Document RpNQX6xE6EKOxxmNYXR0q7ZzX

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Ul "5 lb TX G 4* rt rt N ct G in n> T rt a 3" lb * Hi X X lb ft in Ta M CJ < X M "S in c- n in in lb G T o *5 N 43 n a i cH in lb in G ft in "5 "5 C `O a CT Q 1> H X CT in UJ 0 CT lb lb i O C Ul n H Itl ft rt a -- L G T Ui T 1 in T! Ul t- Tt CT G Ib t" 4 in ys a T i--i rt X- Ib in y3 in 3 N 4* in CT < in tn 4/ t--i fb ft --i a UD Ct G 41 U) o y in rt a H Ib T rt "S i-- a ib o V-- n in 3 rt in a CT H n Ul co T lb rf Ul O G X) o (ft X TD 41 n Ib C H in Ul o T n -o n ~5 =3 ^t TI Ib in n cr H X T n *-+ ft c Ib ^+J CT Hi in in Ul rt U4l XJ in C 3 Ib 3 H 3 u> - T a t-- H CT rt n n --1 1--* 3> in 3> Eb (J d H' si lb na t- lb in T3 1 0 3 a CT 3a 3 Ib d *1 lb ib 3 "5 in a rt cr H- Ul U) t- 3 G m id in n 3 rt i~ G a H- H- 3 G a c H Ha in X3 lb ft X 41 U H- C r* 1 X n T> (ft in rt CJ ^ rt i CT CT CJ c O G 1 -5 2 r X TJ T? G T H Ib 3 U) CT X t1> 3 N in fb *5 rt H GT m ft i Ul ro is Cl 4 <1. 4 T4 I> 4 3-1 O 4 mX m T 4 a 2> 2 25 *h2 m Nl 4 n to X 3 J> 2 C X 15 013 X 4f"0 |-- O4 X 4 m ft H o 4 3 2> 2 m 4 m ~i *n H 4 X - O m 400X X 4m23 3 4 2 3> U~i 2 4 4 O -< m 3 H--i 35 H--1 4* TI mX oZ 4X0 O 4 O m Tl z 422T 4mnn 2> n H r X m fXt o --t to --j X*--1 CD C H n 4 -< 2 4* TI m X 4 X X tj n 4 O o o 4 Z c. O 3 4 m Ul G 4 rt n 4 4 4 D3 a? g G 4 4 4 4 HX ro n ft 4 ft 4 4 4 * .. .. 4 ft ft 4 1 1 i Mcn 4~ ro 4 CO CJ ft 400 44 0 w 0 w wCJ 4 4 4* rj M ft 4 4 1 4 i U i 4 (J ft cn 4 CT (J Ul 4 CJ O Ul 4 ft O o 4 4 * 4 * * * * * + 2 H n n --i y H Ul T 3 t--i cn X ti 35 U'j n 3> 15 to ~T X T13--- H- o 31 35 2 r *^T O 25 in i-- T' *i--Hi < rn w m c in in 2 2 X X JT cn t--1 O H p X J. T 3 ^X-1 i--i n fXt 1^"rs to 15 to H H O GT n 3> --i C rt UJ T G t- tfb X (0 3 T! a G in G ib H>' fb rf- XI 1-- rt T G a c C-+T* Xlb id C c T G o h- G C n f-j* itn-* cn 3 X rt G X to hi=n1 G V"5, G X a "5 G G X G iD 3in cr HH> H |G] 3 4i C I--1 0 in C n in T CT H- rt O C J-- in frtt G in T rt ft ui rt G T H to G3 --l 3 ft X +. GG i--i >> ~5 3 n =1 Ti r+ in G H ft "5 < H- 3 0 ic+ G T rt ft H O T 22 2> C 33 m cc m X -n5 3l-H c to an G o^ H -* Ul t G Gfwt 3 I> H m X-4 r t--i Ci rr. 2 H *-H X f-- n X -t M n 2 0 1 c ij l cu ft n G3 Ci n o 3 in r* I*I5I H iU I-- to in ft. Hi <-t Ci ifnt iu Ul y in ft in D rt. lP-Aug-t}9 Lonoco Material Safety Data Sheet Page 2 MSDS No: MISC0011 HAZARDOUS REACTIVITY Instability : Stable. Hazardous Decomposition Products: Normal carbon dioxide? incomplete combustion may monoxide. combustion forms produce carbon Conditions to Avoid: Oxidizing materials, heat, flame. ******* ************************ **-#*********#*****#************##* *.***.*.**.* FIRE AND EXPLOSION DATA Flammable Limits in Air, 7. by Vol. LEL : <1 UEL : 10 Flash Point: Less than Ambient (Variable) FIRE AND EXPLOSION HAZARDS Flash point is variable; handle and store in accordance with NFPA procedures. Could be as hazardous as a Class IA Flammable Liquid - NFPA 30-1987. EXTINGUISHING MEDIA Dry Chemical. CQ2. F o am. SPECIAL FIRE FIGHTING INSTRUCTIONS Special Fire Fighting Procedures: Water may be ineffective to extinguish, but water should be used to keep fireexposed containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Water spray may be used to flush spills away from sources of potential ignition. Unusual Fire and Explosion Hazards: Products of combustion may contain carbon monoxide, carbon dioxide and other toxic materials. Do not enter enclosed or confined space without proper protective equipment including respiratory protection. MCD 000023552 1o-Aug-89 Conoco Material Safety Data -Sheet Page j MSD3 No: MISCOOU HEALTH HAZARD INFORMATION Primary Route of E xposure/" Ent ry : Inhalation, skin. Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure: Studies with mice or rats have shown that some petroleum distillates have caused either damage or tumors of the kidneys or tumors of the liver. However, kidney effects were not seen in similar studies involving guinea pigs, dogs or monkeys. Also, the significance of the liver tumors m rodents is highly speculative. Mouse skin painting studi es have shown that some crude oili caused a low incidence of tumors. However, these studies involved repeated exposur e of shaved skin which was never washed free of test mater ial. The product contains petroleum hydrocarbons wh ich may cause irritation to eyes, skin and lungs after prol onged or repeated exposure, Extreme exposure may caus e weakness, headache, nausea, confusion, blurred vision , drowsiness and other nervous system