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3M 3M General Offices MATERIAL SAFETY DATA SHEET 3M Center SL Paul, MN 55144-1000 6HT733 1110 0&1 1710 Copyright/ 1997/ Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) tho information is copied in full with no changes unless prior agreement is obtained from 3M/ and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: SPECIALTY CHEMICALS DIVISION TRADE NAME: FC-11B FLU0RAD Brand Fluorochemical Surfactant ID NUMBER/U.P.C.: 98-0211-4832-9 00-51135-02697-7 98-0211-8012-4 00-51135-10863-5 98-0211-8858-0 00-51135-10971-7 ISSUED: FEBRUARY 7, 1997 DOCUMENT: 10-4E21-7 ' C7 fid- C o o a j HH 98-0211-4885-7 98-0211-8083-5 00-51135-02745-5 00-51135-10918-2 1. INGREDIENT C.A.S. NO. PERCENT WATER ...................... .... AMMONIUM PERFLUOROOCTANOATE .... . AMMONIUM PERFLUOROHEPTANOATE ____.... 6I30-A3-4 AMMONIUM PERFLUOROHEXANOATE ..... AMMONIUM PERFLUOROPENTANOATE ....____ 68259-11-0 18 0.1 0 0.1 - - 80 21 1.0 0.1 1,0 P H Y S IC A L DATA BOILING POINT:.... VAPOR PRESSURE:___ VAPOR DENSITY: ___ EVAPORATION RATE:.. SOLUBILITY IN WATER SP. GRAVITY:...... PERCENT VOLATILE: pH: ......... ..... VISCOSITY: ....... MELTING POINT..... APPEARANCE AND ODOR 100 c (Typical) 18 mmHg Calc S> 20C 0.62 Air = 1 Calc S 20C < 1.0 Butyl Acetate = 1 complete 1.12 Water = 1 80 X ca. 5 ..... N/D ..... N/A Light colored liquid; slight odor. 3 . F I R E A N D E X P L O S IO N H A Z A R D D A T A _______________________________________________________ FLASH POINT:................ > 100 C Setoflash FLAMMABLE LIMITS - LEL: .... N/A FLAMMABLE LIMITS - UEL: .... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water/ Carbon dioxide, Dry chemical/ Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing/ including helmet/ self-contained/ Abbreviations: N/D - Not Determined N/A - Not Applicable E ID 599980 3[Yt General Offices MATERIAL SAFETY DATA SHEET 3M Center S t Paul, MN 55144-1000 612 733 UI0 1711 USDS: FC-118 FLUORAD Brand Fluorochemical Surfactant FEBRUARY 7, 1997 PAGE: 2 of 6 3. FIRE AND EXPLOSION HAZARD DATA {continued) "" ' positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. *. R E A C T IV IT Y DATA ~" ' STABILITY: Stable INCOMPATIBILITY - MATERIALS TO AVOID: Not Applicable HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen Fluoride, Ammonia. E N V IR O N M E N TA L IN F O R M A T IO N SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personol protective equipment. In the U.S.A., call (612) 733-1110 or (612) 733-6100 for 24-hour spill assistance. Contain spill. Cover with absorbent material. Collect spilled material. For spills to ground: Collect contaminated soil. Pump contaminated water from puddles or stagnant storm sowers. Place collected waste in approved containers, and seal. For spills to ground or surface water: Notify appropriate authorities, Contact 3M to evaluate further needs. RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility in the presence of a combustible material. Combustion products will include HF. Pass contaminated water through enion exchange resin. If necessary, contact 3M for assistance. ENVIRONMENTAL DATA: Data for product solids: Chemical Oxygen Demand (COD): Nil ( .000700g/g). Biochemical Oxygen Demand (B0D20): Nil; 96-Hr. LC50, Dluegill Sunfish (lepomis macrochirus): 569 mg/L; 96-Hr. LC50, Fathead Minnow(Pimephales promelas): 766 mg/L; 48-Hr EC50, Daphnia magna: 632 mg/L; 14-Doy EC50 (cell dry weight). Green Algae (Selonastrum capricornutum) 73 mg/L. Soil Adsorption Coefficient (Koc): 17, indicates very high mobility. (Study used a sandy loam