Document RpZrwZ2kw89LMDV5EJgQ4Lq3V
______________ESC/DAYTON (DepertMnt/Section)
mmjiS
ANALYTICAL (Type of Report)
REPORT NO. MDA-469
1
JOB/PROJECT NO. 484.5130
DATE 5 April 1984
PERIOD COVERED
V) TITLE ANALYSIS OF WATER FOR PCB'S a *
AUTHORS: B. M. Hughes'
A O W O IS : B . Me Ilu< jhes T tT L S t A N A LY S IS OP WATER POR
ABSTRACT:
Four water samples from the .und;ii'> nil facility were analyzed for possible PCB concentrations. The results o' these analyses are shown in this report.
TECHNICAL APPROVAL:
JJ. BrdqksJ Search OToup Leader
APPROVED BY:
R. F. Ivory
*'
Environmental Science Center
Service Project Manager
k* 4 6 9
I
ii n
APPROVAL DATE:
f - I P*
RESTRICTED DISTRIBUTION (see over,
,, -C. SUV-fAH^TM -C 0 N F 1 D E N T I A l
~ - This Nnayt It the property ef Hensente Ceupaay ea4 the
a.
recipient la reepeeolV* fer lte saiekeeplaf
4iopeaitiw>:
It ceutelai CQWUCIfflAL INPOHUTICN ehlch auet not he
.1 LiUtU |o imuoriue ytrm *r ..at Miilh notfile Ceafiny without proper eutherltetlen.
MONS 022799
COPY NUMBER
.1 R. Ratchelor
2 8 M. Hughes
ms 12S0
i r. r. ivory
12S0
4 Central riles
12S0
S Technical Reports Library R2C
ABSTRACTORS H. A. Noltermann
NOTE:
Distribution of this report is restricted. Requests for
Additional copies should be made through the principal contact at the Monsanto location involved or the Manager, Environmental Sciences Center, Dayton Laboratory, Dayton, Ohio.
ACKNOWLEDGEMENT
Contributions of the following Dayton Laboratory personnel to this project are gratefully acknowledged:
Analyses:
R. M. Hughes D. McKenzie
C. Trang
COMPANY CONriDLNTIAl HONS 022800
ANALYSIS REPORT
DATEl March 3*. 1*84
LOO NUMBERi 1-84-03-13-01
PROJECT NO 484.91318
TOi Boh Ivorv/Research Trionolo Pork
FROM'
Envtranioontol Sciences Center Nonoonto Cempanv/Davten Lahoratorv 1919 Nicholas Road Davton. Ohio 49418
Phono Noi (913) 268-3411
Titloi Analysts of Motor Samples for PCBs. Standard Sampllne Mathod No(s>> N/A Standard Extraction Nothod Nolsli PCEX02 Standard Analysis llothod Nolsli ECAN02 Final Rooort Ftlo Nolsli A91318 TaSlo File Nolsli 891318. C91318
Four yatir samples contalnino sodlaont were analyzed for PC8s. Tahlos 1 and 2 summarise tho results. Noto that those sauries contain Aroclor 1248 rather than tho Aroclor 1232 formulation found in previous samples.
~ enzie and Chi Trans
HONS 022801
TMUE S. fttiwltf of CirtlUfY OC/tC *Mlnn of Arocior imi in mIw twin fro* Rosoarch TrliMlt Pwki N.C.
tK Project Nei 484.31318
ANALYTE
ESC ANALYTICAL
METHOD LOO
Arocior 1248
Rno of Valuoo No of Valuoo Std Deviation X Rol Std Dov
ECAN02 -
-
0.1
-
-
Roooarch
Trlanolo Park 030784-1
MIH March 27.10S4
MITU IDENTIFICATION
Roooarch
Triandlo Park 030784-1 Duollcato
Roooarch
Trlanolo Park 030784-2
60
.84 21 . IF 32
CONCENTRATION luo/o)
.67
o9i
16 .20 29
.97
1.43 21
.33 34
SURAOOATC SPIKINO COMPOUND
AMOUNT ADOCD lut/ol
CL3-boni.no
ECAN02
1.0
>03
RECOVERY (X) 120
83
DOCUMENTATION
ESC Extraction Method
Saaple Aat Extracted <*> Extract Final Voluao tall Extract Dilution ESC Extract No. Procooo File Naa*
PCEX02 10 1
HI PCB333 06246
PCCX02 10 1
111 PC0343
0P263
PCCX02 10 1
1*1 PC0335 0P248
EXPLANATION OF ABBREVIATIONSI LOD liait of detection in u./.
