Document RJvYyDEYj4rBYyb1w1b0mBRGa

Report No,: FC-71-2 E. I, du Pont de Nemours & Company . P. & F. Research & Development Division Marshall Research and Development Laboratory Report 392 LINE INTRA-PLANT COLOR REPRODUCIBILITY Date Issued: 7/30/71 Period Covered: 1970 Project Nos, .6lit0 97 Previous Reports: None Notebooks: None ABSTRACT This report discusses the intra-plant color variations for fifteen 392 Line Lucite Wall Paint colors. The results of this study initiated changes in color approval limits which are also discussed. PREPARED BY: N 29335 MEMORANDUM REPORT INSTRUMENTAL COLOR TECHNOLOGY 392-LINE INTRA-PLANT COLOR' REPRODUCIBILITY The objective of this study is to' determine the inter- \ plant ^reproducibility in manufacturing 392-Line Lucite Wall - \ Paint ~colorsT The~~FS1fults of this study will, be usecTTo \ ^gi'ard^'ihdfVidual offset values from each plant and recommend/ revisions when necessary. DISCUSSION The 392-Line is dependent on the use of offsets for color control because of the poor physical and color durability of its color standards. The offset porcelain provides a permanent anchor from which the relative color position of the standard and subsequent batches can be ascertained instrumentally. This color measurement technique does not allow batch and standard to be compared visually to insure the correct color Is being manufactured. Additionally, the use of offsets requires each plant to make its own color measurements according to. an established STP, and the procedure requires very carefully prepared color measurements. Because of the inherently difficult nature of establishing offset values, C.O.S. decided to test the interplant reproducibility of the 392-Line. Since master batch panels for many of the 392-Line colors are so old they cannot be used for visual comparisons, the plants were judged relative to each other. C.O.S. felt that if all the plants were relatively close in color, the offsets for the batch are probably correct and the color match to. standard is also acceptable.' If a plant is unique in its color position with respect to the group, it has made an error in making its offsets and adjustments are required. If none of the plants agree, the offsets must be investigated. I DUP030000815 Each, of the 392-Line.manufacturing plants---Philadelphia, Tucker, Port MadisonChicago, and San Francisco---v/as asked , to supply a representative sample of their production for each color. After the samples were compared by visual inspection for color, instrumental measurements were made. The panels were than reviewed by 0,R. Volk of the Consumer Paint Group for color. If the color from a particular plant was judged as unacceptable, this, plant was asked to submit a new sample to determine if the color difference was real or a sampling error. ,A summary of results is listed below, but an important point to note in reviewing the data is that the actual point where the consumer would object to the color difference was unknown to us. 0.R. Volk was used as the "typical consumer" but he had no real' data to support his opinion. An objective to define an acceptable color tolerances from the consumer viewpoint is needed. DUP030000816 Conclusions 1. The data presented indicates that the offsets controlling the color of the 392-Line provide acceptable plant to plant uniformity for the samples evaluated. 