Document RJJ9gw05eQBxbGRBJaVy3QLV
Engineers Planners Econom ists Scientists
April 12, 1993 LMS35216.X
AR226-2428
Mr. Roger zipfel Dupont Parkersburg Dupont Road {Highway 892) Washington, West Virginia
26181
m t analytical Data for u m Laboratory Reference Ho. 24340
Dear Mr. zipfels
On March 29, 1993, the CH2M HIM. Montgomery Laboratory (LMG) received fifteen samples with a request for analysis of selected organic parameters. M you are aware, sample 24340012 arrives broken,
The analytical results and associated quality control data are enclosed, any unusual difficulties encountered during the analysis of your samples ar d:LsQiisg@& xii the casts jiaxarative* Under CH2M H I M policy, your samples will be stored for up to 30 day after reporting. If you have not given us prior instructions for diBposa , W will contact you if any samples require disposal as hazardous waste.
CH2M H I M Laboratories appreciate your business and look forward to serving your analytical needs again, if you should have any questions concerning the data, or if you need additional information, please call-
sincerely.
t Q u u h x -
Wanda L Hall
Data Package supervisor
Bnclosures
RI Z O 19094
CH2MHILL
AQnuaallyittyical Laboratories
2567Fairtane Orive, P.0. Box 230548, Montgomery. Alabama 36116
205.271.1444
EID941040
Ta-RT.-R OF CONTENTS n o n Trrr.T. la b o r a t o r y R e f . N o . 24727
- Rage Ho.-
list of Organic Data Quali f i e r s ..................*.................. . 1
List of Sample ID Q u a l i f i e r s ............................. *........ Client Sample Cross-Reference
* iii
F C --143 DATA case Narrative Sample Results Blank Results MS/MSD Results
Copy of COC Documentation
1 3 13 16
18
RJZO16280
C H2M HIUL
D u a lity A n a lytica lLaboratories
2567Fatrlane Drive. P.O. Box230548. Montgomery.Alabama 36116
205371.1444
EID939358
ORGANIC DATA QUALIFIERS
U - indicates the compound was analyzed for but not detected. _ The number adjacent to the "O" qualifier indicates the reporting limit for that compound. The reporting limit can vary from sample to sample depending on dilution factors or percent moisture adjustment when indicated.
J Indicates an estimated value. It is used when the data indicates the presence of a compound helow the stated reporting limit.
C This flag applies to GC pesticide results only- The "C" flag xndiea the presence of this compound-has been confirmed by GC/MS analysis. (This definition is still being reviewed and discussed).
B __ This flag is used when the analyte is found in the associated blank as weXl as the sample. This notation indicates possible blank contamination and suggests the data user evaluate these compounds and
their amounts carefully*
.
E -- This qualifier indicates that the value reported exceeds the linear calibration range for that compound. Therefore, the sample should e reanalyzed at an appropriate dilution. The "E" qualified amount is an estimated concentration, and the results of the dilution will be
reported on a separate Form I.
D __ This qualifier indicates compounds which have been identified during a diluted reanalysis. "D" qualifiers are used for samples that have been analyzed initially at a lesser dilution than required for accurate -
quantitation.
* __ThiB qualifier indicates that the response for the compound exceeded the linear range of the instrument. Therefore, this is an estimated
concentration.
V--
This qualifier is used for a pesticide/Aroclor target analyte when there is greater than 25% difference for detected concentrations between the two GC columns. The lower of the two values is reported on Form I and
flagged with a "P".
N __This qualifier indicates presumptive evidence of a compound. This flag
is only used for tentatively identified compounds, where the
.
identification is based on a mass spectral library search. It is
appi fcrt to n TIC results. For generic characterization of a TIC,
such as chlorinated hydrocarbon, the "H" qualifier is not used.
A -- This qualifier indicates that a TIC is a Buspected aldol-condensation
product.
.
CH2M HILL
d u a lity A nalytical Laboratories
i
2567Fairlane Drive. P.O. Box230548, Montgomery, Alabama36116
20S.27t.1444
RJZ016281
EID939359
ORGANIC LAB SAMPLE ID QUALIFIERS
The qualifiers that may be appended to the Lab Sample ID for organic analyses
are defined belowt
'
DX. __ Dilution Run. Indicates the sample contained compounds exceeding the calibration range. The sample was diluted and reanalyzed. Both results axe reported.
R __Ramon. The sample was reanalyzed. The "R" is not used if the ' sample was also re-extracted.
E g __Re-extraction Analysis. The sample was re-extracted and
reanalyzed.
-
m s __Matrix Spike (may be followed by a digit to indicate multiple matrix spikes within a sample set)
h r t i __Matrix Spike Duplicate {may be followed by a digit to indicate multiple matrix Bpike duplicates within a sample set)
RJZ016282
C H 2 M H IL L
Q u a lity A nalyticalLaboratories
ii
2567Fairiane D rive. P.O. B ox230548, M ontgom ery. A labam a 36116
205.271.1444
EID939360
CLIENT SAMPLE CROSS--REFERENCE r u o u h t t .t. laboratory Ref. Ho. 24727
LMG Sample ID
24727001 24727002 24727003 24727004 24727005
Client Sample XD
CENTRAI STREAK LEACHATE' WEST STREAM WELL #1 . T.W. #25
RJZO16283
C H 2M H ILL
QuaTity A nalyticalLaboratories
iii
2567Fairiane D rive, P.O. Box230S48. M ontgom ery, Atabam a361 IS
205.271.1444
EID939361
CASE NARRATIVE GC FC--143 SAMPLES
LABORATORI :
HILL LABORATORIES
CASE NO.
: N/A
LAB REF- NO.s 24727
CLIENTS DUPONT CONTRACT NO.s N/A
SDG NO.s N/A
X. RECEIPT
A. Dates May 20, 1993
B . Sample Iuforoition
LAB CLIENT SAMPLE ID SAMPLE ID
SAMPLE 'MUT'PTX
24727001 24727001RE 24727002 24727002RB 24727003 24727003KE 24727004 24727004RE 24727005 24727005RE W05243B1 W05243B2 W06013B1
CENTRLSTREAM WATER
CBNTRLSTREAM RE WATER
LEACHATE
WATER
LEACHATE RE
WATER
WEST STREAM
WATER
WEST. STREAM RE WATER
WELL#1
WATER
WELL#1 RE T.W.#25
WATER WATER
T.W.#25 RE
WATER
QC BLANK 1
WATER
QC BLANK 2 QC BLANK 3
WATER WATER
DATE
EXTRACTION ANALYSIS
DATE
DATE
05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93
N/A N/A N/A
05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 05/24/93 06/01/93
05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 05/28/93 06/03/93
RJZO16284
C. Documentation Exceptions s N o exceptions were encountered.
II EXTRACTION
A
Holding tlmess Holding times'were met for all original extractions. However, re-extractions were performed beyond the 7-
day holding time.
