Document RaKoJzLLBj6wBVwXjg1E64nOV
VC4487
ETHYL CHLORIDE )
SPECIFICATIONS
Appearance Ethyl Chloride Vinyl Chloride, ppm 2 MP + VDC, ppm Hexane Acid No. 1-2-DCEE, ppm 1-1-EDC, ppm 1-1-1-TCE + 1-1-2 TCE, ppm 1-2-EDC, ppm
/ Tri, ppm
Isobutane + Isopentane, %
TEL-OPERATIONS
C&C
99.21 Min.
100 Max.
400 Max.
200 Max.
10 Max.
150 Max. 150 Max. 150 Max. 150 Max. 150 Max.
0.7 Max.
) ) ) ) )
*Not more than 800 ppm combined.
)
November, 1981
VC4488
ETHYL CHLORIDE SPECIFICATIONS
Appearance Purity Acid, ppm HC1 Aldehyde, ppm Non-Volatiles, ppm Specific Gravity 00/4 C Color, APHA Water, ppm Boiling Range - C
SALES C&C
99.7% Min.
2 Max. 10 Max. 20 Max.
0.921 - 0.923 10 Max. 50 Max. 12.0 - 13.0
November, 1981
VC4489
METHYL CHLORIDE SPECIFICATIONS
Methyl Chloride Acid, ppm Dimethyl Ether + Methylene Chloride Acetone, ppm Ethyl Chloride, ppm Vinyl Chloride, ppm Acetylene, ppm Methanol, ppm Residue, ppm Water, ppm Boiling Rn-C (5-95) Appearance
Methyl Chloride Dimethyl Ether, ppm Vinyl Chloride, ppm Water, ppm Acid, ppm
^-SPECIFICATIONS
99.82 Min. 10 Max. 20 Max. 50 Max. 150 Max. 100 Max. 200 Max. 50 Max. 100 Max. 100 Max. -24.6 to -23.6 760 mm Colorless
96 .02 Min. 100 Max. 4500 Max. 100 Max.
30 Max.
November, 1981
VC4490
VINYL CHLORIDE SPECIFICATIONS
Appearance Acetylene, ppm Acidity, ppm Acetaldehyde, ppm Iron, ppm Peroxide, ppm Non-Volatiles, ppm Water, ppm Vinyl Acetylene, ppm Chloroprene, ppm 1-3, Butadiene, ppm Methyl Chloride, ppm Ethyl Chloride, ppm Vinylidene Chloride, ppm 1-1,EDC, ppm 1-2,EDC, ppm Total Chlorocarbons, ppm Vinyl Acetylene + 1-3 Butadiene
C & WW 2 Max. 2 Max. 5 Max.
0.!5 Max. 0.06 Max. 100 Max. 100 Max.
2 Max. 15 Max. 10 Max. 25 Max. 50 Max. 50 Max. 50 Max. 25 Max. 100 Max. 10 Max.
November, 1981
VC4491
PERCHLORETHYLENE SPECIFICATIONS
GENERAL CLASSIFICATION; CHLORINATED SOLVENT i
FORMULA: CC12 - CC12
Grade Dry Cleaning Industrial
Neutral Metal Degreasing
Appearance-------------------------------------------------- Clear, free from suspended matter----------------------------------------------
Odor---------------------------------- ------------------ ---------- Characteristic, mildly sweet----- ------- ------------------------------------ -
Residual Odor
None
Slight
Slight
Slight
Color, APHA Boiling Range at 760 mm Hg IBF-DP, C
15 max. 120-122
15 max. 120-122
15 max. 120-122
15 max. 120-122
Specific Gravity at 25/25C
1.617-1.621
1.617-1.621 1.610-1.619 1.617-1.621
Cloud Point, C
-5 max.
-5 max.
-5 max.
-5 max.
Free Halogens
None
None
None
None
Acidity (as HC1), wt % ^^lkalinity (as NaOH), ppm
None
None
7 min-20 max. 30 min-50 max.
None None
None 30 mln-60 max
..wn-volatile matter, wt%
0.0010 max.
0.0010 max. 0.0010 max.i 0.0010 max.
Stability with Copper Weight Loss, mg/24 hr
30 max.
-
-
-
Weight Loss, mg/72 hr.
-
-
5 max.
