Document RawnDgDz8GNDb878ZGJ5rpQZX

Jean B. Sweeney Vice President 3M Environmental, Health and Safety Operations R rvC E !v r n 'l 3M Center, Building 0224-05RV-1)3 St. Paul, MN 55144-1000 651 737 3569 April 13,2010 Document Processing Center (Mail Code 7407M) Room 6428 Attention: TSCA 8(e) Coordinator Office of Pollution Prevention and Toxics U.S. Environmental Protection Agency 1200 Pennsylvania Ave. N.W. Washington, D.C. 20460 226' 3?36 Re: TSCA Section 8(e) Notice: Sulfonate-based and Carboxylic-based Fluorochemicals, Docket 8EHQ-0598-373 - Emerald Coast Utilities Authority Information Dear Sir/Madam: 3M is one of several defendants in litigation in federal court in Pensacola, Florida, brought by the Emerald Coast Utilities Authority ("ECUA"). ECUA contends that low levels of PFOA and PFOS are present in some of its drinking water supply wells. ECUA indicated that it had tested four drinking water supply wells in November 2006 and identified the presence of PFOA and PFOS at low parts per trillion levels in those wells. As EPA may be aware, ECUA published a summary of those data in its 2006 annual Consumer Confidence Report under the Safe Drinking Water Act, which is reported to the Florida Department of Environmental Protection pursuant to EPA regulations. As part of discovery in the litigation, ECUA has now provided 3M and the other parties with additional data in the form of a laboratory report from Columbia Analytical Sendees, reporting on testing conducted for the litigation of 28 supply wells (including the original four wells) for various perfluorinated alkyl acids. We enclose a copy of the 2006 report and this more recent 2010 report. 3M cannot vouch for the reliability of the data. The analyses do not appear to follow EPA Method 537 for determination of perfluorinated alkyl acids in drinking water, and we have not been provided with the analytical method, method validation or supporting quality control data. Although 3M does not believe the enclosed data meet the reporting threshold of TSCA Section 8(e), we recognize the ongoing work by U.S. EPA to assess fluorochemical exposure pathways, and we are therefore placing a notification in the TSCA 8(e) docket. WDC IMANAGE-1483131.1 OONTMNSNOCa 3 L.(o 22 Docum ent P ro ce ssin g C enter (Mail C o d e 7407M) Page 2 p .2 If you have any questions, please do not hesitate to contact Dr. William Reagen at (651) 733-9739 or Gary Hohenstein at (651) 737-3570. Sincerely, Jean B. Sweeney Staff Vice President 3M Environmental, Health and Safety Operations Enclosures (2) WDC IMANAGE-1483131.1 Baron & Budd, P.C. Emerald Coast U tilities Authority Production W ell Sam pling Results Escambia County, Florida February 2010 Final Letter Report P-4 CDM 3522 Thomasville Road, Suite 300 Tallahassee, Florida 32309 Office: 850-386-9500 Fax: 850-668-6745 CDM Transmittal Confidential Client Material To: Organization/ Address: Re: Mr. Chad A. West, Attorney From: Baron & Budd, P.C. 3102 Oak Lawn Avenue, Suite 1100 Date: Dallas, Texas 75219 ECUA - Production W ell Sam pling Results Escambia County, Florida David L. Anderson February 24,2010 Job#: 95779-75319 Via: Mail: Overnight: X Courier: Enclosed please find: For your information X Approved For your review X Approved as noted For your signature Returned to you for correction Message: Mr. West, Camp Dresser & McKee Inc. is pleased to submit this letter report to Baron & Budd summarizing the analytical results of the February 2010 comprehensive groundwater sampling event. One original (with Appendix D lab data) and one copy (Appendix D compact disk) are provided for your use. If you have any questions regarding this submittal, please contact me at (850) 386-9509 or by email at andersondl @cdm .com. Copy: Michael H. Edgar - CDM/Tallahassee Signed CDM 3522 Thom asville Road, Suite 300 Tallahassee, Florida 32309 tel: +1 850 386-9500 fax: +1 850 668-6745 P-5 February 24, 2010 CONFIDENTIAL CLIENT MATERIAL Mr. Chad A. West, Attorney at Law Baron & Budd, P.C. 3102 Oak Lawn Avenue, Suite 1100 Dallas, Texas 75219 Subject: Emerald Coast Utilities Authority - Production Well Sampling Results Escambia County, Florida CDM Project No. 95779-75319 Dear Mr. West: Camp Dresser & McKee Inc. (CDM) is pleased to present this letter report to Baron & Budd, P.C. (B&B) summarizing the February 2010 groundwater sampling of production w ells within the Emerald Coast Utilities Authority (ECUA) water distribution system. These services were performed in accordance with CDM's scope of services and cost estimate dated January 15, 2010--approved by B&B on January 25,2010. Groundwater samples were collected and analyzed for Perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), and other related fluorinated compounds. The U.S. Environmental Protection Agency and the Florida Department of Environmental Protection (FDEP) have not established maximum contaminant levels for these compounds. This letter report presents the groundwater sampling methods and groundwater analytical results. Groundwater Sampling Methods Raw and treated groundwater sam ples were collected from 28 of the 32 active production wells w ithin the ECUA water distribution system. A production w ell location map (which identifies w ells w ith raw water treatment systems) is included in Appendix A. From February 1 to February 3,2010, samples were collected by a Florida-Registered Professional Geologist trained and experienced in FDEP sam pling protocols in accordance with the procedures described in the FDEP Standard Operating Procedures (SOP) FS 2000 and FS 2300. FDEP's sam pling documentation procedures were follow ed as described in FDEP SOP FD 5000 and FD 5100. Field parameters (pH, specific conductance, temperature, dissolved oxygen, and turbidity were measured during purging in accordance with procedures described in FDEP SOPs FT 1100, FT 1200, FT 1400, FT 1500, and FT 1600. In addition, oxidation-reduction potential readings were collected in the field. co n s u ltin g engine e ring construction operations 2010-02-24_BB W ell Sampling Results Letter Report.docx CDM P-6 Mr. Chad A. West, Attorney at Law February 24,2010 Page 2 ECUA staff escorted CDM staff during the sampling activities due to security reasons. A photograph log of all 32 w ells is included in Appendix B. The follow ing sample collection procedures were followed at each w ell location: Samples were collected during active groundwater pumping. Sam pling ports (raw and treated) were opened upon arrival at each site to flush the lines. Field parameters were collected every 3 minutes and recorded until stable. Raw samples were collected at the wellhead and treated samples were collected at the nearest sampling port downstream of final treatment. Samples were collected at a flow rate of approximately 100 milliliters per minute in laboratory supplied bottleware. Samples were labeled, bagged, and stored on ice to maintain a temperature of 4 degrees C elsius (4C). Chain-of-custody forms were completed prior to departure from an individual w ell site location. Samples remained in the custody of CDM prior to nightly overnight shipment (next morning delivery) to the laboratory. At the request of B&B, groundwater samples were analyzed by Columbia Analytical Services (CAS) of Kelso, Washington. Each sample was analyzed for PFOS, PFOA, and other fluorinated compounds by CAS Method HPLC/MS - PFOA. Three field blanks samples were collected (one each day prior to initiating sampling) to document: Sampling environment. Analyte-free water chemistry. Clean bottleware. Sample transport. Storage conditions as required by FDEP field quality control requirements (FDEP SOP FQ 1230). 2010-02-24_BB Well Sampling Results Letter Report-docx CDM p .7 Mr. Chad A. West, Attorney at Law February 24, 2010 Page 3 Matrix spike/m atrix spike duplicate samples (raw and treated) were collected at the Bronson and M cAllister production w ells as requested by CAS. Groundwater Analytical Results The follow ing 28 production w ells were sam pled in the following order: February 1, 2010 1. Ellyson. 2. D avis. 3. O live. 4. Carriage Hills. 5. Watson. 6. K ingsfield Road. 7. Cantonment. 8. N ine Mile Road. February 2, 2010 9. University Parkway. 10. McCory. 11. Dunaway. 12. Lillian. 13. Bronson. 14. W est Pensacola. 15. "W" & Avery. 16. West Plant Well. 17. "F" & Scott. 18. No. 6 WeH Plant. February 3, 201.0 19. Hagler Well Plant. 20. Spanish Trail. 21. Airport North. 22. McAllister. 23. Humphrey. 24. Broad. 25. Tennant. 26. Muldoon. 27. Villa Drive. 28. Royce Street. The follow ing four w ells were not sam pled due to the reasons stated below: 1. Avondale - the pump motor w as hit by lightning in late January 2010 and was not in operation during the sampling event. See Page 26 in Appendix B. 2. F.nsley - the site has been inactive for several years and ECUA has no plans to reactivate the w ell. The discharge lines from the w ell have been plugged and the wellhead has no power.. See Page 30 in Appendix B. 3. Sw eeney - the entire site is currently undergoing complete rehabilitation including underground piping, electrical, a new pump house building, and w ell modifications. This project is expected to be com plete by the fall of 2010. See Page 31 in Appendix B. 4. 01,1-4 A - the w ell w as down because of routine maintenance including extraction of the w ell screen for cleaning. See Page 32 in Appendix B. 2010-02-24_BB Well Sampling Results Letter Report.docx CDM Mr. Chad A. West, Attorney at Law February 24,2010 Page 4 Table 1 is a summary of the CAS analytical data. PFOA concentrations ranged from nondetect (in several wells) to 68 nanograms per liter (ng/1 (or parts per trillion)) in the treated sample from the Bronson well. PFOS concentrations ranged from 0.19 n g/L in the raw sample collected from the Cantonment w ell to 240 n g/L in the treated sample collected from the Hagler well. A groundwater sample collection sheet (raw and treated) for each w ell location and field equipm ent calibration logs are in Appendix C. Hard copies of die CAS analytical reports (including chain-of-custodies, Tier IV Quality Assurance Data Validation Package, matrix sp ik e/ matrix spike duplicate results, and surrogate results) and a compact disk of the data are in A ppendix D. If you have any questions concerning this letter report, please call me at (850) 386-9503 or email m e at edgarmh@cdm.com. Sincerely, Vice President Camp Dresser & McKee Inc. Enclosures: Appendix A - ECUA Production Well Location Map Appendix B - Sample Port Photograph Log Appendix C - Groundwater Sample L ogs/Field Calibration Logs Appendix D - Analytical Data/Chain-of-Custodies (Compact Disk and Hard Copy) c: D avid L. Anderson - CDM/TAL 2010-02-24_BB Well Sampling Results Letter Report.docx nic Acids *nd Perfluorinated HPLC/MS loie Acid c Add nate id >nate id \cid :id mate d d nate (PFOS) 1 (PFOA) id \dd _____________________________ i Units 1 1 Standard 1 | Raw ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L '.g't 0.46 U 0.95 U 0.029 U 0.31 J 0.095 U 0.48 U 0.65 U 0.081 U 0.12 J 0.34 J 0.12 U 0.39 J 0.066 U 0.40 J 13 U 0.46 U 0.95 U 1.6 J 1.9 J 0.095 U 0.48 U 0.85 U 2.7 J 9.3 4.2 J 4.1 J 12 6.8 4.7 J 3o Treated 0.46 U 0.95 U 1.6 J 1.6 J 0.095 U 0.48 U 0.85 U 2.7 J 9.2 4.4 J 4.5 J 12 6.9 4.7 J i 3L ---- Raw Treated " ** Raw 1 Treated | A. f , 1W Raw Treated 1.0 J 0.95 U 0.91 J 0.89 J 0.23 J 0.48 U 0.85 U 1.4 J 3.0 J 2.1 J 0.36 J 4.1 J 4.0 J 2.4 J ,:u - 0.46 U 0.95 U 0.93 J 0.89 J 0.13 J 0.48 U 0.85 U 1.2 J 3.2 J 1.9 J 0.35 J 4.2 J 4.2 J 2.2 J ' 3 l" 0.46 U 0.95 U 2.5 J 2.9 J 0.095 U 0.48 U 0.85 U 4.4 J 9.6 7.3 1.9 J 9.1 10 7.9 13 U 0.46 U 0.95 U 2.6 J 3.0 J 0.095 U 0.48 U 0.85 U 4.5 J 9.6 7.3 1.8 J 9.5 9.8 8.1 t3J 0.46 U 0.95 U 0.32 J 0.36 J 0.095 U 0.48 U 0.85 U 0.32 J 1.6 J 0.79 J 0.12 U 1.6 J 1.3 J 0.84 J 1.3 J 0.46 U 0.95 U 0.31 J 0.31 J 0.23 J 0.48 U 0.85 U 0.34 J 1.5 J 0.69 J 0.12 U 1.4 J 1.2 J 0.76 J 1.3 U 4. /. I V Raw Treated .'M V Raw Treated Rai 0.46 U 0.95 U 0.46 J 0.39 J 0.14 J 0.48 U 0.85 U 0.53 J 2.8 J 0.90 J 0.80 J 3.1 J 1.9 J 1.0 J 1.3 U 0.46 U 0.95 U 0.32 J 0.51 J 0.095 U 0,48 U 0.85 U 0.30 J 0.65 J 0.85 J 0.26 J 0.46 J 0.85 J 1.2 J l.3 0 0.88 J 0.95 U 0.12 J 0.14 J 0.16 J 0.48 U 0.85 U 0.081 U 0.17 J 0.11 u 0.12 U 0.22 J 0.066 U 0.31 J l.3 U 0.46 U 0.95 U 0.13 J 0.25 J 0.095 U 0.48 U 0.85 U 0.28 J 0.26 J 0.60 J 0.12 U 0.33 J 0.066 U 0.96 J i .3 U 0.46 0.95 0.11 0.22 0.095 0.48 0.85 0.29 0.16 0.48 0.12 0.19 0.066 0.28. 1.31 13C5) Nonanoic Acid 1C4) Butanoic Acid JC4) Octanoic Acid i Decanoic Acid ) Hexanoic Acid i Dodecanoic Acid i Undecanorc Acid 2,3,4-13C4) Octane Sulfonate xane(1802) Sulfonate % Recovery % Recovery % Recovery % Recovery % Recovery % Recovery % Recovery % Recovery % Recovery 103 81 90 100 83 67 56 77 80 95 90 96 88 91 98 99 104 103 107 131 76 81 79 83 82 81 75 80 77 88 89 85 102 57 46* 104 93 106 94 99 100 108 113 111 111 133 84 75 100 100 100 100 100 100 100 100 100 100 100 100 100 82 82 81 86 83 86 79 92 94 91 104 66 51 59 61 55 62 51 49* 47* 64 51 66 72 49* 52 50 49* 51 48* 47* 46* 42* 60 48* 56 72 45* 49* 74 71 70 67 66 68 77 80 77 77 100 67 77 82 81 84 81 84 80 78 90 93 87 106 90 80 otentiai mV Standard Units C uS/cm mg/L NTU Observation Observation NA NA NA NA NA NA Clear None NA 5 69 21.4 80 7.3 0 Clear None 192 7 08 21.1 150 7.5 0 Clear None 284 NA 21 7 71 4.2 0 Clear None 395 7.12 19.0 192 5.8 0 Clear None 299 5.32 21.5 96 7.0 1 Clear None NA 6.38 20.5 138 6.9 1 Clear None NA 4.60 22.1 37 7.6 0 Clear None NA 7.14 21,7 82 6.3 1 Clear None 300 5.43 21.6 NA 5.4 0 Clear None NA 7 13 21.9 149 4.6 0 Clear None 221 5.06 21.1 37 3.6 0 Ciear None 576 6.88 21 0 122 3.9 1 Clear None NA 5.66 21.0 33 5.5 0 ---------- - a Clear None w tim p iB w a te Units Standard Raw Treated Raw Treatod | Raw Treated Raw Treated I Raw Treated 4.4. IV Rew Treated 4.4. / V Raw Treated Ran ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L 0.46 U 0.95 U 0.029 U 0.47 J 0.095 U 0.48 U 0.85 U 0.081 U 0.19 J 0.23 J 0.12 U 0.18 J 0.066 U 0.33 J 1.3 U 0.46 U 0.95 U 0.12 J 0.18 J 0.095 U 0.48 U 0.85 U 0.12 J 0.18 J 0.35 J 0.12 U 0.31 J 0.066 U 0.28 J 1.3 U 0.46 U 0.95 U 0.13 J 0.55 J 0.18 J 0.48 U 0.85 U 0.081 U 0.18 J 0.11 u 0.12 U 0.26 J 0.066 U 0.14 J 1.3 U 0.46 U 0.95 U 0.35 J 0.42 J 0.095 U 0.48 U 0.85 U 0.48 J 1.7 J 1.1 J 0.12 U 0.95 J 5.2 0.88 J 1 .3 Li 0.46 U 0.95 U 0.35 J 0.40 J 0.12 J 0.48 U 0.85 U 0.54 J 1.8 J 1.0 J 0.12 U 0.88 J 5.0 0.82 J i. 3 :J 0.46 U 0.95 U 0.15 J 0.29 J 0.095 U 0.48 U 0.85 U 0.15 J 0.56 J 0.34 J 0,12 U 0.47 J 0.066 U 0.33 J 1.3 U 0.46 U 0.95 U 0.14 J 0.15 J 0.095 U 0.48 U 0.85 U 0.093 J 0.55 J 0.33 J 0.12 U 0.38 J 0.066 U 0.18 J 1.3 U 0.46 U 0.95 U 1.9 J 2.0 J 0.26 J 0.60 J 0.85 U 2.9 J 6.7 4.7 J 0.67 J 13 9.2 5.1 .3 u 0.46 U 0.95 U 1.9 J 1.8 J 0.095 U 0.48 U 0.85 U 3.0 J 6.8 4.6 J 0.56 J 11 8.5 5.2 1.3 J 0.46 U 0.95 U 4.5 J 5.4 0.16 J 0.48 U 0.85 U 7.7 33 14 0.98 J 56 25 13 1.3 U 0.46 U 0.95 U 12 9.7 0.095 U 0.48 U 0.85 U 18 98 37 1.6 J 81 68 32 1.3 U 0.46 U 0.95 U 0.76 J 0.54 J 0.095 U 0.48 U 0.85 U 0.74 J 2.6 J 0.92 J 0.63 J 5,9 2.7 J 0.87 J 1.3 U 0.46 U 0.95 U 0.029 U 0.25 J 0.095 U 0.48 U 0.85 U 0.081 U 0.17 J 0.21 J 0.12 U 0.28 J 0.066 U 0.38 J 1.3 U 0.46 U 0.95 U 1.2 J 1.1 J 0.095 U 0.48 U 0.85 U 1.6 J 5.8 2.7 J 0.41 J 5.5 4.4 J 2.6 J 1.3 U 0.46 U 0.95 U 1.2 J 1.1 J 0.095 U 0.48 U 0.85 U 1.7 J 5.9 2.8 J 0.47 J 5.9 5.0 2.6 J l .3 u 0.46 I 0.95 l 1.1 * 0.76. 0.30. 0.48 I 0.85 l 1.2 J 4.1 J 1.8 J 0.56. 7.1 4.4 J 1.4 J 1.3 u % Recovery % Recovery % Recovery % Recovery % Recovery % Recovery % Recovery % Recovery % Recovery 98 73 94 100 75 60 48* 71 70 78 86 97 77 94 87 83 79 95 89 90 93 98 91 94 55 11* 68 66 68 58 74 71 72 74 68 80 74 70 73 78 86 93 82 85 90 88 92 105 90 102 100 105 107 112 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 62 75 71 72 75 65 80 77 83 82 73 86 84 79 82 55 43* 56 47* 68 56 46* 48* 56 52 41* 48* 56 42* 49* 54 47* 60 49* 68 56 47* 39* 49* 52 44* 46* 47* 42* 40* 60 03 74 60 75 75 64 60 70 74 63 64 71 61 68 71 75 83 81 85 76 89 82 81 91 83 82 96 86 87 mV Standard Units c uS/cm mg/L NTU Observation Observation NA NA NA NA NA NA Clear None 188 NA 21.5 37 4.8 0 Clear None 151 7.01 21.1 177 3.9 2 Clear None NA 5.88 21.2 44 7.0 0 Clear None 511 7.01 21.2 110 6.9 0 Clear None 340 5.53 21.0 91 4.8 0 Clear None NA 6.64 20.3 34 4.8 0 Clear None NA 5.77 222 100 4.5 0 Clear None NA 719 21.3 228 3.2 2 Clear None 346 5.83 24.3 40 3.4 0 Clear None 785 7.21 23.1 40 0.2 0 Clear None NA 5.38 22.3 71 5,8 0 Clear None 483 7.15 21 7 180 3.9 0 Clear None NA 571 22.0 107 7.3 1 Clear None 604 7.10 21,8 187 5.4 1 Clear None 471 6.08 21.9 109 3.6 0 u Clear N cxP -- 1----------Units -- Standard -- Raw Treated ------- -- * Raw Treated | ...... Raw Treated | Raw ~1 Treated | .*** Raw Treated a.,% *. i %r Raw Treated Raw Treated Ran ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng/L ng'l 0.46 U 0.95 U 0.020 U 0.17 J 0.095 U 0.48 U 0.85 U 0.081 U 0*12 J 0.18 J 0.12 U 0.19 J 0.066 U 0.14 J 13 0.46 U 0,95 U 44 32 0.19 J 1.1 J 0.85 U 46 170 120 7.3 220 39 96 13 U 0.46 U 0.95 U 45 33 0.14 J 0.79 J 0.85 U 51 180 130 7.6 240 42 100 13 U 0.46 U 0.95 U 8.4 4.1 J 0.13 J 0.48 U 0.85 U 9.4 64 24 20 11 23 h 13 0 0.46 0.95 U 8.7 4.3 J 0.11 J 0.48 U 0.85 U 9.3 64 23 22 11 24 11 13U 0.46 U 0.95 U 5.0 J 2.9 J 0.48 J 1.0 J 1.1 J 6.5 34 14 58 32 14 7.8 2.2 J 0.46 U 0.95 U 4.8 J 2.9 J 0.34 J 0.54 J 1.0 J 6.0 31 14 54 30 15 8.0 13U 0.46 U 0.95 U 5.8 5.0 0.13 J 0.83 J 0.85 U 16 55 26 140 150 38 13 3.1 J 0.46 U 0.95 U 0.29 3 6.7 0.57 J 0.62 J 1.3 J 0.32 J 0.30 J 0.95 J 0.56 J 0.77 J 0.45 J 3.3 J 1.9 J 0.46 U 0.95 U 1.6 J 1.3 J 0.49 J 0.48 U 0.87 J 3.1 J 7.5 4.8 J 0.61 J 5.9 7.9 3.7 J 3J 0.46 U 0.95 U 0.029 U 0.21 J 0.13 J 0.48 U 0.85 U 0.081 U 0.12 J 0.11 J 0.12 U 0.20 J 0.22 J 0.20 J 1.3 C 0.46 U 0.95 U 0.25 J 0.29 J 0.75 J 1.0 J 1.2 J 0.29 J 0.59 J 0.50 J 0.63 J 1.7 J 1.8 J 0.44 J 1.6 J 0.46 U 0.95 U 0.38 J 0.33 J 0.25 J 0.49 J 0,85 U 0.37 J 0.65 J 0.71 J 0.34 J 1.2 J 2.1 J 0.56 J 1,3 U 0.46 U 0.95 U 0.81 J 0.80 J 0.17 J 0.48 U 0.85 U 1.6 J 3.2 J 2.3 J 0.66 J 5.9 3.2 J 2.1 J 1.3 J 0,46 U 0.95 U 0.67 J 0.81 J 0.12 J 0.48 U 0.85 U 1.3 J 3.5 J 2.1 J 0.57 J s.a 3.6 J 2.1 J 1.3 V 0.46 0.95 0.68 0.38 030. 0.48 0.85 0.71 4.5. 1.2. 0.45 4.3. 1.9.. 0.98. 