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A lead mine in the Cow d*A true district of Idaho.
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USEFUL INFO
Published b
Lead Industries
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K*r full analyses. J. Inti. Mrttih. 1:ij <h . MO. 11.1. Table I.
1 l^knur nmruinim brnss a* stuiniar.i n iii*- it lost the >mne prrrrntatrr amount in wnchl u% tin- wrought iron* taken t standard in tin* sea-aclmii ii*l% at Weston
l ( alcululed (ruin data m Table 111.. J.
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it**
-% s
5
I-
? Li
fT
Ef
-- s= y T"
r 5?S =If?! -=2 5 f : i;i-i.! = = -
2. 2 ^ r. . " - 2. 2 "* - -
wuuI,?r s f Iri.f 1.1
1-ilalii
=- = 1=15^ 6 -5 ! 3 S r* e --- ,
2 2, =:^ cn 2...: ^ 12 =:_- s =r -
= < = ' 2 = ** -rlr-rlL; = r 7 " ~ ^
_ -sCR -- -- V- 5 "^_ 1 = -'
2. 15 Ifl
=`1 2 2.=.
If r r?s!?i; ?-"r.55Tr2-
II: S|i
3 i 55:3i.1.
~ 3 2.ir? S.Sg-1
I |?=fllJII
i iP'l
1 ?3Sh2rSi
ff
I"
"
I'
?r?r
s * ---
=
=' = '
:::K->. *
/
--
=/ .
=
*
r
J. 11
i
-
. . 5' " *
Nil
- - sr r-
ll
vT = =:
lag'i ss? asH
a
is^s^:s55fsEsas
sssks
5* T
-
XZ'iS S tiBo
-
I
?
e S' 5
Ir
IH^
Es.il I.
' = 3"
= 3 :y s.
5* - * s-fT
S 2 i 3'-
5- 2. = V *
1.- * L s
5 J I i-l'
-r- I5 v-e 3" 2 n2=3
t
s I if
W[
S. " *
=-< o
B"*'
: ar,
si. Si
If *= 2,
n
n
>
n O
70 70
O
CO
template working w ilh Irarl w ill fin
tageous to consult the manufacturer technical advice and service which th
mumwmmummn stiU n= >I|T 4-1 S S 2= .s 5 I
o;) <-*|| N !> I I* `
JmMu .iV -'XVi'jV, ,V,J,,
r s s- .5 =:=- -2" r?i * $ s-n E-
x *
*TM
= a. - 5 1.1 3li3it 3 |
: 2 2 3- < r = - =_ -- 7.
=5
4- = y- * = r i_
--1 *
iiUUr = -- -
`' r = :
~
-
-
U
:
=
r=
--. Z
l
Elilfli r: -
; r i - 1 i = $|I-1'= =* 5J ?5
s. = = = -. V. -
r
i:^:rs S -j -' ss"5r=r
5
2.IS ^
=
=
-
E- Z=|
1
* F`
1.1.1*
*
=.
E.
1"
2
-
mm S J 2 =-- S- "
irf--
"f = 2
--
-- ItoJ =
-=
r
L2 -
3
l=
':
-"
* i
=s : := 5i r
r=-
--il-
*= =
i /
t.T
"?- _=
" -- z.
= 2 c
33 -- --
M^
3_" --o h_v^t 5*Z==i ?= =
|;i i* - = 3
il-i
=
= - ^2
=
2 5.
J"" "
irMa i-iH ri- * - = m SL : 2
: =? f-i S s'-i
|i fli *3 2 Ifllll= 4 7
2 =.'
T~
m
>
O
n
O
"O
O
a
CO
iii greater ilr la il in another section. Carbonate w hile lead is
also used in glazing pottery and enameled ware, in p u tty , in the mnniirnelurc of orange mineral and in other indiislrios.
Hydrated basic lead carbonate is a w hite extremely fine powder w ith excellent hiding power innnnfaclurcd in this
=-. = =r
-- 'L ~
iflrMi'
*25 I-1 ^
= i
=
1
=I=^
i
i
|
g
=5
5-
Im nri r?ig =
5 '"* --
L2
:1
=r iT5^
-- -i.