C H 2M H ILL
Q ua lity A n a ly tic a lLaboratories
2567Fairiane Drive, P.O. Box23054B. Montgomery, Alabama36116
000001
205.271.1444
EID939362
FC-- 143 T.fttt BEF- HO. 24727 PAGE 2
B
nn
Exceptions
s All field samples were re-extracted to investigate low spike recoveries in the original extractions. Smaller aliquots were used for the re-extractions to provide more insurance that surrogates would not be
diluted out.
III. ANALYSIS
' Ho other exceptions were encountered.
A. Holding times: All holding times were met.
Analytical Exceptions
Several samples were diluted to prevent FC-143 from exceeding the calibration range. Both the original and the re-extractiona are reported since the re work was performed beyond the extraction holding
time.
'
Ho other exceptions were encountered.
IV QUALITY CONTROL
A. Method Blank
B. Surrogate Recoveries
FC--143 was not present in any of the laboratory blanks.
All samples were re--extracted and reanalyzed as a corrective action for poor spike recoveries observed in the original work.
C. Matrix Spike Results
AT t re--extracted samples met acceptable.QC limits.
Matrix spike results have been reported with this contract along with the laboratory control sample (blank spike) results. The analytical system was not in control for original extractions performed on 05/24/93. Spike recoveries were back to normal for the re-extractions performed on 06/01/93.
I certify that this data package is in compliance with the terms and of the contract, both technically and for completeness, for
other than the conditions detailed above. Release of the data contained in this hardcopy data package has been authorized by the Laboratory Manager or bl n desginee, as verified by the following signature.
RJZ016285
C H 2M H ILL
GC Supervisor
d u a lity A nalyticalLaboratories
2567Fairtane D rive. P.O . B o x230548. M ontgom ery, A labam a36 116
000002
2 0 5 .2 7 t.1444
EXD939363
ORGANICS ANALYSIS DATA SHEET
laboratory Name: CH2M HILb/MGM Lab Sample ID: 24727001----Client Sample ID: CENTRA STREAM
Concentration: LQH___ Date Extracted: 05/24/93
Sample Matrix: WATER Date Analyzed: 05/28/93
Percent Moisture: ______ Dilution Factor:
20
FC-I43
c a s Number -____
ud/I-
3825-26-1 FC-143
26
Perfluorononanoic acid - SS Perfluorodecanoic acid - SS _ HH-Eicosafluoroundecanoic acid - SS
ND % ND % ND %
tj - Analyzed for but not detected,
j - present,' concentration estimated.
B - Detected in QC blank.
.
SS - Surrogate^Standard reported as percent recovery.
Comments: Surrogates were not determined due to the large dilution required for analysis
Form I
RJZ016286
C H 2M H ILL
OuaTity A n a lytica l Laboratories
2567Fairiane Drive, P.O.Box230548. Montgomery. Alabama 36116
000003
2 0 5 .2 7 l.i4 4 4
EID939364
ORGANICS ANALYSIS DATA SHEET
.uaboratory Name : CH2M HXLD/MGM Lab Sample ID: 24727001RB___ Client Sample ID: CENTRI STREAM
Concentration: LOW
Date Extracted: 06/01/93
Sample Matrix: WATER Date Analyzed: 06/03/93
Percent MoiBture: ______ Dilution Factor: ----- 5 -P
FC-143
CAS Humber
_______________ ___________ .ng/D
3825-26-1 FC-143 .................
3'
Perfluorononanoic acid - SS Perfluorodecanoic acid - SS _ liH-EicoBafluoroundecanoic acid - SS
70 * 50 V 42 *
U - Analyzed for but not detected. J - Present/ concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments: This is a re-extraction of sample 24727001 to investigate low surrogate recovery from the original extraction. Only 50 mL were extracted rather than the usual 1000 mL due to the expected high concentration of FC-143.
Form I
RJZ06287
C H 2M H ILL
Q uality A n a ly tic a lLaboratories
2567Fairiane Drive. P.O. Box230548. Montgomery,Alabam a36116
000004
205.271.1444
EID939365
ORGANICS ANALYSIS DATA SHEET
laboratory Name; CH2M HILL/MGM T.ah Sanple ID: 24727002----Client Sample ID: LEACHATE_____
Concentration: LOW
Date Extracted: 05/|l/23.
Sample Matrix: WATER Date Analyzed: ,05 28 9 3
Percent Moisture: ______ Dilution Factor: --- :-- 20
FC-143 '
ras Number
ucr/L
3825-2S-1 FC-143
17
Perfluorononanoic acid - SS
Perfluorodecanoic acid - _SS _ llH-Eicosafluoroundecanoic acid - SS
ND % ND % ND %
U - Analyzed, for but not detected. & _ present,' concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments: Surrogates were not determined due to the large dilution required for analysis
Form I
sr,9X0zra
C H 2M H LL
Q ua lity A n a lytica lLaboratories
2 5 6 /F a irta n e D rive, P.O. B ox230548, M ontgom ery, A labam a36116
fiM ,Q P 5
EXD939366
ORGANICS ANALYSIS DATA SHEET
jaboratory Name : CH2M HILL/MGM
Lab Sample ID:
24727002RB
Client Sample ID: T.KRCHATB_____
Concentration: LOW
Date Extracted: 06/01/93
Sample Matrix: WATER Date Analyzed: 06/03/93.
Percent Moisture: ______ Dilution Factor: -----
FC-143
nas Number..... ................ .. ........ Kh Z$l
3825-26-1 F C - 1 4 3 .............- -
31
Perfluorononanoic acid - SS
Perfluorodecanoic acid - SS
-
llH-Bicosafluoroundecanoic acid - SS
63 % 78 % 60 %
D - Analyzed for but not detected, j - present,' concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported aB percent recovery.
