Document RJ5gLpBKQ9yDYy4G9Xxo9wjR8

TO: Eric Meyer jet act TG6*. Interoffice Communication FROM: DATE: SUBJ: T. G. Grumbles April 29, 1991 PROPOSED LOUISIANA PROCESS SAFETY REGULATIONS VIS1A Attached is an early draft of Louisiana Process Safety Regulations. The requirements of this proposal exceed OSHA's proposed rules and would create greater administrative and technical burdens than those regulations. If we feel we should make comments, they should be coordinated through Mike Hayes at the LCCP. a T. G. Grumbles dlj cc: T. H. Huffman M. G. Hayes, J. Friend-LCCP BUOOY ftOEMIR Governor State of Louisiana Department of Environmental Quality April 19, 1991 PAUL TEMPLET Secretary To: Advisory Committee Member Ret Accident Prevention Advisory Committee Meeting Dear Committee Member, The first meeting of the committee to consider Air Toxics Accident Prevention regulations will take place April 25, at 9:30 AM. The meeting will be held at the sixth floor hearing room at onr new facility on Bluebonnet Dr. For those of you who have not seen our new building, it is located at the back of the Swaggard Ministry complex, on the left side of Bluebonnet as you travel from Perkins toward the MO. As you enter from either entrance on that side of the complex, follow the drive to the back parking lot and look for a six*story gold-colored glass building. Visitor parking is available in front, or you can park in any slot marked DEQ parking. Please find enclosed a copy of the draft regulations and an agenda. We hope you will have adequate time to review the regulations before the meeting. If you should have any questions or problems, please feel free to call me at 765-0129. We look forward to seeing everyone at the meeting. Sincerely yours. William H. Perkins Air Quality Division, DEQ VVV 000006329 OPPlCC OF AIR QUALITY P O. SOX 44006 BATON ROUGE. LOUISIANA 70604 AN EQUAL OPPORTUNITY EMPLOYER Accident meeting agenda April 25, 1991 Prevention Advisory (Tentative Agenda* Committee Time Activity Responsible Person 9S30 9*43 Start Meeting Orientation William Perkins Chuck Handrich io:oo Review Proposed Rule All open Next Meeting Scheduled All Meeting Closed PLEASE NOTE All meraoers of the advisory committee snould have received a copy of the newly drafted proposed Accaoent Prevention rule. Please be prepared to participate in a significant edit of this first draft of the proposed rule at this moating. However, any comments regarding edits should identify specifically what is "wrong*', why the phrase or section Is thought to fie in error, the specific phrasing that would be desired to correct tno suspected error and why the new phrasing is *n imorcvement General comments reqarainq the dislike for a phrase cannot support future edits without a '9CDflinfl#d direction to correct errors? VW 000006330 DRAFT/April 19, 1791 Title 33 ENVIRONMENTAL. QUALITY Part III- Air Chapter 29- Chemical Accident Prevention and Minimisation of Consequences Subchapter A Applicability* Definitions, dimeral Provisions- Prohibitions and S5901. Applicability The requirement * af this chapter apply to any facility at which there ). s present an amount of any uoulsiana Extremely Hazardous Substance equal ts or greater than its threshold planning quantity <See Table 39.13; or any facility designated- after public notice and opportunity for comment, by the Governor. For purposes of this chapter, an "weight of any Louisiana Extremely Hazardous Substance1' means the total amount of a Louisiana Extremely Hazardous Substance present at any one time at a facility at concentrations greater than one percent by weight, regardless of location, number cf containers, or method of storage. 99903. Definitions Acciaental Release--The direct or indirect introduction of a Louisiana Extremely Hazardous Substance into the air under circumstances which are not .authorized pursuant to any permit or amission limitation ar standard. Facility--All auild:ings, equipment- structures, ano other stationary items which are located on a single site or on contiguous or adjacent sites and whicn are owned or operated by 1 WV 000006331 DRAFT/Apr11 19, 1991 the same parson (or by Any parson which controls, ay, or under camiTion control with, such person;. is controlled Louisiana Extremely Hazardous Substance (LEHS)-- 1. A Substance listed in Table 57.1 of this chapter. 