2. The color limits for production control require examination and revision. L 3. The offsets provide numerical, color differences which correlate well with the visual interpretation of those color differences. 4. A definitive study of customer reaction to color difference is required to provide a guide in the establishment of production color limits. Action Taken or Proposed 1. . The color limits for the 392-Line and corresponding 394-Line were reviewed and revisions have been made. See Appendix I. 2. The results of this report have been presented to Marketing, Marshall Laboratory, and Manufacturing Personnel. `i 3 A consumer test to determine acceptable color differences should be made by Marketing. 4, The remaining 392-Line colors should be evaluated. Plants should be asked to supply their passing readings for each batch sent. 4 DUP030000817 392-601 White Visual* = San Francisco and Fort Madison are ye1low. Commercially acceptable. . Instrumental** = San Francisco is yellower than the division.. There is a large 'range in lightness for the division. Limits = Satisfactory. CODE 392-601 G' R B AL Aa Ab STD 1-P006-7 90.45 90.78 88.93 ' PH I LA... 2788 90.07 90,42 88.18 -0.16 -0,27 O i--| o ! TUCKER CHICAGO 411214 . 88.63 88.80 87,59 ` 87.83 87.39 , -O'. 77 85.89 -1.21 -O.13 -0.20 -0.19 . +0.15 F..M. S.S.F. ' 387161 393151 88.17 90.08 88.77 91,18 . 86.59 85.85 -0.96 -0,16 +0.26 +0.13 +0.06 +1.95 * OR Volk's visual comments *.* All numerical values were measured against Philadelphia Plant porcelain standards. -< DUP030000818 392-602 Mission Ivory Visual = Tucker is red. All except Tucker are commercially acceptable. Instrumental = Tucker is red and dark Chicago is yellow Limits = Unacceptable (Too Small) CODE 392-602 G R B AL Aa Ab STD 4-P002-7 70.87 75.94 53.86 PHILA. 0046 69.83 74.77 52,45 -0,51 -0.15 +0,04 TUCKER . 393.976. 68.54 74,12 51.62 -1.16 +0.92 +0.31 CHICAGO' F.M. S.S.E. 454248 386895 393179 69-54 70.72 69.88 74.63 76.01 75.07 51.47 52.90 52.30, -0.66 -0.07 -0.49, -0.39, . +Q.03 -0.02 +1.30 ; +0.83 +0.74 DUP030000819 392-6l8 Spring Green Visual - Fort Madison and San Francisco are yellow. All are commercially acceptable. Instrumental = San Francisco and Fort Madison are yellower than the division. Limits = Satisfactory. CODE 392-618 G R B AL Aa Ab STD - 7-P006-7 69,2k 63.44 56.45 PHI LA., .2066 67-76 61.59 55.38 -0.7 9 -0,54 -0. 29 TUCKER 384219 69.01 63.07 57.03 -0.12 + 0.08 -0.75 CHICAGO F.M. ,4723813 . 387176 68.49 68.50 62.58 62.73 56.23 55.34 -0.38 - -0.37 -0.08 -0.23 -0.42 +0.45 S.S.F. 411976 69.50 63.49 56.67 +0.13 -0.35 +0.01 Is DUP030000820 392-620 Alice Blue Visual = Fort Madison is clean and blue; S,an Francisco is green. All are commercially acceptable. Instrumental = Fort Madison is light and blue; San Francisco is yellow, ^ Limits = Satisfactory, , CODE 392-620 G R B Lh ' ia &b STD 5-P004-7 59.00 51.18 71.58 PR I LA. 0036 58.66 50.82 70.93 -0.19 -0.23 + 0.22 TUCKER . 