Document R23VEaGkwZwkYXDgeYJXQ3QEn
DOW CONFIDENTIAL INFORMATION
CR! NUMBER
R&D REPORT
THE DOW CHEMICAL COMPANY
LABORATORY REPORT CODE
LAD-AR 94.01
DEPARTMENT
RESEARCH AND DEVELOPMENT
GEOGRAPHIC LOCATION
LOUISIANA
DATE ISSUED
January 4,1994
REPORT TITLE
Reactive Chemicals Testing of Compatibility of Absorbents with Process
PAGES IN _22___FULL REPORT
Chemicals
LAB NO. PROBLEM NO.
274 0000
AUTHOR'S LAST NAME AND INITIALS/MASTER NUMBER
J. G. Schell (432167), G. P. Wagener (431616), G. J. Barrilleaux (430781)
AUTHOR'S SIGNATURE
^
^_
.
REVIEWER'S AND/OR SUPERVISOR'S NAME
R. D. Summers
DESCRIPTIVE SUMMARY WITH CONCLUSIONS:
SUPERVISOR'S SIGNATURE
This report summarizes the results of Reactive Chemicals compatibility testing of several absorbents with process chemicals. Over the years, there have been many Reactive Chemical incidents which have been caused by using an absorbent to clean up a spill which was reactive with the chemical. The purpose of this report is to help prevent future incidents by providing a list of absorbents that have been tested for reactivity and emphasizing the need for testing of absorbents not on the list. A search of all of the Reactive Chemicals test results on absorbents and process chemicals which have been performed in the Louisiana Division Reactive Chemicals lab and a search of Reactive Chemicals test results from the REACHEM Global Reactive Chemicals database were combined and summarized in an Excel spreadsheet. This spreadsheet is continually being updated and currently has over 200 entries. Three tables are presented in this report listing the reactivities of the absorbents with process chemicals, sorted by absorbent, process chemical, and plant.
KEY WORDS
absorbent, compatibility, reactivity, Differential Thermal Analysis (DTA), Differential Scanning Calorimetry (DSC), Mixing Cell Calorimetry (MCC), Heat of Mixing (HOM), Accelerating Rate Calorimetry (ARC)
PATENT STATUS:
DISCLOSURE SUBMITTED
CASE FILED
GJ-NO ACTION REQUIRED
ARE THE MATERIALS DESCRIBED IN THIS REPORT ON YOUR COUNTRY'S INVENTORY? (TSCA, EINECS, ELINCS, CEPA, ETC.) STYES NO*
WILL THIS PRODUCT BE SOLD/USED IN OTHER COUNTRIES? YES* "NO
*CONTACT YOUR LOCAL REGULATORY COMPUANCE PERSON AND/OR CHIEF PRODUCT STEWARD.
DISTRIBUTION: FORM NO. C4301 (REV 03/92)
CRI - 566 MIDLAND, Ml CRI - FREEPORT,TX
CRI - PLAOUEMINE. LA DEPARTMENT FILES
DISTRIBUTION LIST IS CONTINUED ON ATTACHED PAGE.__________ _
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INTRODUCTION
Before an absorbent is used to clean up a chemical spill, the user should be sure that the absorbent and chemical are compatible. The purpose of this report is to provide a list of absorbents that have been tested for reactivity with various chemicals. The RESULTS AND DISCUSSION section of the report contains a discussion of the interpretation of the test results. If there is any doubt if an absorbent is compatible with a process chemical based on the test results, the Reactive Chemicals group should be consulted. Also, if an absorbent or chemical is not on the list, the Reactive Chemicals lab should be consulted to determine if testing is necessary. The Technology Center is another source of information on the compatibility of absorbents with process chemicals. Over the years there have been many Reactive Chemical incidents at Dow involving absorbents. A few examples of incidents at Dow and other companies are given below:
PAST INCIDENTS
Exotherm of Propylene Oxide bv Hi-Dri All Purpose Absorbent
A U.S. Area customer overfilled an underground storage tank while unloading a Dow tank car of propylene oxide creating about a 1000 gallon spill. An adjacent sewer leading to the municipal sewerage treatment plant contributed to a conscious decision not to apply water, but to absorb the spill. The fire fighters on the scene had the foresight to set up lines and monitors and to call in additional equipment. Absorbent materials sold for handling chemical spills were applied to the perimeters of the spill area and then a granular material (Hi-Dri) sold for absorption of grease and oil spills was applied within the pool area. Shortly after application, vaporization within the pool of liquid began and rapidly progressed. Ignition followed and rapidly developed into an intense fire engulfing the tank car. Several drums of flammables stored in the area ruptured and were propelled into the air adding to the spectacular situation. The fire was brought under control after several minutes of burn-off, dilution, and finally, the application of an alcohol foam. Subsequent tests with Hi-Dri All Purpose Absorbent revealed incompatibility with propylene oxide.
Liquid Waste/Flv Ash Absorbent Reaction Generates Heat and Foam
A reaction occurred between a liquid waste material and fly ash absorbent while attempting to solidify the waste for incineration. The reaction generated heat and foam and spilled over the top of the drum into a diked hazardous waste area. It was determined that an acid-base reaction caused this incident. A sample of the liquid waste was found to contain 21% sulfuric acid. The source of the base was calcium, magnesium, and potassium oxide components in the fly ash.
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Zorball Incompatible Absorbent for Stvrene
In order to unplug an inlet screen, approximately eight gallons of styrene was discharged into waste drums for incineration at the Environmental Operations Plant (EOP). EOP required solidification of liquid waste with an absorbent prior to incineration. Personnel added an absorbent and within minutes the mixture started heating and generating smoke. Water was added to dissipate the heat. Plant procedures state that only sand or vermiculite should be used to absorb styrene. Zorball absorbent was substituted without conferring with the Styrene Technology Center to verify compatibility.
Potassium Hydroxide Reaction with Absorball
A 55 gallon drum of off-grade aqueous KOH was absorbed with Absorball in eight 15 gallon waste drums. The drums became warm so the drum tops were removed and no further heating occurred.
Sodium Persulfate Reaction with Slik-Wik (Ground Com Cobsl
A leakage of sodium persulfate was absorbed in Slik-Wik (ground com cobs) and packed in drums for later incineration. Several hours later, one of the drums became hot, bulged, and emitted a gas. The persulfate in this and the remaining drums was diluted with water and then absorbed into Safe-T-Sorb (ground clay).
Reactions with Sawdust
A differential pressure instrument on a benzoyl chloride tank was cleared for maintenance. A small amount of benzoyl chloride was put into a waste pail with sawdust absorbent. The contents of the pail was later observed to be smoldering. It was quenched with no damage.
Smoke was seen coming from a plastic waste drum of an acrylate and sawdust. This was found to be the first of ten drums and contained some residual impurities which catalyzed the decomposition. There was no further damage.
A Dowtherm leak occurred during a furnace charging operation (transfusion) and some Dowtherm was spilled on the concrete. Sawdust was applied with the intent of cleaning it up later, but it was in contact with a temporary hot steam line. The heat speeded up the spontaneous combustion process, igniting it.
A drum of toluene diisocyanate was spilled in a warehouse and was cleaned up by using sawdust and placing the mixture in several 55 gallon drums. The drums were placed next to a building where a nearby hot tank was located and the reaction took off. One of the drums caught fire and ail of them overpressured and the lids blew on two of the drums.
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Amines from a leak in a pipe flange were absorbed with sawdust. The sawdust then began emitting fumes of amines due to the onset of an exotherm from an amine/sawdust reaction.
Waste amines were mixed with sawdust and left in a storage building over a weekend. When workers returned, a charred mass was found.
Sawdust was used to clean up a 25 gallon spill of DETA from the slab and roof of a control room. When the temperature of the sawdust began to rise (60-70 degrees C), the material was loaded into 14 gallon drums. The contents of plastic drums were saturated with water and the temperature continued to be monitored until no further reaction could be detected.
About 75 grams of potassium hydride dispersed in mineral oil had been deactivated by adding it to methanol. After the hydrogen evolution ceased, the residual slurry was poured into a 5 gallon waste pail containing sawdust and waste chlorinated solvents, Freon 1131 and Chlorothene2. The fact that the deactivation reaction produces potassium methoxide was not considered, so the residue was not neutralized with acid. The potassium methoxide reacted with the sawdust and Chlorothene to produce heat, possibly leading to the spontaneous combustion. The residue of a fire in the walk-in hood was discovered a few days later.
Sawdust was put in a dumpster to absorb aminoethylethanolamine (AEEA) and caught fire. There were no injuries or property damage.
At the MDI plant, a one-gallon spill of anhydrous ferric chloride (20% in DEG) from a leaking drum was cleaned up with sawdust, placed in a 30 gallon covered plastic drum and stored in a "hot room" (120 degrees F) to keep moisture out. Nine days later, it caught fire. No damage resulted.
Reactions with Peat Moss
An amine spill off-site by the product carrier was absorbed with a peat moss material. The absorbed material was placed in drums and returned to the Dow facility for disposal. The material began to heat up in the drums and was then spread on the ground at a secure landfill to dissipate the heat. Due to the increased availability of air, the hot absorbent ignited. It was quickly extinguished with water with no property damage.
The contents of two 16 gallon open top containers of a polyaromatic polyisocyanate (PAPI) were solidified with peat moss in accordance with procedures outlined by the product group. The water in the peat reacted with the
'Trademark of H. I. duPont de Nemours & Co., Inc. ^Trademark of The Dow Chemical Company
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PAPI, as is normal, but more rapidly than usual, causing a polymerization. Because the drum was overfilled with liquid, the foam generated by the reaction spilled over onto the concrete. A written procedure has been created for disposal of PAPI 27 to use only dry sawdust for solidification and to fill drums only half way.
EXPERIMENTAL
The test results of the reactivity of various absorbents with process chemicals summarized in Tables l-lll were obtained from searches of the LAD Reactive Chemicals lab analyses and test results from the REACHEM Global Reactive Chemicals database. These tests include Differential Thermal Analysis (DTA), Differential Scanning Calorimetry (DSC), Mixing Cell Calorimetry (MCC), Heat of Mixing (HOM), and Accelerating Rate Calorimetry (ARC).
Differential Thermal Analysis (DTA)
DTA was used prior to 1987 to detect exothermic or endothermic reactions and the reaction onset temperatures as the temperature of the sample was increased at a set rate . DTA only measures the difference in temperature between the absorbent and process chemical sample and a reference, and not the heat of reaction.