2. Any flammable liquid or flammable gas, except fort a. Hydrocarbon fuels used solely for workplace consumption as a fuel! b. Flammable Liquids stored or transferred which are kept below their atmospheric boiling point without benefit of chilling or refrigeration. Threshold Planning Quantity--The quantity of an LHE5 in pounds at, or above, which a facility Is required to comply with this Chapter. For a substance referenced in Table 59.1, the quantity listed ;n the column "threshold planning quantity" for that substance. ror flammable liquids and flammable gases, 10,000 pounds. 95905, Prohibitions A. No owner ar operator of any facility regulated under this Chapter shall operate a facility unless they annually (during each calendar year* report to the Department of Public Safety and Corrections in accordance with LAC 332V.Chapter 101 on forms provided by that Department. B. No owner or operator of any existing facility regulated under this Chapter shall, after (insert date-365 calendar days , 000006332 DRAFT/April 19, 1991 from promulgation of this Chapter), opiiratC A -facility unlitt they htva Buonutted a Risk Managemant Plan no the Department of Environmental Quality. Air Quality Division and have rtctived a written letter of acceptance from the department. C. No owner or operator of a new facility regulates under this Chapter snail startup a facility unless they have submitted a Risk Management Plan to* the Department of Environmental Quality, Air Quality Division and have received a written letter of acceptance from tne department. D. No owner or operator af a facility shall handle* use, store* manufacture, or transport an LHES without submitting a Risk Management Plan to the Department of Environmental Quality, Air Quality Oivision and have received a written letter of acceptance from the department prior to handling, using, wtoring, manufactunng, or t.ranaporfing the LHES at the facility in an amount eoual to or greater than it* threshold planning quantity. E. No owner or operator of any facility regulated under this Chapter shall continue operation of the facility without annual notification to the Department of Environmental Quality, Air Quality Division, as specified in Paragraph 8.3. 19907 Qenerel Provision* A. Calculation af Threshold Planning Quantities for Solids and Mixtures 1. If a container or storaqe vessel holds a mixture or solution of a Louisiana Extremely Hazardous Substance* then the VVV 000006333 DRAFT/Apr11 19, 1991 concentration of Louisiana Extremely Hazardous Substance* in weight percent (greater than 1 percent** shall be multiplied by the mass (in pounds) in the vessel to determine the actual Quantity of Louisiana Extremely Hazardous Subetance therein. 2. Louisiana E::tromely Hazardous Substances that are solids are nubjeet to either of two threshold planning quantities as shown in Table i <l.e.f 300/10,QUO pounds). The lower quantity applies only if the solid exists in powdered form and has a particle size less than 100 micronsi or is handled in solution or in molten formt or meets the criteria for a National Tire Protection Association (NFPA) rating of 2* 3 or 4* for reactivity. If the uolid does not meet any of these criteria, it ie subject to the upper <10,000 pound) thresnold planning quantity as shown in Table 39,1. 3. The 100 micron level weight may be determined by multiplying the weight percent of solid with a particle size less than 100 micron* in a particular container by the total weaqht of solids in the container. 4. The weight of solid in solution /nay be determined by multiplying the weight percent of solid in the solution in a particular container by the total weiqht of >3oiution in the container. 