Document QkX2Z07x3nVyN7Rjqrb5nrBNo
TennecoPc' mers
^Tenoeco Company
MATERIAL SAFETY DATA
156
(Approval by u.S. Dapartmant o< Labor as "essentially similar" to FORM OSHA-20)
SECTION I IDENTIFICATION OF PRODUCT
MANUFACTURER'S NAMl
TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT
EMERGENCY TELEPHONE NO.
1609-386-9200 713-479-3411
AOORESS
RIVER ROAD, P.0. BOX 129, FLEMINGTON, NEW JERSEY TRAOE NAME AND SYNONYMS TENNECO PVC RESIN
08822
175, 185, 190, 195, 200, 225, 225F, 225PG, 225SG, 250, 250-3, 10R, 501, 530. 540
CHEMICAL NAME ANO SYNONYMS
POLY(VINYL CHLORIDE), PVC H0M0P0LYMER
CHEMICAL FAMILY
CHL0R0HYDR0CARB0N POLYMER
MOLECULAR FORMULA
(ChVcHCI)n
mol wt.
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
COMPONENT
Va
THRESHOLD UMIT
VALUE
COMPONENT
THRESHOLD % UMIT
VALUE
0SHA Standard 1910.93q(. 1017) on vinyl"cfiYoride sets a permissible exposure limit^o?*
Ippm averaged over any 8 hr. period and 5ppm over any 15 min. period. On the basis that jolyvinyl chloride may contain and release small amounts of monomer, the Standard applies to the manufacture, reaction, packaging, repackaging, storage, handling, use or transportation of PVC, but not to handling or use of "fabricated products", as defined, if not sub.iect to processing sufficient in time or temperature to cause mass melting.
APPEARANCE AND OOOR
White powder, odorless
BOIUNG POINT (DEGREES FAHRENHEIT)
Not applicable
VAPOR PRESSURE (MM. OF MERCURY)
Not applicable
VAPOR DESITY (AIR ml)
Not applicable
SOLUBILITY IN WATER
Negligible
SECTION III PHYSICAL DATA
applicableMELTING POINT
(degreesFahrenheit)
Rot
Softens about 160 - 180*F
SPECIFIC GRAVITY (WATER a 1)
1.4
PERCENT VOLATILE (BY WEIGHT)
Approx. 1% (Moisture)
EVAPORATION RATE
Not applicable
SECTION IV FIRE AND EXPLOSION HAZARD DATA
Ignition about 735F auto- FLAMMABLE LIMITS
LOWER
,P^^TOi??OUt 850" F (ASTM D-1929)________ (PERCENT BY VOLUME) Not applicable
FIRE EXTINGUISHING MEDIA
Water spray, carbon dioxide or dry chemical.
SPECIAL FIRE-FIGHTING PROCEDURES
Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes.
UPPER
NFPAunusual fire ano explobion hazards lists ignition temperatures of 725"F for layer and 1220*F
for PVC dust cloud. Produces combustible gases above 570*F. Fire conditions produce hydrogen chloride, requiring protective equipment.
TTil, Information N tumlahad without warranty, raoraaantatMn. Inducamant Of liconto ol any kind. a*cact that it i* accurata t thy Daal ot Tannaco Polymar, knowlaooa w ottalnad hont aoureaa ballaaad By Tannaco Potymar, to Da accural, and Tannoco Polymara doaa not aaaurna any lag*! roaponalMIty lor uaa or rationca upon *ama. Cuatomara an ancouragad to conduct thair own taats. Baton uatng any product road lla laM.
TPOL 291
ten
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
See Section II
s or overexposure None expected - inert resin. See Section IX. Prolonged breathing of concentrated dust may be harmful. (Processing at high temperatures produces flines irritating to eyes and respiratory tract requiring local exhaust).
EMERGENCY AhO FIRST AID PROCEDURES
Ordinary measures of personal hygiene.
In case of exposure in hot processing move to fresh air, flush eyes with water.
SECTION VI REACTIVITY DATA
STABILITY
UNSTABLE
stable
INCOMPATIBILITY <Ml,'ial 10 avoid)
None in ordinary use.
conditions to avoid Normal processing temperature, about 350*F, causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1.
Soluble in certain ketones and organic solvents.
HAZARDOUS DECOMPOSITION PRODUCTS
_ ___ __,
Thermal decomposition produces HC1, and CO and COg (above 570 F).
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOID
X None in ordinary use.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
if Sweep up and remove to disposal container.
WASTE disposal method
Bury in an approved landfill.
SECTION VIII SPECIAL PROTECTION INFORMATION
respiratory protection (Soaofy tyoai In case of concentrated dut, use Bureau of Mines approved dust respirator (NIOBM TC-21C-132 or equivalent). See Sections II and IX.
ventilation
local exhaust
For not processino. ^or^or^fneTry handling.
SPECIAL
Vent to elevated stack. \feni1ate enclosed spaces.
PROTECTIVE GLOVES
Not ordinarily required.
EYE PROTECTION
Safety glasses.
other protective equipment None required for ordinary handling. For exhaust, safety glasses and aloves are reconmended.
hot
processing
local
SECTION IX SPECIAL PRECAUTIONS
OSHAPRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Standard 110.93q{. 1017} requires monitoring and
??bIfi^reSf?^n5cJnntifnr??ny?a2hdlinr?dl-n^nU^ Mtffi'.'JlSSfrJ&l'iljient".
Kw PVC resins with a low monomer content make it easier to operate below the OSHA tion level of O.Sppm in a processor's work area, assuming normal conditions and ventilation, simplifying compliance with some of the regulatory requirements. Further developments on resins and on regulations are pending.
DATE
3/12/84
NAME ANO TITLE
D. GOODMAN. PRODUCT REGULATIONS
SHEET NUMBER ICC
1
TEN 2875