Document Rape1o95O9LNpmb9jkVd940j7

AR 286 -- 0218 STUDY SUMMARY OF ENVIRONMENTAL EFFECTS OF LIGHT WATER BRAND AFFF AND COMPONENTS - 1991 TEST SUBSTANCE Identity: ArefmeirxrteudretocaonstPaiFnOiSng, pFeCr-f9l5u,oroorocatsanaescuolmfponoanteen,twhoficFhC-m2a0y6CaEl.so b(1e- Octanesulfonic acid) (CAS # 2795-39-3). RiseFmCa-rk2s0:6C_E T(2h/e163/8M9)p.roCduurcrteinotnilnotfonrummatbieorn winadsicnaottesnoitteisd.a mTihxetutreestosfam0p.l92e% PSuFlOtSo,ne1f5o%amdeire,th1y.l5e5n%e gsloydcoilumbuotcytlyletshuelrf,at7e6,.10.90%5%waptoerl,yo4xy%etuhryela,en1e.28% monooctylphenyl ether, 0.06% sodium lauryl sulfate, and 0.05% tolytriazole. The following summary applies to a mixturwe ith incompletely characterized concentrationsofimpurities. Data may not accurately reflect toxicityofthe fluorochemical component of the test sample. RESULTS Degradability [Study ---- [Vale(sourcey~~ 7] [BODs ____ [aegrem Bob [eowmow | BOD,/COD ratio [2m | Total Organic Carbon (TOC) [130g GM) | OECD Method 301E 89-02% biodegradability in 14 days (3M) 001520 Aquatic toxicity [Swdy -- Vaws@owe) | Cosmi loon c,| OECD Activated Sludge Respiration Inhibition Test 209 48-hrStatic LCs| >1000 mg/L (3M) Microtox (Photobacterium phosp1h5omrienumE)Cs[4500m5g | Riliish (FundulusG6h-ehtrerCoocnittiunsu)ous Flow LCs[r( 52--00-0m_af___| ------------ (Fathead Minnow (Pimephales promefas) | | 96-hr Continuous Flow LCs| >2000 mg/L (3M) 96-hrStatic LCs| >1000 mg/L (3M) * Any study marked with "3M" as the source includes studies done at the request of 3M by labs other than the 3M Environmental Lab. DATA QUALITY Reliability: These studies have been assigned Klimish rankings = 4. Values are from a summary list only. OTHER. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 Last changed: 6/28/00 -- 001821 > . . rTeemcehrngical Report>Summary am To: Patorit & Technical Communications Services -- 201-2C-12 : potSummarymustSo ypewrton.Guldelinsar anrevs ide.ort prinatnBeld sidesofpaper, en tw copies 04 TGS, r-- -- or Ere onmentalEnginserios & Rallusion Conia Ee o4-m1-e91 n EE Lor lose | geen cchand Development "En onmen [Keywords e " of LIGHT WATER Brand AFFF and Component: |UGHT WATER, aqueous foam, FC-203, FC-206, ethylene glycol, butyl Carbitol, sodium lauryisulfate, Duponol, sodium |dodecylsulfate, sodium octylsulfate, L-4640, triethanolamine, urea, Triton X-305,foamer, filmer, surfactant, tolyltriazole, environmental effects, toxicity, Daphnia toxicity, Microtox, algal toxicity, fish toxicity, degradability, biochemical oxygen |demand, BOD, chemical oxygen demand, COD. FretSoot Raper AS - |1.coTmopaodndenttos tuhseekdnionwtlheedpgrebodauscetso.f2.eTnvoiirdoennmteinytatolxeifcfcecotmspoofnLeInGtsHTanWdAtToEcoRrrberlaanted caoqmupeoonuesnftilamfnodrmpriondgufcotatmoxsicaintides.the This technical report includes a summary of environmental effects data on 3M's products and the components used in them. The data was taken from the literature and from previous studies by the 3M Environmental Laboratory. The data [for each component and each product have been evaluatedforcompleteness and accuracy and additional testing requirements have been noted. Where sufficient data on the toxicity and degradabiliotfy individual components were available, the data were evaluated and recommendations regarding inclusion of the component in future products have , - been made. |Anattemptwas made to correlate the toxicity of FC-203 to the toxicity of its components by takinginto'consideration the component concentration in the product. While product toxicity could not be conclusively correlated to the toxicity and concentration of individualcomponents, major contributors to product toxicity are believed to be the filmer, the foamer, butyl CarbitolTM, and DuponolTM ME (sodium laurylsulfate). Components likely to contribute less to product toxicity are ethylene glycol, tolyttriazole, sodium octylsulfate, and Di-water. Further toxicity testing of components and product formulations should enable better correlation between component and product toxicities. [RpoRT3 |etesonkAatarance LLL 5 PRiRoOmpaan sasndOaovirpmahnt 00 WMaannustgaacmvainnSgommary . @3 TFAAPCtoyoErxpFeraimeRnetport O3 ERNOcRianceootrngot vention Co GToewo. Spreovjeent a omen .- [| ienmeoctn bros [FimCode [NuomfbPaegess| 001822 or . Contents 1 PUIPOSE covessrsesssssssssssssssssssssssssssssssssssssssssssssssosissoses 2. LE Sr 1 GONOTR] COMMIS vce 4 IV. CORCIUSIONS &Nd RECOMMENTEHIONS rss 8 V. ENVIronmental Effects LIOAIUTS SSAC .....c.wiwerreerressssmmssssss. 1. Ethy1one GIYCO! (RM 8017)... 10 72. Butyl Carbo (RM 8887) ..vveveserrsresssssrssssssiessssessssssssssssesmesersomermesnnss 12 "3. Duponol (RM 3021); Duponol ME Dry Surfactant (Sodium Lauryl Sulfate) ...... 14 4. Tolyltriazole (RM 27513; CorrosionInhibitor Tolyltriazole Technical Grade) .... 16 5. FOAMET (FVM-A115) ssn 18 6. FIlMer (FM-3820 OF FC-95) verve 18 7. Naoctylsulfate (RM 32067 OF RM 55040) creer 19 8 DHWAST (AD 199) costs: 20 9. FC-203 ws. 21 10. VW160380 (FC-203without Tolylriazole AM 27513) ics 23 % 1. FC203CE connie fon. 28 : 12. FC-R0BCE worn. 25 ' 13. FC-2030F ov 28 14. FC20BOF ovis mss 28 16. L-4640 (NOW FORO) creer 26 16. WHCOIt 7093 (RM 45666)... rrr 27 7. THONGNOIAMING crs. 27 1B.UIBR oss. 20 19. THON X305 snr: 30 1. ` 001823  Environmental Effects of LIGHT WATERTM Aqueous Film Forming Foam and Components 1. Purpose The purpose of this study is to increase LIGHT WATERTM aqueous film forming 3M's foam knowledge of the and the individual environmental effects components used to of make the product. And, by understanding these effects, to minimize them through formulation changes. Ii.Background This study was undertaken in response to testing done by the Grman Army which was reported in "Investigations Agents in Wastewater" by of Toxic Effects Ekkehard Ising. and The Biological Degradabilty of Foam Extinguishing report, hereafter referred to as the "German Amy Report', included data for 16 fire fighting materials,ofwhich two were 3M's FC-203 and FC-206. The 16 fire extinguishing agents were categorized as: 5 multi-range foam agents 6 