5. The weight of solid in molten form must be multiplied by 0.3 to determine whether the lower threshold planning quantity is met* VVV 000006334 4 DRAFT/ApMl 19, 1991 B. Risk rianagement information 1, Risk management Plane which are submitted to the Department of Environmental Quality snail contain* as a minimum, the following: a. A list of LHESs which arm handled. used, stored, manufactured, or transported in quantities qraater than or equal to the threshold planning quantity with information on all of the methods and conditions of storage, and with material safety data sheets +or sach LHES that identifies the suoetanee's toxicity, permissible exposure limits, reactivity, corrosivity, and chemical and thermal stability, to. A summary of the facility's process hazard analysis program. c. A summary of the facility's filing system, including internal and external correspondence, and a list of operating procedures. d. A description of the maintenance program. facility's preventive . A description of the operator training program, and contractor awareness training activities. f. A description of emergency response plans with names of site personnel responsible for emergency and environmental activities, phone numbers of responsible persons, and letters from the Local Emergency Response Commission (LERC) and the local fire department acknowledging receipt of Sara III emergency 5 VVV 000006335 DRAFT/April 19, 1991 planning ln-fornation. g. A description of accident investigation procedures and Risk Management Program. h. A summary of the 'worst-case, singl e-component failure1' accident and "mast probable accident*' with an explanation of planned response activities to minimise the impact of such events. i. A summary of all accidental ar emergency LHES releases in the past five years and measures taken to prevent similar events in the future, and incidents which have occurred at other facilities throughout th* United States at facilities which are similar and which have impacted practices and procedures. J A projected schedule for emergency response training drills in cooperation with the Local Emergency Response Zommittees (LERCs) and local response units <e.g. police, fire department). A copy cf the annual notification given to schools, hospitals, registered nursing homes. and registered day-care facilities as required in Subsection 0 of this Section. 2. Risk Management data which shall be available to the Department of Environmental Quality upon visiting the facility, or uoen request at the Department's office, shall include. minimum, the following: as a a. Process technology information 6 VVV 000006336 DRAFT/April 19, 1991 process 'flaw diagram s.q, , skematics, r'MDs, etc...)i ii. process chemistry* chemical balaneas, and chemical kinetics data; iii. process -flow calculations! iv. proeess control logic diagrams ana electrical circuit diagramsi v. equipment. component, and instrumentatian design 3oeeifieaticns ana process specifications! and vl. process data, operating procedures, process specifications. logsheets, checkoff sheets, etc.... during startup, shutdown. and continuous or batch operations. and deviations outside the process specificatians! b. Risk assessments -or equipment associated with LHES operations* and the methods of determining the risk. c. Internal ana external risk management audit procedures. d. A topcqraphical map and aerial chatOQraph af the site arid surrounding environs with dimensional key. 9 Auxiliary systems etc...) diagramn. (supply water, sewage* drainage* f. A "worst"ease4 accident analysis of a "single-component failure" with exposure of the closest public and the most populous public are* near the facility with topographies! map overlay and emergency response olan. 7 VVV 000006337 DRAPT/April 17, 1971 q. Incident roporta regarding accidents ana deviations from procedures And response activities to prevent similar incidents and incident reports from similar facilities nationwide with Local facility evaluations cf local improvements related to comparable profilers. and h. Emerqency Planning and Louisiana Community Right to Know Informat1 on. t. Chemical storage records and site plan including the storage tank locations. j. Records which document the operation of the facility and execution of the programs referenced in Suoparagraphs B.l#a through h. 3* Annually, between July 1st and August 31st. all facilities governed by this Chapter snail submit an updated "port to the Department of Environmental Quality, Air Quality Division whicn shall include, as a minimum, the following: a. A summary of *il accidental or emergency releases wnich occurred in the past calenaar year. b Actions which were taken in response to each release to notify emergency response groups. minimize the release and litigate any damages. e* Actions taken to prevent similar events from occurring in the future. d. A comparison of these events to potentially similar 9v*nts in the past, and how the events are and are not the same* vvv 00000633B 9 DRAFT/Apr11 19f ITT! e. Modifications which wore made to program*, procedure*, or processes referenced In Subparagrapns 3-1.