ND non* detected with a detection Halt oivon br th* LOD valu*
NA - not analvx*d
Rno of Valuof - Total ranoo of Arocior foraulation concontration* aoaturod from individual PCB ieoaore. Tho nvobtr of ItOAaro uod in thio calculation i* oivon bv No. of Valuoo
No of Valuoo Nuabor of PCB iooaoro uood to aoaour* Arocior concontration
X Rol Std Dov CiStd Poviation>/(Conc*ntr*tlon)3 X 100X.
TABLE FILE NOi B3I31.IMH
HONS 022802
TMLI 2. hNlti a# eirtllwv OC/tC
ef Urtelir 1243 in Mlir
Iwrlti irt* Roeearch Trian*le Park. N.C.
CSC PnJlCt Nl 484.51318
ANALYTE
ESC
ANALYTICAL
METHOD
LOD
Aroclor 1248
Rn* of Value* N tf V1uft
Std Deviation X Rol Std Oov
ECAN02
-
-
O.l
-
-
R**arch
Trianel* Park 030784-3
Onto March 27.1*84
SAMPLE IDENTIFICATION
Research
Research
Trian*l* Park Trianel* Park
0307S4-4
Mthtf DUnk
CONCENTRATION
3.3 2.39 NO
4*4 2.53
21 21
M * 74
-
34 32
-
SURROOATE SPIKINO COMPOUND
AMOUNT ADDED
</>
1.0
100
RECOVERY (X) 104
104
DOCUMENTATION
CSC Extraction Method Scant* Aat Extracted (>
Extract Pinal Veluae (a))
Extract Dilution CSC Extnct H. Prtetii Ft I* NtM
PCEX02 10
1 1*10 PCS269 BP337
PCEX02 10
1
1*10 PCD270 BP339
PCEX02 0
1
m PCt263 SP34I
EXPLANAT ION OP ABBREVIATIONSI LOO Halt of 44t4Cti*n in u*/
NO * non* iittclii with * 4ot*ctlon Unit oivon br th LOD vtlut
NA not anal vied
Rn* of Value* Totat ran*# of Aroclor foraulation concentration* aeaiured fro* individual PCS itoaer*. Th* nuabor of lioaer* f*d in thi* calculation 1* oivon bv No. of Valu**
No of Volvo* a Nuabor of PCS iooaoro mod to aoaour* Aroclor concentration
X Rol 8td Oov a t(Std Deviation)/(Concentration)3 X IOOX.
TABLE FILE N0> C91318IRH
RONS 022803
DETAILED EIPLANATION OT TAM.lt
In ir #M*rt to
rtMfti NMfatitf tv ESC an PCD* present
In i Ut variety of iiUMib* us In* % M| virittv of tehRl<HMi ttmtirt
titnctUR
(SCflt) ml StiRttrl AmIviIi Method* (SAMs) have NtR
tvtUNl which an It Hilly HttMicH with ttch ether. An abbreviated
form of these SCMt H SAM* have Htn stored en tht Hewlett-Packard 3S9T-LAS
laboratory ivtmtlH ivitH used bv ESC. I ft Mrt to communicate Ihttt
details with customers t# ESC* tht* information I* iumIIH with ttch ACS
analysts* However **Ry projects Ihvtlvt t vtrr smell ngtbtr of sample*
which ere not necessarily tht seme Htrlx. TRtftHrt. meJor information
or. tht technical details tf on analysis ere presented In tabular form
within tht seme ttllt which report* tht dote.