365166 59.17 51.44 . 71,68: +0-.09 +0.16 +0,08 COM O i CHICAGO 377177 58.96 50.86 72.08 -0.29 -0.45 F.M. ' 377177 59.95 . 51.52 74.12 + 0.53 -0.31 -1,18 S.S.F. 373816 59.48 51.78 71,02 +0.27 -0.22 +0.91 * Visual shaders often describe a color as green which numerically is yellow. '' .. '. .. ~4t DUP030000821 395-623 Candy Pink Visual - Philadelphia is dirty and yellow. All except Philadelphia are commercially acceptable. Instrumental = Chicago and Philadelphia are green compared to the division. Philadelphia is also dark and yellow. Limits = Unacceptable (Too Large) CODE . 392-623 G R B AL Aa' Ab STD 3-P013-7 67.85 78.85 58.74 PHILA. .1239 65.83 75.67 55.85 -1.03 -1.97 +1.01 TUCKER 374364 68.14 78.77 59.06 +0.15 -0.62 -0,05 0 H O 1 CHICAGO 67.66 77.44 ,, 58.43 -1.97 +0,13 P.M, 358991 68.60 79.42 59-22 +0.38 -0.49 +0.19 DUP030000822 392-630 'Antique White . ' Visual = -Chicago Is green. Fort Madison is red. All are commercially acceptable. Instrumental = Chicago is dark and yellow. Fort Madison, is red, ' Limits = Satisfactory. v CODE 392-630 G R' . . B, AL Aa Ab STD 1-POO4-7 76.67 79.92 63.92 PHILA. 00-43 74.83 77.79 62.23 -0.87 -0.47 -0.05 TUCKER ? . 75.62 78.87 62.14 -0.49 -0.29 +0.76 CHICAGO 401310 73.26 76.45 59-84 .-1.62 -0.36 + 0.-97 F.M, 387235 76.05 79.63 63.08 -0.29 +0.43 + 0.26 S.S.F. 393154 74,63 77,99 62.17 -0,96 +0.29 -0,05 % DUP030000823 392-638' Autumn Gold * Visual = Fort Madison is clean. All are commercially acceptable. Instrumentally = Fort Madison is light and yellow compared to the division. Limits = Satisfactory. v CODE STB . PHILA. 392-638 6-P0li|-7 2121 G 59.37 59.82 R' 66.52 . 66.9I B 33.82 33.81 AL +0.24 Aa fib s ' * '''' -0,33 > +0.43 . - TUCKER F.M. ' S.S.F. 345142 358922 450118' 60.69 62.19 60.59 67.67 69.92 67.84. 34.38 .34.52 34.61 + 0.73 +1.54 +0.67 -0.68 + 0.05 -0.03 ^+0.46 ' -+1..63 ' + 0.07 CHICAGO'. 60.89 68.43 34.29 +0.83 +0.02 + 0.77 DUP030000824 392-640 Spring White Visual = Chicago and Port Madison are too green. All except Chicago are commercially acceptable. Instrumentally = Chicago and Fort Madison are yellow. Chicago is also dark. Limits - Unacceptable* (Too Large) CODE 392-640 G R BAL Aa Ab STD 1-P006-7 87.16 86.02 85.17 PHILA. 352045 87-74 87.09 85.21 + 0.25 + 0.52 + 0.39 TUCKER 365087 87.52 86.54 85.45 + 0.15 . +0.21 + 0.05 P.M. 377197 85.86 84.85 83.08 -0.5,6 -0.12 + 0.60 S.S.F. 383647 86.71 86.04 84.14 -0.19 -0.46 -0.43 CHICAGO 83.77 83.04 79-00 -1.47 -0.49 +2.14 1 -f DUP030000825 392-643 Pink Champagne Visual = San Francisco is too dirty. AH except Sari Francisco ape commercially acceptable. Instrumental = San Francisco is dark, green, and blue compared to the division. Limits -Unacceptable (Too Large) CODE 392-643 G R B AL Aa Ab STD 3-P025-7 72.26 81.23 59-54 PHILA. 2616 74.03 82.76 60.52 , +0.85 -0.82 +0.53 TUCKER 440576 72,77 81.52 . 