Document Rp7a1n8VQMeaRZggXOY5EwzMB

SUPPLIERS FOR SMOOTH PRODUCTION Postbus 281, 7500 AG Enschede NL Therrnen 5, 7521 PS Enschede NL T +31 53 435 32 35 F +31 53 433 61 37 E infoehardick.n1 Material safety data sheet PTFE glass, silicone adhesive backed 1: IDENTIFICATION 1.1Product Identifier Product name: PTFE-coated glass fabric with silicone adhesive 1.2 Relevant identified use of the product Industrial applications where high chemical and temperature resistance and excellent release is required 1.3 Details of the supplier of the material data safety sheet Company: HARDICK BV Address: Thermen 5 7521PS, Enschede The Netherlands E-mail: @hardick.nl Telephone: +31 53 435 32 35 2: HAZARD IDENTIFICATION 2.1 Classification of the product Our products are articles according Article 3 (3) of Regulation (EC) No. 1907/2006 (REACH) and therefore not subject of any legal requirements regarding Material Safety Data Sheets, safety assessment or testing. 2.2 Label elements Symbol: Signal word: Hazard statement: Precautionary statement: None Not applicable Not applicable P261 -- Avoid breathing any fume or dust that may be generated P264 -- Wash hands thoroughly after handling P370 -- In case of fire: Wear facemask and self-contained breathing apparatus Hardick by Rabobank Enschede Iban NL54RABO0317243403 Swiftcode RABONL2U Handelsreigister Enschede nr. 06032773 BTW nr. NL 0014 01 336 B01 www.hardick.nl Revision no. Revision date Page no. 2.0 Jan. 27, 2021 2 of 9 2.3 Other hazards The products are considered nonhazardous when used according to accepted practices for the intended use. Cut offs are very slippery when on the floor and can cause slipping. Material dust caused by cutting, sawing or sanding may cause eye and/or skin irritation. Exposure to fumes generated if the product is heated above 400C (752F) may result in "Polymer Fume Fever"flulike symptoms (chills, fever, tightness in the chest), appearing two or more hours after exposure and subsiding within 36 to 48 hours. Remove patient to fresh air and consult a physician if severe. Thermal degradation of the product at temperatures over 400C (752F) yields a range of highly toxic and corrosive products like carbonyl fluoride, hydrogen fluoride, carbon dioxide an carbon monoxide. 3: COMPOSITION / INFORMATION ON INGEDIENTS 3.1 Substances Not applicable 3.2 Mixtures Ingredient CAS# % by Weight Exposure limits1 Symbol Risk phrases Polytetrafluoroethylene Glass fiber cloth 9002840 65997173 25 - 57 33 - 49 N/A OSHA PEL - 5 mg/m3 ACGIH TLV - 5 mg/m3 None None None None Silioxane adhesive 556672 7 - 19 None None PVC liner 9002862 7 - 19 None None Above products are defined under the European Union's REACH regulation as articles and as such are exempt from the material data sheets provisions of 29 CFR 1910.1200 This product is REACH compliant and does not contain REACH SVHC's (Substances of very high concern) and is considered nonhazardous when used as intended and in accordance with recommended specifications and parameters. 4: FIRST AID MEASURES 4.1 Description of First Aid Measures Inhalation: Not applicable when product is used according accepted practices for the intended use. Processing at high temperature (> 400C (752F)) may generate fumes which can cause "Polymer Fume Fever". Remove the patient to fresh air and consult a physician if severe. 1 According to OSHA and ACGIH Revision no. Revision date Page no. 2.0 Jan. 27, 2021 3 of 9 If the PVC liner decomposes due to overheating or fire, remove affected persons to fresh air. If unwell after prolonged exposure, seek medical attention. Skin contact: Contact with dust caused by cutting, sawing or sanding may cause skin irritation. Also contact with the adhesive may cause skin irritation. Skin contact with molten PVC liner may cause burns. Wash with water and treat as for thermal burn. Eye contact: Contact with dust caused by cutting, sawing or sanding may cause eye irritation. Wash with plenty of water. If irritation persists, get medical attention. After eye contact with molten PVC liner, immediately flush with water for several minutes and get medical attention. Ingestion: If swallowed, get medical advice. Do not induce vomiting unless instructed by medical personnel. 