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ACUTE TOXICITY TO FISH TEST SUBSTANCE Identity: PreefrefrlrueodrotoocatsanPeFsuOlSfAonAy,laFmCi-do1(2e8thoyr)aascetthaetem;ajmoarycoalmspoobneent of F[(Ch-e1p2t7ad,ecFaCf-i1uo2r9o,ocFtCy-l)1s0u9l,foonrylFlC--,1p09o-tXa.ssi(uGmlyscailnt,e,CNA-Set#hy2l9-9N-1- 51-7) aRemmiaxtrukrse:of 8T6h%etteessttssuabmsptlaencies FaCn-d12184.%CCu.r-reCn;tfliunofrooramlaktyilocnairnbdoixcyaltaetseitis compounds. 3M production lot number 751 METHOD: Method: Not noted Type: Static acute GLP: No Year completed: 1977 Species: Pimephales promelas Supplier: Not noted. Analytical Exposure monitoring: Temperature, period: 96-hours pH and DO Statistical methods: Probit analysis. Test fish age: Not noted. Length and weight: Average length = Not noted Pratreatment: Not noted Average weight = 1.1 g Test conditions: Dilution Dilution water: water Aerated carbon-filtered chemistry: well water Initial Dissolved Oxygen: hardness: Not noted >9.0 mg/L alkalinity: Not noted pH: Conductivity: Not noted Not noted Stock andtestsolution Concentrations dosing preparation: rate: Once Not noted Stability of the test Exposure vessels: chemical Not noted. solutions: Not noted Number of replicates: one Number of fish per replicate: 10 Number of concentrations: five plus a negative control 0n338 Water chemistry Dissolved during oxygen the study: range (0 - 96 hours): 5.7 ->9.0 5.1->9.0 mg/L mg/L (control exposure) (180 mg/L exposure)* PH range (24 - 96 hours): 7.67.8 75-79 (control exposure) (180 mg/L exposure)* *in 1th8e03m2y0lLmgt/eLs.ttgersotugproduatpabgyi7ve2nhboeurcsauasnedtaoltlaldamtoartwalaistynooctcurred collected Test temperature (0 - 96 hours): 62 to 67F a RESy ULTS Nominal Element concentrations: Bk value: 96-hour LC50 control, 32, = 100 (70 - 56, 100, 180, 142) mg/L and 320 mg/L All element values based on nominal concentrations. SPtraotbiisttaincaallyEsvisalwuaastiuosneodftMoocratlacluiltayt:e LC50 value and the corresponding confidence limits. c0 CoOnNcCiLbUsSIiOoNnSs 00000 The 100 test sample mg/L. with a 96-hour LCs for 95% confidence fathead interval minnow was determined of 70 - 142 mg/L. to be Submitter: 3M Company, St. Paul, Minnesota, 55133 Environmental Laboratory, P.O. Box 33331, bD0 aAtTAAQQuUAAuLrIyTyY ~~ 0 Reliability: information Koinimtihsechmertahnokdionlgog3.y. ThSiasmpstluedypulraictykswdaoscunmotenptraotpieorlnyand characterized. Test concentrations were not characterized. RREEFFEERREENCEESS ~~~ 02000000 TLahbiosrsattuodryy,wSat.s Pcaounld,uMctNe,dcboymptlheet3eMd oCnomApuagnuyst, 2E6n,vi1r97o7n.mental OLTaHER Last changed: 5/18/00 cen339 --_-- ~~ - Po . 