* through n, and the reasons -for those change*. C. Program* 1. The Procscn Hazard Analysis Program shall, as a minimum, contain the 'following: a. A list a* valves, piping, tanks, and other components and nu&components which identifies the praDAbility cf that item to fail in its applicable situation. If a specific item is used at several locations under similar situations, the item need only be listed once. b. For the items in the highest potential for failure cupper 2ZV. of all failure potentials), identify the quantities of materials that could ce released from any single-component failure and the quantities and characteristics (e.g., flammable, toxic, corrosive, etc..) of the material<s) released. c. Identify the complexity of the process, ae a minimum, identify the process *rom self~controlling to multiple side rtactinns, from endothermic to exothermic, from automatic shutdown with minor controls ta runaway reactions without any possible control, and evaluate all these factors related to a potential accident. Cf. The severity of operating conditions including, high pressure, nigh temperature, corrosive and/or abrasive materials, and the compatibility of materials of construction for the 9 00006339 VVV 0 DRAFT/April 19, 1991 condition* and long term exposure of the materials to the process conditions. e. The proximity of the potential risk to plant and offisite personnel* prevailing wind speed and direction, and time delay before exposing the closest public to any airborne release, 2. The Preventive Maintenance Program shall, as a minimum, contain the following: a. A list of valves, piping, tanH, and other components and auocomponent* which Identifies the prsoability of that item to fail (mean time between failures) in its applicable situation. If a specific item is used at several locations under similar situations, the item need only be listed ones. b. Maintenance records indicating what maintenance work was performed on which items, where, when, why, how and with what -esuits. c. Equipment and component testing racoras during construction or maintenance activities, and as a continual program to detect and repair deficient components. d. The mean--time-between--fai1ure projections for equipment and components. e. A written program strategy which documents the Preventive Maintenance Program, responsible individuals for directing and controlling the program, methods of projecting and scheduling projected maintenance activities to prevent failure of components during process operations, a data control and filing 10 VVV 000006340 DRAFT/April 19, 1991 system. *nd the process of directing ' maintenance from the generation of a work order througn the completion csf the repairs And heck to recording the completion of the preventive maintenance work. Z. The Operator Training Proqram shall, ae a minimum, contain the fallowing: a. A listing of all plant personnel by job title and jab remponsi&l1ity. b. A joD task analysis by job title that identifies activities that are to bo performed by that individual and the judgements and decisions wnieh are required to be made. c. Identification of the knowledge and experience that la required to enable an individual in a specific job title to perform their responsible tasks without any expected errors. d. A sequence of training, testing and evaluation of personnel to ensure that personnel holding a specific job title are capable of performing their required tasks. a. Documentation on all plant personnel by name which contains a record of their training, development and tasting that was conducted by the company, or through the individual's efforts, to ensure that the individual is capable of properly executing the tasks assigned to their job title. 