mitchel, JE Moore, HJ Page 8 General Subject Matter Manning of new Trichlorophenol plant Overrun 245-Trichl orophenol new facility 245-Trichl orophenol new facility (economic summary 39458-65) 245-Trichlorophenol (cost estimate) 245-Trichlorophenol new facility (Dow Bd. of Dir. agenda) 245-Trichlorophenol new facility economic summary 245-Trichlorophenol new facill ties 245-Trichlorophenol new facilities M-213 (Acute oral toxicity) M-213 (Acute oral toxicity) ) ) Dow Number 02783930278395* 02783960278404* 05012850501288* 05012890501291* 0501292 * 0501356501360* 0501415 * Date 540106 540106 701111 701110 700615 651105 660105 0501418 * 660105 0501659 * 05016600501668* 0502357502358* 691015 700629 650618 ^0^ 0502631 * O CD n 660630 Author Recipient Hoerger, FD USDA ARS Hoerger, FD USDA ARS Gladstone, MM Dow Hoerger, FD Dow Dow Turner, WF Parsey, ES Van Horn, RL Sachs, SD Downard, GM Dow ) Distributees Rutherford, RE Sunderland, WW Hammer, OH General Subject Matter M-213 Page 9 M-213 (Skin irritation) Brush Killer LV2-2 Brush killer LV2-2 Product registration Brush killer LV 2-2 composition statement Brush killer X confidential state ment of formula Brush killer X confidential statement of formula Registration of economic poisons Butyl 400 evaluation DMA-6 confidential Ingredient statement Esteron brush killer OS complete Ingredient statement Dow Number 0502740 * Date 690108 Author Dow Recipient 0503722 * 670111 Dow 0503890 * 0503923 * 0504055 * 630910 000000 660721 Dow Dow Dow 0504056 * 667021 Dow 0504060 --1 640422 White, LC, Jr. Delong, HC H1ghh1ll, CA Hudberg, RN Loucks, MF Ouellette, FE Korsmeler., KB ) ) Distributees Alford, HG McColHster, DD Davidson, JH McCoy, WJ Sunderkland, WW Talcott, AT Hammer, OH Downard, GM Sachs, SB Hammer, OH Sunderland, WW Downard, GM Sachs, SB Hammer, OH Sunderland, WW Sheddel, RJ Higgins, HS Page 10 General Subject Matter Esteron 3-3 weed and brush killer production specifications Esteron 67-33 OS confidential complete statement of Ingredients and sources of raw materials Esteron 76BE production specification Esteron 76BE Production specifications for Esteron 76E and sources of raw materials Production specifications for Esteron 76E and sources of raw materials Production specifications for Esteron 76E I )) ) Dow Number 0504090- 0504093* 0504094 * 0504438 * 05044390504447* 0505582 * 0525660- 0525661* 0526601 * 05266020526603* Date 000000 620521 700619 700519 000000 660427 671030 671030 Author Dow Hoi deman , GE Recipient Glldart, CM Van Horn, RL Parsey, ES Dow Dow Dow 05266040526605* 05266060526607* 0526608- o 0526612* CTj QO. 671030 671030 671103 Dow Dow Dow ) Distributees Vanvalkenburg, JW Page 11 General Subject Matter Information on inert ingredients used in Dow pesticides Carlisle base 5136 Carlisle chemical works Esteron 99 concentrate, com position and raw materials Esteron 99 concentrate - eva luation of revised formulation Formula 40, Ingredient statement M-3060 specifications Composition and raw materials for Tordon 2S weed killer Composition and raw materials for Tordon 202 mixture Composition and raw materials for Tordon 212 mixture Composition and raw materials for Tordon 225 herbicide Composition of formulations used 1n experimental work for registration Dow Number 0538171- 0538172* 0538173 * 0538174 * 0538175 * 0538176 * 0538177 * 0538178 * 0538179 * 0538180 * 0538181 * 0538182 * 05541250554176* Date 710114 710114 710114 710114 710114 710114 710114 710114 710114 710114 710114 680613 Author Dow Dow Dow Dow Dow Dow Dow Dow Dow Dow Dow Seidel, M Brown, M. H1ghh1ll, C Recipient )) Distributees Ble1we1ss, J Beauchamp, R Crummett, W Dellne, D Delong, H Dosser, R Fernandez, J H1ghh1ll, C Hoff, D Page 12 General Subject Matter Brush killer LY 4T specifications Brush killer T specifications Brush killer TX specifications Esteron 3-3 specifications Esteron 245 specifications Esteron 245 specifications Esteron brush killer specifi cations Reddon specifications U p p o n 2-2 specifications U p p o n T6 specifications Veon 245 specifications A technological review of phenoxy and Tordon formulation v \) ) Dow Number Date Author Recipient 05648500564851* 000000 07066490706659* 07248390724844* 07248450724872* 650518 000000 631104 Dow Hoyle, HR JMN Dow Dow Seidel, EM 07248730724885* ^rrrA O -1 o 640309 Seidel, EM 1 ) ) Distributees Seidel-, M Schwark, J Snodgrass, B Woodward, D Chase, FI Seidel, EM Dosser, RC Amstutz, FC Dylewskl, SW Dellne, DD Del Isle, NG Crose, WL Fernandez, JB Sculatf, JJ Seidel, EM Dosser, RC Amstutz, FC Dylewskl, SW Del Ine-, DD Del Isle, NG General Subject Matter Page 13 Tordon 225 herbicide (Data sheet of properties, health hazards, and precautions for safe handling of materials) 245T plant operations course P.O.C. 6020-Un1t 13 General process description new processes for 2,4-D, 2,4,5-T Preliminary economics 1n alter nate 245T ester process Economic evaluation of alternate 245T ester process } .) Dow Number Date Author Recipient 07248860724892* 0724963 * 07250720725075* 07250760725078* 07251070725112* 0725134 * 07251350725136* 07251370725144* 0725145 * 0725179^6 0725184* tiSs> O 640104 000000 000000 000000 000000 000000 660608 000000 000000 650615 Seidel, EM Dow Dow Dow Dow Chase, FI Dow Dow Dow Dow Pistributees Grose, WL Highhlll, CA Fernandez, JB Sculatl, JJ Chase, FI General Subject Matter Page 14 Analysis of two processes for producing phenoxy esters 245T process block flow chart Direct ester operating Instructions Transfer of raw materials to H, E &C Procedures Switching pumps, Instructions Column flush Operating Instructions v Instructions Pulsafeeder test sheet hydroch loric acid )t ) Dow Number 07251900725191* 07252180725224* 0725503 * Date 000000 000000 640810 Author Dow Recipient T.A.G. White, LC, Jr. Delong, HC Hlghhill, CA Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Ouellette, FE Hoi deman, GE 0725504 * 640810 White, LC, Jr. Delong, HC Hlghhill, CA Amstutz, FC Hudberg, RN Loucks, MF Corbin, WL Ouellette, FE Hoi deman , GE 0725505 * O ro 601101 Dosser, RC Hlghhill, CA Luce, EN 1 )) ) Distributees White, LC, Jr. Delong, HC Highhill, CA Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Ouellette, FE Hoi deman, GE Scheddel, RT Higgins, HS White, LC, Jr. Delong, HC Highhill, CA Amstutz, FC Hudberg, RN Loucks, MF Corbin, WLN Ouellette, FE Hoi deman , GE Scheddel, RT Higgins, HS Dosser, RC Highhill, CA Luce, EN General Subject Matter Instructions, procedures Page 15 Direct Ester reaction information 489 Bldg. Diehlorophenol Dowanol Product specification for Veon 245 Product specification for Veon brush killer Product specification for 245T Amine weed killer i )) Dow Number Date 0725508 * 660406 0725509 * 670413 Author Loucks, MF Nyman, FA Smith, HL Ouellette, FE Highhill, CA White, LC, Jr. Delong, HC Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Holdeman, GE Recipient Falkenstein, WJ Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Holdeman, GE 0725510 * a co 690227 Matuska, RJ Murphy, RW Loucks, MF Fraser, JM ) )) ) Distributees Loucks, MF Nyman, FA Smith, HL Ouellette, FE H1ghh1ll, CA White, LC, Jr. Delong, HC Amstutz, FC Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE Scheddel, RP Higgins, HS Falkensteln, WJ Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE Scheddel, RT Higgins, HA Richardson, HA Skory, L Brown, R Matuska, RJ Murphy, RW Loucks, MF Fraser, JM General Subject Matter Page 16 Product specifications for weed killer LV4 Product specification for Verton T A "r Product specification for Verton 4D J; ) Dow Number Date 0725511 * 680416 Author Hawley, HM Sheldon, HW Talcott, AT Hoi deman, GE Recipient White, LC Falkensteln, WJ Hawley, HM Corbin., WL Talcott, AT Hoi deman , GE 0725512 * 670708 Falkensteln, WJ Scoles, GW Amstutz, FC Hudberg, EN Scheddel, RT Luce, EN McCoy, WJ Talcott, AT Hoi deman , GE 0725513 * O 730223 Blosser., KC G U I , HH Chase, FI Woodward, R ) Distributees Hawley, HM Sheldon, HW Talcott, AT Hoi deman , GE McCoy, WJ White, LC Falkensteln, WJ Hawley, HM Corbin, WL Talcott, AT Hoi deman, GE Scheddel, RT Relgler, PT Falkensteln, WJ Amstutz, FC Hudberg, EN Scheddel , RT Luce, EN McCoy, WJ Talcott, AT Hoi deman , GE W1ff1n, EE Richardson, HA Skory, L Brown, R Butler, A Blosser, KC G U I , HH Chase, FI Woodward, R General Subject Matter Page 17 Product specification for Verton 2D Product specification for Verton CE Product specification for Dow Butyl 400 24D weed killer )) ) Dow Number Date 0725514 * 630507 0725515 * 720316 0725516 * 630507 k-P* O -a cn Author Hoff, RC Fraser, JM Seymour, KG Hanson, KY Flannery, RF Talcott, AT Hoi deman, GE White, LC, Jr. Delong, HC Highhill, CA Amstutz, FC Niehoff, BR Loucks, MF Korsmeier, RB Ouellette, FE Hoi deman, GE Flannery, RF Seymour, KG Chase, FI Woodward, R Gill-, HH Blosser, KC Hoff, RC Scoles, GW Talcott, AT Hoi deman , GE White, LC, Jr. Delong, HC Highhill, CA Amstutz, FC Recipient ) Distributees Hoff, RC Frazer, JM Seymour, KG Hanson, KY Flannery, RF Talcott, AT Hoi deman, GE White, LC, Jr. Delong, HC H1ghh1ll, CA Amstutz, FC Nlehoff, BR Loucks, HF Ouellette, FE Hoi deman, GE Flannery, RF Seymour, KG Chase, FT Woodward, R Gill, HH Blosser, KC Hoff, RC Scoles, GW Talcott, AT Hoi deman, GE White, LC. Jr. Delong, HC H1ghh111, CA Amstutz, FC General Subject Matter Page 18 Product specification for Dow Butyl 400 Product specification for lawn weed killer Product specification for Reddon I ) Dow Number 0725517 * 0725518 * 0725519 * Date 640213 630415 730822 Author Niehoff, BR Loucks, MF Korsmeler, RB Ouellette, FE Hoi deman, GE Recipient White, LC, Jr. Delong, HC H1ghh1ll, CA Amstutz, FC Niehoff, BR Loucks, MF Korsmeler, RB Ouellette, FE Hoi deman, GE H1ghh1ll, CA Amstutz, FC White, LC, Jr. Niehoff, BR Loucks, MF Korsmeler, RB Ouellette, FE Hoi deman, GE Seymour, KG Blosser, KC Hodges, KL Chase, FI Woodward, R Hoff, RC Fraser, JM 14076 Distributees Niehoff, BR Loucks, MF Ouellette, FE Holdeman, GE White, LC, Jr. Delong, HC H1ghh1ll, CA Amstutz, FC Niehoff, BR Loucks, MF Korsmeler, RB Ouellette, FE Holdeman, GE Highhill-, CA Amstutz, FC White, LC, Jr. Niehoff, BR Loucks, MF Ouellette, FE Holdeman, GE Seymour, KG Blosser, KC Hodges, KL Chase, FI Woodward, R Hoff, RC Fraser, JM >/ > General Subject Matter Page 19 Product specification for U p p o n 2-2 Product specification for U p p o n T4 Production specification for Uppon T6 weed and brush killer ' ) ) Dow Number Date 0725522 * 0725523 * 690106 690106 Author McCutchen, L Flannery, RF Talcott, AT Hoi deman, GE Dow Dow Recipient 0725524 * 660418 White, LC, Jr. Delong, HC Amstutz., FC Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE 0725525 * 720218 Seymour, KG Chase, FI Flannery, MF Ta1t, SR Woodward, R Scoles, GW Hoff, RC Talcott, AT Flannery, RF Hoi deman , GE o -c Distributees McCutchen, L Flannery, RF Talcott, AT Hoi deman, GE White, LC, Jr. Delong, HC Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Holdemari, GE Scheddel, RT Higgins, HS Seymour, KG Chase, FI Flannery, MF Ta1t, SR Woodward, R Scoles, GW Hoff, RC Talcott, AT Flannery, RF Hoi deman, GE General Subject Matter Suggested product specification for brush killer T 334 Suggested product specification for brush killer 50-25 Product specification for brush killer LV 4T Product specification for brush killer LV 2-2 ) Dow Number 0725526 * Date 660418 Author White, LC, Jr. Delong, HC Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE Recipient 0725527 * 651007 Dow 0725528 * 0725529 * 630424 721013 Delong, HC Highhlll , CA Amstutz, FC White, LC, Jr. Hoff, RC Loucks, MF Korsmeler, RB Ouellette, FE Flannery, RF Blosser, KC Gill, HH Chase, FI Woodward, R Hoff, RC Fraser, JM Talcott, AT Hoi deman, GE 140 ) Distributees White, LC, Jr. Delong, HC Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE Scheddel, RT Higgins, HS Delong, HC H1ghh1ll, CA Amstutz, FC White, LC, Jr. Hoff, RC Loucks, MF Ouellette, FE Hoi deman, FE Flannery, RF Blosser, KC G111, HH Chase, FI Woodward, R Hoff, RC Fraser, JM Talcott, AT Hoi deman , GE Page 21 General Subject Matter Product specification for brush killer LV 2-2 Product specification for brush killer Lv 2-2 Product specification for Esteron brush killer OS Product specification for Reddon V Dow Number 0725530 * Date 630424 0725531 * 720108 0725532 * 601004 0725533 * h* 0725534 * O CO 650125 640612 Author Delong, HC Highhill, CA Amstutz, FC White, LC, Jr. Hoff, RC Loucks, MF Korsmeler, RB Ouellette, FE Flannery, RF Seymour, KG Loucks, MF Ta1t, SR Chase, FI Woodward, R. Hoff, RC Scoles, GW Talcott, AT Hoi deman , GE Recipient Dosser, RC Delong, HC Loucks, MF Luce, EN Nyman, FA Smith, HL Ouellette, FE Dow White, LC, Jr. Delong, HC I Distributees Delong, HC Hi ghh111, CA Amstutz, FC White, LC, Jr. Hoff, RC Loucks, MF Ouellette, FE Hoi deman, GE Flannery, RF Seymour, KG Loucks, MF Ta1t, SR Chase, FI Woodward, R Hoff, RC Scoles, GW Talcott, AT Hoi deman, GE Dosser, RC Delong, HC Loucks, MF Luce, EN Nyman, FA Smith, HL Ouellette, FE White, LC, Jr. Delong, HC Page 22 General Subject Matter Product specification for Esteron Ten-Ten Product specification for Esteron 44 weed killer Product specification for Esteron 44 Suggested product specification for Esteron 47 Product specification for Esteron 67-33 OS ) Dow Number Date 0725535 * 660721 Author H1ghh1ll, CA Amstutz, FC Hudberg, RN Loucks, MF Korsmeier, RB Ouellette, FE Hoi deman , GE White, LC, Jr. Delong, HC H1ghhi11, CA Deline, DD Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE Recipient 0725536* 681118 0725537 * 710317 o 00 CD H1ghh1ll,CA Woodward, RE Hawley, HM Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE Seymour, KG Chase, FI Loucks, MF ) Distributees Hudberg, RN Loucks, MF Korsmeler, RB Ouellette, FE Holdeman, GE Higgins, HS Scheddel, RT White, LC, Jr. Delong, HC Highhill, CA Deline, DD Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Holdeman, GE Scheddel, RT Higgins, HS H1ghh1ll, CA Woodward, RE Hawley, HM Talcott, AT General Subject Matter Page 23 Product specification for Esteron 76E Product specification for Esteron 76BE Seymour, KG Chase, FI Loucks, MF Product specification for Esteron 76E herbicide ) Dow Number Date 0725538 * 630424 0725539 * 670717 Author Relgler, PF Woodward, R Hawley, HM Talcott, AT MacDonald, LA Hoi deman, GE Delong, HC Highhill, CA Amstutz, FC White, LC, Jr. Hoff, RC Loucks, MF Korsmeler, RB Ouellette, FE Hoi deman , FE Highhill, CA White, LC Deline, DD Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE Recipient 00 ) Distributees Relgler, PF Woodward, R Hawley, HM Talcott, AT MacDonald, LA Hoi deman, GE Delong, HC H1ghh1ll, CA Amstutz, FC White, LC, Jr. Hoff, RC Loucks, MF Ouellette, FE Hoi deman , GE Hlghhill, CA White, LC Deline, DD Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman , GE Higgins, HS Scheddel, RT Wlffen, EE Richardson, HA Skory, LK Brown, R Butler, A General Subject Matter Page 24 Product specification for Esteron 99 Product specification for Esteron 99 concentrate * Dow Number 0725540 * Date 670214 Author White, LC Delong, HC Highhlll, CA Deline, DD Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE Rec1p1ent 0725541 * 630507 White, LC, Jr. Delong, HC Highhlll, CA Amstutz, FC Niehoff, BR Loucks, MF Korsmeler, RB Ouellette, FE Hoi deman, GE 0725542 641019 White, LC, Jr. Delong, HC Highhlll, CA Amstutz, FC Hudberg, RN Loucks, MF ; Distributees White, LC Delong, HC H1ghh1ll, CA Deline, DD Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman , GE Higgins, HS Scheddel, RL Richardson, HA Skory, L Brown, R White, LC, Jr. Delong, HC H1ghh1ll, CA Amstutz, FC Niehoff, BR Loucks, MF Ouellette, FE Hoi deman, GE Page 25 General Subject Matter Product specification for Esteron 245 OS Product specification for Esteron 245 concentrate White, LC, Jr. Delong, HC H1ghh1ll, CA Hudberg, RN Loucks, MF McCoy, WJ Product specification for Esteron 600 )) 1 ) Dow Number Date 0725543 * 610906 0725544 * 660121 Author Rec1p1ent McCoy, WJ Ouellette, FE Hoi deman, GE Vanvalkenburg, W White, LC, Jr. Delong, HC Luce, EN Loucks, MF Nyman, FA Smith, HL Ouellette, FE White, LC, Or. Delong, HC H1ghh1ll, CA Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman , GE 0725546 * 0725547 * 571226 620104 Watson, G Scoles, GW ^ 0725548 * O GO QJ 690219 Vanhorn, R )) J Distributees Hoi deman , FE Scheddel, RT Higgins, HS Vanvalkenburg, W White, LC, Jr. Delong, HC Luce, EN Loucks, MF Nyman, FA Smith, HL Ouellette, FE White, LC, Jr. Delong, HC H1ghh111, CA Amstutz, FC Hudberg, RN Loucks, MF McCoy, WJ Talcott, AT Hoi deman, GE