Differential Scanning Calorimetry fDSCI
DSC is currently used as a screening tool to determine the exothermic or endothermic heat of reaction at elevated temperatures and the reaction onset temperature. The DSC method is similar to the DTA method except that the sample and reference material are maintained at the exact same temperature as the temperature is increased at a set rate. If the absorbent and process chemical sample exothermically react at a certain temperature, the sample heater requires less energy input than the reference heater to maintain the same temperature. This energy input difference is precisely equivalent to the exothermic heat evolved and is a direct calorimetric measure of the heat of reaction. Thus DSC is considered to be more quantitative than DTA.
Mixing Cell Calorimetry (MCC) for Heat of Mixing
MCC is used to measure the heat of mixing evolved from mixing an absorbent and a process chemical at ambient temperature. The LAD Reactive Chemicals lab and several other sites use a Two-drop heat of mixing calorimeter while other sites use a Two-milliliter heat of mixing calorimeter.
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Simple Heat of Mixing Test (HOM)
Sometimes a simple heat of mixing test was performed at ambient temperature by mixing the absorbent and process chemical in a near-adiabatic Dewar flask and measuring temperature rise.
Together, the DSC and heat of mixing tests are screening tools used to determine if there are any signs of reactivity between an absorbent and process chemical at ambient and elevated temperatures.
Accelerating Rate Calorimetry (ARC)
If more accurate and detailed thermal data are deemed necessary after the DSC and heat of mixing tests, then an ARC test is performed. A larger sample of the absorbent and process chemical are loaded into an ARC sphere and a waitsearch-heat sequence with a heat step usually of 10 degrees C is repeated from ambient temperature to an end temperature. If the self heat rate of an exothermic reaction between the absorbent and the process chemical exceeds 0.02 degrees C per minute, the reaction is allowed to proceed on its own under near-adiabatic conditions. This method gives an accurate measure of the heat of reaction after corrections are made for the thermal inertia of the sample container, and also a fairly conservative estimate of the conditions for a runaway reaction. The ARC onset-of-reaction temperature is more accurate and lower than the DSC onset temperature, since the DSC onset temperature increases with higher temperature scan rates.
RESULTS AND DISCUSSION
Table I (pp. 8-12) lists the reactivity of absorbents with process chemicals and is sorted by absorbents. The table includes the absorbent, process chemical, plant, reference number (corresponding to the Reactive Chemicals test number), test (DTA, DSC, MCC, HOM, or ARC), reactivity and onset temperature, and heat of reaction. Table II (pp. 13-17) is sorted by process chemical and Table III (pp. 18-22) is sorted by plant. If no thermal reactivity was observed between the absorbent and the process chemical, and the test was run, for example, to 200 degrees C, the remark under the Reactivity and Onset Temperature heading would read "No exo to 200 C." If an exothermic reaction was observed with an onset temperature of 100 degrees C, the remark would read "Exo at 100 C."
If MCC or HOM and DSC or ARC test results indicate no reactivity between an absorbent and a process chemical at ambient and elevated temperatures, then they can be considered compatible.
If MCC or HOM and/or DSC or ARC test results indicate an exothermic reaction between an absorbent and a process chemical, then the Reactive Chemicals
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group should be consulted to help interpret th r suits to decide if an absorbent should or should not be used.
If only DTA, DSC, or ARC tests were run and indicated no reactivity at elevated temperatures, then a MCC or HOM test should be performed to check for reactivity at ambient temperature before an absorbent and process chemical are considered compatible.
There may be some absorbents in the REACHEM Global Reactive Chemicals database that were not found by our search, and therefore not included in the tables. REACHEM does not search using name fragments or wild cards for letters. The search had to be made by entering specific names of known absorbents. If an absorbent is not in the tables, the Reactive Chemicals group should be consulted. A search will be made for the absorbent in the REACHEM database and if not found, will be tested.
It is important to remember that according to the Reactive Chemicals Program, it is the responsibility of the owner of the chemical or process (plant personnel) to obtain sufficient data to assure safe operation. The Reactive Chemicals Program is designed to assist the owner in doing this. The Reactive Chemicals group is available for testing, interpretation of results, consultation, reviews, training programs, and investigation of incidents.
The absorbent Excel spreadsheet is continually being updated as new tests are run. These include re-checks, new absorbents, and absorbents used with new process chemicals. Therefore, if an absorbent is not in the table, the Reactive Chemicals group should be contacted to see if it was run since this report was issued. Updated versions of the tables will be re-issued at appropriate times.
CONCLUSIONS
1. Before an absorbent is used to clean up a chemical spill, the user must be sure that the absorbent and chemical are compatible. If the absorbent or chemical is not on the list of tested materials included in this report, Reactive Chemical testing should be performed.
2. The Reactive Chemicals testing used to check for reactivity have included DTA, DSC, MCC, HOM, and ARC.
3. An Excel spreadsheet with over 200 entries of the reactivities of different absorbents and process chemicals resides in the LAD Reactive Chemicals lab. The spreadsheet is continually being updated.
4. Over the years there have been many Reactive Chemical incidents at Dow involving absorbents. The majority of incidents involved sawdust or other cellulosic materials.
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ABSORBENT
ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD CALCINED OIL ABSORBENT CV DtATOMACEOUS EARTH FLOOR DRY ABSORBENT FLOOR DRY ABSORBENT FLOOR DRY SORBENT FLOOR DRY SORBENT FLOOR DRY SORBENT FLOOR DRY SORBENT
8 TABLE!
REACTIVITY OF ABSORBENT WITH PROCESS CHEMICAL (SORTED BY ABSORBENT)
PROCESS CHEMICAL
PLANT
REF.
TEST
REACTIVITY & HEAT OF RXN
ONSET TEMP (C)
(CAL/G)
AMOKON 32 OIL AMOKON 32 OIL DOW CORNING 561 SILICONE OIL DOW CORNING 561 SILICONE OIL NUTO H-46 (EXXON) NUTO H-46 (EXXON) STYRENE TERESSTIC 33 OIL (EXXON) TERESSTIC 33 OIL (EXXON) TERESSTIC 68 (EXXON) TERESSTIC 68 (EXXON) UNIVISJ13 (EXXON) UNIVISJ13 (EXXON) UNIVOLT N 61 MINERAL OIL (EXXON) UNIVOLT N 61 MINERAL OIL (EXXON) AMOKON 32 OIL AMOKON 32 OIL DOW CORNING 561 SILICONE OIL DOW CORNING 561 SILICONE OIL NUTO H-46 (EXXON) NUTO H-46 (EXXON) TERESSTIC 33 OIL (EXXON) TERESSTIC 33 OIL (EXXON) TERESSTIC 68 (EXXON) TERESSTIC 68 (EXXON) UNIVIS J 13 (EXXON) UNIVISJ 13 (EXXON) UNIVOLT N 61 MINERAL OIL (EXXON) UNIVOLT N 61 MINERAL OIL (EXXON) METHYLENE CHLORIDE + CHLOROFORM PROPYLENE OXIDE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE 21% PHOSPHORIC ACID 28% HYDROCHLORIC ACID 5% HYDROCHLORIC ACID 50% SODIUM HYDROXIDE
TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX B-7101 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 METHANES GLYCOL 1 LGTI LGTI LGTI LGTI LGTI LGTI
RCT-91-0252 RCT-91-0252 RCT-91-0256 RCT-91-0256 RCT-91-0248 RCT-91-0248 RCT-B7-0890 RCT-91-0241 RCT-91 -0241 RCT-91 -0245 RCT-91-0245 RCT-91-0237 RCT-91-0237 RCT-91-0260 RCT-91-0260 RCT-91-0251 RCT-91-0251 RCT-91-0255 RCT-91-0255 RCT-91-0247 RCT-91-0247 RCT-91-0240 RCT-91-0240 RCT-91-0244 RCT-91-0244 RCT-91-0236 RCT-91-0236 RCT-91-0259 RCT-91-0259 91301 92150 92003 92003 92173 92173 92173 92173
DSC MCC DSC MCC DSC MCC ARC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC DSC MCC DSC MCC HOM HOM HOM
NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C SL EXO AT 25 C EXO AT 96 C SL EXO AT 65 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25C NONE TO 200 C NONE AT25C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C EXO ATI 46 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C SL EXO AT 25 C SL EXO AT 25 C SL EXO AT 25 C
0 0 0 0 0 -0.7 -72 -0.5 -0.7 0 -0.5 0 -0.5 0 -0.5 0 0 0 -0.7 0 -0.7 0 -0.5 0 0 0 0 0 -0.5 0 INCOMPLETE -1.8 0 0 1 DEG C RISE 1 DEG C RISE 3 DEG C RISE
DO 0 7 2 3 9 1 C O N F ID E N T IA L
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C O N F ID E N T IA L
FLOOR DRY SORBENT FLOOR DRY SORBENT FLOOR DRY SORBENT FLOOR DRY SORBENT FLY ASH FLY ASH FUMEAWAY CRYSTALS FUMEAWAY CRYSTALS HI DRY HI DRY HI DRY HI DRY K SORB K SORB K SORB K SORB K SORB K SORB K SORB K SORB K SORB K SORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB
EPICHLOROHYDRIN
E RCHLOROHY DRIN
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
21% SULFURIC ACID IN WATER
METHYLENE CHLORIDE + CHLOROFORM
EPICHLOROHYDRIN
EPICHLOROHYDRIN
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
NATURAL GASOLINE
NATURAL GASOLINE
ALLYL PROPYLENE DICHLORIDE
ALLYL PROPYLENE DICHLORIDE
BENZENE, TOLUENE, XYLENE
BENZENE, TOLUENE, XYLENE
DIETHANOLAMINE
DIETHANOLAMINE
METHYL DIETHANOLAMINE
METHYL DIETHANOLAMINE
NATURAL GASOLINE
NATURAL GASOLINE
25% SODIUM HYDROXIDE
25% SODIUM HYDROXIDE
43% 2,3-DICHLOROPROPENE,23% EPI,...
43% 2,3-DICHLOROPROPENE,23% EPI,...
