Document R2XBm7mdGzb7ReyXMK2ZZ078z
BIODEGRADATION (BOD/COD)
TEST SUBSTANCE
Identity:A mixturecontainingperfluorooctanesulfonatweh,ich may alsobe referredto as PFOS, FC-95, oras a component of FC-780B. (1Octanesulfoniaccid)(CAS # 2795-39-3).
Remarks: The 3M productionlotnumbers were 1 and 501. The test sample isFC-780B. Currentinformationindicateistisa mixtureof0.58% PFOS, 14% diethyleneglycolmonobutyl ether,76.7% water,5.5% urea, 1.17% Hydroxy foamer, 1.15% sodium octylsulfate0,.8% polyoxyethylene monooctylphenylether,0.05% sodium laurylsulfatea,nd 0.05% benzotriazole.
The followingisan abbreviated summary of multiplebiodegradation studies on FC-780B. These studies apply to a mixture with incompletely characterized concentrations of impudties. Data does not accurately reflectdegradation potentialof the fluorochemical component of the testsample.
METHOD:
Method: Specificmethods notnoted. Type: AerobicBOD and Dichromate refluxCOD GLP: No Year completed: 1978 - 1982 Contacttime: 20 days lnnoculum: Seed was from varioussources.
RESULTS
Chemical Oxygen Demand (COD) range: 292,600 - 377,000 mg/kg
BiochemicalOxygen Demand (BOD) range: 5-Day: 23,000 - 165,000 nig/L
1O-Day:
44,000 - 290,000 mg/L
15-Day: 192,000 - 380,000 mg/L
20-Day: 205,000 - 490,000 mg/L
Remarks: Testingwas conducted on the mixtureas descdbed intheTest Substance Remarks field.The values reportedapplytothatmixtureand not the fluorochemicalproportionalone.
CONCLUSIONS
No reliablceonclusionscan be derivedfromthese studies.The indicatioins thatthe majorityofthe productcomponents are readilybiodegradable.
Submifter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St. Paul,Minnesota,55133
DATA QUALITY
ReliabilitKyJ:imischranking= 3. The studieslackdescriptioannd recordsof themethod followed.The valuesforthe studyconducted under Lab Request number 7685 are from a summary sheet only- raw data notfound. The inoculumwas notproperlycharacterized.The sample puritywas not propedy characterizedand thestudylacksanalyticaclonfirmationoftheamount of fluorochemicalproportioninthe solution.
REFERENCES
Testingwas conducted by multiplelaboratorieastthe requestofthe 3M Company, Lab Request numbers 4461, 4653, 4657, 4673, 5598, and 7685.
OTHER
Lastchanged: 6/28/00
-@AB REQ. LAB :)ATE
@OD 30D 5 BOD
10 BOD 15 BOD 20
BOD /COD 20
LOT LAB REQ. LAB D
COD BOD 5 BOD
10 BOD 15 BOD
20
BOD 20/ COD
COD BOD
5 BOD
10 BOD 15 BOD 20
BOD 20/COD
TABLE 1 COD AND BOD DATA FOR FC-780B
501 4673 SERCO 3/28/79
377,000 140,000 290,000 300,000 320,000
0.85
501 4673 Haller 3/28/79
293,000 165,000 190,000 192,000 205,000
0.70
501 4673 Babcock 3/28/79
345,000 27,000 44tooo
220,000 230,000
0.67
1 4461 3M ENV.@. 11/10/78
360,000 140,000 260,000 280,000 280,000
0.78
Avg-
346)000 93,000
202,000 245,000 264,000
0.76
1 4657 3M ENV.4/23/79
353,000 53,000
220,000 240,000 280,000
0.79
95% C. I.
326,000-376,000 28,000-158,000
113,000-292,000 204,000-287,000 221,000-307,000
0.69 - 0.83
1 4653 3M ENV. 5/29/79
348,000 34,000
210,000 240,000 .17(),Ooo Qk@'.O'Y.
-41 0.78
Naval Research Lab Washington, DC
387)000
0.96
Form 10620-5-PWO cc: LAS RIEGUEST BOOK
- 42-5W
Ref: ENVIR. ASSESS.
-@* PRODUCT:
INQ. #
PRODUCT ECOLOGICAL ASSESSMENT
REQUEST FOR LABORATORY WORK
-79o,37 (7,r3o9j
DIVISION Lo'r,5101
LAB REQUEST No. '-7V
REQUESTER
Name: Reque@t-Date: Project No.: Code No.: Sample Date:
l?e,3rLil-
/-,31-79
.
