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ARR3G- IHS] J EE CATTT SE: - TRHi. LELL WHtreisgthatnd JE.0T0.. CChaensgseerre 2%E. 2.*7 ...DUSPPOECNITALCONCFOINDTERONLTIAL P.M. Humanick/ BRLEF.. RGaelaldows - cE . : +E.R1..A,FogSghinn * 3. A. Thoroug . : .: . .: JEuC F0.. MSceostotn . FETE : . . 22 Jgurinme 1978 -to. : JSadELo en} uRayc,y,e. p 0 Te: TC. Kuchler, Adnfnfstration Buflding ; Heng, From: R. D.Richardson,Jgo4 Bufldtng a EI Msg : FLUOROSURFACTANTS COMMINTCATION WITH CHAMBERS WORKS EMPLOYEES ' 7i"7.of"orgTahneicffolluloorwiinneg ssucbhsetdaunlceeshaiinbheeunmandevbellooopdedplafsomrat{hceopcyammaitntiaccahteido)ntoonChtahenbeprrsesWeon "personnel who handle fluorosurfactants and their intermedfates: i: Day/Date \ *Fri6/d2a3y/'18 Had Joes 3 Time Be4fpo.rme. 4pepf.omr.e Action ~ " Respons{bil aInnnfoournmceCmheanmtbertso oemrpklsoyeEexsecwuitlilvebSetamfafdetahtat 10 a.n., 6/21/78. : R. D. .Richar oo Stiuopnermveisssiaogne.will be provided. with a communica ** R:i D. Richar i T6u/e2s7d/a7y8 A8fta.emr. aSnudperlvociaslionUnwiiolnl ReipnrfeosremntUantiiovnesLeaders - co ChDeevneflcoaplmseAnrtesManufacturing ACorea : Jackson & Technical Laboratories EEnngviinreonemreinntgalDeparStemrevnitc)e*Department" General Analytical Laboratory)* R. J. Lyng RL.o JJ.. HLyanrgcot E. 0. Langer FEJTJ.. FMoegagdow RF. Staizer - - . 10 a.m. Supervision will inform 211 personnel who : hthaenidrleiorrtemranyedicaotnetsactinfltuhoeriorsuarsfsaicgtnaendtsworakn.d DCheevneflcoaplmsenAtreMaanufacturing Area Jackson & Technical Laboratories LR.JJ.. HLyanrgcot EO Langer GEST COPY AVAILABLE [Emi Li eur (Engineering Department)* (General Analytical Laboratory)* LyF. J. Meadow 3 RF Staize . 6Em/p2l1o/y7e8eswiwlhlobaereinfnootrnepdrewsheennt atthey10nae.xmt. EID110651 7s report tovork. }[_FoinritiTaalfmoermdaitciaoln opnrloyg.ram.EmpTlohyeeyesshoinuldthibse gardovuipsewdiolfl tmhoetprpaorgtriacmi,phaotweevienr.the 000121 : VERBAL COMMUNICATION TO CHAMBERS WORKS: EMPLOYEES HF WHHOOL HHAANNU DDLLEEOFLRUOROOSUS RFAU CTAR NTSF AANNDDATHTHC EEIIRRTINITNATEERRMNMEEDDIT IAATTES ESS has bTehcroomeughawairnefortmhaattioenlevsautpepdlieodrgabnyictheflu34oriCnoempalneyv,elsDuhaPyoent - oberegnandiectefcltueodriniantetdhe sbulrofoadctaonfts3Hawndorktehres ienxtpeorsmeeddiattoesceratsasionci- ated with their manufacture. These Works, but specific fluorochemicals we do manufacture a line are not used on the Chambers of fluorosurfactantsy The . CtheacmhbneorlsogyWoraknsd hfalvueoronsoturfbaecetnanitmspliacraetemda,nufaAsctuarepdrebcyautdiiofnfaerryent rmeeacsourrdes, anhdowetvoexri,colwoegiacrael rienvfioerwimnagtiohnandrieilnagtedprotcoedouurresf,luomerdoi-cal surfactants. blo|odAsofa Chpaamrbterosf fluorosurfactants Wtohrisks permopglroaymeetshewhoorgaanreicwofrlkuionrginewiltehvetlhesien will be determined for comparison with the the - tgheenereamlplopyoepeu'lsatinoenx.t rTehgiuslarchepclkantwilplhysbiecamladeexaatmintahteiotni.me of are noAt praewalrieminoafryanyrepaodrvtersferomheatlheth 3MefCfeocmtpsanyamoinngdicaaftfeedctetdhatemptlhoeyyee: 3M has manufactured fluorinated surfactants for over 20 years, : -an.werYeodu.r supervision will see that any questions you may have are - 6RO/R22/18 : . ' a ' z= 5 EID110652 g . 