45% PHENOL, 35% ACETONE. 20% CUMENE
45% PHENOL, 35% ACETONE, 20% CUMENE
50% SODIUM HYDROXIDE
50% SODIUM HYDROXIDE
60% CUMENE HYDROPEROXIDE,20% CUMEN
B0% CUMENE HYDROPEROXIDE,20% CUMEN
95% PHENOL IN WATER
95% PHENOL IN WATER
9B% SULFURIC ACID
/
98% SULFURIC ACID
ACETONE
ACETONE
ALLYL CHLORIDE
ALLYL CHLORIDE
ALLYL CHLORIDE TARS (T-314 BOTTOMS)
ALLYL CHLORIDE TARS (T-314 BOTTOMS)
BENZYL TRIMETHYL AMMONIUM CHLORIDE
BENZYL TRIMETHYL AMMONIUM CHLORIDE
9
GLYCERIN 2 GLYCERIN 2 LGTI LGTI METHANES METHANES TX B-7503 TX B-7503 PROMIX PROMIX PROMIX PROMIX SOL/E DC SOL/E DC LHC 3 LHC 3 LHC 3 LHC 3 PROMIX PROMIX PROMIX PROMIX TX B-6201 TX B-6201 TX B-7503 TX B-7503 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX B-6201 TX B-6201 TX OC-301 TX OC-301 TX B-6201 TX B-6201 TX B-7503 TX B-7503 TX B-7503 TX B-7503 TX B-6201 TX B-6201
RCT-85-0311 RCT-85-0311 RCL-92-0034 RCL-92-0034 92002 91301 RCT-92-0614 RCT-92-0614 93057 93057 93057 93057 93096 93096 93013 93013 93013 93013 93057 93057 93057 93057 RCT-91-1232 RCT-91-1232 RCT-92-0477 RCT-92-0477 RCT-91-1206 RCT-91-1206 RCT-91-1204 . RCT-91-1204 RCT-91-1207 RCT-91-1207 RCT-91-1235 RCT-91-1235 RCT-91-1200 RCT-91-1200 RCT-91-1237 RCT-91-1237 RCT-92-03B9 RCT-92-0389 RCT-92-0454 RCT-92-0454 RCT-91-1234 RCT-91-1234
DTA MCC DSC MCC MCC DSC DSC MCC DSC HOM HOM DSC HOM DSC HOM DSC DSC HOM HOM DSC HOM DSC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC
EXO AT 235 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C EXO AT 25 C NONE TO 200 C EXOAT 143 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 150 C NONE AT 25 C NONE TO 200 C NONE TO 200 C SL EXO AT 25 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C EXO AT 36 C EXO AT 25 C EXO AT 154 C NONE AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 60 C EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 56 C EXO AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 128 C NONE AT 25 C EXOAT 141 C NONE AT 25 C EXOAT 150 C NONE AT 25 C
INCOMPLETE -0.3 0 -1.8 -95 0 -147 -0.5 0 0 0 0 0
INCOMPLETE 0 0 0
1 DEG C RISE 0 0 0 0
-101 -5.5 -50
0 0 0 INCOMPLETE -1 0 0 0 0 -6.9 -13 0 0 -6.2 0 -11 0 INCOMPLETE 0
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OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD (3M) OIL ABSORBENT PAD (3M) OIL ABSORBENT PAD (3M) OIL ABSORBENT PAD (3M) n OIL SORBANT (3M) O O OIL SORBANT (3M) Z OIL SORBENT BOOM TYPE 270 O OIL SORBENT BOOM TYPE 270 OfTJ >N*) OIL SORBENT PAD TYPE 156 zw
rH U 3>
BETZ OPTIMEEN BETZOPTIMEEN CUMENE CUMENE EPICHLOROHYDRIN EPICHLOROHYDRIN EPICHLOROHYDRIN + WATER EPICHLOROHYDRIN + WATER METHYL ISOBUTYL KETONE METHYL ISOBUTYL KETONE NUTO 46 LUBE OIL NUTO 46 LUBE OIL PHENOL TERESSTIC 33 LUBE OIL TERESSTIC 33 LUBE OIL VARSOL VARSOL ZERICE 68 LUBE OIL ZERICE 68 LUBE OIL 30-40% SULFURIC ACID 60-80% SULFURIC ACID 60-80% SULFURIC ACID 60-80% SULFURIC ACID DIESEL DIESEL METHYLDIETHANOLAMIN E DOWTHERM A DOWTHERM J SYLTHERM 800 TOLUENE DIISOCYANATE TOLUENE DIISOCYANATE VORANATE 3071 VORANATE 3072 VORANATE TCPA ISOCYANATE VORANATE TCPA ISOCYANATE 21% PHOSPHORIC ACID 28% HYDROCHLORIC ACID 5% HYDROCHLORIC ACID 50% SODIUM HYDROXIDE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE REGAL 32 LUBE OIL + 25% NaOH REGAL 32 LUBE OIL 4 25% NaOH REGAL 32 LUBE OIL + 25% NaOH
10
TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX B-6201 TX B-6201 TX B-7503 TX B-7503 TX B-6201 TX B-6201 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 METHANES METHANES METHANES METHANES PLS PLS PROMIX TX B-3831 TX B-3831 TX B-3831 TX B-451 TX B-451 TX B-451 TX B-451 TX B-451 TX B-451 LGTI LGTI LGTI LGTI LGTI LGTI CAUSTIC CAUSTIC CAUSTIC
RCT-91-1199 RCT-91-1199 RCT-91-1208 RCT-91-1208 RCT-91-1233 RCT-91-1233 RCT-92-0342 RCT-92-0342 RCT-91-1236 RCT-91-1236 RCT-91-1201 RCT-91-1201 RCT-91-1209 RCT-91-1205 RCT-91-1205 RCT-91-1202 RCT-91-1202 RCT-91-1203 RCT-91-1203 92033 92033 92033 92033 92096 92096 91103 RCT-86-0306 RCT-86-0304 RCT-86-0305 RCT-91 -0819 RCT-91-0819 RCT-91-0818 RCT-91-0818 RCT-91-0817 RCT-91-0817 92173 92173 92173 92173 92003 92003 92035 92035 92035
DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC DSC MCC DSC MCC DSC MCC HOM MCC HOM DSC MCC DSC MCC DTA DTA DTA DSC MCC DSC MCC DSC MCC MCC HOM MCC MCC MCC DSC MCC DSC MCC
EXO AT 67 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C EXO ATI 46 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C SL EXO AT 25 C SL EXO AT 25 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 325 C NONE TO 325 C NONE TO 325 C NONE TO 300 C NONE AT 25 C NONE TO 300 C NONE AT 25 C NONE TO 300 C NONE AT 25 C NONE AT 25 C SL EXO AT 25 C NONE AT 25 C NONE AT 25 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C
-27 -3.8
0 0 0 0 >-323 0 0 0 0 0 0 0 0 0 0 0 0 1 DEG C RISE -4.9 4 DEG C RISE 0 -0.8 0 0 0 0 0 0 0 0 0 0 0 0 1 DEG C RISE 0 0 -1.1 0 0 0 0
Dow Confidential
OIL SORBENT PAD TYPE 156
REGAL 32 LUBE OIL + 25% NaOH
OIL-SORB
74% METHANOL. 15% EO. 4% EG
OIL-SORB
74% METHANOL, 15% EO, 4% EG
OYLGONE (BAG)
SYNESSTIC 100
OYLGONE (BAG)
SYNESSTIC 100
OYLGONE (BAG)
TERESSTIC 32
OYLGONE (BAG)
TERESSTIC 32
OYLGONE (PEAT)
SYNESSTIC 100
OYLGONE (PEAT)
SYNESSTIC 100
OYLGONE (PEAT)
TERESSTIC 32
OYLGONE (PEAT)
TERESSTIC 32
OYLGONE (PEAT)
TERESSTIC 32
PEAT MOSS
BENZENE, TOLUENE,XYLENE
PEAT MOSS
BENZENE, TOLUENE,XYLENE
PEAT MOSS
DIETHANOLAMINE
PEAT MOSS
DIETHANOLAMINE
PEAT MOSS
METHYLENE CHLORIDE
SAND
PDC + DEGREASER SOLVENT
SAND
PDC + DEGREASER SOLVENT
SAND
PROPYLENE DICHLORIDE (PDC)
SORBATHENE
1.1.1 -TRICHLOROETHANE
SORBATHENE
1.1 -DICHLORO-1 -FLUOROETHANE (R-141B)
SORBATHENE
1,1-DICHLORO-2,2,2-TRIFLUOROETHANE
SORBATHENE
DICHLOROTETRAFLUOROETHANE (R-114)
SORBATHENE
EtCI + 1.1-DICHLORO-2-FLUOROETHANE
SORBATHENE
ETHYLCHLORIDE (EtCI)
SORBATHENE
FLUORODICHLOROETHANE (R-141B)
SORBATHENE
FREON R-11
SORBATHENE
FREON R-11
SORBATHENE
FREON R-12
SORBATHENE
METHYLAL + TRIMETHYLAMINE
SORBATHENE
METHYLENE CHLORIDE
SORBATHENE
N-BUTANE
SORBATHENE
STYRENE
SORBATHENE
STYRENE
SORBATHENE
TRIFLUORODICHLOROETHANE (R-123)
SORBATHENE ON PU-FOAM
ETHYLACETATE .