4, The Risk Management Program shall, as a minimum, contain the followings a. A plant-wide evaluation of the most probable U 000006341 vvv DRAPT/April IT, 1991 failure's), or accident's), and emergency response plans to minimize any releases to the environment. or exposure of the general puollc to the released chemical(sj. b. A plant-wide evaluation of the most endangering failure's), or accident's). and emergency response plans to minimize any releases to the environment, ar exposure of the general public to the rwi9**Bei chemlcal(s). The most endangering accident is not to be limited by probability. If it :s possible, it is significant. c. A listing of the 27% most common equipment, or component, failures expected to occur 'the mean-time-between- failure multiplied by the number of such components at the facility) and emergency response plans to minimise any releases to the environment, or exposure of the general public to the released chemical(s). d. A written proqram strategy which documents the methods for monitoring accidents from similar facilities, or of similar equipment and components used at the facility, responsible individuals for directing and conducting the monitoring, methods of evaluating the applicable risk of similar events occurring at the facility and response mechanisms to control and minimize similar potential events from occurring at the facility. D. Requirements for Public Notice 1, Each owner pr operator shall annually (once during each 12 0000063^2 VW DRAFT/April 19, 1991 calendar year) provide written notification to all icnnols, hospitals, registered nursing homes, and registered cay-care facilities located within T.000 feet of the facility fencelin# of the following: a. The identities and quantities of the Louisiana Extremely Hazardous Substances used at the facility; b ft description of the hazards that these su&stancss pose c. ftn explanation of how public notification will be made when an accident or release occurs at the facility* d. The appropriate actions to be taken in the event of an accident or release at the facility; q. A description of the modes of transportation used to transport Louisiana Extremely Hazardous Substances to or from the facility; f. ft map showing the location of the facility, the .location of all schools, hospital a, registered nursing homes, and registered day-care facilities located within 3,000 -feet of the facility fenceline, and the location of transportation routes likely to be used to transport Louisiana Extremely Hazardous Substances to or from the facility, 2. Each owner or operator shall provide written pre- notification to schools, hospitals* registered nursing homes, and registered day-care facilities of the date, time, .and location of any hazardous chemical exercises to ba conducted by the facility. 13 YVV 0000063*3 DRAFT/April 19, 1991 3. Noticsv maty be made thrcugn the local newsoaper. AUTHORITY NOTE: PromuigAted in accordanca with R.5. 30S20S4. HISTORICAL. NOTE: Promulgated by the Department of Envlronmental Quality. Office of Air Quality and Radiation Protection, Air Quality Division, LR WV 000006344 14 ORAFT/Apri1 19, 1991 TABLE 39.1 THE LIST OF EXTREMELY HAZARDOUS SUBSTANCES AND THEIR THRESHOLD PLANNING QUANTITIES (ALPHABETICAL ORDER) 2aa No. 73-ei-6 1752-30-3 107-02-8 79-06-1 107-13-1 914-6S-6 Hi--69-3 116-06-3 309--00-2 107-18-6 107--11-9 20859-73-8 Chemical Mama Threshold planning Quantity (pounds) Aeetone Cyanohnydrin Acetone Thloaomicarhazid* Acrolein Acrylamide Acrylonitrile Acrylyi Chloride Adipam tri le Aldicarb Aldrln Allyl Alcohol A11ylamine Aluminum Phosphide IS 1,000 1,000/1,000 300 1,000/1,000 10.000 100 1,000 100/10,000 500/10,000 1,000 500 300 VVV 000006345 DRAFT/April 19, 1991 34-62-6 Aminopterin 79--53--3 Ami tan 3734-97-2 Amiten Oxalate 7644-41-7 Ammonia 300-62-9 62-53-3 aa-03-i 7793-70-2 Amphstamine Ani1 in* Anl 1 in*. 