Document Qkxy9rLLpbvk5LKeRNLL6eqDR

DownloadSearchable PDFRandom document
00/18/90 10:12 0502 634 7730 PURCHASING @002 UnitedCatalysts Inc. Glrdler and CO Catalysts Catalysts DMsion P-O. Box 32370 Louis/ilto. KY 40232 USA Telephone: 502-634-7200 TeJexr 204190.204239 Fax 502-637-3732 material safety data shkkt G-72D CA 0 60 SECTION X PRODUCT XDBNTXFXCATXOH Trade Kama and Synonyms: G-72D Chemical Famllyx Heterogeneous Catalyst Formula: CaAliO*+ZnO SECTION XX HAZARDOUS INGREDIENTS Hazardous Components in the Solid Mixture COMPONENT CAS NO. % Calcium alinninate 12042-68-1 Zinc oxide 1314-13-2 5-10 90-95 OSH&/PEL 5.0 mg/m3 10.0 mg/m3 ACGIH/TLV 2.0 mg/m3 10.0 mg/m3 SECTION XXX PHYSICAL P*Tn Appearance and Odor: White extrusions. No odor. Melting Point: Greater than 2000C, greater than 3500F. Solubility in water: Insoluble. Bulk Density: 70 Ibs./cu. ft. Percent Volatile by Weight at 1000Ft Less than 5%. SECTION IV FIRE EXPLOSION DATA Fire and Explosion Hazard Negligible fire and explosion hazard when exposed to heat or flame by reaction with incompatible substances. Flash Point Nonflammable 0009439 S At 00 09/18/00 10:13 0302 03J 7730 PURCHASING 0003 ^ UnitedCatalysts Inc. CA0 60 \TArTrFrgTAT, SAFETY DATA SHEET G--720 Firefighting Hedia Dry chemical, water spray, or foam. For larger flares, use water spray fog or foam. Firefighting Nonflammable solids, liquids or gases: Cool containers that are exposed to flames with water from the side until well after fire is out. For massive fire in enclosed area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn- Withdraw immediately in case of rising sound from venting safety device or any discoloration of the tank due to fire. SECTION V HEALTH HAZARD DATA Health hazards may arise from inhalation, ingestion, and/or contact with the skin and/or eyes. Calcium aluminate may cause irritation of the eyes and skin, especially when wet- inhalation of zinc dust, mists, or fumes may irritate the respiratory tract, mucous membranes and skin. At higher levels of exposure rtzinc chills" or "zinc fume fever" may occur with symptoms of metallic or sweet taste, marked thirst, coughing, weakness, fatigue, muscular pain, nausea and vomiting, followed by fever, perspiration and chills, dyspnea, rales throughout the chest, and tachycardia. Onset of symptoms usually occur about 4-12 hours after exposure- Workers in zinc refining have been reported to suffer from a variety of nonspecific intestinal, respiratory, and nervous symptoms. Excessive contact may cause perforation of the nasal septum. Prolonged or repeated contact under poor hygienic conditions may produce a papular, pustular eczema or dermatitis called "oxide pox." Contact with the eye tissue may produce irritation and/or conjunctivitis. First Aid (Inhalation) Remove to fresh air immediately. If breathing has stopped, give artificial respiration. Keep affected person warm and at rest. Get medical attention immediately. First Aid (Ingestion) Do NOT induce vomiting- Immediately give large quantities of water. If vomiting does occur, give fluids again. Do not induce vomiting or give anything by mouth to an unconscious person. Call a physician or the nearest Poison Control Center immediately. TTrxi^ted: Aoril 20. 1990 SAL 000009440 O? (T6 "> 09/18/90 10:14 502 054 7730 PURCHASING 12 004 *jp linkedCatalystsInc. MATERIAL SAFETY DATA SHEET 0-720 CA060 First Aid (Eyes) Immediately flush the eyes with large quantities of running water for a minimum of 30 minutes- Hold the eyelids apart during the flushing to insure rinsing of the entire surface of the eye and lids with water. Do not attempt to neutralise with chemical agents. Oils or ointments should not be used. Obtain medical attention as soon as possible* First Aid (shin) Immediately flush affected areas with large quantities of water. Remove contaminated clothing while flushing the skin. Get prompt medical attention. SECTION VI REACTIVITY DATA Reactivity Is stable under normal temperatures and pressures in sealed containers. Hazardous polymerization will not occur. Calcium aluminate reacts with water to form alkaline slurry. Toxic fumes are emitted when heated to decomposition. SECTION VII SPILL OR LEAK PROCEDURES