Document QgKg56O5Yby6mJL5gDNLr2NzL
*
Waste Material Uata Sheet o*r ie#*. 'RECeHTlRXO
t<W
a GENERAL INFORMATION
CUST MER INFO
Invoice Address Cert Address Kl
Contact W . H. COOPER______________
pustomer Name PPG INDUSTRIES. INC.
''Address P. 0. BOX 1000
City LAKE CHARLES
State
LA
Zip. 70602
Phone# (318) 491-4250
USEPA ID# LAD008086506
N /A
SHIPPING FACILITY
Invoice
Contact GINGER BUSBY
Facility Name PPG INDUSTRIES. INC.
Address P.O. BOX 1000
City LAKE CHARLES
State___ LA
Zip. 70602
Phone# (318) 491-4526
USEPA id # LAD008086506
Generator Name lit different)
DESCRIPTION NAME OF WASTE___ Combustible Filters PROCESS GENERATING WASTE Production of chlorinated hydrocarbons
GENERAL CHARACTERISTICS (at 70 F unless otherwise specified)
COLOR Clear_______ CXlJQUID 5-10 % FREE PHASES
Qnfpa hazard code
ODOR yes CXSOUD
SINGLE LAYER
NONE flSTRONG SLUDGE
DOUBLE LAYER
MILD
POWDER
MULTI-LAYER
SPECIAL HANDLING INSTRUCTIONS
If special handling techniques are required, specify . use OSHA approved breathing air equipment ____________ and minimize skin exposure
REACTIVE
Is a representative sample provided?
Yes No )( Sample Purchase Order No..
RCRA INFORMATION
Tar SHIPPING INFORMATION
DOT hazardous matenai
*
Is this a USEPA hazardous waste? X Please give USEPA hazardous waste codes:
PROPER Sb HAZARD CL
ite, combustible liquid,Xn.o.s.
1" Mftr NA1993
B/n 1 lb.
F025
ANTICIPATED VOLUME 7QQ GAL,
YDS,
.LBS.
--x DRUM(S). BULK X
RAIL
cribe nature of reactivity if D003 waste:
ONE TIME WK
MO
[XYR
OTHER
Type and size of container _ plastic. 55 gal.
WT PER CONTAINER
lOO lbs.
WT PER GALLON:_________ 1.81 lbs.
SPECIFIC GRAVITY
VISCOSITY (cent!poise)
ASH (HWT) <0.1
TOTAL SUSPENDED
pH
SOLIDS (HWT)
<2
D>12.5
BTU's 1000/lbs. <1 12-16
<0.8
1.4-1.7
1-100 IINK r o.i-i.o
<0.5
020 a 2-6
1-4 0>16
GQ0.8-1.0 >1.7
100-1000
1.0-5.0
0.5-2.0
ITNK
J 6-8
B 4-8 _A . 800
1.0-1.2 1.2-1.4
actual
1000-10.000 >10,000
5.0-20 IS >20
2.0-5.0 5.0-20
n A-io
10-12.5
8-12
| FLASH POINT (dosed cup)
SULFUR (HWT)
HALOGENS (H)
METAL BBTCLP(PPM) EPA E P (mg/Li
<100 F
D>200F
n <0.5
>5
Arsenic (As)________ .................................
100-140 F
O0.5-2.0
____
Chlorine^^C^fiuorine 0
Barium (Ba)__
<1
3-200 F
2-5
Bromine _Q___ Iodine 0
Cadmium (Cd).
Q.l
LRDOU8 CHARACTERISTICS AND OTHER COMPONENTS
Chromium (Cr)
>5 -410QQ
Reactivity:
fi None
Explosive
Pyrophoric
Shock Sensitive Mercury (Hg) _ <0.005
Water Reactive
Etiological
Radioactive
Acutely Hazardous Waste
I (Pb)------- >5 -<7500
Cyanides NONE----- (ppm) PCS'# NONE(ppm) Pesticides
Chromium-Hex (Cn-6) UNK
Sulfides ...NONE___ (ppm) Phenolics NONE (PPtn)
CHEMICAL COMPOSITION (MUST TOTAL 100%)
i chloroethane
l 2l!i in 1
iTrichloroethane
i o,
1
<1,1 .Trichloroethane i10t12 xu, i
iFilter cartridge
i 75--85 i% 1
PERCHL0R
i F.nr. ...
i It 2__ i% 1
, TCE
,10, 17 |% 1
, UNSYM
,10, ^ i% 1
l SYM
,8 , 10 ,% 1
, PENTA
,2 , ..5 |% 1
I HEREBY CERTIFY THAT ALL information submitted in this and-----------
ALL ATTACHED DOCUMENTS IS COMPLETE AND ACCURATE. AND THAT ALL
KNOWN OR SUSPECTED HAZARDS HAVE BEEN DISCLOSED
0, 1 i
1% 1% 1% 1% 1% 1% 1% 1% 1%
Selenium (Se) .< P.-..Q..Q5 ,,
Silver(Ag)______ < 0.03
Copper (Cu)__
7,200
Nickel (Ni)____
45
Zinc (Zn)_____
13
Thallium (Ti) _
<20
Other (Specify).