740101 . ENVIRONMENTAL ENGINEERI | (2 . AQUATIC TOXICITY WNOGR,KLASBHOEREATTORY = Type Test 96 Hours STATIC Test Organisn_Fathead Minnow Material Tested f-/c 2g Lo7 757 Date Started 8-22-77 Avg. Weight _ yy = PThilmuetiSotnarMtaetder--CCe2anr:bo0n0FpFiilptteerreedd-- weeirdt amtateerrPD(la(RotAdteatrreCadovrmeLperdlge),ted joy ol8l-24-77 _ sen 109geel Cone. 24 hrs survi$val pu Dp.n0 48 hrs Survi4val pH Dp.pm0 72 hrs survi$ve; BH Dpp.mo 96 hrs Survi%val ph Dp.om0 #Bs 07i0sggLoe oeeeobJaaellellTooosooloFFollfleeyo[]oopoooooJ]f{EmoErStE ei<5t : 55 220 90o JbuleTw Joos] [ed =] =d - Sy op RIS To2e0 Tus]5 ledoFaf v Lill LEI | oAvmeernatges:Temperature00(.2. >4.0, 5 HI 100 EERIE TT HTH ] Logo Calculation HTE HTI T7] 55 HH HELHCHLLTToraHi Hi | eH HE mr Tt LT - BEEepo ws EER! H ACH H Ld THR TFT ETTH ee HT 82 HH AH ill Ba LEHT R iim rE mHH 2S eo ; P~ : CenoantH beiO alE;S | I!E ET M H Hilil chy Jjiiann d Cl l Hive Bn] pil pi & -- * - W 0003p 100g gag 30 a0 TR +Survivay 70 80 50 foo EE EE PE PERT EpFer er vP i e e Eni aL E Haan ; . 2 ght SEEii im :a i = E [ nit G E a e Eee n Wem SEE Hi HH Co S ofF g E E Ey Cpm IH NE E ;3 TyTe mei= LE : = Er Se en EEHid HH Hh HiE ra a s HE i. Ba So Ea CEE HEE EF SSESHiEEEE SEEICH EE ERREE RSHFEETHEiEEEHi [HETbHE TnHnEHEi EE fa oH Jii mii i HHH H HH | ~~ AQUATIC TOXICITY - PROBIT ANALYSIS WORK SHEET Date Started: Material Tested: FC-\9 Time Started: (M4) (PM) Test Organism (Fathead minnow) Type Test: (Continuous Flow) (Static) Avg. ht. (gram) Avg. Size (ine Exposure Period: Hour Date Completed: Diluent:(carbon-filt.-St.P. City Wer.) Analysis by: ax No. of Doses 3 |"| observed 3| @ Expected 3| ) Corrected. 0-E Observed-| Contributi to. chi Cire Plotted | Cone. Mortality | Mortality | Values| Expected | Nomograph 1 [o] oo [ TT = 2 [seToTTT 3 Loo| co| 11 4 5 [ee| [ze] go [TT eo[00a| oan rr TT 7 | 11 K=_]0__Aninals/Dose = Total contribution to chi = Total Animals = (chi?)= contrib. to chi x Tot. Animals = ani? (p-.05) for (K-2) degree of freedon (from Table 2) = is less than ; therefore, the data are not significan heterogenous. 95% Confidence' Limits for LCgy* gy=- __L2Compld Lego== seC e i mill Wyg = 622 wuillll Slope function (S) = LCgy/LCsy + LCo/LCg= _/ + / =%S +/47= Total number of animals used between 16% and 84% expected effects (N)= _J0 . acy = 77M . 0 (1.49S5 C (tron Nomograph 12) 1 do Lsq/fLCgq = lower limit = \eo /i.az = __ 7p, of Le X iC, = upper limit = tov X ld = [qo Legg = 100 Vi (95% confidence limits _70.4 to /d> 70 --1a=2 (1) cDoonnsoetcutliivset m1o0r0e% etfhfaencttsw.o consecutive 0% effects or more than two (2) Expected value for any dose should be greater than 0.01% or less than 99.99%. (3) Corrected value for each 0% or 100% effect (from Table 1). * There is a 95% chance that the true value of Ly) lies within these limits. oen3az RCEiEtE.e.. Fe, 3tontIt 32? EE] ke TH TIE T Ee i rE TR Hi EEE < ii s EE = HEE a Sl HEiE p[ELe Ee 4 af ESE ae ER EEE TRE LE PR Een ee Et ele ee g Hh E e TEE iihE 1 m N|i E IEEEEe Rape HLL EE LETT ITEC SEE Pe F[lErt poort mae EEh EdEe Rses oa EE reFE E EE E L ea TLE LRT SHEEEET Llhm LEeE TTT TT ET itt fe = i : Ll eeree PlayFo Sibel bE er CLT he EES Eh Cl i i Hr : TT a ` ' 000343