Scheddel, RT Higgins, HS General Subject Matter Page 26 Product specification for Esteron seventy Product specification for Esteron 6E Production specification Brush Killer 21 Production specification Brush Killer 50-50 Brush Killer T production specification ) Dow Number 0725549 * 0725550 * 0725551 * 0725555 * 0725558 * 07258710725881* 0725903 * 0725904 * 0725905 * 0725906 * 0725907 * ^0725908 * # * V V' di* Date 620213 620213 650809 610928 661011 000000 000000 000000 000000 000000 000000 000000 Author Scoles, G Scoles, G Vanhorn, R Scoles, G Vanhorn, R Dow Dow Dow Dow Dow Dow Dow Recipient I ) ) Distributees Page 27 General Subject Matter Brush Killer TX production specification Brush Killer X production specification Esteron T2 production specification Clover Killer (discontinued) pro duction specification Verton 2 (not released) production specification Safe work procedure Tordon 225E Tordon production charges Tordon 101 batch calculations and adjustments Tordon 212 batch calculations and adjustments Tordon 2696 batch calculations and adjustments Tordon K salt and Tordon 22K batch calculations and adjustments Tordon 155 batch calculations and adjustments ) Dow Number 0725909 * 0725910 * 0725911 * 0725912 * 0725915 * 0725917- 0725920* 0725940 * 0725954- 0725960* 0725961- 0725963* 0725977 0726026- 0726036* 0726037 * 0746427O 0746472* CD CJS Date 000000 000000 000000 000000 000000 000000 700414 690612 700921 720218 000000 701020 670109 Author Dow Dow Dow Dow Dow Dow Dow Dow Dow Dow Dow Johnson, RL W1d1ger, AH Recipient J I Distributees Johnson, RL Widiger, H Page 28 General Subject Matter Tordon 472 batch calculations and adjustments Tordon 40 batch calculations and adjustments Loading TIPA Tordon concentrate Tordon formulations Tordon formulations Tordon 22K batch 810713 Tordon 225 product specification Tordon 225 formulation Description of process for produc tion of Tordon 225 245T production specification Formulating Instructions for Tordon 472 * Tordon brush killer 520 production and sales specifications Thermal decomposition of dry sodium salts of chlorinated phenates )I Dow Number Date Author Recipient 07464300746447* 07471260747128* 07503320750354* 650804 640730 571122 Wagoner, EJ Cobler, JG Holmes., R W1d1ger, A Johnson, RL Hoyle, HR Dow McCollister, DD Olson, KJ o c. cn ) ) Distributees Bender, S Bailey, C Silverstein, L Cobler, J Haberstroh, W Sauers, R Allinson, RL Athay, RN Beshgetoor, AW Boundy, RH Colby, RW Dosser, RC Dow Elshere, D Gay, HH Greene, LM Hart, A Hymas, TA Jones, GD K111an, DJ Luce, EN Martin, D McIntyre, HH Mussel 1, DR Perkins, RP Tisdale, WO General Subject Matter Page 29 Differential thermal analysis of various chlorophenols Trichlorophenol manufacture Results of range finding toxicolo gical tests on Brush Killer X, Weed Killer X, and Brush Killer TX V * Dow Number Date Author Recipient 07504650750469* 501017 07504700750484* 530217 Adams EM Dow McColHster, DD Rowe VK Allen, WW Alqulst, FN Britton, JW Dosser, RC Dow Dutton, WC Irish, DD Kagy, JF Lynn, GE Dow RJE McColHster, DD Oyen, F 14GC7 ) / )I Distributees White, LC Wright, N General Subject Matter Page Results of skin irritation and skin sensitization tests conducted on human subjects with Esteron 245 (New Ester) Allen, WW AlUnson, RL Al qui st, FN Beshgetoor, AW Boundy, RH Britton, EC Britton, JW Collier, B Davidson, JH Dow Dutton, WC Gay, HH Gibson, J Greene, LN Heath, SB Johnson, JE Kagy, JF Kelly, JA Kriner, RR Results of range finding toxicolo gical tests on Esteron 245 .V * Dow Number Date Author Recipient 07505600750587* 531030 Adams, EM Oyen, F 14088 Distributees Luce, EN Lynn, GE MacCutcheon Mel ass, VH Nation, HA Otis, CE Prendergast, DT Southwick, L Sunderland, WW Vanhorn, JC Walker, H White, LC Wright, P Zuhl, HH Allen, WW Alllnson, RL Alqulst, FN Barrons, KC Beshgetoor, AW Boundy, RH Britton, EC Davidson, JH Dow Dutton, WC Gay, HH Greene, LM Kagy, JF Luce, EN Lynn, GE MacCutcheon, SM Prescott, RF Sunderland, WW General Subject Matter Results of range finding toxlcolo gical tests on Dow Brush Killer T Dow Number Date Author Recipient 07506020750633* 560501 Dow McColHster, DD Torkelson, TR 07506660750693* 560409 Dow HcColHster, DD Wolf, MA Distributees White, L Wright, P AlUnson, RL Beshgetoor, AW Boundy, RH Britton, EC Coulter, LL Dow Elshere, D Gay, HH Greene, LM Hart, A K1l1an, DJ Luce, EN McCutcheon, SM Martin, D Scoles, G Sunderland, WW Wright, N AlUnson, RL Beshgetoor, AW Boundy, RH Britton, EC Colby, RW Dow Elshere, D Gay, HH Greene, LM Hart, A Kagy, JF General Subject Matter Page 32 Results of range finding toxicolo gical tests on M-631 (Esteron 245-Type Formulation) Results of range finding toxicolo gical tests on formulations of Reddon (M-640 and M-713) /) bow Number Date Author Recipient 07506940750714* 560702 Dow McColl 1ster, DD 01 son, KJ 0750719M 0750726* O o<> 570806 Dow Hoyle, HR Wolf, M4 ) Distributees Kelly, J Kilian, DJ Luce, EM Lynn, GE MacCutcheon, SM Sunderland, WW Wright, N Alllnson, RL Alquist, FN Barrons, KC Beshgetoor, AW Boundy, RH Britton, EC Colby, RW Dow Elshere, D Gay, HH Greene, LM Hart, A Kagy, KF Kelly, JA K1l1an, DJ Luce, EN Lynn, GE MacCutcheon, SM Sunderland, WW Wright, N Alllnson, RL Athay, RM Beshgetoor, AW Boundy, RH General Subject Matter Page 33 Results of range finding toxicolo gical tests on Esteron Brush Killer O.S. (M-726) > Results of range finding toxicolo gical tests on M-1085 {A 245T Triethyl amine Liquid Formulation) ) Dow Number Date Author Recipient 07507270750736* 570510 07507390750740* 570510 0750741^ 0750743* 03 000000 Babcock, I Dow Dunn, EE KS MAW Dow Wolf, MA Dow Hoyle, HR McCollister, DD Wolf, MA Dow Hoyle, HR McCollister, DD Wolf, MA Di strlbutees Colby, RW Dow Elshere, D Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McCollister, DD McIntyre, HH Mussel 1, DR Perkins, RP Scoles, GW Tisdale, WL Wright, N General Subject Matter Page 34 Request for application testing for M-1085 with eye and skin contact tests attached M-1085 data sheet of properties, health hazards, and precautions for safe handling of materials V * M-1085 data sheet of properties, health hazards, and precautions for safe handling of materials ) Dow Number 07507440750746* Date 580521 07507470750764* 580425 Author Recipient Dow Coulter, LL McCollister, DD Dow Olson, KJ Dow Hoyle, HR McCollister, DD Olson, KJ M 0750769- fc* 0750790* ` cp, to 610316 Hoyle, HR Olson, KJ Oyen, F Thompson, E  ) Distributees AlUnson, RL Athay, RM Beshgetoor, AW Boundy, RH Colby., RW Coulter, LL Dow El shere-, D Fletcher, FW Gay, HH Greene, LM Hammer, OH Hart, A Jones, GD Kagy, JF K1l1an, DJ Luce, EN McIntyre, HH Perkins, RP Scoles, GW Tisdale-, WL Vanvalkenburg, W Wright, N Barrons, KC Boundy, RH Colby, RW Dow Page 35 General Subject Matter Results of range finding toxicolo gical tests on Weed Killer Formulation M-1094 containing a 245T Ester M-1094 Weed Killer Formulation Data sheet of properties, health hazards and precautions for safe handling of materials Results of range finding toxicolo gical tests on M-1123 Dow Number Date Author Recipient 07507910750793* 07507950750813* 000000 600125 Hoyle, HR Olson, KJ Oyen, F Dow Oyen, F Wolf, MA ) Distributees Eishere, D Falkenstein, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Shrader, SA Tisdale, WL Vanvalkenburg, W Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF General Subject Matter Page 36 M-1123 data sheet of properties, health hazards, and precautions for safe handling of materials Results of range finding toxicolo gical tests on Esteron 245 OS (M--1257) Dow Number Date Author Recipient 07508140750827* 610601 Dow Olson, KJ Oyen, F 07508330750854* 571122 Dow McCollister, DD Olson, KJ Distributees K111an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Stenger, VA Tisdale, WL Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Falkensteln, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Shrader, SA Tisdale, WL White, LC, Jr. Wright, N AlUnson, RL Athay, RM Beshgetoor, AW General Subject Matter Page 37 Results of range finding toxicolo gical tests on Esteron 245 OS (Replacement for present Formulation M-1257) V f Results of range finding toxicolo gical tests on Brush Killer X, Weed Killer X, and Brush Killer Dow Number Date Author Recipient 07508550750873* 590818 Olson, KJ Oyen, F ) ) Distributees Boundy, RH Colby, RW Dosser, RC Dow Elshere, D Gay, HH Greene, LM Hart, A Hymas, TA Jones, GD K111an, DJ Luce, EN Martin-, D McIntyre, HH Mussel 1, DR Perkins, RP Tisdale, WL White, LC Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Gray, HE Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF General Subject Matter TX Page 38 Results of range finding toxicolo gical tests on M-1413 (Formulation of Dowanol Ester 245T) made for the Stull Chemical Company V )) ) Dow Number Date Author Recipient 07508740750876* 590706 07508780750903* 590506 Dow Hoyle, HR Olson, KJ Oyen, F Dow McCollister., DD Wolf, MA <r: ) ; ) Distributees K1l1an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Scoles, G Stenger, VA Tisdale., WL Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Gray, HE Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF Kill an, DJ Luce, EN Lynn, GE McIntyre, HH General Subject Matter Page 39 M-1413 Formulation of K 7856 (Dowanol Ester 245T). Data sheet of properties, health hazards and precautions for safe handling of materials Results of range finding toxlcolo-. glcal tests on M-1447 and M-1443 Weed Killer Formulations (Similar to Esteron 245 OS and Esteron Brush Killer OS respectively) ) ) Dow Number Date Author Recipient 07509150750940* 590506 Dow McCollister, DD Wolf, MA 07509510750952* 591209 r Dow Wolf, MA McIntyre, HH I) ) Distributees Perkins, RP Stenger, VA Tisdale, WL Vanvalkenburg, JW Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Gray, HE Greene, LM Hammer, OH Hart, A Hymas, TA Jones, JD Kagy, JF K1l1an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Stenger, VA Tisdale, WL Vanvalkenburg, JW Wright, N Dow Wolf, MA General Subject Matter Page 40 Results of range finding toxicolo gical tests on M-1447 and M-1433 Weed Killer Formulations (Similar to Esteron 245 OS and Esteron Brush Killer OS respectively) Toxicological Information on Esteron 99 granules (M-1741) suitable for presentation to the USDA Dow Number 07509560750974* Date 590903 Author Dow Olson, KJ Oyen, F Recipient 07509750750976* 590811 07509770550996* H4 O r O 600216 Dow HRH Olson, KJ Oyen, F Dow Olson, K Oyen, F )} Distributees Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF K111an, DJ Leasure, JK Luce, EN Lynn, GE McIntyre, HH Perkins, RP Scoles, G Stenger, VA Tisdale, WL Wright, N Barrons, KC Boundy, RH Colby, RW Dow General Subject Matter Page 41 t# Results of range finding toxicolo gical tests on Agricultural Chemical Formulation M-1511 con taining Dowanol 97B70 Ester 245T (K--7856) M-1511 Data sheet of properties, 1 health hazards and precautions for safe handling of materials * Results of range finding toxicolo gical tests on Agricultural Chemical Formulation M-1683 (Esteron 245 Type) Dow Number Date hither Recipient 07509980751016* 600223 Diw Ctfson, KJ 0/ern, F O CO to ) ) Distributees Elshere, D Gay, HH Greene-, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF K11ian, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Scoles, GW Stenger, VA Tisdale, WL Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF K11Ian, DJ Luce, EN Lynn, GE General Subject Matter Page 42 Results of range finding toxicolo gical tests on Agricultural Chemical Formulation M-1684 (Esteron Brush Killer Type) Dow Number Date Author Recipient 07510560751058* 611120 Dow Olson, KJ Oyen, F PI orner, ET Scoi es, GW 0751059 * 611120 h-* O O ) Distributees McIntyre, HH Perkins, RP Scoles, GW Stenger, VA Tisdale, WL Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Falkensteln, W Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K1l1an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, P Scoles, GW Shrader, SA Tisdale, WL Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D General Subject Matter Page 43 Results of range finding toxicolo gical tests on M-2115, an agricultural chemical formulation containing 245T and triethyl amine First aid measures V 'k I I Dow Number Date Author Recipient 07510600751075* 611106 Dow Hoyle, HR Olson, KJ Oyen, F Plomer, ET C; I ) I Distributees Falkensteln, W Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K111an., DJ Luce, EN Lynn, GE McIntyre, HH Perkins, P Scoles, GW Shrader, SA Tisdale, WL Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Falkenstein, W Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K1l1an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, P Scoles, GW General Subject Matter Page 4< M-2115 data sheet of properties, health hazards and precautions for safe handling of materials 'A Dow Number Date Author Recipient 07510780751080* 620403 Dow Olson, KJ Oyen, F Vanvalkenburg, W 0751081 * 620323 ) D1strlbutees Shrader, SA Tisdale, WL Wright, N Barrons, KC Boundy, RH Brown, R Colby, RW Dow Elshere-, D Falkensteln, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McIntyre, HH Nash, HA Perkins, RP Shrader, SA Vanvalkenburg, W Wilson, AW Wright, N Barrons, KC Boundy, RH Brown, R Colby, RW Dow Elshere, D General Subject Matter Page 45 Results of range finding toxicolo gical tests on M-2235, an emu!si zable formulation of 24D and 245T Dowanol Esters 1n kerosene First aid measures V V* Dow Number Date Author Recipient 07510820751098* 620323 Dow Hoyle, HR Olson, KJ Oyen, F o CO ) Distributees Falkenstein, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH Nash, HA Perkins, RP Shrader, SA Yanvalkenburg, W Wilson, AW Wright, N Barrons, KC Boundy, RH Brown, R Colby, RW Dow Elshere, D Falkenstein, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH General Subject Matter Page 46 M-2235 data sheet of properties, health hazards, and precautions for safe handling of materials V ;/ ))) ) Dow Number Date Author Recipient 07510990751101* 0751102 * 07512090751210* 630809 620124 630225 Hoyle, HR Olson, KJ Oyen, F Dow Wolf, MA Dow Olson, KJ Oyen, F Scoles, G Dow McIntyre, HH O ) ) ) Distributees Nash, HA Perkins, RP Shrader, SA Vanvalkenburg, W Wilson, AW Wright, N General Subject Matter Page 47 Verton T sales specification Barrons, KC Boundy, RH Brown, R' Colby, RW Dow Elshere, D Falkenstein, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH Mullison, WR Nash, HA Norton, TR Suggested precautionary labeling for M-2235 Results of range finding toxicolo gical tests on agricultural chemi cal formulation N-2422 containing 91 percent Dowanol PIB Ester of 24 5T Dow Number Date Author 0751211 * 630225 Recipient 07512120751213* 630220 o ai Dow Hoyle, HR Olson, KJ Oyen, F ) ) Distributees Shrader, SA Wilson, AW Wright, N Barrons, KC Boundy, RH Brown, R Colby, RW Dow Elshere, D Falkensteln, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McIntyre, HH Mull 1son, WR Nash, HA Norton, TR Shrader, SA Wilson, AW Wright, N Barrons, KC Boundy, RH Brown, R Colby, RW Dow Elshere, D General Subject Matter Page 48 First aid measures 'r M-2422 data sheet of properties, health hazards and precautions for safe handling of materials I) ) ) Dow Number Date Author Recipient 07512140751236* 630225 O ao )I ) ) Distributees Falkensteln, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McIntyre, HH MulHson, WR Nash, HA Norton, TR Shrader, SA Wilson, AW Wright, N Barrons, KC Boundy, RH Brown, R Colby, RW Dow Elshere, D Falkensteln, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K1l1an,, DJ Luce, EN Lynn, GE McIntyre, HH . General Subject Matter Page 49 Toxicological properties of Formulation M-2422 V Dow Number Date Author Recipient 07522640752265* 670328 0752266 * 661220 07523600752361* 07523850752386* 670410 690415 Dow Hoyle, HR McCollister, DD Olson, KJ Buerge, TE Dow Dow Lynn, GE Dow Norris, JM Torkel son, TR I J Distributees Mull 1son, WR Nash, HA Norton, TR Shrader, SA Wilson, AW Wright, N Axe, FD Barton, J Beauchamp, RR Blair, EH Burgert, BE Dow Edwards, H Elshere, D Gordon, HL Holder, BB Johnson, JE Kagy, JF K1l1an, DJ Klmmel, CE Lloyd, BH General Subject Matter Page 50 M-3060 data sheet of properties, health hazards and precautions for safe handling of materials M-3060 request for screening or application testing M-3060, Safety Data and Formulation M-3401 Brush K1ller-A Tordon Acid Formulation 'r Dow Number Date Author Recipient 07523880752389* 690320 07523900752395* 07525500752552* 690417 700130 07525530752554* 690429 Dow