7 A e) 1 2:7 o 0
/-2c
Description:
Purpose of Tests:
7b
h%A@ It,
Phone No. @5-0 '7.9
Prob. No.
Date Needed:
6&0 tt-t C-f 3 0 1-fU"
) f--
"
etc-4-
t-4li--F--;@,@YI-Sa
PHYSICAL & CHEMICAL PROPERTIES HostofCombustionCal/G(BTU/Lb.) Density Ash Other
7 ?0 A3
LABORATORY
Date Received Sampi -
Analyst:
Date Completed:
Hours Spent:
Y-B
-P-
Please Call Requester If Delays Are Encountered.
tie h@@ 4@,46
WATER POLLUTION pH COD B OD 5 BOD,.A
cia
Oxygen Uptake Dehydrogenase Activity(TTC) Other
I l-T77,0.00
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o 60
OOC-1
BIOASSAY Specify Organism and Method:
LEACHATE
FROM LEACHING
PH
COD BOD 5 BOD, Ultimate
TOC GC
Bioarsa%., Other
TEST
OTHER -Bioaccumulation Persistence Degradation Products
White - Return to Requeetw Canary - Environmental Engrg.OfficeFile' Eink -Environmental Engrg. Lob Goldenrod -Return to P14quener
xxw YoziL M. I.
piloVIDEMCF- IL L
BOSTON. MAU.
NEW HAVEN. CONN.
BUFFALO. U. Y.
THE HALLER
TESTING
DICORPORILTED
LABORATORIES
336 Lelcmd Avenue PlcdnfieldN,. J.07061
P.0. BM ts
PLABOW.LD, N. 1.
TWTMG
LNSPEcnom
<9> CONSULTAnOri
This reportis the confidenficpdropertyof the Cfient,and informationcc,-Llcdned may not be pubIL-12edor reproduced witlioutour writtenpermission.
cuent@
Projed sumed
rwUW2
Minnesota Mining & Mfg. Co., St. Paul, Minnesota
Purchase Order No. 711707 - 400 Laboratory Testing for C.O.D. and B.O.D.
ReportNo. P-79-4611 Lab. No. L-2954
Ehate March 15, 1979
The following are the test results of Sample No. 7901 delivered to our laboratory on February 5, 1979.
TEST RESULTS
C.O.D.
292,600 mg/l
B.O.D-5
165,000 mg/l
B.O.D.10 B.0-0-15 B.O.D-20
190,000 mg/l 192,000 mg/l 205,000 mg/l THE HALLER TESTING LABORATORIES, INC.
RWH:I.G Reported to: Minnesota Mining Mfg. Co.
Bldg. 20, 881 Bush Ave.,
St. Paul, Minnesota 55106 Att: Mr. David Seely -3-
Rog'erW. Haller vice-President
ELY ROOSSEEVVIILLLLEE@,MN MN PERU, ILLINOIS
SANITARY ENGINEERING LABORATORIES, INC. 2982 N. ClevelandAve. RosevilleL,4n.55113 (612)636-7173
REPORT OF LABORATORY ANALYSIS (MethodologiesEPA approved)
CLIENT: 3H Company
DATE COUJCTZD:
DATE 219CRITED: 02/01/79
SAKM MWRIPTION:
VISTEVATER
RICIPORT NO.
205
02/21/79
COLLECTED FICND-UP
BY: CLIENT BY:
PAGE 2 OF 2
LAS NO:
629
SAMPLE SITE:.
(@1@167 AgALY31S: -------------------------------------- ------
COD, Chesical.Oxygen Demand, mg/l
377000
BOO, 5-day, mg/l
140000
SM, 10-day, mg/l
290000
15-day, mg/l
300000
BOD, 20-day, mg/l
320000
Approved by:
< S"na *less than"
AsocuounAL CONN&tAm VIOM WAM L*AOLMM
L4BmTomn 321SCHWAM AVOU
TO 3 N Company
gnv. Lab 2-3 9 935 Bueb Avenue St. Paul,my 55106
Att: David Seely
L*AVU MAN=
7901
MAKIDW low
EDWARD S. NABCOCK
P.06 BW 4M W#SUM CAUFOOM "M
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- 42-5W
PRODUCT
REQUEST
INQ. 7S-3,')i- 71
DIVISION - 7S-a iG I-o-t--f
ECOLOGICAL ASSESSMENT FOR LABORATORY WORK
LAB REQUESTNO.