Etch ttllt includes t tthtrtl title* ESC Project Number and Dttt on
which tht telle wts eenereted. Tht sememe identification Is tht customer identification which mi on th stmtIt bottle. Tht next section tf tht ttllt tivtt result* for tht particular analvto listed. Por Aroclor formu lations* thr formulation is identified either visual I* or from ESC developed dtto ir.41i i i rroerems. The concentration of the formulation is calculated from tht Oversee value of the Aroclor formulation* Itsed ueon the analysis uf t nutter of PCS isower*. The number of isomer*
used in this ctlculttion is eiven ts "No. of Values" end the rente of Arocto* concentret ion* for this number of PCS isowers is tiven
l. "Rno vf Vtlues"* The sttndtrd deviation end X relttive standard Jv.ietien for this number of doterminttions of tho Aroclor formwlttion tre tiven in the followine two lines of the ttbles*
The ne ;t section of the ttble detls with ouallty control used in etch Stmsle enei.sis. The surrovate spikine compound which is tdded to the sample before *trscti-r. end enalrsi* is listed* tlont with its amount tnd X Recover* measured for etch sample. In cases where PCS concentre!ions tre ver* Mth tnd thus require extract dilution* no effort is made to outntify this com* round. This could bo done If ESC knows that this data is important* but treicallr 50 u/ is the important level to ouentlfr accurately so that urreette data for concentrations larer than this valuo* from a regulator* standpoint* are not important.
The ne.vt section documents how each sample was extracted and analysed. The ESC Extraction Method* amount of sample extracted, extract final volume, e tract dilution factor. ESC extract number and the computer data file in which *.he processed data is stored are tiven in this section. The last section elves a brief description of abbreviations or elves anv footnotes that five additional Information about specific samples.
This table format is both compact and precise* It ms developed in ah attempt to nuicklv and accurately eenerate data which the customer can wuickW and accurately evaluate* If there are anv sueeestiens concernine this
format* Please contact me at extension 396.
DESCRIPTION STORED IN TKXOUMH
HONS 022804
TM fallolnt raaao daicriba Standard Extraction Hathoda and Standard nalvala Hathada uaad tor tMa rreJoct.
HONS 022805
ESC Standard Extractlsn Itathed I SEN) TtTLSl PCS* In Nan-EC Active Matrices
hatriid.icesh
Salta and athar nan-EC actlva salIds and saivants
CSC Standard ExtractW* Itathed Nat PCEX02
TYPICAL SAMPLE
SIZE (a)
TYPICAL EXTRACT
VOLUME (all
0.3 - 3.0
10
TYPICAL ANALVTESI Araclars 1232. 1242. I24S. 1234. 1260. 1262. trlchloroblahan.l Iseaiera threush ectachlerebiahanrl iaoaera
ESC Standard Analvals Method Non ECAN01. ECAN02
INTEAEEAENCESt Any alactron caaturlna saaciaa In tha ratantlan tiaa raaian ad trichlorobl)iarw 1 laaaars throuah
ectachlereblnhenvl laaaars.
TYPICAL
SURROGATES -------------------
TYPICAL
RECOVERIES IX) ------- --------------
aantachlorobanzene 2.4.6-trlchlore-
biaher.vl
SO - 120 SO - 120
APPARATUS AND MATERIALS)
Surdick and Jackaan banzana far aaapla extraction or dilution. Dltaasabla'eliaeware.
LIMITATIONS) riathod anal lee only to aatrlcaa which do not contain Inter/arrlne alactran cantgrins saaciaa In tha trtchlarablahanyl through ectachtereblahanyl laaaar ratantlan tiaw raaian.
SAFETY PRECAUTIONS! Saa PCS handllns aratacats in laboratary safatv nanual.