Hoyle, HR Norris, JM Torkel son , TR Dow Norris, JM Dow Gowell, JH Loucks, MF Lynn, GE Naegele, RE Newport, JJ Rldner, JM Seymour, KG Stein, JS Williams, CS Williams, RW Wolf, MA Dow Hoyle, HR ) ; Distributees MacCutcheon, SM McColl1ster, DD McIntyre, HH Morse, D P1tman-Moore Robinson, VB Schwartz, AJ Wright, N General Subject Matter Page 5: M-3402 Brush Killer data sheet of properties, health hazards and precautions for safe handling of materials Toxicological properties of M-3401 Brush K1ller-A Tordon acid for mulation Tordon 225 herbicide release to sales Tordon 225 mixture herbicide data sheet of properties, health ) ) Dow Number Date 07624930762496* 500829 0762497 * 0762498 * 000000 490309 0762499 * 490412 0762500 * 07625010762504* 0762505 * 490321 490000 490517 o D Author Norris, JM Dow Rowe, VK Spencer, HC Recipient Allen, WW Barrons, KC Britton, JW Dosser, RC Dow Dutton, WC Irish, DD Kagy, JF Lynn, GE Dow Irish, DD McCollister, DD Rowe, VK White, L Dow Wyse, H Dow Wyse, H Dow Wyse, H Dow Wyse, H Distributees J' ) Page 52 General Subject Matter hazards and precautions for safe handling of materials Results of range finding toxicolo gical tests on Esteron 245T for mulations Sunriary of toxicological Infor mation on 24D & 245T formulations Esteron 245T (New formulation) (Request for biological test) K7716-1 Esteron 245T (New formulation) (Acute oral toxicity) Esteron 245T (New formulation) K7716-1 Esteron 245T (New formulation) (Skin Irritation) K7716-1 Esteron 245T (New formulation) (Single absorption exposure record) j J Dow Number 0762506 * Date 490225 0762507 * 0762508 * 07625090762512* 0762513 * 490414 490321 490000 490517 07666980766699* 690415 Author Dow HAS RSH Irish Rowe, VK White, L Dow Wyse, H Dow Wyse, H Dow Wyse, H Dow Wyse, H Recipient Beauchamp, RR Dow Norris, JM Torkelson, TR o 1 ) Di stributees Page 53 General Subject Matter Esteron 245T formulation (Request for biological test) Axe, FD Barron, J Beauchamp, RR Blair, EH Burgert, BE Dow Edwards, H Eishere, D Gordon, HL Holder, BB Johnson, JE Kagy, JF Kilian, DJ K7716-2 Esteron 245T formulation (acute oral toxicity) Esteron 245T formulation K7716-2 Esteron 245T formulation (Skin Irritation) K7716-2 Esteron 245T formulation (Single absorption exposure record) M-3401 Brush Killer-A Tordon Acid Formulation ) Dow Number Date Author ) Recipient 07667000766701* 690320 07667020766708* 0766709 * 690417 681008 0766710 * 07667110766726* 07667270766729* 681008 680000 690310 Dow Hoyle, JR Norris, JM Torkelson, TR Dow Norris, JM Beauchamp, RR Dow McCollister, DD Byrd, BC Dow Hoerger, FD McCollister, DD Dow Dow Litchfield, N Norris, JM Dow Norris, JM h-4 )I ) Distributees Klmmel, CE Lloyd, BH MacCutcheon, SM McCollister, DD McIntyre, HH Morse, D Robinson, VB Schwarz, AJ Wright, N General Subject Matter Page 54 M-3401 Brush Killer (Data sheet of properties, health hazards and precautions for safe handling of materials) Toxicological properties of M-3401 Brush Killer, a Tordon acid formulation Proposed name, Tordon 124V Brush Killer (M3401) (Request for screening or application testing) Toxolcology work sheet (Tordon 124V Brush Killer) Tordon 124V Brush Killer (Acute oral toxicity) * i M-3401 Brush Killer, oral dosage to male rats ) Dow Number 07667300766737* Date 680000 07667380766740* 07667410766744* 07667450766746* 07667470766750* 07667510766765* 0766766 * 0766767 * 681000 681104 690128 690000 690123 690123 681008 07667680766769* 000000 Author Dow King, CD Litchfield, N Sparschu, 6L Trice, V Dow Dunn, FL Dow Dunn, FL Dow Dunn, FL Dow Litchfield, N Dow Norris, JM Recipient Dow Beauchamp, RR Dow McColHster, DD Dow 0 ) Distributees ) Page 55 General Subject Matter Tordon 124V Brush Killer (Request for pathology) Tordon 124V Brush Killer (Eye con tact test) Tordon 124V Brush Killer (Skin contact, Irritation) M-3401 Tordon 124Y Sample 2, (Skin contact, Irritation) Tordon (Skin contact absorption) Toxicological properties of Tordon 124V Brush Killer made with CA Tordon acid Tordon 124V Brush Killer (Toxicology work sheet) Proposed name Tordon 124V Brush Killer (Request for screening or ^ application testing) l M3401 Brush Killer (Data sheet of properties, health hazards and precautions for safe handling of materials) )} ) Dow Number 07667700766800* Date 680000 07668010766821* 680000 07668220766823* 690107 07668240766847* 690113 07668480766849* 690320 0766850 * _ 0766851 0766852* h- CO 560524 690320 Author Dow Dunn, FL Litchfield, N Conran, PB Dow King, CD Litchfield, N Sparschu, GL Trice, V Beauchamp, RR Dow Leong, BKJ Trice, VR Recipient Beauchamp, RR Conran, PB Dow Leong, BKJ Sparschu, GL Trice, VR Morris, JM Torkel son, TR Hoyle, HR Peterson, JE HRH JHN H ) J Distributees Page 56 General Subject Matter Tordon 124V Brush Killer, male rat testing Tordon 124V Brush Killer (Request for pathology) Summary report on the effect of acute Inhalation of the volatile components of California Tordon Acid and Texas Tordon Acid (Biochemical Res Lab Sample 1) Summary pathology report on the effect of acute Inhalation of the volatile components of California Tordon Acid and Texas Acid (Blochem Res Lab Pathology Report Sample) M-3401 Brush Killer (data sheet of properties, health hazards, and v precautions for safe handling of * materials) Brush Killer M-3401 Brush Killer (safety information) I )) ) Dow Number 07670180767019* 07670200767021* Date 560412 610525 07670220767023* 07670240767025* 07670260767027* 790216 720329 580613 07670280767029* 610525 0767030 * 0767031 * 0767032 * h* H* f 610531 000000 700721 Author Dow Recipient Dow Hoyle, HR Olson, KJ Oyen, F Dow Flshbeck, WA Keeler, P Dow Dow McColHster, DD Wolf, MA Dow Olson, KJ Oyen, F Dow Dow Dow J ) Di stributees Page 57 General Subject Matter Esteron Brush Killer OS M-726 (T2.30-71-1), safety data sheet with formulation Esteron 99 data sheet of proper ties, health hazards and pre cautions for safe handling of materials Esteron 99 medical information Esteron 99 material safety data sheet Esteron 99 data sheet of proper ties, health hazards and pre cautions for safe handling of materials Esteron 99 data sheet of proper ties, health hazards and pre cautions for safe handling of materials Esteron 99 (Replacement formulation) Esteron 99 medical Information symptomatology and treatment Esteron 99 toxicology, anticipated human response >) ) Dow Number 07670330767034* 07670540767055* Date 720329 570514 07670560767057* 580514 0767058 * 000000 07670590767060* 0767061 * 0767062 * 710900 580716 610112 07670630767064* 580425 0767065 * (" * tc-'/-r 580717 Author Dow Recipient Dow Hoyle, HR McCollister, DD Wolf, MA Dow Hoyle, HR McColllster, DD Wolf, MA Dow Hoyle, HR Wolf, MA Dow Dow Wolf, MA Dow Wolf, MA Dow McIntyre, Dow McIntyre, Dow Hoyle, HR McCollister, DD Olson, KJ Dow Hoyle, HR Olson, KJ ) ) i Distributees Page 58 General Subject Matter Esteron 99 material safety data sheet M-1086 data sheet of properties, health hazards and precautions for safe handling of materials Veon brush killer (M-1086) data sheet of properties, health hazards and precautions for safe handling of materials M-1086 (A herbicidal formulation T2.3098), safety data sheet Veon brush killer Suggested precautionary labeling for M-1094 Suggested precautionary labeling for M-1094 M-1094 weed killer formulation data sheet of properties, health hazards and precautions for safe handling of materials M-1094 containing 245T Ester T2, 30-112-1, safety data sheet } ) Dow Number 0767066 * 07670670767068* Date 570730 571120 07670690767070* 571028 0767071 * 571206 0767072 * 571206 0767073 * 07670730767074* 610112 610311 0767075 * 07670920767098* bH4 610400 531029 Author Recipient Dow Wolf, MA Coulter, LL Dow Dow Hoyle, HR McCollister, DD Olson, KJ Dow Hoyle, HR McCollister, DD Olson, KJ Dow Hoyle, HR Olson, KJ Dow Hoyle, HR Olson, KJ Dow Wolf, MA Dow McIntyre, HH Dow Hoyle, HR Olson, KJ Oyen, F Dow Adams, EM Ji ) > Distributees Allen, WW Page 59 General Subject Matter Inverton, a letter showing concern for hazards Inverton M-1116 data sheet of pro perties, health hazards and pre cautions for safe handling of materials M-1116 dilution Cl-14-100 data sheet of properties, health hazards and precautions for safe handling of materials Inverton weed killer (M-1116) T2.30-101-1, safety data sheet M-1116 dilution Inverton for mulation Suggested precautionary labeling for M-1123 M-1123 data sheet of properties, health hazards and precautions for safe handling of materials M-1123, safety data sheet Results of range finding J )) ) Dow Number Date Author Dow Eslunn, E Maxey, JS Oyen, F Recipient 07670990767119* 530325 07671530767160* 570806 Dow HCS Rowe, VK Wolf, MA Dow McCollister, DD Wolf, MA t I ) / Distributees Allinson, RL Alquist, FN Barrons, KC Beshgetoor, AW Boundy, RH Britton, EC Davidson, JH Dow Dutton, WC Gay, HH Greene, LM Kagy, JF Luce, EN Lynn, GE MacCutcheon, SM Prescott, RF Sunderland, WW White, LC Wright, P Allinson, RL Athay, RM Beshgetoor, AW Boundy, RF Colby, RW Dow Elshere Gay, HH Page 60 General Subject Matter toxicological tests on Dow Brush Killer 50-50 Toxicity of Dow Brush Killer 50-50 (T2.30-28-1) Results of range finding toxicolo gical tests on M-1085 (A 245T triethyl amine liquid formulation T2.30-97-1) Dow Number Date Author ) Recipient 07671540767155* 571005 0767161 * 0767162 * 07671630767164* 07671650767166* 570228 570301 570402 570415 Dow Hoyle, HR McCollister, DD Wolf, MA Dow Dow Babcock, D Dow Wolf, MA Dow Barrons, KC Dow V'a oe Distributees Greene, LM Hart, A Jones, GD Kagy, JF K111an, DJ Luceen Lynn, GE McIntyre, HH Mussel 1, DR Perkins, RP Scoles, GW Tisdale, WL Wright, N ) ) General Subject Matter Page 61 M-1085 (A 245T alkyl amine formulation) data sheet of pro perties, health hazards and pre cautions for safe handling of materials Sample 1, M-1085 (T2.30-97-1), eye and skin contact M-1085 request for applications testing (2.30-97-1) Sample 1 (2.30-97-1) (eye contact test) Sample 1 M-1085 skin contact Irri tation T2.30-97-1 ) Dow Number 07671840767191* Date 570806 Author Recipient Dow McCollister, DD Wolf, MA 07671850767186* 570511 0767192 * 0767193 * 570228 570227 Dow Hoyle, HR McCollister, DD Wolf, MA Dow Wolf, MA Dow Scoles, G Barrons Dow t- ' I CD ) ) I) Distributees Allison, RW Athay, RM Barrons, KC Beshgetoor, AW Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Russel, DR Scoles, G Tisdale, WL Wright, N Page 62 General Subject Matter Results of range finding toxicolo gical tests on M-1086 (A 245T and 24D alkyl amine formulation) M-1086 (Data sheet of properties, health hazards and precautions for safe handling of materials) ^ Sample 1, M-1086 (Toxicology work sheet) M-1086 (2.30-96-1) (Request for applications testing) ; )} ) Dow Number 07671940767195* 07671960767197* 07672130767222* Date 570326 570228 580521 Author Dow Stagerstron, E Dow Recipient Dow McColl1ster, DD Olson, K 07672160767217* 580425 Dow Hoyle, HR McCollister, DD Olson, KJ ofrO ) ) ) Distributees AlHnson, RL Athay, RM Beshgetoor, AW Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Jones, GD Kagy, JF K111an, DJ Luce, EN McIntyre, HH Perkins, RP Scoles, GW Tisdale, WL Vanvalkenburg, W Wright, N Page General Subject Matter Eye contact test M-1086, 12.30-96-1 M-1086 (Skin contact Irritation) (T2.30-96-1) Results of range finding toxlcolo glcal tests on weed killer for mulation M-1094 containing a 245T Ester (T2.30-112-1) Y M-1094 Weed Killer formulation (Data sheet of properties, health hazards, and precautions for safe handling of materials) Dow Number 0767223 * 0767224 * 0767225 * Date 580225 000000 580218 Author Dow Dow Scoles, G Coulter, LL Dow Recipient Dow Rowe, VK 0767226 * 580225 07672270767228* 07672290767230* 0767231 * 530311 580525 580402 Dow NCG Dow NCG Dow NCG Coulter, LL Dow Dow Rowe, VK 07672430767251* 571220 Dow McCollister, DD Olson, KJ to'' Distributees Dow Fletcher, FW Scoi es, GW Vanvalkenburg, W Dow Fletcher, FW Scoles, GW Vanvalkenburg, JW Allfnson, RL Beshgetoor, AW Boundy, RH Colby, RW Coulter, LL Dow Page 64 General Subject Matter Sample 1 Weed Killer formulation (M-1094) (Toxicology work sheet) 245T (Request for screening or application testing) Formulation M-1094, contemplated sales program Sample 1 Weed Killer formulation (M-1094) (T2.30-112-1) (acute oral toxicity) Sample 1 Weed Killer formulation (M-1094) (eye contact test) Sample 1, weed killer formulation (M-1094) (T2.30-112-1) (skin con tact Irritation) M-1094, will remain 1n development during 580000 Results of range finding toxicolo gical tests on Inverton (brush killer). (T2.30-101-1) Dow Number Date Author ) Recipient 07672450767246* 571120 0767252 * 0767253 * 0767254 * 07672550767256* r 10 Q 570520 000000 570520 570520 Dow Hoyle, HR McCollister, DD Olson, KJ Dow Dow Scoles, G Dow Babcock, D Dow ) Di stributees Eishere, D Gay, HH Gray, HE Greene, LM Hart, A Hymas, TA Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH Mussell, DR Perkins, RP Scoles, GW Tisdale, WL Wright, N General Subject Matter Page 65 Inverton M-1116 (Data sheet of properties, health hazards and precautions for safe handling of materials) Sample 1 M-1116 (T2.30-101-1) (Toxicology work sheet) M-1116 (Request for applications testing) (2,30-101-1) Sample 1 M 1116 (Acute oral toxicity) (T2.30-101-1) Sample 1 M-1116 (Eye contact test) (T2.30-101-1) ;> ) Dow Number 07672570767258* 07672590767260* 0767261 * 0767262 * 07672630767267* Date 570624 570730 580221 580408 610316 Author Recipient Babcock, D Dow Dow Wolf, MA Coulter, LL Dow Dow Dow Olson, KJ Dow Wolf, MA Dow McIntyre, HH Dow Olson, KJ Oyen, K Thompson, E Vanvalkenburg, W 03 ) ) Distributees Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Falkenstein, WJ Gay, HH Greene, LM Hart Jones, GD Kagy, JF K1l1an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Shrader, SA Tisdale, WL Vanvalkenburg, W Wright, N Page 6( General Subject Matter Sample 1 M-1116 (Skin contact Irritation) (T2.30-101-1) Inverton, a letter showing concern for hazards Request for report Suggested precautionary labelling for Inverton (M-1116) Results of range finding toxlcologlcal tests on M-1123 (T2.30-201-1) ^ ) )I ) Dow Number 07672680767269* Date 610311 0767270 * 0767271 * 0767272 * 601228 601229 601223 0767273 * 0767274 * 07672750767276* 07672770767280* 07672810767282* 07672880767300* 610106 601228 610110 601228 610120 610601 Author Dow Hoyle, HR Olson, KJ Oyen, F Dow Recipient Dow Dow Dow Vanvalkenburg, W Olson, KJ Dow Wolf, MA Dow Dow Ri tty, PM Dow Thompson, E Dow Thompson, E Dow Thompson, E Dow White, LC, Jr. ro I I >' ) Distributees Dow Johnson, JE Ri tty, PM Barrons, KC Boundy, RH Colby, RW Page 67 General Subject Matter M-1123 (Data sheet of properties, health hazards and precautions for safe handling of materials) M-1123 (Toxicology work sheet) (T2.30-201-1) M-1123 (request for screening or application testing) M-1123, Formulation, use, release to sale plans Formulation for M-1094, no data available on toxicity for M-1123 Sample 1 M-1123 (Acute oral toxicity) (T2.30-201-1 ) Sample 1 M-1123 (Eye contact test) (T2.30-201-1 ) Sample 1 M-1123 (Skin contact Irritation) (T2.30-201-1) Sample 1 M-1123 (Skin contact absorption) (T2.30-201-1) Results of range finding toxicolo gical tests on Esteron 245-OS (replacement for present for- )) ) Dow Number Date Author Recipient 07673010767314* 600125 Dow Wolf, MA j D1stributees Dow Eishere, D Falkenstein, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH Oyen, F Perkins, RP Shrader, SA Tisdale, WL White, LC, Jr. Wright, N Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF K111an, DJ Luce, EN Page 68 General Subject Matter mulatlon M-1257) (BC T2.30-167-2) Results of range finding toxicolo gical tests on Esteron 245 0S(M.1257) (BC T2.30-167-1) ' :c Dow Number Date Author Recipient 0767309 * 591102 Dow Dow Vanvalkenburg.JW Wolf, MA **">*= 0767315 * i~s K? Ob 591028 Dow R1tty, PM Dow Wolf, MA J ) Distributees Lynn, GE McIntyre, HH Oyen, F Perkins, RP Stenger, VA Tisdale, WL Wright, N Barrons, KC Boundy, RH Colby, RW Coulter, LL Dow Eishere, D Gay, HH Greene, LM Hammer, OH Hart, A Heath, SB Hymas, TA Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH Oyen, F Perkins, RP Stenger, VA Tisdale, WL Wright, N . Barrons, KC Boundy, RH General Subject Matter Page 69 Esteron 245 OS (M-1257), For mulation plans for toxicological evaluation V k Need toxicology information sheets on Esteron Brush Killer Dow Number Date Author Recipient 07673210767342* 571122 Dow 01 son, KJ ^*4 I) Distributees Colby, RW Coulter, LL Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Heath, SB