PC / WSE
SL 021665
ENSCO USE ONLY
US' fS.
RECERTIFICATION DATE
AUTHOnIZZEEO0 SIGNATURE ^
7
TITLE
n-u t
_u ,,___
ATTACHMENT EDO - 1,2-Dichloroethane Trichlor - Trichloroethane Carbon Tet - Carbon Tetrachloride TCE - 1,1,2-Trichloroethane UNSYM - 1,1,1,2-Tetrachloroethane SYM - 1,1,2,2-Tetrachloroethane Perchlor - Perchloroethylene Hexa - Hexachloroethane HCBD - Hexachlorobutadiene PDCB - Para-Dichlorobenzene
021666
Sh
r 501-863-7173
American Oil Road P O Box 1957
El Dorado, Arkansas 71/31-1957
SEPTEMBER 20, 1989
PPG INDUSTRIES, INC. ATTN: ANDY P PLAUCHE'
p.O. BOX 1000 LAKE CHARLES
PO # --------------------DATE RECEIVED-- 09/07/89
SAMPLE:
LA 70669 111 TRICLOROETHANE FILTER CARTRIDGES
LAB FEES: ........................................................................................................ 5
200.00
SAMPLE # LS 00114940
TESTS BTU/LB
\ CHLORIDE % SULFATE % ASH FLASH POINT
F
RESULTS =*
*
* <
8,113.00 8.00 . 20
32.00 140.00
Waste Material Data Sheet
//V No.
Regional OMce
GENERAL INFORMATION
ENSCO CLIENT .
Inyoica Address Cert Address N/A SHIPPING FACILITY
Invoice Address Cert Address N/AQ
' ~ " _______ ._______ !______________ Contact____________
Customer NameILZ__________________I!________-----------------------------
Facility Name.
Address__________________ ..1 Cityir~-------------------------------------------------------------------------
Address_____ City_________
State. Phone #.
.Zip.
State_______ Phone#____
Zip..
- T1 -_
USEPAID*
USEPAID # _
: Generator Name (il different)___ NAMF nF^ARTF710**T/ZlsUl
__________________________ Qfi- / LufTfOeS _ fi-Cnt/eS GENERATION RATE
PROCESS GENERATING WASTE
w .110 r: r.e 1: r ~ y^y j rc CA,
GENERAL CHARACTERISTICS (at 70s F unless otherwise specified)
pusCT/o /J |J NFPA HAZARD CODE
. (Qty/Time) FDTOTOBCE
COLOR ~ ODOR SOUD
LIQUID____ lI_%FREE PHASES b SINGLE LAYER
HEALTH /\ /\ REACTIVE
NONE STRONG SLUDGE
- MILD
POWDER
SPECIAL HANDUNO INSTRUCTIONS
If s. p.e.c.i:al^handlinrg technrique\s~ar^e re1qi u.irewd*,i..sxpweicti.f1y. :
DOUBLE LAYER MULTI-LAYER
to.^o..rr__' ` i; i. wwi
TVi-.c i.'iien
keeucSan* :oncer.tr.it <J% .-- w.. - V- --. wD --^ "
RCRA INFORMATION la this a USEPA hazardoua waata? Plaaaa give USEPA hazardoua waste codes:
_ SHIPPING INFORMATION
DOT hazardous material
"proper shipping name Wiste Cait.ustii.lx : vi i, i. j
*!SHAZARD CLASS Cariudtitle LI
ANTICIPATED SHIPPING VOLUME
\AIaZ JC GAL
_ R/Q__ _ yds; --
LBS.
kfiQ
A. 11
be nature of reactivity if D003 waste:
__ ___DRUM(S),
BULK
ONETIME OWK
ffIlMSOics/62?
Type end size of container: tceviE
Wt PER CONTAINER:____
RAIL OTHER _
WT PER GALLON:_______
SPECIFIC GRAVITY
ASH (%WT)
<0.8
1.4-1.7
(centipoise) 1-100 _
<0.1 ai-i.o
02-1.0 >1.7
100-1000
1.0-5.0
1.0-12 n
1000-10.000
5.0-20 _
12-1.4
>10400
>20
] FLASH POINT (closed cup)
SULFUR (HWT)
TOTALSUSPENDED SOLIDS (NWT)
CKO* 02-2.0
>20
2.0-5.0
5.0-20 HALOGENS (H)
pH BTU's 1000/lbe.
<2 >12$A <1 12-16
2-8 ____ _ 1-4 >16
6-8 8-10
4-8 ___________
8-12
aoual
10-12.5 KW MMEETAL QT^MPPM) EPA E P (mg/L)
<100 F
0> 200F
<0l5
D>5
Araenic (As).
100-140 F _________
05-24
____
Chlorine. . Fluorine.
Barium (Be)__
140-200 F
2-5
^ KKilAZARPOUSCHARAC I MMSflCSANO OTHER COMPONENTS
* Reactivity:
None
Explosive
Pyrophoric
Shock Sensitive
Water Reactive
EBotogtaN,
Cyanides.
rTPPai ______ (ppm) PCffe.