59-64 .+0.25 -0.54 + 0.32 0 CM 0 1 S.S.F. 440181 71.84 80.10 58.49 -1.33 -0.64 CHICAGO 72.20 80.73 59.95 -0.03 -0.66 -0.06 `*V 'I DUP030000826 392-652 Celery Visual = All colors match. All are commercially acceptable. Instrumental = No trend. Limits = Unacceptable (Too Small) . ' CODE 392-652 G R B AL Aa Ab STD PHILA. 7-P010-7 78.4.5 2134 77.16 79.10 58.44 77.85 58.18 -0.60 +0.40 ' -0.75 TUCKER 393962 74,86 75.85 . 55.69 ' -1.68 +0 . 68 -0.19 P.M. 386786 76.43 77.00 56.84 -0.94 -0,68 -0.06 10 0 ro .S.S.P. 402$43 ' 78,41 79.29 58.28 +0,32 +0.12 CHICAG*O 75.68 76.62 55.73 -1.29 +0,03 + 0.42 - DUP030000827 / 392-663 Dove Blue Visual - Philadelphia is too green. All are commercially acceptable. Instrumental = Philadelphia is greener than the division. V.. Limits = Unacceptable (Too Large) ' CODE 392-663 G R B A Ij Aa Ab STD 5-P024-7 68.00 62.81 80.39 PHILA. 2997 68,01 62,45 80.26 +0.01 -0.70 +0.11 TUCKER ' F,M. S.S.P. 365256 358325 354975 68.54 69.16 . 69.43 . 63.30 80.68 63.90 .81.61 64.15 82.12 +0.93 +0.58 +0.72 -0.39 -0,05 ,+0.02 + 0.16 +0.06 ' -0.10 0 -cr 0 1 CHICAGO: 68.01 62,65 8.0.15 .+0.01 +0.19 k DUP030000828 392-664 Robins Egg Blue Visual = Chicago is green.. All are commercially acceptable! Instrumental = Chicago is dark, green and yellow compared to the division. Limits = Satisfactory, v' CODE 392-664 G R B AL Aa Ab STD 5-P008-7 81.50 75.22 88.05 PHI.LA. 351383 82.07 75-47 89.41 +0.26 -0.16 ' -0.54 TUCKER 355472 82.00 75.82 88.41 + 0.22 +0.13 + 0.12 F.M. S.S.P. 368324 . 364487 83.52 82.27 76.-94 75.73 . 90.27 89,34 +0.90 . +0.34 -0.26 -0.16 . 10 0 -3 -0.34 CHICAGO 80.67 . 74.19 86.14 -0.37 -0,79 +0.75 DUP030000829 392-665 French Violet ' Visual = Fort Madison is blue. All except San Francisco are- commercially acceptable. Instrumental - Fort Madison is green and blue. is yellow. V.. Limits - Unacceptable. (Too Large) San Francisco CODE 392-665 G R B AL Aa Ab STD PHILA. 5-F015-7 ' 340009 60.83 61.09 58.70 59-02 71.76 72.09 + 0-14 +0.14 *0.03 TUCKER 355315 61,65 ' 59.38 72.79 + 0.44 . -0.18 -0.09 F.M, 358316 61.16 58.65 72.63 + 0.18 -0.45 -0.4l S.S.F. 354973 60.92 59.25 70.87 + 0.05 + 0.39 + 0.81 CHICAGO 60.80 58.33 . 71.73 -0.02 -0.62 +0.00 * DUP030000830 392-666 Crocus Vi sual Tucker is blue.I All are commercially acceptable.. Instrumental = Tucker is blue , San Francisco is light. Limits = Unacceptable. (Top Small) CODE 392-666 G R B AL Aa - Ab ' ' STD 6-PORR--7 7,3.60 75.67 ' 81.27 *. s PKILA. 352983 74.61 76.86 81.88 +0.48 +0.07 '+0.35 TUCKER 355318 73.14 74.93 81.82 -0.22 -0,02 -0,78 . F.M. S.S.F. 358695 354440 73.79 76 . TO 75.99 81.86 78.29 84.02 ' +0.09 +0.35 .+1-.19 +0.15 -0.29 -0.06 CT\ O O 1 CHICAGO 73.41 75.26 80.95 -0.39 +0.09 DUP030000831 ' 392-667 Jade Mist . -. ,_ Visual - All samples are commercially acceptable. Instrumental = Chicago is blue and red. Limits = Satisfactory. CODE 392-667 G R .. B AL Aa Ab STD 7-P009-7 76.95 76.10 '67.36 PHILA. 1395 79.00 78.08 ' 69.73 +O..94 + 0.10 -0.41 TUCKER 355563 78.59 77.59 : 68.73 +.0.7-6' -0.27 + 0.11 S.S.P. 364439 78.55 . 