Comments: This is a re-extraction of sample 24727002 to investigate low surrogate recovery from the original extraction. Only 50 mL were extracted rather than the usual 1000 m L due to the
expected high concentration of FC-143.
-
Form I
RJZ016289
..`u.'T.
C H 2M H ILL
Q ua lity A n a lytica lLaboratories
2567F airfane D rive. P .0 . B ox230548. M ontgom ery. Alabam a 36116
OOOOOG
20 5.27 t.144 4
EID939367
ORGANICS ANALYSIS DATA SHEET
laboratory Name : CH2M HILL/MGM
Lab Sample ID;
24727003-----
Client Sample ID: WEST STREAM__
Concentration: LON
Date Extracted: 05/24/93
Sample Matrix: WATER Date Analyzed: 05/28/23.
Percent Moisture: ______ Dilution Factor: ----- ILJ)
FC-143
c as Humber
Ug/li
3825-26-1 FC-143
3.2
Perfluorononanoic acid - SS Perfluorodecanoie acid - SS llH-Eicosafluoraundecanoie acid - SS
25 V 27 * 27 %
U - Analyzed for but not detected, j - Present, concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery
Comments:
Form I
RJZ016290
C H 2M H ILL
.
Q uality
.
A nalyticalLaboratories
2567Fairiane Drive, P.O. Box230548. Montgomery,A!abam a36116
EID939368
ORGANICS ANALYSIS DATA SHEET
Laboratory Name; CH2M HILL/MGM
Lab Sample ID;
24727003HB
Client Sample ID: WEST STREAM
Concentration: LOW
Date Extracted: 06/01/93
Sanple Matrix: WATER Date Analyzed: 06/03/93
Percent Moisture: ______ Dilution Factor: _____ 5.0
FC-143
CAS Number
__________________ _______!-- ucf/h._
3825-26-1 FC-143 .................
11
PerflUoronananoic acid - SS
102 %
Perfluorodeeanoic acid - SS
66 %
IIH-Eicosafluoroundeeanoic acid - SS 62 %
U - Analyzed for but not detected, or - Present,, concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments This is a re-extraction of sample 24727003 to investigate low surrogate recovery from
the original extraction. Only 200 mL were extracted rather than the usual 1000 mL due to the
expected high concentration of FC-143.
'
Form I
RJZO16291
C H 2M H ILL
Q u a lity A n a lytica lLaboratories
2567Fairlane D riveJ'.O. Box230548. M ontgom ery. Alabam a36116
000008
205.271.1444
EID939369
ORGANICS ANALYSIS DATA SHEET
laboratory Name : .CH2M HILL/MGM Lab Sample ID: 24727004_____ Client Sample ID: WELDfll__ :____
Concentration: LON Sample Matrix: WATER
Percent Moisture : ____.
Date Extracted: 05/24/93 Date Analyzed: 05/28/93
Dilution Factor: -----
FC-143
pas Number 3825-26-1 FC-143 .
uq/L 0.6
Perfluorononanoic acid - SS Perfluorodecanoic acid - S S ^ 11H-Eicsafluoroundecanoic acid - SS
8V 11 %
8%
V - Analyzed for but not detected, j - present/ concentration estimated.
B - xDetected in QC blank. SS - Surrogate Standard. reported as percent recovery.
Comments:
Form I
RJZO16292
CH2MHILL
Q uality A nalyticalLaboratories
2567Fairkmo Uvo, P.O. Box23G548, Montgomery. Alabama3611B
000009
205.271.1444
i
EID939370
ORGANICS ANALYSIS DATA SHEET
jratory Name: PH2M HILIi/MGM
ah Samole ID;
247270D4RB
'lient Sample ID: NEU. #1
Concentratiioonn: Sample Matrix;
DOW WATER
Percent Moisture: _____
Date Extracted: 06/01/93 Date Analyzed: 06/03/93 Dilution Factor: _____ l'.O
FC-143
!AS Number
1825-26-1 FC-143 .
2.1
Perfluorononanoic acid - SS Perfluorode canoic acid - SS 11H-Eicosafluoroundecanoic acid - SS
67 * 74 * Gl *
U - Analyzed for but not detected-
-
j - Present,' concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
'omments: This is a re-extractioh of sample 24727004 to investigate low surrogate recovery from he original extraction. Only 200 ml. were extracted rather than the usual 1000 mL due to the
.imitation of raw sample available.
'
Form I
RJZO16293
CH2MHILL
Quality AnalyticalLaboratories
2567Fairiane Drive, P.O. Box230548. Montgomery,Alabam a 36116
000010
205.271.1444
EID939371
frecHVTrrPfl AHALYSIS DATA SHEET
Laboratory Harne: CH2M HILL/MGM Concentration: Lab Sanrole ID: 24727005______ Sample Matrix: Client Sanale ID: T.W.#25_______ Percent Moisture:
Date Extracted: 05/24/93
Date Analyzed: 05/28/93
Dilution Factor:
'_5.0
FC-143
CAS Humber
un/L
3825-26-1 FC-143
4.3
Perfluorononanoic.acid - SS
Perfluorode canoi c acid - SS ^ HH-Eicosafluoroundecanoic acid - SS
tJ - Analyzed for but not detected. a - Present,-' concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments:
Form I
RJZO16294
C H 2M H ILL
QuaSty A n a ly tic a lLa b ora to rie s
2567Fatitene D rive, P.O. B ox230548. M ontgom ery, Alabam a 36116
000011
205.271.1444
EID939372
ORGANICS ANALYSIS DATA SHEET
Laboratory Name : CH2M HXLL/MGM Lab Sample ID : 24727005RB Client Sample ID: T.W.f25------
Concentration: LOW
Date Extracted: 06/01/9.3
Sample Matrix: WATER Date Analyzed: 06/23/21
Percent Moisture : _ _ _ _ _ Dilution Factor: ----- 5---0
FC-143
CAS Number
_____________ _______________ u9/**-
3825-26-1 F C - 1 4 3 .................
5
Perfluorononanoic acid - SS Perfluorodecanoic acid - SS IH-Eicosafluoroundecanoic acid - SS
88 V 81 % 77 V
U - Analyzed for but not detected.
