Document QgM21LGRJMVdNX473eLDxLJD5
GENET
"OR'S WASTE MATERIAL PROFH
PLEASE PRINT IN INK OR TYPE (Elite. 12-pttC*).
RECERTIFICATION
SHEET
SUBMITTED TO WASTE TECH SERVICES
DATE:
November 29, 1990
NTS -001 Waste Profit* Sh**t Cod*
A. GENERAL INFORMATION
' Generaior Name: ?PG
...-ncJ
, 2. Generator USEPA ID; -HE
3 Faculty Address: . ?* * 3ox iU<W
. 4. Generator State ID. Jame___________
-ake Charles. LA
''Columbia Southern Road! ------------------------------------------------------ 5. Zip Cod*:__ 7--0.6.r0."2*:__ __
5. Tecnmcai Contact: __ ___ Ggrstlfl L.._Perry
7. Title: Env, Control Spec. B phon8-.( 318) 491. 4370
a. MAIL WASTE TECH SERVICES 2 Company Name: -----------------------t Address: ----------------------------------
INVOICES TO 1. SI Generating Facility (A, above), or __________ ____________________________ 3. Phone: (
5. Zip Code:
C. 1 NAME OF WASTE
Classifier/WTU Separator Sludge
PROCESS GENERATING WASTE
Derivatives Waste Treatment Unit
3. Is mis waste a Dioxin listed waste as defined in 40 CFR 261.31 (e.g., F020. F021, F022. F023. F026. F027, or F028)?
Yes UNO If yes. DO NOT COMPLETE this form.
O. PHYSICAL CHARACTERISTICS OF WASTE
1. Color: Black
2. Does the waste have a
strong incidental odor?
C No 3 Yes U known,
descnoe:
3. Physical state @ 70* F:
G Solid 3! Semi-Solid G Liquid G Powoer
Other Slirige
4. Layers:
G Multilayered
0 Bi-layered
G Single Phased
5. Specific Gravity: Ra?gej _ 1<4
6. Free Liquids:
Yes G No
Volume:
at
7 pH: -- < 2 3 >2-4 4-7 G7 7-10 10-<12.5 > 12.5 Range.
NA
3. Liquid Flash Point: U < 73 F 0 73-99 F 100-139 F 140-199 F > 200F None Closed Cup GOpenCuc
E. CHEMICAL COMPOSITION
RANGE
F. METALS Indicate if this waste contains any o
Water
AsH Chlorinated
~ Hydrocarbons
M,5b: W
the following:
------ 5~--2T "2TT ~5tT
% %
1 2BcTX/TCLP or
METAL
LESS THAN
2. Total or ACTUAL
% (Parte Par Million)
% Arsenic
j2< 5 < 500 __
% Barium % Cadmium
3 < 100
_______
3< 1 _ < 100 _______
% Chromium % Leao % Mercury % Selenium
5
rxj< 5 < 0.2
G< 1
_ < 500
<< ?20o < 100
_______ _______
0.3
% Silver
S< 5
% Chromium-Hex
5 < 500
Please note. The cnermcat comDOSition total in the maximum
column must be greater than or equal to 100%.
TOTAL _ 125 . %
Copper Nickel
G< 5 < 5 Q< 134
2 mcncate if this waste contains any of the following
NONE or LESS THAN or ACTUAL
PCB's
0 < 50 ppm
ppm
Cyamaes 3
H < 50 Dpm
opm
Phenoucs X Suifioes --
n < 50 onm _ < =0 ppm
ppm ppm
Thallium Zinc
02i8?8
0< n<
. <
. G< G<
5 < 130 5
GENERATOR'S V \$TE MATERIAL PROFILE HEET (Continued)
WTS-001 Wait# PfOlll* Sheet Cod*
Q. OTHER HAZARDOUS CHARACTERISTICS
i IS this wast* a listed solvent waata as dalinaa by 4Q CFR 261.31 (F001. F002. F003. FQ04, or F005)?
2. Does this watte contain greater than 1000 ppm total hatogenated organic compounds?
3 indicate II this waste la any of the following:
RCRA Reactive
Radioactive
G Water Reactive
Etiological
Explosive
G Pesticide Manufacturing Waste
Shock Sensitive
Other
Pyrophoric
SI None of the above
Yea E3 no
0 Yes no
H. COMPLETE ONLY FOR WASTES INTENDED
I. OPTIONAL -- RECLAMATION. FUELS. OR INCINERATION
FOR FUELS or INCINERATION
PARAMETERS Provide if Information la available.
LEEE THAN or ACTUAL
Range 1. Heel Value (BTU/lbl: J00 . 2000
2. Water: - 20r5Q %
Beryllium Potassium Sodium Total Bromine Total Chlorine Total Fluorine Total Sulfur
GD< 6000ppm Q < 6000 ppm 0 < 6000 ppm < 2% 5)< 36% < 1%
- ppm UNK - ppm
- ppm nror-/
-m_%
3. Viscosity tapefc@Q______________________ #F O 100*F 150*F
4. Ash: ___ ^"25
% 5 saleable solids:*a
5. Vspor Prassure @ STP (mm/Hg):
7. la this waste a pumpable liquid?
O Yes No
Type of pump?
8. Can this waste be heated to improve flow? Yes 0 No
9. Is this waste eoluble In water?
Yes
0No
* TRANSPORTATION INFORMATION
10. Particle alia: Will the solid portion of this wastepete through
a 1/S inch screen?
Yea
QQNo
1. Is this DOT Hazardous Material? C3 Yes no
2. Antlolpetad Annual Voluma/Unlts: ___________
3. Proper Shipping Nfglmame; maWblaesteliqFulaimTmable liquid. n.o.s.. Flammable liquid, UN]993. RQ
4. Hazard Clasa:
aui.c j.j.iuj.u
6 IO tf`
UN 1993
6. Additional Description: ( ^fetliylene Diehl pride, Ethyl Chloride)
[technical names
7 Method of Shipment: El Bulk Liquid Bulk Solid B Drum fTyne/fti*|.. $5 gal /
Other;.
6 CERCLA Reportable Quantity <RQ): ------------------------1----------------
9. RO Unite (lb/kg): , , T, F,..,
,,
i0. USEPA Hazardous Waste? EF Yes No
11. USEPA Hazardous Waata Number(s):
^2 > DC
12. State Hazardous Waate? ED Yea No
13. Siata Hazardous Waate Number(a): W29.D039,1)040 (State ana
dimS.TJrTVfJ
K. SPECIAL HAHOUNO INFORMATION MSDS-LC-5C
Additional Page(a) Attache
L. GENERATOR CERTIFICATION I hereby certify that all Information aubmittad In this and all attached documents contslns true sn accurate descriptions of this waste materiel, and all relevant Information regarding known or suspected hazards in the possession c me generator nes been disclosed.
Signature
Gere Id L. Perry 3.
Name (Type or Print!
SL 021879
Env. Control Spec.
2.
Title 12//^0
oate
5TE -.NALY5I5 REPORT Ei. - i rcnmentai Da.Dorac.crv PPG Industries. Inc.. _iKe ''hanes.
Soutn Ciassirier Sludge. N'TS-OOI
aeacion or Sample: ample oilecrcr:
Drums ac HNS A. A, 'ooper
ample Method/Dev ice: lace, Time : r Sampling :
Ranaom grao - dipper
d-2 - 90 5:30 am
Sate All Analyses Completed: y-fe-90
Report Submitted Bv: Date :
Tarv Prejean 9-24-90
-DIALYSIS RESULTS
est Parameters
I Standard
|
; m* ability 1
N/A 1 140 F
!
'orrosivitv
PH ! 2-12.5
|
''' N/A
inch/vr 0.250 max 1
leac c i v11 v
!
/A
AS
">. 0 max
ND
:clp
Ba
100.0 max
1 . 70
'oxicitv
Cd
1.0 max
0.30
(mg/L )
Cr
5.0 max
1 . 10
Pb
5.0 max
0.40
i N/A
Ha
0.2 max
0.30
Se
1.0 max
ND
Ak
5.0 max
0.02
Lab 1
1
Log
Sample \~o 1351
|
... |
,
i i. .
i
1 _1 .
| i
i
i 1
ii
.............. ;
1!