Notify safety personnel of spills or leaks, clean-up personnel need protection against inhalation of dusts or fumes. Eye protection is required- Vacuuming and/or wet methods of cleanup are preferred. Place in appropriate containers for disposal, keeping airborne particulates at a minimum. Disposal Consult applicable local, state, and federal regulations to select the method of disposal. Recover metal components by reprocessing whenever possible. SECTION VXII SPECIAL PROTECTION INFORMATION Respiratory Protection Provide a NIOSH/Msha jointly approved respirator in the absence of proper environmental control. Contact your safety equipment supplier for proper mask type. T---A -> . i don SAL Ooo Oo 9 T'l--. -- 09/1* 80 10:15 502 634 7730 purchasing <2)005 UnitedCatalysis Inc. C A 0 60 MATERIAL SAFETT DATA SHEET 0-720 ventilation Provide general and/or local exhaust ventilation to keep exposures below the TLV. ventilation used must be designed to prevent spots of dust accumulation or recycling of dusts. Protective Clothing Wear protective clothing, including long sleeves and gloves, to prevent repeated or prolonged skin contact. Bye Protection chemical splash goggles designed in compliance with OSHA regulations are recommended. Consult your safety equipment supplier. SECTION XX REGULATOR? INFORMATION This product contains substances which appear on lists of the indicated act or agency. XX American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values for Chemical Substances in the Work Environment ___ California Proposition 65 ___ Clean Air Act 40 CFR 61 XX Clean Water Act 40 CFR 116 XX Comprehensive Environmental Response, compensation, and Liability Act of 1980 (CERCLA) 40 CFR 302 ___ International Agency for Research on Cancer (XARC) Monographs on the Evaluation of carcinogenic Risks to Humans Volumes 1-42. ___ OTP Annual Report on Carcinogens XX Occupational Safety and Health Administration (OSHA) 29 CFR 1910 ___ Resource Conservation and Recovery Act (RCRA) 40 CFR 261 Subpart C XX Superfund Amendments and Reauthorization Act of 1986 (SARA) Title XII Section 313 40 CFR 372 XX Toxic Substances Control Act (TSCA) 40 CFR 700 SAL 000009442 09/1890 10:16 302 834 7730 PURCHASING [2)006 f UnitedCatalystsInc. CA 060 MATERIAL SAFETY DATA SHEET G-72D SECTION X BIBLIOGRAPHY clinical Toxicology of Commercial Products, Fifth. Edition, Gosselin, Smith, Hodge, Williams and Wilkins, Baltimore, 1984. Dangerous Properties of Industrial Materials, Sax, N. Irving, ed.. Van Nostrand Relnhold company. New York, 7th. Edition, 1989. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, International Agency for Research on Cancer, 1987. IARC Monoqraphs on the Evaluation of Carcinogenic Risks to Humans: Silica and Some Silicates, Volume 42, Lyon, World Health Organization, International Agency for Research on cancer, 1987. Kentucky Occupational Safety and Health Standards for General Industry, 29 CFR Part 910 as adopted by 803 KAR 2:020 with Amendments as of July 31, 1986, Promulgated by Occupational Safety and Health Administration, tJ.S. Department of Labor, Kentucky Occupational Safety and Health Program, Kentucky Labor Cabinet, Commerce Clearing House, Inc., Chicago 1986. Occupational Diseases, A Guide to their Recognition, U. S. Department of Health, Education, and Welfare, Public Health Service, Center for Disease Control, NIOSH, Revised Edition, 1977. June Patty's Industrial Hygiene and Toxicology, Clayton, G.D., Clayton, F.E., eds., John Wiley and Sons, New York, 3rd Edition, Volume 2, A-C, 1981. TLVs* Threshold Limit Values and Biological Exposure Indices for 1988-1989, American Conference of Governmental Industrial Hygienists, Cincinnati, OH, 1988. MSDS's from Suppliers of Raw Materials. 000009^43 SAL O9'18''00 10:17 0302 634 7730 PURCHASING * DriftedCatalysts Inc. CA060 MATERIAL SAFEri rfta G-72D SBCTXOH ZZ The information presented herein is believed to be accurate but is not warranted* Recipients are advised to confirm in advance that the information is current and applicable to meet their circumstances. Ho Information Available Doc* 91 SAL 000009444 flfr United Catalysts Inc. ^ Gifdler and CC1 Catalysts Post Office Bo* 32370 Louisville. Kentucky USA 40232 Telephone 502-634-7200 Telex 204190. 