.
J - Present, concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
This ia a re-extraction of sample 24727005 to investigate low surrogate recovery from . . a ratter tlrm tho rrurl loot X L a to tho
expected high concentration of FC-143.
Form I
RJZO16295
C H 2M H ILL
Q ua lity A n a lytica lLaboratories
2567F a irlane D rive. P.O. B ox230543. M ontgom ery. A labam a 36116
000012
2 0 5 .2 7 1 .1 4 4 4
EID939373
RGAHICS ANALYSIS DATA SHEET
Laboratory Same ; CH2M HILL/MGM Lab Sample ID: W05243B1_____ Client Sample ID: PC BLANK 1___
Concentration: LOW___ Date Extracted: Sample Matrix: WATER Date Analyzed: ,05/28/33 Percent Moisture: ______ Dilution Factor: ----- 1J0
PC-143
ras Humber
no/li
3825-26-1 PC-143
0.1 U
Perfluorononanoic acid - SS
Perfluorodecanoic acid - SS llH-Bicosafluoroundecanoic acid - SB
13 % 5% 7*
U - Analyzed for but not detected.
.
j - Present, concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments:
Form I
RJZO16296
CH2MH1LL
Q u a lity A n a ly tic a l Laboratories
2567Fairiane Drive, P.O. Box230549. Montgomery.Alabama 36116
000013
2D5.271.t444
EID939374
ORGANICS ANALYSIS DATA SHEET
Laboratory Name : rCHa2wM HwItLtL.t/.]/m g m . Concentration: LON
Lab Sample ID:
WW0055224433BB22________ Sample Matriixx:
WATER
Client Sample ID: OC BLANK 2
Percent MoiBture: _____
Date Extracted: 05/24/93
Date Analyzed: 05/28/93 Dilution Factor: _____ 1-- 00
FC-143
CAS Number _______ _
3825-26-1 FC-143 . .
Perfluorcrcionanoic acid - SS Perfluorodecanoic acid - SS _ llH-Eicosafluoroundecanoic acid - SS
19 % 20 % 17 %
0 - Analyzed for but not detected.
.
" j - present, concentration.estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments:
Form I
RJZ016297
CH2MHIUL
Q ua lity A n a ly tic a lLaboratories
25 67F airiane D rive. P.O. B ox230543, M ontgom ery,A labam a 36116
000014
205.271.1444
EID939375
ORGANICS ANALYSIS DATA SHEET
Laboratory Name: CH2M HILL/MGM Lab Sanale ID: W06013B1_____ Client Sanale ID : OC BLANK 3
Concentration: LON
Date Extracted: 06/01/93
Sample Matrix: WATER Date Analyzed: PJZ.Q3Z.g3
Percent Moisture: ______ ' Dilution Factor: ___;__l_-_Q
PC-143
CAS Number
__________________________
Z^1--
3825-26-1 PC-1 4 3 ...... ..
0 .1 V
Perfluorononanoic acid - SS Perfluorodeeanoic acid - SS IIH-Eicosafluoroundecanoic acid - SS
100 % 92 %
77 %
Xj - Analyzed for but not detected.
a - Present, concentration estimated.
B - Detected in QC blank.
'
SS - Surrogate Standard reported as percent recovery-
Coxnments :
Fona I
RJ2016298
C H 2M H ILL
Q ualify A n a ly tic a lLab ora to rie s
2567Fairiane Drive, P.O.Box230548.
Montgomery, Alabama 36116
000015
205271.1444
EID939376
FC --143 MATRIX SPIKE / MATRIX SPIKE DUPLICATE RESULTS
Moratory Name: CH2M HILL/MGM
Case No: 24727
Extraction (S E P F/C O N T/S O N C ): SEPF
Matrix: Water
Native Sample Lab ID: 24727004
Laboratory Method Blank: W05243B1 and
W05243B2
Spike Sample
Added Cone.
Compound
(uq/L) (ug/L)
FC--143
2 0.57
MS Laboratory ID: 247Z7M04 MSD Laboratory ID: 24727D04
MS 1 MS
Cone.
%
(ug/L) Recov
0.75
9
MSD Cone. (ug/L)
0.87
MSD %
Recov
15
RPD 15
C9 - Surrogate C10 --Surroqate C11 -- Surrogate
2 ---------- 2-- 2--
0.13 0.13 o .n
7 0.25 7 0.30 6 0.20
12 62 15 78 10 56
Associated Blank Spike Laboratory ID: BW052431.
Compound FC--143
Spike Added fug/L)
1
BS Cone.
(ug/L)_ 0.21
BS % Recov
21
C9 - Surrogate
C10 -- Surrogate C11 -- Surrogate
1 0.12
1 0.11 1 0.13
12
11 13
Comments: Only 0.5 L was extracted for the MS and for the MSD due to a limitation of raw sample available.
RJZ016299
Rie ID: F24727F3.WK1
Form 3
000016
EID939377
FC --143 MATRIX SPIKE f MATRIX SPIKE DUPLICATE RESULTS
Laboratory Name: CH2M HILL/MGM
Case No: 24727
Extraction (SEPF / CONT / SONC): SEPF
Matrix: Water
Native Sample Lab ID: 24727001RE Laboratory Method Blank: W06013B1
MS Laboratory ID: 24727M01 MSD Laboratory ID: 24727D01
Compound FC--143
G9 - Surrogate C10 --Surrogate C11 -- Surrogate
Spike Sample Added Cone.
(ug/L) (ug/L) 20 36.6
MS Cone. (ug/L)
52.5
MS
% Recov
80
MSD Cone. (ug/L)
55.7
MSD
% Recov
96
RPD 6
20 -- 20 -- 20 --
14.0 12.4 12.9
70 21.80 62 21.40 65 17.80
109 107
89
44 53 32
Associated Blank Spike Laboratory ID: BW060131
Compound FC--143
Spike Added
(ug/L) 1
BS Cone. (ug/L)
0.64
BS
% Recov
64
G9 - Surrogate C10 -- Surrogate C11 -- Surrogate
1 0.83 1 0.91 1 0.86
83 91 86
Comments: Only a 0 .0 5 -liter aliquot was extracted for the MS, the MSD, and 2472701 RE due to a limitation of raw sample available.