1.3 . % Recovery 110 95 91 78 80 81 107 96 97 90 96 103 81 82 89 86 % Recovery 89 104 111 91 85 SO 107 96 113 97 94 84 77 74 97 86 % Recovery 110 113 121 93 102 107 116 118 120 104 116 120 95 97 103 102 % Recovery 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 % Recovery 94 105 109 89 90 87 109 103 115 101 101 88 86 79 101 86 % Recovery 81 61 58 49* 44* 34* 64 63 56 54 58 77 4 4 * 50 45* 46* % Recovery 52 62 67 67 64 51 66 79 67 69 68 97 58 59 47* 52 % Recovery 83 92 87 74 78 75 98 101 93 89 92 117 75 84 90 93 % Recovery 88 118 118 106 100 110 129 121 118 120 118 112 109 104 113 105 mV Standard Units c uS/cm - mg/L NTU Observation Observation NA NA NA NA NA NA Clear None 441 6.69 22.3 83 6.8 0 Clear None 402 7.Q0 19.7 179 6.8 1 Clear None 322 5.36 22.0 44 9.1 0 Clear None 564 710 21.4 130 5.7 1 Clear None 481 6.17 22.0 50 7.6 0 Clear None 655 6.90 22.0 107 7.3 0 Clear None 539 5.90 22.1 60 7.0 0 C le a r None 630 7,27 20.4 157 3.5 1 Clear None NA 6.83 22.2 78 6.6 0 Clear None 639 6.90 21 7 160 5.9 0 Clear None 379 8.33 21.3 64 5.2 0 Clear None 654 7.24 20.3 110 5.8 0 Clear None 377 5,46 22.1 59 6.2 0 Clear None 607 7.10 22 1 102 6,8 1 Clear None 364 6.90 21.8 59 7.2 0 _____ x Clea^ None Notes: ng/L U J * mV C Nanograms per liter (parts per trillion). The analyte was analyzed for, but w as not c The result is an estimated value that was dr The result is an outlier. See case narrative. Millivolts. Donroo Poloiiic p. 12 % Baron & Budd, P.C. Emerald Coast Utilities Authority Production Well Sampling Escambia County, Florida ECUA Production Well Location Map Appendix A A ppendix B Baron & Budd, P.C. Emerald Coast Utilities Authority Production Well Sampling Escambia County, Florida Sample Port Photograph Log Appendix B Baron & B u d d , P.C, (Dallas, Texas) ECUA Production Well Sampling - February 1 , 2010 Escam bia County, Florida Ellyson-Raw Sampling Port Ellyson-Treated Sampling Port ll d Baron & B ud d, P.C. {Dallas, Texas) EtU Production Well Sampling - February 1, 2010 Escambia County, Florida Davis-Raw Sampling Port Davis-Treated Sampling Port B aron & B u d d , P.C. (Dallas, Texas) EC U A P ro d u ctio n Well S a m p lin g - F e b ru ary 1, 2010 Escam bia County, Florida Olive-Raw Sampling Port Olive-Treated Sampling Port Baron & B u d d, P.C. (Dallas, Texas) E C U A P ro d u ctio n W e ll S a m p lin g - Fe b ru a ry 1, 2010 Escam bia County, Florida Carriage Hills-Raw Sampling Port Carriage Hills-Treated Sampling Port Baron & B u d d , P.C. (Dallas, Texas) E C U A P ro d u ctio n W e ll S a m p lin g - F e b ru a ry 1, 2010 Escam bia County, Florida Watson-Raw Sampling Port Watson-Treated Sampling Port B aron & B u d d, P.C. (Dallas, Texas) EC U A Production Well S a m p lin g - Feb ru ary 1, 2010 Escam bia County, Florida Kingsfield Road-Raw Sampling Port Kingsfield Road-Treated Sampling Port Baron & Budd, P.C. (Dallas, Texas! EC U A P ro d u ctio n W e ll S a m p lin g - F eb ru ary 1, 2010 Escam bia County, Florida Cantonment-Raw Sampling Port Cantonment-Treated Sampling Port B aron & B u d d, P.C. (Dallas, Texas) E C U A P ro d u ctio n W e ll S a m p lin g - F eb ru ary 1, 2010 Escambia County, Florida Nine Mile Road-Raw Sampling Port Nine M ile Road-Treated Sampling Port Baron & Budd, P .C (Dallas, Texas) EC U A P ro d u ctio n W e ll S a m p lin g - F e b ru a ry 2, 2010 Escam bia County, Florida University Parkway-Raw Sampling Port University Parkway-Treated Sampling Port Baron & B u d d , P.C. (Dallas, Texas) EC U A P ro d u ctio n W ell S a m p lin g - F e b ru a ry 2, 2010 Escam bia County, Florida McCory-Raw Sampling Port McCory-Treated Sampling Port p. 26 Baron & B u d d, P.C. (Dallas, Texas) ECU A Production Well Sam plin g - Feb ru ary 2, 2010 Escam bia County, Florida p. 27 Baron & Budd, P .C (Dallas, Texas) ECUA Production W ell Sam pling - February 2, 2010 Escam bia County, Florida Lillian-Raw Sampling Port Lillian-Treated Sampling Port 9> CV| Q. B aron & B u d d , P.C. (Dallas, Texas) ECU A P rodu ction W ell Sam pling - February 2, 2010 Escam bia County, Florida Bronson-Raw Sampling Port Bronson-Treated Sampling Port Baron & Budcf, P ,C (Dallas, Texas) ECUA P ro d u ctio n Well Sampling - February 2, 2010 Escam bia County, Florida West Pensacola-Raw Sampling Port West Pensacola-Treated Sampling Port B aro n & B u d d , P.C. (D allas, Texas) EC U A P ro d u c tio n W ell Sampling - February 2, 2010 Escam bia County, Florida p. 32 f: Baron & Budd, P.C (Dallas, Texas) ECUA Production W ell Sam pling - February 2, 2010 Escam bia County, Florida West Well Plant-Raw Sampling Port West Well Plant-Treated Sampling Port p. 33 Baron & Budd, P.C. (Dallas, Texas) EC U A P ro d u c tio n W ell S a m p lin g - Feb ru ary 2, 2010 Escam bia County, Florida "F" & Scott-Raw Sampling Port "F" & Scott-Treated Sampling Port Baron & B u d d , P.C. (Dallas, Texas) EC U A P ro d u c tio n W ell S a m p lin g - Feb ru ary 2 , 2010 Escam bia County, Florida m\\ \\i No. 6 Well Plant-Raw Sampling Port No. 6 Well Plant-Treated Sampling Port Baron & Budd, RC. (Dallas, Texas) ECUA P ro d u ctio n W ell Sam pling - February 3, 2010 Escambia County, Florida Hagler Well Plant-Raw Sampling Port Hagler Well Plant-Treated Sampling Port Baron & Budcf, P.C. (Dallas, Texas) EC U A P ro d u ctio n W ell S a m p lin g - Feb ru ary 3, 2010 Escam bia County, Florida Spanish Trail-Raw Sampling Port Spanish Trail-Treated Sampling Port Baron & Budd, RC. (Dallas, Texas) ECU A P ro d u ctio n W e ll S a m p lin g - February 3, 2010 Escam bia County, Florida Airport North-Raw Sampling Port Airport North-Treated Sampling Port Baron & B ud d, P.C. (Dallas, Texas) ECUA Production W ell Sam pling - February 3, 2010 Escambia County, Florida McAllister-Raw Sampling Port McAllister-Treated Sampling Port Baron & B udd, P.C. (Dallas, Texas) ECU A Produ ction W e ll Sam pling - February 3, 2010 Escambia County, Florida Humphrey's-Raw Sampling Port Humphreys-Treated Sampling Port Baron & B u d d , P.C. (D allas, Texas) ECU Production W ell Sam pling - February 3, 2010 Escam bia County, Florida Broad Street-Raw Sampling Port Broad Street-Treated Sampling Port Baron & B ud d, P.C. (D allas, Texas) EC U A P ro d u ctio n W e ll S a m p lin g - F e b ru a ry 3, 2010 Escam bia County, Florida Tennant-Raw Sampling Port Tennant-Treated Sampling Port p. 42 Baron & Budd, RC, (Dallas, Texas) ECUA Production Well S a m p lin g - February 3, 2010 Avondale-Temporarily Inactive B aron & B u d d , P.C. (Dallas, Texas) ECU A Produ ction W ell Sam pling - February 3, 2010 Escam bia County, Florida Muldoon-Raw Sampling Port Muldoon-Treated Sampling Port B aron & B u d d , P.C. (Dallas, Texas) ECU A P ro d u ctio n W ell Sam pling - February 3, 2010 Escam bia County, Florida Villa Drive-Raw Sampling Port Villa Drive-Treated Sampling Port B aro n & B u d d , P.C. (Dallas, Texas) EC U A P ro d u ctio n W e ll S a m p lin g - F eb ru ary 3, 2010 Escam bia County, Florida Royce Street-Raw Sampling Port Royce Street-Treated Sampling Port p. 46 Baron & Budd, R C (Dallas, Texas) ECUA Production Well S a m p lin g - February 3, 201 Escambia County, Florida Ensley-Permanently Inactive p. 47 o d iu n m DuCiU; r .c . (u a iid b , le xa b j ECUA P ro d u ctio n Well Sampling - February 3#2010 Escambia County, Florida Sweeny-Temporarily Inactive B aron & B u d d , P.C. (Dallas, Texas) EC U P ro d u c tio n W e ll S a m p lin g - Feb ru ary 3, 2010 Escam bia County, Florida OLF 4 A-Temporarily Inactive (Well Screen Extraction) OLF 4 A-Temporarily Inactive (Inactive Motor) OLF 4 A-Temporarily Inactive (Drill Rig/Well Screen Extraction) Appendix C 9> Q. Baron & Budd, P.C. Emerald Coast Utilities Authority Production Well Sampling Escambia County, Florida Groundwater Sample Logs/Field Calibration Logs Appendix C GROUNDWATER SAMPLING LOG p. 51 I SITE I NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv, Florida 'ELL NO: / l y f a * SAM PLE ID: DATE: February / , 2010 PURGING DATA WELL CASING -7 TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): Y C l DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons -- = ( 3 -f 0 feet - UNK feet) X gallons/foot EQUIPMENT VOLUM E PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out If applicable) = gallons + ( gallons/foot X feet) + gallons gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 6 ? -S3 /o me FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING c INITIATED AT: u 7 `T-> PURGING ENDED AT: PURGE RATE (gpm) ORP (mV) pH (standard units) TEMP. (C) 5: u S.iol a.{.2 -2/.7T MS COND. (gS/cm) & &C o DISSOLVED OXYGEN (mg/L) 7-2- Z3Z. J..3I TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) Clear Clear Clear ODOR (describe) None None None W ELL C A PA C IT Y (Gallons Per Foot): 0.75" 0.02; 1" = 0.04; 1.25" =0.06; 2 " = 0.16; 3" = 0.37; 4" 0.65; 5"=1.02; 6" 1.47; 12" 5.88 TUBING INSIDE DIA. CA PA CIT Y (GaliFt.): 1/8" = 0.0006; 3/16* =0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPM ENT CODES: B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; P P = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) /AFFILIATION: David L. Anderson/CDM SA^PLERjS) ^|GNATURE(S): SAMPLING . INITIATED AT: / O i SAMPLING ENDED AT: PU M P DEPTH IN W E LL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^ Y e|) or No. MS/MSD sample collected - Yes o^ Ni> ) Collection Time: Well has fluoride treatment - Yes or No. Photograph No. / CAjVrvjMATERIAL CODES: A G =Amber Glass; C G =Clear Glass; Fio\& SltmK. I C<s/lacf^A /y4P E =Polyethylene; P P =Polypropylene; S = Silicone; T = Teflon; O =Other (Specify) 'AM PLIN G EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; R FPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. S tabilization C riteria for ran ge o f variation o f last three co n secutive readings (see FS 2212. section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 52 I SITE I NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv, Florida ELL NO: / ! y J ^ SAM PLE ID: DATE: February / ,2010 PURGING DATA WELL CASING , DIAMETER (inches): ^ G TUBING DIAMETER (Inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PU RGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) =( 3 ? 0 feet- UNK feet) X gallons/foot = gallons_________________________________________ [____________________________________ _________________________________ ________ EQUIPMENT VOLUM E PURGE: 1 EQUIPMENT V O L = PUM P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CE LL VOLUME (only fill out Ifapplicable) gallons + ( gallons/foot X feet) + gallons = gallons PUMP DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /ooj // /O 13 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING INITIATED AT: / G O O PURGE RATE (gpm) ORP (mV) /8s /7c /?* pH (standard units) TEMP. (C) i.o / -21 -z-./y Z l . N ? .o 8 /. 0 COND. (pS/cm) tfc / r0 PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) % .v TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) O O COLOR (describe) Clear Clear Clear ODOR (describe) None None None ./ELL CAPACITY (Gallons Per Foot): 0.75" =0.02; 1" =0.04; 1.25" =0.06; 2" =0.16; 3" =0.37; 4" =0.65; 5" = 1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (Gal /FL): 1/8" =0.0006; 3/16" =0.0014; 1/4" =0.0026; 5/16" =0.004; 3/8" =0.006; 1/2" =0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM B P = Bladder Pump; E SP = Electric Submersible Pump; P P = Peristaltic Pump; SAMPLING DATA SAMPLER(S) SIGNATURE(S): SAMPLING . INITIATED AT: / G / 5 O = Other (Specify) SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA urn Filtration Equipment Type: NA FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling^Ye>5? o r No. MS/MSD sample collected - Yes oiCTncl) Collection Time: Well has fluoride treatment - Yes or No. Photograph No. . 2 . C-Aj-Yny MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S =Silicone; T =Teflon; O = Other (Specify) \MPLING EQUIPMENT CODES: A P P =After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constituteall of the Information required by Chapter 62-160, F.A.C. 2. STABILIZATIO N C R IT E R IA FO R RANGE O F VARIATION O F LA ST TH R E E C O N SEC U TIV E READIN G S (S E E F S 2 2 1 2 . SECTIO N 3) pH: +0 .2 units Temperature: +0 .2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 2 0 % saturation (see Table FS 2 2 0 0 -2 ); optionally, + 0 .2 mg/L or + 1 0 % (whichever is greater) Turbidity: all readings < 2 0 NTU; optionally + 5 NTU or + 1 0 % (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 53 I SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida LLN0: P a i x T SAM PLE ID: J PURGING DATA DATE: February / , 2010 WELL CASING , TUBING WELL SCREEN INTERVAL PUMPING WATER PU RG E PUMP TYPE: DIAMETER (inches); LP DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out If applicable) aallons =( feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW C E LL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons =______ gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /o 3? / c > 3 (o FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING ,? INITIATED AT: / O J O PURGE RATE (gpm) ORP (mV) x sz -2 8<f pH (standard units) TEMP. (C) -- 2/(> Zl- k ? -- -2- / - U COND. (pS/cm) *?-/ PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) y .n H -n 4 /. / (p TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) c> Clear None Clear None Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 1I2" =5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004: 3/8" = 0.006: 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer, SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S) SJGNATURE(S): SAMPLING ,. INITIATED AT: / C > Y 0 O = Other (Specify) SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. Was the well pumping (active) prior to sampling^Ye^) or No. Well has fluoride treatment - Yes or No. / UNK - Unknown. MS/MSD sample collected - Yes or ('No?) Collection Time: Photograph No. ^ MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) ' MPLING EQUIPMENT CODES: APP = After Peristaltic Pump: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see F S 2212. section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 m g/Lor + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 54 I SITE I NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County, Florida ILL NO: SAM PLE ID: DATE: February / ,2010 PURGING DATA WELL CASING . TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons = ( 2 .S S feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PU M P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUMP DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /C. 7 2 /o</7 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) 38/ 372 pH (standard units) ? // ?J( T fS 7 -/ 2 PURGING PURGING . INITIATED AT: / 0 3 2 . ENDED AT: /> < // TOTAL VOLUME PURGED (gallons): TEMP. (C) CONO. (pS/cm) DISSOLVED OXYGEN (mg/L) TURBIDITY (NTUs) COLOR (describe) ODOR (describe) /-C2 /<?.>( /?oo /a ? /?* Z72. *.4 7 <r. a / r .tj / O O Clear Clear Clear None None None .<LL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (GaL/FL): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0,0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0,010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SA'MPLER(S) SJGNATURE(S): SAMPLING INITIATED AT: /C > 5 2 . SAMPLING ENDED AT: PUMP DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^ Y ej) or No. MS/MSD sample collected - Yes a^ N g )C o lle ctio n Time: Well has fluoride treatment - Yes or No. Photograph No. 2j, CA f-'A j /o ' MATERIAL CODES: AG =Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) 'MPUNG EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b i l i z a t i o n C r i t e r i a f o r r a n g e o f v a r i a t i o n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e FS 2212, s e c t i o n 3) pH: + 0.2 units Temperature: + 0.2 C S p e c ific C o ndu ctance: +5% D isso lve d Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 55 SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida ELL NO: SAMPLE ID: DATE: February / ,2010 PURGING DATA WELL CASING DIAMETER (Inches): 2 4 TUBING DIAMETER (Inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) . = ( 2 O [g feet- UNK feet) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out If applicable) = gallons + ( gallons/foot X feet)+ gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) //> Q> /A> 7 /f/2 . FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING ,7 INITIATED AT: / / J PURGE RATE (gpm) ORP (mV) -2 7 / 2 -7 1 pH (standard units) TEMP. (C) S -J ! r.7 o 5 -.7 2 _ -Z -A 'cyf COND. (pS/cm) I? 77 ? (o PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) (o- 75* L- ? 4 (0 - <7 S TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) / 1 COLOR (describe) Clear Clear Clear ODOR (describe) None None None .,ELL CAPACITY (Gallons Per Foot): 0.75" = 0.b2; 1" = 0.04; 1.26" -0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Qal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; SIB" =0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAWPLERfS) SO^NATURE(S): SAMPLING _ INITIATED AT: / I S SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA um FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 m L by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^ Yes^ or No. MS/MSD sample collected - Yes or ( no^ Collection Time: Well has fluoride treatm ent-Yes or No. Photograph No. C tf)S~'v\) MATERIAL CODES: I/O . A G =Amber Glass; CG =Clear Glass; PE =Polyethylene; PP =Polypropylene; S = Silicone; T =Teflon; O =Other (Specify) \MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O =Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. STABILIZATIO N C R IT E R IA FO R RAN G E O F VARIATION O F LA S T TH R E E C O N SE C U T IV E READINGS (S E E FS 2 2 1 2 . SECTIO N 3) pH: + 0.2 units Temperature: 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally. + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG P" SITE I NAME: ECUA Water Distribution System (Countv-wide) ELL NO: O / iU Q . SAM PLE ID: SITE LOCATION: Escambia Countv. Florida - 7} ^ ^ DATE: February j , 2010 PURGING DATA WELL CASING , DIAMETER (inches): 2 Y TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons = ( 2.0 (p feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PU M P VOLUME + (TUBING CAPACITY TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUMP DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) ///f // o //2 J FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING . INITIATED AT: / / 7 PURGE RATE (gpm) ORP (mV) -- *--- ----- pH (standard units) TEMP. (C) >JS ,.7 8 -3 8 -2 c .tf? COND. (pS/cm) /3 J A/C> /3 % PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) (,.? 2 L . 92. TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) 3 Clear None i Clear None / Clear None VELL CAPACITY (Gallons Per Foot): 0.75" =0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CA PA CIT Y (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0,0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0,010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED BY (PRINT) /AFFILIATION: David L. Anderson/CDM B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SASJPLER(S) SIG^ATURE(S): SAMPLING , INITIATED AT: 1 1 2 . 5 O =Other (Specify) SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA urn Filtration Equipment Type: NA FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fiuorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -^Yes) or No. MS/MSD sample collected - Yes o r( N a ) Collection Time: Well has fluoride treatment - Yes Photograph No. (> C f l i >'v\5 e)Y'f-V> //o ` . MATERIAL CODES: A G =Amber Glass; CG =Clear Glass; P E =Polyethylene; PP =Polypropylene; S = Silicone; T = Teflon; O =Other (Specify) \MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see F S 2212. section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: t 5 A Dissolved Oxygen. all readings ^ 20 /o saturation (see Table FS 2200-2), optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 57 SITE NAME: ECUA Water Distribution System (County-wide) ELL N0: CArf'ft5^ H ills SITE LOCATION: Escambia County, Florida /?fvSAMPLE ID: VaJ PURGING DATA ,DATE: February / 2010 WELL CASING . _ TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): / DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out If applicable) = ( 2. 0.2 feet - UNK gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY feet) X gallons/foot = X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons == gallons PUM P DEPTH IN W ELL (feet): UNK FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING , INITIATED AT: / / Y - i PURGING ENDED AT: TOTAL VOLUME PURGED (gallons): TIME (CST) //y e / / s '/ //ry VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) ORP (mV) -- -- pH (standard units) TEMP. (C) 2 X .ll Z/X y . 4 o 2 2 - // COND. (gS/cm) yz 31 DISSOLVED OXYGEN (mg/L) TURBIDITY (NTUs) o o COLOR (describe) Clear Clear Clear ODOR (describe) None None None .vELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4* = 0.0026; 5/16 =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAM fLER(S) SIGNATURE(S): SAMPLING , INITIATED AT: ! / S ip SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA um SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -^Yes) or No. MS/MSD sample collected - Yes or(^Ng^ Collection Time: Well has fluoride treatment - Yes o^ Na) Photograph No. 2^-- CftX'.'nj- cWi'+l'' IS2*. MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) \MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. S T A B IL IZ A T IO N C R IT E R IA F O R R A N G E O F V A R IA TIO N O F L A S T T H R E E C O N S E C U T IV E R E A D IN G S ( S E E FS 2212. S E C T IO N 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever Is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever Is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 58 SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County. Florida ELL NO: C a f <; A f Q. SAMPLE ID: DATE: February / , 2010 PURGING DATA WELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUM P TYPE: DIAMETER (inches): 1 DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1W ELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons =( 0 2 feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUMP DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) //S % /2 a I /Za q FINAL PUMP DEPTH IN WELL (feet): UNK PURGING INITIATED AT: / / V 5 PURGE RATE (gpm) ORP (mV) - -- -- pH (standard units) TEMP. (C) ? -/y ? -/y 2/ -U z f . 4fc> Z f. COND. (pS/om) ! 