film-forming foam agents - 3protein foam agents 1 film-forming fluorine-protein foam agent 1 special foam agent for deep-try pan fires Environmental effects considered in the German Army Report were: 1. Acute toxicity to the marine photoluminescent bacterium Photobacterium Pphosphoreum using the Microtox system. The toxicity was expressedas EC.,, and ECq,, have bheoewenv1e0r,,2t0h,eoerx3p0osmuirneutteism.eTiswonotmucllteia-rrfanrgoemftoheamGeagremnatns AwrermeycRoenpsoirdteraendd may >5 "highly toxic". Three multi-range foam agents and 2 film forming agents were found to be "toxic". Four film-forming, all 3 protein, the film-forming fluorine-protein agent, and the deep-fry agent were considered to have "low toxicity". FC-203 and FC-206 were in the "low toxicity" category. - 2. oArlggaaneicsemllwmiutlhtiapnliecaxtpioosnuirnehitbiitmieonofte7s2t uhsoiunrsg.STcoexinceidtyeswmaussesxupbrsepsisceadtuassaEsCth1e, atnesdt "EtCoyx,i.c"Altlofaolgaame.agTehnetstwwiothprtohteeienxfcoepatmioangeonfttswohaodf twheeakprtootxeiicnitfyotaomalaggaeen.tsBowtehr3eM products were considered "toxic" to algae. 3. eAxcpurteestsoexidciatsy tLoC,D,apahnndiLaCm4a,gbnuat tahfteeerfefxecptoscruirteerfioorn 2w4ashotuhres.orTghaenitsoxmisc'itlyowssasof ability to swim and will be referred 10 as EC ,, and EC, in this report. All 5 muti-range foam agents, all fim-forming agents except FC-206, and the deep-fry agent were "toxic" to 2. 001EZ4 a fDialpmh-nfioar.miOngnfelufoirlimn-ef-oprrmoitneginaaggeenntt(FhCa-d20"6l)o,w talolxitchirtey"etporoDtaepihnnaigae.ntFsC,-2a0n3d:t"hteoxic; FC-206: "low toxicity". ~~4. cArciutetreiatwoaxiscitdyetaothZeabnrdaftihseh t(oBxricaicthyywdaasnieoxrperrieos)saefdtearsexLpCos,uarnedfoLrCy4,8.hOonulrys.twTohe fmiullmt-if-orramnignegfaogaemntasgweentrsew"eborred"etrolxiince"ttooxificsihw.eTahkrlyeetomxiucl"t.-"rWaenagkelfyotaomxiac"gewnetrsea4nd two faiglemn-tfoarnmidngthaegfeinltms-,fo2rmpirnogtefilnuofroianem-pargoetnetisn,aagnendttwheerdeee"pn-ofnr-ytoaxgiec"n.t.FOC-n2e0f3ilamn-dforming FC-206 were in the "weakly toxic" category. -- 6. oCfhaem3i%caslolOuxtiyognoefntDheemtaesntdma(tCeOrDia)lainn dwa5t-edra.yTBhieocrahteimoiocfalBOODxy4gteonCDOeDmawnads(uBsOedD a5)s bairoacthienmgigcuaildedleignrea,dwaittihona".BOTDwo/CmuOlDti-rraatnigoeofag0e.5ntosralnesdsocnoensfiidlemr-feodrm"iinnsgufafgiecinetnt (FC-206) were `was 0.35. One considered multi-range iangseufnfticainendtloyndeefgirlamdfeodrmbiinogchaegmeincatl(lFy.C-T2h0e3)rawteiorafor FC-206 `rceomnasiindienrgedag"pernotbsawbleyreinaslulffsiucfifeincti"enbtewcitahustheetihreiBrOBDOCDO/CDODratriaotsiorsanwgeirneg 0f.r5o5m. 0T.h6e09to 0.89. `bTehleodwa.tTahferdoamttaheforGtehremaMincrAortomxy, RZeebproarftisfhor, tChOeDt,woan3dMBpOroDducttesstasreseseummmtaorbieze"dreianstohneabtlaeb"le daantda"fsrelofm-cpornesviistoeunst"3.MThsteuddiaetsaaanrde caornesciodnesriedderreeadssoenlafb-cloensbiesctaenutsebetchaeuysaegrtehee FfaCi-rl2y0w6eldlawtiath are roughly half that of FC-203. - i. > Summary of German Army Report Data : Motor ose ECw ECw ECW EC Dap Low LC Zotar Low LG 800,000 Rao "6Lo2wToc2t5y0 1"69Tose 160 316"Tose:4% | 1W0o88aky T1or8e4" | ro0b5a2sty 200 500 | "Low Tosty tes 10 | "Tot: soows Toszeay|[W2o0akyTeacneesr||24--s Not:al concentratinimogns. 03s suticiont -3- 001825 FAromryt'hse aallggaaletdoaxitcaitsyhdoatwa,estshenetriaalrlye etqwuoiviamlpeonrttatnoxticpiotiynftosrtooucrotnswiodeprr.odFuicrstts,.tOheneGewromuladnexpect tmeosrtse. tHooxiwceivtyerfo,rhFiCg-h2er03totxihcaintyfobryFFCC--22006,3 tahsasnhboywnFCi-n2t0h6e mMiacyrontootx,aZweabyrasfibseh,traune.dFDoarphnia tehxeampphloet,ostyhnetrheetmiacyprboeceassc.omSpeocnonedn,t owuhricPhEiDs pfaorrtFicCu-la2r0l3y tionxdiiccattoeaslngaoe,efpfeecrthtaoptswdoisarlugpatling `tshpeesciaemseatacsotncheonstsriantitohnesGueprtmoa1n,A00r0mymgR/eLp.orWth,iltehetyheatrweoallalfgraelshswpaetceiresspoencitehse PED are and such not a lthaartgeitddiaftfeesrefnrcoemin1t9o7xi4ciatnydwoitulhdans'tbebeeneixpmepcotseds.ibOltneoeviemripfoyrttahnetelxiamcittatfioornmuwliatthitohneofPEthDe data is `sample used in those tests. FFoCr-2th0e3 Dvaapluhensiasedaetmasilnatrhgee GwehremnacnonAsrimdeyriRnegpotrhte, wtahteedricfofenrteenncteobfetthweetewnotfhoermFuCl-a2ti0o6nsa.nAdlso, there PED is a has considerable a 48-hr static differance between Daphnia magna LC the PED data and the German Army data. Our , of 1,600 mg/L, while the German Army Report fhoarsmuala2t4i-ohnr osftatthiec tDeaspthsnaimapmleagcnananEotCb,eivser4i3f0iedm.g/TLh.erTeheisPaEmDajdoartadiifsfqeurietneceolbdet(w19e7e3n)tahned the dPeEaDthdtaota5a0n%dotfhteheGeDrampahnniAartmesytdpaotpaulianttihoant (tLhCe Ps,)EaDnddatthaeisGethremcaonncAernmtryavtaiolnuewhisitchhecauses `concentration Concentration which causes = ECs). The 50% of the test population to German Army value is in fair stop swimming agreement with (Effective recent result*s which show a 48-hr static Daphnia magna EC, of 229 mg/L. Oannde ptrheicnigstihoantosfhtoouxlicditbyeteksetpst ciannmvianrdywchoensnidceornasbildyerfirnogmtlhaebtoorxaitcoitryy dtaotlaabisortahtaotryreaprnodduocviebirlity t`immoer.e Hliokweelyvedru,e tthoechdiafnfgeeresncinesfobremtuwlaeteinonthreatohledrdtahtaan(cchiracnag1e9s74in)taenstdptrhoetomcoolreofrteecsetntspdeactiaesi.s Atany rate, our primary interest should be be concerned with having current, reliable the toxicity data on our of our current PEDs. products and We'should ; Il. General Comments _ The following general statements summarize the factors guiding this study. 1. Tfhoermpurliamtairoynspuarnpdosinegroefdtiheentesnvainrdonnmoetnitnatleenfdfeedctfsordsautbamisisfsoiroinntteorngaolvuesmemeinnteavlaluating regulatory authorities. non-GLP methods. An Therefore, exception any may tbeestdinagtashfoorultdhebneedwonfeoaumseirng(Llo-w4-6c4o0s)t,which may need to be submittedforthe European PMN currently underway. 1 DErnavftirRoeSpyosrttefmrsotmoErnevpieraotStyhseteDmasphLnaibaortaetsotsryfodraFtCed-2M0a3rcahnd10V,W11969013,9W0e. have asked The preliminary results from EnviroSystems on the rest of the samples were acceptable. 