Hymas, TA Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH Oyen, F Perkins, RP Stenger, VA Tisdale, WL Wright, N AlUnson, RL Athay, RM Beshgetoor, AW Boundy, RH Colby, RW Dosser, RC Dow Elshere, D Gay, HH Greene, LM Hart, A O CO General Subject Matter Page 70 Results of range finding toxicolo gical tests on Brush Killer X, Weed Killer X and Brush Killer TX (T2.30-76-1 T2.30-77-1 T2.30-78-1) Dow Number Date Author Recipient 07673660767385* 590423 Dow Wolf, MA 5CnO3 )I Distributees Hymas, TA Jones, GD K111an, DJ Luce, EN Martin, D McColllster, DD McIntyre, HH Mussel!, DR Perkins, RP Tisdale, WL White, LC Wright, N Athay, RM Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McColllster, DD McIntyre, HH Perkins, RP Stenger, VA General Subject Matter Page 71 Results of range finding toxicolo gical tests on Forron brush killer (M--1368) (T2.30-123-1) V A )I Dow Number Date Hrfctior Recipient 07674020767416* 590818 11son, KJ lyen, F <S ioyle, HR 07674170767418* 590506 Da*# NdCollister, DD Wail f , MA 07674190767421* CtXo5 590202 Da>w Ha>yle, HR Distributees Tisdale, WL Vanvalkenburg, W Wright, N Barrons, KC Colby, RW Lynn, GE Boundy, RH McIntyre, HH Perkins, RP Hart, A Wright, N Hammer, OH Hymas, TA Jones, GD Gay, HH Tisdale, WL Luce, EN Green, LM Stenger, LM Scoles, G Gray, HE K111al, DJ Elshere, D Kagy, JF General Subject Matter Results of range finding toxicolo gical tests on M1413, formulation of Dowanol Ester 245T made for Stull Chem. Data sheet of proper ties, health hazards and pre cautions for safe handling of material s Results of range finding toxicolo gical tests on M-1447 and M-1433 weed killer formulations {Similar to Esteron 245 OS and Esteron Brush Killer respectively) A concentrate formulation of 245T Dowanol 97B70 Ester data sheet of Dow Number Date 07674220767930* 590202 Author Recipient McCollister, DD Wolf, MA Dow Hoyle, HR McCollister, DD Wolf, MA 0767431 * 0767432 * 590127 581120 Dow Dow Wade, J )) ) Distributees Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Gray, HE Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Stenger, VA Tisdale, HH Vanvalkenburg, W Wright, N Page 73 General Subject Matter properties, health hazards and precautions for safe handling of materials A concentrate formulation of 24D and 245T Dowanol 97B70. Esters data sheet of properties, health hazards and precautions for safe handling of materials k M-1433 Toxicology work sheet A concentrate brush killer for mulation of 31b. 24D and 31b. 245T acid equlv per gal. based on Dowanol 97B70 Esters. Request for screening or application testing ) ) Dow Number 0767433 * Date 581121 07674340767439* 07674400767441* 581120 590506 Aithor Recipient Cow Dow Vanval kenburg,JW Olson, Dow Daw MrCol lister, DD Waif, MA 07674420767444* 590202 07674450767453* 590202 Daw Hiyle, HR MrColHster, DD Wrlf, MA Diw Hiyle, HR McColllster, DD Wrlf, MA >:I ) Distributees Coulter, LL Dow Heath, SB Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Gray, HE Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF Kllian, DJ Page 74 General Subject Matter M-1433 and M-1447, formulations M-1433 eye contact test Results of range finding toxicolo gical tests on M-1447 and M-1433 weed killer formulations (Similar to Esteron 245 OS and Esteron Brush Killer OS respectively) M-1447 A concentrate formulation of 245T Dowanol 97B70 esters. Data sheet of properties, health hazards and precautions for safe handling of materials M-1433 A concentrate formulation of 240 and 245T Dowanol 97B70 esters. Data sheet of properties, health hazards and precautions for safe handling of materials ) Dow Number Date Author Recipient 0767454 * 07674550767456* 07674570767462* 07674630767464* 590127 581120 581120 590202 07674650767466* 07674780767479* 07674800767485* 700709 590713 590414 Dow Dow Vanvalkenburg, JW Dow Dow Hoyle, HR McCollister, DD Wolf, MA Dow Dow McCol11ster, DD Wolf, MA Dow McCollister, DD 05 \D ) Distributees Luce, EH Lynn, GE McIntyre, HH Perkins, RP Stenger, VA Tisdale, WL Vanvalkenburg, JW Wright, H Barrons, KC Boundy, RH General Subject Matter Page 75 M-1447 toxicology work sheet M-1447 request for screening or application testing M-1447 acute oral toxicity M-1433 A concentrate formulation of 24D and 245T Dowanol 97B70 esters. Data sheet of properties, health hazards and precautions for safe handling of materials Dowanol 97 B-70 medical Infor mation Results of range finding toxicolo gical tests on Forron 235T Forron 245 M-1456 data sheet of properties, health hazards and Dow Number Date Author Peterson, JE Wolf, MA Recipient 0767486 * 0767487 * 590319 590127 Dow Dow 0767488 * 590113 07674890767493* 590127 Dow Dow Vantaikenburg,JW Olson, RJ Dow ) Distributees Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GS Kagy, JF K111an, DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Stenger, VA Tisdale, WL Yanvalkenburg, W Wright, N Coulter, LL Dow Heath, SB Page 7 General Subject Matter precautions for safe handling of materials M-1456 (Forron 245T) toxicology work sheet M-1456 (Contains K-7756) (Forron 245) Request for screening of ? application testing ^ Formulation M-1456 M-1456 acute oral toxicity Dow Number 0767494 * 07674950767497* Date 000000 590610 0767498 * 590722 07674990767504* 590702 Author Recipient Dow Wolf, MA Dow McCollister, DD Peterson, JE Wolf, MA Dow Olson, K Oyen, F Dow Hoyle, HR Olson, KJ ) ) Distributees Athay, RM Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Gray, HE Greene, LM Hammer, OH Hart, A Hymas, T Jones, GD K111an, DJ Lynn, GE Martin, D McIntyre, HH Perkins, RP Scoles, GE Stenger, VA Tisdale, WL Wright, N Page 77 General Subject Matter Suggested precautionary labeling for Forron 245 Forron 245 (M-1456) Data sheet of properties, health hazards and precautions for safe handling of materials Results of range finding toxicolo gical tests on M-1459. Formulation of K-7797 and K-7856 M-1459 formulation of K-7797 and K-7856 f )) ) ) Dow Number 0767505 * 0767506 * Date 590618 590216 Author Dow Dow 07676350767637* 590901 Dow Olson, K Oyen, F Scoi es, GE Recipient 07676380767639* l--,,i en- 590811 Oow Hoyle, HR Olson, KJ Oyen, F ) ) Distributees Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF Kilian, DJ Leasure, JK Luce, EN Lynn, GE McIntyre, HH Perkins, RP Scoles, GE Stenger, VA Tisdale, WL Wright, N Page 7) General Subject Matter M-1459 Toxicology work sheet M-1459 formulation of K-7797 and request for screening or applica tion testing Results of range finding toxicolo gical tests on M-1586 (Formulation containing Dowanol 97B70 Esters of 24D and 245T) (T2.30-156-1) f M-1586 (Data sheet of properties, health hazards and precautions for safe handling of materials) I) > ) Dow Number 0767640 * 0767641 * Date 590729 590611 Author Dow K0 Dow Scoles, G 0767642 * 590610 Dow Scoles, GW R e d pi ent Dow 01 son, KJ 0767643 * 590710 07676440767646* 07676470767649* 07676500767652* 590721 590727 590811 ^rrrA i- 4 CO Dow Greenhoe, NC KO Dow Greenhoe, NC KO Dow Greenhoe, NC KO Dow Hoyle, HR Olson, KJ Oyen, F Distributees Coulter, LL Dow Scoles, G Coulter, LL Dow Dosser, RC Heath, SB Maddox, JF White, LC General Subject Matter M-1586 (Toxicology work slbMtK\ (T2.30-156-1) Formulation containing the Dow*A' 97B70 Esters of 24D and 245T 1 (M-1586) (Request for screening application testing) Improved Esteron formulation M-1586 (Acute oral toxicity) (T2.30-156-1) M-1586 (Eye contact test) (T2.30-156-1) M-1586 (Skin contact Irritation\\ (T2.30-156-1) i M-1586 (Data sheet of properties, health hazards and precautions safe handling of materials) / .) 1 ) Dow Number 07677670767780* Date 600331 Author Dow Olson, KJ Scoles, G Recipient 07677920767793* 600128 0767794 * 0767824 * ^4 ! oo 600313 600216 Dow Hoyle, 1 Olson, 1 Oyen, F Dow Dow Olson, 1 Distributees Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF K11Ian, DJ Luce, EN Lynn, GE McIntyre, HH Oyen, F Perkins, RP Scoles, G Stenger, VA Tisdale, WL Wright, N Barrons, KC Boundy, RH or General Subject JSiSEf,'1 Results of range glcal tests on agricvlt ' cal formulation M-1639 killer type) lew tyfe* M-1639 (Veon brush k 1 ll\er (Data sheet o f p ro p e rty ' fe 1 hazards and precautions * handling of m ate rials) . tJHrpe ' I er j, M-1639 (Veon brush k m e ,.,,-* Safety data sheet rig^tl ^2 ?.c 0. Results of range f in d in g 1" g lc a l te sts on agrlcu ltu nii- ;) ) Dow Number Date Author Oyen, I Recipient 07678250767828* 600223 Dow Olson, KJ I ) Distributees Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH {fart, A ttymas, TA Jones, GD Kagy, JF Kill a n , DJ Luce, EN Lynn, GE McIntyre, HH Perkins, RP Scoles, G Stenger, YA Tisdale, WL Wright, N General Subject M a t f r g ,y cal formulatiom M-1683 (i 245 Type) Corrections 1n b1ochem1ci research laboratory repofe*!' (T2.30-177-1) Results oftff finding toxicological tej agricultural chemical foj M-1683 (Esteronj 245 Type) Results of range finding^ toxicological tests on B1 Acetonltrllo Decaborane (T23.14-94-2); Results of; finding toxicological tes Alpha Phenoxy PYoplonlc A ) Dow Number 07678290767830* Date 600126 07678310767841* 600000 07678510767852* 600126 0767853 * 0767854 * 0767872 * 600212 551108 600406 07678730767875* 600215 07679880767990* 611031 Author Dow Hoyle, HR Olson, KJ Oyen, F Dow EO NS O'Connor Scoles, GW Torkelson, TR Dow Hoyle, HR Olson, KJ Oyen, F Dow Dow Dow Wolf, MA Reel pient Dow McIntyre, H Dow Olson, KJ Oyen, F Dow Olson, KJ Oyen, F co ) D1stributees Dow Sales Wolf, MA Dow Hoyle, HR Dow Hoyle, HR i1 General Subject Matter M-1683 (Esteron 245T) (Data, of properties, health hazar precautions for safe handll materials) Toxicology work sheet, acuty' toxicity, eye contact test ,2TM contact irritation, single v \ f n 1 exposure record (M-1683) r In M-1683 (Esteron 245T) ( D a t a ^ s of properties, health hazarc^f'va precautions for safe handilyV* material s) AG chem formulation M-1683: ^ Esteron 245T, safety data Suggested precautionary labw' l-1i for M-1684 M-1684 (Esteron Brush K l l l e ^ ' Data sheet of properties, h^jjj hazards and precautions forr3 ! handling of materials v| M-2016 data sheet of proper health hazards and precauti safe handling of material s< \) ) Dow Number 07679940767997* Date 611106 07680100768025* 611117 Author Dow Hoyle, HR Oyen, F Plomer, ET Dow Olson, KJ Plomer, ET Recipient 07680870768103* ofcp* I 611108 Olson, K Oyen, F Hoyle, HR KS Scoles, GW Tompson, E ) Distributees Dow Hoyle, HR Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Falkensteln, W Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF Kill an, DJ Luce, EN Lynn, GE McIntyre, HH Oyen, F Perkins, RP Scoles, GW Shrader, Sa Tisdale, WL Wright, N Boundy, RH McIntyre, HH Perkins, RP Hart, A Jones, GD Scoles, G Page 83 General Subject Matter M-2115 data sheet of properties, health hazards and precautions for safe handling of materials * Results of range finding toxicological tests on M-2115, an agricultural chemical formulation containing 245T acid and tr1ethyl amine i Results of range finding toxicolo gical tests on agricultural chemclcal formulation M-2016 containing 35 percent Dowanol Ester 245T, Material safety data sheet Dow Number Date Author Recipient 07681040768143* 631129 Dow Lynn, GE Olson, KJ Distributees Gay, HH Tisdale, WL Luce, EN Greene, LM Shrader, SA Falkensteln, W Elshere, D Kagy, JF Barrons, KC Colby, RW K111an, DJ Lynn, GE Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Epstein, J Falkensteln, WJ Gordon, HL Greene, LM Hake, CL Hart, A Jones, GD Kagy, JF K111an, DJ Koerker, FW Luce, EN Lynn, GE McIntyre, HH Mull 1son, WR Norton, TR Results of range finding t glcal tests on Verton T h^ (M-2137) a formulation con . Dowanol Ester of 245T TT her/ i com* j 'o'e 7 )) ) Dow Number Date Author Recipient 07682360768254* 620403 Olsen, KJ Oyen, F Vanvalkenburg, W 0768240768241* H-4 M T3.-A FO 620323 Olsen, KJ Oyen, F Hoyle, HR ) Distributees Oyen, F Shrader, SA Wilson, AW Wright, N Boundy, RK McIntyre, HH Perkins, RP Hart, A Wright, N Lynn, GE Jones, GD Barrons, K Yanvalkenburg, V Brown, R Gay, HH Wilson, AW Luce, EN Greene, LM Shrader, SA Falkensteln, WJ Nash, HA Colby, RN K1l1an, DJ Elshere, D Kagy, JF Boundy, RH McIntyre, HH Perkins, RP Hart, A Wright, N Lynn, GE General Subject Wat Results of tox. tests dowanol esters Ifl ker on osene Data sheet for M2235 ) Dow Number Date Author Recipient 0768243768244* 611108 Vanvalkenburg, W Olson, KJ ( ) Distributees Jones, GD Barrons, H Vanvalkenburg, V Brown, R Gay, HH Wilson, AW Luce, EN Greene, LM Shrader, SA Falkensteln, WJ Nash, HA Colby, RW K1l1an, DJ Elshere, D Kagy, JF Johnson, JE Boundy, RK McIntyre, HH Perkins, RP Hart, A Wright, N Lynn, GE Jones, GD Barrons, K Vanvalkenburg, V Brown, R Gay, HH Wilson, AW Luce, EN Greene, SA Falkensteln, WJ Nash, HA General Subject Matter Cover letter with sample for testing <P UPDATED INDEX OF C O N FIDENTIAL DOCUMENTS )> Dow Number Date Author Recipient 07682620768263* 0768264 * 07682680768269* 620323 620300 720416 Olson, KJ Oxen, F Hoyle, HR Dow Wolf, MA Hoyle, HR 07682700768271* 07682970768299* 720413 630108 07683000768301* 0768302 * M 0768303** 0768304* at 710400 630507 720328 Wolf, MA Dow Hoyle, HR Olson, KJ Oyen, F Dow Dow D1stributees Colby, RN K1l1an, DJ Elshere, D Kagy, JF General Subject Matter M-2235 (data sheet of proper health hazards, and precaute safe handling of materials)'-'' M-2235 (safety Informati on Y* Verton CE (data sheet of p ties, health, hazards, and rcautions for safe handling "cmaterials) Verton CE (medical Informate M-2422 (Data sheet of propofor safe handling of materia Esteron 245 concentrate Esteron 245 concentrate {Sa^spec1f1cat1on) Esteron 245 concentrate bru*? weed killer (Material safety sheet) ;) ) Dow Number 07683050768306* 07686800768699* Date 780401 660526 Author Dow Recipient Dow Stevenson, GT 0768961768962* 0768963768964* 0768965768966* 07689840769027* 610601 580630 610531 660510 V"4 I 'cn Olson, KJ Oyen, F Hoyle, HR Wolf, MA McCollister, DD Hoyle, HR Dow Dow Lynn, GE Olson, KJ ) Distributees General Subject Watter'- Esteron 245 coicentrateR ^ weed killer (Material sfc^ sheet) ^ Dow A summary of acutte oral1 Haagsma, TA LD50 studies 1a poultry^ ^ BLS TOX-37 thru T0X-S6 InclV'X GTS (Report GH-A 186)) KJO Prod. Plan Target Team Mgr. Robinson, VB RJS RMS RVJ Safety data sheet for E s \ v OS Safety data sheet for Ris' centrate (M-2157) Barrons, KC Boundy, RH Dow Elshere, D Falkensteln, WJ Hart, A Safety data Information i * 245 OS > Toxicological properties* blclde formulation) talnlng 4-am1no-356-tr1<ifl1' ^ ^ plcollnlc acid, fs3Doctyl'!T\y! 245T polypropylene glycoVV t ether ester ) ) Dow Number Date Author Recipient 0769080 * 001216 Dow Getzendaner, ME Herman, JL Moss, RD ' )I ) i Distributees Holder, BB Johnston, RV Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McCollister, DD McIntyre, HH Moss, RD Mullison, WR Norton, TR P1tman-Moore Shrader, SA Wilson, AW Wright, N Barrons, KC Baurledel, WR Dow Dowell, FH Hanson, RG Hymas, TA Johnston, RY Kagy, JF Laning, ER Ludwig, PD Moss, RD Osborne, DW Popoff, FP Rldner, JM Rowe, VK Seymour, KG General Subject Matter Page 89 A residue study plcloram and 245T 1n grass from application of M-3060 formulation (GH-C 343) ))I ) ) Dow Number Date Author Recipient 07690810769082* 07690830769085* 670410 661205 07690860769087* 661108 07690880769094* 07691600769162* 660816 670316 Dow Dow Olson, KJ Oyen, F Wilson, H Dow Hoyle, HR Olson, KJ Oyen, F Wilson, H Dow Wilson, H Olson, KJ Oyen, F ^ is n < 4 GO )' ) > Distributees Shaver, RJ Spalding, JL Williams, CS Dow Lynn, GE Boundy, RH Buerge, TE Dean, P Dow Elshere, D Holder, BB Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH General Subject Matter ' M-3060, safety data sheet Results of range finding toxi. gical tests on Esteron O.S. (M--3094) (T2.3094-1) Esteron 245 O.S. (Data sheet properties, health hazards art precautions for safe handlinc materials) Esteron 245 O.S. (M-3094) Tox logy work sheets -vToxicological properties andcv industrial handling hazards o Tordon 105 mixture (T2.MO-3132-1) o J Dow Number Date Author Recipient 07691630769179* 660000 07692680769271* 671224 07692720769297* 680104 Dow Tinker, B Wilson, H Dow McCollister, DD Olson, KJ Dow Lynn, GE 01 son, KJ rf* 0769351!"