83 82. PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) 1^31 TOTAL VOLUME PU RGED (gallons): TURBIDITY (NTUs) 3 I / COLOR (describe) Clear Clear Clear ODOR (describe) None None None .#ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" =0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" =0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S1SIGNATURE(S): SAMPLING / INITIATED AT: / * O = Other (Specify) SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA urn Filtration Equipment Type: NA FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 m L Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^ Y ei) or No. MS/MSD sample collected - Yes or^t3o5 Collection Time: Well has fluoride treatment - Yes qFN^> Photograph No. ^ C-Q-r.'nr MATERIAL CODES: K2 A G =Amber Glass; C G = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) MMPLING EQUIPMENT COOES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tublng Gravity Drain); 0 = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2 . S t a b i l i z a t i o n C r i t e r i a f o r r a n g e o f v a r i a t i o n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2 2 1 2 . s e c t i o n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: 5% Dissolved Oxygen: all readings < 20% saturation (see Table F S 2200-2); optionally, + 0.2 m g/L or + 10% (w hichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 N T U or + 10% (w hichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 59 SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County, Florida 'ELLN0: ( A j f m SAM PLE ID: PURGING DATA DATE: February / ,2010 WELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): 0 N K DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons =< UNK feet- UNK feet) X gallons/foot = EQUIPMENT VOLUM E PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out If applicable) = gallons + ( gallons/foot X feet) + gallons - gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /2.H- !2 2 o (Z2l FINAL PUMP DEPTH IN WELL (feet): UNK PURGING /, INITIATED AT: PURGE RATE (gpm) ORP (mV) -Z F f 221 "3c>o pH (standard units) TEMP. (C) 5*. h i s. HZ sw ? A\S~1 /' COND. (pS/cm) -- -- -- PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) s .ll S'-3 7 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) CD Clear None O Clear None O Clear None .E L L CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CA PA CIT Y (Gal./Ft.): 1/8" =0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Ballen B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: / - - - b SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. Was the well pumping (active) prior to sampling Well has fluoride treatm ent^ ^ B or No. or No. UNK - Unknown. MS/MSD sample collected - Yes or^ N o) Collection Time: Photograph No. ^ MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) 'MPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) No TES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2 . S T A B ILIZ A T IO N C R IT E R IA F O R R A N G E O F V ARIA TIO N O F L A S T T H R E E C O N S E C U T IV E R E A D IN G S (S E E F S 2 2 1 2 . S E C T IO N 31 pH: +0 .2 units Temperature: +0 .2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 2 0 % saturation (see Table FS 2 2 0 0 -2 ); optionally, + 0 .2 mg/L or + 10 % (whichever is greater) Turbidity: all readings < 2 0 NTU; optionally + 5 NTU or + 10 % (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 60 I SITE I NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv. Florida ELL NO: SAM PLE ID: - 7 ^ . ^ DATE: February ! , 2010 PURGING DATA W ELL CASING DIAMETER (inches): TUBING DIAMETER (inches): NA W ELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons = ( U/I/IC. feet - UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW C E LL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons : gallons PUMP DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /22f /2Jo 2.33 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING INITIATED AT: / 2 / Li PURGE RATE (9Pm) ORP (mV) -- pH (standard units) TEMP. (C) X/. ?l COND. (pS/cm) /$2. -- 113 '< /7 PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) V -t2 . V -U TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) / Clear None Clear None Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 12" =5.08 TUBING INSIDE DIA. CAPACITY (GalTFt.): 1/8" = 0.0006; 3/16" =0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/B" = 0.006; 1/2" = 0.010; 5/8* = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O =Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SA^ LR^ SI^ TU RE(S): SAMPLING , INITIATED AT: ( 2 . 3 b SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. Was the well pumping (active) prior to sampling -^ 5^ or No. Well has fluoride treatment ^ Y e sp r No. UNK - Unknown. MS/MSD sample collected - Yes q^ n 5) Collection Time: Photograph No. / MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) ' MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NO TES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE F S 2212, SECTION 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date; February 12, 2009 GROUNDWATER SAMPLING LOG I SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia Countv. Florida =L L N O :/ u o ^ r - P , W J SAM PLE ID: PURGING DATA DATE: February / , 2010 WELL CASING . . TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): Vn> DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( V /U lC feet- UNK feet) X gallons/foot gallons EQUIPMENT VO LU M E PU RGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons : gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) / ? ? 2. 13 3 f /33Z FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING / 7 -, o INITIATED AT;/ PURGE RATE (gpm) ORP (mV) 22Z Z 2.? 22) pH (standard units) TEMP. (C) -2J-0 r.fc ? r.fc t -2/-C> -ZY-o COND. (pS/cm) 18 3k> 3^ PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) 3.ST- 3 7 -^ C . TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear None o Clear None O Clear None .ELL C A PA CIT Y (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16: 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DIA. C A PA C IT Y (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0,0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B= Bailer;____ B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SjGNATURE(S): SAMPLING l ? s j n INITIATED AT: SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: NA DUPLICATE: FILTER SIZE: No NA um SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. Was the well pumping (active) prior to sampling -(^ e?) or No. Well has fluoride treatment ^Ye)or No. UNK - Unknown. MS/MSD sample collected - Yes or^No^) Collection Time: Photograph No. / / MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; P P = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) ' MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O =Other (Grab) N O TES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2 2 1 2 . s e c t io n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 62 I SITE I NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County, Florida ELLNO: SAMPLE ID: ~7} PURGING DATA DATE: February / ,2010 WELL CASING y TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons =( UW K feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY (only fill out if applicable) TUBING LENGTH) + FLOW CELL VOLUME = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /3<r* PS3 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING 17 7 INITIATED AT: i J J v PURGE RATE (gpm) ORP (mV) Jffo ra S ilo pH (standard units) TEMP. (C) l .ih Las 2 ?S 2 .? f 2 .??- COND. (pS/cm) /22. PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) 3. 8 ? S3 G> TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) 2. / / COLOR (describe) Clear Clear Clear ODOR (describe) None None None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" = 1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0,0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/6" =0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED BY (PRINT) / AFFILIATION; David L. Anderson/CDM B P = Bladder Pump; E SP = Electric Submersible Putnp; PP = Peristaltic Pump; SAMPLING DATA SA riPLER(S) SIQNATURE(S): SAMPLING <7 r e INITIATED AT: / O O = Other (Specify) SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA urn Filtration Equipment Type: NA FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA ff CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorlnated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. W as the well pumping (active) prior to sampling -(^ ? or No. Well has fluoride treatment or No. UNK - Unknown. MS/MSD sample collected - Yes or (No5 Collection Time: Photograph No. 2. MATERIAL CODES: A G =Amber Glass; C G = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) ' MPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) N O TES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2 2 1 2 . s e c t i o n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County, Florida E H NO: ( 2 p \K iT<0\r\{ i\^ 'i4 ' SAM PLE ID: Uj DATE: February , 2010 PURGING DATA W ELL CASING -, DIAMETER (inches): ^ ^ TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons =< 7 3 8 feet - UNK EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY feet) X gallons/foot = TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) gallons + ( gallons/foot X feet) -t- gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) / V o (o /V O ? H /2 . FINAL PUMP DEPTH IN WELL (feet): UNK PURGING j INITIATED AT: / 7 J PURGE RATE (gpm) ORP (mV) 2zs -- pH (standard units) .S'. 64 TEMP. (C) 2 o .? Y f.L S', t i o ito -? ? .2=>.?y COND, (liS/cm) JV 33 32 PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) r.r/ r.ro r.< ro TOTAL VOLUME PU RGED (gallons): TURBIDITY (NTUs) G O Q> COLOR (describe) Clear Clear Clear ODOR (describe) None None None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6"=1.47; 12" = 5.88 TUBING INSIDE PIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: /?/ > SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -^Ye?) or No. MS/MSD sample collected - Yes or/Nc^) Collection Time: Well has fluoride treatment or No. Photograph No. 13 C f l J T n i <UM\s 3 V S ' ' . MATERIAL CODES: AG =Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) VMPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O =Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. Stabilization C riteria for range o f variation o f last three con secutive readings (see FS 2212. section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date; February 12, 2009 GROUNDWATER SAMPLING LOG p. 64 I SITE I NAME: ECUA Water Distribution System (County-wide) ELL NO: SAMPLE ID: SITE LOCATION: Escambia County. Florida DATE: February / ,2010 PURGING DATA W ELL CASING n TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): ^ G DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out it applicable) gallons = ( 13 8 fast - UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PU M P VOLUME + (TUBING CAPACITY (only fill out if applicable) TUBING LENGTH) + FLOW CELL VOLUME = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) H 2** FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) L&s 7- 33 PURGING _ INITIATED AT: ' " PURGING ENDED AT: TEMP. (C) COND. (gS/cm) DISSOLVED OXYGEN (mg/L) / 7 -f if.tb //s' // 4 r - 4// r.J jT TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) 1 Clear None 0 Clear None H Z* s . l l4/6 7 -/ 4 -2c.- cs/ //? / Clear None m i* 4/0 7/7 .2-0.01 //4 r.v o 1 ./E L L CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04: 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" =1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" =0,0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0,010; 5/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S)SIGNATURE(S): SAMPLING . , INITIATED AT: / L f 2 (<, SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Eguipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^Ye) or No. MS/MSD sample collected - Yes or ( N o ) Collection Time: Well has fluoride treatment ^Yjs or No. Photograph No. /^/* 6 t)T rfly 3V i MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) ' MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NO TES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. STABILIZATION CRITERIA FOR RAN GE O F VARIATION OF LAST THREE CO NSECUTIVE READINGS (SEE F S 2 2 1 2 . SECTION 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG I SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida ELL NO: y V W /V\( )e SAM PLE ID: DATE: February j , 2010 PURGING DATA W ELL CASING -, TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) =( 3 40 feet- UNK feet) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out If applicable) = gallons + ( gallons/foot X feet) + gallons : gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) % FINAL PUM P DEPTH IN W ELL (feet): UNK PURGING , INITIATED AT- . i H H > PURGING ENDED AT: PURGE RATE (gpm) ORP (mV) -- -- -- pH (standard units) r.io TEMP. (C) (*> P f-C /f- COND. (pS/cm) 3 DISSOLVED OXYGEN (mg/L) So TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) c Clear None Clear None O Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/B" = 0.006; 1/2" = 0.010; 5/8` = 0.016 PURGING EQUIPMENT CODES: B = Bailer; SA M PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S)lSIGNATURE(S): SAMPLING INITIATED AT: / V S -T O = Other (Specify) SAMPLING ENDED AT: PU M P DEPTH IN WELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorlnated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling -{Ye^ or No. MS/MSD sample collected - Yes or(^No) Collection Time: Well has fluoride treatment - j'fls jo r No. Photograph No. / " c a r.-Aj- cX^f-l' - 2 . S 0 MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) 'MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2 2 1 2 , s e c t io n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 66 I SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia Countv. Florida ELL NO: w SAMPLE ID: /You PURGING DATA DATE: February 2 .2010 WELL CASING -, DIAMETER (inches): ^ TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons =( 335" feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out If applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN WELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) OSc 8 6 8 It FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING INITIATED AT: PURGE RATE (gpm) ORP (mV) /e r /e? pH (standard units) TEMP. (C) -- -- JU-S1 COND. (pS/cm) 3? /< 8 -- 2 .1-S H 3 - PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) o Clear None Clear None Clear None ./ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (GalVFt.): 1/8''= 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8 =0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S)jSJGNATURE(S): SAMPLING _ _ INITIATED AT: !*- O = Other (Specify) SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA ff CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling or No. MS/MSD sample collected - Yes o^ n 3>j Collection Time: Well has fluoride treatment No. Photograph No. I cft/vn f m o '. 2?/a w K i . c a 4- uo<xIk**), C T iS g o o . MATERIAL CODES: AG =Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) 'MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) N O TE S: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. STABILIZATIO N C R IT E R IA F O R R A N G E O F VARIATION O F L A S T T H R E E C O N S E C U T IV E R E A D IN G S (S E E FS 2212. SECTIO N 3) pH:+0.2 units Temperature:+0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 m g/Lor + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 67 SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida `ELL NO: SAM PLE ID: DATE: February , 2010 PURGING DATA WELL CASING ^ TUBING W ELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): 0 DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) =( 3 3 5 feet - UNK feet) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. =PUM P VOLUM E +(TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons +( gallons/foot X feet) + gallons = gallons PUM P DEPTH INW ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) C6N FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING INITIATED AT: PURGING b 2- ENDED AT: PURGE RATE (9Pm) ORP (mV) fSt /iTZ / 2T/ PH (standard units) TEMP. (C) ?-e.r 7 - l -2 /. 13 -2 f ./ y COND. (pS/cm) 2 r* /& /?& I1- DISSOLVED OXYGEN (mg/L) 3.8< 7. 87 3.5o TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) 7 Clear None ~Z- Clear None 2- Clear None .ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" = 1.02; 6" = 1.47; I2" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal/Ft.): 1/8" =0.0006; 3/16" =0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" =0.006; 1/2" =0.010; S/8" =0.016 PURGING EQUIPMENT CODES: B =Bailer; BP =Bladder Pump; ESP =Electric Submersible Pump; PP = Peristaltic Pump; O =Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S)IGNATURE(S): SAMPLING INITIATED AT: O g -2. SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE; NA TUBING: NA FIELD-FILTERED: No Filtration Egulpment Type: DUPLICATE; NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^Y|^ or No. MS/MSD sample collected - Yes oi^No^) Collection Time: Well has fluoride treatment -y or No. Photograph No. 2 -- C fti'rn vy /V O * . MATERIAL CODES: A G = Amber Glass; CG =Clear Glass; P E = Polyethylene; PP =Polypropylene; S = Silicone; T = Teflon; O =Other (Specify) ' MVIPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Grab) NoTES: 1. The above do not constituteall of the information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see F S 2212, section 3) pH: 0.2 units Temperature: + 0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or 10% (whichever is greater) Revision Date; February 12, 2009 I W in I w v v v f c - r GROUNDWATER SAMPLING LOG p. 68 SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv. Florida ELL NO; /)) c C o t / SAM PLE ID: DATE: February Z . ,2010 PURGING DATA WELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons = ( 2.1 0 feet - UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 6 8 VO FINAL PUM P DEPTH IN W ELL (feet): UNK PURGING INITIATED AT: O 'o PURGE RATE (gpm) ORP (mV) pH (standard units) TEMP. (C) S'. 8 ? r.s s J -l-!< i z \- n COND. (pS/cm) vv r.S 8 PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) 7 -0 ? I TOTAL VOLUME | PU RGED (gallons): TURBIDITY (NTUs) 6 COLOR (describe) Clear Clear Clear ODOR (describe) None None None . ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal ./Ft): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SA M PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SJGNATURE(S): SAMPLING INITIATED AT: SAMPLING Y G ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Eguipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorlnated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -(Yes) or No. MS/MSD sample collected - Yes or (N o ) Collection Time: Well has fluoride treatment - Yes Photograph No. 3 c ft r .'A j /8<5' . MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) 'M P LIN G EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) N o TES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b iliza t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t iv e r e a d in g s (s e e F S 2212. s e c t io n 3) pH: +0.2 units Temperature: + 0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings <20% saturation (see Table F S 2200-2), optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally +5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 I W i l l i W W W W V 'fc*T GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution Svstem (Countv-wide) /ELL NO: /\!\cC&f~f SAMPLE ID: SITE LOCATION: Escambia Countv, Florida DATE: February 2. ,2010 PURGING DATA WELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER DIAMETER (inches): U J V K DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) qallons = ( (2 / 0 feet - UNK feet) X EQUIPMENT VO LU M E PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY (only fill out if applicable) = gallons + ( gallons/foot X feet) + PURGE PUMP TYPE: Existing Pump gallons/foot = gallons gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) Q r7 6 8 5 " (t> FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING PURGING INITIATED AT: 8 e/Ci ENDED AT: PURGE RATE (gpm) ORP (mV) SV2 S '// pH (standard units) TEMP. (C) ? -0 / .