Document RJvLYrL9JK56ERB9qexYvYYda
U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration
r<m Apprxra
OMP N*. 44.A]J?
i MATERIAL SAFETY DATA SHEET
Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 191G. 19171
SECTION 1
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
Uniroyal Chemical - Division of Uniroyal, Inc.
203/723-3000
AOORESS (Sumbcr. Street, City, Slate, end ZIP Code)
Elm St. - Naugatuck. Connecticut_06770
CHEMICAL NAME ANO SYNONYMS
Polvvinvl Chloride. PVC
1
CHEMICAL FAMILY
Polvmerized chlorinated hydrocarbon
TRAOE NAME ANO SVNONYMS
MARVINOL 22
FORMULA {_H2CCHC1)n
__
SECTION II HAZARDOUS INGREDIENTS
paints, preservatives. & solvents FIGMENTS
X TLV
tUninl
ALLOYS ANO METALLIC COATINGS
BASE METAL
CATALYST vehicle SOLVENTS AOOlTIVES
ALLOYS
METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS
OTHERS
'"HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR GASES
TLV
% (Units!
i TLV
X (Units)
URL 00805
NOTE:
May contain trace amounts of vinyl chloride monomer. *0SHA Regulation #1910.93q sets lppm TLV limit.
OILING POINT (*F.) VAPOR PRESSURE (mm H.) VAPOR DENSITY (A|R*1) # SOLUBILITY IN WATER APPEARANCE ANO OOOR
SECTION III - PHYSICAL DATA
HA NA HA
SPECIFIC GRAVITY (H,OM)
PERCENT. VOLATILE BY VOLUME ()
EVAPORATION RATE
1 -1)
insolub] e
White powder with no significant odor
1.4 HA HA
_
PLASH POINT
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
utcdj
NA
FLAMMABLE LIMITS
UM
EXTINGUISHING MEOIA
Water spray
SPECIAL FIRE FIGHTING PROCEDURES Respiratory protection may be needed due to
release of corrosive gases under fire conditions.
UNUSUAL FIRE AND EXPLOSION HAZAROS
CoBDsive gases may be liberated under intense heat conditio is
pace m
(Continued on reverse side)
Form OSHA-20
Rif. Mir ts
r SECTION V HEALTH HAZARD DATA MARVINOL* 22
THRESHOLD LIMIT VALUE
OSHA. STD. (#1910.93q) sets 5 ppm ceiling and
EFFECTS OP OVEREXPOSURE
___________1 ppm TLV for vinvl chloride monomer
No adverse effects
known associated with handling or use a Maryjnol 22._______
EMERGENCY AND FIRST AIO PROCEDURES
URL 00806
STABILITY
UNSTABLE
SECTION VI REACTIVITY DATA
CONDITIONS TO AVOIO
STABLE
INCOMPATABILITY (Material! to avoid}
--X.__
HAZARDOUS DECOMPOSITION PRODUCTS
HAZARDOUS POLYMERIZATION
MAV OCCUR WILL NOT OCCUR
CONDITIONS TO AVOID
SECTION VII * SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Sweep up powder and discard,
WASTE DISPOSAL METHOD
Sanitary land fill
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specif* type1
Dust niasx advised.
VENTILATION
LOCAL EXHAUST
(mechanical General)
Monitor workplace for VCM ia air.
SPECIAL
OTHER
PROTECTIVE LOVES OTHER PROTECTIVE EQUIPMENT
EYE PROTECTION
Refer tO #1910.93q*
Goqqles
i
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store in wel1-ventH1atpd area.
Any intensive mixing operations should be equipped with efficient
OTHER PRECAUTIONS
exhaust ventilation.