1
_
i j i 1
i
11 he r r -irameters
t if neeaed )
N/A
1 ' i.oik :e t ec cea
CHLORINATED'HYDROCARBONS % ) ` 1
Chlo roethene
( VC )
1 'hloroethane
! EC )
Dichiormetnane
(MeC12 )
1 , 1-Dichioroethene
; vdc i
1 , 1-Dichloroethane
1 DCE )
1 ,2-Dichloroethene
(cis/trans)
Trichloromethane
f CHC13 )
1 , 2-Dichloroethane
( EDC )
1.1.1-Trichloroethane
(MC)
Tetrachioromethane
(CC14 )
Trichloroethene
(Trichlor)
1 . 1 . 2-Trichloroethane
( TCE )
Tetrachlorethene
(Perchlor)
1.1,1.2-Tetrachlorcethane .unsvm ) 1 , I .2.2-Tetrachloroethane ! s vm )
i4
Pentacnioroethane
iPenta )
oara-uichloroDenzene Texachloroethane Eexacnlo ronu taa i ne
(d-DCB ) 1 HEXA ) 'HCBD!
i
\i
CnKnown C1HC
|
Total C1HC
( % ! `1
| PCBs
i :Heat
Yal ,e
|
! !
Chlo r me
Wate r
Dens 1 tv
Ash
11 Sodium
i ; :
1
' 1\
I[
1 SL
O2I00U i
DDm 1 ! i
ETC/-b
%
wt%
-
nL/mi
wt%
v- fL O/o/
Disposal Method
Profile No
NTS 001
SSOSSOSSOSSOS*SOSSOS*SOS*SOSSOS*SOSSOSS9SSOS*SDS*S9SSOSSOSSOS*SOSSOSSOS*SOSSOS*SOS*SOSS9SSOS*S9SSDS*
SGS#SGSSGSSQS*SGS*SGSSGS* i*SGS*SGS*SGSSGS*SGS*SGS*SGf 3SSGS*SGSSGS*SGS*SGS*SGS
SGS Environmental Laboratories E9008-038
C/1
RESULTS - Sample ID: .1351 Classifier Sludge
SGS ID: E9008-38-17
TCLP Metals
Date Extracted: 8/14/90 Date Analyzed: 8/17/90
Concentration m ppm (mg/L) in TCLP Extr;
EPA HW
D004 D005 0006 D007 D008 D009 D010 D011
TCLP Metals
Arsenic Barium Cadmium Chromium Lead Mercury Selenium Silver
Result
ND 1.7 0.3 1.1 0.4 0.3
ND 0.02
Blank
ND ND ND ND ND ND ND ND
Method Detection Limit
0.5* 0.02 0.03 0.04 0.1 0.0002 0.3 0.02
Total Metals Date Analyzed: 8/20/90
Antimony Arsenic Barium Beryllium Cadmium Chromium Lead Mercury Nickel Silver Thallium
Result
Concentration in ppm (mg/Kg) in sample
Blank
Method Detection Limit
* High MDL due to spectral interferences. ND denotes Not Detected at a level above the method detection limit.
SL 021881 Member of the SGS GrouD isonot*
<|fQ*iai*iQ'iQiBa8*aa6*8as*SQS*sai*sQS*ias*ioi*iaitiaiQssc9iG9sQtiBQ8iaoi*tQi*iGSi
$
SOS Environmental Laboratory
E9008-038
RESULTS - TCLP TOXICITY VOLATILES
SGS IDi 59008-038-17
PPG IDt 1351 Classifier Sludge Date Extracted! 8/27/90 Date Analyzedi 8/29/90
Concentration in ppb (ug/L) in TCLP Extract
Method
1851 Classifier Detection
Sludoe
Unit
Benzene
400 250
carbon Tetrachloride
2*150
250
Chlorobcnsene Chloroform
325 33,100
250 250
1,4-Dichlorobenzene
ED 250
1,2-Dichloroethane
13,000
250
l, l-Dlchloroethylene
8,950
250
Methylethylketone
7,200
500
Tatrachlorosthylene
60,550
250
Trichloroethylene
35,050
250
vinyl Chloride
ED 500
TCLP bjiuk
ED ED ED ED ED ED ED ED ED ED ED
Blank Detection
Lialt
5.0 5.0 5.0 5.0 5.0
5.0 5.0 10.0 5.0 5.0 10.0
i
Surrogate Standard Percent Recovery (at 0.050 nc/L)
1351 ciiBiititr Sluflgt
1,2-Dichloroethane-d4 Toluene-dB 4-Bronofluorobensene
103 t 91 % 3 %
98 % 101 t 112 %
SL 021882
XD d notes X t Det oted at t 1 v 1 above the nethed d teotlon Halt.
8
Mamber of tha BQS OrouD (OociM Mn**M <m Immuimw)
&
fOI*MI*IQIIQIIO4QS*SQI*8Q8 8U*IQI*iaH6t*IQI*l(II*M8*M8*80tIOIeQI*Ql*IQ8iaiY
aai4Gtai40aGMG8>aitQt*IGIIQI*IQ*<)aIOt*tQI*QSIQaIQMI|QiUi|QI|
SQS Environmental Laboratories
RESULTS - TCLP TOXICITY SEMIVOLATILES
H90O8-d38
I
308 ID t 89008-038*17
PPG IDi 1351 Classifier Sludge
Date Extracted! 8/31/90
Date Analysed! 9/08/90 Concentration In ppb (ug/L) in TCLP Extract
o-cresol -cresol p-crasol Cresol
1351 Classifier Sludge___
ND MD
MD
MD
Blmnk MD MD MD ND
Method Detection Llnlt
10.0 10.0
10.0
10.0
2,4-Dlnitrotoluene Hexachlorobenxene Hexachlorobutadlane Hexachloroethane
ND ND MD. MD
MD MD MD MD
10.0 10.0 10.0 10.0
Mitrobenzene
MD MD 10.0
Pentachlorophenol
ND
MD
50
Pyridine
MD MD 10.0
2,4,5-Trichlorophenol
ND
MD
50
2,4,6*Trichlorophenol
MD
MD
50
Surrogate Standard Percent Recovery (at 0 i2M aa/LL
1351 Classifier Sludoa
BltnK
Z-Pluorophenol Phenol-dS
2,4,6Tribroaophenol Nltrobensene-dB 2-Fluoroblphenyl Tarphenyl-dl4
10 %
15 % 14 % 25 % 17
44 %
17 % 18 %
32 1 33 % 38 % 41 t
SL 021883
ND denotes IT t Detected at a level above the !eeth d detection lia
Manfeer of the Ml Group (tow* omm suiwmmam)
O
fa>8*$Gs*eQs*8GSsa8*sasSGs satSQ3*608*8Q6*eQi`a&*QQS`tot-afeG*Qt*as'tGfta'ai?
. 1 - T0 1
WASTE ANALYSIS REPORT nvironmentai Laboratory
PPG Industries. Inc.. _ake Charles. La.
d1e :
at ion of Sample:
'ample Collector: Sample Method/Device:
South Classifier Sludge. (WTS-001 Drums at HWSA. W. Cooper Random grab - dipper
Date/Time of Sampling :
6-2-90 5:30 am
Date All Analyses Completed: 9-6-90
Report Submitted By: Date:
Gary Preoean 9-24-90
ANALYSTS RESULTS
Test Parameters r-mi: ability ( Corrosivity
! "") N/A Heactivitv
N/A
TCLP ""oxic lty
(mg/L)
1 N/A
N/A PH .nch/vr
As Ba Cd Cr Pb Hg Se Ag
Standard 140 F 2-12.5 0.250 max
!
Lab Loa Sample No 1051
5.0 max 100.0 max 1.0 max 5.0 max 5.0 max 0.2 max 1.0 max 5.0 max
ND 1 . 70 0.30 1 . 10 0.40 _0.30___ . ND 0.02
... __
| i|
0 the r Parameters (if needed I 1 .1 /
. D/none :e t ec t ed
CHLORINATED HYDROCARBONS ( % )
!