effects; greater e xposure may cause dizziness, slurred speech, flushed f ace, unconsciousness or convulsions. A few studies have indicated that workers exposed to high concentrations of benzene have a slightly incidence of leukemia. Benzene can also be toxic blood and blood-forming tissures. many years higher to the Carcinogenicity The following components are listed by IARC, NTP, OSHA, or r-tCuin as carcinogens. A 'P' indicates a Proposed Carcinogen. Chemical IAR NTP _-H Al Benzene XA DuPont controls the following chemicals as potential carcinogens Benzene . Exposure Limits for Crude Oil (Sweet) TLV ** (ACGIH) s None Established PEL (OSHA) : None Established Other PEL: Petroleum Distillate 400 ppm, 1600 mg/m3 Other Applicable Exposure Limits: 000023553 MCD 16-Aug-89 Conoco Material Safety Data Sheet Page 4 MSDS No: MISCOVll (HEALTH HAZARD INFORMATION - CONTINUED) Exposure Limits for Bensene AEL * (DuPont) TLV ** (ACGIH) PEL (OSHA) 1 ppm " 5 ppm 10 ppm, 1 ppm 5 ppm 0.5 ppm S & 12 Hr. TWA 15 Min. TWA 30 mg/m3 (A2) - 8 Hr. TWA - (Short term exposure - Action level limit) * AEL is DuPont's Acceptable Exposure Limit. TLV is a registered trademark. Safety Precautions Avoid breathing vapors or mist. Avoid contact with eyes. Avoid contact with skin. *******+************************** + ********#************************-*-**-*- FIRST AID INHALATION If inhaled, remove to fresh air. If not respiration. If breathing is difficult, physician. breathing, give artificial give oxygen. Call a SKIN CONTACT In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, consult a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water fos at least 15 minutes. Call a physician. INGESTION If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Call a physician. NOTES TO PHYSICIAN Gastric lavage by qualified medical personnel may be considered, depending on quantity of material ingested. *******+*#**# ************************************************^******************* PROTECTION INFORMATION Generally Applicable Control Measures and Procedures Ventilations Mechnical ventilation required only in emergency or extreme conditions, such as confined spaces. Personal Protective Equipment MCD 000023554 Respiratory Protections Select appropriate NIOSH-approved 16-Aug-89 Conoco Material Safety Data Sheet Page 5 MSDS No: MI SC001 I (PROTECTION INFORMATION - CONTINUED) respiratory protection where necessary to maintain exposure below acceptable limits. Protective Gloves: Neoprene or NE*R gloves should be worn to protect against chronic skin contact. Eye Protection: Safety glasses with side shields and/or face shield where splashing is present. Other Protective Equipment: present. Coveralls if slashing is +4 + *##### ********************-**-**#***-*********-**** *********#-****- *- + **-*-***- SPILL, LEAK AND DISPOSAL INFORMATION Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Contain spill immediately in smallest possible area. Recover as much of the product as possible by mechanical means, followed by recovering residual fluids by using absorbent materials. Nonrecoverable product, contaminated soil, debris and other materials should be placed in proper containers for ultimate disposal. Avoid washing, draining or directing material to storm or sanitary sewers. Waste Disposal Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and regulations. Recycle as much of the recoverable product as possible. ********************************************************************** SHIPPING INFORMATION ** DOT Flashpoint Proper Shipping Name: Hazard Class: UN/NA No.: Label: Placard: IATA/IMO Flashpoint < 100 deg F > or = 100 deg f Crude oil, petroleum Flammable liquid UN 1267 Flammable liquid Flammable Crude oil, petro.Combustible liqu i : UN 1267 None Combustible MCD 000023555 < 73 deg F > or = 73 deg t- 16-Aug-S9 Conoco Material b-afety Data Sheet Page o MSDS No: MISCuOil (SHIPPING INFORMATION - CONTINUED) Proper Shipping Name: Hazard Class: UN No.: IMU/ICAQ Label: Packaging Group: Petroleum Crude Oil 3 (3.2 IMu) UN 1267 Flammable liquid 11 Petroleum Crude Oil 3 (3.3 IMO) UN 1267 Flammable liquid III STORAGE CONDITIONS Store in accordance with National Fire Protection Assn regulations. REGULATORY INFORMATION FEDERAL REGULATIONS CERCLA, 40 CFR 302 Not Applicable SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, TITLE III - SECTIONS 302, 304, 311, 312, 313 SECTION 302/304 - Extremely Hazardous Substances, 40 CFR 355 The material does not contain extremely hazardous substances at greater than 