soil). REGULATORY INFORMATION: Volatile Organic Compounds: N/A. VOC Less H20 & Exempt Solvents: N/A. Abbreviations: N/D - Not Determined N/A - Not Applicable. E ID 599981 3M General Office* MATERIAL SAFETY DATA SHEET 3M Center 51. Paul, MN 55144-1000 612 733 1110 ~ 1712 MSDS: FC-118 FLUORAD Brand Fluorochemical Surfactant FEBRUARY 7, 1997 PAGE* 3 of 6 5 . E N V IR O N M E N T A L IN F O R M A T IO N ___________( c o n t i n u e d ) Since regulations wary, consult applicable regulations or authorities before disposal. U.S. EPA Hazardous Waste Number = Nona (Not U.S. EPA Hazardous). The components of this product are in compliance with the chemical registration requirements of TSCA# EIN6CS, CDSL and AICS. EPCRA HAZARD CLASS: ' FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes 6 . SUGGESTED F IR S T A ID ~ EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Immediately wash skin with soap and large amounts of water. Remove contaminated clothing. If signs/symptoms occur# call a physician. Wash contaminated clothing before reuse and dispose of contaminated shoes. INHALATION: If signs/symptoms occur# remove person to fresh air. If signs/symptoms continue# call a physician. I F SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7 . P R E C A U TIO N AR Y IN FO R M A TIO N EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended* butyl rubber. Use one or more of the following personal protection items as necessary to prevent skin contact: head covering# coveralls. Protective garments (other than gloves) should be made of either of the following materials* polyethylene/polyvinylidene chloride (Saranax) Coverall made of Tyvak(r). Wear rubber boots when cloaning up spills. VENTILATION PROTECTION: Use with appropriate local exhaust ventilation. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate# use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors# mists or spray. Avoid breathing of Abbreviations: N/D - Not Determined N/A - Not Applicable E ID 599982 3M General Offices MATERIAL SAFETY DATA SHEET 3M Center ' St. Paul. MN 55144-1000 612 733 1110 - 1713 MSDS: FC-118 FLUORAD Brand Fluorochomical Surfactant FEBRUARY 7, 1997 PAGE: 4 of 6 7. PRECAUTIONARY INFORMATION (continued) -- airborne material. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: full-face high-efficiency filter respirator/ full-face supplied air respirator. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. RECOMMENDED STORAGE: Do not store containers on their sides. Store at room temperature. Keep container closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. No smoking while handling this material. OTHER PRECAUTIONARY INFORMATION: HMIS HAZARD RATINGS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions/ section 7.) EXPOSURE LIMITS INGREDIENTS VALUE WATER .......................... . AMMONIUM PERFIU0R00CTAN0ATE ..... AMMONIUM PERFLUOROHEPTANOATE .... AMMONIUM PERFLUOROHEXAHOATE ..... AMMONIUM PERFLUOROPENTANOATE .... UNIT NONE mg/m3 mg/m3 mg/m3 TYPE ATJTH SKIN* NONE NONE TWA ACGIH Y TWA 3M Y TWA 3M Y TWA 3M Y * SKIN NOTATION: Listed substances indicated with "Y" under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye/ either by airborne or, more particularly/ by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - AIHA: American Industrial Hygine Assoc. Workplace Environmental Exposure Level- 3M: 3M Medical Department Guideline - NONE: None Established B . HEALTH HAZARD DATA EYE CONTACT: No toxicity data for the solution. Ammonium perfluoroalkyl carboxylate can be irritating to the eye and may cause eye injury from airborne exposure. SKIN CONTACT: May be absorbed through the skin and porsist in the body for on Abbreviations: N/D - Not Determined N/A - Not Applicable E ID 599983 i ! 