Chloroethene
(VC )
Chloroethane
( EC )
Dichiormethane
(MeC12)
1 . 1-Dichloroethene
(VDCL
1 .1-Dichloroethane
( DCE)
1 . 2-Dichloroethene
(cis/trans)
Trichloromethane
(CHC13)
1.2-Dichloroethane
( EDC )
1.1.1-Trichloroethane
( MC J
Tetrachloromethane
(CC14 )
Trichloroethene
(Trichlor)
1.1.2-Trichloroethane
(TCE)
Tetrachlorethene
(Perchlor)
1.1.1.2-Tetrachloroethane (unsvm)
1 , 1 ,2,2-Tetrachloroethane ( svm)
Pentachloroethane
1Penta
para-Dichlorobenzene
(p-DCB)
Hexachloroethane
(HEXA)
Hexachiorobutadiene
I HCBD
Unknown C1HC
Total C1HC
(% )
JisDosai Method
Waste Tech
Profile No
1j I 1PCBs
Heat Value
I i
i i
Chlor me
Water
Density
Ash Sodium
j
ITRjn ! i
BTU/Ib
%
wtX
-
g/ml
wt%
SL 02188V WTS-001
PARAMETER P:n:tabi!itv
1 j i
i
w- ."i Xj L* w1 .N * , w 3 1
METHOD USED
Pen-sky-Martens CLosed 'up Tester ASTM Standard 0-93-79
Setafl&sh Closec Cup Tester .-.STM Standard D-3278-7o
It he r (Speclty i 1
`.'uri'DSivit <' pH )
^ N/A
SW-846 Methoa 9040 pH measurement
Othe r (Spec 1fy i ;
Corrosivity i incn/'yr ) ^ N / -i
National Association of Corrosion Engineers Standard TM-01-69
Other
j
( Spec i t'y ) ;
Readtivitv
1 . Normally unstable without detonating-.'
i
Reacts violently with water?
~
|
^ N/A
fine a t firmat;ve mswer will
ciassifv waste reac 11ve )
3 . Forms potentially explosive mixture with water?
j
4 . Cyanide or sulfide bearing waste which can generate toxic
gases, vapor or fumes under pH conditions between 2 ana
12.5?
D . Capable of detonation or explosive reaction if subjected to!
. strong initiating source or if heated under confinement?
|
6 Readily capable of detonation or explosive decomposition or|
reaction at standard temperature and pressure?
i , Forbidden Class A, or Class B explosive as defined in
. |
49CFR 173.51, 173.53, and/or 173.88? ----------------------- r
|
:clp* N/A
`Toxicity
SW 84 6'
SW 846 1
SW 846
Parameter Method Parameter Method Parameter Method
||
A3
HO 10
Ag
6010
! PCB
|LD-2571
Ba
6010
C1HC
5030
1 C1HC
1 LD- 2 5 62A
Cd
6010
Sodium 3050.60101 Heat VajLue l LD-2362B
Cr
6010
PH
>045
1 Chlorine iLD-2562D
Pb 6010
water
]LD-2 5 6h
Hu 7 4 7 0
asn
. LD-2 5 6'.
Se 6010
1j
Characteristic Leach ins Procedure
LABORATORY IDENTIFICATION Laboratorv: PPG Lake Charles \naivst(s ) : SGS Labs
Test Parameters Analv-ed
Total metals
S --20- 90
TCLP metals
8-17- 90
TCLP volatiles
8-29- 9 0
TCLP semi-voiatiles 9- 6-90
and
Date
oc : iarv Pre.iean
SL 021885
SGSSGS*SGS*SGS*SGSSGSSGS*SGS*SGS*SGS*SGS*SGSSGS*SGS*SGS*SGS*SGS*SGS*SGS*SGSSGSSGS*SGS*SGSSGS*SGS*SGS*SGSSGS*SGS
<*SGS*SGSSGS*SGS*SGS*SGSSC "!GS*SGS*SGS*SGS*SGS*SGS*SGS*S 0 CA
CA
a
SGS Environmental Lab ratories
SGS*SGS*SGSSGS*SGS*SGS*SGS
e9008-038
CO
(O O RESULTS - Sample IDs 1351 Classifier Sludge
(A
SGS IDt E9008-38-17
CO
a CO TCLP Metals
CO
O CO Date Extracted: 8/14/90 (aA Date Analyzed! 8/17/90
CO
Concentration in ppm (mg/L) in TCLP Extract
(A
u
CA EPA HW
CO
U
(A D004
CA
a
D005
(A D006
TCLP Metals
Arsenic Barium Cadmium
CA
O
D007
CA DO08
Chromium Lead
CA
0
D009
Mercury
CA DO 10
Selenium
CO DO 11 0
Silver
CA
CA
0
CA
Total Metals
Result
ND 1.7 0.3 1.1 0.4 0.3
ND 0.02
Blank
ND ND ND ND ND ND ND ND
Method Detection Limit
0.5* 0.02 0.03 0.04 0.1 0.0002 0.3 0.02
# Date Analyzedt 8/20/90
Concentration in ppm (mg/Kg) in sample
CA
0
CO
Method
CO
0
Result
Blank
Detection Limit
CA
CO Antimony
a CA
CO
Arsenic Barium
0
CA CO
Beryllium Cadmium
0
CA
Chromium
CO Lead
a
CO
Mercury
ND ND 85 ND
6.3 114
44 23/22
ND ND ND ND ND ND ND ND
20 20
2.0 2.0 3.0 4.0 10.0 0.09
CA Nickel
0
CO
Silver
110 ND
ND 10.0 ND 2.0
CA Thallium a
ND
ND 30
CA
CO
0 * High MDL due to spectral interferences.
CA
CaA
CO
ND denotes Not Detected at a level above the method detection limit.
CA
a
CO
co_ SL 021886
CA
0 CA
CA
0
CA CA
O Member of th6 SQS Group iSociete Generate de Surveillance}
CA
>;iqi*miio9*ioi sutias*aa8 ios*QstQi*sas*iat*taiiflt*tQi*tc3iG9*s&iaaatiaitQii(it
i
8Q8 Envlronmontal Laboratory
E9008-038
i
i
RESULTS - TCLP TOXICITY VOLATILES 8GS IDi B9008-O38-17 PPG IDt 1351 Classifier Sludge Date Bxtractedi 8/27/90 Date Analyzed! 8/29/90
Concentration In ppb (ug/L) in TCLP Extract
Benzene
1351 Classifier ____3 Hid 9#
Method Deteotion
-.
400 250
carbon Tetrachloride
2,150
250
Chlorobensene Chloroform
325 33,100
250 250
1,4-Dlehlorobenzene
HD 250
1,2-Dichloroethana
13,000
250
1,l-Dichloroethylene
8,950
250
Methylethylketone
7,200
500
Tetrachloroethylene
60,550
250
Trichloroethylene
35,050
250
Vinyl Chloride
HD 500
TCLP
UioJl
HD HD HD HD HD HD HD HD HD HD HD
Blank Deteotion
5.0 5.0 5.0 5.0 5.0 5.0 5.0 10.0 5.0 5.0 10.0
Surrogate Standard Percent Recovery (at 0.050 no.'Ll
1,2-Dichloroethane-d4 Toluene-d8 4-Broaofluorobenzene
1351 Classifier Sludge
103 t 91 % 3 %
Blaofc
98 101 % 112 \
SL 021887
S
a
ND denotes Sot Detect d at a level above the noth d deteotion Halt.