3 M vcuw2oo np.
REQUESTER
Name:Request Date: ProjectNo.I:F97i5ol.2100 Code No.:
Sample Date:
Phone No. Prob.No.
Date Needed:
Description: Purpose of Tests: 71 s-
; f- 4"
a-0 79
LABORATORY
Date ReceivedSample: Analyst: DateCompleted: Hours Spent: -12@
/ --Z-.Y-7 -I
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B-P-
+I;Z4/7
Please Call Requester IfDelays Are Encountered.
PHYSICAL & CHEMICAL PROPERTIES Heatof Combustion Cal/G (BTU/Lb.) Density Ash Other
WATER POLLUTION
pH
COD
nm
BOD 5
BOD, Ultimate
I
TOC
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LEACHATE
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pH
COD
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TOC GC Bioa!;say
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White - Return to Requester Canary - Environmental Engrg. Office File tl,,:ke:n-vironmental Engrg. Lob Goldenrod - Return to Requeetw
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310,
2-2-
Fr, FVW'
4
404*
ENVIRONMENT AL LABORATORY BOD WORK SHEET
Blanks:
Bottle No.
Sample Size
42d
Desaiption
BOD&104D S-rb /S'-
0 =-
D.0 ;Ott
-iJP'A
/1
y-
v
-V
/.o
.2,0 3,0
1-t
ol
Depletion
ts-PA
A
DilutioWnater. Bk.Avg.
10 -Day BOO
Aloo
130 '3-61D 120
AA---
Avg. L
iovA
Boni@ No.
71 35
031VO4
ENVIRONMEPITAL
LABOR ATO RY
800 WORK SHEET
BW*S:
Semple Size
D"crlption
GOD leoj> s--rb ts-
41
0.0.
Depletion
/.0 .2,0 3.-0
illISO' .4-,% o Ail-
5-,-35
Date:.-3- /' - I-)@) --
DilutioWnater:Lli@--
sew
Lf.3 . -
Sk. A% g
DOY BOO
Avg.
32-0
rL-
&10 0
42U& -V,
30ttioNo.
84nks:
EN%@IRONMENTA L LA;@RAT SOD WORK SHEET
olfmyAAO&#*& V/X
Date: DilutionWater:
Sk. Avg.
Sample Size
Description
go r,> le-0 D
D.O.
Depletion 20 Day SOD
Avg.
122=
71
/.o
.2,0
3,0 4(,4
A
OL
-)e- 326 c@s io0 --)f
-1,- -3s-D t)@- '3)0*-
4bli -V
-o
67r-
i06l@&B.PWO
Aii A;@q fidGUMffOWK - 42-.GW
PRODUCT REQUEST
Ref:t*i4VIR. ESS.'INQs.y 79o37 -
)IVISION
I -,.PRODUCT: re- yea A 4-Olt
ECOLOGICAL ASSESSMENT FOR LABORATORY WORK
LAB REQUESTNO
3MVAUWSDCftw
"7 LF
Name: /1" Requou Date: Proiw No.i. Cod*No.: sample.Do@u-: Description:.
cFTfUU! Pur
PHYSICAL & CHEM
REQUESTER
PhoneNo
5'0 7,q
:Zoo
Prob.No.
7
DateNeeded:
M i@ollau-s6o4@0 'tt-4 =4 (>
4,4 1.@Avl&
':A@ rl--.A dA-
F-
1
7
LABORATORY
DateReceiveSdample:
Anajyst-:DateCompleted:
l@?@ . -tla- Z7
HoursSpent:
Y,B
p
PlewiCeallRequesteirfDelaysArt E@'rcko-'Untere@@.'
0 tie
41t
RE.0t@Et P, LABORATORY
FIMAL REPORT.
WORK
LAB,-@,@REQUE.ST tII3. 46c"S
--REdtIESTOP,'-'ql-IE-.EAP
P13JECT tiO@.' 997'01)12701) I)ESC.,: FC. 7Sn-P,- LOT. E-@X)l
DATE RECEl'v4ED--
ONSLYSTT
DCS
DATE COTIPLETF-D-
MRS SPEtiTz
ACTION DATE
CODE
TYPE
DATE
TIME
FLOtt
FIDD. DEC
TEST SOD BOD
BUD BOD
COD
11) 15 LILT C2-0?
.1401000 MGVL liC @,L
3L)1)1)-0t) tiG'@IL 3.'r-1")1'1OXi I-IC,7L
377111)1)tir:,-,L
I C,5 1)1)1) M67L.