SORBATHENE ON PU-FOAM
METHYLENE CHLORIDE
SORBATHENE XFS-4022
PROPYLENE OXIDE
SORBATHENE XU-43522.00 GASOLINE VAPOR RECOVERY
SORBATHENE XUS-40323.00
PROPYLENE OXIDE
SORBATHENE XUS-43493
PERCHLOROETHYLENE
SORBATHENE XUS-43493.00
PROPYLENE OXIDE
SORBENT ABSORBENT PAD
85% BUTYLENE OXIDE, 8.5% ETHYL ACETATE
11
CAUSTIC GLYCOL 2 GLYCOL 2 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 LHC 3 LHC 3 LHC 3 LHC 3 METHANES GLYCOL 1 GLYCOL 1 GLYCOL 1 SOLVENTS C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE STADE R&D C4-1 STADE C4-3 STADE C4-1 STADE C4-3 STADE C4-1 STADE C4-1 STADE C4-1 STADE GLYCOL 1 LARKIN LAB GLYCOL 1 SOLVENTS GLYCOL 1 TX B-1510
92035 91200 91200 RCT-92-0074 RCT-92-0074 RCT-92-0076 RCT-92-0076 RCT-92-0075 RCT-92-0075 RCT-92-0077 RCT-92-0077 RCT-92-0142 93013 93013 93013 93013 92105 91304 91304 91304 RCM-91 -0221 RCR-91-3028 RCR -91-3029 RCR-92-1091 RCR-91-3232 RCR-91-3231 RCR-91-6406 RCR-92-1623 RCR-92-1623 RCR-92-0921 RCR-90-0126 RCR-91-3091 RCR-91-3056 RCR-91-6408 RCR-91-3055 RCR-91-6405 RCR-91-3304 RCR-91-6438 92120 RCM-92-0207 92120 RCM-92-0456 92120 RCT-93-0063
DSC DSC HOM DSC MCC DSC MCC DSC MCC DSC MCC ARC HOM DSC HOM DSC HOM DSC ARC DSC ARC DSC DSC DSC DSC DSC ARC DSC MCC DSC DSC DSC DSC ARC DSC ARC DSC ARC DSC ARC DSC ARC DSC DSC
NONE TO 200 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 221 C NONE AT 25 C NONE TO 200 C SL EXOAT 25 C NONE TO 200 C NONE AT 25 C EXO AT 200 C NONE TO 200 C EXO AT 2(X) C NONE TO 250 C EXO AT 197 C EXO AT 194 C EXO AT 249 C EXO AT 224 C EXO AT 232 C SL EXO ATI 57 C SL EXO AT 220 C EXO AT 25 C EXO AT-112 C EXO AT 46 C NONE TO 350 C EXO AT 231 C EXO AT 99 C EXO AT 206 C SL EXOAT 162 C EXO AT 183 C NONE TO 250 C NONE TO 200 C NONE TO 300 C NONE TO 200 C NONE TO 300 C NONE TO 200 C NONE TO 200 C
0 0 2 OEG C RISE 0 -1 0 -1 0 -0.5 0 0 -157 0 0 1 DEG C RISE 0 0 INCOMPLETE 0 INCOMPLETE 0 -1.2 -2.4 -8.6 -6.7 -41 INCOMPLETE -1.2 -6.7 -8.8 -6.9 0 -29 -177 -100 INCOMPLETE -4.3 0 0 0 0 0 0 0
DO 0 7 2 3 9 4
CONFTDFNTT
1> Dow Confidential
SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBITOL SORBITOL SORBITOL SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB SPILL-KLEAN SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN
12
85% BUTYLENE OXIDE, 8.5% ETHYL ACETATE
TX B-1510
90% 1,2-DICHLOROETHYLENE, 10% CL'D C2S
TX B-1510
90% 1,2-DICHLOROETHYLENE, 10%CL'DC2'S
TX B-1510
B-RECYCLE (40% TETRACHLOROETHANE, ETC) TX B-1510
B-RECYCLE {40% TETRACHLOROETHANE, ETC) TX B-1510
CRUDE PERCHLOROETHYLENE
TX B-1510
CRUDE PERCHLOROETHYLENE
TX B-1510
DOWTHERM G
TX B-1510
DOWTHERM G
TX B-1510
SUN OIL 21
TX B-1510
SUN OIL 21
TX B-1510
TRICHLOROETHYLENE
TX B-1510
TRICHLOROETHYLENE
TX B-1510
ZERICE 68 COMPRESSOR OIL
TX B-1510
ZERICE 68 COMPRESSOR OIL
TX B-1510
30/70% HEXA & ME HEXAHYDROPHTHALIC ANHYDRTX B-1470C
ETHYLENE CARBOANTE/K CARBONATE
TX B-1470
ETHYLENE CARBONATE
TX B-1470
21% PHOSPHORIC ACID
LGTI
28% HYDROCHLORIC ACID
LGTI
5% HYDROCHLORIC ACID
LGTI
50% SODIUM HYDROXIDE
LGTI
METHYL DIETHANOLAMINE
LGTI
METHYL DIETHANOLAMINE
LGTI
MIXED LAB WASTE
LGTI
MIXED LAB WASTE
LGTI
METHYLENE CHLORIDE
METHANES
WATER (CONOENSATE)
TX B-2405
WATER (CONDENSATE)
TX B-2405
WATER (COOLING TOWER)
TX B-2405
WATER (COOLING TOWER)
TX B-2405
WATER (POTABLE)
TX B-2405
WATER (POTABLE)
TX B-2405
WATER (RIVER)
TX B-2405
WATER (RIVER)
TX B-2405
RCT-93-0063 RCT-93-0065 RCT-93-0065 RCT-93-0071 RCT-93-0071 RCT-93-0069 RCT-93-0069 RCT-93-0077 RCT-93-0077 RCT-93-0075 RCT-93-0075 RCT-93-0067 RCT-93-0067 RCT-93-0073 RCT-93-0073 RCT-93-0040 RCT-93-0559 RCT-93-0558 92173 92173 92173 92173 RCL-92-0035 RCL-92-0035 92003 92003 92105 RCT-92-0081 RCT-92-0081 RCT-92-0079 RCT-92-0079 RCT-92-0078 RCT-92-007B RCT-92-0080 RCT-92-0080
MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC DSC DSC MCC MCC MCC MCC MCC DSC MCC DSC HOM DSC MCC DSC MCC DSC MCC DSC MCC
NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C EXOAT 151 C EXO AT 191 C EXO AT 131 C NONE AT 25 C NONE AT 25 C NONE AT 25 C NONE AT 25 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 167 C ENDO AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 200 C EXO AT 25 C
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 -13.6 INCOMPLETE -6.9 0 0 0 0 -2 0 -2 0 2 DEG C DROP 0 -5.5 0 -5 0 -6.9 0 -8.6
DO 0 7 2 3 9 5
CONFIDENTIAL.
Dow Confidential
ABSORBENT
SORBATHENE SORBATHENE SORBATHENE FLOOR DRY SORBENT OIL ABSORBENT PAD (3M) SPAGH SORB FLY ASH OCLANSORB OCLANSORB FLOOR DRY SORBENT OIL ABSORBENT PAD (3M) SPAGH SORB OIL ABSORBENT (CALCINED) SORBITOL OCLANSORB OCLANSORB OCLANSORB OCLANSORB FLOOR DRY SORBENT OIL ABSORBENT PAD (3M) SPAGH SORB FLOOR DRY SORBENT OCLANSORB OCLANSORB OIL ABSORBENT PAD (3M) SPAGH SORB OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL-SORB OIL-SORB OCLANSORB OCLANSORB SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD
13 TABLE tl
REACTIVITY OF ABSORBENT WITH PROCESS CHEMICAL (SORTED BY PROCESS CHEMICAL)
PROCESS CHEMICAL
PLANT
REF.
TEST
REACTIVITY & HEAT OF RXN
ONSET TEMP (C)
fCAL/GI
1,1,1 -TRICHLOROETHANE
SOLVENTS
1,1-DICHLORO-l-FLUOROETHANE (R-141B)
C4-1 STADE
1,1-DICHLORO-2,2,2-TRIFLUOROETHANE
C4-1 STADE
21% PHOSPHORIC ACID
LGTI
21% PHOSPHORIC ACID
LGTI
21% PHOSPHORIC ACID
LGTI
21% SULFURIC ACID IN WATER
METHANES
25% SODIUM HYDROXIDE
TX B-6201
25% SODIUM HYDROXIDE
TX B-6201
28% HYDROCHLORIC ACID
LGTI
28% HYDROCHLORIC ACID
LGTI
28% HYDROCHLORIC ACID
LGTI
30-40% SULFURIC ACID
METHANES
30/70% HEXA & ME HEXAHYOROPHTHALIC ANHYDR TX B-1470C
43% 2,3-DICHLOROPROPENE,23% EPI,...
TX B-7503
43% 2,3-DICHLOROPROPENE,23% EPI,...
TX B-7503
45% PHENOL, 35% ACETONE, 20% CUMENE
TX OC-301
45% PHENOL. 35% ACETONE, 20% CUMENE
TX OC-301
5% HYDROCHLORIC ACID
LGTI
5% HYDROCHLORIC ACID
LGTI
5% HYDROCHLORIC ACID
LGTI
50% SODIUM HYDROXIDE
LGTI
50% SODIUM HYDROXIDE
TX OC-301
50% SODIUM HYDROXIDE
TX OC-301
50% SODIUM HYDROXIDE
LGTI
50% SODIUM HYDROXIDE
LGTI
60-80% SULFURIC ACID
METHANES
60-80% SULFURIC ACID
METHANES
60-80% SULFURIC ACID
METHANES
74% METHANOL, 15% EO. 4% EG
GLYCOL 2
74% METHANOL, 15% EO, 4% EG
GLYCOL 2
80% CUMENE HYDROPEROXIDE,20% CUMEN
TX OC-301
80% CUMENE HYDROPEROXIDE,20% CUMEN
TX OC-301
85% BUTYLENE OXIDE, 8.5% ETHYL ACETATE
TX B-1510
85% BUTYLENE OXIDE, 8.5% ETHYL ACETATE
TX B-1510
90% 1,2-DICHLOROETHYLENE, 10% CL'DC2'S
TX B-1510
90% 1,2-DICHLOROETHYLENE, 10% CL'D C2S
TX B-1510
RCM-91-0221 RCR-91-3028 RCR -91-3029 92173 92173 92173 92002 RCT-91-1232 RCT-91-1232 92173 92173 92173 92033 RCT-93-0040 RCT-92-0477 RCT-92-0477 RCT-91-1206 RCT-91-1206 92173 92173 92173 92173 RCT-91-1204 RCT-91-1204 92173 92173 92033 92033 92033 91200 91200 RCT-91-1207 RCT-91-1207 RCT-93-0063 RCT-93-0063 RCT-93-0065 RCT-93-0065
ARC DSC DSC MCC . MCC MCC MCC DSC MCC HOM HOM MCC HOM DSC DSC MCC DSC MCC HOM MCC MCC HOM DSC MCC MCC MCC MCC HOM DSC DSC HOM DSC MCC DSC MCC DSC MCC
NONE TO 250 C EXOAT197C EXOAT 194 C NONE AT 25 C NONE AT 25 C NONE AT 25 C EXOAT 25 C EXOAT 36 C EXO AT 25 C SL EXO AT 25 C SL EXO AT 25 C NONE AT 25 C SL EXO AT 25 C EXO AT 151 C EXOAT 154 C NONE AT 25 C NONE TO 200 C NONE AT 25 C SL EXO AT 25 C NONE AT 25 C NONE AT 25 C SL EXO AT 25 C EXO AT 60 C EXO AT 25 C NONE AT 25 C NONE AT 25 C SL EXO AT 25 C SL EXO AT 25 C NONE TO 200 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C