PAGE (2)
form OSHA-20
Rw. May 72
aL--------
unkujyal
Trade Names Uses: Chemical Name:
DATE: February 23, 1972
UNIROYAL CHEMICAL Division of UN I ROYAL Inc. Elm Street Naugatuck, Connecticut 06770
SS-78-S241
PRODUCT SAFETY DATA SHEET
MARVIN0L*50
Blending resin
Polyvinyl Chloride
URL 00807
Chemical and Physical Prooerties
Appearance:
White powder
Melting Point: Solubility s
Will so/ten when heated Insoluble in water
Specific Gravity:
1.4
Corrosivity: Volatility:
Not corrosive Not volatile
Fire and Explosion Hazard
Flash Point:
NA.
Autoignition Temperature: NA
Special Decomposition/Reactivity Precautions: None
Fire Fighting Media and Procedures: Water spray
NOTES: Corrosive gases *tay be liberated under burning conditions*
4` PRODUCT SAFETY DATA SKSST (Cont.)
Health Related Data . Specific Hazard:
None
Handling Precautions: ......
None
MARVINOL50
' %
First Aid Procedures:
None
2.
Toxicology Background:
Synthetic polymer generally recognised . as being physiologically inert*
URL 00808
Storage and Waste Disposal
Storage:
Store in cooly dry place*
Cleanup:
May be swept up.
Disposal:
f
Sanitary landfill.
Data Supplied Ey: R. J. DCMLING
URL 00809
C
Trade Name: Uses: Chemical Name:
CATE
November 17, 1972
UNIROYAL CHEMICAL Division of UNIROYAL. Inc. Elm Street Naugatuck. Connecticut 06770
203-729-S241
PRODUCT SAFETY DATA SHEET HARVINOL 56 Blending resin Polyvinyl Chloride - Polyvinyl Acetate Resin
Chemical and Physical Properties
Appearance:
White powder
Melting Point: Solubility:
Will soften when heated Insoluble in water
Specific Gravity: 1.38
Corrosivity: Volatility:
Not corrosive Not volatile
Fire and Explosion Hazard
Flash Point:
NA
Autoignition Temperature:
NA
Special Decomposition/feeactivity Precautions: None
Fire Fighting Media and Procedures: Water spray
NOTES: Corrosive gases may be liberated under burning conditions.
\
V
PRODUCT SAFETY DATA SHSET (Cont.)
Health Related Data Specific Hazard:
None
Handling Precautions:
None
MARVINOL 56
2.
First Aid Procedures:
None
Toxicology Background:
Synthetic polymer generally recognized ' as being physiologically inert.
(
URL 00810
Storage and Waste Disposal
Storage:
Store in cool, dry place,
Cleanup:
May be swept up
Disposal:
c
Sanitary landfill,
Data Supplied By:
R. J, DOWLIIC
U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration
MATERIAL SAFETY DATA SHEET
WWp nO
,
I J| r
Required under USOL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916. 1917)
\ ^
SECTION 1
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
Uniroyal Chemical - Division of Uniroyal, Inc.
203/723-3000
aoopcss ISumber, Street. City. State, and ZIP Code} Elm St. - Naucratuck. Connecticut 06770
.
CHEMICAL NAME AND SYNONYMS
Polvvinvl Chloride. PVC
I
TRADE NAME AND SYNONYMS
MARVINOL 5051
chemical family
formula
(^H2CCHC1)n
Polvmerized chlorinated hvdrocarbon
SECTION II - HAZARDOUS INGREDIENTS
PAINTS. PRESERVATIVES. & SOLVENTS
PIGMENTS
TLV
% (Unitt!
ALLOYS AND METALLIC COATINGS
BASE METAL
CATALYST VEHICLE SOLVENTS ADDITIVES
ALLOYS
METALLIC COATINGS
FILLER METAL PLUS COATING OR CORE PLUX OTHERS
OTHERS
HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLtOS. OR CASES
TLV
% (Units)
TLV
% * (Units)
URL 00811
NOTE: May contain trace amounts of vinyl chloride monomer. "
BOILING POINT (*F.J VAPOR PRESSURE (mm H.) VAPOR DENSITY (A|R1J ^ SOLUBILITY IN WATER APPEARANCE AND OOOR
SECTION III - PHYSICAL DATA
NA NA NA
SPECIFIC GRAVITY <HsOl)
PERCENT. VOLATILE BY VOLUME (nj EVAPORATION RATE
t
insolubl e
White powder with no significant odor
1.4 NA NA
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
PLASH POINT (Mttnod wud)
NA
FLAMMABLE LIMITS
Ltl U1
EXTINGUISHING MEOIA
Water spray
SPECIAL FIRE FIGHTING PROCEDURES Respiratory protection may be needed due to
release of corrosive gases under fire conditions.