4 001826  2. TAhremGyeirsmparneseAnrtmlyy upseirnfgortmhse eitvsaoluwantitoenstsicngheamnde nuoseadutihnortihteyroetphoerrt tchitaendtahbeovGee.rman Taphpelriecfaobrlse, otnhleyretoisthneoGneeremdatno cAhromoyseteastlsacbohreamteor.y,Intsetsetapdr,otteosctolm,eotrhtoedsst sapnedcisepsecies "= should be chosen sothattest results can be used in as many countries as possible. 3. Wfhreormethpeoslsiitbelrea,tudreatoar ofnrotmheraewnvmiartoenrmiaelntsaulppelfifeercstsinoforcdoemrptoonreendtusceshtoeusltidnbgecoosbttsaiannedd time. 4. TrheelaNtiavteiotonxailciItnysotiftuttheeocfoOmcpcounpaetnitosnaalndSatfheetyfoarnmdulHaetailotnhs w(iNllIbOeSHu)setderinmtihneolofogry the - dReipsocruts,sitohneoyfatroexigceneeffreacltlsy. aWchcielpettehdesinettheermUsS.weTrheentooxtiucisteydanindtchoerGreesrpmoandniAngrmtyerms are: Concentration Acutely Toxic to Test Population co NIOSH Terminology <1 mol "Highly Toxic" 1-10 mgiL "Moderately Toxic" 10-100 mg/L "Slightly Toxic* 100 1,000 mg/L. "Practically Non-Toxic" 1,000 mg/L Insignificant Toxicity" 5. - The LIGHT WATER AFFF formulations and : components considered are: a 21.. EButthyylleCnaerbGiltyoclol((RRMM83808177)) 3. Duponol ME (RM3021) 4. Tolyltriazole (RM 27513) 5. Foamer (FM-4115) 2 6.Filmer (FM-3820 = FC-95) 7. 8. Na-octylsulfate (RM Dl-water (RD 199) 32067 or RM 55040) 9. FC-203 10. 11. VW160390 FC-203CE (FC-203 (same as without Tolyitriazole FC-203C) RM 27513) 12. FC-206CE 13. FC-203CF 14. FC-206CF >. : - -5- 001827 w 15.L-4640 16. Witcolate 7093 (RM 45666) 17. Triethanolamine 18. Urea "= 19.Triton X-305 1i0te1m3sw1etroe1g0ivaernetfortohmeaaulstthogrivbeynWtoimEriVcanRneiensetreb2y/5W/9i1m. Vhaenmnses1t4e103/1162/w9e0.retgeimvsen11 to the author by Roger Alm (2/4/91). IV. Conclusions and Recommendations `Incoomrpdoenretnotccorornecleantteratthieotnoxiisctiatykeofntihnteopcroondsuicdtertaotitohne.toIxnitcihteytoafbilnsdbiveildouwa,l tchoemptooxniecinttyst,o the Desatpihmnaitaedoftotxhieciptiuersebcaosmepdononenptrsodaurcetgfiovremnuliantitohne.thTihridsciosltuhment.oxTihcietyfiwfthhiccohlwuomunlcdobnteaeixnspected "when the example, component s diluted inwater one would expect that since to the the same toxicity of concentration as in pure butyl Carbitol the is product, For about 700 mg/L, the toxicity ofa about 2,000. solution made of 35% butyl Carbitol and 65%water would have a toxicity of `Some interesting observations can be made tolyitriazoleisquite toxic, it is present at low from these numbers. First, even concentration in the product and though when diluted in the product it analysis does probably does not exonerate ntooltylctornitarziobluetaessaubmstaajnotriaclolnytrtiobpurtoodrutcotptrooxdicuictty.toHxoicwietvy.erS,ectohinsd, the lowest numbers in the contributors to product ftifothxiccol:ubmuny!inCdaircbaitteoclo,mpDounpeonntolswhMiEch(dwioldlecbyelstuhlefamtoes),t likely the foamer, and. tthhee ffiifltmhecf.olUunfmonrtwuhniactheliys,stuhbesrteanitsianloltyaloswinegrltehcaonmapllotnheentreswth.iTchhisstmaandysmoeuat nwitthhatatnhuemrebeisrain 3 `synergistic effect between components. ! -6- 001828 4 _-- feni. Name re _T-- aCeatia -_o -- e T_o-- ars -_-- Em. Elon 7 aoyden Summary of Recent Daphnia Toxicity Data SEUII) Sto Toe 2z1a.1000 203-29) Fomofomutin ma aso 10% compe, Fr) zon 200 Tonz-2 ECED =) asc 7 ae oO OE To asst 5170-100) 20% =) Mego Probattmoyt Protty Proatty promi OOPrOatOl Pratl Pratott r-- e rF-- TTee-- ese-- Setos------ ra ---- ese ----No-- --o__fgom_mm_ee_ms_=2w201e o50 m4sn) x x x crr e m meee an d`Tahteaiimspno~eretdaentd,coenscpleucsiialolnyffroormaltghaees.eTDhaephtanbilaerbeesullotws sisutmhamtaar"maiozrteehsecoamdpdliettioenasledo|atftatonxieceidtyed > ; to complete the Additional tests aerneviirnodnimceantetdalwietfhfeacntsXd.atabase on our products and their ingredients. 2 Preliminary results from EnviroSystems, March 10, 1881. 7. 001879 4 F _--: mm M-- oc w`Summartyieof Aidditiiotne ael mTesting . Mw m ow wn _S Pa eRseyms x. x A m par ogre PE-- r PE Sf -- E mFpe nms PE x x x ` x> TeEifeoerom PE-- eeeegret Sre ea Brsaea eee erm eee Sx eN -- e IiEE S, x x xx Ja EERrSa. FE-- x : o2e w S m moa m e mer T w To e xT w xTx e Tx Tw x ex mrx a w } 0 eeoe xowx m wWer y Cr ewe 0Fv ] Cx. oxor ea weeo=ewwss x eT Tx e TeT x e T x TTTx Te TTx . [ST -------- : Ls. 001E350 2 V. Environmental Effects Literature Search Data from previous `summarized in this 3M Environmental Laboratory section. Toxicity data noted by Studies and from the [iterature *AQUIRE" were obtained from are asearch of tdhaetUaSfrEoPmAAQAUQIURIEREardeatthaebdaasteeoonf Fpeubbl.ic1a2t,i1on99o1f.thIencolruidgiendalasjopuarrntalofartthieclreeafnerdetnhcee rfoervitehwe `code established by a group the literature by the following of EPA scale: reviewers. The reviewers have ranked toxicity data from 1. Meets all review criteria. 2. Procedures generally satisfactory. __ 3. Insufficient in some areaof the test methodology or test report. 4. Abstract or foreign paper with data in limited format, TbheceacuosmepltehetedactoantbeanstesionfctluhdeeAsQmUaInRyEodbastcaurbeassepefcorieesacofh lcithtelemiinctaelreisstn(ootpgoisvseunminsthhriismpre,port iIsndcioannsicadtefrieshd,bsyntahkeehEePaAd rcaetvfiieswh,erosysttoebrse,ocflqaumess,tisopnoanbgleesvaalnude,many others) and data which Additional degradabilty Environmental Data on and toxicity data have Organic Chemicals by been Karel taken from the Handbook of Verschueren (Nostrand Reinhold, New Ytohreko,ri1g9i8n3al).reTfheersenecea.reThreefreeraernecemdabnyypcaagseesnuinmbwehricihn tthhee sHaamnedbdoaotka faoplpleoawrededbyonthAeQdUaIteREof and in Verschueren but only the AQUIRE quality rating of the original reference. reference is given because it includes the EPA `Rcaonwtamcatteedriaanldsaupspkleiderfsorwearney identified from environmental tdhaeta3tMhePyRhIaSveM.dUantfaobratusneataenldy,suepnpvliireornsmweentrael data was not generally available from raw material suppliers. And, the suppliers were slow in `sending the limited data do have. 1 Tenhveirsoonumrecnetaalndasresleiasbsilmietyntofotfhtehleitceormatpuorenednattaswaansd tthaekernecinotmomceonndsiadteiroantsiofnorinfutrhteher testing. 