0 -1.2 -2.4
0 0 0 -95 -101 -5.5 1 DEG C RISE 1 DEG C RISE 0 1 DEG C RISE -13.6 -50 0 0 0 1 DEG C RISE 0 0 3 DEG C RISE INCOMPLETE -1 0 0 -4.9 4 DEG C RISE 0 0 2 DEG C RISE 0 0 0 0 0 0
D0 072396
C O N F ID E N T !A
Dow Confidential
14
OCLANSORB OCLANSORB OCLANSORB
95% PHENOL IN WATER 95% PHENOL IN WATER 98% SULFURIC ACID
TX B-6201 TX B-6201 TX OC-301
RCT-91-1235 RCT-91-1235 RCT-91-1200
DSC MCC DSC
NONE TO 200 C NONE AT 25 C EXO AT 56 C
OCLANSORB OCLANSORB
98% SULFURIC ACID ACETONE
TX OC-301 TX B-6201
RCT-91-1200 RCT-91-1237
MCC DSC
EXOAT 25 C NONE TO 200 C
OCLANSORB
ACETONE
TX B-6201
RCT-91-1237
MCC
NONE AT 25 C
OCLANSORB OCLANSORB
ALLYL CHLORIDE ALLYL CHLORIDE
TX B-7503 TX B-7503
RCT-92-0389 RCT-92-0389
DSC MCC
EXO ATI 28 C NONE AT 25 C
OCLANSORB
ALLYL CHLORIDE TARS (T-314 BOTTOMS)
TX B-7503
RCT-92-0454
DSC
EXO AT 141 C
OCLANSORB
ALLYL CHLORIDE TARS (T-314 BOTTOMS)
TX B-7503
RCT-92-0454
MCC
NONE AT 25 C
K SORB
ALLYL PROPYLENE DICHLORIDE
SOL/EDC
93096
HOM
NONE AT 25 C
K SORB
ALLYL PROPYLENE DICHLORIDE
SOL/E DC
93096
DSC
EXO ATI 50 C
ABSORBENT BOOM
AMOKON 32 OIL
TX A-1230
RCT-91-0252
DSC
NONE TO 200 C
ABSORBENT BOOM
AMOKON 32 OIL
TX A-1230
RCT-91-0252
MCC
NONE AT 25 C
ABSORBENT PAD
AMOKON 32 OIL
TX A-1230
RCT-91-0251
DSC
NONE TO 200 C
ABSORBENT PAD
AMOKON 32 OIL
TX A-1230
RCT-91-0251
MCC
NONE AT 25 C
SORBENT ABSORBENT PAD
B-RECYCLE (40% TETRACHLOROETHANE, ETC) TX B-1510
RCT-93-0071
DSC
NONE TO 200 C
SORBENT ABSORBENT PAD
B-RECYCLE (40% TETRACHLOROETHANE, ETC) TX B-1510
RCT-93-0071
MCC
NONE AT 25 C
K SORB
BENZENE, TOLUENE,XYLENE
LHC 3
93013
HOM
NONE AT 25 C
K SORB
BENZENE, TOLUENE, XYLENE
LHC 3
93013
DSC
NONE TO 200 C
PEAT MOSS
BENZENE, TOLUENE, XYLENE
LHC 3
93013
HOM
NONE AT 25 C
PEAT MOSS
BENZENE, TOLUENE, XYLENE
LHC 3
93013
DSC
NONE TO 200 C
OCLANSORB
BENZYL TRIMETHYL AMMONIUM CHLORIDE
TX B-6201
RCT-91-1234
DSC
EXOAT 150 C
OCLANSORB
BENZYL TRIMETHYL AMMONIUM CHLORIDE
TX B-6201
RCT-91-1234
MCC
NONE AT 25 C
OCLANSORB
BETZOPTIMEEN
TX OC-301
RCT-91-1199
DSC
EXO AT 67 C
OCLANSORB
BETZOPTIMEEN
TX OC-301
RCT-91-1199
MCC
SL EXO AT 25 C
SORBENT ABSORBENT PAD
CRUDE PERCHLOROETHYLENE
TX B-1510
RCT-93-0069
DSC
NONE TO 200 C
SORBENT ABSORBENT PAD
CRUDE PERCHLOROETHYLENE
TX B-1510
RCT-93-0069
MCC
NONE AT 25 C
OCLANSORB
CUMENE
TX OC-301
RCT-91-1208
DSC
NONE TO 200 C
OCLANSORB
CUMENE
TX OC-301
RCT-91-1208
MCC
NONE AT 25 C
SORBATHENE
DICHLORO TETRAFLUOROETHANE (R-114)
C4-1 STADE RCR-92-1091
DSC
EXO AT 249 C
OIL ABSORBENT (CALCINED)
DIESEL
PLS 92096
MCC
SL EXO AT 25 C
OIL ABSORBENT (CALCINED)
DIESEL
PLS 92096
DSC
NONE TO 200 C
K SORB
DIETHANOLAMINE
LHC 3
93013
DSC
NONE TO 200 C
K SORB
DIETHANOLAMINE
LHC 3
93013
HOM
SL EXO AT 25 C
PEAT MOSS
DIETHANOLAMINE
LHC 3
93013
HOM
SL EXO AT 25 C
PEAT MOSS
DIETHANOLAMINE
LHC 3
93013
DSC
NONE TO 200 C
ABSORBENT BOOM
DOW CORNING 561 SILICONE OIL
TX A-1230
RCT-91-0256
DSC
NONE TO 200 C
ABSORBENT BOOM
DOW CORNING 561 SILICONE OIL
TX A-1230
RCT-91-0256
MCC
NONE AT 25 C
ABSORBENT PAD
DOW CORNING 561 SILICONE OIL
TX A-1230
RCT-91-0255
DSC
NONE TO 200 C
ABSORBENT PAD o OIL ABSORBENT PAD
DOW CORNING 561 SILICONE OIL DOWTHERM A
TX A-1230 TX B-3B31
RCT-91-0255 RCT-86-0306
MCC DTA
SL EXO AT 25 C NONE TO 325 C
SORBENT ABSORBENT PAD
DOWTHERM G
TX B-1510
RCT-93-0077
DSC
NONE TO 200 C
SORBENT ABSORBENT PAD
DOWTHERM G
TX B-1510
RCT-93-0077
MCC
NONE AT 25 C
0 0 -6.9 -13 0 0 -6.2 0 -11 0 0 INCOMPLETE 0 0 0 0 0 0 0 0 0 0 INCOMPLETE 0 -27 -3.8 0 0 0 0 -8.6 -0.8 0 0 1 DEG C RISE 1 DEG C RISE 0 0 0 0 -0.7 0 0 0
DO 0 7 2 3 9 7
3> Dow Confidential
OIL ABSORBENT PAD FLOOR DRY SORBENT FLOOR DRY SORBENT FUMEAWAY CRYSTALS FUMEAWAY CRYSTALS OCLANS0RB OCLANSORB OCLANSORB OCLANSORB SORBATHENE SORBATHENE ON PU-FOAM SORBATHENE SORBITOL SORBITOL SORBATHENE SORBATHENE SORBATHENE SORBATHENE FLOOR DRY ABSORBENT FLOOR DRY ABSORBENT FLOOR DRY SORBENT FLOOR DRY SORBENT HI DRY HI DRY K SORB K SORB OIL SORBANT (3M) OIL SORBANT (3M) SPAGH SORB SPAGH SORB OCLANSORB OCLANSORB SORBATHENE OIL ABSORBENT (CALCINED) PEAT MOSS SORBATHENE SORBATHENE ON PU-FOAM SPILL-KLEAN CALCINED OIL ABSORBENT FLY ASH SPAGH SORB O SPAGH SORB SORBATHENE HI DRY
DOWTHERM J EPICHLOROHYDRIN EPICHLOROHYDRIN EPICHLOROHYDRIN EPICHLOROHYDRIN EPICHLOROHYDRIN EPICHLOROHYDRIN EPICHLOROHYDRIN + WATER EPICHLOROHYDRIN + WATER EtCI + 1.1-D1CHLORO-2-FLUOROETHANE ETHYLACETATE ETHYLCHLORIDE (EtCI) ETHYLENE CARBOANTE/K CARBONATE ETHYLENE CARBONATE FLUORODICHLOROETHANE (R-141B) FREON R-11 FREON R-11 FREON R-12 METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOWMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE METHYL DIETHANOWMINE METHYL DIETHANOWMINE METHYL DIETHANOLAMINE METHYL DIETHANOWMINE METHYL DIETHANOWMINE METHYL DIETHANOWMINE METHYL ISOBUTYL KETONE METHYL ISOBUTYL KETONE METHYLAL + TRIMETHYLAMINE METHYLDIETHANOWMINE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE METHYLENE CHLORIDE + CHLOROFORM METHYLENE CHLORIDE + CHLOROFORM MIXED WB WASTE MIXED WB WASTE N-BUTANE NATURAL GASOLINE
15
TX B-3831 GLYCERIN 2 GLYCERIN 2 TX B-7503 TX B-7503 TX B-6201 TX B-6201 TX B-7503 TX B-7503 C4-1 STADE C4-1 STADE C4-1 STADE TX B-1470 TX B-1470 C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE LGTI LGn LGTI LGTI PROMIX PROMIX PROMIX PROMIX LGTI LGTI LGTI LGTI TX B-6201 TX B-6201 STADE RAD PROMIX METHANES C4-1 STADE C4-1 STADE METHANES METHANES METHANES LGTI LGTI C4-3 STADE PROMIX
RCT-86-0304 RCT-85-0311 RCT-85-0311 RCT-92-0614 RCT-92-0614
RCT-91-1233 RCT-91-1233 RCT-92-0342 RCT-92-0342 RCR-91-3232 RCR-91-3304 RCR-91-3231 RCT-93-0559 RCT-93-0558 RCR-91-6406 RCR-92-1623 RCR-92-1623 RCR-92-0921 92003 92003 RCL-92-0034 RCL-92-0Q34 93057 93057 93057 93057 92003 92003 RCL-92-0035 RCL-92-0035 RCT-91-1236 RCT-91-1236 RCR-90-0126 91103 92105 RCR-91-3091 RCR-91-6438 92105 91301 91301 92003 92003 RCR-91-3056 93057
'
DTA DTA MCC DSC MCC DSC MCC DSC MCC DSC DSC DSC DSC DSC ARC DSC MCC DSC MCC DSC DSC MCC DSC HOM HOM DSC MCC DSC MCC DSC DSC MCC DSC MCC HOM DSC ARC HOM DSC DSC MCC DSC DSC HOM
NONE TO 325 C EXOAT 235 C SL EXOAT 25 C EXOAT 143 C SL EXOAT 25 C NONE TO 200 C NONE AT 25 C EXOAT 146 C NONE AT 25 C EXOAT 224 C EXOAT 183 C EXO AT 232 C EXOAT 191 C EXOAT 131 C SL EXO AT 157 C SL EXO AT 220 C EXO AT 25 C EXO AT-112 C SL EXO AT 25 C NONE TO 200 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE TO 200 C NONE AT 25 C EXO AT 48 C NONE AT 25 C NONE AT 25 C NONE TO 350 C NONE TO 250 C ENDO AT 25 C NONE TO 200 C NONE TO 200 C SL EXO AT 25 C NONE TO 167 C EXO AT 231 C NONE AT 25 C
0 INCOMPLETE
-0.3 -147 -0.5
0 0 >-323 0 -6.7 -4.3 -41 INCOMPLETE -6.9 INCOMPLETE -1.2 -6.7 -8.8 -1.B 0 0 -1.8 0 0 0 0 -1.1 0 -2 0 0 0 -6.9 0 0 0 0 2 DEG C DROP 0 0 -2 0 -29 0
DO 0 7 2 3 9 8
Dow Confidential
DO 0 7 2 3 9 9
C O N F ID E N T I