- il 2 !-2 < z COND. (pS/cm) // /// //o DISSOLVED OXYGEN (mg/L) 7 - il T -./o TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) 2 -, Clear None Clear None Clear None o .,E L L CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CA PA CITY (Gal./Ft.): 1/8" = 0.0006; 3/16* = 0.0014; 1/4" = 0,0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" =0,010; S/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; P P a Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING A D _ n INITIATED AT: O i 8 SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: NA DUPLICATE: FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorlnated Cm ps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling ^ V e i) or No. MS/MSD sample collected - Yes or Cno3Collection Time: Well has fluoride treatment - Yes t^No) Photograph No. C A Tr<y /fiO . MATERIAL CODES: A G =Amber Glass; CG = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) ' '.MPLING EQUIPMENT CODES: A PP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; E SP = Electric Submersible Pump; RF P P = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b iliz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t iv e r e a d in g s (s e e F S 2212. s e c t io n 3) pH: +0 .2 units Temperature: +0 .2 C Specific Conductance: + 5 % Dissolved Oxygen: all readings < 2 0 % saturation (see Table F S 2 2 0 0 -2 ); optionally, + 0 .2 mg/L or + 1 0 % (whichever is greater) Turbidity: all readings < 2 0 NTU; optionally + 5 NTU or + 10 % (whichever is greater) Revision Date: February 12, 2009 ru m i I u 9uuv6^ GROUNDWATER SAMPLING LOG SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida /ELL NO: P U f l A W f y f SAMPLE ID: DATE: February 2 . ,2010 PURGING DATA WELL CASING -7 . DIAMETER (inches): TUBING DIAMETER (Inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PU RG E PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) _ ,, __ gallons =( feet - UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 0 ?z/ J2^b FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING INITIATED AT:. 0 ? / g PURGE RATE (gpm) ORP (mV) pH (standard units) TEMP. (C) COND. (pS/cm) 341 3^ 0 f.ff S',i l 2 *1 1 - II PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) J f-f1 y .& f 4 -1 1 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) c Clear None Clear None 0 Clear None ./ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY(Gal./Ft.): 1/8" = 0.0006; 3716" = 0.0014; 1/4" = 0,0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0,010; S/8' = 0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA &AMPLER(S1SIGNATURE(S): SAMPLING INITIATED AT: C>12-1 O = Other (Specify) SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA urn Filtration Equipment Type: NA FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 m L by HPLC/MS. REMARKS: NA - Not Applicable. Was the well pumping (active) prior to sampling ^'S'es^ or No. UNK - Unknown. MS/MSD sample collected - Yes orjfNoJ) Collection Time: Well has fluoride treatment - Yes c^fNo) Photograph No. C-A-Tm* / S 'z '. MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) \MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; R FPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. STA B ILIZA TIO N C R IT E R IA FO R RANGE O F VARIATION O F LA ST T H R E E C O N SE C U T IV E READIN G S (S E E F S 2 2 1 2 , SECTIO N 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, +0.2 mg/Lor + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 r u m i r l/ cw w v - .t GROUNDWATER SAMPLING LOG I SITE I NAME: ECU A Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida /ELL NO: SAM PLE ID: - DATE: February 2 . ,2010 PURGING DATA WELL CASING o TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (Inches): ^ U DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUM E PURGE: 1 W ELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons =( 3 7 S feet - UNK EQUIPMENT VO LUM E PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY feet) X gallons/foot = X TUBING LENGTH) + FLOW CELL VOLUME (only fill out If applicable) gallons + ( gallons/foot X feet) + gallons gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) ^ 71/ Cb W FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING ^ o /A INITIATED AT: W ' O PURGE RATE (gpm) ORP (mV) L 'o V --- pH (standard units) TEMP. (C) L -tv 2 < S.Zg 2 C .-2 8 COND. (pS/cm) 3V 35 -- L .U h PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) A /-? 7 TOTAL VOLUME PURGED (gallons): TURBIDITY COLOR (NTUs) (describe) ODOR (describe) O Clear None O Clear None Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2 " = 0.16; 3" = 0,37; 4" =0.65; 5" =1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006: 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" =0.006; 1/2" = 0.010; 5/6" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING 3INITIATED AT: O '7 7 SAMPLING ENDED AT: PU M P DEPTH IN W E LL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 m L Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -^ e ^ or No. MS/MSD sample collected - Yes or (Ncp Collection Time: Well has fluoride treatment - Yes o{fio) Photograph No. (p C A . r r i \ r W t* * / S '-2- '. MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) \M PLIN G EQ UIPM EN T CODES: A PP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S T A B I L I Z A T I O N C R I T E R I A F O R R A N G E O F V A R IA T IO N O F L A S T T H R E E C O N S E C U T I V E R E A D I N G S ( S E E F S 2212. S E C T IO N 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 rw i n i r i/ ouvvA .-r GROUNDWATER SAMPLING LOG p. 72 I SITE I NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv, Florida ELL NO: , - / / i > A SAMPLE ID: ^ P r U J DATE: February J 2 . , 2010 PURGING DATA WELL CASING , DIAMETER (Inches): -C. (o TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons n s, _ _ =( feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT V O L = PUMP VOLUME + (TUBING CAPACITY TUBING LENGTH) + FLOW CELL VOLUME (only fill out If applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) o?^6 oJS1 /be>2- FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING ._,, INITIATED AT: PURGE RATE (gpm) ORP (mV) /b 3 /-/V? -- pH (standard units) T-43- TEMP. (C) 22-2. Z 2 .Z xy 2223 COND. (pS/cm) /6 ?? PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) /-VS y-s'? y-s\ TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) O Clear None O Clear None Clear None W ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" = 1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CA PA CITY (GaliFt.): 1/B" = 0.0006; 3/16" = 0.0014; 1/4" = 0,0026; 6/16* = 0.004; 3/6" = 0.006; 1/2" = 0.010; 5/6" =0.016 PURGING EQUIPMENT CODES: B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. AndersorVCDM SAMPLER(S) SIGNATURE(S): SAMPLING . , INITIATED AT: / O & i SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA am FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1 liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -(Ye|) or No. MS/MSD sample collected - Yes or (No) Collection Time: Well has fluoride treatment -(^Y^or No. Photograph No. ^j- C A i\ 'A 5 d'epfl' /Ob . MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) 'MPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Fleverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) N O TES: 1. The above d o not constitute ail of the information required by Chapter 62-160, F.A.C. 2. S t a b iliza tio n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t iv e r e a d i n g s (s e e FS 2212, s e c t io n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/Lor + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally +5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 ru m i r u wuu-t*t GROUNDWATER SAMPLING LOG p 73 I SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida 'E L L NO: / / ^ SAM PLE ID: 7 > * / v 4 J DATE: February 2 - ,2010 PURGING DATA WELL CASING , TUBING W ELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): ^ ^ DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) =( 17b feet - UNK gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VO L = PUM P VO LU M E + (TUBING CAPACITY feet) X gallons/foot = X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) / o (p /6 o ? / 0 / 2. FINAL PUMP DEPTH IN WELL (feet): UNK PURGING INITIATED AT: 3 PURGE RATE (gpm) ORP (mV) (s>*q L -- pH (standard units) TEMP. (C) 3-/7 -2o + I- 3 I i- n COND. (pS/cm) -2 - / 8 2 .3 % 2-2. g PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) 3 .2 2 . 3 ./< * IIS TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) 3 Clear None Z. Clear None 2 Clear None </ELL CAPACITY (Gallons Per Foot): 0.75" =0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3'' = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING . INITIATED AT: / O S SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^3el) or No. MS/MSD sample collected - Yes or^ N o3 Collection Time: Well has fluoride treatment or No. Photograph No. ^ c A i'fA j / 0 6 ' MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; P E = Polyethylene: PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) ' AMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b iliz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t iv e r e a d in g s (s e e F S 2212. s e c t io n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever Is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 I W illi I U W W W 't T GROUNDWATER SAMPLING LOG PTM SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia Countv. Florida /ELL NO: f C , 1 J o A SAM PLE ID: DATE: February 2 . ,2010 PURGING DATA WELL CASING _ 1 TUBING DIAMETER (inches): ' DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons = ( 2 Jt-I '' feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PU M P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUM P DEPTH IN WELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /c>3 3 /c> 3& /o ?T FINAL PUMP DEPTH IN WELL (feet): UNK PURGING ,- PURGING INITIATED AT: / S 0 ENDED AT: PURGE RATE (gpm) ORP (mV) 3 /6. pH (standard units) f.B G TEMP. (C) COND. (pS/cm) 3? DISSOLVED OXYGEN (mg/L) 3 .7 / 3 7 ^ <r. 8 ? *7^ 8 37 Vo 3 .7 2 - 3.37 I TOTAL VOLUME | PURGED (gallons): TURBIDITY (NTUs) O COLOR (describe) Clear Clear Clear ODOR (describe) None None None ,/E L L CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" =0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED BY (PRINT) / AFFILIATION: David L. Andersort/CDM B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SftMPLER(S)SIGNATURE(S): SAMPLING INITIATED AT: / c <-// O = Other (Specify) SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA um FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorlnated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -^ e^ or No. MS/MSD sample collected or No. Collection Time: / & * / ! Well has fluoride treatment -^ p> or No. Photograph No. ^ C A / T n y ft- '' / .j- . MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; PE = Polyethylene; P P = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) \MPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Grab) NO TES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b iliza tio n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e FS 2212. s e c t io n 3) pH: 0.2 units Temperature: 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, +0.2 mg/L or 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 I V I III h* i / w v ^ - r GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv, Florida /ELL NO: SAM PLE ID: DATE: February 2 - ,2010 PURGING DATA WELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (Inches): M 1 DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out If applicable) gallons = ( 2 / l ' feet- UNK feet) X gallons/foot EQUIPMENT VOLUM E PURGE: 1 EQUIPMENT V O L = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = _ gallons PUM P DEPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /o<-/3 /Q V i /c> FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) 7 .2 / 7 -g fc 1S 1 -2 ) PURGING , -, INITIATED AT: / J C b TEMP. (C) COND. (gS/cm) 2-3-11 2 3 -/0 So Sto PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) > 2 3 .2.J o-ZJ TOTAL VOLUME PURGED (gallons): TURBIDITY COLOR (NTUs) (describe) ODOR (describe) Clear Clear Clear None None None -YELL C A PA C IT Y (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY(Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4* = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPM ENT CODES: B = Bailer; SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM B P = Bladder Pump; E S P = Electric Submersible Pump; P P = Peristaltic Pump; SAMPLING DATA S&MPLER(S)SIGNATURE(S): SAMPLING . ^ INITIATED AT: / s O = Other (Specify) SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED; No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling or No. MS/MSD sample c o lle c te c ^ Y ^ or No. Collection Time: / Q Z * / Well has fluoride treatment -^ ep > r No. Photograph No. / O C A / v it j ckf+ Vv MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) 'AM P LIN G EQUIPM ENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constituteall of the Information required by Chapter 62-160, F.A.C. 2 . Stabilization Criteria for range of variation of last three consecutive readings (see F S 2 2 1 2 . section 3 ) pH:+0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 I V I I I I I ^ < / V W V mm' T GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County. Florida VELLNO; U j e r f - SAM PLE ID: DATE: February 2 . ,2010 PURGING DATA WELL CASING y ,, TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): ^ 7 DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out If applicable) aallons = ( 2 to (p feet - UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out It applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) US? /A T 8 /2 *l FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING , INITIATED AT; / / > 2 - PURGE RATE (SPm) ORP (mV) 32% -- pH (standard units) TEMP. (C) r. 2 2 2 U r.? ? 2ZZ* 2 2 .Z & COND. (pS/cm) 2/ 7-2 2 -; PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) r.f ? <r.<3f TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Co C le a r None C Clear None o Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DfA. CAPACITY (Gal./Ft): 1/8" = 0.0006; 3/16" =0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING .. - INITIATED AT: / O j SAMPLING ENDED AT; PUM P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP; No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE IDCODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. Was the well pumping (active) prior to sampling - ( e j or No. UNK - Unknown. MS/MSD sample collected - Yes or (fto) Collection Time: Well has fluoride treatment -^ e^ or No. Photograph No. / j e f t m s ' MATERIAL CODES: A G =Amber Glass; C G = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) 'A M P LIN G EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; R FPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O =Other (Grab) N O TES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2 . S t a b i l i z a t i o n C r i t e r i a f o r r a n g e o f v a r i a t i o n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2 2 1 2 . s e c t i o n 3) pH: + 0.2 units Temperature: +0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, +0.2 mg/L or 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 ru m i r u auvu'tn GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida VELLNO: ^ a c /V SAMPLE ID: - 7 ^ .* 4 < = J DATE: February 2 _ ,2010 PURGING DATA WELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PU RGE PUMP TYPE: DIAMETER (inches): DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) . = ( - 2 I t (# feet - LINK gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY feet) X gallons/foot = X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) gallons + ( gallons/foot X feet) + gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) Z& S /Zo8 fZ!\ FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) ^8 2 vs / Y8 ? pH (standard units) V* PURGING INITIATED AT: / / 3 J - PURGING ENDED AT: TEMP. (C) COND. (gS/cm) DISSOLVED OXYGEN (mg/L) /& o 3.?* V/L /a/ /feo 2 .1 3 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear None o Clear None O Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" =0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" =1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft,): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; S/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; S/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O =Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) /AFFILIATION: David L. Anderson/CDM SAMPLER(S)SIGNATURE(S): SAMPLING . . . . . . INITIATED AT: SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling or No. MS/MSD sample collected - Yes or ( nq ) Collection Time: Well has fluoride treatment or No. Photograph No. / 2. C A jV n y Fti MATERIAL CODES: /V S '/. A G =Amber Glass; C G =Clear Glass; P E =Polyethylene; PP =Polypropylene; S = Silicone; T =Teflon; O =Other (Specify) ' AMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above d o not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e FS 2212. s e c t io n 3) pH: +0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally +5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 rumi ru GROUNDWATER SAMPLING LOG I SITE I NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County, Florida ELL NO: U j o' / \ U w ^ SAM PLE ID: DATE: February 2 . , 2010 PURGING DATA WELL CASING , DIAMETER (Inches): 2 TUBING DIAMETER (Inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out If applicable) qallons = ( 2 -S 1 feet - UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) tZZS /2 2 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (m V ) -- -- pH (standard units) sr.?* PURGING . INITIATED AT: / Z 2 2 . TEMP. (C) COND. (pS/cm) 22-^3 22-&T- / O (o /OS' PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) * 31 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) / Clear None o Clear None JZV -- S'. 1-1 /o?- * 27 / Clear None ./ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (GalVFt ): 1/8" =0.0006: 3/16" = 0.0014; 1/4" = 0.0026; 5116" =0.004; 3/8" = 0.006; 1/2" =0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING n INITIATED AT: / S Y SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAM PLE CONTAINER SPECIFICATION SAMPLE IDCODE NA if CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling or No. MS/MSD sample collected -Yes or (iQoj Collection Time: Well has fluoride treatment-^Ye^ or No. Photograph No. 1 3 c a /v a ? MATERIAL CODES: / f t 1AG =Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NO TES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. STABILIZATION CRITERIA FOR RAN GE O F VARIATION O F LAST THREE CONSECUTIVE READINGS (SEE FS 2 2 1 2 , SECTION 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME; ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida VELLNO: \\J c SAMPLE ID: DATE; February J L ,2010 PURGING DATA WELL CASING _ I TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): ^ DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) =( j I feet - UNK qallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME +(TUBING CAPACITY feet) X gallons/foot = X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) un /2</2 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING PURGING INITIATED AT: / 2 - 2 'z- ENDED AT: PURGE RATE (gpm) ORP (mV) 0 4 pH (standard units) TEMP. (C) ?-*>? 