Document Rp5QDaZEdX3E4XJwk41VXMgkk
U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration
MATERIAL SAFETY DATA SHEET
Form Approved OM8 No. 44-R1387
01
Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)
MANUFACTURER'S NAME
SECTION 1
EMERGENCY TELEPHONE NO.
-Richard Klinger Inc.____________
(513) 498-1(81
ACOBESS tXumber. Street. City. State, and ZIP Code)
--235Q Campbell Road____ Sidney. Ohio___45365__________
CHMCAt_ NAME ANO SYNONYMS
TRAOE NAME ANO SYNONYMS
Compressed Rubber Bonded Asbestos Sheet Packing Kiineer K-62 BLack
Chemical family
FORMULA
Mixture of SBR Rubber and Asbestos_________
N/A
SECTION II - HAZARDOUS INGREDIENTS
PAINTS. PRESERVATIVES. & SOLVENTS
y. TLV
(Units)
ALLOYS AND METALLIC COATINGS
pigments
carbon Black
0.52- 1.5 3.5ME/M3 BASE METAL
CATALYST
N/A
ALLOYS
VEHICLE SOLVENTS
N/A N/A
METALLIC COATINGS
FILLER METAL PLUS COATING OR CORE FLUX
Aoomves
N/A
OTHERS
OTHERS
N/A
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES
X
TLV (Units!
N/A
N/A
N/A N/A N/A
%
TLV (Units)
Chrvsotile Asbestos CAS #.1332-21-4 Stvrene Butadiene Polymer CAS #9003-55-8 Carbon Black CAS #1333-86-4_____
- Two fibers/cc greater than 5 urn in length.
70- 90 #i 8- 15 if 2
____ 1% 3.^fe>/M:
#2 - No TLV established.
SECTION III - PHYSICAL DATA
BOILING POINT (F.| VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR=1) SOLU8ILITY IN WATER
Decomposes N/A N/A
SPECIFIC GRAVITY (H:0*l)
PERCENT, VOLATILE BY VOLUME (%) EVAPORATION RATE
( , .... =U
Insoluble
apreahance and ooor Black with white spots.
1.65-1.85. N/A N/A
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FlASh POINT {Method used}
N/A
FLAMMABLE LIMITS
N/A
Extinguishing media
Water, Carbon Dioxide, Dry Powder, or Foam.
SPECIAL FIRE FIGHTING procedures
Firefighters should use self-contained breathing equipment and
eye
protection
for
the rubber fumes.
unusual fire and EXPLOSION HAZAROS
The rubber, once ignited mav need extra cooling to prevent reignition.
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PAGE (1)
(Continued on reverse side)
Form OSHA-20
R*v. May 72
2- -
SECTION V - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE (TLV) - Asbestos - 8 hour TWA (Time Weighted Average) of 2 fibers/cc greater than 5 um in length.
EFFECTS OF OVEREXPOSURE - The material in its finished form presents no known health hazard. A chronic health hazard may be created if further processing of the sheet allows asbestos fibers to be released into the atmosphere. Inhalation of free asbest's fiber over a long period of time can cause lung disorders, including asbestosis, pleural plaque, lung cancer, and mesothelioma.
SECTION VI - REACTIVITY DATA
STABILITY - The material has infinite storage stability.
INCOMPATABILITY - Strong oxidizers, strong acids, or bases.
HAZARDOUS DECOMPOSITION PRODUCTS - Burning rubber (See Section IV), and free asbestos (See Section V).
HAZARDOUS POLMERIZATION will not occur.
SECTION VII - SPILL OR LEAK PROCEDURES
I
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED - Dust from sheet should be treated as free asbestos. Secure area and clean up using HEPA-filtered vacuum, or wet sweep. DO NOT clean up in a method that generates dust into atmosphere.
WASTE DISPOSAL METHOD - Bury in solid landfill as required by 29 CFR 1910.1001 (N)C.!.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION - None required where local controls ensure negligible asbesc.'s dust released into atqnosphere. Where local controls not adequate, use respirator approved pursuant to 29.CFR 1910.1001 (D)(2). See section IX - Special Precautions.
VENTILATION - Where dust producing processes are used, local ventilation, air filtrar and good work hygiene must be used to ensure negligible asbestos dust released to atmosphere.
EYE PROTECTION - None required for normal use.
OTHER PROTECTIVE EQUIPMENT - None required for normal handling or fitting of gasket'. Where gasket removal involves scraping, wire brushing, or other potential dust pro ducing operations; local ventilation, air filtracion, good work hygiene, and where applicable, wetting down should be used to ensure negligible asbestos dust releasei
a tmosphere.
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING - In the manufacture of Klinger com
pressed asbestos sheet packing, the asbestos is encapsulated into the sheet by a rubber matrix. In normal handling of sheet and cut gaskets, no significant release of asbestos dust occurs. In the production of cut gaskets; local ventilation, air filtration, and good work hygiene must be used where the production process may release fibers into the workplace. The material must not be drilled, sawed, gr'\:-!'. sanded, or subjected to any other dust producing process without the necessary equ: - ment required to ensure that released fibers are contained.
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SECTION X - DATE AND SOURCE OF INFORMATION
DATE - November 20, 1985 NAME - Derek Coomber.
resident ISSUE *185-01
SECTION V HEALTH HAZARD OATA
THRtjHOLO LIMIT VALUE
N/A (See IX Below)
EFFECTa OF OVEREXPOSURE
E,. 'ENCY AND FIRST AIO PROCEDURES
STABILITY
UNSTABLE
SECTION VI - REACTIVITY DATA
CONDITIONS TO AVOID
STABLE INCOMPATABILITY (Materials to avoid)
X
HAZARDOUS DECOMPOSITION PROOUCTS
Infinite Storage stability Strong Oxidizers/Acids/Alkalis
HA2AROOUS POLYMERIZATION
MAY OCCUR
WILL NOT OCCUR i
CONOrriONS TO AVOIO
X
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
N/A
- Y'- -
WASTE DISPOSAL METHOD
Sanitary landfill in accordance with State and Federal Regulations.
SECTION VIII - SPECIAL PROTECTION INFORMATION
respiratory protection (Specify type)
VENTILATION
LOCAL EXHAUST
None
required
MECHANICAL (General)
SPECIAL OTHER
PROTECTIVE GLOVES
None required
EYE PROTECTION
None required
other protective equipment
Special precaution not needed in normal handling-or.
gac;VF>t - (See TY he!owl
SECTION IX - SPECIAL PRECAUTIONS
,
..sheet
PRECAUTIONS TO BE TAKEN IN HANOLINQ ANO STORING
If drilled, sawed, sanded,
ground or subjected to any other dust producing process, dust level )ther precautions not to exceed 10 MG/M . (Nuisance Dust)
PAGE (2)
cro U4.no
Form OSHA-20
Rtv. My 72
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