RJZ016300
File ID: F24727F3.WK1
Form 3
000017 EID939378
000018
RJZ016301
CHSM HILL Project S
PrejeetNam
L OC,*e- t U p J f I
C . ^ tv
y __ - 3 _________________ -
Company Nme/CH2M HILL Olile
project Manager 4 Pftona a
Report Copy to:
Mr. J I
/C7
,,,
Ma. [ J Or. r 1
e t u < L o o V T b to n -V
Requeated Complallon Dqte: Sampling Requirement -Sample'Dlapoaal!
SOWA NPOES RCRA OTHER Dlapoa Return
---------
Sampling
CLIENT SAMPLE ID (9 CHARACTERS)
i - lil0 **
\D%
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(tifili-
U va T651r uuuc 3
ANALYSES requested r -------------- 1
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Project *
L M r o ? , $ a l l > ` ' X x{
Noi ol Sample
Pagi
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LAB 1 LAB 2 ID ID
OC]
Ar*-* dpU'.tCC.H- s T"
T U * 7 ^
co-2
003 ao<-fi
'Jo fc. 'T h'*Sy C O ,
S t * i f t * 5 &Q~~
__________!1:___; \sA&.-^vStk__ _`___: _____--^
TRHTJR OF CONTENTS ov n v tttt.t. laboratory Kef. Ho. 24727
` List of Organic Data Qualifiers .......... ................ *
.....
Page
Ho.X
LiBt of Sample ID Qualifiers ................... ........................
Client Sample Cross-Reference ........ .......................... .
iii
FC--143 DATA case Narrative Sample Results Blank Results KS/MSD Results
Copy of COC Documentation
1
3 13 16
18
RJZ016280
CH2MHILL
d u a lity A nalyticalLaboratories
2S7Fairlane D rive,P.O. B ox23054B. M ontgom ery,A labam a 36115
205-271.1444
EID939358
ORGANIC DATA gOALIFlEBS
XJ -- Indicates the compound was analyzed for but not detected. The number adjacent to the "0" qualifier indicates the reporting limit for that compound. The reporting limit can vary from sample to sample depending on dilution factors or percent moiBture adjustment when indicated.
J -- Indicates an estimated value. It is used when the data indicates the presence of a compound below the stated reporting limit.
c __This flag applies to GC pesticide results only- The "C" flag indicates the presence of this compound-has been confirmed by GC/MS analysis. (This definition is still being reviewed and discussed).
B -- This flag is used when the analyte is found in the associated blank as well as the sample. This notation indicates possible blank contamination and suggests the data user evaluate these compounds and
their amounts carefully.
.
B -- This qualifier indicates that the value reported exceeds the linear calibration range for that compound. Therefore, the sample should be reanalyzed at an appropriate dilution. The "B" qualified amount is an estimated concentration, and the results of the dilution will be
reported on a separate Form I
D __ This qualifier indicates compounds which have been identified during a diluted reanalysis. "D" qualifiers are used for samples that have been analyzed initially at a lesser dilution than required for accurate -
quantitation.
.
* __ This qualifier indicates that the response for the compound exceeded the linear range of the instrument. Therefore, this is an estimated concentration.
P __This qualifier is used for a pesticide/Aroclor target analyte when there is greater than 25% difference for detected concentrations between the two GC columns. The lower of the two values is reported on Form I and
flagged with a "P " .
H __This qualifier indicates presumptive evidence of a compound. This flag
is only used for tentatively identified compounds, where the
.
identification is based on a masB spectral library search. It is
applied to all TIC results. For generic characterization of a TIC,
such as chlorinated hydrocarbon, the "H" qualifier is not used.
A -- qualifier indicates that a TIC is a suspected aldol-condensation
product.
.
CH 2M H ILL
O va lity A nalytical Laboratories
i
2567Fairiane D rive. P.O. B ox230548. M ontgom ery.Alabam a 36116
205.271.1444 .
RJZ016281
EID939359
ORG&NIC TAB SBMPtK 10 QTOX.IFIERS
The qualifiers that may be appended to the lab Sample XD for organic analyses
are defined belowt
E L __ Dilution Run. Indicates the sample contained compounds exceeding the calibration range. The sample was diluted and reanalyzed. Both results are reported.
X i __Rerun. The sample was reanalyzed. The "R" is not used if the ' sample was also re-extracted.
ICE -- Re--extraction ftnalysiB. The sample was re-extracted and
reanalyzed.
.
U S __Matrix Spike (may be followed by a digit to indicate multiple
matrix spikes within a sample set)
-
U S D __Matrix Spike Duplicate (may be followed by a digit to indicate multiple matrix spike duplicates within a sample set)
RJZ016282
- :
' " -S .
C H 2M H ILL
Q uality A n a lytica lLaboratories
ii
2S67Fm riane D rive. P.O. Box230548, M ontgom ery.A labam a 3611S
205.271.1444 ~
EID939360
CLIENT SAHELS CROSS--BKFEHKNCK PH9H TTTT.T. Laboratory Ref. Ho. 24727
LMG Sample ID
24727001 24727002 24727003 24727004 24727005
Client Sample ID
CENTRAL STRBAK LEACHATE WEST STREAM WELL #1 . T.W. #25
RJ2016283
C H 2M H ILL
Q uality A nalyticalLaboratories
ill
2567Fairtane D rive, P.O. Box23054ff, M ontgom ery,Alabam a36116
205.271.1444
EID939361
CASE NARRATIVE GC FC--143 SAMPLES
LABORATORI : CH2M HILL LABORATORIES
CASE NO.
t N/A
LAB REF- NO.: 24727
CLIENT: DUPONT CONTRACT NO.: N/A
SDG NO.: N/A
I. RECEIPT
A. Date: May 20, 1993
B. Sample Information
LAB CLIENT fcMPT.F. TT) SAMPLE ID
SAMPLE MATRIX
24727001 2472700IRE 24727002 24727002RB 24727003 24727003RE 24727004 24727004RE 24727005 24727005RE WD5243B1 W05243B2 W06013B1
CENTRLSTREAM WATER
CENTRLSTREAM RE WATER
LEACHATE
WATER
LEACHATE RE
WATER
WEST STREAM
WATER
WEST. STREAM RE WATER
WELLil
WATER
WELLtl RE T.W.425
WATER WATER
T.W.#25 RE
WATER
QC BLANK 1
WATER
QC BLANK 2
WATER
QC BLANK 3
WATER
DATE
EXTRACTION ANALYSIS
SAMPLED
'DATE
DATE
05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93 05/19/93
N/A N/A N/A
05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 06/01/93 05/24/93 05/24/93 06/01/93
05/28/93 06/03/93 05/28/93 06/03/93
05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 06/03/93 05/28/93 05/28/93 06/03/93
RJZ016284
C. Documentation Exceptions : No exceptions were encountered.
II. EXTRACTION
A. Holding times: Holding times were met for all original extractions. However, re-extractions were performed beyond the 7-
day holding time.