2 f- Z 7-/0 zhty COND. (pS/cm) /sr DISSOLVED OXYGEN (mg/L) r.v r r.xyz TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) / Clear None Clear None 1 Clear None ,/ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1M= 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4"=0.65; 5" = 1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" =0.0006; 3/16" =0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 8/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP =Electric Submersible Pump; PP = Peristaltic Pump; O =Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SfGNATURE(S): SAMPLING , INITIATED AT: / 2 Z / 3 SAMPLING ENDED AT; PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP; No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE; No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH___ NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorlnated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling or No. MS/MSD sample collected - Yes or<^Ro> Collection Time: Well has fluoride treatment or No. Photograph No. / C L A rrn y MATERIAL CODES: I S 4>' AG = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) SAM PLING EQUIPMENT CODES: A PP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; R FPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O =Other (Grab) NOTES: 1. The above do not constituteall of the information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see FS 2212. section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L o r + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 I W illi I W GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida VELLNO: U ie r - P llK M l SAM PLE ID: DATE: February " 2 . ,2010 PURGING DATA WELL CASING ^ i TUBING DIAMETER (inches): ^ DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUM P TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME =(TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out If applicable) =( 2JZ U> fest~ UNK test) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. =PUM P VOLUME +(TUBING CAPACITY X TUBING LENGTH) +FLOW CELL VOLUME (only fill out if applicable) = gallons +( gallons/foot X feet) + gallons = gallons PUMP DEPTH INW ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /zsi IZST /3e>2- FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING INITIATED A T M 5 5 PURGE RATE (gpm) ORP (mV) PH (standard units) TEMP. (C) HT'1 (s -/O 2/i ff ] L-G1- 2/-S 6.-0% ?!?o COND. (pS/cm) /o /oy /o? PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) 3-61 3.ko ? . 2 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) o Clear None o Clear None Clear None /ELL CAPACITY (Gallons Per Foot): 0.75" =0.02; 1" = 0.04; 1.25" =0.06; 2" =0.16; 3" =0.37; 4" =0.65; 5" =1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (Gai/Ft ): 1/8" =0.0006; 3/16" =0.0014; 1/4" =0.0026; 5/16"=0.004; 3/8" =0.006; 1/2" = 0.010; 5/B" =0.016 PURGING EQUIPMENT CODES: B = Bailer; BP =Bladder Pump; ESP =Electric Submersible Pump; PP =Peristaltic Pump; O =Other (Specify) SAMPLING DATA SAMPLED BY (PRINT)/AFFILIATION: David L. Anderson/CDM SAMPLER(S)jIGNATURE(S): SAMPLING i~) INITIATED AT: l i Q y SAMPLING ENDED AT: PUMP DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling-(^esj or No. MS/MSD sample collected - Yes or fNo3 Collection Time: Well has fluoride treatment - Yes o^N) Photograph No. / 5~ C A j V a j - <Ao.F-Fh I I 3 . MATERIAL CODES: AG = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) 'AMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Grab) NOTES: 1. The above d o not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d in g s (s e e FS 2212. s e c t io n 3) p H : +0.2 units Temperature: +0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, +0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally 5 NTU or + 10% (whichever Is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida VELLNO: lU c r+ - Ui*-U SAM PLE ID; ^ DATE: February Z2. ,2010 PURGING DATA WELL CASING DIAMETER (Inches): . TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) . = ( 2 -2. (p feet - UNK feet) X gallons/foot = qallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUMP DEPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) llo q 13 I3/ FINAL PUM P DEPTH IN W ELL (feet): UNK PURGING . INITIATED AT: ! * S 3 PURGE RATE (9Pm) ORP (mV) fe y pH (standard units) TEMP. (C) L .H 'i 2 c . o L q z 2 o -/6 COND. ( S/cm) Z& Uf Um z 2*3 PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) 2.-3 Cp TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) z Clear None Clear None / Clear None WELL CAPACITY (Gallons Per Foot): 0.76" =0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" =1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" =0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O =Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) /AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING i, INITIATED AT: / J 1 SAMPLING ENDED AT: PUMP DEPTH IN W E LL (feet): UNK FIELD DECONTAMINATION; PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE IDCODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (ml) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -(^Yes) or No. MS/MSD sample collected - Yes or (fig ) Collection Time: Well has fluoride treatment - Yes or^p) Photograph No. / Id CAi">'v\f MATERIAL CODES: H 3 1. A G =Amber Glass; C G =Clear Glass; PE = Polyethylene; PP =Polypropylene; S = Silicone; T = Teflon; O =Other (Specify) SAMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Grab) ivOTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2 . S t a b i l i z a t i o n C r i t e r i a f o r r a n g e o f v a r i a t i o n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s ( s e e F S 2 2 1 2 . section 3 ) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever Is greater) Revision Date: February 12, 2009 I W WWW GROUNDWATER SAMPLING LOG p. 82 I SITE I NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County, Florida 'ELL NO: f j $ c & r SAMPLE ID: DATE: February 2010 PURGING DATA WELL CASING / TUBING DIAMETER (Inches): ^ DIAMETER (Inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( 2 -^ 7 feet- UNK feet) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL = PUM P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUMP DEPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) I3 2 Z 1 3 2 .5 FINAL PUMP DEPTH IN WELL (feet): UNK PURGING 1 7 /Q INITIATED AT: I J ' / PURGE RATE (gpm) ORP (mV) 3T6 -- - pH (standard units) C>Vb > .3? TEMP. (C) ZZ-tle 2Z.iei 22 4 b COND. (pS/cm) 8<r & (> V PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) 0 .? 4 0.< r/ 0 .7 3 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear None Clear None C le a r None vELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (GaUFt.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM S)MVIPLER(S) Slj^NATURE(S): SAMPLING 17 7 / INITIATED AT: /->->/ SAMPLING ENDED AT: PUMP DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1 liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -^Y^ or No. MS/MSD sample collected - Yes or^N^ Collection Time: Well has fluoride treatment -^Ye^or No. Photograph No. / -f c A r.'n y / V V '. MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T= Teflon; O = Other (Specify) \MPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2 2 1 2 , s e c t i o n 3) pH: + 0.2 units Temperature: +0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally + 5 NTU or + 10% (whichever Is greater) Revision Date: February 12, 2009 I V/IIII I U J W V U - . T GROUNDWATER SAMPLING LOG I SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida /ELL NO: f ^ SAMPLE ID: "T x e PURGING DATA DATE: February 2 . .2010 WELL CASING - / TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): ^ ^ DIAMETER (Inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out it applicable) =( 2 V i feet- UNK feet) X gallons/foot = gallons EQUIPMENT VO LU M E PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons - gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 1233 /3 H /3 7 T FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) HL SIS PURGING 1* 7 / 0 INITIATED AT: ' i / ( TEMP. (C) COND. (pS/crn) n .3 *t n .n n -H i / fti is t PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) *./? .1 3 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear Clear Clear None None None .(/ELL CA PA CITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" =1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (GalTFt.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; S/16" =0.004; 3/8" = 0.006; 1/2" = 0,010; S/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SA^^ER(S|^IGNATURE(S): SAMPLING INITIATED AT: / i V 2' SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling or No. MS/MSD sample collected - Yes or(''N5) Collection Time: Well has fluoride treatm ent^ Y^ or No. Photograph No. / q c.ft rr n . y / V V *. MATERIAL CODES: A G =Amber Glass; C G = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) AMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S T A B IL IZ A T IO N C R I T E R I A F O R R A N G E O F V A R IA T IO N O F L A S T T H R E E C O N S E C U T I V E R E A D I N G S ( S E E F S 2212. S E C T IO N 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 r o r m r u uu u- h GROUNDWATER SAMPLING LOG p. 84 I SITE 1NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County. Florida /ELL NO: b u s .l| SAM PLE ID: DATE: February 2. ,2010 PURGING DATA WELL CASING . TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): DIAMETER (inches): NA | DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) gallons = ( J2. / 5 feet - UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons+ ( gallons/foot X feet)+ gallons = gallons PUM P DEPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /3 S 3 !3*< n s^ FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING - INITIATED AT: I J 5 0 PURGE RATE (gpm) ORP (mV) rn -- - pH (standard units) TEMP. (C) U3 4 -0 2 . 4 .c3 22- 21. ?S COND. (pS/cm) m J/o //o PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) Z . l3 r Z .1 3 z -3 3 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) O Clear None O Clear None Clear None WELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Qal.ZFU: 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S)SIGNATURE(S): SAMPLING . INITIATED AT: / V 0 V O = Other (Specify) SAMPLING ENDED AT: PUM P DEPTH IN W E LL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Eguipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK Unknown. Was the well pumping (active) prior to sampling or No. MS/MSD sample collected - Yes or ( N ^ Collection Time: Well has fluoride treatment -^^Sjor No. Photograph No. / ^ CR-T.-wy MATERIAL CODES: //>' A G =Amber Glass; CG = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) AMPLING EQUIPM ENT CODES: A PP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t iv e r e a d in g s (s e e FS 2212, s e c t io n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally +5 N T U or + 10% (whichever is greater) Revision Date; February 12, 2009 ro riii r u uuu-x* GROUNDWATER SAMPLING LOG p 35 I SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida 'ELL NO: / P o . 4> u , * ! I M v a V SAMPLE ID: DATE: February '2__ , 2010 PURGING DATA WELL CASiNG , TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): - 2 U> DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( J2, / feet - UNK feet) X gallons/foot = qallons EQUIPMENT VO LU M E PURGE: 1 EQUIPMENT V O L =PUM P VOLUME +(TUBING CAPACITY X TUBING LENGTH) +FLOW CELL VOLUME (only fill out if applicable) = gallons +( gallons/foot X feet) + gallons = gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (aallons) /yctf- N/b m3 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) ro 6. S' ? kSl PURGING . INITIATED AT: 3 i t TEMP. (C) n i 2. mi COND. (pS/cm) ns 8 1 PURGING ENDED AT; DISSOLVED OXYGEN (mg/L) (p e>.%S TOTAL VOLUME PU RGED (gallons); TURBIDITY (NTUs) COLOR (describe) ODOR (describe) O Clear None Clear None / 0 Clear None W ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" =0.04; 1.25" = 0.06; 2'' = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" =0.0006; 3/16" =0.0014; 1/4" =0.0026; 5/16" =0.004; 3/8" =0.006; 1/2" = 0.010; S/8" = 0.016 PURGING EQUIPMENT CODES: B =Bailer; B P =Bladder Pump; E S P =Electric Submersible Pump; PP =Peristaltic Pump; O =Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S)SIGNATURE(S): SAMPLING INITIATED AT: I H ! T SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE; NA TUBING: NA FIELD-FILTERED; No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA ft CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mLper minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling -^Yebj or No. MS/MSD sample collected - Yes or (N o) Collection Time: Well has fluoride treatment - ^ e s } x No. Photograph No. J 2 . 0 Cftrr< \5 to'. MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) 'A M P LIN G EQUIPMENT CODES: A P P = After Peristaltic Pump, B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; R FPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) N O TES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2 2 1 2 . s e c t io n 3) pH: + 0 .2 units Temperature: + 0 .2 C Specific Conductance: +5% Dissolved Oxygen: all readings <2 0 % saturation (see Table FS 2 2 0 0 -2 ); optionally, + 0 .2 mg/L or +10 % (whichever is greater) Turbidity: all readings <2 0 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 VI I GROUNDWATER SAMPLING LOG p. 86 SITE NAME: ECUA Water Distribution Svstem (Countv-wlde) SITE LOCATION: Escambia County, Florida VELLNO: Uj Q|/ /V flrv r SAM PLE ID: R p m DATE: February 3 ,2010 PURGING DATA WELL CASING I TUBING DIAMETER (Inches): 2 - (p J DIAMETER (Inches): NA W ELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK I PURGE PUMP TYPE: | Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) gallons = ( 2 ( 0 feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT V O L = PUM P VOLUM E + (TUBING CAPACITY X TUBING LENGTH) + FLOW C E LL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUM P DEPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) b lS l s is I FINAL PUMP | DEPTH IN WELL (feet): UNK PURGE RATE (gpm) ORP (mV) 4^ 2. PH (standard units) 4-?-/ 0 W 4 -b 8 (o.>1 PURGING INITIATED AT: - TEMP. (C) COND. (pS/cm) 2 1 . 2 <0 2 2 .2 .1 2 2 .2 -1 84 62 &3 PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) I TOTAL VOLUME j PURGED (gallons): TURBIDITY COLOR (NTUs) (describe) ODOR (describe) O Clear None C le a r None 0 Clear None YELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" = 1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B= Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLING DATA S ^ P L^ (S|^ G N A T U R E(S): SAMPLING _ INITIATED AT: C g C Z SAMPLING ENDED AT: PU M P DEPTH IN W E LL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorlnated Cmps by HPLC/MS. REMARKS: NA --Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^YeiP^Or No. MS/MSD sample collected - Yes or^Ng) Collection Time: Well has fluoride treatment fYos)tii No. Photograph No. f ( S a 4-c Ii j ' ) C.P1JV A 5 MATERIAL CODES: IS ? A G =Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) 'A M P LIN G EQUIPM ENT CODES: A P P = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) N O TES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t iv e r e a d in g s (s e e F S 2212, s e c t io n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see T ab le F S 2200-2); optionally, + 0.2 m g/L or + 10%-(w hlchever is greater) Turbidity: all readings < 2 0 NTU; optionally + 5 N T U or + 10% (whichever is greater) Revision Date: February 12, 2009  W i m I w <fw w w f c ' GROUNDWATER SAMPLING LOG I SITE I NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida fELLNQ; / . / ^ / ^ u ^ | l SAMPLE ID: - DATE: February ^ , 2010 PURGING DATA W ELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): b DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) =( ^ 1 feet - UNK - feet) X gallons/foot = gallons________________ ____________________________________________________________________________________________ ______ ___________________ EQUIPMENT VOLUM E PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( _______ gallons/foot X_______________ feet) +_____________ gallons =_______gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 6 8 oV CbSc l 63/0 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) 37> pH (standard units) ?-ol tj/k t/GT. X .c o 2-. PURGING PURGING INITIATED AT: 0 + 7 . 5 ENDED AT: TEMP. <C) COND. (pS/cm) DISSOLVED OXYGEN (mg/L) mi mi m/&o m ?.c4 (a. TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear None 2. Clear None ) Clear None ./E L L CA PA CITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4"=0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DfA. CA PA CITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8'= 0.006; 1/2* = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; SA M PLED B Y (PRINT) /AFFILIATION: David L. Anderson/CDM B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: 813 O = Other (Specify) SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME NA 2 PE I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling - Y e ^ o r No. MS/MSD sample collected - Yes or (N o ) Collection Time: Well has fluoride treatment ^ 3 ^ r No. /5~-f MATERIAL CODES: A G =Amber Glass; CG =Clear Glass; Photograph No. I^ Jl P E =Polyethylene; 3 C c /| c (-a3 /A 4 P P =Polypropylene; S =Silicone; T =Teflon; ^7" >4S' 6 . O =Other (Specify) ' \M PLIN G EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) N O TE S: 1. The above d o not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b iliza t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2212. s e c t io n 3) pH: +0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally +5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) V E L L N O :^ ^ SAMPLE ID: I SITE I LOCATION: Escambia County, Florida DATE: February ,2010 PURGING DATA WELL CASING ,, TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches); O DIAMETER (inches); NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) gallons =( 2 40 feet- UNK EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY X (only fill out if applicable) = gallons + ( gallons/foot X feet) X gallons/foot = TUBING LENGTH) + FLOW CELL VOLUME feet) + gallons = gallons PUM P DEPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) O B IS ' 62 8 063/ FINAL PUMP DEPTH IN WELL (feet): UNK PURGING PURGING INITIATED AT: O q 2 2 . ENDED AT: PURGE RATE (gpm) ORP (mV) 3-2 2 pH (standard units) TEMP. (C) 2-2.- u / COND. (pS/cm) DISSOLVED OXYGEN (mg/L) < j.ts 3 *1 322- S -.3 8 S \3 & 22-00 22.0) i/T - 7 . 0(0 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) 6 Clear None Clear None O Clear None .vELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" =0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLING DATA SfeMPLER(S) SIGNATURE(S): 3 X'i- - 33SAMPLING INITIATED AT: 8 SAMPLING ENDED AT: PUMP DEPTH IN W E LL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA urn Filtration Equipment Type: NA FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE IDCODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorlnated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling Y e s ) or No. Well has fluoride treatment -^e^fcr No. MS/MSD sample collected - Yes or Photograph No. 3 0 Collection Time: /V C . MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T=Teflon; O = Other (Specify) '4 M P L IN G EQUIPM ENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Grab) NOTES: 1. The above d o not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e FS 2212, s e c t io n 3) pH: + 0.2 units Temperature: +0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/Lor + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally +5 NTU or + 10% (whichever is greater) Revision Date: February 12,2009 ru m i rw owwvfcf GROUNDWATER SAMPLING LOG SITE NAME: ECU A Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida V E L L N O : X p A A , a T f ftCl SAM PLE ID: " 7 7 PURGING DATA DATE: February J ,2010 W ELL CASING n 0 TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): ^ DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( O feet- UNK feet) X gallons/foot = aailons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. =PU M P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons +( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) O I S 6638 b Hi FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) 2-/2 0*5 ?