Document RpgRQX9zroL5mZQ4DMdyrRKav
REQ 41220
ARii&-0Z>5
R. Howells
GC/MS analyses of these samples were accomplished using a 25 m X 0.32 mm HP-1 GC column to introduce the samples into the Finnigan SSQ-70 mass spectrometer. The sample components were ionized pruaestriencgeonfct1hs0esmdheoigcwraeltehisoenpfieozrlalmotiwoinninuwgte:i.thTmheetrheasnueltsasotfhtehreeseagaennatlygsaess. cTohmebGinCedcowluitmhnthweiarscooprreersapteodndfrinogmG4C0/tFoID30a0reCaat a
Component I.D.
NLLo-.R1t0.0N5-9EtFOSE LWo.tR5.4N7-EtFOSE
N-Ethyl-carboxamides (Rf-C(0)N(Et)H)
0.22% 1.76%
N-EtFOS Amide ( C8Fi7S02N(Et)H)
0.04% 0.13%
C2F5S02N(Et)CH2CH20H
0.01% 0.12 %
C3F7S02N(Et)CH2CH20H
0.13% 1.17%
C4F9SO2N(EOCH2CH2OH
0.11% 1.52%
CFi7S02N(Et)2
0.03% 0.04%
CsFi iS02N(Et)CH2CH20H
0.03% 1.34%
C6Fi3S02N(Et)CH2CH20H
0.51% 3.52 %
C8Fl7SO2N(EOCH2CH2CI
0.08% 0.16%
C7Fl5SO2N(EOCH2CH2OH
0.82% 1.40%
N-EtFOSE C8FnS02N(Et)CH2CH20H
96.09 %
87.16%
CsFi5S02N(Et)CH2CH20H
0.78% 0.50 %
C8Fi7S02N(Et)(CH2CH20)2H
0.17%
C8HnS02N(Et)H
0.16% 0.37 %
C8Fi7S02N(Et)CH2CH20C02CH2CH3 (or similar)
0.21 %
0.22 %
Other High Boilers
0.28% 0.59%
003I0G
Component I.D.
N-Methyl-carboxamides (Rf-C(0)N(Me)H) C2F5S02N(Me)CH2CH20H C8FnS02N(Me)2 C3F7S02N(Me)CH2CH20H C8Fi7S02N(Me)H C4F9S02N(Me)CH2CH20H C5FnS02N(Me)CH2CH20H C6Fi3S02N(Me)CH2CH20H C8FnS02N(Me)CH2CH2Cl C7Fi5S02N(Me)CH2CH20H N-MeFOSE C8Fi7S02N(Me)CH2CH20H C9Fi9S02N(Me)CH2CH20H C8Fi7S02N(Me)(CH2CH20)2H CsHi7S02N(Me)H Other High Boilers
LNLo--M1t 2e7F6OSE 1.46% 0.24 % trace 1.15% trace 1.62% 1.34% 5.05% 0.13% 1.69% 83.88 % 0.87% 0.34% 0.54% 1.55%
APtdFrerumisefrliltiugidhmnoeererinuodwaantrcodoyeretkirrincethvhsaaeuenssltthCbsiyg-esda3ehrtnaeoidlwdctehoot(enhhTepoaFlotbAptayeenAnGaat)kiClayailznnoipdnnwrgaotighbdtaheleeisenmreEawssntaFitgmthOehapmSBtlEceSaostAuuewnrld(ihdatieolbc.rhegivHioivanovetviweztroehelldovevoeectrksro,iedumadelnderbatiyhvhlyaiyadztlniisenziylaagyotlsitnoihegneetnhmosiefafriemcstth)ah.eneomdtTaahloacmitfoseoharwuinoaonlalsrtltykwhosafwiisttNh.ahs-aEstFbeOeSn elbdixkyepretielhvyceateetdixdzeiersbditvewcwaatiiitutzhhseedMToFCefFA-t8OhAeaSslnEchuooamhwnobdsle.twrhToailhtfleadbnBiefyfSeevEAreetnFndOtemrcSioovEmrae-tcpichvooelnomhernpiadtsliescnitanohtteatdbtheieisensnpatrhmeevespaeallnenut.aaitlTnyehdstihesyeseoastfa,mMmbeueptsFloseOrimtiSsoiEnlfaAoprwr.porcboolbemmlepmslewsteaillrylemmoasstked
7/2/93 003107
REQ 41343
J. Grant
introducGeCth/Me sSamanpalleysseinstoofththeeFseinsnaimgapnleSsSwQe-r7e0amccaosms psplieschterdomuseitnerg.aT2h5e msamXp0le.3c2ommmpoHnePn-t1s GweCrecoiolunmiznedto using chemical ionization with methane as the reagent gas. The GC column was operated from 40 to 300 C at praetreceonfltOs sdheogwretehsepfeorllmowininugte:. The results of these analyses combined with their corresponding GC/FED area
Component I.D.
N-Ethyl-carboxamides (Rf-C(0)N(Et)H) C6Fi3S02N(Et)H C2F5S02N(Et)CH2CH20H C7Fi5S02N(Et)H N-EtFOS Amide ( CsFi7S02N(Et)H) C6Fl3S02N(Et)2 C3F7S02N(Et)CH2CH20H C4F9S02N(Et)CH2CH20H CsFi iS02N(Et)CH2CH20H C6Fi3S02N(Et)CH2CH20H C7Fl5S02N (Et)CH2CH20H N-EtFOSE CsFi7S02NCEt)CH2CH20H
9WP7r.e9Rc0u.0tN-1-1E2t-F1OSE 68.34 % 1.28% trace trace 0.41 % 1.41 % 1.53% 0.62% 1.48% 20.16% 3.52 % 1.14%
9Wm7a.9Ri0n.0cN-u1-t1E2tF-2OSE 1.27% 0.32% trace trace trace trace 0.51 % 0.42% 2.16% 60.86 % 22.55 % 11.92%
Component I.D.
B9N7..PR9.0. 01N-31-2M07e-F2OSE
003I0S
mw 137 possibly -S02N(Me)CH2CH20C7FisS02N(Me)CH2CH20H N-MeFOSE C8Fi7S02N(Me)CH2CH20H C9Fi9S02N(Me)CH2CH20H C8FnS02N(Me)(CH2CH20)2H C8HnS02N(Me)H Other High Boilers
Component I.D.
N-Ethyl-carboxamides (Rf-C(0)N(Et)H) C3F7S O 2NOEOH C4F9S02N(Et)H C 5F n S 02N (E t)H C6Fi3S02N(Et)H C7Fi5S02N(Et)H N-EtFOS Amide CCsFi7S02N(Et)H) CsFi5S02N(Et)H numerous other impurities o f most homologs that include hydrides, chlorine in the backbone, and unidentified high boilers
0.58 % 0.41 % 98.19% 0.59% trace trace 0.23%
W.R. N-EtFOS 9A7m90id0e-111 10.23 %
trace
0.71% 3.58% 52.50 % 20.06% 12.93 %
trace
trace
3l09
