Document R8RYJKz21KM60wOJY773Ne6X

A47 UtBQKW - OKHWl. BSttlKH flyralagnit of a Alballth 362 Tn* NLasrol Product* LabontPi^ Voraabar i, JS$6 A trial 1st of llthapana, Lot CTOJb, intended to aIsolate Alballth 362, bo* bM aada la th* llthopoaa plant, Tsata in tbs JohnaJfacrvill* fomnla Indicate that this raa via conplalaljr umuacaoaful, Tho Nnolltt llthopsaa ms fanad ta ba ottrldljr lewar la opacity and la mtsr absorption capacity, Tito ralatia* hiding power* of tba aararai partlaant llttepoaaa tasted aarat Alballtk 362 SaaaUth 76C Paraalith 60-2 Paraolith 1-320 Paraolith 362 Type 10 9 8 7.8 7 Thar* la oonsldembla ewidanea to indicate that a lithopoos of th* Alballth 362 typa aonuot ba aada by obanioal traatmnt aleaat bwt mat ba aa prooaaaad aa ta pandt a vary nanine! fialah dry ailling. Soap* of PepbtBM Th* Tntno Hnirin racgiaiy aaaa lithopooa la a raain anilcion palat which ia applied aa a easting aa thoir aall board* Op ta tlliia tiaa, thay baa* baaa using a lil blaod af Alballth 362 (lav Java*? Zina) and Paraolith 60-2 at thoir latches. Miss, plaotf ad a bland of Alballth 362 and Sonollth 76C ((Hidden Co.) at tho Jarrwtt, Ta, plant. Prior to tha Una defeat diaaontlaaad tha predaatlon af llthapana, thay had aaad PonaUth HC laotaad af Alballth 361, la* that tha la* Jaraay Zina Ca. haa likaviaa dlaaootlnaad tha pradaatloa of lithopono, thay ara requesting Mphiiamt fdr tha Alballth 362* *" altaxmataly far tha oowbiaotloa of Alballth 362 ad Paraolith 60-H, It tooald bo --lUoooti that Jbhna-Hanollla aarlaoaly eaaaldarod rafniml atlwg tha seating around tltmlm dioxide, bat war* dissatisfied with tha application aharastaristlaa thqr Mahnd, Alballth 362, and Smallth 76C to a slightly laoaar axtmt, exhibit astro high dry-hiding prapartlaa and a Tory high water absorption capacity. Tha Johns Hwirllla feroala aacna ta mrfeadly mphaalan this eharaotarlatla, ato it la aapairUlly the bldlac proparty af tha Alballth 362 that vast ba mtshort, Aeaardlagly, a trial m was aada at th* Coffayrille Llthapana Plant, duplicating, aa nearly aa available pie- ssaslac rnthods and aqalpnant woald pandt, tha praaadar* aaad by lev Jersey Zinc far tho namfastara of Alballth 362. 0007-S WP-043681 N23230 A saapl* of tbla lot, C?034 AUBL 4446, wmm tubKLttod for evaluation in tbo Jobna-Manvill# fomula. A a*allor quantity of Aiballth 332 typo of litbopono, Lot P?034 ADSL 4449, waa aodo on tbo mm baao try addin* 0,5 totraaodlun pyrophoaphato at tha *111, For brevity, tbaao lota will bo doalgnatod Poxnolith 362T (for typo) and Paraollth 332T, roapactivaly. aValaatlont A total of alx lithoponM, alono and in various aoabinatloaa, war* aada up la ttao Johna-Hanvill* fozmlai Hteae* Aiballth 362 (#1) Aiballth 362 (#2) Parnelltb 362T Ponolith W-320 Paraollth 60-H Swallth 760 MSdkx U3$9 438$ 4448 3370 2844 4391C Fornalai 63d 6600 826$ 10-0-14 ($120} (5120) aiWM Lithopona Calolm Carbonate, natural inataoa Titaniu* Dioxide Farrito Tellev, Ok, Qrang* Protola tonlalon Dovieid# 0 Parafonaldahydo Matar Grind in Pro*!ar Colloid Mill at 0.005" TMn-dra Motor 173 154 19.2 3.8 220 1.$ 1.2 192.4 (Koto) 115 Natoi Iba perefoimldebgrd* mo aotaally bald oet until thin-down baaaaaa It oaaaad gallinf of tb* paint* within 8 boor*# Tlla-doMa vara *ad* tb* day fbUowing th* prep aration of tb* poato*. -2- nno7-swi>-04:>682 0007-SWP Pmtain -Million (5120) (2016) Material Water Seym Protein, Proaoym L Caaoln Caaotle Soda Anti-Pom Cook 15 adnata# at li*0P. Prana 169i 251 169 li*,8 17 Refined Soya Oil Ple*alyn-C 70 212 (flexalym C la a dlethrlane glyoalresln aator) Ta* group* of point* won proptrad m tha ibon femala, the* wwwt groap oonaiatlng chiefly of a dsplleatlaa of mm of thee# is tbo flret troop* Thio mi done to determine nprodaoabilitgr of raoalta la the fonola. Dm point* in eeefa o*ri*a voro rated for hiding power toy --no of ooeblnotlona of "doable itroo deeaa". Thao* mam nod* on Momot hiding power aheote fen 021 at a gaga totting of 6 alia. Orovp