Member of the BOS Group (SeeiM NrMi O* turwMlmwl l<M*8O$*SG88ae*0Q80QS9OS*8Q8*0Q88OS*BGS*8Q8*SQ8*8G8*8QS*8ft8*8Q8*8Q88QS*eat*$Gt*9QaV
MMGI*iai*iaMQS*IQMail*QI*iai*IOI>IM*IOIMl*Q4QIQia4a4Q|ilWi
SQS Environment*! L*bor*torl8
RESULTS - TCLP TOXICITY 8EMIVOLATILES
B9098-038
SOS IDi B9008-008-17
PPG IDi 1351 Classifier Sludge
Date Extractedi 8/31/90
Date Analyzedt 9/06/90 Concentration In ppb (ug/L) in TCLP Extract
o-eresol a-ereaol p-cresol Cresol
1351 Classifier 81udce
BD MD
HD
MD
filABfc MD MD MD MD
Method Detection Linit
10.0 10.0
10.0
10.0
2,4-Dinitrotoluene
MD
MD
10.0
Hexaohlorobenzene
MD
MD
10.0
Hexachlorobutadiene
MD
MD
10.0
Kexaohloroethane
MD MD
10.0
nitrobenzene
MD MD 10.0
Pentaohlorophenol
MD
MD
50
j Pyridine
MD MD 10.0
2,4,3-Trichlorophenol
MD
MD
50
2,4,6-Trichlorophenol
MD
MD
50
Surrogate Standard Percent Recovery lt 8.2M ,/LI
1381 Claaaifler
&mdae
Blank
2-Pluorophenol
Phenol-d3 2,4,6-Tribroaophenol
Mitrobenxene-dS 2-Fluorobiphenyl Terphenyl-dl4
10 % IS %
14 % 25 % 17 1
46 %
17 %
18 t 32 % 33 38 % 41
SL 021888
MD denotea X t Detected at a level above the math d detection Halt.
i
A
?
Member of the 4<11 Group rSoMM oMn m turmumm)
Q
f8O8*808*8aS8G6eSaS*8aSaQS8O88QS6O8*Sa6*808*8a8*80S*8Q8fOS*8O86Qftaae8Q8eSO8*aaaV
GENERATOR'S WASTFMATER1AL PROFILE SHEET ^ev Se^ Z0/2/2Z
(cite.pvAsspaint in ink on-rn>e
_srCL(L-
SUBMITTED TO WASTE TECH SERVICES
DATE:
9/28/88
WTS -001
Lake Charles, LA
6. Technical Contact:
.(C_o_l.u.mmm bia Southern Road) Anne Corbello
2. Generator USEPA ID:
008086506
4. Generator State ID: ^ame
70602
Black
j strong incidental odor?
O No Yes It knoen.
Solid 51 Ssad-SoMd Liquid Powder
I Ottwr
Multilayered SBHayerad Single Phased
f. METALS Indicate if this waste contains any o
Water
_2a_
the following:
-SO. %
i. eptox/tclp
or 2. 0 Total
Aab_
METAL
~2n__ %
THAN or-- ACTUAL (Parts Per Mdllon)
Chlorinated Hvdrnr...yhnn
__ So/Ms-
Reference Analysis Renorra T.T.S70T and LL0794--------
-2JL
--------- % _50_ %
--------- %
_ZL_ % ____ %
Arsenic Barium Cadmium Chromium
Mercury
< 5< 500
< 100 < 1 <100 < 5
u< 5 <500 < 0.2 < 20
.--g.. 93 1317 L. Of 165. 1A.9 ! 17'
______ %
^Oease note: The chemical composition total in the maximum
______ %
^btumn must be grea r than or equal to 100%.
total; > 120
Selenium
< 1 <100 0-64
Silver
< 5
<1 41
Chromium-Hex Q < 5 <500 . UNK
Copper
< "5-
358.
2. Indicate if this waste contains any of the following:
PCB's Cyanides Phenolic* Sulfides
NONE
Q
or LESS THAN or
< 50 ppm < 50 ppm _< 50 ppm < 40 r*rim
ACTUAL
ppm ppm -ppm
Nickel
<
Thallium
D<
SL 021889 Zinc
<
<
<
----------------------<
5 <134 i/.c 5 < 130 --mar
5 --UNK
GENERATOR b *ASTE MATERIAL PROFILE SHEET (Continued)
WTS-001 iPreMo Sheet Code
G. OTHER HAZARDOUS CHARACTERISTICS
1. Is this waste a listed solvent waste as defined by 40 CFR 261.31 (FQ01, F002, F003. F004. or F00S)7
2. Does this waste contain greater than 1000 ppm total halogenatad organic compounds?
3. Indicate if this waste is any of the following:
D RCRA Reactive
Q Water Reactive
G Explosive
G Shock Sensitive
O.Radioactive
QEUotogicai
G Pesticide Manufacturing Waste
G Other _
Q Pyrophoric
i&None of the above
Q Yes ETMo SI Yea No
COMPLETE ONLY FOR WASTES INTENDED FOR FUELS or INCINERATION
L OPTIONAL -- RECLAMATION, FUELS. OR INCINERATION PARAMETERS Provide if information is available.
Beryllium Potassium Sodium Total Bromine Total Chlorine Total Fluorine Total Sulfur
LESS THAN
u< 5000 ppm
G< 5000 ppm G< 5000 ppm G.< 2%
G< 35%
G< 1%
or ACTUAL <0,71 opm
0J3. ppm
-IfflL .% 3fli35.%
SHK % J3HL__ %
1. Heat Value (BTU/lb):. JSXL
3. Viscosity (cps):_____
am.
2. Water 2Q=2SL
.*F Q 100*F G ison
4. Ash: 5-?iv -
S. Settleable solids:
____ <h
6. Vapor Pressure @ STP (mm/Hg): --___
7. Is this waste a pumpable liquid?
5 Yes Q N
Type of pump?
drCYM -- -- -
6. Can this waste be hasted to improve flow? G Yes SNo
9. Is this waste soluble in water?
Q'ybs STno
10. Particle size: WHI the sohd portion of this waste rasa through
a 1/B Inch screen?
O'Yea AT No
4. TRANSPORTATION INFORMATION
1. is this a DOT Hazardous Material? SVes G No
2. Anticipated Annual Volume/Units:
3. Proper Shipping Name:____ f1 anmihle llauid. n.o.s. 4. Hazard Class:____ F1TMmahte Liquid____________________
5.1.0. #: UNt995
6. Additional Description: ( />-h1 nHmtaH hydrocarbons_______________
7. Method of Shipment: El Bulk liquid G Bulk Solid 13 Drum (Type/Siza): D0T21-C / 55 gal
8. CERCLA Reportable Quantity (RQ): 10. USEPA Hazardous Wasta? IP Yea 12. State Hazardous Waste? $p Yea
G No G No
9. RQ Units (lb/kg): 11. USEPA Hazardous Waste Number!*): 13. State Hazardous Wasta Number!*): _
1800
/ tons (Ma
K. SPECIAL HANOUNG INFORMATION MSPS LC-5C
G Additional Pagefs) Attach*
L. GENERATOR CERTIFICATION I herebycertify that ail information submitted in this and ail attached documents contains true an accurate descnptions of this waste material, and all relevant information regarding known or suspected hazards in the possession c
the generator has bean disclosed.
i. Signature
A P,_____________ 2. r^rJmnKL SPEClMST
sj~ g
TWe
3. GERALD L. PERKY Name iType or Prim)
4 9/28/88 Oate
SL 021890___
0<i> ~----------GENERATOR'S WASTE MATERIAL PROFILE SHEET
PUASC PRINT IN INK OR TYPE (Bite, 12-pHrt>.
SUBMITTED TO WASTE- TECH SERVICES
DATE:
9/28/gj__________________
WTS-00*Watte Profile Sheet Code
(PPG Lab Log#s 793, 794)
A. GENERAL INFORMATION 1. Generator Name: EPG !n|U85ries> Inc. 3. Facility Address:__ P --B<g TOT
Lake Charles. LA_________ (Columbia Southern Road) 6. Technical Contact: Anne Corbello
7. Title:
___ 2. Generator USEPA ID:
J?2!--JL5.
___ 4. Generator State 10: 31116
5. Tip C<vte.- 70602___________ Laboratory Associate phone: (318) 491.4364
B. MAIL WASTE TECH SERVICES 2. Company Name: ________________ 4. Address:______________________
INVOICES TO 1. SI Generating Facility (A. above), or
,__ --__________________________________ 3. Phone: (
)
5. Zip Code:
C. 1. NAME OF WASTE
rlaea-t.f-ter/UTIl Sena-rator filndee------------------------ .------------------------------------------ --
2. PROCESS GENERATING WASTE Production, of chlorinated_hydroca_rbon waste jeggyrnry unit
3. Is this waste a Dioxin listed waste as defined in 40 CFR 261.31 (e.g., F020, F021. F022. F023. F026. F027. or F028)?
Yes SNo If yet. DO NOT COMPLETE this form.