C H 2M H ILL
Q ua lity A n a ly tic a lLaboratories
2567Fabiane D rive. P.O. Box230548. M ontgom ery, A fabam a36116
000001
205.271.1444
EID939362
FC--X43 hAB BEF- HO- 24727 PAGE 2
B. Extraction Exceptions
: All field samples were re-extracted to investigate low spike recoveries in the original extractions.'
Smaller aliquots were used for the re-extractions to provide more insurance that surrogates would not be
diluted out.
.
1X1. ANALYSIS
No other exceptions were encountered.
A. Holding timess All holding times were met.
B. Analytical Exceptions
.
t Several samples were diluted to prevent FC-143 from exceeding the calibration range. Both the original
and the re-extractionB are reported since the re
work was performed beyond the extraction holding
time.
`
No other exceptions were encountered.
XV. QUALITY CONTROL
A. Method Blank ; FC-143 was not present in any of the laboratory ' blanks.
B. Surrogate Recoveries : All Bamples were re-extracted and reanalyzed as a corrective action for poor spike recoveries observed in the original work.
C. Matrix Spike Results
All re--extracted samples met acceptable .QC limits.
Matrix spike results have been reported with this contract along with the laboratory control sample (blank Bpike) results. The analytical system was not in control for original extractions performed on 05/24/93. Spike recoveries were back to normal for the re--extractions performed on 06/01/93.
I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in thiB hardcopy data package has been authorized by the Laboratory Manager or his desginee, as verified by the following sxgnature.
C H 2M H ILL
GC Supervisor
Date
Q uality A n a lytica lLaboratories
2567Fairtane D rive. P.O. B ox230543. M ontgom ery. A labam a 36116
000002
205J271.1444
RJZ016285
EXD939363
ORGANICS ANALYSIS DATA SHEET
Laboratory Name : CH2M H1LD/MGM Dab Sample ID: 24727001 Client Sample ID: CENTRI STREAM
Concentration: DOW
Date Extracted: 052.493.
Sample Matrix: WATER Date Analyzed: 05/28/93
Percent Moisture: ______ Dilution Factor: ...-.20
FC-143
CAS Number
............... ........ uq/D.
3825-26-1 FC-143 ................
21
Perfluorononanoic acid - SS
HD %
Perfluorodecanoic acid - SS
HD %
HH-Eicosaf luoroundecanoic acid - SS ' HD If
TJ - Analyzed for but not detected,
j - present,' concentration estimated.
.
B - Detected in QC blank.
.
SS - Surrogate .Standard reported as percent recovery.
Comments: Surrogates were not determined due to the large dilution required for analysis.
Form I
RJZ016286
s'r 4t
CH2MHILL
Ouanty AnalyticalLaboratories
25 67Fairiane D rive, P.O. B ox230548. M ontgom ery. Alabam a 36116
000003
205.271.1444
EID939364
ORGANICS ANALYSIS DATA SHEET
Laboratory Name: CH2M HILL/MGM
Lab Sample ID:
24727001RB
Client Sample ID: CENTRA STREAM
Concentration: LOW
Date Extracted: 06/01/93.
Sanale Matrix: WATER Date Analyzed: 06/03/93
Percent Moisture: ______ Dilution Factor:
5.0
FC-143
CAS Number
_______________ ___________WtZt
3825-26-1 FC-143 .................
3'
Perfluorononanoic acid - SS Periluorodecanoic acid - SS ^ HH-Eicosafluoroundecanoic acid - SS
70 * 50 % 42 *
D - Analyzed for but not detected. J - Present, concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments: This is a re-extraction of sanale 24727001 to investigate low surrogate recovery from the original extraction. Only 5 mL were extracted rather than the usual 1000 L due to the
expected high concentration of FC-143 .
-*
Form I
RJZ016287
CH2MHILL
Duality . A n a ly tic a lLaboratories
2567FatrianeDrive, P.O. Box230548, Montgomery.Alabama36116
000004
205.271.1444
EID939365
ORGANICS ANALYSIS DATA SHEET
Laboratory Name: CH2M HIIX./MGM Concentration
LOW
Lab Sample ID:
24727002______ SSaanmppllee MMaattrriixx:
WATER
Client Sample ID: LSACHAi'b
Percent Moisture: _____
Date Extracted: 05/24/93
Date Analyzed: 05/28/93
Dilution Factor:
~ 20
FC-143 '
CAS Number
u g /k
3825-26-1 FC-143
Perfluorononanoic acid - SS Perfluorodecanoic acid - SS llH-Eicosafluoroundecanoic acid - SS
ND % ND V ND %
U - Analyzed for but not detected, j - present,' concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments: Surrogates were not determined due to the large dilution required for analysis.
Form I
RJZ0162S
CH2MHLL
Q uality .
A nalyticalLaboratories
25 67F airian e D rive, P.O. B o x230548, M ontgom ery. Alabam a 36116
EXD939366
ORGANICS ANALYSIS DATA SHEET
Laboratory Name: CH2M HILL/MGM
LaJb Sample ID:
24727002RB
Client Sample ID: T.RRCHA.TR_____
Concentration: LOW
Date Extracted: 06/01/ 9.3
Sample Matrix: WATER Date Analyzed: 06/03/93
Percent Moisture: ______ Dilution Factor: --- 5 -..
FC-143
CAS Number
.................... ........ P H
3825-26-1 F C - 1 4 3 .......... ..
31
Perfluorononanoic acid - SS Perfluorodecanoic acid - SS llH-Eicosafluoroundecanoic acid - SS
63 % 78 % 60 %
D - Analyzed for but not detected, j - present,' concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments: This is a re-extraction of sample 24727002 to investigate low surrogate recovery f*pm the original extraction. Only 50 m L were extracted rather than the usual 1000 m L due to the ejected high concentration of FC-143.