3M 3 M General Offices MATERIAL SAFETY DATA SHEET 3 M Center St. Paul. M N 55144-1000 612 733 1110 1714 USDS: FC-118 FLVORAD Brand Fluorochcmical Surfactant FEBRUARY 7, 1997 PAGE: 5 of 6 8. HEALTH HAZARD DATA (continued) ~ extended time. . No toxicity data for the solution. Ammonium perfluoroalkyl carboxylato is slightly toxic when absorbed through the skin; it is non-irritating to the skin. INHALATION: May be absorbed by inhalation and persist in the body for an extended time. .. No toxicity data for the solution. Ammonium perfluoroalkyl carboxylate may cause respiratory system irritation from inhalation; can be considered moderately toxic by inhalation on a single exposure; a median^lethal concentration for a 4-hour exposure in the albino rat is 980 milligrams per cubic meter. Repeated inhalation exposure produced liver changes and elevated blood organofluoride levels in rats. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. No toxicity data for the solution Ammonium perfluoroalkyl carboxylate is considered moderately toxic from a single oral exposure; acute oral LD50 (rat) is 540 mg. per kg. of body weight. CANCER: WARNING: Contains a chemical which can cause cancer. (3825-26-1) (1903 and 1993 studies conducted jointly by 3M and DuPont). M U T A G E N IC IT Y : Ammonium perfluoroalkyl carboxylate was not mutagenic in invitro mutagenicity assays. Did not cause cell transformation in a mammalian cell transformation assay. REPRODUCTIVE/DEVELOPHENTAL TOXINS: Ammonium perfluoroalkyl carboxylato was not teratogenic in rabbits by oral administration and was not teratogenic to rats by gavage and inhalation exposures. S E C T IO N C H A N G E D A T E S ___________________________________________________________ ;________ HEALTH HAZD. DATA SECTION CHANGED SINCE AUGUST 23, 1996 ISSUE Abbreviations: N/D Not Determined N/A - Not Applicable, E X D 599984 3M General Offices MATERIAL SAFETY DATA SHEET 3M Center St. Paul, MN 55144-1000 612 733 1110 USDS: F C -1 1 8 FLUQRAD B ra n d F lu o r o c h e m ic a l S u r fa c t a n t FEBRUARY 7, 1997 S E C T IO N CHANGE DATES 1715 PAGE: 6 of 6 Abbreviations: N/D - Not Determined N/A - Not Applicable The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for userTs method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the roraoto possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. E ID 599985 `MRTERIRL SAFETY 3M ' DflTfl SHEET 3M Center St. Paul, Minnesota 55144-1000 {612] 733-1110 Copyright, 1997, Minnesota Mining and Manufacturing Company. All rights reserued. Copying and/or downloading of this Information fa r the purpose of properly utilizing 3M products Is allowed prouided that: 1 ) the Information is copied in full with no changes unless prior agreement Is obtained from 3M, and 2] neither the copg nor the original is resold or otherwise distributed with the Intention of earning a profit thereon. diuision: sPECiniTY chemicals diuision THROE NRME: Fc-118 FLUOBHD Brand Fluorochemlcai surfactant ID NUMBEfi/lLPX.: 38-0211--4832-9 OD-S113S-02697-7 98-0211-488S-7 00-51135-02745-5 98-0211-8012-4 00-51135-10863-5 98-0211-8083-S 00-51135-10918-2 98-0211-8858-0 00-51135-10971-7 ISSUED: February 19,1997 SUPERSEDES: February 07, 1997 document: 10-1221-7 1. ingredient c.r.s. no. percent UJH1EB--------------------------- 7732-18-5 80 HMMONIUM PERFEUOROOCTRNORTE............ 3825-26-1 18 AMMONIUMPERFLUOROHEPTRNORTE______ 6I3U-43-4 0.1 HMMDN1UM PERFLUOROHEKRNORTE--......... 