-- "* s
*
? i'|1r1 i
=
=*
5rr
5 5" s
-s " S " ^ 3; = `3l
? Z
--
=.= >=' x- S S
-- = -S
X~
i=2
"
3
i c: '--J- r=-. = M I-
-
\
I
[
if
n*h -3^ -s = F !=fi'
p;
\'A
- ' rr
= ^ 7l ^< --
3
IS.
= 7' =L 7
= =
'
7- = i,-
5-
i{ fi ==
^
r 2=2 =
ir-J.
=
,13: is
15 ~-
-=
= = Z. Z "
'
m
Z S.
*=$
M*5'-s
SX
< s.
"r
2S
_ 7. = 5 2.r =
r rK 5 2 =y =
nil-/- - tl Sl3
r z.
IL ?s:i infr
?s i= i! = - S 2.S = file-
ri |_5-=.
= Z1!-.
-- =
~-
= E- ~VI --
if II " i i- Mvn-
~
= -* = 5 5 **
iri=: ; z.
Z 5 !* 7
* =
= I.: s i.
l-'t:
I Ll:-- --. 3. ^1
riS| *< s=
l\"i'
=== - 5 bi-5 : n b k
Li L
Sr-
ri
-=
_=. ~
2 d.
%- i -
=- z-= =
- i. Z =
5Ij= = = =
=
-s
i
I S
II v -- "" x * 3 5* -: =
1 ?! r3-in
7` H` =* " =
= -- ^ -- 2. -- z. --
--
=..j
" z --x
Z r 3=
r
j. 5
XX
-- - -i -- 3 T5 ~ = - -
i3?- t - x rr
~r i : i - : -
-- ri-rs- 5-r
r-i; ' --
--. r
- _. =.
--L --J
7 t= =
=:" ?
X =*
---= -
= 7B
Is -=
_S
. r
i.
~
5
5 - = =
: -/ -
S2 i
2--1
I3 ^
x' --
s -
= -
---
TL
i -g =.3
5 s " i.
. X- = =*
^ 2 ); ..
=t-** =
z--
r 6-
2- L
~
IT 1L
7 '-i
-X - 7z rs
F,,r,y -''""
Su p p l e me n t Any Lis t o f Le a d Co mp o u n d s
,Samf ' Formula
Apptaranrr
^olabthii/
Miinntocturr
Remarks
Lead acetate
(plumbous '
ISUffar of lead
PbiCsHjOsis.SlIrO
W hite nr brownl%h m|i)te (TVstuiLliioresren.
:-oluhlc io water
I Dissolve litharge tn ililuir *< tir I hv strain uni* < rvtalll/rs
cooled l^-ad (iirlKJiiuii- limy
I place of hUiurgc
and heated I l *cd in manufacture
out wlu u of other lead s u I|a.
be used h i mordant in qvr*.
I urvrf in paint*. had i coating atti i
Lead acetate
(plumbic
i PWOHj Oih
Colorless crv*iiil.
l)ccnrnt>oe<l he
Add muriu glacial acetic acid to red lead and
wilier Kilo PbOr cool
uml neet ic acid
Lead acetate, basic
! Sl'MCrHiO.:; I'hOdSHrO
Needles
."`olubie in mater
, Made from 1'bU aud normal acetate 1
i 1
Lead acetate, basic
Lead aaumonate
PhtUrHiO. .. *l*b04lMl
Phit>bOs:
Lead imutt
! I PbitAsOn:
Amorphous
* Orshire-vclinu
| pnmcler
W hat- pou
. soluble in mater
Made iroiu 1'bU and ooftuai acetate i
| 1
insoluble in mater Interaction of leud nitrate ami {totassiuni l *rd us pigmrtii in
i utitiinoimir solutions, coDCentruiiuii and i paint, ceramics, crork-
: cr\stnhitaiiou
erv and gi** indu<-
< 1 tries
Insoluble in mater 1 Action of ar*cmc acuj on litharge in prrscnrr >oiuble in H.NOj t <>f acetic or nitric arm a* eainiv*t. or mill
i solution of Iruii acetHtr or nitrate to sodium I arsenate laillrr method give* liilllure of I bn*ir ami dibasic lead afscimtr nmi should I not he used tf it i> to be mixed with hnir* I sulphur aolution
insecticide
Lead aside
: PbNt
i ( rvslalline lull' I stance
Add lead acetate or nitrate to solution of
i mmIiu b i aside
l eti as primer in * \piosivrs mill) mtrogivcerinr
Lead beoxoau-
FblGlLO: :
Lead borate
PbdlOH.HjO i PbO-SJWJj
1
' W lute rrvslalhne i pomUer
; \\ hite pomih r
Mightlv soluble in mater
Insoluble in matrr.1 Add aft excess of lorai solution to a solution
>oluhle in dilute i of lead salt. huMon of boric acid mith lead
llNOi
i carbonate or oxide
Used as drier in paint* l srd m flaxes and enameU
Same
formula
.Ipjyoronrr
Sulubihty
M unujnclurc
Remark*
Lead bromide
PbBr?