0. PHYSICAL CHARACTERISTICS OF WASTE
1. Color Black
2. Does the waste have a 1 Physical State @ 70*F:
strong incidental odor?
Solid ElSsm-SoUd
No Q Yes If known, Liquid Powder
detente:
Other Sludge
4. Layers:
Multilayered
Si BHayerad
Single Phased
L Specific Gravity.
Range: 1.2 -
1.4
6. Free Liquids: ^Qyss On Volume:
_ S-3 0_
7. pH: D2 S>2-4 D4-7 Q7 Q7-10 lO-<12J Q 12 l~l a<y
Q|
8. Liquid Flash Point D<73*F Q 73-99* F 100-138*F 140-199*F 200* F None G3 Closed Cup QOpenC
E. CHEMICAL COMPOSITION * 1.
RANGE
Mater
2Q - SO %
Ah-
% -.5----2H %
Chlorinated Hydrocarbons
% 30 50 %
%
%
*Reference Analysis Reports LL#793 and LL0794____________________
% % %
%
Please note: The chemical composition total in the maximum
column must be greater than or equal to 100%.
TOTAL.
2. Indicate if this waste contains any of the f Mowing:
%
120 %
NONE or LESS THAN or ACTUAL
PCB's
< 50 ppm - 16 ppm
Cyanides O
Q < 50 ppm
ppm
Phanoiics
Q < 50 ppm
ppm
Sulfides
^ 50 ppm _____ DDm
P. METALS Indicate if this waste contains any
the following:
i. DeptOX/TCLP or 2. QTotal
METAL
LESS THAN or- ACTU/
(Parts Per MUlion)
Arsenic
< 5 < 500 --
Barium
< 100
Cadmium
< 1 < 100
Chromium
< 5
Lead
< 5 < 500
Mercury
< 0.2 < 20
Selenium
< 1 < 100
Silver
< 5
Chromium-Hex < 5 < 500
Copper
< ~5 -
Nickel Thallium
5 < 5 < 134
< < 130
Zinc
< 5
n<
nn<< SL 021891
A. 0
, lfil 14. 1.1
JLfe <1M . UHK
-358
--MS UNK UrnHrRw.
GENERATGi. o WASTE MATERIAL PROFILE SHEET (Continu d) <
MTS-001 Wl Profile Sheet Code
G. OTHER HAZARDOUS CHARACTERISTICS
1. Is this waste a fisted solvent waste as defined by 40 CFR 261.31 (F001. F002, FQQ3. F004, or F00S)?
2. Does this waste contain greater than '<000 ppm total hatogenated organic compounds?
3. Indicate if this waste is any of the following:
Q RCRA Reactive
Q Radioactive
Water Reactive
Etiological
G Explosive
Pesticide Manufacturing Waste
G Shock Sensitive
Q Other_________________
G Pyrophoric
fj(U4one of the above
Q Yes Kj'No
SI Yes No
H. COMPLETE ONLY FOR WASTES INTENDED FOR FUELS or INCINERATION
Beryllium P tassium Sodium Total Bromine T tal Chlorine Total Fluorine Total Sulfur
LESS THAN
a< 5000 ppm a< 5000 ppm
< 5000 ppm
a< 2* < 35% < 1%
or ACTUAL
<0^4,- opm UHK- ppm
0.63 ppm
UBK %
,30.3,5 %
*
jm . %
L OPTIONAL -- RECLAMATION, FUELS, OR INCINERATION
PARAMETERS Provide if information is available.
Range
1. Heat Value <BTU/lb): 7QQ . 2QQQ
2. Water --20=50
3. Viscosity (cps):@G_______ *F Q 1WF G M
4. Ash: s,?n% s. Settleable solids:
6. Vapor Pressure <a STP (mm/Hg): ------------------------------- -------- ---
7. Is this waste s pumpabte liquid?
S Yes G No
Type of pump?
dry vac
--
8. Can this waste be heated to improve flow? G Yes S N
9. Is this waste soluble In water?
Yes S N
10. Particle size: WUI the solid portion of this wsste rasa threurtMk
a 1/6 Inch screen?
Q Yes S
J. TRANSPORTATION INFORMATION
1. Is this a DOT Hazardous Material? Qyss Gno 2. Anticipated Annual Volume/Units:
1800 -
3. Proper Shipping Name:____ liquid, n.o.s._________________________________ ____________________
4. Hazard Class:____ FI *imnnblp_Liquid
_ am e- ^1993
6. Additional Description: ( r-hift-rtnared hydrocarbons
__
7. Method of Shipment ED Bulk Liquid Bulk Solid (3 Drum (Type/Size): P0T21rC / 55 gal other:
8. CERCLA Reportable Quantity (RQ):1___________________________
9. RQ Units (lb/kg):Ik___
10. USEPA Hazardous Waste? f0 Yea G No 11. USEPA Hazardous Waste Number(s):
F024/D001
12. State Hazardous Waste?
Yes No 13. Stats Hazardous Waste Number(s):
FO24/D001_
K. SPECIAL HANOUNO INFORMATION MSDS LC-5C
Additional Pagefs) Atta<
L GENERATOR CERTIFICATION 1 hereby certify that all information submitted in this and all attached documents contains true accurate descriptions of this waste material, and ail relevant information regarding known or suspected hazards in the possessK the generator has bean disclosed.
1. Signature
a/J?
3. CSRALP L.-EBttX
Name (Type or Print!
V Sap
SL 021892'
2. rNVTRONMFNTAL PE(CLX Title
9/28/88 Dam
:i-7oi
WASTE ANALYSIS REPORT
Environmental Laboratory PPG Industries, Inc., Lake Charles, LA
-DOl
Sample Location of Sample
" SoJ/eJs, & -^rtc l<Cod$ ~fro)9\
yJT'U ^
(LhtAJn-bvj-
*2, j , aWA *T/i,jk (eo-%^7, Tcfrt. Are*.
fl^r
sample Collector
^,y.
^
sample Hetiiod/Device -
<,roJo e>n ,,,,s dn*
Date of Sampling
- %f/sj$s
Date All Analyses Completed -
._
ANALYSIS RESULTS
____ - -
/3^
Report Submitted by: r>/?* (Lrbe.
______
4/JL7/93 --
Corrosivity
( 1 - ^A
Reactivitv
(y > * *'A
(as/U "7^A/ MehJs
< ) - h/a
Othsr
Paranatars (IX nwM)
( ) N/A
M).' /'Jwe, ])eJ`4cjz.d
iTEST procedure
i-L 79
Parameter
Method. Used
Ignitability 3" N/A
PenSky-Martens Closed
Cup Tester* ASTM Standard D-93-79
Setaflash Closed -- Other (specify) Cup Tester ASTM
Standard D-3278-78
Corrosivity
(pH) N/A
B^SW-846 Method 9040 pH Measurement
Other (specify)
Corrosivity (inch/yr) tTN/A
National Association of Corrosion Engineers Standard TM-01-69
O Other (specify)
Reactivity
^N/A
(One affirmative answer will classify waste reactive)
1) Normally unstable without detonating?
2) Reacts violently with water?
3) Forms potentially explosive mixture with water?
4) Cyanide or sulfide bearing waste which can generate toxic gases,
vapor or fumes under pH conditions between 2 and 12.5?
5) Capable of detonation or explosive reaction if subj acted t stroi^
initiating source or if heated under confinement?
Wk
6) Readily capable of detonation or explosive decomposition or
reection at standard temperature and pressure?
7) Forbidden Class A, or Class B explosive as defined in
49 CFR 173.51, 173.53, and/or 173.88?
SV 846
Parameter
Method
Parameter
EP Toxicity
As
7060 L .. A*
SW-846
Ba
7080
ClHC
(Method 1310)
Cd
7131
2 N/A
Cr
7190
Pb
7420
&
TCLP*
Hk
7470
N/A
Se
7740
* Toxicity Characteristic Leaching Procedure
SV 846
Method
7761 5030
boiQ 90*4-
Parameter
fits* <LLH C
Ask . .