2161S-47-4 0 BMMONIUM PERFUIflROPENTflNORTE........... 68259-11-0 0.1 -21 - 1.0 -0.1 - 1.0 2. PHYSICAL OHTfl ---------------------------- r----------------------------------------------- BOILING POINIi_________ 100 C [Typical) OflPOR PRESSURE:--.......--... 18 mmHg C a lc 20C DRPDR DENSITY:;_________ 0.62 fllr-l Calc @ 20C. EURPORHTION RATE:______ < 1.0 8uORc-1 SOLUBILITY IN IDtlTER:........complete SPECIFIC GRRUITY:------------1.I2U later-l PERCENTUDLRTILE:........ ......80 % Pit---------------------- ca. S UISCOSITY:----------------- N/0 MELTING POINT:_________ N/R - BbbreulatlDns: N/B - Not Determined N/R - Not Rpplfcable CR - RpproHimatelg P I.8195 . . EID008492 IC I MSDS FC-118 FLUORAD Brand Fiuorochemlcal Surfactant February 19, 1997 PAGE 2 2. FHVSICRL OATH (continued) HPPEHRHNUE BND BOOR: lig h t colored liquid; slight odor. 3. FIRE RND EHPLOSION HAZARD OATH FLASH POINT:_________ > i oo C Setaflash FLAMMABLE LIMITS - LEL:..*..... N/H FLHMMAHLE LIMITS - OEL:_.__ N/H AUTOIGNJTION TEMPEHATUHE:-----N/H .. EHTINGU1SH1NG MEDIA: ' Wafer, Carbon dioxide. Dry chemical, Foam SPEC1RL FIRE FIGHTING PROCEDURES: Wear Tull protectlue clothing, Including helmet, self-contained, pnsltlue pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protectlue cotiering for exposed areas of the head. UNUSUHL F1HE RND EHPLOSION HRZRRDS: See Hazardous Decomposition section for products of combustion. 4. RERCTIUITV ORTH STABILITY: Stable 1NC0MPRT1BILTTV - MRTERIHLS/CONOITIONS TO ADOID: Not Applicable HRZRRODUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS! Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen Fluoride, Ammonia. 5. ENUIAONMENTAL INFORMATION SPILL RESPONSE: Refer to other sections of this MSOS for Information regarding physical and health hazards, respiratory protection, uentilatlon, a n d '' personal protectlue equipment. In the U.S.R., call (612) 733-1110 or (612)733-6100 for 24-hour spill assistance. Contain spill. Couar with absorbent material, Collect spilled material. Bbbreuiations: N/D - Not Determined N/H - Nol Rppllcable CH - Approximately P I.8195.2 EID008493 < 7/ld.w. ' MSDC FC-118 FLUORflD Brand Fluorochemicat Surractant February 19,1997 PRGE 3 S. ENLI1R0NMENTRL INFORMATION (continued) For spills to ground: collect contaminated soil. Pump contaminated inater from puddles or stagnant storm seuiers. Place collected waste in apprnued containers, and seal. For spills to ground or surface water: Notlfg appropriate authorities. Contact 3M to eualuate further needs. RECOMMENDED DISPOSAL: Incinerate in an Industrial or commercial facility In the presence of a combustible material. , Combustion products will Include HF. Pass contaminated mater through anion exchange resin. If necessary, contact 3M for assistance. ENUIRONMENTRL DRTR: Data forproduct solids: Chemical Oxygen Demand (COD): Nil (,000700g/g). Biochemical Oxygen Demand (BDD20): Nil; 96-Hr. LCSO, Biueglli Sunfish (Lepomis macrochlrus): 569 mg/L; 96-Hr. LCSO, Fathead MinnaiuiPImephaies promelas): 766 mg/l; 48-Hr EC50, Daphnia magna: 632 mg/L; H -D a y EC50 (cell dry weight), Breen Rlgae [Selenastrum capricnrnutum) 73 mg/L. Soli Adsorption Coefficient (Koc): 17, indicates uery high mobility, (Study used a sandy loam sail). REGULRTnnV INFORMATION:. Uolalile organic Compounds: N/H. DOC Less H20 & Exempt Soluents: N/fl. Since regulations uary, consult applicable regulations or authorities before disposal. li.S. EPR Hazardous Waste Number - None (Not U.S. EPfl Hazardous). The components of thts product are in compliance with