* 0769352* CD 690121 Dow Hoyle, HR Distr1butees Moss, RD Sheetz, DP Shrader, SA Wilson, AW Wright, N Boundy, RH Dean, P Dow Elshere, D Holder, BB Jones, GD Kagy, JF Luce, EN McCollister, DD McIntyre, HH Moss, RD Olson, KJ Robinson, VB Sheetz, DP Shrader, SA Wilson, AW Wright, N General Subject M$ Tordon 105 mlxtur worksheet) Tordon 144 mlxtur sproperties, healt precautions for Toxicological per Industrial handll Tordon 144 mlxtur M-3199X Tordon bicide data sh Dow Number Date Author Norris, JM Recipient 07693530769354* 700130 07693550769356* 07700430770058* 681213 571122 Bjork, C Dow Gowell, JH JBD Loucks, MF Nagele, RE Newport, JJ Seymour, KG Sheldon, HW Stein, JS Talcott, AT Williams, CS Wolf, MA Dow Norris, JM Dow Olson, KJ ) ) Distributees General Subject Matter Page 92 health hazards and precautions for safe handling of materials (T2.M0-003199-1 ) Tordon 225 herbicide release to sales Hum Allinson, RL Athay, RM Beshgetoor, AW Boundy, RH Colby, RW Dosser, RC Dow Elshere, D Gay, HH Greene, LM Hart, A M-3199X Tordon 225 herbicide (T2.M0-003199-(1)), safety data sheet Results of range finding toxicolo gical tests on Brush Killer X, Weed Killer X and Brush Killer TX * Dow Number Date Author Recipient 07700440770045* 571115 07700470770048* 571115 0770049 * 000000 Dow McColHster, DD Olson, KJ Peterson, JE Dow McColHster, DD Olson, KJ Peterson, JE Dow 07700500770052* 571115 Dow McColHster, DD Olson, KJ Peterson, JE ; Distributees Hymas, TA Jones, GD Kilian, DJ Luce, EN Martin, D McCollister, DD McIntyre, HH Mussel1, DR Perkins, RP Tisdale, WL White, LC Wright, M General Subject Matter Page 93 Brush Killer TX (Data sheet of properties, health hazards and precautions for safe handling of materi als) Weed Killer X (Data sheet of pro perties, health hazards and pre cautions for safe handling of materials) Brush Killer X (Data sheet of properties, health hazards and precautions for safe handling of materials) Brush Killer X (Data sheet of pro perties, health hazards and pre cautions for safe handling of materi al s) 1) ) Dow Number 0770059 * 07700600770061* 07700620770063* 07700640770065* Date 560308 560424 560521 571115 07706650770684* 660526 Author Dow White, LE Dow Recipient Dow Dow McCollister, DD Olson, KJ Peterson, JE Dow Stevenson, GT Stock, BL 07817910781794* 501017 Dow Rowe, VK to Allen, WW Alquist, FC Britton, JW Dosser, RC Dow Dutton, WC Irish, FN Kagy, JF Lynn, GE ; ) ) Distributees BLS GTS KJO RJS RMS RVJ TAH VBR General Subject Matter Brush Killer TX (Request application testing). Brush Killer TX (Eye co test) Brush Killer TX (Skin c irritation) Brush Killer TX (Data s properties, health haza precautions for safe ha materials) A summary of acute oral LD50 studies in poultry TOX-37 thru TOX-66 incl 186) Results of skin irritat skin sensitization test on human subjects with (New Ester) (T2.30-3-1) ) ) ) Dow Number 0781795 * Date 500405 07817960781810* 530217 CJ! CO Author Dow REW Streeter, LE Dow Oyen, F Recipient Dow White, L Allen, WW AlUnson, RL Alqulst, FN Beshgetoor, AW Boundy, RH Britton, EC Britton, JW Collier, B Davidson, JH Dow Dutton, WC Gay, HH Gibson, J Greene, LM Heath, SB Johnson, JE Kagy, JF Kelly, JA Krlner, RR Luce, EN Lynn, GE MacCutcheon, SM Melass, VH Nation, HA 0t1s, CE Predergast Southwlck, L Sunderland, WW Vanhorn, JC Distributees General Subject Matter Y* Esteron 245T (Main lab ref0 sheet) \v|C Results of range finding i0' glcal tests on Esteron 24 (T2.30-3-2) Dow Number Date Author 07820850782091* 531030 Dow Oyen, F Recipient Walker, H White, LC Wright, P Zuhl, HH 0782092 * 530305 07820930782100* f. .--A 'm 530000 Dow Rowe, VK Spencer, HC White, L Dow Wolf, MA Wyse, H ) Distributees General Subject Matter Page Allen, WW AlHnson, RL Alqulst., FN Barrons, KC Beshgetoor, AW Boundy, RH Britton, EC Davidson, JH Dow Dutton, WC Gay, HH Greene, LM Kagy, JF Luce, EN Lynn, GE MacCutcheon, SM Prescott, RF Sunderland, WW White, L Wright, P Results of range finding toxlcolo glcal tests on Dow Brush Killer T Dow Brush Killer T (Request for biological test) Dow Brush Killer T (Acute oral toxicity) /I ! Dow Number 07821010782103* 07821040782112* 07821130782114* 0782115 * 07821160782117* Date 530000 530000 700721 000000 710714 07821180782119* 07821780782198* 710920 560501 Author Dow Wyse, H Dow Wyse, H Dow HCS Dow Recipient Dow Hoyle, HR Wolf, MA Dow Wolf, MA Dow McCollister, DD Torkelson, TR H"4 i-A aann Distributees Allinson, RL Beshgetoor, AW Boundy, RH Britton, EC Coulter, LL Dow Elshere, D Gay, HH Greene, LM Hart, A KilIan, DJ Luce, EN MacCutcheon, SM General Subject Matter Page 97 Brush Killer T (Eye irritation) Brush Killer T (Skin irritation) Brush Killer T, safety data sheet Brush Killer T (Medical information) Brus* killer T (Data sheet of properties, health hazards and precautions for safe handling of materials) Brus* Killer T (Medical information) Results of range finding toxicolo gical tests on M-631 (Esteron 245 type formulation) (BC T2.30-67-1 ) Dow Number Date Author Recipient 07821990782200* 580916 0782201 * 560504 Dow Hoyle, HR Torkel son, TR Dow 07822020782220* 560409 Dow McCollister, DD Wolf, MA II ) I Distributees Martin, D Scoles, G Sunderland, WW Wright, N Allinson, RL Beshgetoor, AW Boundy, RH Britton, EC Colby, RW Dow Elshere, D Gay, HH Greene, LM Hart, A Kagy, JF Kelly, J K111an, DJ Luce, EN Lynn, GE MacCutcheon, SM Sunderland, WW Wright, N General Subject Matter Page 98 Esteron 245 type formulation (M-631) (Data sheet of properties, health hazards and precautions for safe handling of materials) M-631 (Esteron 245 type for mulation) (T2.30-67-1), safety data sheet Results of range finding toxicolo gical tests on 2 formulations of Reddon (M-640 and M-713) / I )! ) >> Dow Number 07822850782306* Date 560503 Author Recipient Dow Lockwood, D McCollister, DD Torkel son, TR 07823790782393* 560702 Dow Lockwood, D McColHster, DD Olson, KJ !-a zn -a Distributees AlHnson, RL Beshgetoor, AW Boundy, RH Britton, EC Coulter, LL Dow Elshere, D Gay, HH Greene, LM Hart, A KlUan, DJ Luce, EN MacCutcheon, SM Martin, D Scoles, G Sunderland, WW Wright, N AlHnson, RL Alqulst, FN Barrons, KC Beshgetoor, AW Boundy, RH Britton, EC Colby, RW Dow Elshere, D Gay, HH Greene, LM Hart, A Kagy, JF Kelly, JA K111an, DJ General Subject Matter Results of range flmeting to)^ gleal tests on M-69^ (Esterogn Brush Killer type fcornulat1 ogn (T2.30-66) t Results of range flmding toxicological tests Esteron Brush Killer OS (M-7726) (T2.30-71-1) ) I) ) Dow Number Date Author Recipient 07869420786954* 07869550786975* 07870000787030* 08903940980398* 09703300970343* 09790330979047* 000000 000000 680122 000000 700901 691215 Dow Dow Delong, HC Dow Blair, EH Dow Bailey, RE Pv. cm oo Distributees Luce, EN Lynn, GE MacCutcheon, SM Sunderland, WW Wright, N Blair, EH Fernandez, JB Johnson, JE Moss, RD Chamberlain, LC Peterson, LI Strojny, EJ Tobey, SW Hillary, BB Rehurg, CE Moyer, JR Pumpelly, CT General Subject Matter 24D Esters-process Information" Direct Ester process Acid Ester operating Instructor0 489 Bldg General process description, VHI process Chemistry of the Dow agrlcultur^ department Miniplant preparation of 2,4-1) a 2,4,5-T ) ) Dow Number Date Author Recipient 09791880979210* 09794110979416* 09794290979430* 0979686 * 0979732 * 0979733 * 0979734 * 0979735 * 680000 670828 670906 670915 670914 670914 670914 670914 Dow Seidel, EM Tacy, W Seidel, EM EMS EMS WHH EMS EMS pSst Q ' ) . I Distributees Poffenberger, N Haberstroh, WH Deline, DD Ayers, JE Woodward, RE Jones, 6D Blue, RD Vanwestenburg, JA General Subject Matter Page 101 Historical overview of chloracne experiences, Includes process information Agent Orange related costs and capacity Process flow chart with recommended raw material unit ratios for Orange Flow chart with costs and capacity for making Agent Orange Trichlorophenol plant unit ratios Dlchlorophenol plant unit ratios t J * Chloroacetic acid plant unit ratios Crystalline chloracetate acid unit ratios Dow Number 0979736 * 0979737 * 0979738 * 09798830979884* 0979885 * Date 670914 670914 670914 000000 670311 Author EMS EMS EMS Dow Delisle, NG Recipient 09798860979887* 09799270979934* 0979935 * 09799890979994* 0980024 * 670829 670411 670427 670417 670130 Delisle, NG Delisle, NG Del Isle, NG Dellsle, NG EMS Jossl, JA I ) Distributees Page 102 General Subject Matter Butyl chloroacetate plant unit ratios Butyl ester 24D plant unit ratios Butyl ester 245T plant unit ratios Process flow chart indicating costs and capacity for Agent Orange production Process flow chart indicating costs and capacity for Agent Orange production Process flow chart indicating costs and capacity for Agent Orange production Agent Orange production flow charts ' showing capacities Chart showing capacity and costs for Agent Orange production Flow sheets on 24D butyl ester acid Orange 24D1chlorophenol block flow sheet .) Dow Number 09800850980086* 0980089 * 09801780980188 Date 661227 670130 690307 Author Gilbert, PW EMS GTG Wen, RY Recipient 09803200980341* 660121 09803940980398* 0980971 * crs 000000 000000 Amstutz, FC Highhill, CA Koslnski, JE Delong, HC Dow Dow J) ) Distributees Look, AT Sheetz, DP Pumpelly, CT Hennis, HE Thompson, CJ DeMott, DN McGee, TW Fernandez, JB Llndy, L Molehouse, D Wlsner, R Wen, RY DeLine, DD Woodward, RE Seidel, EM Thurston, DH Kellom, DB Page 10 General Subject Matter 245-Trichlorophenol block flow chart Ester production product Orange Manufacture of 24D, 245T and 2,4,5-Tr1 chi oropheno^propl on1 c Acid: a literature survey Dow customer - Weed killer for- * mulating plant General process description, 24D process Mexico Phenoxy Ester process flow chart Dow Number 09809940981006* 09810120981024* 09810250981030* 09810310981036* 09813660981372 Date 750000 691030 000000 691022 620227 Author Dow Recipient Dow Dow Haberstroh, WH Fernandez, JB 0981474 * 0981484 711209 690227 Hoff, RC Williams, CS Chase, FI Woodward, R Blosser, KC Scoi es, GW 2 Illegible White, LC DeLong, HC Chase, FI Loucks, MF Hawley, HM Distributees Doser, RC Prescott, RF Sculatl, JJ Hillary, BB Johnson, D Hlghhill, CA Hoff, RC Williams, CJ Chase, FI Woodward, R, Blosser, KC Scoi es, GW 2 Illegible White, LC DeLong, HC Chase, FI Loucks, MF Scheddel, RT I General Subject Matter Cost data, process 1nfoml3^'tli M Technology review Flow chart for 2,4-D procssss 1 Projected book costs to 1 H H and 2,4-D) 1969 accoppi 1sftm(,,'*! and goals, 1970 G & P 'W The preparation of Esters 01,l Phenoxy Acetic Acid 1 Brush killer, LV4T, M3508y U duct specification, 12662- ^ 24D, Butyl-Isopropyl E s t e H ^ > 50-50 mix Dow Number Date Author Sheldon, HW Talcott, AT Hoi deman , GE Recipient 0981538 * 0981590 701005 690227 Chase, FI Loucks, MF Tait, SR Woodward, RE Hoi deman, GE Hawley, AM Seymour, KG Talcott, AT MacDonald, LA Williams, JL Loucks, MF Stobby, GE White, LC Hawley, HM Sheldon, HW Talcott, AT Hoi deman, GE 0981591 0981596 671011 690227 Hawley, HM Sculatl, JJ White, LC Williams, JL Loucks, MF Distributees Sheldon, HW Talcott, AT Hoi deman, GE Relgler, PF McCoy, WJ Chase, FI Loucks, MF Ta1t, JR Woodward, RE Hoi deman, GE Hawley, HM Seymour, KG Talcott, AT MacDonald, LA Williams, JL Loucks, MF Stobby, GE White, LC Hawley, HM Sheldon, HW Talcott, AT Hoi deman, GE Relgler, PF Scheddel, RT Williams, JL Loucks, MF General Subject M a t t e r y Esteron Ten-Ten, M3503,?>, v only 245T - product speclflcaagfI P87523 245T - raw material specifici. 245T - product specificai**^r P87523 )) ) Dow Number Date Author Stobby, GE White, LC Hawley, HM Sheldon, HW Talcott, AT Hoi deman, GE Recipient 0981597 0981617- 0981620 0981895 * 0981896 0981899 0981900 671011 680207 690227 671011 671011 690227 White, LC Sculatl, JJ Hawley, HM Kubiak, CJ VanHorn, R White, LC Sculatl, JJ Hawley, HM White, LC Sculatl, JJ Hawley, HM Williams, JL Loucks, MF Stobby, GE White, LC Hawley, HM Sheldon, HW Talcott, AT ; Distributees Stobby, GE White, LC Hawley, HM Sheldon, HW Talcott, AT Hoi deman, GE Relgler, PF Scheddel, RT Williams, JL Loucks, MF Stobby, GE White, LC Hawley, HM Sheldon, HW Talcott, AT I] General Subject Matter 245T - raw material spec^ec l 245T - Butyl Esters - an^na method - 87554A M-3393 - 2nd revision 245T - raw material spe< uy 245T - raw material spec^ff 245T - product speclfleiM f i Dow Number Date Author Hoi deman, GE Recipient 0981901 11194991119500 11195951119599* 710316 670317 650315 Gill, HH Rei gl er, PF Loucks, MF Tait, SR Chase, FI Woodward, RE Hawley, HM Hoff, RC Talcott, AT MacDonald, L Hol deman, GE DeLong, HC White, LC Hawley, HM Anderson, RE Del isle, NG ) } Distributees Hoi deman, GE Relgler, PF Scheddel, RT McCoy, WT Gill, HH Relgler, PF Loucks, MF Talt, SR Chase, FI Woodward, RE Hawley, HM Hoff, RC Talcott, AT MacDonald, L Hoi deman, GE Coulter, KE Graves, HE Wolf, RR Goergen, GG Lueck, A Dylewskl, S Trapp, W Sauers, R Poffenberger, N Hutchenreuther, N Wappenhensch, CA Morello, VS Wehn, WR General Subject Matter Page 107 245T, Butyl Esters production specification N-Butyl 2,4,5-Trlchlorophenoxyacetate raw material specifica tion Trlchlorophenol plant scope of project X' > Dow Number 11199431119944* 11199471119952* Date 670420 670417 Author Dow Dow Reef pfent Nummy, WR 11199531119960* 111 99611119968* 1119969 * 670410 670419 000000 Dow Dow Dow 1119990H* 1119991* 660614 McCoy, WJ Bryant, CA ))) i li Distributees Staehling, EC Kennett, WW Putnam, MS PI etcher, DE Bosscher, H Timm, WC Coulter, KE Tacey, WJ Hensley, EF Gunkler, AA Kennett, WW Deline, DD Goergen, GG Carlson, RG Bender, SL Putnam, MS Nielsen, WH Staehling, EC Putnam, MS Vanarsdale, JD Van Arsdale, JD Gill, WM Hanson, KY General Subject Matter Page 108 Agent Orange proposal listing capacity of non-herbicide product Orange information for development of reply to H.G. Fredricks letter dated 670331 Costs and capacity Information about Agent Orange Costs, capacity and technical information about the proposed production of Agent Orange Tetrachlorobenzene capacity information | k. % 245T capabilities ) ; Dow Number 11200901120092* 11241 SO IT 241 60* Date 671220 650302 Author Heath, WO Cornell, JL Anderson, RE Recipient Koster, W 11273971127398 641208 Johnson, D ) ) Distributees General Subject Matter Page 109 Coulter, KE Dylewski, SW Goergen, GG Haberstroh, WH Lueck, AF Poffenberger, N Sauers, RC Trapp, WB Wappenhensch, 0 West, KD Wehn, WE Widiger, AH Graves, HE Wolf, RR Delisle, NG Hutchenreuther, C Morello, VS Beyer, DG Harris, JS Denisik, R Hay, JM Hillary, BB LeSueur, RW Maunder, WG Morrison, JA Mul holl and, RS Smart, JL Project conference 14 Billion pounds per year. Trichlorophenol plant Job 50175 Condensation of Butyl Diehloroacetate with Sodium 24-Dichlorophenate > s )) ) ) > ) Dow Number Date Author Recipient 12321171232129* 12321301232143* 570806 600331 Dow McCollister, DD Wolf, MA Dow Olson, KJ Oyen, F 12323551232378* 571122 Dow McCollister, DD 14168 )) ) Distributees Smy, K6 Sundberg, FA Veach, RH Young, DM Barrons, KC Boundy, RH Colby, RW Dow Elshere, D Gay, HH Greene, LM Hammer, OH Hart, A Hymas, TA Jones, GD Kagy, JF Kilian, DJ Luce, EN Lynn, GE McIntyre, HH Scoles, G Stenger, VA Tisdale, WL Wright, N Allinson, RL Allison, WE General Subject Matte,. ---------------------- Results of range find gical tests or M1086^ig(. 24D al kyl ami ne formuj. : t Results of range finch gical tests on agricuy*g;, cal formulation Ml63$"ttirr. Killer type) fVec Results of range flndi. gical tests on Brush i: )) ) ) Dow Number Date Author Olson, KJ Recipient 12847281284733 12881531288155* ! 72 CD 650622 700130 Tiffany, PA G111, HH Rldner, JM Williams, CS Loucks, MF Wolf, MA Seymour, KG Bjork, C ) ) im Distributees Athay, RM Beshgetoor, AW Boundy, RH Colby, RW Dosser, RC Dow Elshere, D Gay, HH Greene, LM Hart, A Hymas, TA Jones, GD K111an, DJ Luce, EN Martin, D McIntyre, HH Mussel 1, DR Perkins, RP Tisdale, WL White, LC Wright, N General Subject Matter r .ft XIliei Weed Killer X and Brush K"? Analytical method for deteif^^ | of TCDD 1n 2,4,5-T by GLC 1 Tordon 225 - Release to ))) ) Dow Number 1298300 * 12983011298302* 1298303 * 12983041298305* 1298306 * 12983071298309* 12983101298312* Date 640921 000000 000000 681030 741202 730315 490720 12983131298315* 680826 Author Dow EMS Dow Dow Dow Erickson, AC Dow JNJ Dow Dow BFW WJC Luce, EN Waling, BF Dow JJ RH Stobby, G Recipient Dow Schrauf, B 12983161298320* 731128 Dow Messing, S Dow Hart, JP 14171 D1strlbutees Colby, A Dow Hoi deman, GE K11ey, L Shrader, S Wengert, GB Arestin, Ble1we1ss, J Page 11 General Subject Matter Dowanol Ester of 245T (Physical properties data sheet) SHvex (Physical properties data sheet) 24D NA salt monohydrate (Physical properties data sheet) 245-Tr1chlorophenol (Physical pro perties. data sheet) 245T (Physical properties data sheet) Freezing point molten 24D HgO 24D report sheet (Main lab No. SSR 146-851) Herbicides, vapor pressure datak (Analytical laboratories report* AL 79-202) 24D acid ester process solub1l1t1es ) Dow Number Date Author Recipient 12983211298322* 12983231298326* 1298328 * 670327 691022 710917 1298329 * "s CnD 720615 Dow Stull, DF Walker, 1: Dow Sinke, C Stull, DF Dow Gilbert, * Hawley, Hoi deman, Loucks, IF MacDonalc. j Relgler, *= Talcott, r Blosser, C Chase, R 1/ DiSTTEE Chas. " Dhinare. Dow Habe-srr Jones Lafe*r Martf-*. Martn_ ' Mill?