DATES OF METHOD CREATION AND UPDATES! 10/31/83. 2/3/84
MORS 022806
CSC
Analytic Method (SAM)
TITLE! Araclar PtrMilitUM lit Solvent*
CSC Standard AuItiIi Method ti ECAN02
ANALYTICAL INSTRUMENT AND MOOC OF OPERATION! HF-SSDO Carl I lory OC/CC InterTaced to an HP-3357-LAS Laboratory Data Svatea
TVFICAL ANALYTE
TVFICAL INSTRUMENT LEVEL OF DETECTION (LOD)
(ua/Al>
Araclar feraulatlam
1232. 1242. 1240. 1294. 1240. and 1242
0.1
TYPICAL PRECISION IOX LOO
(X)
30
TYPICAL ACCURACY IOX LOD
(X)
30
INTERFERENCES AND LIMITATIONS! Anv electron certurine I'adai in the retentlan tlee rattan of trlchlerehlrhenyl thraueh actachterehirhenvl Itoeert ara rotantial InterCerencee. Exact retention tla.ee of *t llialr PCS itaaert can 4a attained from the analytic of Araclar 124S. Araclar 1294 or Araclar
1240 Teraulatlone.
CMI0MAT00RAPH1C COLUMN! 30-eeter Tuted lilica J4W DB-9 (0.29 uM> uith Ida kart (0.32ae).
COLUMN TEMPERATURE PROORAHI 130(11/4/300
INJECTION TYPE* Sri it let!
CALISRATION AND STANDARDIZATION! Uta Internal etandard auantitatian technique and callkrata lnttrueent ratranta factare from authentic Aroclar Tareulation atandarde. Uta a atniaua of 10 PCD ieaeert Tar the determination of Teraulatian Identity and uuantltv.
CALCULATIONS*
Faraulatian cancantratian - (iaeaer araal/litaaar RAF)
hare> RRF it the relative ratranta Teeter Tar the arrrarriate PCD Itaaar In a elvan Tarauiatian. Faraulatian cancantra tian It aktainad Troa the avaraaa of at leaat 10 tuch cal culation!.
SAFETY PRECAUTIONS! Saa PCD handline rratacalt In lakaratarv oofot- annual.
DATES OF METHOD CREATION AND METHOD UPDATESi 10/29/83. 2/3/84
HONS 022S07
Tin ftllMlnt retro describe AmItII Reouost Information oenereted for thto project.
HONS 022808
MIC ENVIAOMSNTAL SCIENCES CCNTER ANALYSIS REQUEST
DATE! NAACH 20. IPS4
LOO NO* 1-*4-03-13-01
ACQUCSTEAi RTP/MUOME*
PROJECT NO*
4*4.3131*
REPORT RESULTS TOt FILCS/REES. IVORY. SAOOKS
ANALYSIS ACQUESTS SENT TOl files, ivory, brooks, huohcs
TATTLE PICKUP BYI 0. HCKENIIE SAMPLE LOCATION!
SAMPLE DESCRIPTION FOR 4 SAMPLES
SAMPLE IDENTIFICATION
NUMBER OF BOTTLES
ATP SAMPLE NO. 0307*4-1
ATP SAMPLE NO. 0307S4-2 ATP SIMPLE NO. 030784-3 ATP SAMPLE NO. 030784-4
1 DUPLICATE EXTRACTION
1 1 1 METHOD BLANK
ESC NUMBER'S)
PCS333 PC0343 PCD33S PC*269 PC027O PCS243
RECORDED BYt P. HUPP
REQUIRED ANALYSES! PCS
ANALYTICAL TECHNIQUES! X OC/EC (IS)
DATE
COMPLETED 3/2T/84
QUALITATIVE! YES REQUIRED QA/OCl
SEMIQUANTITATIVE!
QUANTITATIVE! YES
COMPLETION DATE REQUESTED!
COMMENTS! ttoivll* rMM4 t* Dtvid Btcl>l.r,on 3/13.
Mfti DISPOSITION!
X HOLD FOR 30 DAYS
SAFETY PRECAUTIONS!
ANALYSIS REQUEST PILE NAME! AAS130ILI
HONS 022809