the chemical registration requirements of TSCR, EINECS, CDSL and HICS. EPCRfi HBZRRD CLASS: FIRE HRZRBD: No PRESSURE: No RERCTIUITV: No RCUTE: Ves CHRONIC: Yes 6. SUGGESTED FIRST RID EYE CONTACT: Immediately flush eyes wilh large amounts of mater for at least 1S minutes. Get immediate medical attention. SKIN CONTACT: Immediately wash skin with soap and large amounts or mater. Remoue contaminated clothing, if signs/symptoms occur, call a physician. . * UJash contaminated clothing beTore reuse and dispose or contaminated shoes. Rbbreuialions: N/0 - Not Determined N/l) - Not Rppticable CR - Approximately P I.8195.3 EID008494 M sdS: FC-118 FLUOHHB Brand Fluorochemical Surfactant - February 19, igg7 PRGE 4 6. SUGGESTED FIRST fUO (continued) 1NHBLBTI0N: trslgns/sym ptom s occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SlUBLLOUIED: Do not Induce uomiting. Drink tiuo glasses of mater. Call a physician. 7. PRECRUTIONRRV INFORMATION EVE PROTECTION: . Ruold eye contact. Wear uented goggles. SKIN PROTECTION: ituoid skin contact. Wear appropriate gloves when handling this material, n pair of gloues made from the following materlal(s) are recommended: butyl rubber. Use one or more of the following personal protection item s as necessary to preuent skin contact: head couering, coueralls. Protective garments (other than gloues) should he made o f either of the following materials: polyethylene/polyulnylidene chloride (Saranex) Couerall made ofTyuek(r). Wear rubber boots when cleaning up spills. RECOMMENDED UENTILnTION: Use with appropriate local exhaust uentilation. Provide sufficient uentflatfon to maintain emissions below recommended exposure limits. I f eHhaust uentilation is not adequate, use appropriate respiratory protection. RESPIRATOR? PROTECTION: Ruold breathing of vapors, mists or spray. Ruold breathing of airborne material. Select one of the following NIDSH approved respirators based on airborne concentration of contaminants and In accordance with OSHH regulations: rull-face high-efriciency filter respirator, full-face supplied air respirator. PREUENTION OF RCCIOENTRL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly, with soap and water. Wash hands a fte r handling and before eating. RECOMMENDED STORRGE: Do not store containers on their sides. Slore at room temperature. Keep container closed when not In use. fibbreuiations: N/D - Not Determined N/fl - Not Applicable CR - Approximately P I.8195.4 EID008495 Q s \ ' MSDS: F C -U 8 FLUORRD Brand Flunrochemical Surfactant February 19. 1997 - PRGE 5 7. PRECRUTIONRRY INFORMATION (continued) FIRE RND EHPLDSION RUOIORNCE: Keep container tightly closed. Nonflammable. OTHER FRECRUTIDNnBV INFORMflriON: No smoking: Smoking luhite using this product can result in contamination of the tobacco and/or smoke and lead to the formation o f the hazardous decomposition products mentioned In section 4 of this MSDS. AMIS HRZHHD RATINGS: HERLTH: 2 FLRMMRDILITY: I REHCTIU1TY:0 PERSONAL PROTECTION: K (See precautions, section 7.) EHPQSUHE LIMITS INGREDIENT URLIIE UNIT TYPE RUTH SKIN* lilHTER ............. NONE NONE AMMONIUM PERFLUORQOCTRNORTE......... AMMONIUM PEBFLUOROHEPTRNQRTE____ HMMONIUM PERFLUOROHEHnNORTE...... BMMONIUM PERFLUORDPENTRNORTE.