-/o PURGING 6 PURGING INITIATED AT: 0 8-22. ENDED AT: TEMP. (C) COND. (pS/cm) DISSOLVED OXYGEN (mg/L) 2\.y2 Z i - H 7- HI m 13 o r. tv r .t ? r. i t TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) / Clear None 0 Clear None / Clear None /ELL CAPACITY (Gallons Per Foot): 0.75" =0.02; 1" =0.04; 1.25" =0.06; 2" =0.16; 3" =0.37; 4" =0.65; 5" = 1.02; 6" =1.47; 112" =5.88 TUBING INSIDE DIA. CAPACITY (Gal/Ft.): 1/8" =0.0006; 3/16" =0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" =0.006; 1/2" =0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B =Bailer; SA M PLED B Y (PRINT) /AFFILIATION: David L. Anderson/CDM BP =Bladder Pump; ESP = Electric Submersible Pump; PP =Peristaltic Pump; SAMPLING DATA SAMPLER(SLGIGNATURE(S): VSAMPLING INITIATED AT: C S 0 =Other (Specify) SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE It CONTAINERS MATERIAL CODE VOLUME NA 2 PE 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling or No. MS/MSD sample collected - Yes or/'No) Collection Time: Well has fluoride treatment -{Ygpor No. Photograph No. J \- (. c V> j W0C A T.-fty Ai2.<h V\ MATERIAL CODES: AG =Amber Glass; C G =Clear Glass; P E =Polyethylene; PP =Polypropylene; S = Silicone; T =Teflon; O =Other (Specify) SA M PLIN G EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) vUTES: 1. The above d o not constitute all of the information required by Chapter 62-160, F.A.C. 2. S tabilizatio n C riteria fo r r a n g e o f variatio n o f l a s t t h r e e c o n s e c u t iv e r e a d in g s fS E E F S 2 2 1 2 . section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: ail readings <20% saturation (see Table F S 2200-2); optionally, + 0.2 m g/L or + 10% (w hichever is greater) Turbidity: all readings < 20 N TU ; optionally + 5 N T U or + 10% (w hichever is greater) Revision Date: February 12, 2009 I V4I111I WVWU-faT GROUNDWATER SAMPLING LOG p. 90 SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv, Florida VELL NO: , P & rV / / r+ ^ SAM PLE ID: DATE: February ^ ,2010 PURGING DATA WELL CASING ~ ^ ^DIAMETER (Inches): TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump =W ELL VOLUM E PURGE: 1 W ELL VOLUME (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) ^ =( 2 (p t feet- UNK feet) X =gallons/foot gallons = + +EQUIPMENT VOLUME PURGE: 1 EQUIPMENT V O L PUM P VOLUME (TUBING CAPACITY X TUBING LENGTH) FLOW CELL VOLUME (only fill out If applicable) = gallons +( gallons/foot X +feet) =gallons gallons PUMP DEPTH IN W ELL (feet): UNK FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING AQvt INITIATED AT: PURGING ENDED AT: TOTAL VOLUME PURGED (gallons); TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) PURGE RATE (gpm) ORP (mV) VfS VSo pH (standard units) TEMP. <C) &./<r 2 / . ? ! L /? 2 /- f b CONO. (gS/cm) r2 DISSOLVED OXYGEN (mg/L) 1 -L 2 TURBIDITY (NTUs) o o COLOR (describe) C le a r Clear ODOR (describe) None None V 8 I L i V 2/. T l S' ? .L I 0 Clear None /ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 = =TUBING INSIDE DIA. C APACIT Y (Gal./Ft.): 1/8" 0.0006; 3/16" =0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" =0.010; 5/8" 0.016 = =PURGING EQUIPMENT CODES: B Bailer; B P Bladder Pump; =E S P Electric Submersible Pump; =PP Peristaltic Pump; =O Other (Specify) SAMPLING DATA SAMPLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: SAMPLING I3- ENDED AT: PUM P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE IDCODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1 liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 m L Fluorinated Cm ps by H PLC/M S. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling Y e s) or No. MS/MSD sample collected - Yes or (No) Collection Time: Well has fluoride treatment - ^ e ijo r No. Photograph No. ^ C P , r-~<\S b a f lM / U 2 '. MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) '4M PLIN G EQUIPMENT COOES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above d o not constitute all of the Information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d in g s (s e e FS 2212, s e c t io n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever Is greater) Turbidity: all readings <20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p . 91 SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida V E L L N O : / i; , p o r f- / ) / 0 f t V\ SAM PLE ID: DATE: February ^ , 2010 PURGING DATA W ELL CASING -, TUBING W ELL SC R E EN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): J DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out If applicable) gallons =( X 4 + feet- UNK EQUIPM ENT VO LU M E PURGE: 1 EQUIPMENT VOL. = PU M P VOLUME + (TUBING CAPACITY feet) X gallons/foot X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons : gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 0 7 /S' o ?/e FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING Q INITIATED AT: / O PURGE RATE (gpm) ORP (mV) pH (standard units) TEMP. (C) 4*8 ? U 7 7 COND. (pS/cm) /os' L?H ( 2/- 7 8 i/o /o7~ PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) T~3 D I-! 7 V 3o TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear None Clear None Clear None /E L L CA PA CITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CA PA CIT Y (Gal./Ft.): 1/8" = 0.0006; 3/16* = 0.0014; 1/4" =0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/6" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; PP = Peristaltic Pump; 0 = Other (Specify) SAMPLING DATA S A M PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING -, INITIATED AT: O y - ^ 0 SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 m L Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling -(Y@) or No. MS/MSD sample collected - Yes or Collection Time: Well has fluoride treatment-^Yegiiir No. Photograph No. (p C $ a 4-c V\ | ^ C A -r.-w j- Jk^.r+K / (q2. . MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) SAMPLING EQUIPMENT CODES: A PP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain): O = Other (Grab) i.oTES: 1. The above do not constituteall of the information required by Chapter 62-160, F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS (SEE F S 2212. SECTION 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date; February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv. Florida VELLNO :/hC / V / ; ^ W SAMPLE ID: PURGING DATA DATE: February 3 , 2010 WELL CASING . TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): ^ DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: (only fill out if applicable) gallons 1 WELL VOLUME = (TOTAL W ELL DEPTH - = ( 2. V2. feet - STATIC DEPTH TO WATER) X WELL CAPACITY UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME +(TUBING CAPACITY X (only fill out if applicable) = gallons+( gallons/foot X TUBING LENGTH) + FLOW CELL VOLUME feet) -r- gallons = gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) >??? o fy z o<? /(p FINAL PUM P DEPTH IN W ELL (feet); UNK PURGE RATE (gpm) ORP (mV) *HS TV* S31 pH (standard units) S-S'? PURGING _ I PURGING INITIATED AT. 7 J 3 | ENDED AT: TEMP. (C) COND. (pS/cm) DISSOLVED OXYGEN (mg/L) 2 2 - 0 fc 22-07 2. ?.ofe 7 .02. 22-/0 O TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) O Clear None O Clear None 0 C le a r None YELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" =0.37; 4" = 0.65; 5" =1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DlA. CAPACITY (Gal./Ft ): 1/8" =0.0000; 3/16" = 0.0014; 1/4" =0.0026; 5/16" =0.004; 3/8" =0.006; 1/2" =0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B =Bailer; BP =Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O =Other (Specify) SAM PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLING DATA SAMPLER(S) SIGNATURE(S): SAMPLING iQ INITIATED AT: 7 V 7 SAMPLING ENDED AT: PUMP DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1 liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorlnated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -(Ye^) or No. MS/MSD sample collected ^Yes) or No. Collection Time: * 3 7 ^ * 7 Well has fluoride treatment or No. Photograph No. - f - V\ \ C A T f A j toff* y ? o ' . MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) "AMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) ivuTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d in g s (s e e FS 2212, s e c t io n 3) pH: +0.2 units Temperature: +0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever Is greater) Turbidity: all readings <20 NTU; optionally +5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 93 SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida WELL NO: A / / i/ W SAM PLE ID: J DATE: February 3" . 2010 PURGING DATA WELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): -2 (o DIAMETER (Inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) = ( X V2. feet - UNK feet) X gallons/foot = qallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME +(TUBING CAPACITY X TUBING LENGTH) +FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (qallons) o^sz 0 <k 8 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) ui ,2e? 13 o pH (standard units) -7-2 g 7--2U PURGING INITIATED AT: 7 3 3 TEMP. <C) COND. (pS/cm) Zo.qz 2o.cfl IS* /SB IS* PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) /V i" 3 .si 3. So TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) z 1 1 COLOR (describe) Clear Clear Clear ODOR (describe) None None None WELL CAPACITY (Gallons Per Foot): 0.75" =0.02; 1" =0.04; 1.25" = 0.06; 2" =0.16; 3" =0.37; 4" =0.65; 5" =1.02; 6 " =1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" =0.0006; 3/16" =0.0014; 1/4" =0.0026; 5/16" =0.004; 3/8" =0.006; 1/2" =0.010; ii/8" =0.016 PURGING EQUIPMENT CODES: B =Bailer; BP =Bladder Pump; ESP =Electric Submersible Pump; PP = Peristaltic Pump; 0 =Other (Specify) SAMPLING DATA S A M PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM S/\MPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: / O * SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA If CONTAINERS 2 MATERIAL CODE PE VOLUME 1 liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling - ^ e s ) or No. MS/MSD sample collected -(Yes) or No. Collection Time: Well has fluoride treatment fYespor No. Photograph No. C -B a V c -H ) ") C A r.- i\.f Aer+K t l o ' . MATERIAL CODES: A G =Amber Glass; C G = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) SAM PLIN G EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; R FPP = Reverse Flow Peristaltic Pump; SNI = Straw Method (Tubing Gravity Drain); O = Other (Grab) ivOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2 . S t a b i l i z a t io n C r i t e r ia f o r r a n g e o f v a r ia t io n of l a s t t h r e e c o n s e c u t i v e r e a d i n g s ( s e e F S 2 2 1 2 . s e c t io n 3) pH: +0 .2 units Temperature: +0 .2 C Specific Conductance: 5 % Dissolved Oxygen: all readings <2 0 % saturation (see Table F S 2 2 0 0 -2 ); optionally, + 0 . 2 mg/L or + 1 0 % (whichever is greater) Turbidity: all readings < 2 0 NTU; optionally +5 NTU or + 1 0 % (whichever Is greater) Revision Date: February 12, 2009  V VW GROUNDWATER SAMPLING LOG p. 94 SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv. Florida VELLN0: SAMPLE ID: DATE: February 3 ,2010 PURGING DATA WELL CASING o DIAMETER (inches): TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) = ( 7L lob feet - UNK feet) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PU M P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out If applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUMP DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /o />*/<o As rc FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING INITIATED AT: / O V 0 PURGE RATE (gpm) ORP (mV) -- - pH (standard units) TEMP. (C) (d -B % C-81 C&3 Z 2.2 .G 2 2 .2 .1 2 2 .2 \ COND. (nS/cm) n 7-8 PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) S '? 6 ,-U .2 . TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) 0 Clear None O Clear None 0 Clear None I ,/ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" =1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY(Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.0f0; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAMPLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): uL*-- R w U y SAMPLING . INITIATED AT: / C S 5 " SAMPLING ENDED AT: PUMP DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fiuorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling or No. MS/MSD sample collected - Yes or(7t^ Collection Time: Well has fluoride tre atm e nt-^ ^ or No. Photograph No. / ( # a +c V> Z l) c p i c Wr V \ /L fC '. MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; P E = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) 'A M P LIN G EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; R FPP - Reverse Flow Peristaltic Pump; SM = Straw Method (Tublng Gravity Drain); O - Other (Grab) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2 2 1 2 , s e c t io n 3) pH: +0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: ail readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally +5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 I W h/WVfc-T GROUNDWATER SAMPLING LOG SITE NAME: E C U A Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida V ELL NO: r g y 'J SAM PLE ID: J PURGING DATA DATE: February 2010 WELL CASING TUBING W ELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (Inches): -> DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) = ( 2. t S feet- UNK qallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VO L = PUM P VOLUME + (TUBING CAPACITY X (only fill out If applicable) = gallons + ( gallons/foot X feet) X gallons/foot = TUBING LENGTH) + FLOW CELL VOLUME feet) + gallons = gallons PU M P D EPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) / D i' 8 // / //o< y FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING .,, INITIATED AT: / " & PURGE RATE (gpm) ORP (mV) LVe pH (standard units) TEMP. (C) 6 > . V .2 /-? o (e. 7 1 2j. COND. (gS/cm) / io /< e ? (o 3 J 2 /.1 0 / to PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) r.s ? TOTAL VOLUME PURGED (gallons): TURBIDITY COLOR (NTUs) (describe) ODOR (describe) o Clear None Clear None Clear None /ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 6/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SA M PLED B Y (PRINT) / AFFILIATION; David L. Anderson/CDM 5WMPLER(S)SIGNATURE(S): SAMPLING INITIATED AT: / / 6 SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE; NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA um SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 m L Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling( Y e j) o r No. MS/MSD sample collected - Yes or ( N o3 Collection Time: Well has fluoride treatment^Yej) or No. Photograph No. f ^+.4-^ J2. (L -a A - ^ K C A /riij- /y r '. MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) SAMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) iiOTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see F S 2212. section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wlde) SITE LOCATION: Escambia Countv. Florida A/ELLNO: j$ / - 0 A 4 SAMPLE ID: DATE: February ,2010 PURGING DATA WELL CASING -n TUBING WELL SCREEN INTERVAL PUMPING WATER PU RGE PUMP TYPE: DIAMETER (inches): DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: (only fill out if applicable) gallons 1 W ELL VOLUME = (TOTAL WELL DEPTH = ( feet- STATIC DEPTH TO WATER) X WELL CAPACITY UNK feet) X gallons/foot = EQUIPMENT VOLUM E PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X (only fill out if applicable) = gallons + ( gallons/foot X TUBING LENGTH) + FLOW CE LL VOLUME feet) + gallons : gallons PUMP DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 1178 //Ml FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING , INITIATED AT: / / 3 5 PURGING ENDED AT: PURGE RATE (gpm) ORP (mV) 3 383 pH (standard units) TEMP. (C) U . 3 5 - 2-1- 2 1 COND. (pS/cm) (d 3 s DISSOLVED OXYGEN (mg/L) s .n r-2 o 311 6 - 3 3 2 / -2-1 6>t/ $ '8 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear Clear Clear None None None V E L L CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" = 1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CA PA CIT Y (Gal./Ft ): 1/8" =0.0006; 3/16" =0.0014; 1/4" = 0,0026; 5/16" = 0,004; 3/8" = 0.006; 1/2" =0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLING DATA SAMPLER(S) SIGNATURE(S): SAMPLING ., u , INITIATED AT: / / 7 uj SAMPLING ENDED AT: PUMP DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 m L by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling -^ eS) or No. MS/MSD sample collected -Y es or ^o^)Collection Time: Well has fluoride treatment VYes)or No. Photograph No. 3 C B a V c.V\ J2.") r-'rv j MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) ~AMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NOTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. S T A B IL IZ A T IO N C R I T E R I A F O R R A N G E O F V A R IA T IO N O F L A S T T H R E E C O N S E C U T I V E R E A D I N G S ( S E E F S 2212, S E C T IO N 3) pH: + 0.2 units Temperature: 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 97 SITE NAME: ECU A Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida VELLNO: $ , 0 * J S-\- SAM PLE ID: DATE: February 3 2010 PURGING DATA W ELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) . =( JZt I feet - UNK gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY feet) X gallons/foot = X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P D EPTH IN W ELL (feet); UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) tm i/s z FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) (d C ip pH (standard units) 7 -zs" PURGING //y r INITIATED AT: U J -S TEMP. (C) COND. (pS/cm) SCI .1 o 2 - ?o //o //O //o PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) r.$ 2 r . ?- u r . f <o TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) C le a r None / C le a r None C C le a r None ,,ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5"=1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (GaliFt.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SA M PLE D B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING .- INITIATED AT: / - 2 a 6 SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SA M PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling -^Yes) or No. MS/MSD sample collected - Yes or ( nq^) Collection Time: Well has fluoride treatm ent^ YesV No. Photograph No. C 3 A+ 2-3) c W H \ / 4 ? '. MATERIAL CODES: A G =Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) SAMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NuTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see F S 2212. section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, +0.2 m g/Lor + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG p. 98 SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County, Florida A/ELLNO: ' 7 ^ A r ,A A 4 - SAMPLE ID: R p i U j DATE: February 3 ,2010 PURGING DATA WELL CASING DIAMETER (Inches): TUBING DIAMETER (Inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PU RGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out If applicable) gallons = ( JZ O g feet- UNK feet) X gallons/foot = EQUIPMENT VO LU M E PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW C E LL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons : gallons PUMP DEPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /S W /If* /3 o * FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING INITIATED AT:. / X Sb PURGING ENDED AT: PURGE RATE (gpm) ORP (mV) 3-M - 31$ 311 pH (standard units) TEMP. (C) S / (d 2 2 - 0 ^ r-n 1 - 22. COND. (pS/cm) SS S"6 DISSOLVED OXYGEN (mg/L) & /? b-l 8 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear None & Clear None Clear None /E L L C A PA CIT Y (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" = 1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DIA. C A PA C IT Y (Gal,/Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S) SIGNATURE(S): SAMPLING ,, _ INITIATED AT: l - i ^ S O =Other (Specify) SAMPLING ENDED AT: PUMP DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling^Yes) or No. MS/MSD sample collected - Yes or(N o) Collection Time: Well has fluoride treatment ^Ye^or No. Photograph No. $ " C 2 . ") c ft/T n j (c> MATERIAL CODES: A G =Amber Glass; CG = Clear Glass; PE = Polyethylene; P P = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) SAMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) iwTES: 1. The above do not constituteall of the information required by Chapter 62-160, F.A.C. 2. S t a b iliz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t iv e r e a d in g s (s e e F S 2212. s e c t io n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever Is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever Is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECU A.Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida KELL NO: 7 e D R A n + - SAM PLE ID: DATE: February ^ ,2010 PURGING DATA WELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): '2-<r DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out If applicable) = ( ^2. C> 8 feet - UNK feet) X gallons/foot = aallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT V O L = PU M P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /3og I3 H 13 FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING ., - INITIATED AT: s 0 PURGING ENDED AT: PURGE RATE (gpm) ORP (mV) c(p pH (standard units) TEMP. (C) ? ./o 27- 0 5 COND. (gS/cm) <7? DISSOLVED OXYGEN (mg/L) fc-i 8 <00? 7 -0 ? 7 -/o 2 2 .0 S 22. 0S /o ? / c > 2. L IZ TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) I C le a r None C le a r None I Clear None .ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft ): 1/8" = 0.0006; 3/15" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SA M PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM PU M P DEPTH IN W ELL (feet): UNK SAMPLING DATA SAMPLER(S) SIGNATURE(S): fe o u w A x i/TUBING MATERIAL CODE: NA SAMPLING M INITIATED AT: / J / + SAMPLING ENDED AT: FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling ^Ye^) or No. MS/MSD sample collected - Yes orf'^No) Collection Time: Well has fluoride treatment -(Y'esfor No. /'Hk /T (e Photograph No. (p ^ >p - \ c h 3 ") MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) "A M P L IN G EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Plow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) Nu CES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see F S 2212. section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever Is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv. Florida WELL NO: A U CO J f t k SAMPLE ID: DATE: February 3 ,2010 PURGING DATA WELL CASING // DIAMETER (inches): ' ^ TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PU RGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) , = ( 2. 0 4 feet- UNK feet) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) PURGING INITIATED AT: TEMP. (C) COND. (gS/cm) PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear None Clear None Clear None J L s A rAp L e V E L L CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" =0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CA PA CIT Y (Gal./Ft ). 1/8" = 0.0008; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE IDCODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1 lite r SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sam pling-Yes or No. MS/MSD sample collected - Yes or No. Collection Time: Well has fluoride treatment - f is t a r No. Photograph No. 2 .") d n .rt1' /^o i-- y / 'sA-M.-nj-- MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) '' AMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) ivoTES: 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r ia t io n o f l a s t t h r e e c o n s e c u t iv e r e a d in g s (s e e F S 2 2 1 2 , s e c t io n 3) pH:+ 0 . 2 units Temperature: +0 .2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 2 0 % saturation (see Table F S 2 2 0 0 -2 ); optionally, 0 .2 mg/L or + 10 % (whichever is greater) Turbidity: all readings < 2 0 NTU; optionally + 5 NTU or + 10 % (whichever is greater) Revision Date: February 12, 2009 I W i l l i I LS v V W V " L T GROUNDWATER SAMPLING LOG p. 1 0 1 SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida VELLNO: SAM PLE ID: DATE: February 3 ' 2010 PURGING DATA W ELL CASING -7 TUBING WELL SCREEN INTERVAL I PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): J DIAMETER (inches): NA DEPTH: UNK | LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) = ( 2 .0 0 feet - UNK feet) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PU M P VOLUM E + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 1331 13 42. FINAL PUM P DEPTH IN W ELL (feet): UNK PURGING . INITIATED AT: 1 3 3 S PURGE RATE (gpm) ORP (mV) 36>s 3 Ly I PH (standard units) TEMP. (C) * fe. 8 - fe . 2 /- b o 4.1-80 a -l.n COND. (pS/cm) to to SI PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) ? . 2 (j> .a 2 TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) / Clear None O Clear None 0 Clear None , ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 5" = 1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (GalTFt.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; /S A M PLE D B Y (PRINT) AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP Peristaltic Pump; SAMPLING DATA 9AMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: I J 7 T O = Other (Specify) SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL C00E PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling ^Ye^ or No. MS/MSD sample collected - Yes oi(^N^ Collection Time: Well has fluoride treatment or No. Photograph No. CISprVcV\ 12. c a t .-i i j MATERIAL CODES: />yf'. = =A G Amber Glass; CG Clear Glass; =PE Polyethylene; = = = =PP Polypropylene; S Silicone; T Teflon; O Other (Specify) ~\MPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) NitTES: 1. The abovedo n ot constituteall o f the information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see F S 2212. section 3) pH: + 0.2 units Temperature:+0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, 0.2 mg/L or + 10% (whichever Is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia Countv. Florida /VELLNO: SAMPLE ID: DATE: February ^ ,2010 PURGING DATA WELL CASING ^ TUBING WELL SCREEN INTERVAL I PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): -> ^ DIAMETER (inches): NA DEPTH: UNK I LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) =( 2 O O feet - UNK feet) X gallons/foot gallons EQUIPMENT VOLUM E PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) 13 r 13 S 3 l3S<o FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) s '$ 4 rs i PURGING ,? - INITIATED AT: > 3 S S TEMP. (C) COND. (pS/cm) 2 c ..S > (,4 PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) -H (IS (e TOTAL VOLUME PURGED (gallons): TURBIDITY COLOR (NTUs) (describe) ODOR (describe) Clear Clear Clear None None None /ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (QalTFt.): 1/8" = 0.0006; 3/16" =0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: I t y t 6 0 = Other (Specify) SAMPLING ENDED AT: PUM P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^ Yei) or No. MS/MSD sample collected - Yes or (No) Collection Time: Well has fluoride treatment -^7e^ or No. Photograph No. c | -2. c a /v a / /</ ' MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) SAM PLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) u o T E S : 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b i l i z a t i o n C r i t e r i a f o r r a n g e o f v a r i a t i o n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e FS 2212, s e c t i o n 3) pH: +0.2 units Temperature: 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, +0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally +5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG i SITE NAME; ECU A Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida .VELLNO: | / / / / A Q , UQ. SAM PLE ID: Ka k ) PURGING DATA DATE: February 3 , 2010 WELL CASING _ TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (Inches): 3 O DIAMETER (Inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) = ( 2 3 2_ feet - UNK feet) X gallons/foot = aallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. =PU M P VOLUME +(TUBING CAPACITY X TUBING LENGTH) +FLOW CELL VOLUME (only fill out If applicable) = gallons +( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /VO? Hn H/S FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING . , / PURGING INITIATED AT: / V O * ENDED AT: PURGE RATE (gpm) ORP (mV) nn pH (standard units) XU f'L i <. (A TEMP. (C) Al- (,6 Al- U COND. (gS/cm) rS rt DISSOLVED OXYGEN (mg/L) / I S / a ? /. ?o TOTAL VOLUME PURGED (gallons): TURBIDITY COLOR (NTUs) (describe) ODOR (describe) O Clear None O Clear None O Clear None ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" =0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" =0.65; 6" =1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (GalVFt ): 1/8" = 0.0006: 3/16" =0.0014; 1/4" =0.0026; 5/16" = 0.004; 3/8" =0.006; 1/2" =0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B =Bailer; BP =Bladder Pump; ESP =Electric Submersible Pump; PP =Peristaltic Pump; O =Other (Specify) SAMPLING DATA SA M PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): I SAMPLING | INITIATED AT: / V / 8 SAMPLING ENDED AT: PU M P DEPTH IN W E LL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA It CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling^Yes^or No. MS/MSD sample collected - Yes or (N O C o lle ctio n Time: Well has fluoride treatment -^Yes)cr No. Photograph No. / b C S Z2. C A .rri\ j /cc ' MATERIAL CODES: A G = Amber Glass; CG = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) SAM PLING EQUIPM ENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) .. _ i'ES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S t a b i l i z a t i o n C r i t e r i a f o r r a n g e o f v a r i a t i o n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e FS 2212. s e c t i o n 3) pH: + 0.2 units Temperature: +0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/Lor + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) NELL NO: [/ f / / A Q , (vJ SAM PLE ID: SITE LOCATION: Escambia Countv. Florida -f, DATE: February 3 , 2010 PURGING DATA WELL CASING -j DIAMETER (inches): TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out If applicable) = ( 2 . 3 2. feet- UNK feet) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY TUBING LENGTH) + FLOW CELL VOLUME (only fill out If applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /^ 2 o AV23 / V - 7 Ip FINAL PUMP DEPTH IN W ELL (feet): UNK PURGING . INITIATED AT: r V 0 ( ? PURGE RATE (9pm) ORP (mV) 6Y8 U V<o pH (standard units) TEMP. (C) 2 o .? % 2 0 -? $ COND. (pS/cm) /8 o I I ?/* /g o PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) I I (e / p y /. o l TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear Clear Clear None None None E L L CAPACITY (Gallons Per Foot): 0.75'' = 0.02; 1" = d.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4"=0.65; 5" = 1.02; 6" = 1.47; 12" =5.88 TUBING INSIDE DIA. CA PA CITY (QaUFt): 1/8" = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2"=0.010; S/8* = 0.016 PURGING EQUIPMENT CODES: B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAM PLED BY (PRINT) / AFFILIATION: David L. Anderson/CDM SAMPLING DATA SAMPLER(S)SIGNATURE{S): SAMPLING , INITIATED AT: ' 7 2 6 SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME i liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cm ps by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. W as the well pumping (active) prior to sampling rYe^> or No. MS/MSD sample collected - Yes or C 5 g 3 Collection Time: Well has fluoride treatment No. Photograph No. f t ( i? h 4 - c k 2."^ CAr-ny W+'h / c '- MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; P E = Polyethylene; P P = Polypropylene; S = Silicone; T = Teflon; O = Other (Specify) RAMPLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E SP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) i.^ T E S : 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. STABILIZATION C R IT E R IA FO R R A N G E O F VARIATION O F L A S T T H R E E C O N S E C U T IV E R E A D IN G S (S E E FS 2212. SECTIO N 3) pH: +0.2 units Temperature: 0.2 C Specific Conductance: 5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, +0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings <20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECU A Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida W ELL NO: j ^ e / C e SAM PLE ID: ^ DATE: February J ,2010 PURGING DATA W ELL CASING ~ TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (Inches): DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: 1 WELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X W ELL CAPACITY (only fill out if applicable) = ( 2-V O feet- UNK feet) X gallons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PU M P VOLUME +(TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) iq ss W St /5c f FINAL PU M P DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) V -20 1/2.3 pH (standard units) r .3 7 S -.2- ? s '. 2-3- PURGING INITIATED AT: / V S Z PURGING ENDED AT: TEMP. (C) COND. (pS/cm) DISSOLVED OXYGEN (mg/L) 2 2 - ILj 2 2 . IH 7-4 S~.fl 1* TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) o COLOR (describe) Clear Clear Clear ODOR (describe) None None None ELL CAPACITY (Gallons Per Foot): 0.75" =0.02; 1" =0.04; 1.25" = 0.06; 2" =0.16; 3" =0.37; 4" =0.65; 5" = 1.02; 6" =1.47; 12" =5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" =0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" =0.006; 1/2" =0.010; SIB"= 0.016 PURGING EQUIPMENT CODES: B = Bailer; SA M PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM BP =Bladder Pump; ESP =Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S)SIGNATURE(S): SAMPLING . INITIATED AT: I S (ij O =Other (Specify) SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING: NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAM PLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL pH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorlnated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling ^ Y e i> o r No. MS/MSD sample collected - Yes af^Ng) Collection Time: Well has fluoride treatm ent-as)or No. C ftr.-n y /3 fc\ Photograph No. / 2- C 8 e 4 c V \ 2.") MATERIAL CODES: A G = Amber Glass; C G = Clear Glass; PE = Polyethylene; P P = Polypropylene; S = Silicone; T =Teflon; 0 = Other (Specify) I SAM PLING EQUIPM ENT CODES: APP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; RFPP = Reverse Row Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) .. - (ES: 1. The above do not constituteall of the information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see F S 2212. section 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 m g/Lor + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date; February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County, Florida W ELL NO: SAM PLE ID: DATE: February , 2010 PURGING DATA WELL CASING TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): 3 DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump WELL VOLUME PURGE: (only fill out if applicable) gallons 1W ELL VOLUME = (TOTAL W ELL DEPTH - = ( 2.V 0 feet - STATIC DEPTH TO WATER) X WELL CAPACITY UNK feat) X gallons/foot = EQUIPMENT VOLUM E PURGE: 1 EQUIPMENT VOL. = PUM P VOLUME + (TUBING CAPACITY X (only fill out if applicable) = gallons + ( gallons/foot X TUBING LENGTH) + FLOW CELL VOLUME feet) + gallons = gallons PUM P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) /r* * / r /o /r/3 FINAL PU M P DEPTH IN W ELL (feet): UNK PURGING PURGING INITIATED AT: ^ S 2 . ENDED AT; PURGE RATE (gpm) ORP (mV) pH (standard units) TEMP. (C) COND. (nS/cm) DISSOLVED OXYGEN (mg/L) ml -22-02. S', fev mi ? ./g in 22.-o 1 22. 0 3 ** r. U S'. U S TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) o Clear None Clear None Clear None ,E L L CAPA CIT Y (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal/Ft.): 1/8 =0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; PP = Peristaltic Pump; O =Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) /AFFILIATION: David L. Anderson/CDM ^AMPLER(S) SIGNATURE(S): SAMPLING .^ . i INITIATED AT: / b / SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK FIELD DECONTAMINATION: PUMP: No TUBING MATERIAL CODE: NA TUBING; NA FIELD-FILTERED: No Filtration Equipment Type: DUPLICATE: NA FILTER SIZE: No NA urn SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH___ NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorlnated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling^Ye^) or No. MS/MSD sample co llected -Y e s o r/ 'N ip C o l lection Time: Well has fluoride treatment - { S to r No. CA rn\f 3 la . Photograph No. 13 C B f v V c K -2_') MATERIAL CODES: AG =Amber Glass; CG =Clear Glass; PE =Polyethylene; PP =Polypropylene; S = Silicone; T =Teflon; O =Other (Specify) SAM PLING EQUIPMENT CODES: A P P = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; R FPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); 0 = Other (Grab) i.^ T E S : 1. The above do not constitute all of the Information required by Chapter 62-160, F.A.C. 2. S t a b il iz a t io n C r it e r ia f o r r a n g e o f v a r i a t i o n o f l a s t t h r e e c o n s e c u t i v e r e a d i n g s (s e e F S 2 2 1 2 , s e c t i o n 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings <20% saturation (see Table FS 2200-2); optionally, +0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (County-wide) SITE LOCATION: Escambia County, Florida W ELL NO: / ) j - J o . V SAM PLE ID: DATE: February 3 2010 PURGING DATA WELL CASING , q TUBING WELL SCREEN INTERVAL PUMPING WATER DIAMETER (inches): ' D DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) = ( JZ8 0 ,e0t - UNK feet) X PU RGE PUMP TYPE: Existing Pump gallo ns/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PUMP VOLUME + (TUBING CAPACITY X (only fill out if applicable) gallons + ( galtons/foot X PUM P DEPTH IN W E LL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) PURGING INITIATED AT: TEMP. (C) COND. (gS/cm) TUBING LENGTH) + FLOW CELL VOLUME feet)+ PURGING ENDED AT: gallons = gallons TOTAL VOLUME PU RGED (gallons): DISSOLVED OXYGEN (mg/L) TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear None Clear None Clear None /V c T a N \ PI<Z. ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25'' = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" = 1.02; 6*' = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8* = 0.0006; 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; O = Other (Specify) SAMPLING DATA SAM PLED BY (PRINT) /AFFILIATION: David L. Anderson/CDM SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA urn Filtration Equipment Type: NA FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE IDCODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorinated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. N A -N c ri Applicable. K W as the well pumping (active) prior to sam pling-Y es or No. UNK-Unknown. D- l~i\as o. r\ C A -r-rn * d.r+Vt / o ' . MS/MSD sample collected - Yes or No. Collection Time: f Well has fluoride treatment - Yes or No. Photograph No. ^4/ C * V t.V \ 2 . UlO-ll U t MATERIAL CODES: i'A A C + C o . -P<v 3 - V Y AG =Amber Glass; CG =Clear Glass; A c 4PE =Polyethylene; o r A'o fu4vrt<J. OS'<3. oiL + W , f r iQ . PP =Polypropylene; S = Silicone; T =Teflon; O =Other (Specify) SAMPLING EQUIPMENT CODES: APP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP =Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) CES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. S T A B I L I Z A T I O N C R I T E R I A F O R R A N G E O F V A R IA T IO N O F L A S T T H R E E C O N S E C U T I V E R E A D I N G S ( S E E F S 2212. S E C T IO N 3) pH: + 0.2 units Temperature: + 0.2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (Countv-wide) SITE LOCATION: Escambia County, Florida W ELL NO: ^ y SAM PLE ID: DATE: February "R ,2010 PURGING DATA W ELL CASING , TUBING WELL SCREEN INTERVAL PUMPING WATER PURGE PUMP TYPE: DIAMETER (inches): *- & DIAMETER (inches): NA DEPTH: UNK LEVEL (feet): UNK Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL W ELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) , gallons =( 4 0 1 feet- UNK feet) X gallons/foot = EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL. = PU M P VOLUME + (TUBING CAPACITY (only fill out If applicable) TUBING LENGTH) + FLOW CELL VOLUME = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) PURGING INITIATED AT: TEMP. (C) COND. (pS/cm) PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) ODOR (describe) Clear None Clear None yVc> S A l ^ p L Z r Clear None /ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1'' = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" = 1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006: 3/16" = 0.0014; 1/4" = 0.0026; 5/16" = 0.004: 3/8" =0.006; 1/2" = 0.010; 5/8" = 0.016 PURGING EQUIPMENT CODES: B = Bailer; SAM PLED BY (PRINT) /AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP a Peristaltic Pump; SAMPLING DATA SAMPLER(S) SIGNATURE(S): SAMPLING INITIATED AT: O = Other (Specify) SAMPLING ENDED AT: PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE: NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE # CONTAINERS MATERIAL CODE VOLUME NA 2 P E 1liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & Fluorlnated Cmps SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL by HPLC/MS. REMARKS: NA - Not Applicable. UNK - Unknown. Was the well pumping (active) prior to sampling - Yes or No. MS/MSD sample collected - Yes or No. Collection Time: Well has fluoride treatment -<Yes)or No. T k < * J'i'A- W A T TAj ft c> MATERIAL CODES: AG =Amber Glass; CG =Clear Glass; Photograph No. 1S' C.dA<=V\-2.") r^-l\ ftb 1i'-fi4A-''*r\. /b t i C A jV n ^ PE =Polyethylene; PP =Polypropylene; S = Silicone; T =Teflon; 2 / t> . O =Other (Specify) SAMPLING EQUIPMENT COOES: APP = After Peristaltic Pump; B = Bailer; BP = Bladder Pump; ESP = Electric Submersible Pump; RFPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) ...TES: 1. The above do not constituteall of the information required by Chapter 62-160, F.A.C. 2. STABILIZATIO N C R IT E R IA FO R RANGE O F VARIATION O F LA S T TH R EE CO N SECU TIV E READ IN G S (S E E F S 2 2 1 2 , SECTIO N 3) pH: +0 .2 units Temperature: +0 .2 C Specific Conductance: +5% Dissolved Oxygen: all readings < 2 0 % saturation (see Table FS 2 2 0 0 -2 ); optionally, +0 .2 mg/L or +1 0 % (whichever is greater) Turbidity: all readings <2 0 NTU; optionally +5NTU or +1 0 % (whichever is greater) Revision Date: February 12, 2009 GROUNDWATER SAMPLING LOG SITE NAME: ECUA Water Distribution System (County-wide) AWELL NO: L F -- SAM PLE ID: SITE LOCATION: Escambia County, Florida JDATE: February ,2010 PURGING DATA WELL CASING DIAMETER (inches): 3o TUBING DIAMETER (inches): NA WELL SCREEN INTERVAL DEPTH: UNK PUMPING WATER LEVEL (feet): UNK PURGE PUMP TYPE: Existing Pump W ELL VOLUME PURGE: 1 W ELL VOLUME = (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) _ .,, =( 3 V g feet- UNK feet) X gallons/foot = gallons EQUIPMENT VO LU M E PURGE: 1 EQUIPMENT VOL. = PU M P VOLUME + (TUBING CAPACITY X TUBING LENGTH) + FLOW CELL VOLUME (only fill out if applicable) = gallons + ( gallons/foot X feet) + gallons = gallons PU M P DEPTH IN W ELL (feet): UNK TIME (CST) VOLUME PURGED (gallons) CUMUL. VOLUME PURGED (gallons) FINAL PUMP DEPTH IN W ELL (feet): UNK PURGE RATE (gpm) ORP (mV) pH (standard units) PURGING INITIATED AT: TEMP. (C) COND. (pS/cm) PURGING ENDED AT: DISSOLVED OXYGEN (mg/L) TOTAL VOLUME PURGED (gallons): TURBIDITY (NTUs) COLOR (describe) Clear ODOR (describe) None Clear None S f\ ya P i . r Clear None ELL CAPACITY (Gallons Per Foot): 0.75" = 0.02; 1" = 0.04; 1.25" = 0.06; 2" = 0.16; 3" = 0.37; 4" = 0.65; 5" =1.02; 6" =1.47; 12" = 5.88 TUBING INSIDE DIA. CAPACITY (Gal./Ft.): 1/8" = 0.0006; 3/16" = 0.0014; 1/4* = 0.0026; 5/16" =0.004; 3/8" = 0.006; 1/2" = 0.010; 5/8" =0.016 PURGING EQUIPMENT CODES: B = Bailer; SA M PLED B Y (PRINT) / AFFILIATION: David L. Anderson/CDM BP = Bladder Pump; ESP = Electric Submersible Pump; PP = Peristaltic Pump; SAMPLING DATA SAMPLER(S) SIGNATURE(S); SAMPLING INITIATED AT: O = Other (Specify) SAMPLING ENDED AT; PU M P DEPTH IN W ELL (feet): UNK TUBING MATERIAL CODE; NA FIELD-FILTERED: No FILTER SIZE: NA Filtration Equipment Type: NA urn FIELD DECONTAMINATION: PUMP: No TUBING: NA DUPLICATE: No SAMPLE CONTAINER SPECIFICATION SAMPLE ID CODE NA # CONTAINERS 2 MATERIAL CODE PE VOLUME I liter SAMPLE PRESERVATION PRESERVATIVE USED None TOTAL VOL ADDED IN FIELD (mL) None FINAL PH NA INTENDED ANALYSIS AND/OR METHOD PFOA, PFOS, & SAMPLING EQUIPMENT CODE O-Grab SAMPLE PUMP FLOW RATE (mL per minute) <100 mL Fluorinated Cmps by HPLC/MS. REMARKS: N A - N o t Applicable. UNK-Unknown. W as the well pumping (active) prior to sampling - Yes or No. MS/MSD sample collected - Yes or No. Collection Time: Well has fluoride treatment -CYeskir No. Photograph No. / ! o - / 8 (_B a A-c Y\ 2 " ) ^ \( i,'n 4 i-n A r'C S , A* po\*a<tr c A r . ' n y d i'+ ^ 2 . / S' . MATERIAL CODES: A G =Amber Glass; C G = Clear Glass; PE = Polyethylene; PP = Polypropylene; S = Silicone; T =Teflon; O = Other (Specify) SAM PLIN G EQUIPMENT CODES: A PP = After Peristaltic Pump; B = Bailer; B P = Bladder Pump; E S P = Electric Submersible Pump; R FPP = Reverse Flow Peristaltic Pump; SM = Straw Method (Tubing Gravity Drain); O = Other (Grab) wTES: 1. The above do not constitute all of the information required by Chapter 62-160, F.A.C. 2. Stabilization Criteria for range of variation of last three consecutive readings (see F S 2212. section 3) pH: 0.2 units Temperature: + 0.2 C Specific Conductance: + 5% Dissolved Oxygen: all readings < 20% saturation (see Table FS 2200-2); optionally, + 0.2 mg/L or + 10% (whichever is greater) Turbidity: all readings < 20 NTU; optionally + 5 NTU or + 10% (whichever is greater) Revision Date: February 12, 2009 Form FD9000-8 CALIBRATION LOG (FDEP SOP FT 1000-FT 1500, FD 1000-FD 4000) -11 1 * 0 5 ^5Project/Ste:: 3 Pi JB oJl - u s ^ - i l r _________ Date: F * ir . / - 3 , <2c>/o Meter# S 'S 'b ( & / ( ? ' ) Tem perature (Quarterly) F o r D a te o f L a s t T e m p e ra tu re V e rific a tio n s e e in lo o b o o k D .is s o l,,v e d. O_ xy g en D^E P1S5QO0P .in.i.t.ia.ls _D a t.e T im e cPhraorbgee PGr oa jbne CAL CAL CAL CAL ICV ICV ICVCCV^ ICV C C V -3 /o ofcs-o O f OO mg/L Tem p c % DO Saturation mg/L (from chart) Pass or Fail A c c e p ta n c e Criteria:+/-0.3mg/l 7 ?5 CAL ICV C CV C AL ICV C C V CAL ICV C C V CAL ICV C C V pH DEP SOP FT 1100 Initials Date CAL CAL CAL CAL CAL CAL CAL CAL CAL ICV c v l ICV C C V I ICV C C V ICV C C V ICV C C V ICV C C V ICV C C V ICV C C V ICV JIcCgCy J bJJb- M aintenance: W eekly pH Slope: Notes: j; - / -fa Z -l-h * 2 ,-7 '*'= * 2-(-/<=> X -?-*> T im e Standard SU Exp. Date 4 T" /to Lot# e>T :c o /e / Specific Conductance Probe Cleaned? Y e s No P P P P Bottle # Slope Reading SU Pass or Fail A c c e p t a n c e Criteria: +/- 0.2 S U y- M 7 .o g /6./ j.y e ?. at / o .o e Ct> jy .o i L -T ? Cel) Dissolved Oxygen Membrane Changed: Y e s Q ^ Perform only in Calibrate Mode: Perform only in Run Mode: Perform only in Run Mode: C A L - Calibrate ICV - Initial Calibration Verification C C V - Continuing Calibration Verification Page p. 110 p. 111 Date of C alib ration: '/ z 7 A & Field Equipment Calibration Record D evice ( M ake and M odel) C a lib ra tio n S ta n d a rd s Calibrated by: 7P h u . . p h 3TT Loca tio n of Instrum ent Use: + A t t u r f M r& R u J / i 9 . * //3 5 / <u+0> 7 > la o Z . * # * r 0 A F > ? `> <? f o f r c c l m V. Date of Equipm ent Use: 2 .-/-/D 2 -X -/* 2 -3-A& T a ti) A - i - f j t t f t c h " C o ri.) CZCV " ' CCI/ V*lv Soci * > b fc. Camp Dresser & McKee 50 Hampshire St. Cambridge, MA 02140 p. 112 Date o f C alibration: \/Z7/l0 7/ Field Equipment Calibration Record (D e v ic e M a k e a n d M o d el) C alib ration Standards C alibrated by. O ittrQ .. 'T o T/f */fesfc ZO 160 tir /j o Location of Instrum ent Use: F<fZ/J-rd F a trt/t& 'rl Date of Equipm ent Use: C a m p Dresser & McKee 50 Hampshire St. Cambridge, MA 02140 D ate o f C a lib ra tio n : \/Z7/(0 ^ ~ r~ Field Equipment Calibration Record D e v ic e ( M a k e an d M o d e l) C a lib ra tio n S ta n d a rd s H * <n '/an P 0 J #7*0 'T uiK Z t 7>iry l * 2 0 ti r o l S 'a s C a lib ra te d by: L o c a tio n o f In s tru m e n t U se: FTBrtrtft'Z* r i D a te o f E q u ip m e n t U se: p. 113 Dam p Dresser & M cK ee 50 H am pshire St. Cam bridge, M A 0 2 1 4 0 p. 114 O D xipuaddv Baron & Budd, P.C. Emerald Coast Utilities Authority Production Well Sampling Escambia County, Florida Analytical Data/Chain-of-Custodies (Hard Copy and Compact Disk) p. 115 Appendix D A C Columbia C . J Analytical Services" p. 116 www.caslab.com February 22, 2010 Analytical Report for Service Request No: K1000911 David Anderson Camp Dresser & McKee, Incorporated 325 John Knox Road Building M, Suite 100 Tallahassee, FL 32303 RE: Baron & Budd P.C/95779-75319 Dear David: Enclosed are the results of the samples submitted to our laboratory on February 02, 2010. For your reference, these analyses have been assigned our service request number K1000911. Analyses were performed according to our laboratory's NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.caslab.com. All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report. Please call if you have any questions. My extension is 3281. You may also contact me via Email at PDivvela@caslab.com. Respectfully submitted, Columbia Analytical Services, Inc. Pradee, Project Chemist PD/afs Page 1 of 3/ 1) ASTM A2LA CARB CAS Number CFC CFU DEC DEQ DHS DOE DOH EPA ELAP GC GC/MS LUFT M MCL MDL MPN MRL NA NC NCASI ND NIOSH PQL RCRA SIM TPH tr Acronyms p. 117 American Society for Testing and Materials American Association for Laboratory Accreditation California Air Resources Board Chemical Abstract Service registry Number Chlorofluorocarbon Colony-Forming Unit Department of Environmental Conservation Department of Environmental Quality Department of Health Services Department of Ecology Department of Health U. S. Environmental Protection Agency Environmental Laboratory Accreditation Program Gas Chromatography Gas Chromatography/Mass Spectrometry Leaking Underground Fuel Tank Modified Maximum Contaminant Level is the highest permissible concentration of a substance allowed in drinking water as established by the USEPA. Method Detection Limit Most Probable Number Method Reporting Limit Not Applicable Not Calculated National Council of the Paper Industry for Air and Stream Improvement Not Detected National Institute for Occupational Safety and Health Practical Quantitation Limit Resource Conservation and Recovery Act Selected Ion Monitoring Total Petroleum Hydrocarbons Trace level is the concentration of an analyte that is less than the PQL but greater than or equal to the MDL. 2 Inorganic Data Qualifiers # 'Die result is an outlier. See case narrative. # The control limit criteria is not applicable. See case narrative. B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD orNELAC standards. E The result is an estimate amount because the value exceeded the instrument calibration range. J The result is an estimated value that was detected outside the quantitation range. U The analyte was analyzed lor, but was not detected ("Nnn-detect") at or above the MRL/MDL. D O D -Q S M 4 l d e fin itio n : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution, i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference. X bee case narrative. Q See case narrative. One or more quality control criteria was outside the limits. Metals Data Qualifiers # The control limit criteria is not applicable. See case narrative. J The result is an estimated value that was detected outside the quantitation range. E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample. M The duplicate injection precision was not met. N The Matrix Spike sample recovery is not within control limits. See case narrative. S The reported value was determined by the Method of Standard Additions (MSA). \ j The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. D O D -O S M 4 } d e fin itio n : Analyte was not detected and is rqxirted as less than the LOD or as defined by the project. The detection limit is adjusted for dilution. W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance. i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference. X See case narrative. + The correlation coefficient for the MSA is less than 0.995. Q See case narrative. One or more quality control criteria was outside the limits. Organic Data Qualifiers # The result is an outlier. See case narrative. # The control limit criteria is not applicable. Sec case narrative. A A tentatively identified compound, a suspected aldol-condensation product. B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD orNELAC standards. C The analyte was qualitatively continued using GC/MS techniques, pattern recognition, or by comparing to historical data. D The reported result is from a dilution. E The result is an estimate amount because the value exceeded the instrument calibration range. J The result is an estimated value that was detected outside the quantitation range. N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed, p The GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results. y The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. D O D -Q S M 4 1 d e fin itio n : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution. i The MRL/MDL or LOQ/LOD is elevated due to a chromatographic interference. X See case narrative. Q See case narrative. One or more quality control criteria was outside the limits. Additional Petroleum Hydrocarbon Specific Qualifiers F The chromatographic fingerprint of the sample matches the elution pattern of the calibration standard. L The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of lighter molecular weight constituents than the calibration standard. H The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of heavier molecular weight constituents than the calibration standard. O 'file chromatographic fingerprint of the sample resembles an oil, but does not match the calibration standard. Y The chromatographic fingerprint of the sample resembles a petroleum product eluting in approximately the correct carbon range, but the elution pattern does not match the calibration standard. Z The chromatographic fingerprint does not resemble a petroleum product. 3 P- 118 p. 119 Columbia Analytical Services, Inc. Kelso, WA State Certifications, Accreditations, and Licenses Program Alaska DEC UST Arizona DHS Arkansas - DEQ California DHS Colorado DPHE Florida DOH Hawaii DOH Idaho DHW Indiana DOH Louisiana DEQ Louisiana DHH Maine DHS Michigan DEQ Minnesota DOH Montana DPHHS Nevada DEP New Jersey DEP New Mexico ED North Carolina DWQ Oklahoma DEQ Oregon - DHS South Carolina DHEC Utah DOH Washington DOE Wisconsin DNR Wyoming (EPA Region 8) Number UST-040 AZ0339 88-0637 2286 - E87412 - - C-WA-01 3016 LA050010 WA0035 9949 053-999-368 CERT0047 WA35 WA005 - 605 9801 WA200001 61002 COLU C1203 998386840 - ACIL m ig rili 4 Case Narrative p. 121 COLUMBIA ANALYTICAL SERVICES, INC. Client: Project: Date Received: Sample Matrix: Camp Dresser & McKee. Inc. Baron & Rudd, P C 02/02/1() to 02/03/1() Water Service Request No.: K1000911 CASE NARRATIVE All analyses were performed consistent with the quality assurance program of Columbia Analytical Services, Inc. (CAS). This report contains analytical results for samples designated for Tier III validation deliverables including summary forms and all of the associated raw data for each of the analyses. When appropriate to the method, method blank results have been reported with each analytical test. Sample Receipt Nineteen water samples were received for analysis at Columbia Analytical Services between 02/02/10 and 02/03/10. The samples were received in good condition and consistent with the accompanying chain of custody form. The samples were stored in a refrigerator at 4C upon receipt at the laboratory. Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Surrogate Exceptions: The recovery of Perfluoro-n-[ 1,2-13C2]undecanoic Acid in Field Blank 2, Bronson "Raw", W & Avery "Raw", West Well Plant "Treated", F:Scott "Raw", Bronson "Treated" MS. and Bronson "Raw" DMS was outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken. The recovery of Perfluoro-n-[ 1,2,3,4-13C4] butanoic acid, Perfluoro-n-[l,2-13C2]undecanoic Acid and Perfluoro-n[I,2-13C2]dodecanoic Acid in University Parkway "Treated" were outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken. The recovery of Perfluoro-ii-[l,2-13C2]undecaiioic Acid and Perfluoro-n-[l,2-13C2]dodecanoic Acid in McCory "Treated", Lillian "Raw", ", Lillian "Treated", West Pensacola "Raw", West Pensacola "Treated", W & Avery "Treated", West Well Plant "Raw", F:Scott "Treated", and Bronson "Raw" DMS were outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken No other anomalies associated with the analysis of these samples were observed. Approved by Date 6 Chain of Custody Documentation Columbia Analytical Services* 1317 South 13th Ave CHAIN OF CUSTODY Kelso, WA 98626 (360)577-7222 (800)695-7222x07 FAX (360) 636-1068 PAGE SR#: m m CO C# 123 RELINQUISHED BY: Signature Printed Name Date/Time 'Firm -- ------------------------------------------------ ------------------------------------------------------------------------------ V \ "RECEIVED BY: Z-l /0 Stonature a . fiv A L D ate /T im e C ,o fj\ Printed Nam e Firm H \ rsRELINQUISHED BY: Printed Nam e Firm RECEIVED BY: Signature ^n'rited Nam e C -A i Firm RCOC #1 07 0 ` Columbia Analytical Services CHAIN OF CUSTODY 1317 South 13th Ave. Kelso. WA 98626 (360)577-7222 (800)695-7222x07 FAX (360) 636-1068 PROJECT NAME PROJECT NUMBER /Ko X i\ .d ? Z t 'i n (V.KV t dPROJECT MANAGER A v ^ e i l A M i v \ COMPANY-ADDRESS _________ m _____________ rt______ \riX -- T|rx/rv\vA\ \f>\h _ (l A 2 in C/TY'STATE ZIP T a LU W E-MAIL ADDRESS a/V W -- tro SAMPLER'S SIGNATURE S A M P L E I.D. U / a V j c M TrsvL<%J '* X r> o 5/X veL,V Ojs, / ^ K c a j i i f i J*t ciA -f DATE 2.1O 2 -/-/C 2 -/7 0 Z 'U * T IM E IZ 'iS mo 13 S S m is O a a c a, ^ ^ U ^ 11 O 2 --Q Z / .X mu l i o8 L A B I.D. MATRIX 6^ Y KJ Z z a. 6 -UJ 6 -^ 2_ 2~ lU 2 - 6-U 3 ' Z PAGE 'Z , SR#: k ./ O ^ 1 OF -2_ COC # REM ARKS Y X Y _X X - REPO RT REQUIREMENTS ___ 1. Routine Report: Method Blank, Surrogate, as required II. Report Dup., M S, M S D as required III. Data Validation Report (includes all raw data) X IV. C L P Deliverable Report INVOICE INFORMATION P .O .# B ill To: Total Metals: Al A s Sb Ba Be B C a Cd C o C r Cu Fe Pb Mg Mn Mo Ni K Ag Na Se Sr Tl Sn V 2 n Hg Dissolved Metals. Al A s Sb Ba Be B C a Cd Co C r Cu Fe Pb Mg Mn Mo Ni K Ag Na Se Sr Tl Sn V Zn Hg "INDICATE STATE H YD RO CARBO N PR O CED U RE: AK C A Wl NO RTH W EST OTHER: TU RN ARO U N D REQ UIREM ENTS SPECIAL INSTRUCTIONS/COMMENTS: _____ 24 h r . _____ 48 hr. _____ 5 Day Standard (10-15 working days) _____ Provide FAX Results (CIRCLE ONE) X V. EDD RELINQUISHED BY: Signature Printed Name DateTTime Firm Requested Report Date V fv RECEIVED BY: IS W U ./O / 6 i o Signature D ate -T im e n ftL--a L . M -XuaifcA c X fA Printed Nam e Firm \ t \ IV R ELIN Q U ISH E D BY: //fix X.}.f o Printed Nam e Firm -^gTWiifflr.. Signature., JU X , K e nm Printed Nam e l Firm RCOC *1 07 Of Columbia Analytical Services- CHAIN OF CUSTODY 1317 South 13th Ave. Kelso, W A 98626 (360) 577-7222 (800) 695-7222x07 FAX (360) 636-1068 "" " PROJECT NUMBER <=J ^ - H v J ,A ^5"3/T ' 7,^P> C D iL iv v M /v tM /fvOMPROJECT MANAGER ^ avi A VL iVvilVVVXA Ulj?COMPANY/ADDRCSS w A a |A / t-f) C^~i\ I1 /1 VfIfi/ Ci TY/ STATE/ Zl P _______ ~ __e -m ail a o g r ess ., , _J ' A A I sJls^rjp a trrLr 7 PHONE' SAMPLER'S SIGNATURE" FAX # ^ ^ 1-2 S^ _ 1 of i / J7 oAt// fj// S A M P L E l.D. DATE T IM E / ^ 7/ /,LA B l.D. MATRIX f 14 - W O n^ 2- AJo T ~ fT fi lr A*0 " 2 ..2 -/0 ^ v a . 27 PAGE SR#: Y ()i\() u/ / / OF 3 COC # REM ARKS X REPO RT REQUIREMENTS ___ 1. Routine Report: Method Blank, Surrogate, as required ___ II. Report Dup., MS, M S D as required ___ III. Data Validation Report (includes all raw data) IV. C L P D eliverable Report ^ V. EDD INVOICE INFORMATION P.O . # _____________________ B ill To: Circle which metals are to be analyzed: Total Metals: A l A s S b B a B e B C a C d C o C r C u Fe P b Mg M n M o Ni K A g N a S e Sr T l S n V Zn Hg Dissolved Metals: A l A s S b B a B e B C a C d C o C r C u F e P b M g M n M o Ni K A g N a S e S r T l S n V Zn Ftg INDICATE STATE H YD R O C A R B O N PR O C E D U R E : A K CA Wl N O RTH W EST OTHER:. TU RN ARO U N D REQ UIREM EN TS SPECIAL INSTRUCTIONS/COMMENTS: _____ 24 hr. _____ 48 hr. . (CIRCLE ONE) _____ 5 Day Standard (10-15 working days) Provide FAX Results C o n ta in e r S u p p ly N u m b er 16394 Requested Report Date 16394 RELINQUISHED BY: Signature Printed Name D ate /T im e Firm \ RECEIVED BY: |j Signature n Printed Nam e D ate/T im e c* ^ Firm ^ \ RELINQUISHED BY: Signature , 0 A v-'-J A tA J e c A Printed Nam e D ate/T im e C j O lA\ Firm RECEIVED BY: S ig n ature Printed Name "Firm /o zc RCOC 1 07 125