- Mints * Mores ~ Yea- . Dow Fernae. Holc&Bt E Dow G1lh~s* Hawlet Holds. E Louce. * MacDne-s _r Reig*te- Talcxr. Tree. B1o s r Chase " General Subject Matter I p. "'rermal data for process step synthesis of 24D (HL-304) ^eat of reaction of dimethyl a* Ian aid 24D (HL-527 ) '1* 1,4-Dichlorophenol, technical' <il product specification) ^ 55T propylene glycol butyl e.t\JJMM esters (Product specificationp II ) Dow Number Date 1298330 * 1298331 * 720615 710118 1298332 * 730412 OD Author Dow Flannery, RF Fraser, JM Gill, HH Hoff, RC Hoi deman, GE Talcott, AT Woodward, R Dow Recipient Chase, FI Dow Hawley, HM Hoi deman, GE Loucks, MF MacDonald, LA Relgler, PF Seymour, KG Tait, SR Talcott, AT Woodward, RE Blosser, KC Chase, FI Dow Flannery, RF Fraser, JM Hoff, RC Hoi deman, GE Seymour, KG Talcott, AT Woodward, RE Distributees Dow Flannery, RF Fraser, JM Gill, HH Hoff, RC Talcott, AT Woodward, R Chase, FI Dow Hawley, HM Hoi deman, GE Loucks, MF MacDonald, LA Reigler, PF Seymour, KG Tait, SR Talcott, AT Woodward, RE Blosser, KC Chase, FI Dow Flannery, RF Fraser, JM Hoff, RC Hoi deman, GE Seymour, KG Talcott, AT Woodward, RE General Subject Matter 245T propylene glycol b u t y ^ esters (Sales specificati o \ v .V . Formula 40 Weed killer M-3 (Product specification) 55 DMA-6 unsequestered 11-2255* (Product specification) I )) ) \) Dow Number 1298333 * Date 710601 1298334 * 000000 Author Chase, FI Dow Hawley, HM Hoi deman, GE Loucks, MF MacDonald, LA Reigler, PF Seymour, KG Tait, SR Talcott, AT Woodward, RE Dow Recipient 1298335 * 1298336 * 000000 000000 Dow Dow 1298337 * 1298338 * 000000 000000 Dow Dow Distributees Chase, FI Dow Hawley, HM Hoi deman, GE Loucks, MF MacDonald, LA Reigler, PF Seymour, KG Tait, SR Talcott, AT Woodward, RE General Subject Matter DMA-6 sequestered H-3637 (Prp^ specification ','JtC Propylene glycol butyl ethers^ esters of Silvex (Physical properties) Isooctyl esters of 245T properties) ^ Low volatile esters of &5T/C sales grade 245T, propylenes (C3H60 to C9H1803) butyl ethf esters (Physical poperties)i Isooctyl esters of 240 (Pkysji properties) N-Butyl ester of 240 (Piys1qik\ properties) TM Dow Number 1298339 * Date 000000 1298340 * 710316 1298341 * 720117 1298342 * 000000 Author Dow Dow Blosser, KC Chase, FI Dow Flannery, RF Gill, HH Hoff, RC Hoi deman, GE Scoles, GW Talcott, AT Woodward, RE Dow Recipient 12983431298344* 611017 1298345 * 000000 Dow Hoyle, HR Olson, KJ Dow 12983461298347* 570927 Dow Hoyle, HR Peterson, JE Distributees Blosser, KC Chase, FI Dow Flannery, RF Gill, HH Hoff, RC Hoi deman, GE Scoles, GW Talcott, AT Woodward, RE General Subject Matter 24D Butyl esters (Physical properties) 24D propylene glycol butyl e ester (Product specification 24D (Product specification)'^ Tordon 101 mixture (Data she^|> properties, health hazards a/TM\l precautions for safe handl 1ncv.r materials) Dowanol PIB mix ester of 241)^ f(|h sheet of properties, health'' hazards and precautions for' handling of material si 245-Tr1 chi orophenol (Data she^Cf properties, health hazards at^r precautions for safe handliiig! M materl al s) ,, . 24D (Data sheet of propertied' health hazards and precaution^ f safe handling of materials) )) I J Dow Number 12983481298349* 1298350 * Date 000000 741202 1298351 * 750109 1298352 * 700801 1298353 * 1298354 * 741211 750123 1298355 * 750123 1298356 * 750123 12983571298360* 741204 Author Dow Recipient Bethke Boust, HF Dersnah Dow Jones, W Dersnah Dow Fey, K Abegg, CF Dow Harris, W Higgins, HS Woznlak, LJ Dersnah Dow Jones, JN, Jr. Dersnah Dow Jones, JN, Jr. Dersnah Dow Jones, JN, Jr. Dow Jones, J Distributees General Subject Matter Hre Consequences of overexposi chemicals 1n 489 building-'3 ^ B1s-(24D) (Reactive cheimlc hazard data) id iid; Ethylene Glycol W/ 24D aci've molten 24D process (Reacti mlcal hazard data) i3' an 24D (Reactive chemical ha? data) DE waste treatment plant eccee<h Waste treatment, butyl est^ct 24D, distillation feed IRe chemical hazard data) tei ;H1%h Waste treatment, butyl esalta 24D solvent (Reactive chem hazard data) est. , a-fct Waste treatment of butyl e> fc- 24D tars (Reactive chsvica / data) e^ ' '9 Alcohols, and molecular we data summary )) j Dow Nimber 12983611298362* Date 710526 12983631298369* 12986031298605* 12986061298607* 730000 000000 650119 12986081298609* 650125 12986101298611* 12986121298614* 12986151298617* 740300 780601 780601 -si Author Boggs, GU Dow Dow Southwlck, L Dow Dow Hoyle, HR Olson, KJ Oyen, F Dow Hoyle, HR Olson, KJ Dow Dow Recipient Dow Dunlap, R Haberstroh, W Higgins, HS Thels, JM Dow General Subject fetter Direct ester "T" wastes 489 (Analytical labara report AL28-830) Kuron S H v e x herbfcffde to gain acceptance ffln< mgmt 5(2), 18-24) Properties and hazards-"^ points of various prod ' Tordon 50D formulatflon t of properties, health "ft1'' precautions for safe Tordon 101 mixture trtee&fcj killer (Material saffetiij sheet) (Form 336-15B-7^f Tordon (R) 101 ixtaires^ brush killer (Miatarfialrr sheet) Tordon (R) 101 arixtuire-j* brush killer private m (Material safety fltarttavi Dow Number 12986181298620* 12986211298623* 12986241298625* Date 780601 780601 660412 12986261298627* 12986281298629* 740300 660201 12986301298632* 12986331298634* 780601 671031 12986351298636* -1298637' 1298638* \ 3. 760800 780601 Author Dow Dow Recipient Dow Hoyle, HR McCol lister, DD Olson, KJ Dow Dow Hoyle, HR McColHster, DD Olson, KJ Dow Dow Hoyle, HR Norris, JM Olson, KJ Dow Dow General Subject Matter Tordon (R) 101R forestry (material safety data shee^et Tordon (R) 155 mixture brrfUf' killer (Material safety dar*1 sheet) 1 Tordon 155 (Data sheet o'0^ perties, health hazards ariff16 cautions for safe handlind?? ' materials) (T2.MO-2993-1 )*' Tordon 155 mixture brush (Material safety data shee^1, Tordon 202 mixture (Data s ^ ' properties, health hazards^.* precautions for safe handr* materials) (T2.MO-2861-1) ' Tordon (R) 202C mixture (Material safety data sheer*J Tordon 212 (Data sheet of ties, health hazards and p cautions for safe handling? materials) (T2.M0-320O-1V Tordon 212 mixture herblci^if > (Material safety data sheer^ 1 336-161-76) Tordon (R) 212 mixture herl?? (Material safety data sheer* t \i Dow Number 12986391298640* 12986411298643* 12986441298651* Date 771001 780601 750811 12986521298653* 700514 12986541298655* 750600 12986561298658* 12986591298660* 780601 710422 12986611298662* 710917 Author Dow Recipient Dow Dow Gutenkunst, V Porter, DF Skelly, NE Dow Hoyle, HR Norris, JM Dow Dow Dow Hoyle, HR Norris, JM Dow Hoyle, HR Wolf, MA i" CD General Subject Matter Tordon (R) 225 herbicide (M^ > safety data sheet) Tordon (R) 225E mixture ftieri^ (Material safety data sfteetf,^ Analytical method Tondon 22,` ture herbicide by liquid chj tography (Method 871 431 ) Tordon 472 herbicide (fDa-ta^a^. of properties, healthi i a z a r ^ ^ precautions for safe toaodflizi** materials) (BC12.M0-3427-l7^ . Tordon 472 herbicide safety data sheet) (Fa>n 336-166-75) Tordon (R) 472 weed IdTller-,,. (Material safety data sfteet^j DMA4 (Data sheet of piropert^^. health hazards and precauiitiji^' safe handling of materials\\ (NB T2.MO-3538-1) 245T Dowanol 97B ester of properties, health) precautions for safe teKfflifi^ materials) (K-7856 NaOTSJI 'l ) \ Dow Number 12986631298664* Date 790310 12986651298666* 760823 1298667 * 12986681298670* 12986711298672* OOOOOO 760600 71CH17 12986731298674* 650125 12986751298676* 6909Q9 12986771298678* 650119 GO o Author Recipient Dow Silversteln, LG Wolf, MA Dow Langner, RR Wroblewski, D Dow Lamott, S Dow Rafos, G Dow Hoyle, HR Wolf, MA Dow Hoyle, HR Olson, KJ Dow Hoyle, HR Norris, JM Dow Hoyle, HR Olson, KJ Oyen, F Distributees General Subject Matter 24D Triisopropanol amine sal tit #_ sheet of properties, health n hazards and precautions foc-ss*, handling of materials) (K-$$ DMA-6 (Data sheet of properttta. health hazards and precautlonus', safe handling of materials) 'r (M--3637) Cover memo for data sheets Tordon 212 mixture herbicide (Material safety data sheet) (Form 336-161-76) 245T Dowanol 97B ester (Data ihu. of properties, health hazards precautions for safe handling materials) (K-7856 NBT25.14-T0$jj Tordon 101 mixture (Data sfteetofr properties, health hazards and precautions for safe handling j# materials) (T2.MO-2439-1) Tordon 472 herbicide (Data shee of properties, health hazards precautions for safe handling 0 materials) (BC T2.M0-3472-1) Tordon 50D formulation (Data shtt* of properties, health hazards ar> precautions for safe handling of materials) (BC T2.M0-2777X-1 ) \) ) Dow Number 12986791298680* Date 660412 12986811298682* 751009 Author Recipient Dow Hoyle, HR McCollister, DD Olson, KJ Dow Hoyle, HR Yakel, HO 12986831298684* 700319 Dow Hoyle, HR Norris, JM 1298685 * 12986861298689* 1298690 * 750711 750711 711116 12986911298692* 000000 Dow Krumel, KL Dersnah, H Dow Brown, M Dow JL Robb, J Dow Dow Krumel, Kl ) ) Distributees II General Subject Matter Pag materials) (T2.MO-2993-1) M Tordon 212 mixture herbicide (Dr sheet of properties, health (i hazards and precautions for saf& handling of materials) (HET | M-3179-(2)) Tordon 212 mixture herbicide (D: sheet of properties, health w hazards and precautions for saf<i handling of materials) ^ (T2.M0-3179-1) 24D (Reactive chemical hazard data) +tj Dust explosion properties of 2 4^ acid (Analytical report) 2>( DMA-6 (unsequestered) (Reactlv chemical hazard data) 24D (Summary of chemical reac-,, tllvlty precautions amd properties) )) ) Dow Number 1298693 * Date 741031 12986941298695* 690716 12986961298697* 1298698 * 690716 750206 12986991298700* 1298701 * 691003 710830 12987021298703* 690716 Author Dow Hebbourn, R Kerby, JE Dow Dullap, RL Mandrel!, ME Dow Dunlap, RL Mandrell, ME Bethke Dersnah Dow Hoi deman, G Keeney, N Vanhorn, R Dow Gilbert, PW Mandrel 1, ME Dow CJR JRL RSS Dow Dunlap, RL Mandrell, ME Recipient boI -~A, CO ) ; Distributees I) Page 124 General Subject Matter 24D PGBEE (Reactive chemical hazard data) Tordon 212 mixture (Summary of chemical reactivity precautions and properties) Tordon 101 mixture (Summary of chemical reactivity precautions and properties) Tordon 101 R (Reactive chemical hazard data) Tordon acid (Summary of chemical reactivity precautions and properties) Tordon 225 (Reactive chemical hazard data) Tordon 155 mixture (Summary of chemical reactivity precautions and properties) Dow Number 12987041298714* Date 710125 1298715 * 710801 12987161298717* 12987181298719* 1298726 * 1298766 * 12991651299169* 12992561299265* 12992671299270* 13394201339423* 690627 690718 000000 000000 000000 000000 000000 650810 Author Dow Prophet, H Stull, DR Dersnah, H Dow McCarty, WM Dow Gilbert, PW Mandrel 1, ME Dow Gilbert, RW Mandrel 1, ME Dow Dow Dow Dow Dow Barrons, KC Lynn, GE Recipient ) ) Di stributees Page 125 General Subject Matter Studies of hazardous chemicals and their reactions, kinetics of che mical destruction by burning (NCT-5007) Esteron 245 CONC (Reactive chemi cal hazard data) Dowanol PIB esters of 245T (Summary of chemical reactivity precautions and properties) 24D TIPA mix (Summary of chemical reactivity precautions and properties) Chioro-Pyr1dines dept. Block flow H2 O form. Tordon Formulations, special formulations area Tordon operations manual TIPA and TIPA 2D storage and transfer from 489 building Esteron TR2 (Release to Sales 12) Dow Number Date 13418341341853* 700422 Author Recipient McCoy, WJ Southwick, L Wolf, MA Vanvalkenburg,W Sachs, SB Branaman, J Gill, WM Delong, HC Matutz, H Davis, H Corbin, WL Johnson, J CEO DEP Fauver, VA MacDonald,LA 14107901410792* 701217 Dow Gehring, PJ Norris, JM Williams, CS ) ) Distributees General Subject Matter Page 126 Demott, DN Hanners, HH Martin, RA Tree, RM Deline, DD Kennedy, TL Robbins, LA Plepys, RA Stamand, VE Clark, GA Spencer, RA Dylewskl, SW Blelwelss, JC Barton, J Blair, EH Burgert, BE Clegg, DH High purity 245-trlchlorophenol, state of the art review V ? Toxicological properties and Industrial handling hazards of formulation M-3592 containing the propylene glycol butyl ether ester )} ) Dow Number Date Author Recipient 14107931410794* 14107951410798 701228 701217 Dow Hoyle, HR Norris, JM Dow Norris, JM 14107991410800* ^14108011410802* Ci). 701119 701228 Bourne, JE Dow SHversteln, EH ) ) Di stributees Dow Edwards, H Frevel , LK Gordon, HL Goring, Ca Holder, BB Johnson, JE Kilian, DJ Kimmei, CE Lloyd, BH MacCutcheon, SM McColUster, DD McIntyre, HH Morgan, RW Morse, D Pltchforth, L Robinson, VB Schwarz^ BA Williams, CS General Subject Matter of 245T Page 127 M-3592 (Data sheet of properties, health hazards, and precautions for safe handling of materials) Acute toxicological properties of Formulation M-3592 containing the propylene glycol butyl ester of 245T M-3592 (Acute oral toxicity) * M-3592 (Acute oral toxicity) Dow Number 14108031410804* 1410805 * 14108061410807* 14108101410811* 14108121410813* 14108141410815* Date 701110 701106 701210 701210 701210 701217 Author Rec1p1ent S1lverste1n, EG Sllversteln, EH Sllversteln, EH Sllversteln, EH Sllversteln, EH Dow Gehrlng, PJ Norris, JM Williams, CS COOi , ) ) Distributees Bergeri, BE Blair, EH Clegg, DH Dow Frevel, LK Gordon, HL Goring, CA Holder, BB Johnson, JE Klmmel, CE Lloyd, BH MacCutcheon, SM McCollister, DD McIntyre, HH Morgan, RW Morse, D Pltchforth, L Robinson, VB General Subject Matter M-3592 (Eye Irritation) Page 128 M-3592 (Primary skin Irritation patch test (household chemical)) M-3592 (Skin contact absorption) M-3592 (Skin contact absorption) M-3592 (Skin contact absorption) Toxicological properties and Industrial handling hazards of formulation M-3592 containing the propylene glycol butyl ether ester of 245T Dow Number Date Author Recipient 14108161410817* 14108181410821* 701217 701217 Dow Hoyle, HR Norris, JM Dow Norris, JM 14108221410823* 14108241410825* 14108261410827* 1410828 * 14108291410830* 14108311410832* 1410833^1410834* 701119 701228 701110 701106 701210 701210 701210 Bourne, JE S1lverste1n, EH S1lverste1n, EH SHversteln, EH S1lverste1n, EH S11verste1n, EH SHversteln, EH ) ; Distributees Schwarz, AJ Williams, CS III General Subject Matter Page 12 M-3592, (Data sheet of properties, health hazards and precautions for safe handling of materials) Acute toxicological properties of formulation M-3592 containing the propylene glycol butyl ether ester of 245T M-3592 (Acute oral toxicity). M-3592 (Acute oral toxicity) M-3592 (Eye Irritation) M-3592 (Primary skin Irritation - ' patch test (household chemical)) ^ r M-3592 (Skin contact absorption) M-3592 (Skin contact absorption) M-3592 (Skin contact absorption) ) ))) ) Dow Number 14108351410836* 14108801410902* Date 701210 630225 Author S1lverste1n Dow Olson, KJ Oyen, F Scoles, G Recipient 14109031410909* 531030 Dreyer, F CO OQ ) Distributees Barrons, KC Boundy, RH Brown, R Elshere, D Falkensteln, WJ Gay, HH Greene, LM Hart, A Jones, GD Kagy, JF K111an, DJ Luce, EN Lynn, GE McIntyre, HH Mull 1son, WR Nash, HA Norton, TR Scoles, G Shrader, SA Wilson, AW Wright, N Adams, EM Allen, WW Alllnson, RL Alqulst, FN Barrons, KC Beshgetoor, AW Page 130 General Subject Matter M-3592 (Skin contact absorption) Results of range finding toxicolo gical tests on agricultural chemi cal formulation M-2422 containing 91 percent Dowanol PIB ester of 245T (Biochemical Research Laboratory) Results of range finding toxlcologlcal tests on Dow Brush Killer T ), ) ) /1 Dow Number Date Author Recipient 14286101428611* 14312591431263* 14363541436364* 14370601437102* 611228 000000 000000 660622 Dow Winston, AW, Jr. Ivon Watkins Graves, HH DRE CO Distributees Boundy, RH Britton, EC Davidson, JH Dow Dutton, WC Gay, HH Greene, LM Kagy, JF Luce, EN Lynn, GE MacCutcheon, SH Prescott, RF Sunderland, WW White, L Wright, P Goergen,GG Lueck,A Sauers, RC W1d1ger, AH Tuttle, FC Poffenberger, N Wolf, RR General Subject Matter Page 131 Fish toxicity of some herbicide formulations and their Ingre dients IWD 245T Esters Compounds showing toxicity to f1shv, at 5 MG/L or less Pilot Plant Study of the Caustic Hydrolysis of 1245 Tetrachlorobenzene CF-1043-2 Dow Number 14439251443928* 