3 BIenfpoornmtatFioornmafotr:each component or formulation is organized as folloiw: s: - CFhoremmuilcaatlioAnbosrtrcacotmspoSnerevnitcen(aCmAeS)anNdumRbMernumber Vendors ADqeugartaidcaTboixticyidtyatdaatfarofmrotmhethleitleirtaetruarteuorre forrofmropmrepvrieovuisou3sM3aMssaessssemsesnmtes.nts Environmental Assessment Recommendations for Additional Testing "e- 001831 oF Detailed information list above. for components and formulations are given in the same order as in the 1. Ethylene Glycol (RM 3017) CAS #107-21-1 `Vendors: CUhneimotnecCha,rbAisdhe,laTnedxtCilheemCihceamli,caDlo,wAsChhleamnidcaClh,eTmiecxaalc,oUCnhoecmailcal, Olin, Shell Oil, "Degradability: `Theoretical Oxygen Demand (ThOD) BOD; BOD, . BOD, BOD,, co-p BOD,/COD Ratio BOD,/COD Ratio 1.29 g/g (Verschueren p 646) 0.443f0r.o2m2Vge/rgs(cahvugeroefn12p c6i4t6at)ions. 0.52 g/g (Env. Lab. Req. #1940) 0.67 1.19 g/g g/g (Verschueren p (Env. Lab. Req. 646; 1953) #1940) 0.92 g/g (Verschueren p 646; 1953) 1.14 g/g (Env. Lab. Req. #1940) 1.0040.08 g/g (avg of3 citations from Verschueren p 646) 1.02 g/g (Env. Lab. Req. #1940) 1.2410.04 g/g (avg of 3 citations 1.28frgo/mg V(eErnvs.chLuaebreRneqp.6#4169)40) 0.4 (Env. Lab Req. #1940) 0.8 (Env. Lab Req. #1940) Toxicity:* Gree7n-AdlagyaSeta(tSiccePnopeudle.sGmruoswqtuhadInrhiicba.uda) 8-day static Popul. Growth Inhib. : 10,000 mg/L (AQUIRE 2; 1980) 10,000 mg/L (AQUIRE 2; 1978) >; - 33M Environmental Labwork done in Dec. 1973. 4 The toxicity data are a partial listing of 38 tests on 16 species from the EPA AQUIRE Pdoaptualbaatsieo.n Growth Inhibition: Change in cell number of algal species including pre-exponential lag rate effects. -10- 001832 Protozoa (Entosiphon sulcatum) 72-hr Static Popul. Growth Inhib. 10,000 mg/L (AQUIRE 2; 1980) ._ Blue-green Algas (Anacystis aeruginosa) 8-day Static Popul. Growth Inhib. 2,000 mg/L. (AQUIRE 2; 1978) Bacteria (Pseudomonas putida) >10,000 mg/L (Verschueren p 647) gas (Microcystis aeruginosa) 2,000 mg/L (Verschueren p 647) Protozoa (Uronema parduczi) 10,000 mg/L (Verschueren p 647) Water flea (Daphnia magna) 48-hr 24-hr Static Static EC LC, 1,000 10,000 mg/L mg/L ((EAnQvUiIrRoSEy2s;te1m9s771)991) i= 24-hr Static LCq 48-hr Static LCq 10,000 10,000 mg/L mg/L (AQUIRE (AQUIRE 3; 3; 1983) 1983) Brine shrimp (Artemia salina) - 24-hr Static LC4 24-hr Static LCq 20,000 20,000 mg/L mg/L (AQUIRE (AQUIRE 2; 3; 1974) 1983) Fathe24a-dhMriSntantoiwc L(CPi,mephales promelas) + 10,000 mg/L (AQUIRE 3; 1983) 48-hr 96-hr Static Static LC, LC4, 10,000 10,000 mg/L mg/L (AQUIRE (AQUIRE 3; 3; 1983) 1983) . 96-hr Static LC, 49,000 mg/L, 53,000 mglL, & Bluegill Sunfish (Lepomis macrochirus) 57,000 mg/L (AQUIRE 2; 1983) 96-hr Static LC, 10,000 mg/L (AQUIRE 2; 1968) Rain9b6o-whrTrSotauttic(SLaClsmo gairdnen) 41,000 mg/L. (AQUIRE 2; 1980) - > . Common Shrimp (Crangon 48-hr Renewal LC, crangon) 100,000 mg/L. (AQUIRE 2; 1974) ; 96-hr Renewal LCs - 50,000 mg/L (AQUIRE 2; 1974) Goldfish (Carassius auratus) 96-hr Static LCqo . 5,000 mg/L (AQUIRE 2; 1879) - Guppy (Poecilia reticulata) 7-day Renewal LCy, 49,300 mg/L (AQUIRE 3; 1981) 6 Acute 1991. Daphnid toxicity testing done by EnviroSystems for 3M. Test results dated March 10, 1- 0041523 A EnEvtihyrloennmeegnltyacollAshsaessisnsmiegnnitf;icant present in high concentration in toxicity and the product, a it high BOD/COD probably does n rat ot io. Even though contribute substa itis ntially to product toxicity. BNonee.commefnordAddaititonail Toestninsg: 2. Butyl Carbitol (RM 8887) CAS# 112-34-5 (Diethylene Glycol Monobutyl Ether) "GlyScolyEtnhaernodDBven(nOdxyoyrcshm:eBmu)st,y!BDuitoyxlitCoalrb(iCtaoilnC(hUenmiiocnalC)a,rbPiodlye-CSoorlpvoDraBti(oOnli-n LCionrdpaorDaitvi.)o,n), Butyl Dioxitol (Shell Chemical Products, Gil Company), Inc.) Dowanol DB (Dow Chemical), Ektasolve-DB (Eastman ThOD BOD, N BOD, BOD, BOD, cop BOD,/COD Ratio BOD,/COD Ratio - Toxiity? Eh Bacteria (Pseudomonasputida) 2.17 g/g (calculated) 0.25 (Verschueren p 524) 0.69 g/g (Env. Lab." Req. #1940) 1.45 g/g (Env. Lab. Req. #1940) 1.61 g/g (Env. Lab. Req. #1940) 1.66 9/g (Env. Lab. Req. #1940) 2.08 1.83 (Verschuerenp 524) g/g (Env. Lab. Req. #1940)" 0.12 (Verschueren p 524) 0.37 (Env. Lab. Req, #1940) 0.85 (Env. Lab. Req. #1940) 255 mg/L (Verschueren p 524) >. Tok - 7 8 3M Environmental Lab The toxicity data are a work done in partial listing Dec. of 15 1973. tests on 10 species from the EPA AQUIRE database. 124 . 001824 3 Green Algae (Scenedesmus quadlicauda) 78--ddaayy SSttaattiicc PPooppuull..GGrroowwtthhIInnhhiibb.. 1,000 mg/L (AQUIRE 2; 1980) 1,000 mg/L (AQUIRE 2 1978) "7Blue-8g-rdeaeynSAtlatgiaceP(oApnualc.yGstrioswatehruInghiinbo.s~a)~ 53 mg/L (AQUIRE 2; 1978) Protozoa (Entosiphon sulcatum) 72-hr Static Popul. Growth Inhib. ~~ 73 mg/L (AQUIRE 2; 1880) Protozoa (Uronema parduczi) 420 mg/L (Verschueren p 524) Protozoa (Chilomonas paramecium) - 48-hr Popul. Growth Inhib. 2,774 mg/L (AQUIRE 4; 1960) Water Flea (Daphnia magna) 48-hr Static EC, 706 mg/L (EnviroSystems 1991) 24-hr Static LCq, 2,850 mg/L (AQUIRE 2; 1977) Bluegill Sunfish (Lepomis macrochirus) 96-hr Static LCq 1,300 mg/L (AQUIRE 2; 1977) Goldfish (Carassius auratus) 24-hr Static LCy 2,700 mg/L (AQUIRE 2; 1979) Guppy (Poecilia reticulata) : 7-day Renewal LCs 1,150 mg/L (AQUIRE 3; 1981) SilveSrtiadteic(LLeCusc,iscus dus) 1,805 mg/L and 2,304 mg/L. (AQUIRE 3; 1978) Inland Siverside (Menidia berylling) ~ 96-hr Static LCs, 2,000 mg/L (AQUIRE 2; 1977), _ Environmental Assessment; BOD data shows fairly high degradabilty. The literature data show this material to have = iAnQsiUgIniRfEicaanrtetcoxoincsiitsytteontfiashndanidnDdiacpahtenithaa.tTbuhteyltwCoarfbrietshowlaitseprrgacrteiecnalalylngoan-vtaolxuiecsofrgormeen gahlagvaee.aTshaemrpeleis" ocfonbsutiydleCraarbblmiytmololretemtsotxeidciftyorsahlogawlnttoxoicbiltuyet-ogrbeeensuarlegaoef,fhsotwoexviecre.ffWecets.should Algae and Microtox. S18 .. 004825 3. Duponol ME Dry Surfactant (RM 3021; Sodium Lauryl Sulfate) CAS# 151-21-3 (Sodium Dodecylsulfate CHy(CH,),,0SO;Na) Vendor; Dupont" ThOD BOD - Toxicity" GreeSntaAtligcaPeop(uClh.loGrerlolwatshp)Inhib. 