-
Acid Acceptance, wt % as NaOH
-
-
0.10 min.
0.13 min.
Important Notice
Although proper product quality requires that the stabilizer specifications be met, they are not to be used in published literature or revealed to customers.
Confidential Specifications Stabilizer Content (wt %)
Dry Cleaning Min Max
Industrial Min Max
Neutral Min Max
Metal Degreasing Min_______ Max
N-methylmorpholine, wt 7, 0.004 0.006 0.015 0.025 ---------------------- 0.015 0.025
xertamyl Phenol, wt % 0.0015 0.0025 0.0015 0.0025 0.0015 .0025 0.0015 0.0025
Methyl Pentynol, vt %
0.08 - .12
-
Epichlorohydrin, wt % November, 1981
0.30 - .40 0.30
0.40
VC4492
PERCHLORETHYLENE PURITY SPECIFICATIONS
Perchlorethylene Ll^ht Ends (DCEE, DCE, CHCl^, etc*) Carbon Tetrachloride Tri 1,1,2 Trichloroethane Dichlorobutadiene Monochlorobenzene U-Tetrachloroethane S-Tetrachloroethane Total Chlorocarbons
99.,75Z Min. 200 ppm Max.
50 ppm Max 500 ppm Max. 200 ppm Max. 500 ppm Max. 1000 ppm Max. 1000 ppm Max. 100 ppm Max. 2500 ppm Max.
November, 1981
VC4493
TRICHLORETHYLENE SPECIFICATIONS Formulai HCC1 CCl^
) Grade
Metal Degreasing High Pnrlty
Neutral Degr asing
Appearance
--Clear, free of suspended matter-------------------
Odor
-----Characteristic, mildly sweet-------------------
Residual Odor
None
None
None
Color, AFBA Boiling Range at 760 mm Hg IBP-DPC
15 max. 86.5-87.9
15 max. includingr87 ?0
15 max. 86.5-87.9
Specific Gravity at 25/25C Cloud Point C Free Halogens Acidity (HC1), wt Z Alkalinity (NaOH), ppm
1.450-1.458 -10 max. None None
7 min-20 max
1.460-1.464 -10 max. None None
7 mln-20 max
1.450-1.458 -10 max. None None None
Acid Acceptance (NaOH), wt Z
0.19-0.22
0.19-0.22
Non-volatile Matter, wt Z
0.001 max.
0.0007 max.
0.0010 max.
Stability with Copper
No discoloration
No discoloration
Spot Test (Residual Stain)
No spot
No spot
celerated Oxidation Acidity (BC1), wt Z
0.02 max.
Important Notice
Although proper product quality requires that the stabilizer specifications be met,
they are not to be used in published literature or revealed to customers.
Confidential Specifications
Stabilizer Content (wt Z)
Diisobutylene Butylene Oxide Ethyl Acetate N-methylpyrrole Epichlorohydrin Diisopropylamine para-tert-anyl phenol
Metal Degreasing Min Max
0.05
0.09
0.18
0.25
0.03
0.07
0.015
0.025
0.20
0.24
0.0025 0.0035
--
Grade High Purity Min Max ---_ --
--
0.0025 0.0035 - -
Neutral Degreasing Min Max
0.05
0.09
0.18
0.25
0.03
0.07
0.015
0.025
0.20
0.24
--
0.0025
0.0035
;
tfovember. 1981
VC4494
TRICHLORETHYLENE PURITY SPECIFICATIONS
Trlchlorethylene Ll^ht Ends (DCEE, DCE, 1 1--TCE, 6tc)
, Each Component Carbon Tetrachloride Bromo chloroethane 1,1,2 TCE Perchlorethylene Heavy Ends Total Impurities
99. 90% Min. 100 ppm Max.
50 ppm Max. 500 ppm Max. 500 ppm Max. 100 ppm Max. 200 ppm Max.