Method w Used
Ln*7J____ i.T'tjisLZA Lb*rL2.J
D
LDotS-k>/
LABORATORY IDENTIFICATION Lab ratorvr/'/K
UJa
Analvst(s): fdnnc. (Lrbetfv r &C
Test Parameters Analvzed and Date
fitaJ
------------------------------------------ "T-
cc: >
SL 021894
31-701 Sample
WASTE ANALYSIS REPORT
Environmental Laboratory
IaJ T$-oo I
PPG Industries, Inc., Lake Charles, LA
- ScA'ds,
fro*** 4f&rfh dJa.s5,-f/r C/e.<**-W J
Location of Sample sample Collector
- Der/t/aJ\ses f UrJs Tric.il fkAc. 7ank
*
- leaAw , T?/c//
Sample Method/Device -
Date of Sampling
Se+A/c. -
j?r0Yn. lr;e/l
S+ar+je.
kese. j5m0z-
Date All Analyses Completed - ^//2jgX
Report Submitted by: /C(iorb&lL
Tut Fuwwi
Standard
riit*biUtY <
CorroaivitT
( ) - M/A
ftaactxvitT ('l ' N/A
1 - F/A
._
140 F min
_________e3______________ -2 - 12.S
ineh/rr
0.230 max
EF Toxicivr <m*/D
(/) - Mk
Aa 3.0 matt B 100^0 max C4 ... . Cr 3.0 <M n> . . ?-0 H*__________ U 1.0 M AA - 5 J **
7_^-_
34,8 _ 3,-f
Lab Lon ShrIi Identification (harbor
'74Mr
*
Otha* Fuhmka (if naadad) ( ) - !/A
cmamiAnD rawacMMow > ,a)b
CMMxam*kaw rhl rtrntfhw niahlrnmanw
(OO * (K) (MadSl
.
^#/W-
'
1 'TTiVT
--netlieBe
(eii/fc^aifa^
_________(U1_______
!.o4-
_ 7,22 .
1.1.1-Trt.chinxnaiUu m (MO
______(Cgl>________
2..Z.+
Z. /7
Mftfcm <)
0,4^
itchww Uni_____
J.33
TatnablMoaCbaua
(Fatahtoe)
PartaolUMeattoms
(Faata)
b.Ls'
_
Haxacnlcrctotitadlan* _ (BOO)
... L.+O
f&v^-lXrklarolavi-Ziin*. (f-0c 1. ^os-
' ^.7?
.
PAAaj
/). 34 K
/nd4.A Tl 7/4
jiat vi Si 4- J
Ash
44.
.L.y
st. noisQ'i --------------------i--------------------n
H
TEST PROCEDURE
L
Parameter
Method Used
Ignitability N/A
IB^Pensicy-Martens Closed Cup Tested*ASTM Standard D-93-79
Setaflash Closed 3 Other (specify) Cup Tester ASTM Standard D-3278-78
Corrosivity (pH)
N/A
[B^SU-846 Method 9040 pH Measurement
Other (specify)
Corrosivity (inch/yr) M N/A
National Association of Corrosion Engineers Standard TM-01-69
Other (specify)
Reactivity
^N/A
(One affirmative answer will classify waste reactive)
1) Normally unstable without detonating? 2) Reacts violently with water? 3) Forms potentially explosive mixture with water? 4) Cyanide or sulfide bearing waste which can generate toxic gases,
vapor or fumes under pH conditions between 2 and 12.5? 5) Capable of detonation or explosive reaction If subjected to stro^
initiating source or if heated under confinement? 6) Readily capable of detonation or explosive decomposition or
reaction at standard temperature and pressure? 7) Forbidden Class A, or Class B explosive as defined in
49 CFR 173.51, 173.53, and/or 173.88?
SV 846
Parameter
Method
Parameter
EP Toxicity
As
7060
Ai
SW-846
Be
7080
C1HC
(Method 1310)
Cd
7131
O' N/A Cr 7190
Fb 7420
TCLP* Hi 7470
S' N/A Se 7740
* Toxicity Characteristic Leaching Procedure
SV 846 Method
7761 5030
Parameter
^Method
"9 Used
lu.*7 t LD&r^z-A .
i-JU~L2. D
Ash LfiaJTlel
1 LABORATORY IDENTIFICATION
Laboratory: JPG
UJ, Lk, CU.Je.s
Test Parameters Analvzed and Date
4.7 furJ
?AxdS&.
__
SL 021896
31-701 Sample
WASTE ANALYSIS REPORT
Environmental Laboratory PPG Industries, Inc., Lake Charles, LA
i&TS'OOl
- ** Sch'Js. & Jree hcv'iJs Qo>n.
dTO^ Alorih Ias
Location of Sample'
^ JrAS t/o-U7, T^rc
sample collector
-
sample Method/ Dev ice -
(2>r/er --d f.//^r
^ ,,,ec/i /scop
Date of Sampling
- %//3}%Z
Date All Analyses Completed - f//?/?*
Report Submitted by: -TT^/pc (Lrb*_t/o 9/^7 m
Teat Parameters
lanitabilitv (
Corrosivity
{ ) - N/A
Reactivity (\/> - N/A
- N/A OH inch/Yr
Standard O
140 F min 2 - 12.5 0.250 max
(m*/L) Told Melds
C ) - M/A
AS 3.0 am
Be 100.0 max
Cd 1.0 max
Cr 3.0 max
ft 3.0 max
H_ 0.2 maa
Se 1.0 max
As daaney
3.0 max
AJYc^l
R*x-J lliUM\______
Lab Loa Sessile Identification Number
~7^3
o.m.
53/7.
f;ZW .
-JUT,
_
. t.4-3
_ i.nn
6
</ .4-z
tea.
3*._ .
do. 7 /
Other Parameters (If needed)
( ) - K/A
CHUSSIARD HYDROCARBONS (
Chloroethane
(VC)
>4/3
DlehLoreMttMOe 1. l-Dlehloroethaie l.i-Dlehloroethane 1.2-Dlehtoroethane Trlchloromethane
(ftC12) (VDC) (DO) .(eja/trana) (CBCI3)
.. .0,07
asD
ref)
MO MO..... . O, t3
A/>/Jem, J)ei&a-fc.d
1
1.1.l-Triehloroetbane (MCI
Tetrachloromethane
(CC1A)
Trichloroethene
(Triehlor)
1.1.2-Trichloroathana (TCZ)
1.1.1.2-Tetrachloroethane (unarm)
1.1.2.2-Tetraehloroethame (arm)
Tetrachloroethene
(Parchtor)
Fentachloroethane
(Pita>
Hexachloroathane
(Beat)
Baxechiorabutadlena
(HC30)
Ajxe--'C.i'lerobe*.Zjie, (f-Dc4:
an knodn s
...................
MO o,4S'/(o Z.ZJh . l./z Z.LS
27-73 0 -32(,07 O.pl 3.S'!
l.qu.As MaJ
-'/D %
A/mf Value.
AJafe.f Dens:4--J Aha t
..fi..3tVe .
Z/34-.9 4Tt) / it
33.?3%
^7,22.%
IS) 7. a /_*<. /7.3A.%
SL 021y'
TOTAL CISC
<
1 1I
i1
II '1
I
||
I
1
j
| 1
I | ! I 1 I 1 1 1 1 1 i 1
TEST PROCEDURE
U 7f3
Parameter
Method Used
Ignitability et'n/a
O Pens ley-Martens Closed Cup Tester ASTM Standard D-93-79
Setaflash Closed Other (specify) Cup Tester ASTM Standard D-3278-78
Corrosivity (pH)
N/A
ig/sW-846 Method 9040 pH Measurement
Other (specify)
Corrosivity (inch/yr) CTN/A
National Association of Corrosion Engineers Standard TM-01-69
Other (specify)
Reactivity
3^N/A
(One affirmative answer will classify waste reactive)
1) Normally unstable without detonating? 2) Reacts violently with water? 3) Forms potentially explosive mixture with water? 4) Cyanide or sulfide bearing waste which can generate toxic gases,
vapor or fumes under pH conditions between 2 and 12.5? 5) Capable of detonation or explosive reaction if subjected to strong
initiating source or if heated under confinement? 6) Readily capable of detonation or explosive decomposition or
reaction at standard temperature and pressure? 7) Forbidden Class A, or -Class B explosive as defined in
49 CFR 173.51, 173.53, and/or 173.88?
SU 846
Parameter
Method
Parameter
EP Toxicity
As
7060
Ag
SW-846
Ba
7080
C1HC
(Method 1310)
Cd
7131
N/A
Cr
7190
Ftp*. /jf a, As
Pb
7420
0
TCLP* Hr 7470
a N/A Se 7740
* Toxicity Characteristic Leaching Procedure
SU 846 Method
7761 5030
3CSbf leo/O -Vote' .