White pomdrr
( uniparntivrlv in* .'same as lead chloride u miic bromine com*
soluble in mater
(Miunds instead of chlorine cntn|iuuud
Lead butyrate
PbiC.HrO: .
Uoiorlc** Hake-
Insoluble h i mater
Lead carbonate PbUb
i Heavy white ma> insoluble lit mater Add lead nitrate to ammonium carboitutc
Occur* in nature u* rerussiir. see page ti
Lead chloride (plumbous;
PbCI;
Lead chloride (plumbic;
1 PbCU |
' While crvstals or i silky needles
Heavy yellow oily liquid. or with mull quantity of mater forms cry* talline hydrate
Hik'htly soluble in mater
Treat lead oxide or carbonate mith 11 Cl or add concentrated solution of soluble lend salt to soluble chloride. Du large scale
Diode by beating litharge with excess of 11C1 at 200 C and atmospheres in acid-raiating autoclave
Dissolve PbClj in concentrated 11C1 in pres* erne of exerss chlorine Tiers* of water
decomposes it to PbO* and UUI
Lead oxychlorides. Numerous. An
i
important one is PbClj.TPbO (Cas-
sel yellow
Yellow powder
Insoluble in water Kuse one purt ammonium chloride with ten Most occur in nature
parts massicot. white or red lead
Pigment
Lead citrate Lead cyanate Lead cyanide
i I*bi(C<HjO:i:
i
| PbfCNOn
i
| Pb(CN ii 1
W hite crystalline Insoluble in water powder
White crystalline >oluble id water powder
White powder
Insoluble in water Action of solution of potassium cyanide oo lead acetate
Lead dichromate 1 PbCnOi
Brick red pomder Insoluble in water
Lead dithiotfurate j (CJLOCSShPb
i
Accelerator in manu facture of rubber
Forty-three
Same
Formula
A pptarancc
Solubility
Man iiinrturt
Jifihart,
Lead etboxidc
TblOCdlu:
Light yellow fri able powder
>ulublr in aod hvdroiysed by water
.**Ut>end thin shreU of lend <*\.r Itb'.ilute aletihol through wlm ti n 'trv.tin .? ozone i|Mted. tben witb wuli uholiol uiul iiry in vacuo over sulphuric and
Lead ferrucyaiude lV:Ke tC.Nls.3l 1:0 Yrllowi-.b a lullpowdt-r
Insoluble 1U water
Lead tluoboruU-
I'btUFo:
Made bv the miioii >>f lit drolioofie un.l (Mine aeid' ou white lend
l 'I II m electroplating with leu< 1
Lead liuoridt
l*bl:
While |wilrr
insoluble id witter
Made u' nre other huiourn h >iii|*>iio iU <>f le.nl lining |iroper Ihionoe eiini|MMiii>i
Lead tiuokilu-uU*
I'bSiF*
Action of li^ii-* on hlburgt
>olul mu of alioiit h ' . I'IimW nod 1 Y.t llv m!- u v o u> electroK te III eleel roly tic fetimiik' of le.ol
Lead foroiati'
l'blCHO*,:
Lustrous wlniirhutnbii* pn>ui> or oeedlr.