Form 1
RJZ016289
C H 2M H ILL
O vality A n a lytica lLaboratories
25 67Fabiane D rive, P.0 . B ox230548, M ontgom ery. Alabam a 36116
000008
2 0 5 .2 7 1 .1 4 4 4
EID939367
ORGANICS ANALYSIS DATA SHEET
Laboratory Name : CH2M HILL/MCM Lab Sample ID; 24727003_____ Client Sample ID: WEST STREAM
Concentration: LOW
Date Extracted: 05/24/93
Sample Matrix: WATER Date Analyzed: .05/28/33
Percent Moisture: ______ Dilution Factor: _____ 5 .0
FC-143
CAS Number ____________________ __________ RaZk
3825-26-1 FC-143 .................
3.:
Perfluorononanoic acid - SS
Perfluorodecanoic acid - SS
llH-Eicosafluoroundeeanoic acid - SS
25 V 27 Ir 27 %
U - Analyzed for but not detected, j - Present, concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments:
Form I
RJZO16290
CH2M HILL
. Quality . A n a lytica lLaboratories
25 67Fairiane Drive, P.O. Box230543. Montgomery, A tabam a36116
nana?
EID939368
ORGANICS ANALYSIS DATA SHEET
Laboratory Name : CH2M HILL/MGM
Lab Sample ID:
24727003RB
Client Sample ID: WEST STREAM
Concentration : LOW Sample Matrix: WATER Percent Moisture: _____
Date Extracted: 06/01/93 Date Analyzed: 06/03/93 Dilution Factor: _____ 5.0
FC-143
CAS Number
' uq/li
3825-26-1 FC-143 .
11
Perfltiorononanoic acid - SS Perfluorodecanoie acid - SS llH-Eicosafluoroundecanoic acid - SS
102 % 66 % 62 %
U - Analyzed for but not detected, j - Present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments: This is a re-extraction of b ample 24727003 to investigate low surrogate recovery from the original extraction. Only 200 mL were extracted rather than the usual 1000 mL due to the expected high concentration of FC-143.
Form I
RJZO16291
C H 2M H ILL
Q uality AnalyticalLaboratories
2567F airianeD rhreJ,.0 . Box230543, M ontgom ery,A Iabam a36116
000008
205.271.1444
EID939369
ORGANICS ANALYSIS DATA SHEET
Laboratory Name: .CH2H HIUi/MGM T-aV> Sample ID: 24727004_____ Client Sample ID: HBIJ>ftl '
Concentration: LOW
Date Extracted: 05/24/93
Sanale Matrix: HATER Date Analyzed: 05/28/93
Percent Moisture: ______ Dilution Factor: _____1JL
FC-143
CAR Number ........................ .. -- -- HS/fe.
3825-26-1 F C - 1 4 3 .................
0-1
Perfluorononanoic acid - SS Perfluorodecanoic acid - SS 11H-Eicsafluoroundecanoic acid - SS
8% 11 1
8V
D - Analyzed for but not detected, j - present," concentration estimated.
B - detected in QC blank. SS - Surrogate Standard, reported as percent recovery.
Comments:
Form I
RJZO16292
CH 2M H ILL
Q uality A n a lytica lLaboratories
2567F airlane D rive, P.O. BOX230548, M ontgom ery. A labam a36116
000009
205.271.1444
EID939370
ORGANICS ANALYSIS DATA SHEET
.moratory Name: CH2M HILD/MGM ' Concentration: PON
jab Sample ID: 24727004RB
Sanmple Matrix: WATER
Hient Sample ID: WEDP #1
Percent Moisture: _____
Date Extracted: 06/01/93 Date Analyzed: 06/03/93 Dilution Factor: _____ l'.O
FC-143
IAS Number
ua/I
1825-26-1 FC-143 - .
2 .1
Perfluorononanoic acid - SS Perfluorodecanoic acid - SS IIH-Eicosafluoroundecanoic acid - SS
67 * 74 V 61 %
U - Analyzed for but not detected. J - Present," concentration, estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
lonments: This is a re-extraction of sample 24727004 to investigate low surrogate recovery from
:he original extraction. Only 200 ml. were extracted rather than the usual 1000 ml. due to the
.imitation of raw sample available.
'
Form X
9
RJZO16293
CH2M HILL
Q ua lity A n a lytica lLaboratories
2 5 6 7 Fairlane Drive, P.O. Box230548, Montgomery.A labam a36116
000010
205.271.1444
EID939371
ORGANICS ANALYSIS DATA SHEET
laboratory Name: CH2M HIU./MGM Concentration: LOW
Date Extracted: 05/24/93
Lai Sample ID: 24727005______ Sample Matrix: WATER Date Analyzed: 05/28/93.
Client Sanple ID: T-W.&25_______ Percent Moisture: ______ Dilution Factor:
:-- 5J0
FC-143
CAS Number_________ :___________ L___________wt/ii-
3825-26-1 F C - 1 4 3 ........ .
. -__________ 4-3
Perfiluorononanoic.acid - SS Perfluorodecanoic acid - SS HH-Eicosafluoroundecanoic acid - SS
11 % B% 7%
tJ - Analyzed for but not detected, j - present,1concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported aB percent recovery.
Comments :
Form I
RJZ016294
C H 2M H ILL
D u a lity A n a ly tic a lLaboratories
2567F airianeD rive,P .O .B ox230548, M ontgom ery.Alabam a 36116
000011
2D 5271.1444
EID939372
ORGANICS ANALYSIS DATA SHEET
Laboratory Name: CH2M HIbb/MGM Concentration:
LOW___ Date Extracted: 06/01/9.3
Lab Sanale ID:
24727005RS
Sanale Matrix:
WATER Date Analyzed: 0 J 03J_93_
Client Sample ID: T-W.S25_______ Percent Moisture: ______ Dilution Factor: ----- 5J
FC-143
g a s Number
_____________ :_______________ hw/h-
3825-26-1 FC-143 .................
9-9
Perfluorononanoic acid - SS
88 %
Perfluorodecanoic acid - SS '
. 81 %
llH-Eicosafluoroundecanoic acid - SS 77 V
TJ - Analyzed for but not detected, j - Present, concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
.