4.2 Most important symptoms and effects, both acute and delayed Symptoms: Symptons of polymer fume fever may be delayed. Repeated episodes of polymer fume fever may result in persistent lung effects. Inhalation of decomposition products from overheating may cause lung irritation or shortness of breath Inhalation of decomposition products of the PVC liner may cause lung irritation. If necessary take action against irritation of the mucous membranes by HCl. 4.3 Indication of any immediate medical attention and special treatment needed Treatment: Treat symptomatically 5: FIRE FIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media are water, CO2, foam and dry chemical 5.2 Special hazards arising from the product Hazardous thermal decomposition products are: Hydrogen fluoride, fluorinated compounds, perfluoroisobutylene, tetrafluoroethylene, hexafluoropropylene, trifluoromethane and carbon oxides. The PVC liner may decompose in hydrogen chloride which form HCl when in contact with water. Revision no. Revision date Page no. 2.0 Jan. 27, 2021 4 of 9 5.3 Advice for firefighters Wear selfcontained breathing apparatus and protective suit. Wear neoprene gloves during cleaning up work after fire Protect from hydrogen fluoride fumes which react with water to form hydrofluoric acid Observe local regulations when contaminated water and burning waste are removed 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions: None For dust and fibers generated during sanding, sawing and cutting, use protective equipment 6.2 Environmental precautions Not applicable 6.3 Methods and materials for containment and cleaning up Collect solid product with broom and shovel and place in nonhazardous waste collection container for disposal. Collect dust and fibers generated during sanding, sawing and cutting by vacuming 6.4 Reference to other sections For disposal instructions, see section 13 7: HANDLING AND STORAGE 7.1 Precaution for safe handling Solid product which presents minimal hazards to personnel when handling in accordance with operating and storage recommendations. Wash hands thoroughly before smoking. Tobacco contaminated with PTFE can cause polymer fume fever Dispose in accordance with local regulations as a solid nonhazardous waste and avoid inappropriate disposal practices Do not incinerate PTFE waste or liner waste 7.2 Conditions for safe storage, including any incompatibilities No special precautions required but recommend storing in a dry cool place protected from contamination Revision no. Revision date Page no. 2.0 Jan. 27, 2021 5 of 9 8: EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Control parameters In abnormal situations in confined spaces where the temperature of the polymer exceeds 400C (752F), thermal degradation products may be produced. Exposure limits for these products, which include perfluoroisobutylene, carbonyl fluoride and hydrogen fluoride, must not be exceeded. Perfluoroisobutylene Carbonyl fluoride Hydrogen fluoride TLVTWA 10 ppb 2 ppm 0,5 ppm TLVSTEL 5 ppm 2 ppm IDHL (NIOSH) 30 ppm In abnormal situations in confined spaces where the temperature of the PVC liner exceeds 120C (248F), thermal degradation products may be produced. Exposure limits for these products, which include hydrogen chloride, must not be exceeded. Hydrogen chloride TLVTWA 2 ppm ceiling TLVSTEL 5 ppm ceiling IDHL (NIOSH) 50 ppm In situations where high levels of airborne dust/glassfibers are present, specified exposure limits must not be exceeded. Dust/glassfibers OSHAPEL 5 mg/m3 - nuisance dust PEL (respirable dust fraction) 15 mg/m3 - 8 hr TWA (total dust fraction) ACGIHTLV 5 mg/m3 - 8 hr TWA (inhalable) 1 fiber/cm3 - 8 hr TWA (respirable) Other 3 x 106 fibers/m3 - 10 hr TWA (NIOSH) 8.2 Exposure controls Engineering measures: Adequate ventilation must be provided when working with the product at elevated temperatures (>400C (752F)) If cutting, sanding or sawing of the product is necessary, to maintain exposures below recommended limits, a properly designed dust collection system is recommended. Eye protection: Throughout basic product handling processes and whenever handling materials containing fiberglass, safety glasses, goggles or face shield should be worn. Hand protection: Throughout basic product handling processes and whenever handling materials containing fiberglass, leather or synthetic fiber gloves are recommended to minimize cuts and abrasions. Revision no. Revision date Page no. 2.0 Jan. 27, 2021 6 of 9 Skin and body protection: To minimize exposure to fiberglass, the wearing of a lose fitting long sleeved shirt and long trousers are recommended. Hygiene measures: Wash hands immediately after handling the product and do not contaminate tobacco products Respiratory protection: Not required for normal use of the product. In situations where high levels of airborne dust/glass fibers are present, a correctly fitting NIOSH/MHSA approved disposable dust respirator should be used. In situations in confined spaces where the temperature of the polymer exceeds 260C (500F), an air supplied respirator should be used 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance: Physical state: Odour: Odour threshold: pH: Melting point (PTFE): Melting point liner (PVC) Boiling point: Flash point: Evaporation rate: Flammability: Upper/lower flammability or explosive