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INCORPORATED 200 GirardStreet,Suite200, Gaithersburg,MD 20877 301-921-0168 Fax: 301-977-0433 Client: 3M MEDICAL DEPARTMENT 3M CENTER BUILDING 220-2E-02 ST. PAUL, MN 55133-3220 (651) 575-3161 Attention: ANDREW SEACAT Date Collected: Date Received: Date Reported: 02/20/1999-02/26/200C 04/18/2000 05/02/2000 Client No. 1492 Study: 6 MONTH PFOS STUDY Species: CYNOMOLGUS ------------------------------------------------------------------------------- Accession s ec. Gp Sex Age No. IE ------- ---------------- * 0098138 I05508M 1 * 0098139 I05519M 1 * 0098140 I05527M 1 * 0098141 I0553OF 1 * 0098142 I05531F 1 * 0098143 I05535F 1 * 0098144 I05544F 1 Mean S.D. TSH, SI UIU/ML 0.45 0.32 0.42 0.43 0.19 0.59 0.80 -----.457 .195 CHOLEST MG/DL 105 145 143 124 116 171 99 ------ 129 25.4 RDL-DIR LDL-DIR VLDL MG/DL MG/DL MG/DL ----------------- ------------- 50 72 44 56 47 42 32 ------ 53 73 97 68 66 128 65 ------ 2 0 2 0 3 1 2 ------ 49 78.6 1.4 12.6 25.6 1.1 Group 1 A 0098145 I05514M 2 A 0098146 I05515M 2 A 0098147 I05516M 2 A 0098148 I05521M 2 A 0098149 I05541F 2 A 0098150 I05547F 2 A 0098151 I0555OF 2 Mean S.D. 0.64 0.69 0.49 0.41 0.51 0.43 0.34 ------ .501 .125 115 80 73 67 92 84 82 ------ 84.7 15.6 43 37 32 34 48 36 25 ------ 36.4 7.5 72 41 36 33 40 48 51 ------ 45.9 13.1 0 2 5 0 4 0 6 ------ 2.4 2.6 Group 2 Reference Range .2 2.6 101 240 Page 1 + 00 00 00 INCOR ORATED 200 GirardStreet,Suite200, GaithersburgM,D 20877 301-921-0168 Fax: 301-977-0433 Client: 3M MEDICAL DEPARTMENT 3M CENTER BUILDING 220-2E-02 ST. PAUL, MN 55133-3220 (651) 575-3161 Attention: ANDREW SEACAT Date Collected: Date Received: Date Reported: 02/20/1999-02/26/200C 04/18/2000 05/02/2000 Client No. 1492 Study: 6 MONTH PFOS STUDY Species: CYNOMOLGUS ---------------------------------------------------------------------------- Accession S ec. No. IE Gp Sex Age TSH, SI CHOLEST HDL-DIR LDL-DIR VLDL UIU/ML MG/DL MG/DL MG/DL MG/DL ------------------------------- A 0098152 I05510M 3 A 0098153 I05518M 3 * 0098154 I05524M 3 * 0098155 I05528M 3 * 0098156 I05532F 3 * 0098157 I05538F 3 * 0098158 I05545F 3 * 0098159 I05548F 3 0.83 0.83 0.54 0.60 0.76 0.46 0.34 0.32 ------ 115 98 110 116 91 88 74 74 ------ 48 44 37 31 23 32 24 31 ------ 66 54 72 76 68 53 50 42 ------ 1 0 1 9 0 3 0 1 ------ Mean S.D. .585 95.8 33.8 60.1 1.9 .207 17 8.8 12 3 Group 3 A 0098160 I05506M 4 * 0098161 105507M 4 * 0098162 I05512M 4 * 0098163 I05534F 4 * 0098164 I05536F 4 * 0098165 I0554OF 4 * 0098166 105551F 4 Mean S.D. Group 4 0.73 0.72 1.15 1.25 1.75 0.89 0.86 1.05 .368 56 25 27 59 53 57 61 ------ 48.3 15.4 14 8 11 16 18 16 22 ------ 15 4.6 42 16 16 40 31 41 35 ------ 31.6 11.3 0 1 0 3 4 0 4 ------ 1.7 1.9 Reference Range .2 - 101 - 0- 0- 0- 2.6 240 0 0 0 Page 2 + C, NCO PORATED 2oo GirardStreet,Suite200, Gaithersburg,MD 20877 301-921-0168 Fax: 301-977-0433 Client: 3M MEDICAL DEPARTMENT 3M CENTER BUILDING 220-2E-02 ST. PAUL, MN 55133-3220 (651) 575-3161 Attention: ANDREW SEACAT Date Collected: Date Received: Date Reported: 02/20/1999-02/26/200C 04/18/2000 05/02/2000 Client No. 1492 Study: 6 MONTH PFOS STUDY Species: CYNOMOLGUS ------------------------------------------------------------------------------- Accession S ec. Gp Sex Age No. TE ---- ------ --------------- A 0098167 I05533F 4R A 0098168 I05542F 4R A 0098169 I05511M 4R A 0098170 I05522M 4R Mean S.D. TSH, SI CHOLEST HDL-DIR LDL-DIR VLDL UIU/ML MG/DL MG/DL MG/DL MG/DL --------------------------------------- 0.85 0.60 0.65 0.93 ------ 117 124 89 106 ------ 51 50 45 37 ------ 61 46 44 68 ------ 5 28 0 1 ------ .758 .158 109 15.3 45.8 6.4 54.8 11.6 8.5 13.2 r--oup 4 WK52 RECOVERY Reference Range .2 2.6 101 240 00 00 00 Approved ------ ------------ Date ---7@Z:2/-C Page 3 of 3 AndrewM. SeacatP,h.D. 3M MedicalDept. 3M Center,Buildinmc2,20-2E-02 St.Paul,MN 55133-3220 Phone: (612)575-3161 FAX: (612)733-1773 e-mail:amseacatl@nu=.com 3/6/2000 PeterJ.Thomford, Ph.D. Study DirectorT,oxicology Covance LaboratoriesInc. 3301 Kinsman Blvd. Madison WI 53704 Phone: 608-241-7202 Fax: 608-242-'-1736 Re: 26-week capsuletoxicitsytudywithperfluorooctanseulfonicacidpotassium salt (PFOS; T-6295) inCynomoigus Monkeys. Covance Study Number: 6329-223, Peter, 3M requestsinformationfrom the studyrecordsof 6329-223 forthe methods used and thedatesof specifichormone determinationcsonducted by Ani LyticsIncorporated, GaithersburcN,M,. Specificallwye, need more informationon themethods of determinationforT3, T4, freeT3, freeT4 and TSH. An explanationof thezerovaluesfor TSH isrequestedW.hat isthelimitofdetection(LOD) and limitofquantitatio(nLOQ) forTSH inthemethod used,and should thezerovaluesbe replacedwith <LOD or < LOQ. Furthermore,we need tounderstandthe hichT3 valuesreportedfortheday 37 samples(referencea,ppendix6 ofDraftinterimReport from Covance),forwhich theT3 valueswere hiah in alldose groups.The datethatthetestswere performed on each sample isalsorequested.Ani LyticsisbeinCg)copied on thisrequestinordertoexpedite thetransferof information. Sincerely, Andrew M. SeacatPh.D. Study Monitor cc: Dr. SarojDas Ani Lvtics 200 dirardStreet,Suite200 GaithersburcyM,aryland 20877 Telephone No.:301-921-0168 FacsimileNo.: 301-977-0433 INCORPORATED 200 GirardStreet,Suite200,Gaithersburg,MO 20877 301-921-0168 800-237-2815 05 April 2000 Andrew Seacat, Ph.D. 3M Medical Department 3M Center, Building 220-2E-02 St. Paul, MN 55133-3220 Dear Dr. Seacat, REF: Fax dated 3/20/00 TSH analysis in Cynos I want to bring to your attention that primate TSH analysis at Ani Lytics, Inc. has always been performed using anti-human TSH polyclonal antibody. During our telephone conversation I told you that as of 1998 all human TSH testing is being done using monoclonal antibody, therefore these test reagents cannot be used in primates. For this reason we initiated an inhouse TSH assay procedure utilizing polyclonal antibody. The reagent source and other information on each of the assays mentioned in your letter along with result reporting policy are