19 2 1)t)0 MG,'L 1)1) 01) MG7L
C/
979
-710131) tIC,7L: 441)1)1) r@-2nOOO MG7L
1)1)1)1) M C,/L S 4'!,1)1)1) I-IC,-/L
OTHER Sioaccumulation Persistence DegradatioPnr*dLtas
Whfto-otowm to Pkeq
S=L-rtnViron"WMIEnr'&o
C*Fft
invwonrnonmatwm LA O*klenmd -14*wrnw Pk"us@ow
: F6rrn10620-B-PWO
I (EE & PC Contact)
-r1)6
7?-o
Lab Request No.
DEPT. CHARGE
0012 - MONITOR
0222 - ENGR.
A0535
- PEA
Water and Wastewater REQUEST FOR LABORATORY
WORK
TO: ENVIRONMENTAL
ENGINEERING
LABORATORY
BUILDING 2-3
*
Requester
!Y-77-qolz-(Poo Name:
Pro:)jecNto.:
Request Date: Prob. 1,4o.:-
Description: 1:---t-tc%.B4zr I /Iw@
Hold Sample For
Days Est. Date Needed:
Special Precaution
Lab Personnel
Date Rec'd. Sample: Analyst: Date Completed: Hrs. Spent:
-(Sllo
No. Sample Description
1 Total Hardness, mg/i as CaC03
2 Calcium Hardness, mg/l as CaC03
3 "P" Alkalinity,mg/i as CaC03
4 "M" Alkalinity,mg/i as CaC03
5 pH
6 Chloride, mg/l as Cl
7 Silica,mg/i as SiOl
8 Total Fluoride, mg/i as F
9 Soluble Fluoride mgll as F
10 Manganese, mg/i as Mn
Total Suspended Solids,mg/i
12 Volatile Suspended Solids,mg/i
131 Turbidity, NTU
14
gli
15
*mwwrus-, mg-/'
16 Conouatiw&V-
17 Sulfate, Mg/l as S04
18 Sulfide, mg/l as S
191 Sulfite,mg/i as SO,
20
Ammonia Nitrogen, mg/i as N
21
Kieldahl Nitrogen, mg/l as N
22 Nitrite,mg/i as N
23
Nitrate,mg/i as N
241 Ortho Phosphate, mg/i as P
25
Total Phosphate, mg/i as P
26 -409,-"V
27
COD, mg/i (Short,Strong, Dilute)
28 Total Organic Carbon - TOC mg/i as C
29 Surfactant, mg/i as LAS
301 Phenol, mg/i
31 Tannin & Lignin, mg/i
32 Total Cyanide, mg/i as CN
33 Oil and Grease, mg/i
34 Standard Plate Count No./100 ml
35 1361
Total Coliform. No./100 mi Fecal Coliform, No./100 ml
1371 Fecal Streptococcus, No./100
Comments:
mi
-70 V
'YOP
0 0.
6000,
or
7-7'9
fly
lnhwnaCloffftpondence cc: D. R. Ricker - 53-4N
D. L. Bacon/R. L. Bohon - 21-2W-05
Ta. J. A. PIGNATO COMMERCIAL CHEMICALS LAB - 236-2A-01
Fmm- E. A. REINER ENVIRONMENTAL LABORATORY/EE SU4ect MIL-SPEC AFFF BOD AND COD TESTING
& PC
21-2W-5
Date.MAY 25, 1982
Attached is a summary of the BOD, carbonaceous BOD, and COD test results on FC-203C, FC-206C; and FC-780B. This testing was conducted at the 3M Environmental Laboratory and four outside laboratories. The results were more variable than I had anticipated.
The Galbraith results on FC-206C were typical of their result from past testing, i.e., they had a very high BOD20/COD ratio. This occurred despite the fact that some of this testing was done with a nitrification inhibitor (the C-BOD results) and some of the tests were done using a seed unlikely to contain a large population of nitrifying organisms (seed from the Knoxville waste treatment system). While I had previously thought that their results were due to nitrification, I must now say that I do not know why Galbraith gets such atypically high BOD results.
I plan to use the average data from all of these tests in preparing ur Product Environmental Data Sheets and input for our Ma-1erial Safety Data Sheets. If you have any questions -oncerning these data, please feel free to contact me on 778-5079.