2, 4,6-Tri methyl Antimony Rentaliuorids 1397-94-0 Antimycin A 96-89-4 ANTU 1303-29-2 1327-53-3 7794-34-1 Arsenic Pento;:id* Arsenous Oxide Arsenous Trichloride 7794-42-1 2642-71-9 96-50-0 Arsin* Azinphos-Ethyl A*inonos-Methyl 99-97-3 Bensal Chloride 98-16-S Bensenamine Z- 100--14--1 <Triflueromethyl) Benren*. i-<Chloromethyl)- 4-Nitro 99-03-5 3615-21-2 Sensenearsonlc Acid Benzimidazole, 4.5-Dichioro- 90-07--7 5-CTri'fluoromethyl) Benzotrichiorids 500/10,000 300 100/10,000 300 1,000 1,000 300 300 1,000/10,000 300/10,000 100/10,000 100/10,000 300 100 1.00/ 10,000 10/10,000 300 300 300/10,000 10/10.000 500/10,000 100 16 VVV 000006346 DRAFT/Aprtl 19, 1991 100-44-7 Banzyl Chi on da 140-29-4 Snzyl Cyanide 300 300 13271-41-7 Blcyclo (2.2.1) Haptane-2 Carbonitrila, 3-Chloro-6- ((< CMathylamino) Carbonyl J Qhy>Imlno)-., (ie-(I-alpha, 534-07-6 2-beta. 4alpha, 5-alpna, 6E))-. 500/10,OOO Bia (Chloromathyl) Katana 10/10,000 4044-63-*? 10294-34-3 7637-07-2 333-42-4 Bitoaeanata 500/10,000 Boron rriehlorlda 300 Boron Tri-fluorlda 500 Boron Trlfluorlds Compound with 20772-56-7 Mathyl Ether (lSl) Bremadialona 1.000 100/10,000 7726-95-6 1306-19-0 2223-91-0 7770-44-1 0001-33-2 Bromin Cadmium Oxide Cadmium Staarata Calcium Areanate Camphechlor 300 100/10,000 1,000/10,000 300/10,000 300/10,000 56-25-7 51-S3-2 26419-73-0 Caniharidin 100/10,000 Carbaehol Chlorlda 300/10,000 Carbamic Acid, hathyl-, 0-<(((2 I 4-D1mathyl-1, 3-Dithiolan-2- 1363-66-2 yl>Mathylana)Amino1Car bo-fur an 100/10,000 10/10,000 17 wvv 0000063*7 DRAFT/April 19, 1991 75-15-0 Carbon Disulfide 10,000 7S6-19-6 CarDophenothion 500 37-74-9 Chlordane 1,000 470-90-6 Chiorfenvinfos 300 7782-50-3 Chlorine 100 24954-91-6 Chlormsphos 500 999--B1-5 Chlcmequat Chloride 100/10,000 79-11-0 Chloroacstic Acid 100/10,000 107-07-3 Chioroetharicl 500 627-11-2 Chioroethvl Chiaraformate 1,000 67-66-3 Chlorcf arm 10,000 342-9B-1 Chloromethvl Sther 100 107-30-2 Chloromethyl Methyl Ether 100 3691-33-0 1902-47-4 Chi orephaemone Chioroxuron 100/10,000 300/10,000 21923-23-9 Chiorthiophos 300 10023-73-7 Chromic Chloride i/10,000 62207-76-3 Cobalt, <1,2-EthanediylblB (Nitrilomethylidyne))Bi*<6- FluorcphenolatoJ)(2-)-n,ist , 100/10.000 10210-68-1 Cobalt Carbonyl 10/10,000 64-06-3 36-72-4 Colchicine Coumaphos 10/10,000 100/10,000 5036-29-3 Coumatetralyl 500/10,000 18 WV 000006348 DRAFT/April 19, 1991 93-46-7 Cresoi. o- 333-99-7 Grimidtne 4170-30-3 Croton*!dehyde 123-73-9 Crotonaidehyde, ()- 306--68--3 Cyanogn Bromide 306-78-2 Cyanogen Iodide 2636-26-2 Cyanopho 675-14-9 Cyanurie Fluoride 66--81-9 Cyeloheximide 100--91-Q Cyclohex y1 amin e 17702-41-9 Deeaoorane (14) 8065-48-3 Demeton 919-86-8 Dflfliet on -S-Methy 1 10311-04-9 Dial!for 19207-45-7 Diborane 111-44-4 Dicnioroethyl Ether 149-74-6 01chioromethylphenyliiane 62-73-7 Dlehlorvos 141-66-2 oicrotophoa 1464-33-5 Diepexybutane 914--49--3 Diethyl Chlarophospate 1642-34-2 71-63-6 2238-07-5 Diethylcardamazine Citrate Digitaxin Diglycidyl Ether 20830-73-5 Digoxin 19 1,000/10,000 100/10,000 1,000 1,000 500/10,000 1,000/10,000 1,000 100 100/500 10,000 500/10,000 500 500 100/10,000 100 10.000 1,000 1,000 100 300 500 100/10,000 100/10,000 1,000 10/10,000 VVV 000006349 DRAFT/Apr11 19, 1991 113-26-4 Dinmfox 4.0-51-5 Dimethoate 2524-03-0 Dimethyl Phoepnoro- chloridothloate 77-70-1 75-70-5 37-14-7 99-90-9 *44-64-4 Dimethyl Sulcata Dimethyidlbhloromi1 ana Dimethyl hydras! ne Dimathyl-p-Fhenylenediamine Dimeti1 an 334-52-1 38-05-7 1420-07-1 7B-34-2 Dinltrocreeol Dinoseb Dihoterb Dioxathion 92-64-6 152-16-9 290-04-4 Diphacmone Diphospftoramide, Octametnyl Dlauliatan 314-73-0 541-53-7 316-42-7 115-29-7 2770-04-3 Dlthiasanina Iodide Dlthlobluret Emetine, Dihydrochlorid Sndoeul-f an Endothion 72-20-0 Endrin 106-09-0 2104-64-5 30-14-6 Epictt1orohydrin EPN Ergocaleifar d! 300 300/10,000 300 300 300 1,000 10/10*000 300/10.000 10/10,000 100/10,000 500/10*000 300 10/10*000 100 500 300/10*000 100/10,000 1/10,000 10/10,000 500/10,000 500/10,000 1,000 100/10,000 1,000/10.000 20 WV 000006350 DRAFT/Apr11 19, 1991 379-79-3 Ergotamine Tartrat .622-32-9 Ethaneaulfonyl Chlorida, n40-97-1 2-ChloroEthanoi, 1.2-Dlcfiloro-, Acetate 363-12-2 Ethion 3194--40--4 Ethoprophoa 338-07-0 Ethylbia 12-ChloroethyliAmin 371-62-0 Ethylene Fluorcnydrin 75-21-e Ethylene Quia 107-13-3 Ethylenadiamina 131-56-4 EthyieneiAins 342-90-5 Ethylthlocyanate 2224-92-6 Fanamiphos 122-14-5 Fnitrothion 115-90-2 Fensulfothion 4^01-50-2 Flusnetl1 7782-41-4 640-19-7 Fluorin FIuoroacetamiae 144-49-0 