inclosed. As I indicated to you, primates in general have quite low TSH levels. Therefore it will be necessary to increase the specimen volume in the TSH test system. At least 0.5ml but preferably l.Oml ser= will be good. Sincerely, Saroi Das, M.S., Ph.D. Director CC: Peter J. Thomford, Ph.D. Study Director, Toxicology Covance Laboratories, Inc. 3301 Kinsman Blvd. Madison, Wl 53704 NCORPORATED 200 Girard Street,Suite 200, Gaithersburg,MD 20877 301-921-0168 800-237-2815 RESULT REPORTING POLICY Linear regression accepted. curve correlation coefficient of 0.99 or greater Results observed over the highest on appropriate dilution. calibrator concentration repeated Lowest limit concentration. generated based In some assays specific. of quantitation is the lowest calibrator Values below this concentration are computer on the standard curve. These values are reported. the exact calibration range is kit lot number A zero value indicates that the counts bound for the sample/s same as or close to or > zero standard counts. were C-""--"A ELM INCORPORATED 200 Girard Street,Suite 200, Gaithersburg,MD 20877 301-921-0168 800-237-2815 ANALYTE: NonRuman Primate Thyroid Stimulating Ho=one (TSH) PROCEDURE: Double Antibody RIA Inhouse Procedure REAGENTS: Human TSH standard (Ref WHO standard Sigma-Aldrich Inc. Cat. #T-4651 68/38) Rabbit-anti human TSH (polyclonal) Sigma-Aldrich Inc. Cat. #T-4651 Radiolabeled HTSH Covance Laboratories, Inc., Vie=a, VA CALIBRATION RANGE: 0.4 to 50 mlu/ml. (Low end sensitivity is dependent upon the integrity of the iodinated hormone.) RESULTS: Computer curve. MIU/ml generated values reported below low end sensitivity of the COMMENT: Overall TSH levels in NHP are extremely low difficult to know if this test offers significant info=ation. so it is clinical 1 N C PORATED 200 Girard Street,Suite 200, Gaithersburg,MD 20877 301-921-0168 800-237-2815 ANALYTE: Free T4 PROCEDURE: Coat-A-Count RIA REAGENT SOURCE: Diagnostic Products Corporation, CA. CALIBRATION RANGE: 0.1 to 10 ng/dl (kit lot # specific) RESULTS: ng/dl Computer generated values reported below the standard. INCORPORATED 200 Girard Street,Suite 200, Gaithersburg,MD 20877 301-921-0168 800-237-2815 ANALYTE: Total T4 PROCEDURE: RIA Coated Tube Assay REAGENT SOURCE: DPC, CA. CALIBRATION RANGE: 1 to 24 ug/dl RESULTS: ug/dl Computer generated values reported below 1 ug/dI. I N C 0 ORATED 200 Girard Street,Suite 200, Gaithersburg,MD 20877 301-921-0168 800-237-2815 ANALYTE: Free T3 PROCEDURE: Coat-A-Count RIA REAGENT SOURCE: DPC, CA. CALIBRATION RANGE: 0.5 - 42 pg/ml (kit lot # specific) RESULTS: pg/ml computer standard generated values curve calibrator reported below the lowest concentration. INCO PORATED 2oo Girard Street,Suite200, Gaithersburg,MD 20877 301-921-0168 800-237-2815 ANALYTE: Total T3 PROCEDURE: Radioinmunoassay (RIA) Coated Tube Assay REAGENT SOURCE: Diagnostic Products Corporation (DPC), CA. CALIBRATION RANGE: 20 to 600 ng/dl RESULTS: ng/dl computer generated values reported below 20 ng/dl