14439291443932* Date 701217 700000 14439331443934* 1443935 * 761110 701106 14439361443941* 1511476 * 701210 800606 15486621548663* 610124 15494971549536* 501214 CO Author Recipient Dow Norris, JM Bourne, JE Dow S1lverste1n, EH Dow S1lverste1n, EH Dow S1lverste1n, EH Dow Sllversteln, EH K&E Wine, LM Braun, WH Dow Strand, D HRH LGS Delisle, NG Strand, D LGS Prior, CA Teal, JL Brittos, WW Arnold, JB Delong, HC Pott, S H1ghh1ll, CA Brown, M )I ) ); Distributees Dow Tucker, M Page 133 General Subject Matter Acute toxicological properties of formulation M-3592T M-3592 (Acute oral toxicity) M-3592 (Eye Irritation) Primary skin Irritation patch test (household chemical) (M-3592) M-3592 skin contact absorption 011 formulations 24D process v * ) I Dow Number 15496411549693* Date 700410 Author Axe, FD Hoyle, HR Recipient 1550150 * 710202 Olson, RD Axe, FE Hoyle, HR 15504011550407* 4^15504241550441* CP Cp 690930 650716 Mutcher, JE Dow Tree, RM Plepys, RA Bailey, CE Kramer, CG Morse, DB Stehl, RH Seidel, EM Rowe, VK Snyder, RE Axe, FD Di strlbutees Lynn, GE Deline, DD Schmldtke, DJ Hodson, RE Miller, DE Kramer, CG Holder, BB Morse, DB Rowe, VK Soule, RD Murray, N Deline, DD Tree, RM Bailey, CZ Seidel, EM Snyder, RE Holder, BB Silverstein, LG Page 134 General Subject Matter Industrial hygiene survey of 245T * Summary of environmental con ditions 1n dowlddes plant Dowidde plant environmental control task force minutes V*' Dowlddes - Industrial hygiene job analysis )) ) Dow Number 1550444 Date 000000 1550445 1550446 1550447 580807 580805 580808 1550448 580806 1550449 1550455 1550456 1550457 1550458 1550459 1550460 1550464 * 581015 651007 651007 651007 651007 651006 651007 000000 H* 1550550 t-* 1550551 u> 580807 580807 Author Dow Bradford, R Bradford, R Bradford, R Bradford, R Synder, RE Krohn, L Krohn, L Krohn, L Krohn, L Krohn, L Krohn, L Dow Bradford, R Bradford, R Recipient )) )) ) ) D1strlbutees Page 135 General Subject Matter Flowchart of production of Dowlddes Flowchart - Dowldde B Flowchart - Dowldde P Flowchart - Scrubber and Trap Phenol Flowchart - Monochlorophenol crude production Flowchart - Monochlorophenol Flowchart - Dowldde 6 Flowchart - Dowldde 6 Flowchart - Orthochlorophenol Flowchart - Diehlorophenol Flowchart - Dowldde 2 / Flowchart - Dowldde DPM * Schematic diagram of 265 Bldg, processes Flowchart - Dowldde 1 Flowchart - Dowldde 2S I) ) Dow Number 1558517 * 1558517 * 15585181558518A* Date 671027 670607 790316 Author Falrey, BP Chang, KY Fernandez, JB Krmel, KL Arnold, RF Howard, AC First, KE Owen, PW Recipient c GR ) Distributees Bumb, RR Johnson, SR Pruitt, ME Ward, WH Williams, CS Maddox, JF Owen, PW May, VT McGregor, SD Williams, AJ Tobey, SW Bohnert, TJ Morehouse, DS BuzzelH, DT Haberstroh, WH Woodward, RE Humbert, D Westover, LB Jewett, G Kl el don, D Fotherglll, W Val core, D Mendoza, C Hormel, T Kennedy, TL Aerstln, FG Manfrom, R Schloemann, P Page 137 General Subject Matter Laboratory preparation of 24D Laboratory preparation of 24D High yield aqueous 24D process a study of the modified Brazil process. Dow Number Date Author Recipient 15585191558520 750101 Mlntz, MJ Brust, HF ))> ) D1strlbutees Ble1we1ss, J Giebelhaus, L Dasilva, AA Blair, EH Hein, ND Karwal, JH Leng, ML M1ntz, MJ Moss., RD Pruitt, ME Sheetz, DP Thels, JM Brust, HF Morehouse, DS Dhingra-, YR Messing, SH Aerstln, FG Yeager, LM Bleiwelss, JC Kennedy, TL Haberstroh, WH McCoy, CE Woodward, RE Lafevor, DR Skelly, NE Robbins, LA Little, DW Kern, WG Hoffman, RL Werllng, CL Mlrsky, MJ Jones, WO General Subject Matter Page 138 Thermal decomposition rate of bis (24 dlchlorophenyl) acetal of glyoxyllc acid (BIS 24D) present 1n 24D V f )) ) ) Dow Number Date Author Recipient 15585211558522* 810204 Krumel, KL Arnold, RF McGregor, SD 1559777 * 15597811559786* ^ 1559787) 1559788* "^1 671102 000000 640625 Seidel, EM T.A.G. Seidel, EM ) 'I ) ! Distributees SwoggerT KW Chase, FI Carlson, RG Osborne, DW Gledhlll, JR Sheetz, DP McGregor, SD May, VT Muench, WC Williams, A Tobey, S. BuzzelH, DT Woodward, RE Haberstroh, WH Gorgacz, S Hormel, T Moser, J Yocum, R Downs, T Veurink, G Westover, W P1erz1nsk1, B Dersnah, BE General Subject Matter Page 139 The continuous preparation of 24D and 2-methly-4-chlorophenoxyacetlc acid (MCPA) 245T process V j* Direct Ester reaction Information 489 bldg. Diehlorophenol Dowanol Material balance considerations )) ) Dow Number 1559789 * 1559790 * Date 640625 640625 Author Seidel, EM Seidel , EM Rec1p1ent 15597911559797* 15597981559799* 1559800 * 15598011559806* 15601781560214* 640618 650118 650118 000000 681017 E.M.S. E.M.S. Seidel, EM Dow Seidel, EM Gilbert, PW Dunlap, RL c oo )j; ) Dlstrlbutees Seidel, EM Gilbert, PW Dunlap, RL Blelwelss, J Chase, FI Dell ne, DD Delong, HC Jossl, JA Rogers, JP Schwark, GJ Williams, JL Woodward, RE Fernandez, JB Page 140 General Subject Matter 24D Ester (unit ratlos) 245T Ester unit ratlos material bai ance Utilities, DE Utility requirements 489 Utility requirements 260 Bldg. Direct Ester General process description Direct Ester process Technical report with Information about 24D and 245T processes, costs, capacity and equipment > )I ; Dow Number 15602151560237* Date 681017 Author Seidel, EM Gilbert, PW Dunlap, RL R e d pi ent 15602381560241* 681111 Seidel, EM Gilbert, PW Dunlap, RL 15602421560265* P-* CO CD 681111 Seidel, EM Gilbert, PW Dunlap, RL Distributees Seidel., EM Gilbert, PW Dunlap. RL Ble1we1ss, J Chase, FI Dell ne, DD Delong, HC Jossl, JA Rogers, JP Schwark, GJ Williams, JL Woodward, RE Fernandez, JB Seidel, EM Gilbert, PW Dunlap, RL Bleiwelss, J Chase, FI Deline, DD Delong, HC Jossl, JA Rogers, JP Schwark, GJ Williams, JL Woodward, RE Fernandez, JB Seidel, EM Gilbert, PW Dunlap, RL Bielwelss, J Chase, FI Page 141 General Subject Matter Technical report with Information about 24D and 245T processes, costs, capacity, plant design and equipment Technical report with Information about 24D and 245T processes, capacity, plant design and equipment k/ Process Information and operating procedures for 24D Esters >)> ) ) Dow Number Date Author Recipient 1560266 * 670109 Johnson, RL W1d1ger, AH 1560539 * 1560540 * 1560542 * 1560548 * 1560549 * 1560550 * to o o 600324 491200 690722 000000 000000 000000 Delong, HC Dow McKnlght, FW Koslnskl, JE Koslnskl, JE Kos1nks1, JE ) >) ; Distributees Deline, DD Delong, HC Jossi, JA Rogers, JP Schwark, GJ Williams, JL Woodward, RE Fernandez, JB Johnson., RL Wldiger, AH Bender, S Bailey, C Silversteln, L Cobi er , J Haberstroh, WH Sauers, R General Subject Matter Page 142 Summary of laboratory research on temperature control of processes related to 24D and 245T formation Safety precautions 24D Amine weed killer hazards and precautions ; Block flow diagram of Amine formulations Unit ratios Amine formulation Cycle times formulating Cycle times packaging > }) ) Dow Number 1560714 * 15609511561000* Date 510228 680826 Juthor Recipient Fernandez, JB Seidel, M &*own, M Pfghhlll, C 15613071561310* 1561311 * 1561312 * 15613431561346* 15613531561375* 670329 670118 670419 670316 681114 as tertensteln ttartensteln, P Sculatl, JJ Jassl, JA S*idel, EM Iff!Hams, Jl to o H*- ) i ; Distributees Hoff, RC Ble1we1ss, J Beauchamp, R Dellne, DD Delong, H Dosser, R Schwark, J Snodgrass, B Woodward, D Dellne, DD Kearney, JK Del Isle, NG Chase, F Jossl, JA Ble1we1ss, J Haberstroh, W Williams, L Marshall, S Rodgers, J Schwark, G, Seidel, M Snodgrass, W Page 143 General Subject Matter Raw material specification L2-0-3 Technology review phenoxy A Tordon formulations 245T process 245T process 245T material balance 245T centrifuge Installation 245T, 245T Esters and for mulations of Esters technology review Dow Number Date Author Recipient 15613761561397* 681114 Seidel, EM Williams, JL Jossl, JA 15616951561698* 15616991561700* 1561701 * 1561702 * 15617031561705* 690417 690413 690709 690319 690417 Dow Wyant, 6 Brown, M CAH H1ghh1ll, CA Dow Chari1e Chase, FI ) 'I ) > Distributees Woodward, RE Del Isle, NG Fernandez, JB DeHne, DD Williams, L Marshall, S Rodgers, J Schwark, G Seidel, M Snodgrass, W Woodward, RE Del Isle, NG Fernandez, JB D e Hne, DD Chase, F Jossl, JA Ble1we1ss, J Haberstroh, W General Subject Matter Page 144 Sllvex acid, Dowanol Ester of S H v e x and Isooctyl Ester of Sllvex technology review Veon 245 process Veon formulat1ons 245T formulation Australia 24D products Veon 245 process )I )) > Dow Number 15617061561707* 15621771562199* 15623411562397* Date 670700 000000 680711 Author Dow Recipient Dow Delise, NG Schmldtke, DJ Deline, DD 1562343 * 15623651562383 ro C") (JO 681024 650000 Delisle, NG Harris, JS West, KD Passmore, L Knopp, DO McClure Owens, B Anderson, RE Cornell, JL Bleiweiss, JC Pumpelly, CT Deli ne, DD Rogers, JP Fernandez, JB Schmldtke, DJ Goergen, GG Schwark, GJ Widiger, AH ) I) Distributees Fernandez, JB Blelwelss, JC Goergen, GC Haberstroh, WH Pumpelly, CT Rogers, JP Schwark, GJ Widiger, AH Page 145 General Subject Matter Esteron brush killer O.S., label & production specification Process descriptions 245T technology review Corrections for Trichlorophenol technology review Trichlorophenol plant I) ) ) Dow Number 1562386 * 15626941562695* 15626961562697* 15642331564240 Date 661212 000000 000000 700209 Author Johnson, RL Recipient Dow Dow Schmidtke, DJ 15684501568452* 15685111568513* 1568528 * 1568532 * 641118 640730 000000 650813 Wldiger, AH Holmes, RD Holmes, R Dow Smith, FB Greiss, GA Hoyle, HE Goodchild, CD tas TO O I Distributees Fernandez, JB Hanners, H Tree, R Fauver, V DeMott, D Stamend, V McDonald, L Haberstroh, W Eigsti, D Goergen, GG Coulter, LL Trapp, WB Page 146 General Subject Matter A1cholic caustic hydrolysis of Tetrachlorobenzene Block flow H2 O from Tordon Tordon 1OK pellets process Routes to higher purity Trichlorophenol 199 building production of Sodium 245 Trichlorphenate Manufacture of Trichlorophenol at 199 building Notes on 245T manufacturing process Ivon Watkins Trichlorophenol know how ) ) Dow Number Date Author Recipient 15685331568534* 650707 Trapp, WB Merz, H 15685351568537* 1568549 1568552 * 1568553- 1568555 15685561568557 650128 000215 650401 650621 650312 Trapp, WB Trapp, WB Trapp, WB Merz, H Deckers Tolkmlth, H Trapp, WB Merz, H Doll, 0 Kooperman, P Trapp, WB Merz, H 1568558 650000 Dow loO I )) ) Distributees Sinclair, JR Cessna, OC Vlsger, HC Coon, ET Wolker, E Farnum, JH Coon, ET Amos, JL Koopman, R Sinclair, J Coulter, LL G111 -, HH Grless, Ga Dylewski, SW S1lverste1n, L Grote, M Amos, L S1lverste1n, L Sinclair, JR General Subject Matter Page 147 Analytical methods to determine TCDD 1n Phenols CTTL Summary of phone conversation between Dow employees 245T manufacturing processing contract CTTL Contract concerning Chloracne Gas Chromatography analyses CTTL Analyses of NA Trlchlorophenate Solution and Ani sole 011 CTTL f GLC analysis of your 245-Tr1chlorophenate Solution }) ) ) I Dow Number 15685591568560 Date 650000 Author Dow Recipient 15685691568572* 650126 Trapp, WB Chamberl a1n,LC 15685771568578* 15685791568580* 15685811568582* 15685831568586* 15685881568589* 1568592 1568593 1568594- 1568595 to O cn 650422 650422 650422 650409 650330 650223 650205 650113 Merz, H Doll-, 0 Merz, H Doll, 0 Merz, H Trapp, WB Mertz, H Sinclair, JR Trapp, WB Merz, H Gerner Trapp, WB Trapp, WB Farnum, JH Trapp WB Merz, H Kudszus, CH )I ) Distributees Coulter, KE Haberstroh, WH Goergen, GG Sauers, RC Amos, L Grote Amos, L Coon, ET Koopman, P Grless, GA Grless, Ga Sllversteln, L Page 148 General Subject Matter Analysis of caustic Insoluble oil and 245 Trlchlorophenol for com position by gas liquid chroma tography Trlchlorophenol research 245T Contract 245T Contract 245T Contract Toxicological studies, Gas Chromatography and Infrared ana lyses CTTL 245T Contract Chioroanlsole 011 samples CTTL Chioroanlsole 011 samples CTTL Request for Process Information ) ) Dow Number Date Author Recipient 15686021568603 650113 Trapp, WB Farnum, JH Kudszus 15686041568605 15686061568608 1568609 15686101568613 641215 641215 641217 551005 Kudszus Merz Trapp, WB Kudszus Merz Merz Jaenicke Boehringer Sohn Dow Dow S11versteln Weyland 15686141568615* * 1568622v O 1568626* r~> "4 650128 650105 Trapp WB Coulter, KE Poffenberger, N ) Dl strfbutees Goergen, GG Lueck, AF Poffenberger, N Sauers, RC Grless, GA Lueck, GA S1lverste1n, L Goergen, GG Poffenberger, N Sauers, RC Johne Knecht Nick Horner Sauers, RC Haberstroh, WH Poffenberger, N Sauers, R General Subject Matter Page 14 Request for additional Infor mation on 245T production Report on Isolation of chloracnegen sent to Dow Report on Isolation of chloracnegen sent to Dow Enclosure letter for rabbit tests conducted 1n connection with 1955 plant disinfection Rabbit tests conducted in connecr t1on with 1955 plant disinfection C.H. Boehrlnger Sohn Contract 245-Tr1chlorophenol notes, pro cess Information and flowsheet Dow Number Date Author Recipient 15686271568630 15686391568646* 15686471568664* 641208 610104 641127 Sauers, RC Poffenberger, N Sorge AWB Sauers, RC 15686661568667 15686661568667 641208 641208 Sorge Sorge 15686871568690* 650105 Poffenberger, N Distributees Trapp, W Lueck, A Wldlger, A Bradley, K Goergen, G Holmes, R Delisle, N Poffenberger, N Sauers, R Trapp, W Lueck, A General Subject Matter Page 15 Chronological survey of the first production period of 245T produc tion . 245-Trchlorophenol flow sheet Description and prints for pro duction methods for ohrtalning 245-Tr1chlorophenolate solution 1n Boehrlnger process Chronological survey of the first production period of 245T pro duction j Chronological survey o f the first production period of 245T % production 245-Tr1chlorophenol nofes, process Information and flowsheet > )) ) Dow Number Date Author Recipient 15686911568735 15687361568778 15687791568780 15687811568795 15687961568797* 650107 560912 641208 641127 650319 Sorge Sorge Merz Sorge Branch, CB CH Boehrlnger Sohn 15688001568801 6503305 Trapp, WB Farnum, JH CH Boehrlnger Sohn 15688021568803* 650000 CH Boehrlnger Sohn Dow too ) Distributees W1d1ger, A Bradley, K Goergen, G Holmes, R Delisle, N General Subject Matter Page 151 Attempts to determine the chloracne Inciter 1n the pro duction of 245T Experiments to determine the chloracnegens 1n 245T production 245T production chronology Trlchlorophenol process Agreement concerning the disclo sure of Information regarding the prevention of Chloracne arising out of the production of Sodium 245-Tr1chl orophenate Revision of agreement regarding v disclosure of Information con- < cernlng 245-Tr1chlorophenate pro cess Agreement concerning the disclo sure of Information regarding the prevention of Chloracne arising Dow Number Date Author Recipient 15688041568805 650305 Trapp, WB Farnum, JH CH Boehringer Sohn 15688061568807* 650000 CH Boehringer Sohn Dow 15688141568815 570222 Smith, FB CH Boehringer Sohn 1568816 15688171568818* 15690061569019* t"-4 O H -4 O 570211 570000 650107 CH Boehringer Sohn Weyland Dow Poffenberger., N )> ) D1stributees Amos, L Doedens, J Haberstroh, W Griswold, AM Vanderweele, JC Hoyle Melchlng, WA Knapp Kleine Myers, JR Krahne, 0 Sauers, R Trapp, WB Poffenberger, N W1d1ger, A Page 152 General Subject Matter out of the production of Sodium 245-Trlchlorophenate Revision of agreement regarding disclosure of Information con cerning 245-Tr1chlorophenate pro cess Agreement concerning the disclo sure of Information regarding the prevention of chloracne arising out of the production of 245-Tr1chlorophenate Preparation of Trlchlorophenol to avoid Chloracne Chloracne, preparation of Trlchlorophenol Preparation of 245T avoiding the formation of Chloracnegens 245-Trlchlorophenol, outline of requirements of applying Boehrlnger data to Midland operations Dow Number Date Author Recipient 15691051569112* 650209 Dow 1569137 * 1569138 * 15691391569140 15691411569142 650127 641128 650127 650310 AHW AHW RAJ AHW Anderson Lueck Goergen West Trapp Morel 1o Wolf Wldiger Poffenberger 15691431569153 1569154^69167* 650211 650107 Bradley, KB Poffenberger, N Distributees Lueck, A Holmes, R Bradley, K Goergen, GG Haberstroh, WH General Subject Matter Page 153 German TCP process, safety techniques Sauers, RC Trapp, WB 245 Trichlorophenol reaction graph time vs temp Graph Chloracne exciter vs temp 245 Trichlorophenol reaction graph conversion vs time at 155c Caustic hydrolysis of 1245 Tetrachlorobenzene graphs conversion vs time at 155uc 4 165"c t Data 4 graphs on hydrolysis of 1245-Tetrachlorobenzene 245-Trichlorophenol; outline of batch reaction )) ) ) ) Dow Number