."'ulublr in water
Lead bydrondr
1'biOHii
While amor, pbou* powder
Vrrv shi'lilly h 1uble in water. >tlllble ill excess -Nh OH
ila> never been prepared h i pure eoudilioo
AO'orh' < 1 h from 11..
air lorming wlm-
lend At rill- ( .1.
.........
lino 1141
niid 1*1.0
Lead "bvpo*ulplHlt-,`
tlhiusulpbalr -
1'bMOi
N bile rrystulhnc powder
insoluble id water 1'rrcipitalrd from h-tnl loelnle uiol valium tiV(Kulphde l III lot ul pilule
1 ret*oni|Mi'i-' witri h 'i "ometMlie Ii'iil a* io eelerulor III \uleam/me rubber, ami le|Mi'il lean mirror-
Lead "hv pnsulphuU " (dilliionuli"
Lead ioduir
1'bl:
W hie crystal.'
Very soluble in water
(loldm crvlal or powdrr
Insoluble iu water Matlr as nre other halogen <iilii|aillliils of lead using profter loOme eouipoutoi'
Same j Formula
Appearance j
SolubUtfy
|
Manufacture
Uemarki
Lead lactate
i Pb(C>H.O.h
Heavy, while. 1 Soluble in water
t crystalline powder;
Lead bnolealv 1 PbfCisHuOih
Yellowish brown 1 Soluble in acid* piasterdike uia*
1 Add litharge t<> rnwlinseed ml andruiv i temperaturetobetween 50U* and 00b 1.
| 1 1
i I'nnnpui use as drvrr : m tiuini ami \*ruih
i hur tins puriNJsr a i< dissolved in turtieni tine while warm
Lead maiatc
| I*b(CH*0i)-3iJs0 W hile powder
Slightly soluble in|
!-water
|
j |
Lead mohUl.u- 1 Pb-MoO.
!
bellow powder
1 Insoluble in water.! Add lead nitrate solution to solution of |
1 soluble In but i ammonium tuolvbdale and concentrate
|
j picric acid
I
1
Lead nitrate
I PbfNUits
White crystalline Soluble in water | Dissolve lead or litharge io nitric acid alt
!
1 Lied m manufacture
! of other lead salts, i matches. breworks, i insecticides
Lead nitrile Lead oleatc
I Pb(NOh i
j Pb(CuHsOm
Yellow crystals
Very soluble in water
1 Decompose silver nitrite with lead chloride j t and concentrate the solution in a vacuum !
While ointment-
like granules or mass
Insoluble in water. Action of olviv avid on a lead salt Soluble in alcohol or ether
i Lsrd as dryer iu j vsroisb, used in rul>i ber and lubricant*
Lead oxalate
j PbCiOi I
Heavy, white powder
Insoluble in waterj
j
Lead peroxide
PbO)
Brown powder
Insoluble is water 1 Action of strong oxidizing agent, as HiOr. on 1 Strong oxidixiog
1 solution of lead acetate or nitrate in presence | agent
1 of alkali. Also bv making lead the anode m |
dilute sulphuric acid solution, and scraping I
the peroxide off the lead as it is formed
!
Lead pbenolate (phenate)
PbtoHioau.
Yellowish to gray Insoluble in water! Boil pbenol with litharge
ish white powder
!
I 1
Lead phenol-sul- 1 Pb|C*Hz(OH)SOi) j White, lustroui Soluble in water ori
pbonale
| .dHiO
| needle*
alcohol
|
Forly-five
.Same
formula
. 1 ppearunt t
>ulubiiitii
Mtiniiiafiiirt
liemark*
Lead phosphate : PbilHO.': s
1 Will tv powder
Insoluble in walcr Prvcipilute exer" of lend ucclntc with small > |uautitv of >uUluui pliuaphulv at UXJ L .
Lead propionate ! Pb.CslhO: :
i (oiurie-- rr> >iuii Inn |Miin r
liiooiuuic in wuicr
Lead resiosic
Pb(C;OHrA>- :
!i i! !