4 *. Gree7n2+AhlrgaSsta(tiCchlGorreolwltahvuIlnghairbisi)tion Gree7n-AdlagyaSsta(tSiccePnopeudle.sGmruoswtquhadInrhiicba.uda) 8-day Renewal Growth Inhibition Flage7l2la-ther ESutgatliecnPooipdul(.EnGtrooswitphhoInnhsiubl.catum) Blue-8g-rdeaeynRAelngeawea(lAnPaocpyuslt.iGsraoewrtuhgiInnohsiab.) BacteCreilal (MuPlsteipuldiocamtoinonasInphuibtiitdiao)n Protozoa (Uronema parducz) - Call Multiplication Inhibition 2.03 g/g (calculated) aSlwkiyslhseurl'fatreesphoratvsetlhaotng"lbieneeanr primary prreicmoagrnyizbeidodaesgreaxdtarteimoenl,yorfatpeind in cdiitseasppaepaprrionxgimiantleelsys 1t0h0anreafdeareyn"caensd w1h0i0c%h wsihtohiwndaegfreawdahtoiuorns roartdeasyosf.80 to 50 mg/L (AQUIRE 4; 1980) 0.05 mg/L (AQUIRE 4) 0.02 0.02 mg/L mg/L (AQUIRE (AQUIRE 2; 2; 1980) 1978) 40mg/L (AQUIRE2;) 5z, > 5 7 mg/L (AQUIRE 2; 1978) - 290 mg/L (Verschueren p 793; 1980) 0.75 mg/L (Verschueren p 763; 1980) 8 Phone: 302-774-1000. 2/15/91:will send information. 108S0w7i-s8h1e1r., R. D.SurfactantBiodeg2nrdead.dMaracetlDeikkoern ;Ne,w York, 1987, P 466, 11ATQhUeItRoxEicdiatytadbaatsaea.re a partial listing of the 409 tests on 49 species from in the EPA 12 Growth Inhibition: Measurable change in length and/or weight. S14 : 0C1Si6 4 Water flea (Daphnia magna) 48-hr Static EC, 24-hr Static LCy 23.39.0mmgg//LL(E(nAvQiUrIoRSyEst2;em1s97179)91) TT 24-hr Static LCq 4srStaticLCy . 77..20,21.01.0m, &g12(.a0vg(AofQU8;IAREQU3;IR1E9823;) 48-hr Static LCy 1982) 5.00.5 mg/L (avg of 3; AQUIRE 3; 48-hr Flow-through LCs 1983) 1.8 mg/L (AQUIRE 2; 1981) Fathead Minnow (Pimephales promelas) 24-hr Static LCyy = 48-hr Static LCy, 7.4 & 8.5 mg/L (AQUIRE 3; 1983) 6.6 & 7.3 mg/L (AQUIRE 3; 1983) 96-hr Static LCs, 6.6 & 6.9 mg/L (AQUIRE 3; 1983) Bluegill (Lepomis macrochirus) 96-hr Flow-through LCs :4.5 mg/L (AQUIRE 2; 1981) Mumm9i6c-hhroSgta(tFiucnLdCulqus heteroclitus) 2.1 mg/L (AQUIRE 2) Sheepshead Minnow 24-hr Static LCy (Cyprinodon variegatus) 10.0 mg/L (AQUIRE 2) 48-hr Static LC, : 96-hr Static LC, 9.0 mg/L (AQUIRE 2) 9.0 mg/L (AQUIRE 2) High-eyes Medaka (Oryzias latipes) 6-hr Renewal LCq 24-hr Renewal LCy 67 mg/L (AQUIRE 2) 46 mg/L (AQUIRE 2) _- 48-hr Renewal LCy, 46mg (AQUREZ) Brine Shrimp (Arteria salina) 24-hr Static LCy 3.6 mg/L (AQUIRE 2; 1974) . RB Atlantic Siverside (Menicia menidia) 96-hr Static Cy - 2.8 mg/L (AQUIRE 2; 1982) Killfish (Fundulus similis) 24-hr Static LCq 47 mg/L (AQUIRE 2) 48-hr Static LCy 96-hr Static LCy, 4.7 mg/L (AQUIRE 2) 4.5 mg/L (AQUIRE 2) Rainbow Trout (Salmo gairdnen) 48-hr Flow-through LCs 96-hr Flow-through LC, 5.95 4.62 mg/L mg/L (Verschueren (Verschueren p p 793; 793; 1977) 1977) 10-day Flow-through LCs, 2.85 mg/L (Verschueren p 783; 1977) 15 . : 001837 a Zebrafish (Brachydanio rerio) 48-hr Flow-through LC, 96-hr Flow-through LC, 8.81 mg/L (Verschueren p 793; 1877) 7.97 mg/L (Verschueren p 793; 1877) __ 10-day Flow-through LCs, 7.97 mg/L (Verschueren p 793; 1977) Flagfish (Gordanella floridas) 48-hr Flow-through LC, * 96+hr Flow-through LCy, 10.0 8.10 mg/L mg/L (Verschuerenp (Verschueren p 793; 763; 1977) 1977) 10-day Fiow-through LCs, 6.90 mg/L (Verschueren p 793; 1877) EnLvitierroatnumreendtaatlaAisnsdiecsastmesefnati;ry lowtoxicityto bacteria and although no actual BOD test data asrheoualvdaibleaboleb,tatihinsedmabtyeroiuarl oswhonulBdObDetreesatdsi.ly degraded by microorganisms. A BOD value This data maagtreereisalweils lmowditehraltiteelryattuorxeidcattoafwishhi, cDhapghinviesa,usancdonafligdaeen.cOeuirn most fecent the contract Daphnia test laboratory's `work on this material. testing is warranted. Because there is sufficient fish toxicity data from the literature, no fish Bacause of the algal toxicity shown in the literature data, algas testing should be done. aEdvveenrstehoeufgfhectthsiswilmlatbeerimailniismatolxiifcittoisapvaasrsieetdytohfraoquugahtiacwaosrgtaenwiastmesr, titrreeaatdmielnytdseygsrtaedmesoranifda sWiegnisfhiocaunltd nduomsbeormoefstmuidcireosoirngawnhiiscmhsoaurrepprroedsuecnttisinpaasnsaetusrtahlrwoautgehratomdoedgerlawdaesitt erwapaitdelry. treatment system and would be a simulation tohfeamneaatusruarlebtohdeytoofxiwcatefefrecutssinogf tahne amgoudaerlisumefsftloucenkte,dAwniotthhfeirshs.tTuhdiys ~~ would give us an understanding of the degradation in a river, pond, or lake. . BOD, COD, and Microtox. 4. Tolyltriazole (RM 27513; Corrosion Inhibitor Tolyltriazole Technical Grade) CAS#C2H93A8N5,-43-1 : O[3r i - y SyMnetohaylnn-d1vHy-eBnedmnozrosstr:iazole -16- 001838 Cd Methylbenzotriazole CPorebvreantteocl TCTI-71-01000((PMMoCb,aIynCco.r)p.TM) Degradability; BOD Toxicity: Water Flea (Daphnia magna) 48-hr Static EC, Bluegil Sunfish _... 96hriCy Rainbow Trout 96-hr LCs, Fathead Minnow 96-hr LCs ng 0: 1H-Benzotriazole (CoH) * CAS Number: 95-14-7 Synonyms: 1,2,3-Benzotriazole Aziminobenzene Benzene Azimide " Benzotriazole - Bluegill sunfish (Lepomis macrochirus) Static 24-hr Stress Rainbow Trout (Salmo gairdner) Static 24-hr Stress Sea LStaamtpicre24y-(hPreSttrroemssyzon mari: nus)" ChinoStoaktiSca2l4m-ohnr M(oOrntacloirthyynchus tshawytscha) <60% ThOD (Mobay Corp.) 19 mg/L (EnviroSystems 1991) 31.0 mg/L (Mobay Corp. and PMC) . + 21.4_ mg/L (Mobay Corp. and . PMC) 255 mg/L. PMC) (Mobay Corp. and | / i ae #- 5 mg/L (AQUIRE 3; 1957) 5 mg/L (AQUIRE 3; 1957) 5 mg/L (AQUIRE 3; 1957) 10 mg/L (AQUIRE 3; 1969) > cd - ------ 13 PMC Specialities Group, Inc. Technical Buletin 3200. Contact: Bill Mautiewicz -. (513-242-3300). 14 Mobay Corp. data given by Matthew Bartman 412-777-2000. 17. * 0064839 Ca CohoStSaatilcmo24n-h(rOnMocrotrahliytnychus Kisutch) 10 mg/L (AQUIRE 3; 1969) NorthSetratnicSq2u4a-whfriMsohrt(aPlittyychocheilus oregonensis) 10 mg/L (AQUIRE 3; 1969) EnWvhiirleontmheenltiamiltAedssdaetsasmsehnotw:s `concentration (0.05%) in the that this product, m it amtearyi ahlaivsemoldtelraeftfeelcyt tionxitch,e tis pre overall steoxnitc at ity such low of the nproodruecats.onBetcoaruespeeaotftthheeftiosxhicdiattya,ofhtohwisevmearte.rial, we need a complete set of data. There is TUhSisEPmAat.erial is listed on the TSCA 8(d) list and any testing done must be reportedtothe BBeOcDo,mmCeOnDd,atailognaes,faonrdAdMdiictriootnoaxl.Testing: - 5. jFoosvaimneerd (FM-4115) Wate4r8F-lheraSt(aDtaipchEniCa magna) 68 mg/L (EnviroSystems 1991) Ene`vTnhvieirrfooonnammmeeennrttaasllhoAefwsfssecestslssi.gmhWetentotsx;ihcoiutyldtohDaavpehanicao,mbpultettehesreetiosfneoffdeacttas dfoartathfeorrtehmiasimnaitnegrial. bCreaeprureessseetdnitoiauntltidhvbeeefsutatamukrpeel.netwhahticthhehsaasmbpeleenupsreoddiunctehdebeyntvhiermoannumfeancteufrfiencgtsmteetshtiondgiwshaicghowoidll v 3 B ; fiona) Testing: BOD, COD, fish, algae, and Microtox. 