___ NONE NONE 0.01 MG/M3 O.t MG/M3 0.1 MG/M3 0.1 MG/M3 TUJR RCGIII Y TWR 3M Y TUJR 3M V TUJR 3M V * SKIN NOTHTION: Listed substances Indicated with 'V under SKIN refer to the potential contribution to the ouerall enposure bg the cutaneous route Including mucous membrane and ege, either by airborne or, more particularly, by direct contact with the substance. Uehicles can alter skin absorption. SOURCE OF EKPOSURE LIM IT ORTR: - ACGIH: American Conference of Oouernmental Industrial Hygienists - 3M: 3M Recommended Exposure Guidelines - NONE: None Established ' 8. HERLTH HRZRRD ORTR EYE CONTACT: No tonicity data fo r the solution. Ammonium perriuoroalkyl carbonylate can be irritating to the eye and may cause eye injury from airborne enposure. SKIN CONTACT: ' May be absorbed through the skin and persist in the body for an entended time. m` No tonicity data T o r the solution. Rmmontum perfluoroalkyl carbonylate Is slightly tonic when absorbed through the skin; it Is non-irrilating to the skin. Abbreviations: N/D - Not Determined N/R - Nat Rpplicable Cfl - flppronlmately P I.8195.5 EID008496 HSUS FC-U8FUI0RRD Brand Ftuorochemlcal Surfactant February 19, 1997 PRGE 6 8. HEALTH HRZRRD DATR (continued) INHALATION: May be absorbed by Inhalation and persist in the body for an extended lim e. No tonicity data for the solution. Rmmonium perfluoroalkyl carboxylate may cause respiratory system Irritation from Inhalation; can be considered moderately tonic by inhalation on a single exposure; a median lethal concentration for a 4-hnur exposure In the albino rat Is 980 milligrams per cubic meter. Repeated Inhalation exposure produced liner changes And eleuated blood organofluoride leuels In rats. IF StURLLDUIEO: Ingestion is not a likely route of exposure to this product. No toxicity data for the solution Rmmonium perriuoroalkyl carbonylate Is considered moderately toxic from a single oral exposure; acute oral LDSO (rat) Is 540 mg. per kg. of body tuelght. LUFIRMING: Contains a chemical uihlch can cause cancer. (3825-26-1) (1983 and 1993 studies conducted jointly by 3M and DuPont). MUTflGENICITV: Ammonium perfluoroalkyl carboxylate u/as not mutagenic In inultro mutagenicity assays. Did not cause cell transformation in a mammalian cell transformation assay. REPADDUCTIUE/DEUELOPMENIRL TOWNS: Ammonium perfluoroalkyl carboxylate mas not teratogenic In rabbits by oral administration and mas not teratogenic to rats by gauage and Inhalation exposures. SECTION CHANGE DATES PAECHIITIDNRHV INFO. SECTION CHANGED SINCE February 07, 1997 ISSUE P I.8195.6 JUibreuIations: N/0 - Not Determined N/fl - Not Applicable Cfl - HpproKimatefy EID008497 oc< p MSUS: FC-118 FtliDRRD Brand Ftuorochemlcal Surfactant February 19. 1997 PBEE 7 The information in this Material Safety Data Sheet (MSDS) is belieued to he correct as o fth e date issued. 3M MAKES NO WARRANTIES. EHPRESSEO OR IMPLIED. INCLUDING, BUT NOT LIMITED TO, RNV IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR H PHRTICULRR PURPOSE OR COURSE OF PERFORMRNCE OR USAGE OF TRADE. User Is responsible for determining whether the 3M product Is fit for a particular purposs and suitable Tor user's method o f use or application. Gluen the uarlety of factors that can a ffe d the use and application of a 3M product, some of which are uniquely uiithln the user's knowledge and control, it Is essential that the user eualuate the 3M product to determine whether It Is fit for a particular purpose and suitable fo r user's method of use or application. 3M provides infom iationjn electronic form as a serulce to its customers. Due to the remote possibility that electronic transfer may haue resulted In errors, omissions or alterations In this Information, 3M makes no representations as to Its completeness or accuracy. In addition, Information obtained from a database may not be as current as the information in the MSOS auailable directly from 3M. P I.8195.7 EID008498 O *oo\