Document RpRVN3126pZO7bgOJpk478j3X
*
Material Safety Data Sheet
DatePrepared (t/7/90
Product identification (Label Name) CertavinTM CT-1110 PVC Polymer
NFPA Rating HMIS Rating
Health Fire Reactivity
110
1* 1
0
DEGREE OF HAZARD 0-Minimal (Insignificant) 1-Slight 2-Moderate
3-Serious (High)
4-Severe (Extreme) -Chronic Health Effect(s)
I. INGREDIENTS
Chemical Name {CAS No.)
Common Name
PVC is not considered a hazardous material under current Department of Labor definitions.
PVC may contain trace amounts of the following materials: *Ethene, Chloro
(CAS 75-01-4)
vinyl chloride (VCM)
Ethene, Trichloro (CAS 79-01-6)
trichloroethylene
* IARC, NTP and OSHA carcinogen
2. PHYSICAL DATA
Boiling Point N/A - Solid Vapor Density (Air = 1) N/A - Solid Vapor Pressure N/A - Solid
Odor
% Volatile By Volume N/A % solubility (H,0) neol i qi bl e Appearance DOWder. white
> CertainTeedEJ
Certarrihed Corporation P.O. Box 860 Valley forge. PA 19*8? (215) 341-7000
(24 Hour Telephone
Chemical Name Ethene, Chi orohomoDol vmer
CAS No.
5002-86-2
Common Name(s) Pol yvi nvl chloride: PVC;
Pol vvi nvl chloride resin
Exposure Limits
None Established
%
ca 100
OSHA PEL: 1 ppm ACGIH TLV: 5 ppm
OSHA PEL: ICO ppm ACGIH TLV: 50 ppm
tion 65 and on
trace trace
Melt Point Specific Grayity j _ 40
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FORM NO. 01-08-0025
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3. FIRE AND EXPLOSION HAZARD DATA
Flash Point & Method
Flammable Limits LEL
About 391C (735F) N/A____________ _
Method:__ Not .specified uel N/A___________
'>
Extinguishinguedid Mater most effective. ABC dry chemical.
specatFnRghimgPmce*ms Wear positive pressure, self-contained breathing apparatus (SCBA) when
fighting a fire and during clean up immediately after a fire.
unusual Fin and Explosion Hazard Combustion or thermal decomposition yields carbon dioxide, carbon monoxide, hydrogen chloride (gas) and small amounts of aromatic and aliphatic hydrocarbons Vinyl resin is not considered to be a dust explosion risk. As a precaution it is
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4. HEALTH EFFECTS
primary Routes ot Entry Inhalation, ingestion
Cananogens None____________ MBC No NTP fjp OSHA ftp
Acute: No significant toxic hazard.
Chronic: No significant toxic hazard.
Conditions Aggravated By: Decomposition products may cause irritation to respiratory tract
and aggravate bronchial asthma and other chronic obstructive respiratory diseases.
Dust Exposure: PVC resin is not known to cause any lung disease when dust exposure is minimized. Routine inhalation of any kind of dust should be avoided.
At processing temperatures the resin, stabilizers, lubricants, modifiers, etc., may emit irritating fumes and vapors including hydrogen chloride.
Special Note:
PVC resin is not a cancer suspect agent. It is the trace amount of unreacted vinyl chloride monomer that must be controlled, not the PVC itself. Employee exposure to vinyl chloride, a carcinogen, is regulated by OSHA {29 CFR 1910.1017). The OSHA PEL is 1.0 ppm for an 8 hour time weighted average (TWA) or 5.0 ppm average for 15 minutes. The action level is 0.5 ppm for an 8 hour TWA. (See also Section 11.)
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5. EMERGENCY AND FIRST AID PROCEDURES
Skin: Flush thoroughly with cool water for at least 5 minutes. Eyes: Flush with water for at least 15 minutes. Get medical attention. Inhalation: Remove to fresh air. Get medical attention. Ingestion: Consult a physician. Treat as inert, granular material.
6. PHYSICAL HAZARDS
None
7. SPECIAL PROTECTION INFORMATION
Respiratory: Not normally required. Abnormal conditions during processing may cause decomposition. Wear NIOSH/MSHA approved self-contained breathing appara tus when removing decomposed materials. If dusty conditions exist, wear NIOSH/MSHA approved nuisance dust respirator.
Gloves: When handling hot material during processing. Eyes: Goggles for dust protection.
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REACTIVITY
n
:able. Hazardous polymerization will not occur. Avoid excessive heat for prolonged ariods. Avoid contact with acetal or acetyl copolymers and with amine containing materials iring processing. At processing conditions these compounds are mutually destructive and nvolve rapid degradation even in trace amounts.
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l STORAGE INFORMATION
;tore in cool, dry place (for product quality). Remove PVC resins from floors and walk ways to prevent slipping.
Ground pneumatic transfer lines to avoid electrostatic accumulation hazard.
10. SPILL LEAK AND DISPOSAL INFORMATION
Iacuum or sweep into a closed container for reuse or disposal.
Vasie Disposal Uethod
dispose of wastes in a licensed landfill or by incinerating in accordance with federal, state and local regulations. Hydrogen chloride is generated by incineration. PVC resins are not defined as hazardous by current provisions of the Resource Conservation and Recovery Act (RCRA-40 CFR 261).
11. ADDITIONAL COMMENTS
Always use PVC compound under well-ventilated conditions and avoid continued or prolonged breathing of process vapors. Wash thoroughly after handling resin, especially before eating or smoking.
'laming on Resin Containers: Acronyms used in this MSDS:
When the further processing of PVC resin will be likely to result in employee exposure to VCM at or above the action level, the OSHA Regulation requires the label state: "Polyvinyl chloride contains vinyl chloride. Vinyl chloride is a cancer suspect agent."
N/A: Not applicable CAS No.: Chemical Abstracts Service Number OSHA: Occupational Safety and Health Administration PEL: Permissible exposure limit LEL: Lower explosive limit UEL: Upper explosive limit IARC: International Agency for Research on Cancer NTP: National Toxicology Program NIOSH: National Institute for Occupational Safety and Health MSHA: Mine Safety and Health Administration
EPA: Environmental Protection Agency US
HMIS: Hazardous Material Identification System
NFPA: National Fire Protection Association
SARA: Superfund Ammendments & Reauthorization Act
TITLE III: Emergency Planning & Community Right to Know Act
Section 302 - Extremely Hazardous Substances
Section 313 - Toxic Chemicals
ACGIH: American Conference of Governmental Industrial Hygienist TLV: Threshold Limit Value PPM: Parts Per Million
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