Comments: This is a re-extraction of sample 24727005 to investigate low surrogate recovery from
the original extraction. Only 200 mL were extracted rather than the usual 1000 m L due to the
expected high concentration of FC-143.
'
Form I
RJZO16295
CH2MH1LL
D u a lity A n a lytica lLaboratories
2567F airtaneD rive,P .O .B ox230548, M ontgom ery.Alabam a 36116
000012
205.271.1444
EID939373
ORGANICS ANALYSIS DATA SHEET
Laboratory Name : CH2M HILL/MGM Lab Sample ID: W05243B1_____ Client Sample ID: OC BLANK 1
Concentration: LOW
Date Extracted: 05/24/93
Sample Matrix: . WATER Date Analyzed: 05/28/93
Percent Moisture: ______ Dilution Factor:
' 1.0
PC-143
ras Number___________ :_____' _____________ m / k
3825-26-1 F C - 1 4 3 ...............-
Perfluorononanoic'acid - SS Perfluorodecanoic acid - SS llH-Eicosafluoroundecanoic acid - SS
13 V
5V 7%
tr - Analyzed for but not detected. J - Present, concentration estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments:
Form I
RJZO16296
CH2M HIUL
Q ua lity A n a ly tic a lLaboratories
25 67Fabiane D rive, P.O. B ox230543, Montgomery, Alabam a 36116
000013
205.271.1444
EID939374
ORGANICS ANALYSIS DATA SHEET
Laboratory Name : CH2M BILL/MSM Lab Sample ID: W05243B2_____ Client Sample ID: OC BLANK 2
Concentration: LOW
Date Extracted: 05/24/93
Ssimple Matrix: WATER Date Analyzed: 05/28/93
Percent MoiBture: ______ Dilution Factor: _____ 1-0.
FC-143
CAS Number
ug/L
3825-26-1 FC-143
0.1
Perfluorononanoic acid - SS Perfluorodecanoic acid - SS ^ llH-Bicosafluoroundecanoic acid - SS
19 k 20 V 17 %
D - Analyzed for but not detected. " j - present,' concentration,estimated.
B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments:
Form I
RJ2016297
'if','
CH2MHILL
QueSty
A n a lytica lLaboratories
25B 7Fairlane D rive, P.O. Box230548, M ontgom ery, A labam a36116
000014
205.271.1444
EID939375
ORGANICS ANALYSIS DATA SHEET
Laboratory Name : CH2M HILL/MGM Lab Sample ID: W06013B1_____ Client Sample ID: OC BLANK 3
Concentration: LOW
Date Extracted: 06/01/93
Sample Matrix: WATER Date Analyzed: 06/03/93
Percent Moisture: ______ Dilution Factor: ' 1.0
PC-143
ras Number
_____________________________ uq/li--
3825-26-1 FC-143 ...... . . . . .
0.1 U
Perfluorononanoic acid - SS
100 %
Perfluorodecanoic acid - SS
92 V
IIH-Eicosafluoroundecanoic acid - SS 77 %
g - Analyzed for but not detected, j - present, concentration estimated. B - Detected in QC blank. SS - Surrogate Standard reported as percent recovery.
Comments:
Form I
RJZ016298
C H 2M H ILL
d u a lity A n a lytica lLa boratories
2567Fairiane D rive, P.O. B ox230548. M ontgom ery, A labam a 36116
000015
20 5271 .14 44
EID939376
-.
FC --143
MATRIX SPIKE / MATRIX SPIKE DUPLICATE RESULTS
aboratory Name: CH2M HILL/MGM
Case No: 24727
Extraction (S E P F/C O N T/S O N C ): SEPF
Matrix: Water
Native Sample Lab ID: 24727004
Laboratory Method Blank: W05243B1 and
W05243B2
Spike Sample
Added Cone.
Compound
(ug/U (ug/U
FC--143
2 0.57
MS Laboratory ID: 24727M04 MSD Laboratory ID: 24727D04
MS Cone. (ug/U
0.75
MS % Recov
9
MSD Cone. (ug/L)
0.87
MSD %
Recov
15
RPD 15
C9 -- Surroqhte C10 --Surrogate C11 -- Surrogate
2-- 2-- 2--
0.13 0.13 0.11.
7 025 12 62
7 0.30
15 78
6 0.20 10 56
Associated Blank Spike Laboratory ID: BW052431
Compound FC--143
Spike Added
(ug/U 1
BS Cone.
(ug/L) 0.21
BS % Recov
21
C9 -- Surrogate
C10 -- Surrogate C11 -- Surrogate
1 0.12
1 0.11 1 0.13
12
11 13
Comments: Only 0.5 L was extracted for the MS and for the MSD due to a limitation of raw sample available.
RJZO16299
Rie ID: F24727F3.WK1
Form 3
00001G
EID939377
FC --143 MATRIX SPIKE / MATRIX SPIKE DUPLICATE RESULTS
Laboratory Name: CH2M HILL/MGM
Case No: 24727
Extraction (SEPF / CONT / SONC): SEPF
Matrix: Water
Native Sample Lab ID: 24727001RE Laboratory Method Blank: W06013B1
MS Laboratory ID: 24727M01 MSD Laboratory ID: 24727D01
Compound FC--143
C9 - Surrogate C10 - Surroqate C11 - Surrogate
Spike Sample Added Cone. (ug/L) (ug/L)
20 36.6
MS Cone. (ug/L)
52.5
MS % Recov
80
MSD Cone. (ug/L)
55.7
MSD %
Recov 96
RPD 6
20 -- 20 -- 20 --
14.0 12.4 1Z9
70 21.80 62 21.40 65 17.80
109
107 89
44 53 32
Associated Blank Spike Laboratory ID: BW060131
Compound FC--143
C9 --Surrogate C10 - Surrogate C11 - Surrogate
Spike Added (ug/L)
1
BS Cone. (ug/L)
0.64
BS
% Recov
64
1 0.83 1 0.91 1 0.86
83 91 86
Comments: Only a 0.05--liter aliquot was extracted for the MS, the MSD, and 2472701 RE due to a limitation of raw sample available.
RJZ016300
File ID: F24727F3.WK1
Form 3
000017
EID939378
J Hv-
RJZ016301
000018