I Paint Xo. JH- 221 222 223 22l 225 226 227 228 229 230 Llthoame Alballth 362-1 Pomolith 3621 Alballth 362 Pmnolith 604 Pomolith 362T Panollth 604 Alballth 362 Sunollth 76C Alballth 362 Panollth W-320 Pomolith 3621 Panollth W-320 Panollth 604 Swaollth 760 Panollth W-320 Pel. Hld^pg 10 6.5 1 7 9 8.5 7.5 0 9 7 1 :l o 5 6 2 3 7 6 2 8 Group 2 Paint Xo. JM- 231 232 233 23k 235 236 Uthoooao Alballth 362-1 Alballth 362-2 Panollth 3629 Alballth 362-2 Panollth 3622 Panollth 604 Ponellth 604 Panollth 60-8 8*1. Hiding 10 10 7.6 9.5 T.9 8 Saak 1 1 6 3 5 k -> (H H)7 - 5 WP -043fS K 3 0007-SWP-000127033 Oo m --apart**-- war* alao aadt on tha imm lithopo-- la tha Wo ga^i of point* with thaaa r--vital WMMh 221/231 222/233 223/231* 22V235 224/236 Alhallth 363-1 MntUtk 3621 Alhallth 362 * Par--Mtb 60-H Fax--Uth 3627 Pax--Uth 60-H Par--Uth 60-H Squal --al &tOMl 23$ Vory Slightly Kl*hor Kqaal filially a larc* n--bar of deahla dr--do--a am --do o--parlnc th* ororall x--alia f Clia^ia 1 and 2* Fr-- th--* o--arlaona, u at--a ratine --a --da whleb tarlM only allfhtly Arm tb* roaalta of Oroap 1. iatN&Jitisci. yutmm 1. AlhaUth 362 2. AlhaUth 362 P--Uth 60-M 3. `tmiiilllli 760 1*. AlhaUth 362 ft--ollth 76C 5. AlhaUth 362 Fax--Uth W-320 6. Far--Uth 60-H 7. Pax--lith V-J20 8. Pax--lith 3627 Pox--Uth 6o-H 9. teatUth 3621 Far--Uth -320 ID, Pax--Uth 3627 mu main* 10 p.t 9 ,6 8.7 8 7.8 7.$ 7.3 7 Watar ahaarptlan dataxminatl--a -- --da -- all tha Uthapon-- inaludad la tha stodjrj tha Oar--ar-Cala--n aathed a-- --ad. Tintl-- atrocth t *1--* am alao ran cm --ral af tha jlp--te. lAth--anp AlbaUth >62 AlhaUth 332 AlhaUth 10 Pas--Uth 3627 Far--Uth 3327 Pax--Uth -320 Fax--Uth 60-H 3--Uth 76c ator Abstnlki 31.1 3UI 2h.l 25.5 22.0 22.$ 22.$ 3U2 9k 100 86 -- n aiWHW ,^m It l* --par--t that tha attaqpt ta --nnfaatan a Fax--Uth llthepona olnilar ta Alhallth 362 --a a--inr--iM. In th* <fahn*-mnrill# fanalii at la--1 It axhlMLtad -- dryhldl-- proportloo ahalaamt, and woo aotaally peorar th-- tha rafolar Far--Uth 60-H. In attanldljn ta find -- txplanattan far tha-- raanlta, it la obaarrod that tha-- la aa-- a--ralatl-- hot-- tha dry-hldl-- --d tha --tar abaarptl-- (Pc--Uth HC( --lah had a --tar ahaarptlan of 35-36,, aha--d at-- battar hiding la tha ifohn* H--rlUa Aaaliu). -U- 0007-SWP-0+3A84 0007-SWP-000127034 tlbalith 362 io nado on aQaanHally tbo mu m bso as Albalith 10* jral baa about 32% blgfaor wtr absorption. fly oontmot* tho Pomolith 362t hu only about 1# Mghor nator absorption than tbo 60~H. It is ouggoatoo that this iaeroaaod watar absorption lndloatoa a particular typo of ntabla pignont nggl it s ration which aots aunouhat like a spcngo. This saws agglowratioc would proddo high dry-hiding bp retaining air la tho lntoratlMa of tbo agglowaratss aa tbo fUa drloo. Tbo Pomolith 362Ta haring littlo diyhldlng proporty, show pooror opacity tbaa ?amoli1h 60-H as lndleatod by ito daflnltoly lowar tinting strength* 3omml ooadltioas aro naooaaary to prodnoo tbo Alballtb 362 typo of llthopeas, flnt, tbo baoo lithopona mot bo an axtra soft typo, kopt soft bp a dallbarato undaraalslnatlan. Sooond, saoo tbo spools! troataaut (which Is usually * astal allleato floating) Is nado, both tho drying snd final willing should bo as nlld as pesslbls. This Is mk traualy lnportaut In ordor to avoid brooking down tbs aggloawrato atruetare that baa boon fomad daring tbs apodal trustwant. 3y drying at a low tanparatura, tbo final willlog baoowoa nothing nora than a dlalntogration of tho drlod oaks. It la axtr--iy doubtful whothor this typo of Utbflpawa can mr bo obtainod if it la ground in a haywond ring-rollor will, alnos this typo of grinding tondo to dlarapt tbo partlola aggloworataa, 3u*h a riow la aupportod by tbs antnal preoosalng uaod by both DuPont and bow Joraay Zino to aannfaoturo tbo typo of Utbayoao which prudueod tbo oariwww offOot In tbo ^ohno-Uanrlllo fomuls. f. c. Vordulnibb *** H, Mans, Hinorul Products Laboratory (I007-SWIMU1685 0007-SWP