HI DRY K SORB K SORB OCLANSORB OC LANSORB ABSORBENT BOOM ABSORBENT BOOM ABSORBENT PAD ABSORBENT PAD SAND SAND SORBATHENE XUS-43493 OCLANSORB SAND CV DIATOMACEOUS EARTH SORBATHENE XFS-4022 SORBATHENE XUS-40323.00 SORBATHENE XUS-43493.00 OIL SORBENT BOOM TYPE 270 OIL SORBENT BOOM TYPE 270 OIL SORBENT PAD TYPE 156 OIL SORBENT PAD TYPE 156 ABSORBENT BOOM SORBATHENE SORBATHENE SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD OIL ABSORBENT PAD OYLGONE (BAG) OYLGONE (BAG) OYLGONE (PEAT) OYLGONE (PEAT) OYLGONE (BAG) OYLGONE (BAG) OYLGONE (PEAT) OYLGONE (PEAT) OYLGONE (PEAT) OCLANSORB OCLANSORB ABSORBENT BOOM ABSORBENT BOOM ABSORBENT PAD ABSORBENT PAD ABSORBENT BOOM
NATURAL GASOLINE NATURAL GASOLINE NATURAL GASOLINE NUT046 LUBE OIL NUTO 46 LUBE OIL NUTO H-46 (EXXON) NUTO H-46 (EXXON) NUTO H-46 (EXXON) NUTO H-46 (EXXON) PDC + DEGREASER SOLVENT PDC + DEGREASER SOLVENT PERCHLOROETHYLENE PHENOL PROPYLENE DICHLORIDE (PDC) PROPYLENE OXIDE PROPYLENE OXIDE PROPYLENE OXIDE PROPYLENE OXIDE REGAL 32 LUBE OIL + 25% NaOH REGAL 32 LUBE OIL + 25% NaOH REGAL 32 LUBE OIL + 25% NaOH REGAL 32 LUBE OIL + 25% NaOH STYRENE STYRENE STYRENE SUN OIL 21 SUN OIL 21 SYLTHERM 800 SYNESSTIC 100 SYNESSTIC 100 SYNESSTIC 100 SYNESSTIC 100 TERESSTIC 32 TERESSTIC 32 TERESSTIC 32 TERESSTIC 32 TERESSTIC 32 TERESSTIC 33 LUBE OIL TERESSTIC 33 LUBE OIL TERESSTIC 33 OIL (EXXON) TERESSTIC 33 OIL (EXXON) TERESSTIC 33 OIL (EXXON) TERESSTIC 33 OIL (EXXON) TERESSTIC 68 (EXXON)
1>
16
PROMIX PROMIX PROMIX TX OC-301 TX OC-301 TX A-1230 TX A-1230 TX A-1230 TX A-1230 GLYCOL 1 GLYCOL 1 SOLVENTS TX OC-301 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 CAUSTIC CAUSTIC CAUSTIC CAUSTIC TX B-7101 C4-1 STADE C4-3 STADE TX B-1510 TX B-1510 TX B-3831 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-240S TX B-2405 TX OC-301 TX OC-301 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230
93057 93057 93057 RCT-91-1201 RCT-91-1201 RCT-91 -0248 RCT-91-0240 RCT-91-0247 RCT-91-0247 91304 91304 RCM-92-0456 RCT-91-1209 91304 92150 92120 92120 92120 92035 92035 92035 92035 RCT-87-0890 RCR-91-640B RCR-91-3055 RCT-93-0075 RCT-93-0075 RCT-86-0305 RCT-92-0074 RCT-92-0074 RCT-92-0075 RCT-92-0075 RCT-92-0076 RCT-92-0076 RCT-92-0077 RCT-92-0077 RCT-92-0142 RCT-91-1205 RCT-91-1205 RCT-91-0241 RCT-91-0241 RCT-91-0240 RCT-91-0240 RCT-91-0245
DSC HOM DSC DSC MCC DSC MCC DSC MCC DSC ARC ARC DSC DSC DSC DSC DSC DSC MCC DSC MCC DSC ARC ARC DSC DSC MCC DTA DSC MCC DSC MCC DSC MCC DSC MCC ARC DSC MCC DSC MCC DSC MCC DSC
NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE TO 200 C NONE AT 25 C NONE TO 200 C SL EXOAT 25 C NONE TO 200 C SL EXOAT 25 C EXO AT 200 C NONE TO 200 C NONE TO 300 C NONE AT 25 C EXO AT 200 C EXO AT 146 C NONE TO 200 C NONE TO 200 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C EXO AT 96 C EXO AT 99 C EXO AT 206 C NONE TO 200 C NONE AT 25 C NONE TO 325 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 221 C NONE TO 200 C NONE AT 25 C SL EXO AT 65 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C
0 0 0 0 0 0 -0.7 0 -0.7 INCOMPLETE 0 0 0 INCOMPLETE INCOMPLETE 0 0 0 0 0 0 0 -72 -177 -100 0 0 0 0 -1 0 -0.5 0 -1 0 0 -157 0 0 -0.5 -0.7 0 -0.5 0
Dow Confidential
I
ABSORBENT BOOM
TERESSTIC 68 (EXXON)
ABSORBENT PAD
TERESSTIC 68 (EXXON)
ABSORBENT PAD
TERESSTIC 68 (EXXON)
OIL ABSORBENT PAD
TOLUENE DIISOCYANATE
OIL ABSORBENT PAD
TOLUENE DIISOCYANATE
SORBENT ABSORBENT PAD
TRICHLOROETHYLENE
SORBENTABSORBENT PAD
TRICHLOROETHYLENE
SORBATHENE
TRIFLUORODICHLOROETHANE (R-123)
ABSORBENT BOOM
UNIVIS J 13 (EXXON)
ABSORBENT BOOM
UNIV1S J 13 (EXXON)
ABSORBENT PAD
UNIVIS J 13 (EXXON)
ABSORBENT PAD
UNIVIS J 13 (EXXON)
ABSORBENT BOOM
UNIVOLT N 61 MINERAL OIL (EXXON)
ABSORBENT BOOM
UNIVOLT N 61 MINERAL OIL (EXXON)
ABSORBENT PAD
UNIVOLT N 61 MINERAL OIL (EXXON)
ABSORBENT PAD
UNIVOLT N 61 MINERAL OIL (EXXON)
OCLAN SORB
VARSOL
OCLANSORB
VARSOL
OIL ABSORBENT PAD
VORANATE 3071
OIL ABSORBENT PM)
VORANATE 3072
OIL ABSORBENT PAD
VORANATE TCPA ISOCYANATE
OIL ABSORBENT PAD
VORANATE TCPA ISOCYANATE
SPILLKLEEN
WATER (CONDENSATE)
SPILLKLEEN
WATER (CONDENSATE)
SPILLKLEEN
WATER (COOLING TOWER)
SPILLKLEEN
WATER (COOLING TOWER)
SPILLKLEEN
WATER (POTABLE)
SPILLKLEEN
WATER (POTABLE)
SPILLKLEEN
WATER (RIVER)
SPILLKLEEN
WATER (RIVER)
SORBENT ABSORBENT PAD
ZERICE 68 COMPRESSOR OIL
SORBENT ABSORBENT PAD
ZERICE 68 COMPRESSOR OIL
OCLANSORB
ZERICE 68 LUBE OIL
OCLANSORB
ZERICE 68 LUBE OIL
SORBATHENE XU-43522.00 GASOLINE VAPOR RECOVERY
O
oz oo
R mO O Nl mm
Z f*
-H O h O
17
TX A-1230 TX A-1230 TX A-1230 TX B-451 TX B-451 TX B-1510 TX B-1510 C4-1 STADE TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX A-1230 TX OC-301 TX OC-301 TX B-451 TX B-451 TX B-451 TX B-451 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-1510 TX B-1510 TX OC-301 TX OC-301 LARKIN LAB
RCT-91-0245 RCT-91-0244 RCT-91-0244 RCT-91-0819 RCT-91-0819 RCT-93-0067 RCT-93-0067 RCR-91-6405 RCT-91-0237 RCT-91-0237 RCT-91-0236 RCT-91-0236 RCT-91-0260 RCT-91-0260 RCT-91-0259 RCT-91-0259 RCT-91-1202 RCT-91-1202 RCT-91-0B1B RCT-91-0818 RCT-91-0B17 RCT-91-0B17 RCT-92-0081 RCT-92-0081 RCT-92-0079 RCT-92-0079 RCT-92-0078 RCT-92-007B RCT-92-0080 RCT-92-0080 RCT-93-0073 RCT-93-0073 RCT-91-1203 RCT-91-1203 RCM-92-0207
MCC DSC MCC DSC MCC . DSC MCC ARC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC ARC
SL EXOAT 25 C NONE TO 200 C NONE AT 25 C NONE TO 300 C NONE AT 25 C NONE TO 200 C NONE AT 25 C SL EXO AT 162 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C SL EXOAT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 300 C NONE AT 25 C NONE TO 300 C NONE AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 300 C
-0.5 0 0 0 0 0 0
INCOMPL 0
-0.5 0 0 0
-0.5 0
-0.5 0 0 0 0 0 0 0
-5.5 0 -5 0
-6.9 0
-B.6 0 0 0 0 0
Dow Confidential
18 TABLE III
REACTIVITY OF ABSORBENT WITH PROCESS CHEMICAL (SORTEO BY PLANT)
ABSORBENT
PROCESS CHEMICAL
SORBATHENE
1,1 -DICHLORO-1 -FLUOROETHANE (R-141B)
SORBATHENE
1,1 -DICHLORO-2,2,2-TRiFLUOROETHANE
SORBATHENE
DICHLORO TETRAFLUOROETHANE (R-114)
SORBATHENE
E1CI + 1,1-DICHLORO-2-FLUOROETHANE
SORBATHENE
ETHYLCHLORIDE (EtCI)
SORBATHENE
FLUORODICHLOROETHANE (R-141B)
SORBATHENE
FREON R-11
SORBATHENE
FREON R-11
SORBATHENE
FREON R-12
SORBATHENE
METHYLENE CHLORIDE
SORBATHENE
STYRENE
SORBATHENE
TRIFLUORODICHLOROETHANE (R-123)
SORBATHENE ON PU-FOAM
ETHYLACETATE
SORBATHENE ON PU-FOAM
METHYLENE CHLORIDE
SORBATHENE
N-BUTANE
SORBATHENE
STYRENE
OIL SORBENT BOOM TYPE 270 REGAL 32 LUBE OIL + 25% NaOH
OIL SORBENT BOOM TYPE 270 REGAL 32 LUBE OIL + 25% NaOH
OIL SORBENT PAD TYPE 156
REGAL 32 LUBE OIL + 25% NaOH
OIL SORBENT PAD TYPE 156
REGAL 32 LUBE OIL + 25% NaOH
FLOOR DRY SORBENT
EPICHLOROHYDRIN
FLOOR DRY SORBENT
EPICHLOROHYDRIN
CV DIATOMACEOUS EARTH
PROPYLENE OXIDE
SAND
PDC + DEGREASER SOLVENT
SAND
PDC + DEGREASER SOLVENT
SAND
PROPYLENE OICHLORIDE (PDC)
SORBATHENE XFS-4022
PROPYLENE OXIDE
SORBATHENE XUS-40323.00
PROPYLENE OXIDE
SORBATHENE XUS-43493.00
PROPYLENE OXIDE
OIL-SORB
74% METHANOL, 15% EO, 4% EG
OIL-SORB
74% METHANOL, 15% EO, 4% EG
SORBATHENE XU-43522.00 GASOLINE VAPOR RECOVERY
FLOOR DRY ABSORBENT
METHYL DIETHANOLAMINE
FLOOR DRY ABSORBENT
METHYL DIETHANOLAMINE
FLOOR DRY SORBENT
21% PHOSPHORIC ACID
FLOOR DRY SORBENT
28% HYDROCHLORIC ACID
FLOOR DRY SORBENT
5% HYDROCHLORIC ACID
PLANT
BEL.