50 ppm Max. 1000 ppm Max,
November, 1981
VC4495
) D. I. I
SPECIFICATIONS
Color Acid Water Specific Gravity 20C
3.0 Max. A.S.T.M. 0.03Z Max. (HC1) 0.05Z Max. 0.960
)
November, 1981
VC4496
LEAD ALKYLS
i
i
VC4497
LEAD ALKYLS AREA MANUFACTURING SPECIFICATIONS
Sample
Analysis
Soap
% Soap
Hypo Reflux Water
% Thiosulfate
ppm Chromate pH
Pot Alloy
Total Sodium (Alkalinity)
Still Sludge
% TEL
Still Water
% Na (Alkalinity)
Bldg. Feed Tanks Rectified Tanks
Purity - Sp. Gr. % Acetone Water Content
Purity - Sp. Gr. % Acetone Water Content
Takeoff
Purity - Sp. Gr. Water Content
Column Feed
Purity - Sp. Gr. Water Content
Column Reflux
Purity - Sp. Gr. Water Content
EtCl - TEL Manufacture (Same as Bldg Feed Tanks)
Purity - Sp. Gr. % Acetone Water Content
Methyl Chloride
Purity Acid Water Vinyl Chloride Dimethyl Ether
Lead
Bismuth Copper As/Sb
Specifications
5.00 - 7.00%
30% Minimum
1000 Minimum 8.3 - 9.0
10.17% Target Set by Alloy Supervisor
<0.20%
<4.0%
99.0% Minimum 0.050 - 0.100
<150 ppm = <-30 C
99.0% Minimum 0.050 - 0.100 <150 ppm =<-30 C
96.0% Minimum <150 ppm s < -30 C
92.5% Minimum <-30 C
18 - 22% <-30 C
99.0% Minimum 0.050 - 0.100 <150 ppm = <-30 C
96.02 Minimum 30 ppm Maximum 100 ppm Maximum 4500 ppm Maximum 100 ppm Maximum
0.05% Maximum 0.05% Maximum 0.02% Maximum
October, 1981
VC4498
LEAD ALKYLS AREA BLENDER RAW MATERIAL SPECIFICATIONS
Sample EDC EDB Acetone
Toluene
*
Kerosene DTBP (65% Solution) IDP Ak33 or MMT (97.5%) AN733 TEL Washhouse
Fluid 99.6% Pure TML (80/20) Red Dye Orange Dye Rework Mix
Analysis
Sp. Gr. Acid No.
Sp. 'Gr. Acid No.
Sp. Gr. % Acid %h2
Sp. Gr. %H 0 B.PT
Sp. Gr.
Sp. Gr.
Sp. Gr.
Sp. Gr.
Sp. Gr.
Sp. Gr.
Sp. Gr.
No Analysis
No Analysis
% TEL Sp. Gr.
Specifications 1.245 - 1.260 20 C 10 Max. s 40 ppm 2.170 - 2.184 20 C 0.5 Max. a 2 ppm 0.791 - 0.793 20 C 0.004% Max. * 40 ppm 0.5% Max. S 5000 ppm 0.867- .005 @ 20 C 300 ppm Max. 110 C -2 0.810-0.005 @ 20C 0.912-0.005 @ 20C 1.173-0.005 @ 20C 1.360-0.005 @ 20C 0.941-0.005 @ 20C
1.650+0.005 @ 20C 1.586-0.005 @ 20C
No Specs No Specs
October, 1981
VC4499
LEAD ALKYLS AREA MISCELLANEOUS SPECIFICATIONS
_________ Sample Methylene Chloride
(Refrigeration) EtCl - Shipments
from Storage - TEL
MeCl Shipments
Dovtherm Sodium Containers
(Greek Tanks)
Analysis
______ Specifications
% Water (K.F.)