Fluoroacatic Acid 359-06-0 Fluoroacetyl Chloride 51-21-9 944-22-9 Fluorouraeil Fonofos 50-00-0 107-16-4 Formaldehyd Formaldhyd Cyanohydrin 21 300/10,000 500 1,000 L * 000 1,000 300 10 1.000 10,000 300 10,000 10/10,000 500 300 100/10,000 300 100/10,000 10/10,000 10 300/10,000 300 300 1,000 000006351 DRAFT/Apr11 19, 1991 3422-53-9 Fornatanato Hydrocniorad 2540-92-1 Formothion 7702-57-7 Forfflptran at a 1540-32-3 3970-19-1 110-00-9 Fomthietan Fuberidaizola Fur an 3450-90-3 Gallium Tri chi or Ida 77-47-4 4835-11-4 Haxaehloroeycl opantadiana Haxamathyl cnedutmine, N, N ' - 302-01-2 74-90-0 7*47-01-0 DibutylHydrazine Hydrocyanic Acid Hyorogan Chloride (Gaa Only) 7664-39-3 7722-94-1 Hydrogen Fluoride Hydrogen Peroxide (Cone >52X3 7703-07-5 7703-06-4 123-31-9 34*3-40-6 297-78-9 70-02-0 102-36-1 Hydrogan Salanide Hydrogen Sulfide Hydroquinona Iran, PantacarbonylIsoben2an Iaobutyromtri1e Isocvanic Acid, 3,4- 465-73-6 01chiorophanyl Eitar laodrin 22 500/10.000 100 100/10,000 500 100/10,000 500 500/10,000 100 500 1,000 100 500 100 1,000 10 500 500/10,000 lOO 100/10,000 1,000 500/10,OOO 100/10,000 VVV 000006352 OKAFT/April 19, 1991 55-91-4 1801s 1 uorphat e 40*6-71-9 Ienphorone Diisocyanate 10B-23-6 I tapropyi CMarotarmate 119-39-0 leoproplymethylpyrazolyl Dimethylearbamafcs 79-97-7 Laetonttrile 1609-90-5 543.-25-3 -19-9 Leptophoa LBWISite uindan* 7580-67-9 Lithium Hydride 109-77-3 Malononitri1* 2100-13-3 Manganese, Trlcaroonyl Methyl cyclopentadienyl 51-75-2 950-10-7 nechiorethamirte Mephaafolan It 7-7 7487-94-7 1908-53-2 Mercuric Aeetate Mercuric Chloride Mercuric Oxide 0476-95-6 Mothacrolein Diacetate 760-93-0 Methacryllc Anhydride 126-90-7 Methacrylonitrile 920-46-7 Methaeryloyl Chloride 0674-00-7 Methacryloyloyethyl 10265-92-6 Isocyanate Methamidophee 23 100 100 1,000 500 1,000 500/10,000 10 1.000/10.000 too 500/10,000 100 10 500 500/10,000 200/10.OOO 500/10,000 1,000 500 500 100 100 100/10,000 00g006353 DRAFT/April 19, 1991 33S-23-8 Methaneaulfonyl Fluoride 980-37-8 Methidatmon 2032-65-7 Methiocarb 16752-77-3 Methamvl 151-38-2 Methcwyethylmercuri e Acetate 80--63--7 Methyl 2-ChLoraaerylate 74-83-9 Methyl Bromide 79-22-1 Methy1 Chi orof or mate T * 624-63-9 Methyl Hydrazine p Methyl 1 isocyanate 556-61-6 Methyl Isothiocyanats 74-93-1 Methyl Mercaptan 3733-23-7 Methyl Fhenkapton 676-97-1 Methyl Phoephonic Dichloride 736-&4-9 Methyl Thiocyanate '4-4 Methyl Vinyl Ketone 302-39-6 75-79-6 Methyl mercuric Dicvanamide Methyltrichioroai1 ane 1129-41-3 Metolcarta 7786-34-7 Mevinphos 313-10-4 Mexacartaate 50-07-7 Mitomycin C *923-22-4 Monocrotophoa 2763-96-4 505-60-2 Mueeimol Muetare 8ae a** '* 1,000 500/10,000 300/10,000 300/10,000 500/10,000 500 1,000 300 300 500 300 500 500 100 10.000 10 300/10,000 500 100/10,000 300 300/10,000 300/10,000 10/10,000 10,000 300 VVV 00000000066335544 DftAFT/Aprll 19, 1771 13463-39-3 Nickel Carbonyl 34-11-5 Nicotine *3-30-5 Nicotine Sul'fate 7697-37-2 Nitric Acid 10102-43-9 Nitric Oxide 98-93-3 Nitrobenzene 1122-60-7 Nitroeyclohexane 10102-44-0 Nitrogen Dioxide 62-73-9 Nitroeodimethyl amine 991-42-4 O Norbormide Qrganorbodium Complex u.*^~0-4 (PMN-02-147) Ouabain 23135-22-0 Oxamyl "3--71--7 Qxetane, 3.3-Bis <Chloromathyl) 2497-07-6 Oxydi sul -f aton 10023-15-6 Ozone 1910-42-5 Paraquat 2074-50-2 Paraouat Nethosulfate 36-33-2 298-00-0 Paratnion Parathion-Metnyl 12002-03-0 19624-22-7 2370-26-5 Paris Green Pentaborane Pentadecylami ne nr 1 100 100/10,ooo 1,000 100 10,000 500 100 1,000 100/10,000 20/10,000 100/10,000 100/10,000 300 500 109 10/10,000 10/10,000 100 100/10,000 500/10,000 300 100/10,000 000006355 DRAFT/Apr11 19, 1991 79-21-0 394-42-3 Per acetic Acid Ferchleroroethyl mercaptan 500 500 108-95-2 Phenol 500/10.000 4419-66-0 Phenol, 2,2'-Thicbls (4-Chlorc-6-Methyl) 100/10,000 64-00-6 Phenol. 3--<i-Methylwthyi )- Methylcrbmatc 300/10,000 30-36-6 PhenostarBi ne 10, 10* --Ostyoi 300/10,000 694-29-6 Phenyl Dichlcroareine 500 39-99-i Phenyl thy dr as me Hydrochloride 1,000/10, r}< ' -T9-4 Phenyimoreury Acetate 500/10,000 2097-19-0 Phenyl si1atrane 100/10,000 103-05-5 Phenyl thiourea 100/10,000 290-02-2 Phorate 10 4104-14-7 Phosacetim 100/10,000 747-02-4 Phos^alan 100/10.000 73-44-5 Phosgene 10 732-11-6 Fhosmet 10/10,000 5171-21-6 Phosphamidon 100 7803-51-2 2703-13-1 Phaspnine Phosphonothioic Acid, Methyl-. 