limits: Vapour pressure: Vapour density: Relative Density: Solubility: Partition coefficient: noctanol/water: Autoignition temperature: Decomposition temperature (PTFE): Decomposition temperature liner (PVC): Viscosity: Light tan or black with yellow liner Solid Odourless Not applicable Not applicable 327C (621C) 60 - 90C (140 - 194F) Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable 0,25 - 1,5 g/cm3 Insoluble Not applicable Not applicable 400C (752F) 150C (302F) Not applicable 10: STABILITY AND REACTIVITY 10.1 Reactivity: Stable at normal ambient temperature and pressure 10.2 Chemical stability: Product is chemically stable Revision no. Revision date Page no. 2.0 Jan. 27, 2021 7 of 9 10.3 Possible hazardous reactions: Stable under recommended storage conditions 10.4 Conditions to avoid: Avoid heating for prolonged periods above the recommended upper usage limit 10.5 Incompatible materials: Alkali metals, strong oxidizing agents, halogenated compounds 10.6 Hazardous decomposition product: May include: fluorinated hydrocarbons, carbonyl fluoride, hydrogen fluoride, carbon oxides, perfluoroisobutylene, tetrafluoroethylene, hexafluoropropylene, trifluoromethane and hydrogen chloride (PVC liner) Note: List not restrictive, dependent on climatic conditions 11 TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects: Acute oral toxicity: Polytetrafluoroethylene, LD50/rat: > 11,280 mg/kg PVC (liner), recognized as safe and biologically inert Skin irritation: Polytetrafluoroethylene Polytetrafluoroethylene Human Rabbit Not classified as irritant Not classified as irritant No skin irritation No skin irritation Eye irritation: Mild eye irritation Sensitization: Polytetrafluoroethylene Human Not classified as skin sensitizer Does not cause skin sensitization Patch test on human volunteers did not demonstrate sensitization properties Repeated dose toxicity: Polytetrafluoroethylene Oral, feed rat: no toxicologically significant effects were found Mutagenicity assessment: Polytetrafluoroethylene Tests on bacterial or mammalian cell cultures did not show mutagenic effects Carcinogenicity assessment: Polytetrafluoroethylene Not classified as a human carcinogen Toxicity to reproduction assessment: Polytetrafluoroethylene No toxicity to reproduction STOTsingle exposure: No data available STOTRepeated exposure: No data available Aspiration hazard: Not applicable Revision no. Revision date Page no. 2.0 Jan. 27, 2021 8 of 9 12 ECOLOGICAL INFORMATION 12.1 Toxicity: Toxicity to fish (Polytetrafluoroethylene): The substance is a polymer and is not expected to produce toxic effects Toxicity to fish (PVC, liner): The substance is a polymer and is not expected to produce toxic effects 12.2 Persistence and degradability: No data available 12.3 Bioaccumulative potential: No data available 12.4 Mobility in soil: No data available 12.5 Results of PBT and vPvB assessment: No data available 13 DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods: Dispose in accordance with local regulations. Incinerate only if incinerator is capable of scrubbing out hydrogen fluoride and other acidic combustion products 14 TRANSPORT INFORMATION No transport restriction (DOT, ADR/RID, IATA/ICAO, IMO/IMDG) 15 REGULATORY INFORMATION 15.1 Safety, health and environment regulations/legislation specific for the substance or mixture Not applicable 15.2 Chemical safety assessment No data available Revision no. Revision date Page no. 2.0 Jan. 27, 2021 9 of 9 16 OTHER INFORMATION 16.1 Abbreviations and acronyms: Section 2.1 3.2 8.1 9.1 11.1 12.5 14 Abbreviation EC REACH CAS CFR OSHA ACGIH TLV TWA STEL IDHL NIOSH PEL ppb ppm pH PTFE PVC LD50 STOT DOT PBT vPvB ADR/RID IATA/ICAO IMO/IMDG Description European Commission Registration, evaluation, authorization and restriction of chemicals Chemical abstracts service Code of federal regulations Occupational safety and health administration USA American conference of governmental industrial hygienists Threshold limit value Time weighted average Shortterm exposure limit Immediately dangerous to life or health (NIOSH) National institute for occupational safety and health Permissible exposure limit Parts per billion Parts per million Potential of hydrogen, Acidity scale Polytetrafluoroethylene Polyvinyl chloride Lethal dose, 50%. Amount of substance required by body weight to kill 50% of the test population Specific target organ toxicity Department of transport Persistent, bioaccumulative and toxic Very persistent and very bioaccumulative Agreement on dangerous goods by road / Regulations concerning the international transport of dangerous goods by rail International air transport association / International civil aviation organisation International maritime organization / International maritime dangerous goods