Parameter Pc6^
. dLjh>C
Value.
.tj.dJ-A.T- . .
Jisk.
.. Method
Used LDdur 7/ cDjlSLZA l&jxlzjJ-.
LD <JSb /
Analyst(s) :
turn , i
^
"V
ujs. - H'UililOL. Jm.4a.il
SL 021898
TEST PROCEDURE
LL 77/
Parameter
Method Used
Ignitability fN/A
Pensky-Martens Closed Cup Tester ASTM Standard D-93-79
Setaflash Closed Other (specify) Cup Tester ASTM Standard D-3278-78
Corrosivity
(pH) N/A
wfSW-846 Method 9040
pH Measurement
Other (specify)
Corr sivity (inch/yr) c/n/a
National Association of Corrosion Engineers Standard TM-01-69
Other (specify)
Reactivity
er n/a
(One affirmative answer will classify waste reactive)
1) Normally unstable without detonating?
2) Reacts violently with water?
3) Forms potentially explosive mixture with water?
4) Cyanide or sulfide bearing waste which can generate toxic gases,
vapor or fumes under pH conditions between 2 and 12.5?
5) Capable of detonation or explosive reaction if subjected to strong
initiating source or if heated under confinement?
6) Readily capable of detonation or explosive decomposition or
v
reaction at standard temperature and pressure?
7) Forbidden Class A, or Class B explosive as defined in
49 CFR 173.51, 173.53, and/or 173.88?
SW 846
Parameter
Method Parameter
EP Toxicity
As
7060
A*
SW-846
Ba
7080
C1HC
(Method 1310)
Cd
7131
eTN/A
Cr
7190
Pb 7420
TCLB* H* 7470
a^N/A Se 7740
* Toxicity Characteristic Leaching Procedure
SW 846 Method r 7761
5030
Parameter
<LLHC
HwA l'a/ve. CJih>T<ne,
Ula inx Ask
,, Method ^3 Used
LDlskzA LQ.uzLzd)
i-bASOb LDAS4/
LABORATORY IDENTIFICATION
Laboratory:/7^ >-L*Js LJu. diW/e.-.
Analvst(s):
)/tze.r>a^ f
Test Parameters Analyzed and Date
CJ-tiC j AoJ- Va/tfc.
1 1
tyf/sx .
------------------------------------ ---------------------------------------- _--------- g
cc:
SL 021900
TEST PROCEDURE Parameter
~
Method Used
lLL 7V-|
Ignitability N/A
ffl-'Pensky-Martens Closed Cup Tester ASTM Standard D-93-79
Setaflash Closed Other (specify) Cup Tester ASTM Standard D-3278-78
Corrosivity (pH)
N/A
gKsW-846 Method 9040 pH Measurement
Other (specify)
Corrosivity (inch/yr) bT'n/a
National Association of Corrosion Engineers Standard TM-01-69
Other (specify)
Reactivity
^ N/A
(One affirmative answer will classify waste reactive)
1) Normally unstable without detonating? 2) Reacts violently with water? 3) Forms potentially explosive mixture with water? 4) Cyanide or sulfide bearing waste which can generate toxic gases,
vapor or fumes under pH conditions between 2 and 12.5? 5) Capable of detonation or explosive reaction if subjected to strong
initiating source or if heated under confinement? 6) Readily capable of detonation or explosive decomposition or
reaction at standard temperature and pressure? 7) Forbidden Class A, or Class B explosive as defined in
49 CFR 173.51, 173.53, and/or 173.88?
SV 846
Parameter
Method
Parameter
EP Toxicity
As
7060
Ag
SW-846
Ba
7080
C1HC
(Method 1310)
Cd
7131
O'N/A Cr 7190
Pb 7420
TCLP* Hg 7470
S' N/A Se 7740
* Toxicicy Characteristic Leaching Procedure
SV 846 Method
7761 5030
Parameter
<IUH1//W Value. iA/PT/yi*f LjoJ-ay dsh
Method "9 Used
Ldus7/
LDJSL2.3
LDA?C,/t> LD ZS-lol
LABORATORY IDENTIFICATION
Laboratory:/)^ *,,.
Analvst(s): 7^^
A!,
cc
Test Parameters Analyzed and Date
Cl/SCf fJu-aJ- l/q-be.,
1_________ ---------------------------------------------------------------- d
SL 021902
From:
American Laboratories and Research. Services, Inc.
P.0. Box 15609 Hattiesburg, MS 39402-5609 601-264-9320
Date: February 6, 1991
To: Mr. Gerald L. Perry PPG Industries Chemicals Division P. 0. Box 1000 Lake Charles, LA 70602
The following analytical results have been obtained for the indicated sample which was submitted to this laboratory:
Sample I.D. AA07095
Sample location: 1002GP
LabLog 1520 Classifier Solids
Collected by: GPP
Collection date: 01/31/91 Time: 9:15
Laboratory submittal date: 01/31/91 Time: 15:57
Received by: RLH
Validated by: RLH
Parameter: TCLP Extraction Method reference: SW846-1311 Result: done Date started: 02/01/91 Time started: 16:00
Parameter: Mercury, TCLP Method reference: SW846-7470 Result: .009 mg/L Date started: 02/05/91 Time started: 08:30
Parameter: Mercury, Total Method reference: SW846-7470 Result: 1.25 mg/L Date started: 02/05/91 Time started: 08:30
Date finished: 02/02/91 Analyst: BLM
MDL or sensitivity: .005 Date finished: 02/05/91 Analyst: BLM
MDL or sensitivity: .005 Date finished: 02/05/91 Analyst: BLM
SL C& 19
Mr. Gerald L. Perry Page: 2 February 6, 1991
Sample I.D. AAG/095 (continued)
Comments: Refernece Lab Report No. R1905.
If there are any questions regarding this data, please call.
SL 021903
GENERATOR'S WASTE MATERIAL PROFILE SHEET
PLEASE PRINT IN INK OR TYPE (Elite. 12-Wtetll.
RECERTIFICATION
SUBMITTED TO TASTE TECH SERVICES
TATE:
November 29, 1990__'
TTS -001 Watts Profile Sheet Coda
A. GENERAL INFORMATION Generator Name: ??G industries. inc,
1 Faclity Address: ?`
3ox 1000
2. Generator USEPA 10. 4 Generator State ID: "ame__________ _
Lake Charles. LA_________
''Columbia Southern. Road) ----------------------------------------------------- 5. Zip Code: 2^02__ __
o. Tecnmcai Contact: Ggrgld L---EffrrY-------------- 7 Title-Env. Control Spec. a Phi-mo- ( 318) _491. 4370
B. MAIL TASTE TECH SERVICES
INVOICES TO 1. S Generating Facility (A, aDove), or
2. Company Name: -------------------------------------------------------------------------- --------------- __---. 3. Phone: ( )
4 Address: ________________________________________________________ _______________ _____ __________
5. Zip Code:
C. 1 NAME OF WASTE
Class!fier/WTU Separator Sludge
2. PROCESS GENERATING WASTE
Derivatives Waste Treatment Unit_________________________
3 Is tms waste a Dioxin listed waste as defined m 40 CFR 261.31 (e.g., F020, F021. FQ22, F023. F026. F027. or F028)?
3 Yes Eno If yes. DO NOT COMPLETE this form.
D. PHYSICAL CHARACTERISTICS OF WASTE
1. Color. Black
2. Does the waste have a
strong incidental odor?