000122 ADDITIONAL INFORMATION FOR SUPERVISION : A 1976 report(?) indicates that the blood serum of the general apnodpulfantoirognanifcn tfhoerm.U.S.Theconctoanicnesntrtartaiceonquoafntiintoiregsaniocf fflluuoorriinnee hinas bobtehenors Tthoerbee irselanotedreatodyfelxupolraindaetifoonn ifnorwattheer psruepspelnicees of(naotrugraanlicafnlduoardidneed.). + and- hAandrleecenftluosrtoudsyurfbaycttahnets34anCdomptahneyirofintteherimrediwaotrekesrshaswhoremvaeanluefdactourrgean fthleusoerinoeperlaetvieolnss.in t3Mh.eirrepobrltoeodd tphlaatsmaa pinreleixmceisnsaryofrtehvoiseew noofttheengmaegdedicailr ahniystourniuseusalandheaclutrhrenctondhietaflotnhs.statAusmoroef daeftfaeiclteedd eemppildoeymeieosloghiacsalnotsturdevye:c 3M workers has been initiated. their3Mopeharsati{odnesn.tiffTehdesetwoareproabsasbolceiatkeedy wsiotuhrce(s1) ofeleecmtprloolyyeteicexpcoelslusre inii wfhnivcohlviknegy pionwtdeerrmeeddiaptreosducatrse. manufactured, and (2) packaging operations "factu:rTehde snopreciufsiecd opnrodtuhcetsChaimmbpelriscatWeodrksi.n thDeiff2eMresnttudyfluevoerosnuortfamcatnau.nts ` mfangnufaarcetausreadndonareChasmobledrsunWdoerrksthein "ZthoenylC"hemtircaadlesmarakn.d DTehveeloCphmeemnbtersManWuofrak hparnodcleesdsesthrdoougnhotoutinvinolvleiqueildectfroorlmsytiacnd flaureorianlasotiosnoldandin thleigupirdodufcotrsms.ar .** Diensgpiptreocetdhueredsisifmoirlafrliutoyrosbuertfwaecetnantthse DaundPoinntteramndedi3aHtetsechsnhooluolgdy,bealrlevihea for adequac.. Assistance may be obtained from R. J. Hubiak (X3415). currenAtlsypeceinaglagmeeddiicnalflupororgorsaumrfawcitllantbse oipneirtaitaitoends.forThaills pemrpolgoryaemeswill SnIountriftaibcaetlaenxpttrseo,ngdreabdmut tiwonhdoipceraastroeenntneohlatlwohnnogeecrehsasvieintvyop.lrveevdiS,oiumsiullnyalrelswyso,rktehEdengwirinetesheurltifsnlguoofrDoe-ptahre -" mnto,yeEensviwriolnlmenntoatl be& SienrcvliucdeedDeipnartthemenitnitainadl GepnreorgariamAntahloyutgihcatlheyLabsohroau . L. vdvised of the program. _the meTdhiecailnitrieaclordsspecoifalthemedeimcpalloyeper,ogranadm w(i2l)l spienccilauldebl(o1)oda arneavliyeswesofat time of the employee's regular physical examination. intermTehdiisatperso.gramOthiesr cofnlcueorrniendateodnlysuwbistthancfelsuorsuocshurfasact"aFnrteosn'andflutohreoicrar and fluoropolymers (e.g., "Teflon", "Viton", etc.) are not implicated. (*) SW.ympSo.siGuumy,, Ceth.iacla:g,o,Pr2o6ceAeudgiunsgts 1A9m7e5r,. PCahpeemr. 7,Socp.a,geFl1u17o.rine and Biological Chemis z= EID110653 g Tg 000123 was ta CC: R. E. Putnam 6/27 = 119::0000 DLiinveisiSounpv'Snu.p-eTrEinFtLeOnNdents 2:00 Affected Wage Roll June 27, 1978 TO: ACLHLIEFDIVCIHSEMIIOSNTSUPERINTENDENTS FROM: CP.RODH.UCTFOSSHUEPEERINTENDENT , FLUOROSURFACTANTS ANNOUNCEMENT Attached is a communications package pertaining to the presence of organic fluorine in the blood of 34 workers. We plan to communicate this information on Tuesday, June 27. Information in the attached letter to TEFLON Supervision should be communicated to TEFLONS, - TEFLON Research and TEFLON Laboratory wage roll personnel. The Questions and Answers are to be used as