1 Yrliowi.il wliiic | pluilK- iVIII|H>llljli 1 1
lioolnbU- m watvr or iiuisi solvent*
i
Heal liliuirgc *itu rc*ni
> l'nnnpal ue h s dryer . iu puiiito. hop this
: Ur tli.ooolvr in pe* trulcnm irdvrnt or mixture of lurpcntioe and iwtrolvum thinner
Lead ulirvl.tl>
PI. ( :JUh - ll.ll \\ lull' rr\ -l.u-
>oiul>lr in wall r aiul aliiiiiol
l^ruii srleiml >
Pb^-u.
1 While |M>W11 'r
lii-.oliii.lv in walrr
l.eud kihcule
I'b.-it),
! W liM < rv -.tullinr 1 JHiwurr
Iiiooluiiir 111 wuicr; Made l>v fli-mii of lilliurce an.I oiin.. ..r
or alcohol
1 iirtion of ivml utelulc un.l Muinuu -ilii.il>-
1 MllutlOllo
l M-d in k'laziiic. rnain. iimrand lirc-prooQOg fubruo
l.rud tluorulr
PloihVll^)
! N\ Inlr rr\-.luliim 1 |Mwlef
Soluble ID wulvr
1 Urn! culco.i or ulhcf lend eimiptiiiii.l- will. i hvtirufliiu-dnte netti. air heimr l.iown i UirmJk'ii mixture ami w.lrr uiiilr.i
Lruii klrurul)
Pb.( ,JhAh .
: Yriiow ion rruinlo i Iv (Miatirr
Iiioolublv ill walvri Ural -olulioli.* of leud imluli am! mmIiij iii . l ord a.o u drver in
>oiul>ir ill alcoiiol < oimruir
' x itriitt.ii uml lacquer
Lead subuinie
I'M)
1 Cray |H>wirr
|
I Art ion of walrr L'u.-. on lit Inirce or i>v lirulim;
1 irul oXtdnie nl ulbollt V?'* ( Willi prt^iiir.-
| below J ini. of mmiiri . Towurin rnd of
| pforeoo. wbrti prrt'iirr i ilown ainniol (o [
' r-rn, lriii|H-rul urr run la-raioi-il lo .H.i.i4'C . i*r j
; iuirio-r
!
Lead Ipiumbou-. i
Pb>0,
II..IN. W III 1
Inooinblr in water A< Mon of .oinblr -nl|>liale or Miiplturu; mil v.hiblr ill uimiioni* Oil Ivuti untuli or lllirillr nn. arvlaie
Lead suiphale Ipluinbu t
PbiSO. :
: \\ litlr en oUllii.r < Mlholum r
[ Kleetr.di oio of eoiieetiiruled lh>0 III a ! 1 divnled eell wilh lend h ih h I. . 1 eiii|MT*lurr 1
i iniiol Ih * kept below "(l <
If ililulc and >
i or higher irmfHTuttire i, nord. I'M*? will be 1
. lorim-d
A'ame
formula
Lead sulpliidt* IfaienaJ
1 PbS
i
Lrad fuipliitc
1 PbMh (
bead sulphoryun- i l'blCN.-vi ate
Lead tanoate
Lead lartrair Lead tetraethyl
1 PkCJMfc I'bfCUl.J.
Lead tetramethyi PbfCHji. Lead thiosulphate FbSiO.
Lead tungstate
PblVOi
Lead vanadate
Potassium plumbate
Pb(VOi), KiFb(OH).
Sodium plumbate NaiPbfOHj*
Sodium plumbtte NiPbfOH).
| Appearance
Solubility
j
Manufacture
JUmarii
1 l-rad-emv crv'lal Insoluble in water Unhide hydrmren stiliihidr Ihrouirh lead salt ' Most common lead
1 line M>lnl with 1
i solution. Tins is delicate test for presence i mineral, ^vv page 6
1 niclalbc lustre i
i
1 of lead, as a sitiull amount w ill color solution
1 gray or black
\
1 (runiblv white i Insoluble in watrr. 1 |M>dvr
i
| ^ rllowisli micro* 1 crvstailiuepowdrr ;
! Prmpitatrd from solutions of lead nitrate Tscd as primer in ex-
l and sodium suiphocyanatr
! plosive*
1 Hruwnith yellow, i SlnrhtK' soluble in
| odorle**. Vastrle--. > water or alcubol | amorphous powder.
