Document RpNBdZzyMEr8ErZmM7BdbmKR8

1 Monsanto I Chemicals AROCLOR Incombustible Lubricants Used High-Pressure Compressors__J Monsanto Technical Bulletin No. P-128 April 15, 1948 Monsanto Chemical Company, St. Louis, 4 Mo. *** Selected AROCLORS*, chlorinated biphenyl, are effective Incombustible lubricants used in high-pressure compressors. Particularly Aroclor 1254 and also Aroclor 1248 are suggested for this purpose. 1. Aroclors eliminate explosion hazard 2. Tests Indicate that Aroclors withstand considerably higher bearing loads than mineral oils used In high-pressure compressors. 3. Wear-rate characteristics of Aroclors are superior to those of mineral oils. This bulletin describes the commercial use of Aroclor In highpressure compressors as related by R. W. Andrews and E. M. Kipp of the Aluminum Company of America. **** Registered in U.S. Patent Office. > o n 0 70 *0 * v 2. 2o * Cl. > 1M o i> CO o zr W c Z o c o The infoirnsuon in chi* bulletin i* b*ed on our experience, repiesentt our bee judgment is cbe matter, and i* intended to be helpful,but *e cannot assume responsibility for any less or accident that nay rcault from its use. 06U8736 TOWOLDMONOQ34299 INCOMBUSTIBLE LUBRICANT USED IN HIGH-PRESSURE COMPRESSORS Jteynal f. Andrews, Aluminum Company of America, and E. U Kipp, Aluminum Research Laboratories (published in the September 28, 1944, American Machinists Magatine) "LOCALIZED OVERHEATING of compressors in operation for long continuous periods pre sented an explosion hazard which has been eliminated through investigations made by the Aluminum Company of America. "Increased leakage of air through the valves and past the pistons causes the localized over-' heating, which often reached temperatures in excess of the flash and lire points of the beBt mineral oils. The presence of oil, oil vapor, or a mixture of oil fractions in the discharge lines and receivers combined with oxygen to support combustion need only be Ignited by a small particle of hot carbon to create a serious explosion. "The possibility of replacing air with an inert gas, such as nitrogen, was abandoned as too costly and difficult from the angle of supply. "Analysis Indicated that removal of all combustible material, such as air compressor oil, would 6olve the problem. Intensive study of organic compounds having a high boiling point led to the tentative selection of a group of biphenyl compounds containing a wide range of sub stituted chlorine in the biphenyl group. Known as Aroclors, these products vary in character from thin, combustible oil substance to an incombustible plastic solid. "One of the group known as Aroclor 1254 has neither flash nor ftre point and is a liquid at room temperature. Its physical data include: Form...........................Yellow-tinted viscous oil Flash Point................ None (Cleveland open cup) Fire Point.................None (Cleveland open cup) - Pour Point.................46 to 54 F. (ASTM) Viscosity.................. ..210 F., 43.5-48.5 . (Saybolt Universal 130 F., 280-400 Seconds) 100 F., 1,800-3,800 "Lubricating characteristics of the matertal were*compared with those of a number of stand ard-type mineral oils widely used as air compressor lubricants. Tests indicated that the material could withstand considerably higher applied bearing loads than the mineral oils be fore failure of the test-bearing piece occurred. Wear-rate characteristics of the material, with a variety of loads and running times, were superior to those of the mineral oils. Oxida tion stability and gum-forming characteristics were determined by heating samples to temperatures of 100, 210, 350 and 500 F., In conjunction with steel, copper, brass and alum inum. "The samples, in contact with the different metals, were held at high temperatures for periods of from six to twelve hours during which a current of air, saturated with moisture, was bubbled through the liquid. No evidence of the formation of hydrochloric acid was found except at temperatures of 350 and 500 F. No sludge was found In the material itself, although at temperatures of 350 and 500 F. some black, gummy sludge formed on the surface of each of the metals. At 350 and 500 F. the amount of oxidation and gas formation was far less than was evident when mineral oils were used under parallel conditions. = -t0b08737 TOWOLDMON0034300 "The field tests Indicated the necessity of procuring a special lubricator, and thermostatically controlled strip heaters for the lubrication suction tank to insure flow Of the material through the inlet ports of the lubricator pumping units. More than 15 high-pressure compressors of various types have been equipped for lubrication with this material and they have given satis factory service. Fxperlcnce indicates that the material should be used sparingly. Rate of feed should be comparable with the best practice for mineral oil lubrication. "The material's viscosity characteristic Introduces an operating problem in cases where room temperature falls appreciably below 70 F., although a properly selected lubricator should pump the material in the more viscous state as long as the suction tank Is heated to Insure the filling of the lubricator cylinders. Dilution with lighter liquids should be reserved as a last resort, as It adversely affects the non-combustible properties of the resultant mixture. "While explosions of air-hydraulic accumulators have been few In number, they have been devastating in effect. The fact that air compressed'to 4,500 lb. per sq. in. weighs approxi mately 23.5 lb. per cu. ft. Indicates a concentration of oxygen sufficient to support the combus tion of a substantial quantity of ordinary compressor oil. Test results have produced a lubri cant without flash or fire points to eliminate the threat of explosions." MONSANTO CHEMICAL COMPANY ,Saint Louis 4 Missouri New York* Chicago* Boston* Birmingham* Charlotte* Cincinnati* Cleveland Philadelphia* Detroit* Los Angeles* San Francisco* Montreal* Toronto poi-rk 1K-SD -I - 0508738 TOWOLDMONOQ34301