Date Author Recipient 15691681569176* 650203 Poffenberger, N 15691771569192* 650212 Poffenberger, N lO ro ) ) Distributees Poffenberger, N Widiger, A Lueck, A Holmes, R Delisle., N Bradley, K Goergen, GG Bradley, K Graves, H Dylewski, S Del 1sle-, N Haberstroh, WH Sauers, R Trapp, W Poffenberger, N Widiger, A Coulter, K Goergen, G Lueck, A Staehllng, E Bradley, K Graves, H Dylewski, S Delisle., N Haberstroh, WH Sauers, R Trapp, W Poffenberger, N Widiger, A Coulter., K Goergen, G General Subject Matter Page 154 245-Tr1chlorophenol preliminary process design 245-Tr1chlorophenol preliminary process design appendix ) ) Dow Number Date Author 15691951569197* 15692091569210* 650311 650518 Graves, HH Trapp, WB 15692211569223* 650302 Cornell, JL to CO Recipient Distributees Lueck, A StaehUng, E Goergen, GG Anderson, RE Delisle, NG Lueck, AF Wehn, WE Hillman, RE Coulter, KE Dellsle, NG Dylewskf, SW Goergen, GG Hutchenreuther, CO Haberstroh, WH Lueck, AF Poffenberger, N Sauers, RC Trapp, WB Wappenhensch, 0 West, KD Wehn, WE W1d1ger, AH Graves, HE Wolf, RR Anderson, RE Morello, VS Beyer, DG Harris, JS Cornell, JL > General Subject Matter Page 155 Pilot plant preparation of Sodium Trlchlorophenate solution TCP Process Project Conference Trlchlorophenol plant Dow Number 15692321569233* Date 650304 Author Harris, JS Recipient 15692391569243* 650315 Anderson, RE Delisle, NJ 15692471569250* 650318 Harris, JS )) ) Distributees Coulter, KE Graves, HE Wolf, RR Haberstroh, WH Dylewskl, SW Trapp, W Widiger, A Morel lo, V Cornel 1, J Goergen, G Coulter, KE Graves, HE Wolf, RR Goergen, GG Lueck, A Dylewskl, SW Trapp, W Sauers, R Poffenberger, N Hutchenreuther, CO Wappenhensch, CA Morrello, VS Wehn, WE Coulter, KE Graves, HE Wolf, RR Haberstroh, WH Dylewskl, SW Trapp, W Widiger, A Morel lo, V Page 156 General Subject Matter Notes from 6th Trlchlorophenol process review Trlchlorophenol plant scope of project Notes from 9th Trlchlorophenol process review > * Dow Number Date Author Recipient 15692511569254* 15701561570165* 1570376 * 1570380 * 15723161572322* 650317 000000 000000 000000 690310 Anderson, RE Dow Dow Jankowski, 3 15724291572440* 15727301572734* 1572735 641110 710202 700914 EMS Theis, JM Knutson, AT Chase, FI Schmldtke, n Dorton, RO O CJ J) ) Distributees Lyon, G Goergen, G Woodward, RE Marshall, SP Chase, FI Gilbert, PW Snodgrass, WA Kensicki, RF Haberstroh, Jankowski, SJ )) General Subject Matter Page 157 Trichlorophenol reactor cycle Tordon process information Oil formulations Phenoxy herbicide formulations Preliminary Investigation of direct ester expansion capabilities Direct ester 24D, alternate facility Dow raw material specification 2,4-Dichlorophenol ))/ I ) Dow Number 1572736 Date 700924 1572737 700406 1572738 700721 1572739 660923 1573474* 700915 Author Knutson, AT Chase, FI Martin, RA Loucks, MF Knytson, AT Dorton, R0 Yeager, LM Recipient Knutson, AT Kennedy, TL Chase, FI Schmldtke, DJ Martin, RA Landis, CA Hawley, HM Delong, HC H1ghh1ll, CA White, LC Hawley, HM Haberstroh, WH Savaso, JC 15734751573482* 700910 Haberstroh, WH Se1del, EM ro hJ an )) Distributees Page 158 General Subject Matter Dow raw material specification Sodium Monochloroacetate solution Caustic soda solution raw material specification Internal Dow raw material speci fication for Hydrochloric acid Ble1we1ss, JC Dell ne, DD Henry, HE Hensley, EF Schmidt, BY Tefft, TH Dow raw material specification 24D 24D Capital Estimates Revision of 24D Capital Estimates )) ) ) / Dow Number 15790031579009* 15805421580566* Date 701231 680514 15805671580585* 15813611581376* 15813821581397* 15819831582013* 15826541582657* 15836671583675* 15836901583691* 1630441* 680822 660000 660000 620700 000000 721125 500600 Author Thels, JM Sledel, M JFL Kern, WG Fernandez Gorgasz Dal man Dow Recipient Dow Dow Gilzorrllla, F FGZ CAH McCauley, V Mathew, BA M1llh1sler, RD Vanhorn, R Bethke to ) .) Distributees > Page 159 General Subject Matter Alkaline hydrolysis of 245T and sllvex Technology review of Industrial chloracetlc acid Dowanol, Butyl & Isooctyl Chloroacetate technology review Chlorophenol Prod. 670000 Chlorophenol Research Preliminary engineering study for Dow Qu1m1ca Argentina, SA Tordon 105 Manufacture Tordon 225E M3990 or Tordon 225E reactive chemical hazard data 24D Amine Weed Killer (Raw materials description and specifications) ? .1 ) ) ) Dow Number 1630444* 1630446* Date 510228 501000 Author Dupont Recipient 16304471630473* 1630466 16304741630478* 16304791630483* 1630485* 16304891630490* 16304911630494* 16318881631889* 1631901H* 1631913* to l* oe 501000 500810 491200 500201 500510 491200 491200 640624 000000 Ott, RC Jirouch, EA Dupont Seidel, EM Seidel, EM ) ) Distributees ) Page 160 General Subject Matter Raw material specification 24D Amine Weed Killer (Raw materials handling & storage conditions) 24D Amine Weed Killer (operating directions) Effect of DMA Concentration on PH of 24D Ajmine Weed Killer 24D Amine Weed Killer (Operational hazards) Tentative Operating Instructions, Dimethyl amine 24D Amine Weed Killer Specifications 4 average analysis 24D Amine Weed Killer (Labor Required for Operation). 24D Amine Weed Killer (Production and Yield Accounting Methods and Information) Direct Ester Authorization Handwritten notes concerning various steps of 245T process ) 1J I I ) Dow Number 16426901642691* 16450901645098* Date 000000 550826 Author JRU Bennett, CM W1d1ger, A Dugan, G Recipient 16500791650081* 630429 16501391650141* 670522 Barrons, KC Coulter, LL Johnson, JE Lynn, GE Wolf, MA Hunt, M Loucks, MF Vanvalkenburg, W Fayerweather, BL McIntyre, HH Branaman, J Lang, HC Falkenstein, WJ Davis, HW Allen, WW Barrons, KC Byrd, BC ro C Distributees Griswold, A Williams, WH Britton, EC Alqulst, FN Colby, A Vanarsdale, J Reese, R Bralnerd, A Poffenberger, N Widlger, A Dugan, G General Subject Matter Trlchlorophenol Manufacturing Phenol, 245 Trlcholor Verton CE with oil (Release to Sales) Tordon 155 Mixture (Release to Sales 9) I) ) Dow Number Date 16501461650148* 671009 Author Wolf, MA Gowel 1 Loucks, MF Falsey, MP Buerge, TE McIntyre, HH Hammer, OH Gill, WM Hlghhlll , CA Woodward, RE Davis, H Corbin, WF Nummy, WR DEP CJK JLS Dow Recipient Woodward, RE 1650262 1650264* 630517 if-sjtA ` ' J O Barrons, KC Coulter, LL Johnson, JE Lynn, GE R1tty, PM Wolf, MA Loucks, MF Vanvalkenberg,W Branaman, J Lang, HC ) ) Distributees ) ) General Subject Matter Page 162 Dosser, RC Hoff, RC Matuska, R Colby, A Stone, F Sales Release Tordon 155 Yerton T (Release to Sales 16) V * ) ) Dow Number Date 16504661650468* 621012 17108381710856* 740221 Author Recipient Falkenstein, WJ Allen Saunders, ES Amstutz, FC Barrons, KC Johnson, JE Lynn, GE Southwick, L Wolf, MA Vanvalkenberg,W McIntyre,HH Branaman,J Lang, HC Allen, WW JLS KEE ES PMR Saunders, E Roush., GJ Hoyle, HR 17108571710885* 700410 Axe, FD Hoyle, HR ro Distributees General Subject Matter Page 163 Esteron 245 Concentrate (Proposed Release to Sales 21) Winters, RE Degeer, JL Williams-, FL Langner, RR Kelyman, M Holder, BB Blair, EH Dellne, DD Hodson, RE Miller, DE Wipe test for Tertiary Butyl Catechol and TCDD 1n 267 bldg, prior to demolition t- ? Industrial hygiene survey of 245T production 267 production Dow Number Date Author Reciplent 1711008 * 000000 Dow 17183181718319* 17183331718335* 17195661719572* 17240981724104* 000000 000000 000000 690310 Dow Dow Dow Jankowski, : 17279671727968* 580630 Dow McCollister Wolf, MA 14222 Ilstrlbutees Iraimer, CG tarse, DB Sole, RD tolder, BB tLbyrwaen,, VGKE Schimldtke, DJ ankowskl, SJ oodward, RE Drase, FI flbert, PW Snodgrass, WA tarshall , SP lenslckl , RF faberstroh, WH 5m fayle, HR General Subject Matter Page 164 Notes on direct Ester production of 24D and 245T IWD 24D & MCPA & 245T esters Process time cycles NATCP Solution IWD 24D and 245T Esters preliminary Investigation of Direct Ester ex pansion capabilities (ACPD 69-10) Dow 245T amine weed killer (Data sheet of properties, health hazards and precautions for safe handling of materials) ) Dow Number 17280491728050* Date 590702 17280531728054* 17280571728058* 17280591728060* 630108 621214 660412 17280611728062* 700514 Author Dow Olson, KJ Oyen, F Recipient Dow Olson, KJ Oyen, F Dow Olson, KJ Oyen, F Dow McCollister, DD Olson, KJ Dow Norris, JM 17281011728102* 17281031728104* 580616 580630 1728167l 1728168* O fO Q 580514 Dow McCollister, DD Wolf, MA Dow McCollister, DD Wolf, MA Dow McCollister, DD Wolf, MA Distributees Dow Hoyle, HR Dow Hoyle, HR Dow Hoyle, HR Dow Hoyle, HR Dow Falkenstein, WJ Hoyle, HR Dow Hoyle, HR Dow Hoyle, HR Dow Hoyle, HR Page 165 General Subject Matter M-1459 formulation of K-7797 and K-7856 (Data sheet of properties, health hazards and precautions for safe handling of materials) M-2422 (Data sheet of properties, health hazards and precautions for safe handling of materials) M-2468 (Data sheet of properties, health hazards and precautions for safe handling of materials) M-2993 (Data sheet of properties, health hazards and precautions for safe handling of materials). (T2.MO-2993-1) M-3427 (Data sheet of properties, health hazards and precautions for safe handling of materials) (BC T2.MO-3427-1 ) Reddon (Data sheet of properties, health hazards and precautions for safe handling of materials) Reddon concentrate (Data sheet of properties, health hazards and precautions for safe handling of materials) Veon brush killer (Data sheet of properties, health hazards and precautions for safe handling of materials) Dow Number Date 17285261728527* 17386271738628* 1765919* 17663001766308 000000 000000 650919 661104 Author Wolf, MA Dow Dow S1nke, GC Wldiger, AH Johnson, RL Dugan-, GF Recipient 17663091766336* 650203 to to ki* Poffenberger,N Bradley, K Ebert Warren  D1 stribmtees Widiger, AH Coulter, KE Johnson., R Thurstom, D Dugan, (S fflaberstrroh, WH Goergen., GG Sauers, RC Bender, S Wolf, RJR Louck, A Poffenbrger, N Bailey, CZ Putnam, MS ielsorri, WH Staehllmg, EC Bradl ey ,,K Graves, H Dylewskii , S Hlaberstroh, WH Page 166 General Subject Matter precautions for safe handling of material s) Tordon formulation plant and Tordon pellet plant Flow chart for Tordon production Heat of reaction data per GC S1nke of the Thermal Lab Phenol , 245 Trlchloro study of Chloracne problem Preparation of 245 Trlchlorophenol from Trichlorobenzene Phenol 245 Trlchloro Preliminary Process Design Using 100 percent NAOH, PL2028-4 Dow Number Date Author Recipient 17666511766660* 17666811766686* 641125 650107 Poffenberger, N 17666871766694* 650112 Poffenberger, N xf ) ) 1 ) Distributees Sauers, R Trapp, W Poffenberger, N W1d1ger, AH Coulter, KE Goergen, GG Lueck, A Redmond, W Del Isle, NG StaehUng, EC Poffenberger, N Sauers, RC Trapp, WB W1d1ger, A Lueck, A Holmes, R Bradley, K Goergen, GG Poffenberger, N Del Isle, NG Sauers, R Trapp, WB Wldiger, A Lueck, A Holmes, R Bradley, K Goergen, G General Subject Matter Page 167 Trlchlorophenol Process 245 Trlchlorophenol - Outline of Requirements Appendix to Report PL2028-3 (245 Trlchlorophenol) j V )) ) ) Dow Number 17666951766698* Date 650105 Author Recipient Poffenberger, N 17667041766708* 17667131766730* 641120 641224 Holmes, R Sorge 17667341766736* 691212 Wldiger, A Sauers Chang, KY 17667391766750* 700720 Chang, KY Tou, JC JO rc) cn ;)) ) Distributees Poffenberger, N Sauers, R Trapp, W Lueck, A Wldiger, A Bradley, K Goergen, G Holmes, R Leavlttg, FC Demott, DN Poffenberger, N Tree, R Plepys, RA Schmldtke, DJ Chang, KY Tou, JC Look, A Leavitt, FC Demott, DN Poffenberger, N Gum, WF Plepys, RA Pierce, JK Page 168 General Subject Matter 245 Trlchlorophenol Process Information Hydrolysis of Tetrachlorobenzene using flke caustic Description and prints for the current production methods for obtaining 245 Trlchlorophenolate solution 1n building 74 (Report 50) Progress report on research on blooming of 245 Trlchlorophenol Oxygen 18 labeling study on the mechanism of caustic hydrolysis of 1245 tetrachlorobenzene 1n methanol )) Dow Number Date Author Recipient 1766760 1766761* 17667621766764* 17667661766769* 17667701766771* 1766772* 17667731766784* 17668241766825* to to '" 3 641118 640730 641120 000000 000000 340905 000000 W1d1ger, AH Holmes, RD Holmes, R Holmes, RD Dow Dow Prescott, RF Dow Grelss, G/ Hoyle, HR ) ) Distributees Frevel, LK Potts, WJ Westover, LB Fauver, VA Kennedy, TL Widiger, AT Pews, G Rodia, RM Nummy, WR Blue, RD Delisle, NG Sheetz, DP Goergen, GG ) General Subject Matter Page 169 199 Bldg Production of Sodium 245 Trichlorophenate Manufacture of Trichlorphenol at 199 Buldlng Hydrolysis of Tetrachlrobenzene using flake caustic TCP Process Flow Sheet TCP Process Flow Sheet 4 Manufacture of 245 Trichlorophenol from 1245 Trichlorobenzol Diehlorophenol and trichlorophenol proccess flow sheet )) ) ! Dow Number 17669441766948* 17682471768249* 17701871770195* Date 000000 650317 661104 Author Dow REA Widiger, A Johnson, RL Dugan, GF Recipient 17707051770709* 700525 Brady, P The following 2,4-D related documents have been deleted: 0725773-0725777, 0981364, 1298570, 1298598, 1580108-1580109, O to 00 ) } Distributees Ifdlger, A Oihnson, RL Digan, GF Ciulter, KE Twrston, D H&erstroh, WH Saiers, RC Wrf, RR Prffenberger, N Goergen, GG Beider, S Lmck, A Bcfley.CZ Pitnam, MS Miel son, WH S^ehllng, EC Sdmrf dtke, DO Itaberstroh, WH ViTHams, L Vcgel sang, P Case, FI Keisfckl, RF ' . Page 170 General Subject Matter 245 Trlchlorphenol operations 804 Building Trichlorophenol Reactor Cycle Phenol 245 - Trichloro study of chloracne problem preparation of 245-Tr1chlorophenoi from Trichlorobenzene, PL 2064-13 Manufacture of Pheno*y Herbicides > 1H0525, 1631287-1631289, 1631290, 1631291, 1721835-1721836 STATE OP NEW YORK ) ) COUNTY OF NASSAU ) ss, : ROSEMARIE CIANI ' b e i n g d u l y sworn, d e p o s e s a n d says: That deponent is not a party to this action, is over IE years of age and resides in New H y d e P a r k , N .Y . the- w ith T in h aNto toi cne tohef C o n f iddaeyn ot ifa l i t yM aarnc dh , U1p9d8a3te d iln adeejDf oon-en. t serve C o n fid e n tia l D ocum ents o f D e fe n d a n t The Dow C h e m ic a l Company upon the attorneys below set forth representing the parties, as indicated, at the addresses shown, said addresses being desig nated by said attorneys for that purpose, by depositing a truecopy of same, enclosed in a postpaid properly addressed wrapper in an official depository under the exclusive care and custody c the United States Post Office Department within the State of Nev, York, TO: SEE ATTACHED SERVICE LIST Sworn to before" me- this day of M a r c h 2. t 19 NOTARY PUBLIC WMQf-f_uVJaliPfiUcTNBaHoLRi.InCY4N,N4S7aUts0asR2tae7Uu0oSCfMoNuenwtyftr* " ' " `" l JWM March 30, ] | ^ ROSEMARIE CIANI TO: M orton B. S ilb e rm a n , Esq. C la rk , G a g lia rd i & M ille r The In n s o f C o u rt 99 C o u rt S tre e t W h ite P la in s , NY 10601 W e n d e ll B. A lc o rn , J r . , Esq. C a d w a la d e r, W ickersham & T a ft One W a ll S tr e e t New Y o rk , NY 10005 John S a b e tta , Esq. T ow nley & U p d ike 405 L e x in g to n Avenue New Y o rk , NY 10174 W illia m K ro h le y , Esq. K e lle y , D rye & W arren 101 P ark Avenue New Y o rk , NY 10178 HL oews at erdr , L Se cahtwe ar ,b , F.Kaqa.tz & D w y e r 120 Broadway New Y o rk , NY 10271 D a vid R. G ro ss, E sq. Budd, L a rn e r, K e n t, G ross, P ic illo & Rosenbaum 33 W a sh in g to n S tre e t N ew ark, NJ 07102 Thomas A. B eck, Esq. A rth u r, D ry & K a lis h , P .C . 1230 Avenue o f th e A m e rica s New Y o rk , NY 10020 V ic to r J. Yannacone, J r ., Esq. Yannacone & Yannacone P .O . Box 109 P a tc h o g u e , NY 11772 Irv in g L ik e , Esq. 200 W est M ain S tre e t B a b y lo n , NY 11702 A rv in M a skin , E sq. T o rts B ranch, C iv il D iv is io n U n ite d S ta te s D epartm ent o f J u s tic e Safew ay B u ild in g 521 - 1 2 th S tr e e t, N.W . W a sh in g to n , D .C . 20530 S ol S c h re ib e r, Esq. M ilb e rg , W e iss, B ershad & S p e c th rie One P e n n s y lv a n ia P la za Room 4915, 4 9 th F lo o r New Y o rk , NY 10119 The C ounsel o f V ie tn a m V e te ra n s 329 E ig h th S tre e t, N .E . W a sh in g to n , D .C . 20002 P a tr ic ia D. Howard C h ie f o f th e J u d ic ia l P anel on M u ltid is tr ic t L itig a tio n 1120 V e rm o n t A ve n u e , N.W . S u ite 1002 W a sh in g to n , D .C . 20005 P aul E s p o s ito , Esq. L e w is , O verbeck & Furm an 135 S outh L a S a lle S tre e t S u ite 1060 C h ic a g o , IL 60603 = ro5_r.--ornur--L>l'1?HcQ2o1-- 5*00 0:5--10 =0 r*o CO ur>o --0 s -3 0u0) va Sb E <