reference material to respond to questions. A communications package is being transmitted to unaffected divisions for information. CHAtFt:ascchments EID080241 000124 June 27, 1978 T0: TEFLON SUPERVISION FROM: C. H. FOSHEE EFLLUOUROOSRUORFSAUCTRAFNTASCIITNNBABLNLOOTOOSDD Du Pont does not manufacture these fluorochemicals, hDauvePobnetenhasdTehtrbeeoccutogemhde iiannwfaortrehmeattibholantoodeplroeofvvaitd3eeMddwoobrrykgeatrnhsiece2xfMplouCsooermdipannetyo,levels certain fluorinated surfactants. but and does purchase one of them for use in FEP dispersions in the Fluorocarbons manufacturing Division. Th TEFLON issurfcaocmmtoannltywkenouwsne is as Cp-e8r.fluoDuro-Poocnttandooiecs e maacniudfaacmtmuorneiduimfsfaelrtenatnd nfoltuobreiennateidmplsiucraftaecdtanwtisth athigDheeeprwabtleoro,d N. J. and levels. these have muasteedrifaolrs.tFhleiurormianrakteedd asbuirlfiacttyantotsmoadriefywattheer wseotltubalbeilicthyemiocfals oF C-8 have been detected among employees in more shay on fluorinatedoursurtfoaxcitcaonltosgichaavle taestlsowionrddiecrateof tthoaxticDiutyP.ont'Nso known ill effects which could be attributed to these chemicals years of experience with the products. relating to these materials, minimize Pu Pont's handling procedures exposure of employees to the have been designed to pAsrocaedpurreecsa,utmieodniacraylmeraescuorred,s, haownedvetro,xicsDeouloPfgolinuctoarliisniarntefevodiremsawutirinfoganctiatnsts, caF:se 5 - 00042S- EIDOSOX2 : QUESTIONS AND ANSWERS 1. 0. Wihnatbloiosd?the effect of elevated organic fluorine levels A. Ailnthtohueghblo3oMdhoasf wfooruknedrseleevxaptoesdedortgoanciecrtafilnuorfilnueorilneavteelds eifnfteecrtmsediianteasn,y otfheythehsaevewoirdkeenrtsifoiredinnotrhoesleateexdpohseeadlthto the surfactants but are continuing a broad investigation. 2. Q. DloeevselsDuinPontthehbalveoodinofformitastioenmplaobyoeuetsoerxgpanoiscedftlouotrhiensee materials? A. Not at this time. 2a. Q. A. Why not? eWexishtaedd noandreansoornmaltoblboeoldievteestasnywopurlodblenomtofshotwhitshitsypekind offluoirnifnoermaltevieolns.unlWeshsileyouwewehraveelnoootkinsgpecpirfeicciaslellyy for looked tathatflnuoorkinneownconhteeanltthinefftehectsblwoohdi,chwecouhladvebebeeanttrsiabtuitsefdied to these chemicals have been detected among employees. 3. 0. WaitllWasDhuinPgotnotnbWeorckosndwuhcotimngayblhoaovde bteeesntseoxnpoesemdplotyoees the fluorinated surfactant purchased from 3M? A. eWestawiblllishcheackbacskogmreouenmdplolyeeveelblfooordflleuvoerlisnattoed compounds. 4. Q. Are employees being notified of findings reported by 3M? A. ves. 5. Q. Wfhlautoripnraotdeudctssuarrfeacmtaanntusfapcutrucrheadsebdy DfuromPon3tM?using the . A. pThoelymmaetreirziaatlionpurprcohcaessesd ffroromma3k4inigs TusEeFdLONin tfhleuorocarbon dispersions. These dispersions contain only about moinlelitoenntohfoffluonoerinpaetrecdentsur(f,a0c01t)anto.r 1000 parts per z s 000126 EID080243 s -2- QUESTIONS AND ANSWERS 6. Q. What are uses for the dispersions? A. TsfEiuFbrLefrOasNcetaannftdlsumoeartroaeclasdr.ebsotnrIondyiestdhpeebrysciooathntesingsairenotpeeurrsiaentdgiotnporoctcoheaestsglass wshuircfhactiasntusseda.re nTohte doensltyroaypepdlicisatipoanckiwnhgesreantdhegaslkueotrso.