EAR/mk Attachment
BOD, CARBONACEOUS
BOD, AND COD DATA ON MIL-SPEC AFFF PRODUCT
BOD20
C-BOD
COD
BOD20
C-BOD20
Lab
(mg/kg)
(mg/kg)
(mg/kg)
COD
COD
FC-203C Lot 501
3M
580,000
600,000
730,000
.79
.81
740,000
Pace
800,000*
730,000*
810,000 730,000
Serco
440,000
440,000
737,000
.60
.60
Capsule
570,000
620,000
950,000
.6
.65
Galbraith
616,000
671,000
776,450
.79
.86
S & W Seed
Galbraith
670,000
641,000
776,450
.86
.82
Knoxville
Average S. D.
575,000
594,000
782,000
.73
.75
85,000
90,000
80,000
.12
.12
Calculated BOD's from different dilutions were very inconsistent. Pace agreed to repeat this work but inadvertently lost their repeated test results as well. We did not request a third testing nor did we include these
values in the averages.
FC-206C Lot 502
3M
Pace Serco Capsule Galbraith S & W Seed Galbraith Knoxville
290,000
350,000 240,000 260,000 416,500
395,500
290,000
370,000 260,000 320,000 411,000
374,000
380,000 360,000 450,000 370,000 410,000 407,250
407,250
0.78
0.78 0.65 0.63 1.02
.97
0.78
0.82 0.70 0.78 1.01
.92
Average S. D.
3M Pace Serco Capsule
3%75,000
338,000
396,000
.81
.83
000
57,00
33,000
.16
.11
FC-780B Lot 501
240,000
230,000
320,000
.74
.71
330,000
250,000
250,000
350,000
.71
.71
210,000
220,000
287,000
.73
.77
240,000
230,000
360,000
.67
.64
Average
235,000
232,000
329,000
.71
.71
28,000
.03
.05
Form 10620-5-PWO cc: LAS RECIUEST BOOK
- 42-5W
Ref: ENVIR. ASSESS.
(@oigm, PRODUCT:
INQ. # 7 @T0
PRODUCT REQUEST
ECOLOGICAL ASSESSMENT
FOR LABORATORY
WORK
DIVISION
LAB REQUEST NO.
3M'Actien'20OPap 7-
Name: 4
Request Date:
Project No.:
Code No.:
Sample Date:
REQUESTC-R
&Jeffey-
@12 7 1'7el
C?cl7 00 / 2600
Description: Purpose of Tests:
col)
PhoneNo. Prob. No. Date Needed:
/
PHYSICAL & CHEMICAL
PROPERTIES
Heatof Combustion Cal/G (BTU/Lb.) Density Ash Other
.!r@7 9 A
LABORATORYA(@-16
Date Received Sa
Z-7
Analyst:
Date Completed: 17 -1()- 7,Y
Hours Spent: 7-,Ah@? -
Y-
B
/0 A4-rC' IF
P
-r--
it/tol-7
1
Please Call Requester If Delays Are Encountered.
t)U-PLVC-ATES
WATER POLLUTION Cp H) rC-OD-) (FD 5)' <BOD, Ulti-mat7e
f0-c-,
GC
Oxygen Uptake Dehydrogenase Activity(TTC) Other
bl'
$E C- ATTA-C
It
ooo
4.(EO 11,4TA
tq
BIOASSAY Specify Organism and Method: 0/(" 4 cj-o
,4!jvcd,@ r
F-0ty
/0,.q t I
LEACHATE
FROM LEACHING
pH
COD
BOD 5
BOD, L!!timate
TOC
GC
TEST
Other
OTHER Bioaccumulation Persistence Degradation Products
S-aA
White - Return to Requester Canary - Environmental Engrg. O"Ice F lie ILnk Environmental Engrg. Lab Goldenrod -Return to Requostw
A-..,,S.S Illm I
F7(_ _ -7'8'9c>
e t3MCt3-TAL LARO$ZA -Mk Y DATA
3
C)
F-tiO.LAi3 REq, po.qq(ol
2 SA(14PLF-r-ot\)CENTP-.4-tioP -i 10 130D -BOT-rLF-S
c
D
E
r
c
-5
6
-P-a-O0ro-7
7
0, C)a7
9
04-lbig-.3
10
0.
II
12
I B@t) VAL es CAOULATF-0
14 Accoa Oiiu (4 Td
PDARD-
'5
17
3-0 0
o,14
6.-7
1.3
1 I.q
2.3
170 000
c, '7!06 >
A L-L
L-t
4,.s
2.0
3.75*
1.2
30acoo
2-8O,coo
2@io
2D 21 22. 23 24 25 26 27 28 20 30
2 33 34 35