204239 Facsimile 502-637-3732 MATERIAL SAFETY DATA SHEET N-339 CA 0 61 * SECTION I PRODUCT IDENTIFICATION Trade Name and Synonyms: N-339 Chemical Family: inorganic Formula! AI2O3+C0O+M0OJ 8ECTION II HAZARDOUS INGREDIENTS Hazardous Components In the Solid Mixture COMPONENT CAS NO. % Aluminum oxide Cobalt oxide Molybdenum trioxide 1344-28-1 1304-96-6 1313-27-5 80-90 1-5 10-15 OSHA/PEL ACGIH/TLV 10.0 mg/m3 10.0 mg/m3 0.05 mg/m3 0.05 mg/ms 10.0 mg/m3 10.0 mg/m3 SECTION III PHYSICAL DATA Appearance and Odor: Blue extrusions. No odor. Melting Point: Greater than 800C, greater than 1450F. solubility In Waters Insoluble. Bulk Density: 32 lbs./cu. ft. Percent Volatile by Weight at 1000F: Less than 5%. SECTION IV FIRE EXPLOSION DATA Fire and Explosion Hazard Negligible fire and explosion hazard when exposed to heat or flame by reaction with incompatible substances. Updated: April 10, 1990 SAL 000009445 Page 1 CA061 MATERIAL SAFETY DATA SHEET N-339 Flash Point Nonf1ammab1e. Firefighting Media Dry chemical, water spray, or foam. For larger fires, use water spray fog or foam. Firefighting Nonflammable solids, liquids or gases: Cool containers that are exposed to flames with water from the side until well after fire is out. For massive fire in enclosed area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of the tank due to fire. SECTION V HEALTH HAZARD DATA Health hazards may arise from inhalation, ingestion, and/or contact with the skin and/or eyes. Alumina particles deposited in the eye may cause necrosis of the cornea. Ingestion may cause stomach and intestinal distress. Salts of alumina may cause dermatoses, eczema, conjunctivitis, and irritation of the mucous membranes of the upper respiratory tract. Prolonged inhalation of alumina dust may result in pneumoconiosis. Lung damage (Shaver's Disease) may result from inhalation of finely divided aluminum oxide particles? it is complicated by silica and oxides of iron in the inhaled air. Excessive inhalation of cobalt may cause irritation of the respiratory tract; asthma-like symptoms with cough, dyspnea, chest tightness and wheezing; lung damage; and pneumoconiosis. Ingestion may produce nausea and vomiting, diarrhea, and sensation of hotness. Chronic ingestion may cause blood abnormalities (polycythemia), increased clotting time, hyperplasia of the bone marrow and thyroid gland, cardiomyopathy, and damage to the pancreas in sensitive individuals, prolonged or repeated contact with the skin, in the absence of proper hygienic practices may result in dryness, irritation and/or an allergic dermatitis. Contact with the eye may cause redness, irritation, and/or conjunctivitis. Research data on cobalt and cobalt compounds based on animal injection studies indicates that cobalt may be a possible carcinogen. Updated: April 10, 1990 0000094*6 SAl* Page 2 gfe United Catalysts Inc *EP* Girdle* end CCI Catalysts MATERIAL SAFETY DATA SHEET H-339 C A 0 61 Molybdenum trioxide may cause irritation of the eyes and mucous membranes. Prolonged, excessive inhalation may affect the liver, kidneys, and red blood cells? cause hypothyroidism; and/or produce molybdenum-induced gout. Ingestion of excessive amounts may produce signs of copper deficiency. First Aid (Inhalation) Remove to fresh air immediately. If breathing has stopped, give artificial respiration. Keep affected person warm and at rest. Get medical attention immediately. First Aid (Ingestion) If large amounts have been ingested, give emetics to cause vomiting. Stomach siphon may be applied as well. Milk and fatty acids should be avoided. Get medical attention immediately. First Aid (Eyes) Wash eyes immediately and carefully for 30 minutes with running water, lifting upper and lower eyelids occasionally. Get prompt medical attention. First Aid (Skin) To avoid repeated or prolonged contact with this chemical, use good hygienic practices. Wash with soap and a large amount of water. Get medical attention if irritation or inflammation develops. SECTION VI REACTIVITY DATA Reactivity Is stable under normal temperatures and pressures in sealed containers. Hazardous polymerization will not occur. Molybdenum trioxide may emit toxic fumes when heated to decomposition. 