6. 5Filmer (FMI-e3820 or FC-95) i - BOD, BOD, BOD;, cop BODICOD Toxicity: nil (PED) nil (PED) nil (PED) nil (PED) 18 001850 Water Flea (Daphnia magna) 48-hr Static EC, 48-hr Static EC, 49 50 mmgg//LL ((EPnEvDi)roSystems 1991) ~._ Activated Sludge Inhibitory Conc. >4,000 mg/L (PED) Fathead Minnow 96-hr LCq, (Pimephales promelas) 38 mg/L (PED) Bluegill Sunfish (Lepomis macrochirus) 96-hr LC, 68 mg/L (PED) Rainbow Trout (Salmo gairdner) 96-hr LCqo 11 mg/L (PED) E`ncTvohimerpfooinnlemmneertn.twialTllhniAosstsmcaeotsnestrrimiaeblnudtteo:etos tshheoBwOsDli/ghCtOtDoxircaittiyo,tosofitsohxiacnidt-yiDsatphheniias.sTuehewriethisthgios od iangtrheeemmeonstt breectewnetednaptraefvrioomusEannvidrporSeyssetnetmDsa.phnia toxicity data which gives us confidence mWaennuefaecdtutroinhgavloetawhciocmhplheatsebseeetnofperfofdeucctseddabtyatfhoearmasnaumfpaclteurriepnrgesmeentthaotidvewhoifcah rweilclenbte uysed in the futu"re. fiona Testing: Algae and Microtox. 7. Ne-octylsulfate (RM 32067 or RM 55040) : CAS#142314 Lo 3 Vendors: Aloolac Incorporated (POLYSTEP B-29). (Sodium Octyl Sulfate Solution); Stepan Company" 3 ThOD 1.88 g/g (calculated) - 1165AWlciomlaVca:nn3e0s1t-e3'5s5-P2R60O0F.SNonodtaetdaaatveadil0a3b/le1.2/1990 gives this RM. 17 Called 708-446-7500 ext. 2283: they have no data. "19- 001841 ca BOD Srweicsohgenri'zedreapsoretxstrtehmatellyinreaapridprinimparriymaarlkyyblisoudlefgartaedsahtiaovne,loofntgenbedeisnappearing . in less than degradation a day" and rates of 80 ctiote1s0a0p%prwoixtihmiantaelfye1w0h0ourresfeorrednacyess.which show. Toxiity: Australian Barnacle (Elminius modestus) 30-min Static Immobilization ECs, 3,970 mg/L (AQUIRE 2; 1976) Water Flea (Daphnia magna) 48-hr Static EC, 517 mg/L (EnviroSystems 1991) "EAnlvtihrooungmhennotaBlOAsDsoerssCmOeDntd;ata are available, this material will most BOD/COD ratio. BOD and COD data should be obtained so thatwe likely have have a high numerical values which have been obtained in tests comparable to those used for the remaining components. Thhoewreeveirs sfuorrptrhiesiDngalpyhlnititale dlaittearaittusrheodwatsacaovnasiildaebrlaebolyn ltehsesatqouxaictiitcyttohxaincittyheofCth1i,sssuurrffaaccttaanntt,, Tahligsa,suarfnadctMainctriostopxretsoexinctitayt 3% so it data are emsaseyntbiealatmoacjoomrpflaectteortthoe toxicity of the product. assessment of this Fish, ingredient. BOD, COD, fish, alga, and Microtox, 8. Di-water (RD 199) pi ' > Water Flea (Daphnia magna) 48-hr Static EC, ~~ >1,000 mg/L (EnviroSystems 1991) EntWrvhaiiclreeodnittmomecanoytnatslaeAmesimnsaeftsoeosdlmidesehnittoo;ntiezsettdhwea.tdeeriosnuipzpleidewsaitnetrhfeopratsotx.iciTthy,etDoaxipchenfifaecrtessuhlatviendbieceatnes tishawtartrheanstuepdp.lywas not contaminated and no further testingof the deionized water sample None. ~t~ r----eem-- 188S0w7i-s8h1e1r., R. D.Surfactant Biodeg2nrdead.d MaracetlDeikkoern ;Ne.w York, 1987, p 466, 19 There was 1 test given in the EPA AQUIRE database. 20 001842 hy 9. FC-208 BOD, BOD, cop - BOD,COD MicrotEoCx, ECs AAcltgiaveat(eCdhlSolreuldlgaepIynrheinbictiidonosa Algae7a2n(-dShrcPehSntoaertdmiiecdsPimoupumusli.snuGubrsnpodiawcttauhtmu)Isn)hib. EC 72-hr Static Popul. Growth Inhib. EC, Wat- e2r4F-lheraSt(aDtaipchEniCa,magna) 2448--hhrr SSttaattiicc EECCq 48-hr Static EC 751670 gg//LL ((PGEeDr)man Army Report) 1,060 g/L (PED) 11,,307730 gg//LL ((PGEeDr)man Army Report) 0R.e5p2or(t)PED and German Amy : 26,35200m,gm/gL/L(G(eGremramnanArAmrymyReRpeoprotr)t) none at 1,000 mg/L (PED) no effect at <1,000 mg/L. (PED*') 1166.09:mm. gg//LL((GGeerrmmaannAArrmmyyRReeppoorrtt)) 4313.06mmgg//LL((GGeerrmmaannAArmmyyRReeppoorrtt)) ~~ pn 212,6900mgm/gL/L(E(nPviErDoS)ystems 1991)2 3 2+0Aa"nr3dm%yBaORpepDpl,oirctar.teisTopnehcestoiGlveeultryim.onaTsn"hewAerGrmeeyruvmsaalenudeAtsrowmoeybrtvaeainl4u1te,hs2e0w0BeOrmeDg/m,LualatnindpdlCi2O1,Db5y0d0a3t3ma.g3i/ntLotfhogeretGtehtehremCvaOanlD 21 iTnetshtiisnrgepdoortn.e 22 EnviroSyste byisInrdeupsetaritailngBitohi-sTetsetstLbaebocraautsoryt,heJraen.w1a8s74n.ot ed eno var ues in t F 23cToenscteinntgradtoinonemssbtyheByiounsoemdictos dLeavbeorlaotporay,goDoedc.set1a9n7d3a.rd curve. ugh iation he G-203 221. 001543 Bl Eastern Oyster Embryo-larvae (Crassostrea virginica) 48-hr Static ECs, <- -- Grass Shrimp (Palaemonetes pugio) 96-hr Static LC, Fathe96a-dhmriSntantoicwL(CPismephales promelas) Zebrafish (Brachydanio rerio) 48-hr Static LC, 48-r Static LCy, Scud48(-GharmSmtaatriucsLCfyas,ciatus) Rainbow trout (Oncorhyncus mykiss?) 96-hr Static LCq, Rainbow trout (Oncorhyncus mykiss) 96-hr Continuous Flow LCy, Common mummichog 96-hr Static LC, (Fundulus heterociitus) Grass Shrimp (Palaemonetes pugio) : 96-hr LCyy 47 mg/L (PED) 510 mg/L (PED*) 750 mg/L (PED) 1,053 1,634 mg/L mg/L (German (German Army Army Report) Report) 1,100 mg/L (PED): Lo 1,300 mg/L (PED) 400 g/L (PED?) 2,500 mg/L (PED) 510 mg/L (PED) En1v. iTrhoenfmiesnh ttoaxlicAistsyedsastamefnrotm:the German Army Report agres well with data from previous. 3M studies, so no fish testing is needed. ` : to 5A 2.TheMicrotox tests from the German Army Report seem reasonable, so this ts&f should > not be repeated. . : 3E.CTqhefr2o4m-thhreEGCse,rmDaanphAnrimaytoRxeicpiotrytfraorme tinhefamirolsytgoroecdeangtrEenevmiernotS.ysHtoewmesvweor,rkwaenwdertehne'4t8-hr satisfied with the concentrations used in the EnviroSystems work'and they are repeating 24 25 Testing Testing done done by by Bionomics Bionomics Laboratory, Laboratory, July Aug. 1980. 1979. 26 27 Testing done by Formerly Salmo Bionomics gairdneri. Laboratory, Dec. 1973. 