77.63 68.72 +0.74 -0.13 +0.09 CHICAGO 77.30 76.42 68.99 + 0.16 +0.48 -1.11 DUP030000832 Appendix- I 392-Line and 394-Line Color Limits As a result of a color study in which all 392-Line Lucite Wall Paint manufacturing plants submitted samples of their production to C.O.S. for fifteen colors., the ' color limits for each code in the study were reviewed. Five codes had their limits reduced while three codes had their limits increased; seven codes remained unmodified. These new limits proposals were presented by C.O.S. to both Manufacturing and Marketing personnel and they have been accepted for the. 392-Line and the corresponding 394-Line codes.. . New colors developed in similar color ranges will also use the new color limits. NEW 392-LINE AND 394-LINE COLOR LIMITS CODE NAME AL Aa. Ab 392-640 392-623 392-643 . 392-665 392-663 392-602 392-652 ' 392-666 Spring White Candy Pink Pink Champagne French Violet Dove Blue Mission Ivory Celery Crocus + .35 + -35 + .35 -35 + .35 -40 + .4 + .40 *30 + .20 .25 i *4o + .30 + .40 +; .40 + .40 + . 40 + .40 .40 *+ .30 ' + ,40 .45 + .45 ' + .40 DUP030000833 392-663 Dove Blue Old Limits .35 + .40 + .40 AL Aa .AL New Limits + .35 + .30 + .40 DUP030000834 i .^0 40 Aa At) ' + ,30 + .Ho I DUP030000835 35 i ' *0 AL + . 35 Aa + .20 Ab + . ijo DUP030000836 -35 ^0 i 1,0 AL + .35 Aa + .25 Ab + .40 -f DUP030000837 392-665 French Violet M ab Old Limits t -35 AL i v^O Aa Ab New Limits + .35 + ,4o + .30 DUP030000838 Old Limits .35 + . -40 + .4o 1 AL A a 1. At) ' * New Limits 4* .40 .40 + .45 DUP030000839 LL Old. Limits + . 35 i -.W ; + .40 flu AL Aa Ab New Limits + .40 + .40 + .45 DUP030000840 35 *1,0 t -^o i, AL Aa Ab + . 1| 0 + .ijo + .Ij o -I . DUP030000841 DISTRIBUTION. ._ Copy Number R.- S. Prengle, Wilmington . .. . Is - R. W. Laurell, Wilmington . 2* H.-S, Wellman, Marshall Laboratory 3* J, 0: Graves., Wilmington ' '. . 4* W. S. Culliton, Wilmington . 5* E. T, Breuer, Wilmington . 6 W. H. Beutel, Philadelphia 7 R. H, Clarke, Tucker 8 C. H. Thompson, Port Madison 9 K. E. Ackley, South San Francisco ' 10 R. A, DeWall, Chicago 11 T. R. Matthews, Wilmington 12 E. H. Berg, Marshall. Laboratory 13 K. A. Saegebarth, Marshall Laboratory : 14 P. I. Poindexter, Wilmington 15 W. S. Zimmt, Marshall Laboratory 16 S. Hochberg, Marshall Laboratory 17 J, R. Huntsberger, Exp, Sta., Wilmington 18 J. R, Chalmers, Marshall Laboratory 19 N. G. Fisher, Exp, Sta,, Wilmington . 20 Central Report Index, Wilmington (2) ' 21 - 22 /Marshall R&D Laboratory Library (5) - _________________ 23 - 27 C. E. DeBoer, Marshall Laboratory .. 28 M. P. Morse, Marshall Laboratory 29 Manager, DuPont Mexico 30 A. B. Castanes, DuPont Venezuela 31 E. Marvonek, Exp. Sta,, Wilmington . 32 J. M. Donatello, Flint 33 C. N. Swinehart, Flint 34 F. M. Gavin, Flint 35 G. E. Lewis, Wilmington 36 A. G. Armour, Marshall Laboratory . , 37 A, L. Becton, Marshall Laboratory 38 R. H, Vining, C.0.S., Philadelphia 39 W. A. Balloon, C.O.S., Philadelphia 40 S. N. Kelly, Wilmington 4l Flint Laboratory Library k2 * These copies contain color chips. DUP030000842