8ECTI0N VII SPILL OR LEAK PROCEDURES Notify safety personnel of spills or leaks. Clean-up personnel need protection against inhalation of dusts or fumes. Eye protection is required. Vacuuming and/or wet methods of cleanup are preferred. Place in appropriate containers for disposal, keeping airborne particulates at a minimum. Updated: April 10, 1990 SAL 000009447 Page 3 CA061 MATERIAL SAFETY DATA SHEET N--339 Disposal Consult applicable local, state, and federal regulations to select the method of disposal. Recover metal components by reprocessing whenever possible. SECTION VIII SPECIAL PROTECTION INFORMATION Respiratory Protection Provide a NIOSH/MSHA jointly approved respirator in the absence of proper environmental control. Contact your safety equipment supplier for proper mask type. ventilation Provide general and/or local exhaust ventilation to keep exposures below the TLV. Ventilation used must be designed to prevent spots of dust accumulation or recycling of dusts. Protective Clothing Wear protective clothing, including long sleeves and gloves, to prevent repeated or prolonged skin contact. Bye Protection Chemical splash goggles designed in compliance with OSHA regulations are recommended. Consult your safety equipment supplier. SECTION IX REGULATORY INFORMATION This product contains substances which appear on lists of the indicated act or agency. XX American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values for Chemical Substances in the Work Environment ___ California Proposition 65 ___ Clean Air Act 40 CFR 61 ___ Clean Water Act 40 CFR 116 ___ Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) 40 CFR 302 ___ International Agency for Research on Cancer (IARC) Monographs on the Evaluation of Carcinogenic Risks to Humans Volumes 1-42. Updated: April 10, 1990 SAL 000009448 Page 4 UnitedCatalysis Inc Oirdier and CCI Catalysts 0 A 0 61 MATERIAL SAFETY DATA SHEET N-339 ___ NTP Annual Report on Carcinogens XX Occupational Safety and Health Administration (OSHA) 29 CFR 1910 ___ Resource Conservation and Recovery Act (RCRA) 40 CFR 261 Subpart C XX Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III Section 313 40 CFR 372 XX Toxic Substances Control Act (TSCA) 40 CFR 700 SECTION X BIBLIOGRAPHY Clinical Toxicology of Commercial Products, Fifth Edition, Gosselin, Smith, Hodge, Williams and Wilkins, Baltimore, 1984. Dangerous Properties of Industrial Materials, Sax, N. Irving, ed.. Van Nostrand Reinhold Company, New York, 7th Edition, 1989. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans, Overall Evaluations of Carcinogenicity; An Updating of IARC Monographs, Volumes 1-42, Lyon: World Health Organization, International Agency for Research on Cancer, 1987. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Silica and Some Silicates, Volume 42, Lyon, World Health Organization, International Agency for Research on Cancer, 1987. Kentucky Occupational Safety and Health Standards for General Industry, 29 CFR Part 910 as adopted by 803 KAR 2:020 with Amendments as of July 31, 1986, Promulgated by Occupational Safety and Health Administration, U.S. Department of Labor, Kentucky Occupational Safety and Health Program, Kentucky Labor Cabinet, Commerce Clearing House, Inc., Chicago 1986. Occupational Diseases, A Guide to their Recognition, U. S. Department of Health, Education, and Welfare, Public Health Service, Center for Disease Control, NIOSH, Revised Edition, 1977. June Patty/s Industrial Hygiene and Toxicology, Clayton, G.D., Clayton, F.E., eds., John Wiley and Sons, New York, 3rd Edition, Volume 2, A-C, 1981. Updated: April 10, 1990 SAL 000009449 Page 5 C A061 MATERIAL SAFETY DATA SHEET M-339 TLVs1 Threshold Limit Values and Biological Exposure Indices for 1988-1989, American Conference of Governmental Industrial Hygienists, Cincinnati, OH, 1988. MSDS's from Suppliers of Raw Materials. SECTION El The information presented herein is believed to be accurate but is not warranted. Recipients are advised to confirm in advance that the information is current and applicable to meet their circumstances. No Information Available Doc. 550 Updated: April 10, 1990 000009*50 SAL Page 6