500 -Ethyl 0-<MethylthiaJ Phenyl) 0782-69-9 Ester Phoephon-thiaic Acid, Methyl-, 500 26 VVV 000006356 ORAFT/Aprll 19, 1991 3-<2-< Bis <i-Methylethyl)Amino) Ethyl 0-Ethyl Ester 100 2663-30-7 Phospnenothioic Acid* riethyl-. 0-(4 Nitropnenyl) Q-Fhenyl Ester 500 3234-63-5 Phosphoric Acid* Dimethyl 4-<fithylthio> Phenyl Ester 300 2397-90-8 Phosphorothioic Acid, 0,0- Dimethyl-S-<2~Mthylthio) Ethyl Ester 300 7723-14-0 Phosphorus # 100 0023-07-7 Phosphorus Oxychlorldo 300 0026-13-0 Phosphorus Pentachioride 300 1314-36-3 Phosphorus FentOKlde 10 "*19-12-2 Phosphorus Trichloride 1,000 47-6 Physaatigmme 100/10,000 -7 Physostigmine, Salicylate 124--07--6 110-69-4 (!!!) PicrotpKin Pi peridine 100/10,000 300/10,000 1,000 3303-41-1 Pir1mifos-Ethyl 1,000 0124-30-2 Potassium Arsenite 300/10,000 151-30-0 Potassium Cyanide 100 306-61-6 Potassium Silver Cyanide 500 2631-37-0 106-96-7 Fromeearto Propargyl Bromide 500/10,000 10 27 vvv OOOQO6357 DRAFT/Apr!1 19, J991 57-57-H Propiolactone. Bet* 107-12-0 Propionitrlle 342-76-7 Propionitr;1. 3-Chloro- 70-69-9 Prapiophenone, 4-Amina- 109-61-5 73-56-9 Propyl Chi oroformate Propylent Oxide 75-53-B Propyleneimine 2275-18-3 Protnoate 129-00-0 Pyrene 140-76-1 Pyridine. 2-Methyl S-vinyi ' -24-S l124-73-0 Pyridine, 4-Amino Pyridine, 4-Nitro-, 1-Qxide 35S3B-23-1 Pyrimini1 4167-18-1 107-44-13 7703.-00-8 7791-23-3 563-41-7 3037-72-7 Saleamine Sarin Selenioua Acid Selenium Owyen1cride Semi carbamide Hydrochlariae Si1ane, (4-Aminobutyl) Oiethaxymethyl 7631-99-2 7794-46-5 6620-22-9 Sodium Arsenate Sodium Arsenite Sodium Aside (Na(N3J) 124-65-2 143-33-9 Sodium Cacodylate Sodium C.anide (Na(CN)) 300 300 1,000 100/10,000 300 10,000 10,000 100/10,000 1,000/10, 000 500 300/10,000 300/10,000 100/10,000 500/10,000 10 1,000/10,000 300 1,000/10,000 1.000 1,000/10,000 300/10,000 300 100/10.000 100 23 yyy O00Q06358 DRAFT/April 19, 1991 62-74-8 Sodium Fluoroacetat* 10/10,000 3410-01-0 Sodium Selenate 100/10,000 (D 1 m 1 WO *o4 Sodium Selenite 100/10,000 0102-20-2 Sodium Tellurite 300/10,000 900-93--8 Sfcannane, Acetoxytriphenyl 500/10,000 37-24-9 Strycnmne 100/10,000 60-41-3 3trychnine, Sulfate 100/10,000 3669-24-3 Sulfstep 300 3369-57-1 Sulfoxide, 3-ChlorcDropyl Octyl soo 7446-09-3 Sulfur Dioxide 500 7703-60-0 7446-11-9 Sulfur Tetraf1uerido Sulfur Trloxide 100 too 7*64-93-9 Sulfuric Acid 1,000 77-81-6 Tabun 10 13494--SO--9 Tol lurlum 300/10,000 CP . * 10 1* Tollurium Hexafluoride too 107-49--3 TEPP 100 13071-79-9 Tertiuf o* 100 73-00-2 Tetraethyl lead 100 397-64-0 Tetraethyltin 100 75-74-1 Teirametnyl1ead 100 309-14-8 Tetranitromethane 300 10031-59-1 Thallium Sulfate 100/10,000 6333-73-9 7791-12-0 Thallous Caroonate Thalleu* Chloride 100/10,000 100/10,000 29 0006js9 DRAFT/AprIX 19, 1991 2737-IB-8 7446-18*6 2231-57-4 Thftllous Malonate Thallous Saif at* Thlacarba2ido 100/10,000 100/10,000 1,000/10,000 39196--IB--4 Thtofanox 100/10,000 297-97-2 Thlanazln 500 100-90-5 THiogbenol 300 79-19-6 ThlofltmicdrbAzide 100/10,000 5344-82-1 Thiour94, <2-Chloropnenvl) 100/30.000 614-70-8 Thiourea, (2-Methylphenvl> 300/10,000 7330-43-0 Titanium Tetracnlonde 100 584-84-9 Toluene 2,4-Diisocyanate 300 91-09-7 Toluene 2,6-Diieocyanato 100 110-37-6 Trans-1,4-0ichiorobutene 500 1031-47-6 Triamipnas 500/10.000 24017-47-9 Triasofos 300 76-02-0 Trichloroacetyl Chloride 500 115-21-9 Trichiroethylsi lane 500 327-90-0 Trlchloronate 300 90-13-5 Tr ichlorophenylsi1ane 300 1359-23-4 Tricnioro CChloromethyl)Si lane 100 L%o o 27137-03-5 Trichioro<Dichlorophenyl)Silane 999--30--1 Tri. ethoxysi 1 ane 500 o H o 75-77-4 Trimethylch1oroai 1ane 024-11-3 1066-43-1 Tri methylolprcpane Phosphite Trimethyl tin Chloride 100/10,000 500/30.000 30 00000636G yv* DRAFT/Apr11 19, 1991 639-58-7 555-77-1 Triphenyltin Chlonoa Trim <2-Chloroethy)i) Amin 500/10,000 100 2Q01-95-S 1314-62-1 100-05-4 01-SI-2 129-06-6 28347-13-9 58270-00-9 Vaiinomycln Vanaolum Pantoxid Vinyl Aetat Monamwr Warfarin War-farin Sodium Xytylmn Dichlorid Zinc, Dicnioro<4,4-Dimthyl-5 1,000/10,000 100/10,000 1,000 500/10,000 100/10,000 LOO/IQ.OOO f ( ( (Methylamlno/ Gardonyi)Oxy> 1314-04-7 Imina)F*ntanenitrile)<T-4>-. Zinc Phoaphlde 100/10,000 500 VVV 000006361 31