C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-1 STADE C4-3 STADE C4-3 STADE CAUSTIC CAUSTIC CAUSTIC CAUSTIC GLYCERIN 2 GLYCERIN 2 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYCOL 1 GLYOOL1 GLYCOL 1 GLYCOL 2 GLYCOL2 LARKIN LAB LGTt LGTI LGTI LGTI LGTI
RCR-91-3028 RCR-91-3029 RCR-92-1091 RCR-91-3232 RCR-91-3231 RCR-91-6406 RCR-92-1623 RCR-92-1623 RCR-92-0921 RCR-91-3091 RCR-91-6408 RCR-91-6405 RCR-91-3304 RCR-91-6438 FtCR-91-3056 RCR-91-3055 92035 92035 92035 92035 RCT-B5-0311 RCT-85-0311 92150 91304 91304 91304 92120 92120 92120 91200 91200 RCM-92-0207
92003 92003 92173 92173 92173
TEST
REACTIVITY & ONSET TEMP (Cl
HEAT OF RXN fCAUQ)
DSC DSC DSC DSC DSC ARC DSC MCC DSC DSC ARC ARC DSC ARC DSC DSC MCC DSC MCC DSC DTA MCC DSC DSC ARC DSC DSC DSC DSC DSC HOM ARC MCC DSC MCC HOM HOM
EXOAT 197 C EXOAT 194 C EXO AT 249 C EXOAT 224 C EXO AT 232 C SL EXO ATI 57 C SL EXO AT 220 C EXO AT 25 C EXO AT-112 C NONE TO 350 C EXO AT 99 C SL EXO AT 162 C EXOAT 183 C NONE TO 250 C EXO AT 231 C EXO AT 206 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C EXO AT 235 C SL EXO AT 25 C EXO AT 146 C EXO AT 200 C NONE TO 200 C EXO AT 200 C NONE TO 200 C NONE TO 200 C NONE TO 200 C NONE TO 200 C SL EXO AT 25 C NONE TO 300 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C SL EXO AT 25 C SL EXO AT 25 C
-1.2 -2.4 -8.6 -6.7 -41 INCOMPLETE -1.2 -6.7 -8.8 0 -177 INCOMPLETE -4.3 0 -29 -100 0 0 0 0 INCOMPLETE -0.3 INCOMPLETE INCOMPLETE 0 INCOMPLETE 0 0 0 0 2 DEG C RISE 0 -1.8 0 0 1 DEG C RISE 1 DEG C RISE
DO 0 7 2 4 0 1 C O N F ID E N T IA L
Dow Confidential
CONF
FLOOR DRY SORBENT FLOOR DRY SORBENT FLOOR DRY SORBENT OIL ABSORBENT PAD (3M) OIL ABSORBENT PAD (3M) OIL ABSORBENT PAD (3M) OIL ABSORBENT PAD (3M) OIL SORBANT (3M) OIL SORBANT (3M) SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB SPAGH SORB K SORB K SORB K SORB K SORB PEAT MOSS PEAT MOSS PEAT MOSS PEAT MOSS CALCINED OIL ABSORBENT FLY ASH FLY ASH OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) PEAT MOSS SPILL-KLEAN OIL ABSORBENT (CALCINED) OIL ABSORBENT (CALCINED) HI DRY HI DRY HI DRY HI DRY O K SORB
ksorb
O K SORB 5 M KSORB
HO
50% SODIUM HYDROXIDE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE 21% PHOSPHORIC ACID 28% HYDROCHLORIC ACID 5% HYDROCHLORIC ACID 50% SODIUM HYDROXIDE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE 21% PHOSPHORIC ACID 28% HYDROCHLORIC ACID 5% HYDROCHLORIC ACID 50% SODIUM HYDROXIDE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE MIXED LAB WASTE MIXED LAB WASTE BENZENE. TOLUENE, XYLENE BENZENE, TOLUENE, XYLENE DIETHANOLAMINE DIETHANOLAMINE BENZENE, TOLUENE, XYLENE BENZENE, TOLUENE, XYLENE DIETHANOLAMINE DIETHANOLAMINE METHYLENE CHLORIDE + CHLOROFORM 21% SULFURIC ACID IN WATER METHYLENE CHLORIDE + CHLOROFORM 30-40% SULFURIC ACID 60-80% SULFURIC ACID 60-80% SULFURIC ACID 60-80% SULFURIC ACID METHYLENE CHLORIDE METHYLENE CHLORIDE DIESEL DIESEL METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE NATURAL GASOLINE NATURAL GASOLINE METHYL DIETHANOLAMINE METHYL DIETHANOLAMINE NATURAL GASOLINE NATURAL GASOLINE
19
LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LGTI LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 LHC 3 METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES METHANES PLS PLS PROMIX PROMIX PROMIX PROMIX PROMIX PROMIX PROMIX PROMIX
92173 RCL-92-0034 RCL-92-0034 92173 92173 92173 92173 92003 92003 92173 92173 92173 92173 RCL-92-0035 R CL-92-0035 92003 92003 93013 93013 93013 93013 93013 93013 93013 93013 91301 92002 91301 92033 92033 92033 92033 92105 92105 92096 92096 93057 93057 93057 93057 93057 93057 93057 93057
HOM DSC MCC MCC HOM MCC MCC MCC . DSC MCC MCC . MCC MCC MCC DSC MCC DSC HOM DSC DSC HOM HOM DSC HOM DSC DSC MCC DSC HOM MCC HOM DSC HOM HOM MCC DSC DSC HOM HOM DSC HOM DSC HOM DSC
SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE AT 25 C SL EXO AT 25 C NONE AT 25 C NONE AT 25 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE AT 25 C NONE AT 25 C NONE AT 25 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 167 C NONE AT 25 C NONE TO 200 C NONE TO 200 C SL EXOAT 25 C NONE AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE TO 200 C EXO AT 25 C NONE TO 200 C SL EXO AT 25 C SL EXO AT 25 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C ENDOAT25C SL EXO AT 25 C NONE TO 200 C NONE TO 200 C NONE AT 25 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C
3 DEG C RISE 0
-1.8 0
1 DEG C RISE 0 0
-1.1 0 0 0 0 0 -2 0 -2 0 0 0 0
1 DEG C RISE 0 0
1 DEG C RISE 0 0 -95 0
1 DEG C RISE -4.9
4 DEG C RISE 0 0
2 DEG C DROP -0.8 0 0 0 0 0 0 0 0 0
Dow Confidential
OIL ABSORBENT (CALCINED) K SORB K SORB SORBATHENE SORBATHENE XUS-43493 SORBATHENE ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT BOOM ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD ABSORBENT PAD SORBITOL SORBITOL SORBITOL SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD
20
METHYLDIETHANOLAMINE
PROMIX
ALLYL PROPYLENE DICHLORIDE
SOL/E DC
ALLYL PROPYLENE DICHLORIDE
SOL/E DC
1,1,1 -TRICHLOROETHANE
SOLVENTS
P ERCHLOROETHYL ENE
SOLVENTS
METHYLAL + TRIMETHYLAMINE
STADE R&D
AMOKON 32 OIL
TX A-1230
AMOKON 32 OIL
TX A-1230
DOW CORNING 561 SILICONE OIL
TX A-1230
DOW CORNING 561 SILICONE OIL
TX A-1230
NUTO H-46 (EXXON)
TX A-1230
NUTO H-46 (EXXON)
TX A-1230
TERESSTIC 33 OIL (EXXON)
TX A-1230
TERESSTIC 33 OIL (EXXON)
TX A-1230
TERESSTIC 68 (EXXON)
TX A-1230
TERESSTIC 68 (EXXON)
TX A-1230
UNIVISJ 13 (EXXON)
TX A-1230
UNIVISJ 13 (EXXON)
TX A-1230
UNIVOLT N 61 MINERAL OIL (EXXON)
TX A-1230
UNIVOLT N 61 MINERAL OIL (EXXON)
TX A-1230
AMOKON 32 OIL
TX A-1230
AMOKON 32 OIL
TX A-1230
DOW CORNING 561 SILICONE OIL
TX A-1230
DOW CORNING 561 SILICONE OIL
TX A-1230
NUTO H-46 (EXXON)
TX A-1230
NUTO H-46 (EXXON)
TX A-1230
TERESSTIC 33 OIL (EXXON)
TX A-1230
TERESSTIC 33 OIL (EXXON)
TX A-1230
TERESSTIC 68 (EXXON)
TX A-1230
TERESSTIC 68 (EXXON)
TX A-1230
UNIVIS J 13 (EXXON)
TX A-1230
UNIVIS J 13 (EXXON)
TX A-1230
UNIVOLT N 61 MINERAL OIL (EXXON)
TX A-1230
UNIVOLT N 61 MINERAL OIL (EXXON)
TX A-1230
ETHYLENE CARBOANTE/K CARBONATE
TX B-1470
ETHYLENE CARBONATE
TX B-1470
3070% HEXA& ME HEXAHYDROPHTHALIC ANHYDRTX B-1470C
85% BUTYLENE OXIDE, 8.5% ETHYL ACETATE
TX B-1510
85% BUTYLENE OXIDE, 0.5% ETHYL ACETATE
TX B-1510
90% 1,2-DICHLOROETHYLENE, 10% CL'D C2'S
TX B-1510
90% 1,2-DICHLOROETHYLENE, 10% CL'D C2,S
TX B-1510
B-RECYCLE (40% TETRACHLOROETHANE, ETC) TX B-1510