2298 TNeostmionrgtadloitnyeobryabBnioornmoamlicesffLeacbtosraattotrhiys,cAoungc.en1tr9a7t9i,on. 22. . 001844 oh this work. be due to The large difference formulation changes between German or changes in the Army value toxicity test and the protocol 1973 PED value may but this cannot be verified. 4t.esAtsingwiitshotfhkenfoowanmecromapnodsiftiimoenr,awndefnreoemdatokbneowcnarmeafunluftahacttutrhiensgaomtp,le submitted for 5. Since toxicity to probably the most algae was important. of concem in the German Army Report, the algae data is BBODe,cCOoD,mamnd ealfgnoare.dAddaititonial Toesntinsg: 10. VW160390 (FC-203 without Tolyjtriazole RM 27513) Toxicity: Water Flea (Daphnia magna) 48-hr Static EC, 165 mg/L (EnviroSystems 1991) En1v.iSrionncemetnhteaolnAlyssdiefsfsemreenncte:between this material and FC-203 is tolyltriazole, testing this material along For the recent with FC-203 seems Daphnia data, there like a goodwayto is litle difference determine the effect between FC-203 and of tolyltriazole. VW160390 and tthheaneftfheecttooxfictiotlyytorfiVazWo1le60ca3n9n0otinbtehseereenc.enItn fact, the toxicity EnviroSystems woofrFkC.-S2i0n3cewaEnsvsilrioghStylsytleesmss. is repeating the Daphnia `completed thes tests bfeorfotrheesmeaktiwnogsaamnpleveasl,uawteionwi.ll have to w- ait until EnviroSystems S has > `2.coAmpMaircerdottooxtahnedFCfi-s2h0t3oxirceitsyttsesttossheoeulidf tbheerdeoinseaomneathsiusrmaabtleerieaflfeacntdctahueseredsublyts 5 tolyttriazole in the product. y Jong Testing: _ BOD, algae, fish, and Microtox. 3c0onEcnevnitrraStyisotnesmtshiesyreupseeatditnogtdheivsetleospt because there was not a good standard curve. enough variation in the 23. 001845 11. FC-203CE BOD, 91 g/L (PED) BOD, 400 g/L (PED) BOD,, . 680 g/L (PED) cop 762 g/L (PED) BOD,/COD ratio 0.89 (PED) -- Total Organic Carbon (TOC) 220 gL (PED) k OECD Method 301E 88-90% biodegradability in 14 days (PED) Toxicity: Algae (Selenastrum capricornutum) 95-hr ICs >1,000 mg:/L (PED) OECDInhAicbtitiivoanteTdesStlu2d0g0e Respiration none at 1,000 mg/L - Water Flea (Daphnia magna) 48-hrStaticLCy 1,000 mg/L. (PED) Microtox (Photobacterium phosphoreum) Exposure: 5 min. ECs, 370 mg/L 15 min. 30min 260 mg/L 230 mg/L % Killifi9s6h-(hFruCnodnutliunsuhoeutserFolcloiwtuLsC)s, 1,400 mg/L (PED) Fath9e6a-dhMriCnonnotiwn(uPoiumseFplhoawleLsCpsromelas) 52,000 mg/L (PED) 96-hr Static LC, 1,000 mg/L (PED) EnTvhieroennvmiernotnamlenAtsasleesfsfemcetnstd;ata for F. C-203CE is fairly complete. ATrhemyPREeDpodrattaansdhofwrosmltohweerretcoxeinctittyetsotsDbayphEnnivairtohSaynsitsemssh.owDnapbhyniFaC-t2es0t3inign sthhoeuGlderbmeadnone Ragain for assur"ance in our Pfiona ED. Testing: Algae and Daphnia. SE - -24- 001846 oy : 12. FC-206CE Regradability: BOD, BOD; BOD, cop BOD,y/COD ratio -- Total Organic Carbon (TOC) OECD Method 301E 46 g/L (PED) 260 g/L (PED) 470 1 (PED) 402 g/L (PED) 1.2 (PED) 130 g/L (PED) 89-92% biodegradability in 14 days (PED) Toxicity: Algae (Selenastrum capricornutum) 95-hr ICs 1,000 mg/L (PED) OECD Activated Sludge Respiration Inhibition Test 209 none at 1,000 mg/L. . Water Flea (Daphnia magna) 48-r Static LC, >1,000 mg/L (PED) MicEroxtpooxs(uPrheo:tobacterium phosphoreur) ECy 5 min. 15 min. 650 mg/L 4500 mg/L - 30 min 4200 mg/L EE Killfish (Fundlulus heterociitus) 96-hr Continuous Flow LC, >2,000 mg/L (PED) Fathead Minnow (Pimephales promelas) 96-hr 96-hr Continuous Static LC, Flow LC, 2,000 mg/L (PED) >1,000 mga (PED) TABghaeine,nvtihreoPnmEeDntdaaltaefsfehcotwssdaionalltoawftooTrxeiFsctiCti-yn2gt:0o3DCaEphisnifaairwlhyiccohmpslheotuel.d be verified. Algae and Daphnia. . cd - .25- : 001847 13. FC-203CF EnNvoirenovnimreonntmaenltAaslseefsfsemctesntda:ta for this product are available and a complete set of environmental effects data should be obtained. B ] ional Testing: BOD; COD, algae, Daphnia, fish, and Microtox. 14. FC-206CF EnNvoireonnvimreonntmaelntAaslseefsfsecmtesndta:ta for this product are available and acomplete set of environmental effectsdata should be obtained. 8 . . i ] BOD, COD, algae, Daphnia, fish, and Microtox. 15. L4640 (New Foamer) Testi1n.gDiaspchunrrieanttloyxiucintdyesrtwuadyy (fCo2arEEEuCrotpesetanmePthMoNd)b.y NOTOX Laboratories: 2. 3: Fish toxicity (C1 Modified Sturm method) test (C5) using Zebra fish (Brachydanio for ready biodegradability. rerio). Alltesting for the European PMN is being done by GLP. cTohmepifolleldowiinntgheenrveiproorntm"eEnntvailreofnfmeecnttsadlatDaataareanfrdoImnsfeovremartailo3n MintSeucphnpiocratlorfetphoretPs MwhNicfhorare Certain-Chemical Substances Designated as L-4640", June 20, 1880. > Degradability; BOD, <0.038 gig 5 BOD, - <0.038 g/g cBoODp, <0038glg 0.41g/g Tesi Theoretical Oxygen Demand 0.75g/g - Acuts Effect on Microbial Respiration Water Flea (Daphnia magna) 48-hr Static LC, Fathe96a-dhrMiSntantoicwL(CPi,mephales promelas) 8%dreepdluecttiioonnaitn 1r,at0e00ofmogx/yLgen 100 mg/L and 111 mg/L 158 mg/L and 166 mg/L. 26 001548 EnBveicraounsmeenoftathleAsimspeosrstmaenncet:of this material to future products, a full set of environmental tBehfepfercetsvidaotuasisstn.uedeideseds.hoTuhledieobnneavloibrtoTaenismnteienndtg:a:lalegfafeecatnsddaMtiacrnoottoxi.ncluded in the PMN work or in Algae and Microtox. 16. Witcolate 7093 (RM 45666) CAS#73665-23-2 "W5i5t%cowaCtoerrp,or4a5ti%onC6(-71C31-043e3t-ho7x2y8l1a)tehdassunlfoateec.oTtohxeyinrfeorcmoamtimoennadveadlaSbwlies.hWeitrcfoolrate7093 is biodegradation information. Lo No information on EPA AQUIRE database nor in Verschuersn. EnNvoierfofnemctesntdaatlaAsissaevsasilmaeblnet.:Testing in future products. depends on the likelihood that this material will be used BCOeD,cBOoD,malmgaee,fnfoisrhdA,dDdaaipthitonniiaal,ToeasntndinMsgi:crotox. 17. Triethanolamine CAS#102716 Degradability:TM! ThOD BOD, BOD, BOD,s BOD, E 1 a . - . 2049/g nil 0.02 g/g withstandardseed 0.17 g/g adapted sewage 0.03 g/g 0.020/g nil with std. diluted sewage 0.05g/g 013g 31 All degradabilty data are from Verschueren p 1150-1. 