1.0% concentration; however, it is possible that this material may contain extremely hazardous substances at a lower concentration so that a large enough spill could warrant an Emergency Release Report under Section 304. SECTION 311/312 - MSDS and Chemical Inventory Reporting Requirements, 40 CFR 370 The material should be reported under the following EPA hazard categories: x Immediate (Acute Health Hazard) x Delayed (Chronic Health Hazard) x Fire Sudden Release of Pressure Reactive Not Applicable Note: See the Hazard Determination Section for the concentration of any ingredients classified as hazardous by OSHA. SECTION 313 - List of Toxic Chemicals, 40 CFR 372 The material contains the following chemical(s) at a level of 1.0% or greater <0.1% for carcinogens) on the list of Toxic Chemicals and is subject to toxic chemical release reporting requirements. MCI) 000023556 l6-Aug-89 Conoco Material Safety Data Sheet Page 7 MSDS No: MISCOOll (REGULATORY INFORMATION - CONTINUED) Toxic Chemical: Benzene CAS Registry Number: 71-40-2 Approximate Concentration (Upper Bound): 2.0'X TOXIC SUBSTANCES CONTROL ACT (TSCA), 40 CFR 710 The material is a mixture as defined by TSCA. The chemical ingredients m this material are in the Section 8(b) Chemical Substance Inventory and/or are otherwise in compliance with TSCA. In the case of ingredients obtained from other manufacturers, Conoco relies on the assurance of responsible third parties in providing this statement. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA), 40 CFR 261, SUBPART C AND D The material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations; however, it could be considered hazardous if it meets criteria for being toxic, corrosive, ignitable or reactive according to U.S. EPA definitions (40 CFR 261). Additionally, it could be designated as hazardous according to state regulations. This material could also become a hazardous waste if it is mixed with or comes in contact with a listed hazardous waste. If such contact or mixing occurs, check 40 CFR 261 to determine whether it is a hazardous waste. If it is a hazardous waste, regulations 40 CFR 262, 263, 264 and 268 may apply. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 116, Section 311 The material contains the following ingredient(s) which is considered hazardous if spilled in navigable waters. Ingredient Petroleum Hydrocarbon Reportable Quantity Film or sheen upon or discoloration of the water surface or adjoining shoreline HAZARDOUS MATERIALS TRANSPORTATION REGULATIONS, 49 CFR 171-178 Not Applicable FOREIGN REGULATION CANADIAN HAZARDOUS PRODUCTS ACT (WHMIS) The material is a WHMIS Controlled Product Canadian MSDS is available. and a STATE REGULATIONS MCD 000023557 CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 ("PROPOSITION 65") i6-Aug-89 Conoco Material Safety Data Sheet Page 8 MSOS No: MISCOOll (REGULATORY INFORMATION - CONTINUED) The material contains mgredient(s) known to the State of California to cause cancer, birth defects or other reproductive harm. Read and follow label directions and use care when handling or using -all petroleum products. Ingredient: Benzene PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW ACT The material contains the following hazardous substances: Categories: S - Special Hazardous Substance (> or = 0.01%) H - Hazardous Substance (> or = 1.0%) E - Environmental Hazard (> or = 1.0%) Ingredient(s) Benzene Petroleum Distillates CAS Registry Number 71-43-2 Mixture Category E,S H Nonhazardous ingredient(s) information is withheld as trade secret in accordance with Section 11 of the Act. **-*-*-****-*-*-***-*-***#-**^-*-**-*****-*-*******'***-*****-****^**-****-****-ft-*--*--*-** * The above data are based on tests, experience, and other information which Conoco believes reliable and are supplied for informational purposes only. However, some ingredients may have been purchased or obtained from third-party manufactures. In these instances, Conoco, i good faith, relies on information provided by those third parties. Since conditions of use are outside our control, CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM USE OF THE ABOVE DATA. NOTHING CONTAINED HEREIN SHALL CONSTITUTE A GUARANTEE, WARRANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATm, THE MATERIAL DESCRIBED, OR ITS USE FOR ANY SPECIFIC PURPOSE, EVEN IF [hhT PURPOSE IS KNOWN TO CONOCO. Date of latest Revision Responsibility for MSDS : 89/06/29 : Env. & Occ. Health Services Conoco Inc. PO Box 2197 Houston, TX 77252 713-293-5550 MCD 000023558