1 White powtlrr liquid
i Insoluble in watrr
1
Volatile liquid
Sre lead hypo* j
sulphite
[
Produced by ariioo of ethyl iodide on lead* sodium alloy, or by action of lead chloride on zinc aikyU
Produced in same manner as Pb(C;IIi)i
I'sed as anti-knock ingredient in motor fuels
Yellowish powder 1 Insoluble m water
!
Yellow powder
Insoluble in water
Interaction of solutions of lead nitrate and sodium tungstate
White crystal*
i
Dissolve lead peroxide in boilmr concen* 1
trated potassium hydroxide and allow to
stand over strong sulphuric acid
j
Anodic oxidation of solution of lesd hydros* ide io sodium hydroxide, using platinum anode. Crystallizes out without evapora tion
1 soluble in water
1
Add litharge to solution of caustic soda. ! W idely used in oil re
agitate by blowing in compressed air and 1 fining. referred to as
raise temperature to 10UK Podium i "doctor solution"
piumbite solution results
j
This handsome miniature farm in the suburbs of I'hdudel/ihin is /minted n itii ;>iire irhilr lend unit nil.
sr*--*
*2
3. S3 " "p e
s2
B ?|3=`2,E2i'ri:S's - * I- i s
i.=-g;3|3g'3Ss,*-sTM
-. -- S g = --
p 2 .. If ^ ^ s 2
|25|-e .;
^ = |
~ ^ ^ 7 & a - P a S' a. 5* 2. a b a ? ~ft
g 3
3_s=
j?
s *.s2. aft- =a;
3. <* 2* 3C ---- f-t 5=* -J s 2 3 v 3 3 eB: ^
fllrf2
j
5 --
3. ^ ft *ea
CC 3' %<
ft j; ^
= ^ ft 5 . 2
ft 3 >3 333* e5--. 5Ti*
3i-=3f-t.*-33S3rf33t o^S333232ftT.'S--2s--5*Sea3f3f=att="- K--A3fI5tS# 0E3c(!A9-
3-*
3. = ft =L ff
c
5* 3--S"* e.
ft *3
S-s. ^09 039'
. *09
^ ft
a* -- 3
<
e 2
3 _,
ft gj
3 ft < 3
=.",'
sa-'^a-a - 5" = :f<t -
3TS
^s*ar S'
"3
*
-i 3-s
CsS ft X
ft
3.2 5T
S
-- i: ----
51
<---* fftt_
fst *--<
5 ~-
?<
8 * | a- 2 j?= * ^ r. 2
ft
2
.
S'
ft ft
ft.
3
3- F
** _
309
S' s
--0 !
? ft
3*ft".
*<
q
3
3" ft
^ S,
--
i^i?s f?t XVs ?na-S2rj. rH= .o>
GO ft
f33t-
o
3
CO ?
3-
ft
09 z.
2t
ft
^
2.
-
^-3--==.
~.
-
rf_t* <f3<1t # 5
ft
-5
v** o2-
c--
""* 5T
-- ft
-s3o
3s3.
ft ft
*X039?
-- ^--1 fvt:
sftr ft .33 -23
.21
<-<Sf
2. -TT 34
ft ft
* 3< .1-- -' a =: = s 3 sf
ft
'2 ?
x. 2-- 31 < .? 1*< ft Za ? WJ
ft
*T* 7:
5. 3 - 2. *
c s^ --< CA m
> ^
*
j.
*_<
^ t! " Z-
7
QS
c. sr
c: a
7Z Si i j; -
~ =c3 -5 ~
a7 rt -
25
3; -- ^ -
e sr
*< ST
-- TZ
.. i: <-< --
2-
- -.~s = ^ --
;5 ? S 2- = ^2 5 r =? f 1. 2 5 -: = = - 5 r
1 L sl' 2 2. - I J- I -= ^ = -;='- r:
s' ? r * s :111 i -1 i - ^ i- =L --^
lb3 5.= ir=sTM 2 " t1i :<5.--5--? ^a !i -i; :5 * f
11 2~
5" r=.; = 3 - I
_- v i-s r -
-- - ~- --
2. 2
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