27. : 002849 cop BOD/COD BOD,/COD Toxicity: Bacteria (Pseudomonasputida) Popul. Growth Inhib. Algae (Microcystis aeruginosa) Popul. Growth Inhib. _ Gree7n-AdlagyaSeta(tSiccePonpeudle.sGmruoswqtuhadInrhiicba.uda) 8-day 8-day Static Static Popul. Popul. Growth Growth Inhib. Inhib. Blue-green Algae (Anacystis aeruginosa) 8-day Static Popul. Growth Inhib. Protozoa (Entosiphon sulcatum) 72-hr Static Population Growth . Protozoa (Chilomonas paramecium) 48hr Renewal Popul. Growth Inhib. Protozoa (Uronema parducz)) Bacteria (Pseudomonas) LC, Algae (Scenedesmus) "LC, Algae (Colpoda) LC, . Water Flea (Daphnia) ~~ - LC, 24-fr Static LCy, Brine24S-hhrrimStpat(iAcrtLeCm,ia salira) * 1.50 g/g nil 0.0.11 0.09 >10,000 mg/L (Verschueren p 1151) 47 mg/L (Verschueren p 1151) 1.8 1.8 mg/L mg/L (AQUIRE (AQUIRE 2; 2; 1980) 1578) 715 mg/L (AQUIRE 2; 1978)" 19 mg/L and 47 mg/L. (AQUIRE 2; 1878) 56 mg/L (AQUIRE 2; 1980) 1,768 mg/L (AQUIRE 4; 1980) >10,000 mg/L. (Verschueren p 1151) 10,000 mg. /L. (Verschueren p 1151) 100 mg/LP"a (Verschuerepn 1161) 160 mg/L. (Verschueren p 1151) So 2,500 mg/L (Verschueren p 1151) 1,390 mg/L (AQUIRE 2; 1977) 5,600 mg/L (AQUIRE 2; 1974) 32 The toxicity database. data are a partial listing of the 16 tests on 10 species given in the AQUIRE 33This value is from a different reference than the previous one. -28- - 00185! Goldfish (Carassius auratus) 24-hr Static LC, 24-hr LC, (85% TEA) 5,000 mg/L (AQUIRE 75,000 mg/L at pH 7 2; 1679) 3,mg/5Lat0 pH 10 0.3 (Verschueren p 1151) En"TvhiisromnatmeernitalalsAhsoswesssinmseingnti:ficant toxicity to Daphnia and fish. aHdodwietivoenr,,ititshhaoswsa cloonwsiBdOeDra/bClOeDtorxaiticoitatonydalwgilale.coFntorritbhuteesatoreaalsoonwsr,atiitowionutlhdebperobdeusctt.noItn fo use this _product wmialtebreiaelxitnrepmreolduycliosw.unless no altemative can be found of its concentration in the The literature data .be reported to .US EisPeAssuenndtoviearllsyecctoimopnlTeStCeecAf8or(dth)i.s material. ~~ - Any testing on this material must None. 18. Urea CAS#57-13-6 Degradabilty Degrades abiotically: HNCONH, + H;0 --> CO, + NH, Degradation rate at 20C . Degradation rate at 2'C Concentration in domestic sewage Toxicity :. Bacteria (Pseudomonasputida) Popul. Growth Inhib. Gree7n-AdalygSata(tSiccePnopeudle.sGmruoswqtuhadInrhiicba.uda) 8-day Static Popul. Growth Inhib. 10.9 mg/Lhr 3.3 mgr 2106 mg i " >10,000 . mglL (Verschueren p 1178) -- 10,000 10,000 mg/L mg/L (AQUIRE (AQUIRE 2; 2; 1980) 1878) 3345 TAlhledetgorxiacdiatbyildiattyadaarteaaarpaertfiraolmliVsetirnsgcohfu3e2retnespts11o7n8-197.species from the EPA AQUIRE database. -29- : 00151 Cd Blue-8g-rdeaeynSAtlatgiaceP(oApnualc.yGstrioswtaherIunghiinbo.sa) 47 mg/L (AQUIRE 2; 1978) ~~ Proto7z2o:ar(SEtnattoisciPpohpounl.suGlrcoawttuhm)Inhib. 29 mg/L (AQUIRE 2; 1980) Proto4z8o-ahr(PCohpiullo.mGornoawstpharIanhmiebc. ium) 2,683 mg/L (AQUIRE 4; 1980) Wate2r4F-lheraSt(aDtaipchLniCa4) 10,000 mg/L (AQUIRE 2; 1977) Crack Chub (Semotilus atromaculatus) - 2244--hhrr LLCC,yy 3106,,000000 mmgg//LL ((AAQQUUIIRREE 22;; 11995522)) EngLirvteieerrnaotnaumlrgeeandeta.atFaluAirsntdshieecrsamstoemrseetn,htai:tt dtehigsramadteesriraeladsihlyowasndinist imgonisfticlainktelf"yoxwiocuttlydtonoDtabpehnaiap,rofibslh,emanind the product. sHhoowuelvderb,e ivtedriofeisedsbhyoowutroxoiwcintytteostbsliufet-igsreteonbaelguasee,dainndthteheprloodwutcotxiactithyitgoh gcroneceenntarlagtaieons. BNonee.commefnordAddaititonialToesntinsg; 19. Triton X-305 CAS# ~c9o0m0p2o:s9i3t-i1on(PoRfIthSeMrsehmoawinsiTnrgit3o0n %X-n3o0t5gitvoebn)e.70% th~i~s material with the i > SynonPyomlsy:(ooxmye-g1a,-2h-ytdhraonxeyd-ipy)o,lyasltphhyal-e{n4-e(g1l,y1c,o3l,p3-a1t,r1a,m3e,t3h-ytlebturtaymle)tphhyelnbyi]- ether OcP-ttoexritn-oolctylphenoxypolysthoxyethanol : utylphenyl VendorR;ohm & Haas Company e 36 Indepe endence e Mall West, Philadelphia, PA 19105. Phone: 215-592-3000. -30- 001352 Toxicity: Bluegill (Lepomismacrochirus) 24-hr Static LC, Fa 24-hr Static LC, 3.5 mg/L (AQUIRE 1; 1975) 24-hr Static LC, 16.2 mg/L (AQUIRE 1; 1975) 1,080 mg/L (AQUIRE 1; 1975) 24-hrFlow-through LCs 96-hr Static LC, 10.0 mg/L (AQUIRE 2; 1975) 96-hr Static LC, 2.8 mg/L (AQUIRE 1; 1975) 12.0mg/L (AQUIRE 1; 1975) 96-hr Static LC,, 96-hr Flow-through LCy 531 mg/L (AQUIRE 1; 1975) 10.0mg/L (AQUIRE 6-day Flow-throughLCy 2; 1975) 9.6 mg/L (AQUIRE 2; 1975) . "TSthaetirceLaCsyo,n(f5o3r1`tmheg/hiLg)havraeluneost fkonrotwhne.24-hr Static LC , (1,08.0 mg/L) and for the 96-hr The vendor for Triton X-305 (Rohm and Haas) biodegradability of Triton X-305. However, has no data on the aquatic toxicity or toxicity of Triton X-100. Triton X-100 has a they are sending adata sheet on theaquatic lower molecular weight than X-305 and they believe that the toxicityof X-305 is less Triton X-305 is not believed to degrade than X-100 because biologically. X-305 is less surfaceactive. Triton product line to Union Carbide (1-800-752-1 Rohm and 1827) and will Haas has recently be transferring the sold their business Tinhtehefnoellaorwfinugtudraet.aTihs efrCoAm SAQnUuImbReErognivtehins bCyARSonhummbaenrd. Haas forthe series is 9036-19-5. CAS#9036-19-5 Toxicity Rainbow Trout (Salmo gairdnen) 48-hr Static LC, 96-hrStatic LC, ~ Marine Polychaete Worm 48-hr Static LC4, (Scolelepistuliginosa) - 96-hr Static LC, ' "i. 7.2mg/L (AQUIRE 2; 1978) 7.2 mg/L (AQUIRE 2; 1978) 17.0 mg/L (avg. of 7 points) 13.7 mg/L (avg. of 8 points) (AQUIRE 2; 1978) > - CR _ pe s---- 37 The toxicity database. data are a partial listing of 13 tests on 5 species from the EPA AQUIRE 38 The toxicity database. data are a partial listing of 36 tests on 5 species from the EPA AQUIRE 31. . 01853 iw Marine Polychaete Worm 48-r Static LC4, (Capitella capitats) 8.2mglL (avg.of 6 points) oo 96-hr Static LCq, 6.0 mg/L (avg.of 8 points) (AQUIRE 2; 1978) Aquat4i8c-hSroRwebnuegwa(IldoLtCeya,balthica) 96-hr Renewal LCs, 10.0 mg/L (AQUIRE 3; 1872) 5.0 mg/L (AQUIRE 3; 1972) EtnBoovxtiichritoGyn.AmSSeinnntcuaemlTbAresirstsoenshXsa-mv3eea0n5t:lisimaitmedajaomrocuonmtpoofnteoxnitciotfytdhaetCa Eavaplrioadbulcetsw,hwicehwsilhlonwesedmoaderate ~complete products satofdata on this material to their formulation. in order in order to correlatethe effects.of the CE BBeOcDo,mmCeOnDd,atailoganes,fDoarpAhdndiiat,iofnisahl,TaenstdinMgi:crotox. . = ' - I" > 32. - 007.354