D No 3 Yes It known.
descnoe:
3. Physical State @ 70 F:
G Solid G9 Semi-Solid G Liquid Powoer
Other Slulge
4. Layers:
G Multilayered
3 Bi-layered
G Single Phased
5. Specific Gravity: _ 1.4
6. Free Liquids:
G Yes G No
Volume:
a
7 pH- C<2 3 > 2-4 Q 4-7 G 7 7-10 10- <12.5 Q > 12,5 FI Range
-
G N/
8. Liquid Flash Point: < 73* F G 73-99 F 100-139F 140-199*F Q > 200F None GciosedCup QopenCui
E. CHEMICAL COMPOSITION
RANGE
F. METALS Indicate if this waste contains any c
' Water
Ash ~ Chlorinated Hydrocarbons
:W
the following:
----- 5~,--7T
% %
ZUT--50" %
1 2fiBcTtX/TCLP or 2. Q Total
METAL
LESS THAN or ACTUAL
(Parts Per Million)
% Arsenic
3< 5 Q< 500
% Barium % Cadmium % Chromium % Lead % Mercury
53 < 100 s< 1 2< 5
3< 5
< 0.2
G< ioo
Q< 500
n < ?n
0.3
% Selenium
Q< 1 Q< ioo
Please note. The cnemical composition total in the maximum
column must De greater than or equal to 100%.
TOTAL:
% %
125 %
Silver Chromium-Hex
QA <
Copper
G<
Nickel
<
5 5 < 500 5 5 Q< 134
I'NK
2 inaicate if this waste contains any of the following:
Thallium
PCB's
aNONE or LESS THAN or ACTUAL
< 50 ppm
ppm
Zinc .
Cyanides "henoiics Sulfiaes
"T, 3C
< 50 ppm < 50 ppm i-i < 50 ppm
ppm SL 021904
ppm ppm
G< 5 < 130
< 5
GENERATOR'S WASTE MATERIAL PROFIi.fi SHEET t PLEASE PRINT IN INK R TYPE (Elite, 12-pttcft).
SUBMITTED TO WASTE TECH SERVICES
DATE:
July 25. 1991__________
WTS - 001 WesteProfit*SheetC dt
A. GENERAL INFORMATION
1 Generator Name: PPG IndustTia*' lnc'_____________
2. Generator USEPA 10: ^^_^08j>_506
3. Facility Address: P` ' Box ^Q0
4. Generator State ID: ame___________
Lake Charles. LA__________________
(Columbia Southern Road)________ ___________________________5. Zip Code: ^0602
6. Technical Contact: _William H. cooper7. Title:
Env. Control Spec. 8, Phone:( 318) 49L 4256
B. MAIL WASTE TECH SERVICES
INVOICES TO 1. SI Generating Facility (A, above), or
2. Company Name: ________________________________________ 3. Phone: (
)
4 Address:_______________________________________________________________________________________
5. Zip Code:
C. 1 NAME OF WASTE Classifier/WTU Separator Sludge
__________
2 PROCESS GENERATING WASTE
Production of Chlorinated hydrocarbon Waste Recovery Unit
3. Is this waste a Dioxin listed waste as defined in 40 CFR 261.31 (e.g,, F020, F021, F022, F023, F026, F027. or F028)? Yes No If yes, DO NOT COMPLETE this form.
D. PHYSICAL CHARACTERISTICS OF WASTE
Color:
2. Does the waste have a 3. Physical State @ 70* F.
strong incidental odor?
D Solid 0 SemnSolid
Black No O Yes if known, G Liquid G Powder
desenhe:
Other
4. Layers: G Multilayered G Si-layered G Single Phased
5. Specific Gravity:
Range: 1.2 - 1.4
6. Free Liquids:
Yes G No
Volume: 8-15
o*,
7. pH: G<2 G3 > 2-4 4-7 G7 7-10 lO-<12.S 12.5 I~1 Range
NA
8. Liquid Flash Point: G<73*F 0 73-99*F 100-139*F 140-199*F > 200*F None Closed Cup Open Cup
E. CHEMICAL COMPOSITION
RANGE
-F. METALS Indicate if this waste contains any of
Water
Ash________________________ __ ____Hhlnrinal-Pri HyHrnrarhnnw
"o*: "ft ,, r": 15 ~ J
3Q --^0- %
the following:
1. EP TOX/TCLP or 2. Total
METAL
LESS THAN or ACTUAL.
(Parts Per Million)
-_______ % Arsenic ___ ________ % Barium
E< 5 < 500 < 100
0.92 3317
- ~______ % Cadmium
< 1 0< 100 4.26
~_______ % Chromium
< 5
-_______ % Lead
< 5 0< 500 ...14--9
~_______ % ~_______ % %
%
Mercury
< 0.2
Selenium
(3 < 1
Silver
0< 5
Chromium-Hex < 5
0< 20 < 100
< 500
1.170
Q.64<1.42
UNK
rPiltease note: The chemical composition total in the maximum
Copper
< 5
*lumn must be greater than or equal to 100%, Indicate if this waste contains any of the following:
TOTAL
N NE or LESS THAN or ACTUAL
PCB's
< 50 ppm
H ppm
Cyanides
< 50 ppm
ppm
Phenoiics
< 50 ppm
ppm
115 %
Nickel Thallium Zinc
<
<
n<< n<
.<
5 < 134 5 < 130 5
si
-24,5 .. UM UNK
Sulfides
< 50 ppm
ppm
GENERATOR'S V ,STE MATERIAL PROFILE . IEET (Continu d)
WTS-001 Waste Profile Shaat Coda
G. OTHER HAZARDOUS CHARACTERISTICS
1. Is this waste a listed solvent waste as defined by 40 CFR 261.31 (F001. F002. F003. F004. or F005)?
2. Does this waste contain greater than 1000 ppm total halogenated organic compounds?
3. Indicate if this waste is any of the following:
RCRA Reactive
G Radioactive
Water Reactive
G Explosive
D Etiological G Pesticide Manufacturing Waste
G Shock Sensitive
G Pyrophoric
Q Other D3 None of the above
Yes No
El Yes No
H. COMPLETE ONLY FOR WASTES INTENDED FOR FUELS or INCINERATION
Beryllium Potassium Sodium Total Bromine Total Chlorine Total Fluorine Total Sulfur
LESS THAN G< 5000 ppm a< 5000 ppm < 5000 ppm a< 2% < 35% a< 1 %
or ACTUAL ppm ppm
--21__ ppm %
13.99 ,
% %
I. OPTIONAL -- RECLAMATION. FUELS. OR INCINERATI N
PARAMETERS Provide if information is available.
Range
1. Heat Value (BTU/lb): 600 - 2200
2. water 20-50 %
3. Viscosity tepSL @ ______________________F 100F 150eF
4. Ash:
________ % 5. Settteabte solids: %
6. Vapor Pressure @ STP (mm/Hg): ____ 7. Is this waste a pumpable liquid?
Yes G No
Type of pump? __ Ary-v\c-------------8. Can this waste be heated to improve flow? 9. Is this waste soluble in water?
G Yes 0 No G Yes P No
10. Particle size: Will the solid portion of this waste pass through
a 1/8 inch screen?
G Yes G N
J. TRANSPORTATION INFORMATION
1. Is this a DOT Hazardous Material? Q Yes G No
2. Anticipated Annual Volume/Units: 1800 tons / year
3. Proper Shipping Name:----- Flammahlp liquid. 4. Hazard Class: Flammahlp 1-ign-iH
n.p.s.--------------------------------------
5. I D. #:
UN1993
6. Additional Description: (__ chlorinated hydrocarbons
7. Method of Shipment: G3 Bulk Liquid G Bulk Solid I Drum (Type/Size): 55 gal__/ D0T-21-Cother..
8. CERCLA Reportable Quantity (RQ): 10. USEPA Hazardous Waste? 0 Yea 12. State Hazardous Waste? GO Yes
Q No
G No
1_________
9. RQ Units (lb/kg):________ lh____
11. USEPA Hazardous Waste Number(s):
F024 D001
13. State Hazardous Waste Humberts): _
F024 D001
K. SPECIAL HANDLING INFORMATION
MSDS L05C
G Additional Page(s) Attachec
l_ GENERATOR CERTIFICATION I hereby certify that all information submitted in this and all attached documents contains true anc accurate descriptions of this waste material, and all relevant information regarding known or suspected hazards in the possession o
th generator has been disclosed. /
Signature
William H, Cooper
3___________________________ Name (Type or Print)
2 Environmental Control ' Title July 24, 1991
4. ___________ ________________ Date
021906 SL