- 7. Q. Where are gaskets and packings used? A. uWaesneydpooupnme'prtatpkianoconkwsinagwlslheratenhdelgpialqsaukcieedtsss,.arheowbeevienrgwetracnasnpoarstseudmemitghhatt 8. Q. iIlfinqguepisadtcsek,dingcbsoyulhadnudmatnhgsea?yskebtescoamrienguseidntoincosnytsatcetmswittohtrlainqsuipdosrt A. acIratetiiosinnspdoussistnirvbiolalelv.ionpgeHrooawutervieodrni,ss.pewresDiuboenlPsoinetviendmopeoassctknionotgfsstahanendctaigpoapnslki-etthse wpuaoscueklidonfgcsoumnesanidnitnegrcaesokdnettaTsEc,FtLOwaNintd,hapfsopuolcdih,caatbsievotenhrsaatgwehisenrveoorltvpheoedtmaiabntleerial water. . 9. Q. Airnevolavneyd?consumer products made and sold by Du Pont A. icNono.ulsducAhlrleaamcawhtaeytrhietahlacstonstuuhsmeienrgsuorfrflaucgoteraninentraatliesdpbusubulrrinfceadctaoarfneftspbreowfchoeircsehsed it goes to the consumer. 10. Q. bIesenthceoraeteadnywiptrhobTlEeFmLOiNnv?olved with cookware which has A. No. 11. 0. Wshuartfacitsamntesanthavwehena you low osradyerthoaft tDuoxiPcointty'?s fluorinated A. mBwaoytuelardi"ablleo.waobroudteraofcuptfouxliciotry"eiwgehtmefalunidthaotuncaesleotfhalthidsoes z =8 000127 EID030244 oo -3- QUESTIONS AND ANSWERS 12. Q. oIrnga3nMi'cs ffilnudoirnignse,whwihcaht wtehreey tfhoeundeleinvattehedirlewvoelrskerosf? A. Tohfethhiisghmeastterlieavlelin3Madepteercstoend'swabsloo4d5.parTthisspeirs meiqluallion ttootaalboubtlooonde-ctoennttehntofofatdheropaveofragtehehmuamtaenribaelingi.n the 13. . WbhyyDaurePno'ntt tihmeplfilcautoerdinbayted3M'ssurffaicntdainntgss?manufactured A. TahecomspulreftaecltyandtisffwehriecnhtDpuroPcoenstsmaannudfaacrteurcehsemiacrealmlayde by dthiefifreresnitmiltahran ftuhnocsteionmaaldeacbtyiv3iMt.y, Hoiwteviesr,posbseicabulsee tohfey mnoaydabteahavteo cionnfairsmimiorlardewnyaythbiust. at this point we have 14. 0. wIhfyDunotPounste'sthfelsueormiantaetredialssurfiancsttaenatdsofarepunrocthasiimnpglictahteemd, rom 3M to make TEFLON? A. dCihfefmeircealnltylyDuandPonatre'snoftlusouriitneadtedtostuhrefacetxainsttsingbehparvoecess for making TEFLON fluorocarbon resins. 15. Q. Aarbeoutoth3e4r'scofmipnadniinegss?involved and have they been alerted A. oTfheou3rM Cknoomwplaendygehasthensoetiafrieedthietsonclusytocmoemrpsa.niesToitnhethebest Uofnittheed Sitnaftoersmatiinovnoldveevde.lopepdu Ponontthiisntesnidtsuattoionshwairethalalny companies in the U.S. and worldwide who might be involved. 16. Q. WrielplortDeudPobnyt3Mb?e notifying customers of the findings A. We will share this information on a need-to-know basis. 17. Q. WaiglelnciDeusPoofnttbheisisniftouramitnigon?the appropriate regulatory A. Aattedthwisithpoitnhte finluotriimneewceonsteeentnoinsitghneifbilcoaondt. riTshkeasesxoisctie-nce | opufblfilsuhoerdineinionpeblnooldithearsatubreee.n known for 10 years and is : 000128 EID080245 Co Ce. QUESTIONS AND ASNWERS 18. Q. Aperresitshteesnet?fluorinated surfactants found in the blood A. pcPeourmbsplioisustnhedensdt.clointHteoarwiaentviuenrrge,oix3ny4dgiehcanasteasnidndtnihciaatttreofdgleuntohraaitrneaotregdanic owffalsutooerrgiapnnraiotcdeudcftlc.uoomrpiDonauatntdaesdaraecroemcposoneufcnlrdiescttediinngbaynaibtmohaueltsb.othdey as a existence 6-26-78 5 g 000129 EDU4