UNUSUAL FIRE AND EXPLOSION HAIAWOS
* ' Conosive gases may be liberated under intense heat conditio is
PACE (1)
(Continued on reverse side!
Form OSHA-20 fta*. Mir n
' * SECTION V - HEALTH HAZARD DATA MARVINOL 5051
thresholdumi:value
oSHA Emergency Temporary Std. (#1910.93q) set 50 ppm
EFFECTS OF OVEREXPOSURE
ceiling for vinyl chloride monomer. No adverse effects Known
associated with handling or use of Marvinol Z2-.
EMERGENCY ANO FIRST AlO PROCEDURES
**
.
STABILITY
UNSTABLE
SECTION VI REACTIVITY DATA
CONDITIONS TO AVOIO
stable
INCOMPATABILITY (Mstenelt to aroutj
X
HAZAROOUS DECOMPOSITION PAOOUCTS
HAZAROOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOIO
X
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEO
Sweep up powder and discard.
WASTE OI5POSAL METHOD
]
c
r* C3 o 09
ISJ
Sanitary land fill.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify t>PtJ
Dust
advised
VENTILATION
LOCAL EXHAUST
.^
SPECIAL
mechanical (General}
OTHER
_____________ 1
e
PROTECTIVE GLOVES
EYE protection
Goggles
OTHER PROTECTIVE EQUIPMENT
.
SECTION IX * SPECIAL PRECAUTIONS
PRECAUTION* TO BE TAKEN IN HANDLING ANO STORING
Store in well-ventilated area.
Any intensive mixing operations should be equipped with efficient
other precautions
exnaust ventilation.
PAGE (2) ro
*
Form O5HA-20 Rn.wiyM
1* ;
Trade .Name': Uses:
* .Cheaical Name:
BATE: 'February 23, 1972
UNIROYAL CHEMICAL'-^
Division of UNIROYAL, Inc. . Elm Street Naugatuck Connecticut C6770 ?ta-72s-53U .
PRODUCT SAFETY DATA SHEET -
- -7 - -- .
t-- .---------------------------
. '
' /,
If/-*-
^ - 1" . *. *r#
MAR VTNOL^S800 .
V
Blending resin
j`: -J`i;
: Polyvinyl Chloride
Cheaical and Physical Properties - ~
Appearance:
White powder
Melting.Point: Solubility:
Will soften when heated Insoluble in water
{ Specific Gravity: ` 1*4
.L*O;'..: ` '-
.
Corrosivity: v. Volatility:
Not corrosive Not volatile
.
.-
v
Fire and Explosion Hazard
Flash.Point:
' HA .
. ;?;>.. v," ' y.
Autoignition'Temperature : NA Special Deccsposition/Reactivity Precautions: None
Fire Fighting Media and Procedures: Water.spray
;
NOTES: Corrosive gases may be liberated under burning conditions* Product is self-extinguishing*'.
- '
:V-.
URL 00813
*'
'
s
. PftODlKTT yATKTY DATA SHHrtT (Cont. )
f Health Related Data: ; :Specific Hazard
None
MARVINOL5600
Handling Precautions:
None
First Aid Procedures:
None
Toxicology Background:
Synthetic polymer generally recognized as being physiologically inert.
URL 00814
Storage and Waste Disposal
Storage:
Store in cool9 dry place.
Cleanup:
May be swept up.
Disposal;
Sanitary landfill.
-V/-V; '
.v'
Data Supplied Gy s R. J. DCWLING