B-RECYCLE (40% TETRACHLOROETHANE. ETC) TX B-1510
CRUDE PERCHLOROETHYLENE
TX B-1510
91103 93096 93096 RCM-91-0221 RCM-92-0456 RCR-90-0126 RCT-91-0252 RCT-91-0252 RCT-91-0256 RCT-91-0256 RCT-91-0248 RCT-91-0248 RCT-91-0241 RCT-91-0241 RCT-91-0245 RCT-91-0245 RCT-91-0237 RCT-91-0237 RCT-91-0260 RCT-91-0260 RCT-91-0251 RCT-91-0251 RCT-91-0255 RCT-91-0255 RCT-91-0247 RCT-91-0247 RCT-91-0240 RCT-91 -0240 RCT-91 -0244 RCT-91-0244 RCT-91-0236 RCT-91-0236 RCT-91-0259 RCT-91-0259 RCT-93-0559 RCT-93-0558 RCT-93-0040 RCT-93-0063 RCT-93-0063 RCT-93-0065 RCT-93-0065 RCT-93-0071 RCT-93-0071 RCT-93-0069
MCC HOM DSC ARC ARC DSC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC DSC DSC DSC MCC DSC MCC DSC MCC DSC
NONE AT 25 C NONE AT 25 C EXOAT 150 C NONE TO 250 C NONE TO 300 C EXOAT 48 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C SL EXOAT 25 C SL EXO AT 65 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C SL EXO AT 25 C EXOAT 191 C EXOAT 131 C EXOAT 151 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONEAT25C NONE TO 200 C NONE AT 25 C NONE TO 200 C
0 0 INCOMPLETE 0 0 -6.9 0 0 0 0 0 -0.7 -0.5 -0.7 0 -0.5 0 -0.5 0 -0.5 0 0 0 -0.7 0 -0.7 0 -0.5 0 0 0 0 0 -0.5 INCOMPLETE -6.9 -13.6 0 0 0 0 0 0 0
DO 0 7 2 4 0 3 C O N F ID E N T IA L
Do* Confidential
SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD SORBENT ABSORBENT PAD OYLGONE (BAG) OYLGONE (BAG) OYLGONE (BAG) OYLGONE (BAG) OYLGONE (PEAT) OYLGONE (PEAT) OYLGONE (PEAT) OYLGONE (PEAT) OYLGONE (PEAT) SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN SPILLKLEEN OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OIL ABSORBENT PAD OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB
CRUDE PERCHLOROETHYLENE DOWTHERM G DOWTHERM G SUN OIL 21 SUN OIL 21 TRICHLOROETHYLENE TRICHLOROETHYLENE 2ERICE 68 COMPRESSOR OIL ZERICE 68 COMPRESSOR OIL SYNESSTIC 100 SYNESSTIC 100 TERESSTIC 32 TERESSTIC 32 SYNESSTIC 100 SYNESSTIC 100 TERESSTIC 32 TERESSTIC 32 TERESSTIC 32 WATER (CONDENSATE) WATER (CONDENSATE) WATER (COOLING TOWER) WATER (COOLING TOWER) WATER (POTABLE) WATER (POTABLE) WATER (RIVER) WATER (RIVER) DOWTHERM A DOWTHERM J SYLTHERM 800 TOLUENE DIISOCYANATE TOLUENE DIISOCYANATE VORANATE 3071 VORANATE 3072 VORANATE TCPA ISOCYANATE VORANATE TCPA ISOCYANATE . 25% SODIUM HYDROXIDE 25% SODIUM HYDROXIDE 95% PHENOL IN WATER 95% PHENOL IN WATER ACETONE ACETONE BENZYL TRIMETHYL AMMONIUM CHLORIDE BENZYL TRIMETHYL AMMONIUM CHLORIDE EPICHLOROHYDRIN
21
TX B-1510 TX B-1510 TX B-1510 TX B-1510 TX B-1510 TX B-1510 TX B-1510 TX B-1510 TX B-1510 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX B-2405 TX 8-3831 TX B-3831 TX B-3831 TX B-451 TX B-451 TX B-451 TX B-451 TX B-451 TX B-451 TX B-6201 TX B-6201 TX B-6201 TX B-6201 TX B-6201 TX B-6201 TX B-6201 TX B-6201 TX B-6201
RCT-93-0069 RCT-93-0077 RCT-93-0077 RCT-93-0075 RCT-93-0075 RCT-93-0067 RCT-93-0067 RCT-93-0073 RCT-93-0073 RCT-92-0074 RCT-92-0074 RCT-92-0076 RCT-92-0076 RCT-92-0075 RCT-92-0075 RCT-92-0077 RCT-92-0077 RCT-92-0142 RCT-92-0081 RCT-92-0081 RCT-92-0079 RCT-92-0079 RCT-92-0078 RCT-92-007B RCT-92-0080 RCT-92-0080 RCT-B6-0306 RCT-B6-0304 RCT-B6-0305 RCT-91-0819 RCT-91-0819 RCT-91-0818 RCT-91-0818 RCT-91-0817 RCT-91-0817 RCT-91-1232 RCT-91-1232 RCT-91-1235 RCT-91-1235 RCT-91-1237 RCT-91-1237 RCT-91-1234 RCT-91-1234 RCT-91-1233
MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC ARC DSC MCC DSC MCC DSC MCC DSC MCC DTA DTA DTA DSC MCC DSC MCC DSC . MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC
NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C SL EXO AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 221 C NONE TO 200 C EXO AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 200 C EXO AT 25 C NONE TO 325 C NONE TO 325 C NONE TO 325 C NONE TO 300 C NONE AT 25 C NONE TO 300 C NONE AT 25 C NONE TO 300 C NONE AT 25 C EXO AT 36 C .EXO AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C EXOAT 150 C NONE AT 25 C NONE TO 200 C
0 0 0 0 0 0 0 0 0 0 -1 0 -1 0 -0.5 0 0 -157 0 -5.5 0 -5 0 -6.9 0 -8.6 0 0 0 0 0 0 0 0 0 -101 -5.5 0 0 0 0 INCOMPLETE 0 0
DO 0 7 2 4 0 4
DONFrDFNTT
Dow Confidential
OCLANSORB OCLANSORB OCLANSORB ABSORBENT BOOM FUMEAWAY CRYSTALS FUMEAWAY CRYSTALS OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB OCLANSORB
EP1CHLOROHYDRIN METHYL ISOBUTYL KETONE METHYL ISOBUTYL KETONE STYRENE EPICHLOROHYDRIN EPICHLOROHYDRIN 43% 2,3-DICHLOROPROPENE,23% EPI.... 43% 2,3-DICHLOROPROPENE,23% EPI,... ALLYL CHLORIDE ALLYL CHLORIDE ALLYL CHLORIDE TARS (T-314 BOTTOMS) ALLYL CHLORIDE TARS (T-314 BOTTOMS) EPICHLOROHYDRIN + WATER EPICHLOROHYDRIN + WATER 45% PHENOL, 35% ACETONE, 20% CUMENE 45% PHENOL. 35% ACETONE, 20% CUMENE 50% SODIUM HYDROXIDE 50% SODIUM HYDROXIDE 80% CUMENE HYDROPEROXIDE,20% CUMEN 80% CUMENE HYDROPEROXIDE,20% CUMEN 98% SULFURIC ACID 98% SULFURIC ACID BETZOPTIMEEN BETZOPTIMEEN CUMENE CUMENE NUTO 46 LUBE OIL NUTO 46 LUBE OIL PHENOL TERESSTIC 33 LUBE CML TERESSTIC 33 LUBE OIL VARSOL VARSOL ZERICE 68 LUBE OIL ZERICE 68 LUBE OIL
22
TX B-6201 TX B-6201 TX B-6201 TX B-7101 TX B-7503 TX B-7503 TX B-7503 TX B-7503 TX B-7503 TX B-7503 TX B-7503 TX B-7503 TX B-7503 TX B-7503 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301 TX OC-301
RCT-91-1233 RCT-91-1236 RCT-91-1236 RCT-87-0890 RCT-92-0614 RCT-92-0614 RCT-92-0477 RCT-92-0477 RCT-92-0389 RCT-92-03B9 RCT-92-0454 RCT-92-0454 RCT-92-0342 RCT-92-0342 RCT-91-1206 RCT-91-1206 RCT-91-1204 RCT-91-1204 RCT-91-1207 RCT-91-1207 RCT-91-1200 RCT-91-1200 RCT-91-1199 RCT-91-1199 RCT-91-1208 RCT-91-1208 RCT-91-1201 RCT-91-1201 RCT-91-1209 RCT-91-1205 RCT-91-1205 RCT-91-1202 RCT-91-1202 RCT-91-1203 RCT-91-1203
MCC DSC MCC ARC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC MCC DSC DSC MCC DSC MCC DSC MCC
NONE AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 96 C EXOAT 143 C SL EXO AT 25 C EXO AT 154 C NONE AT 25 C EXO AT 128 C NONE AT 25 C EXOAT 141 C NONE AT 25 C EXO AT 146 C NONE AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 60 C EXO AT 25 C NONE TO 200 C NONE AT 25 C EXO AT 56 C EXO AT 25 C EXO AT 67 C SL EXO AT 25 C NONE TO 200 C NONE AT25C NONE TO 200 C NONE AT 25 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C NONE TO 200 C NONE AT 25 C
0 0 0 -72 -147 -0.5 -50 0 -6.2 0 -11 0 >-323 0 0 0 INCOMPLETE -1 0 0 -6.9 -13 -27 -3.8 0 0 0 0 0 0 0 0 0 0 0
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Dow Confidential