0.1% Maximum
Purity - VPC Acid No. Vinyl Chloride 2MP Vinylidene Cl Hexane Other C.H. Total Impurities
(above)
99.2% Minimum 10.0 Maximum 100 ppm Maximum 400 ppm Maximum 200 ppm Maximum 150 ppm Maximum
500 ppm Maximum
Purity - VPC Acid Water
Vinyl Chloride Dimethyl Ether
96.0% Minimum 30 ppm Maximum 100 ppm Maximum 4500 ppm Maximum 100 ppm Maximum
Engler Residue
5Z Maximum
Water Content
4 mg/Cu. Ft. Maximum
October, 1981
VC4500
SODIUM
VC4501
n
A
A
SODIUM MANUFACTURING SPECIFICATIONS
Sample____________ Raw Brine S-Tanks
T-Tanks
Sodium
/
Tailpipe Water
Condenser Supply Water
Condensate Water
Nash Pump Acid
Weak Sulfuric
Strong Sulfuric (Incoming)
Refined Salt
Air Nitrogen Liquid Chlorine Sodium Vacuum Containers
Analysis
X CaSO. pH Specific Gravity @ 25C Color
X BaCl_ X CaSOT pH 4 Specific Gravity @25C Appearance
X BaCl2
X CaSO. pH Specific Gravity @25C
X Ca
X NaCl
X NaCl
X NaCl
x h2so4
z h2so4
x h2so4
X Water X Fe 0 X Na2,SO4. Water Content
Water Content
ppm NCl^
Water Content
______ Specification
0.215X Maximum 7.0 - 8.0 1.185 Minimum Clear to Greenish
0.005 - 0.020X Nil 7.0 - 8.0 1.185 Minimum No. Spec.-Typically
clear to greenish
Observed Qualitatively At Present - Light, Medium or Heavy
Nil 7.0 - 8.0 1.185 Minimum
0.045X Maximum
0.05X + C.S.W. X Maximum
0.05X Maximum
0.05X Maximum
94.OX Minimum
80.0 - 85.OX
97.5X Minimum
0.10X Maximum 0.002X Maximum Nil
1.0 mg/cu. ft. Maximum
1.0 mg/cu. ft. Maximum
0.5 ppm Maximum
4.0 mg/cu. ft. Maximum
November, 1981
VC4502
Sample
Air for Drying Chlorine Production Equipment
Atmospheric Tests
Analysis
Water Content
X Oxygen X Combustibles
ppm Chlorine
Specification
75.0 mg/cu. ft. Maximum
19.5% Minimum 20.OX LEL Maximum 1 ppm Maximum
November, 1981
VC4503
ATMOSPHERIC TESTS
VC4504
.
-..vrv'-T";
.
1
ATMOSPHERIC TESTS
; Environment to hfe Sampled
Required Analyses
Specifications
1. Enclosed Area Entry 2. No Air Contamination 3. No Flame to be Used
1. Oxygen Content
1. 19.5% Minimum Less than 19.5% Ojj fresh air supply required.
1. Enclosed Area Entry 2. Flame to be Used 3. No Air Contamination
1. Oxygen Content
1. 19.5% Minimum Less than 19.5% 0^ fresh air supply required.
2. % Combustibles 2. Less than 20% LEL.
1. Enclosed Area Entry 2. Lead in Air Possible 3. No Flame to be Used
/
1. Enclosed Area Entry 2. Flame to be Used 3. Lead-in-Air Possible
1. Oxygen Content 2. Lead-in-Air
Concentration
.1 Oxygen Content
1. 19.5% Minimum Less than 19.5% O2 fresh air supply required.
3 2 microgram/ft no respiratory equipment required. Between 3-14, microgram/ftJ -
double cartridge respirator required. Between 15-50 microgram/ft-3-
fresh air supplied mask required. Above 50 microgram/ ft13-* Special
permission and cleanup required.
.1 19.5% Minimum
Less than 19.5% O2 fresh air supply required.
2. % Combustibles
3. Lead-in-Air Test
2. Less than 20% LEL.
3. 2 microgram/ft^no respiratory equipment required. Between 3-14 microgram/ft3double cartridge respirator required. Between 15-50 microgram/ft^-
VC4505
ATMOSPHERIC TESTS (continued^
Environment to be Sampled
Required Analyses
Specifications
.1. Enclosed Area Entry
2 Cl2-in-Air Possible
1. Oxygen Content
fresh air supplied mask required. Above SO microgram/ ft^- Special permission and cleanup requlr d.
1. 19.57. Minimum Less than 19.5% O2 fresh air supply required.
1. Enclosed Area Entry 2. Vinyl Chloride in Air
2. Chlorine Concentration
1. Oxygen Content
2. Less than 1 ppm without protection.
1. 19.5% Minimum Less than 19.5% O2 fresh air supply required.
2. Vinyl Chloride Concentration
2. Less than 1 ppm without protection.
1. Flame to be Used in Open Area
1. % Combustibles 1. Less than 20% LEL.
1. Enclosed Area Entry 2. Carbon Monoxide
Possible
1. Oxygen Content
1. 19.5% Minimum Less than 19.5% 02 fresh air supply required.
2. CO Concentration
2. Less than 50 ppm for entry without protection.
May, 1982
VC4506