"0
wumiwvm----T------a---a--T--
TH
rifwiwiwN "
Radioactive
Acutely Hazardoua waste
(ppm) Pesticides.
VO""/
|1 CHEMICAL COMPOSITION (MUST TOTAL 100%)
, .,: .x-ininxcrcetiane , umicniaretnyiene
, irix^iyroet-'-lxr.e
, .. i-.i erloroethy ier.e
, . .j orosLiane
___ ,w-
..jrc'C-L.'one
m -
..
'"V
r -ii *-4 . i
r r* h" r* L- ^j.1 t i*
M i exnc::Icrcetr_r:e
ME 1 -T'w.Vilw. ME 1 _ me i ME 1 ME 1 ME 1 ....
'SX^-wilU
1% 1% 1% 1% 1% .1% 1%
i r"r ::'ct-T , . _/r ~a hi
_i .1 i .i
ME 1 1% 1
1%
1%
Cadmium (Cd). Chromium (Cr) Mercury (Hg) _
l(Pb)------Chromium-Hex (Cr+6) Selenium (Se)_______ Silver (Ag)___________ Copper (Cu)_________ Nickel (NO___________ Zinc (Zn)____________ Thallium (Tl)__ Other (Specify).
<40OO <7300
All Blanks Must Be Completed If metal(s) is/are not present indicate "None"
If concentrations are not known, indicate "unknown."
ALL ATTACHED DOCUMENTS IS COMPLETE ANO ACCURATE. ANO THAT ALL KNOWN OR SUSPECTED HAZAROS HAVE BEEN DISCLOSED
PC / WSE
ENSCO USE ONLY
AUTHORIZED SIGNATURE
LL
`.irrc.
TITLE
DATE
RECERTIFICATION DATE
SL 021668
Waste Material Data Sheet
no. 11.49/10
5 GENERAL INFORMATION
CUST MER INFO
Invoice Address E Cert Address
Contact___ Ginger Busbv___________
Customer Name. PPG Industries. Inc.
Address------- ?_ 0 5 ox lQQfl-
City iks Charles
State -- JA.
7iP
Phone #.
21S 491 4526
70602
USEPAID# LACG0808650;
N/A
SHIPPING FACILITY Invoice Address Cert Address il
r-nntam W. H. Cooper
Facility Name-------PPG Industries. Inc.
Address___ P 0 Box 1000.
City _ Lake Charles
State . JA
zip. 70602
Phnne# 318 491 4250
USEPAID # . LAD008086506
Generator Name (if different).
men
1.1.1-Irichloroethane Filter Cartridges
PROCESS GENERATING WASTE
Production of Chlorinated Hydrocarbons
GENERAL CHARACTERISTICS (at 70s F unless otherwise specified)
1NFPA HAZARD CODE
COLOR____ Hmt
(3 LIQUID
ODOR
Yaw a SOLID
S-)fi % FREE PHASES P SINGLE LAYER
HEALTH
NONE EtfTRONG SLUDGE
DOUBLE LAYER
MILD________________ POWDER
MULTI-LAYER
SPECIAL HANDLING INSTRUCTIONS
If special handling techniques are required, speedy..
N/A REACTIVE
Is a representative sample provided?
Yes Cl No Sample Purchase Order No.
RCRA INFORMATION
X v'
M SHIPPING INFORMATION
DOT hazardous material ^
Is this a USEPA hazardous waste? Please give USEPA hazardous waste codes:
PROPER SHIPPING name 1 , 1,1-Trichloroethane, ORtt-A HA7ARnna.lc ORM-A me UK 2831 n/r> 1006 lbs
U226
ANTICIPATED VOLUME _
.GAL,.
. YDS, 8120
LBS.
6 2,, DRUM(S), BULK 5 ; NJ
RAIL / f
ONETIME WK
MO
OOYR
OTHER
Describe nature of reactivity If D003 waste:
Type and size of container.
Plastic/55 gal.
WT PER CONTAINER:____
132 lba.__________
WT PER GALLON:________
2.4 lbs
SPECIFIC GRAVITY
<0.8 aoA-i.o
1.0-1.2
12-1.4
1.4-1.7 >1.7 .
K^j
VISCOSITY (centipoise) 1-100 I'Nl 100-1000 "***
1000-10,000 > 10,000
A8H(HWT) <0.1 0.1*1.0 cXi .0-5.0 est. n an-on n
>20
TOTALSUSPENDED -- SOUDS (HWT)
DC 0.5 nns-on
2.0-5.0
5.0-20
d>20 GNK
***
pH <2 n?A
ne-e
0>12.5 "*1-
ns.m
10-12.5
3 BTU's 1000/lbs.
<1 12-16
1*4 >16
4-8
kkl___
8-12
| FLASH POINT (closed cup)
SULFUR (HWT)
HALOGENS (%)
Q METAL TOTAL (PPM) EPA E P (mg/L)
<100F
>200F
II <3X5
>
100-140 F
None
0.5-2J)
____
140-200 F
2-5
jlQlAZARDOUSCHARACTBWTICSANO OTHER COMPONENTS
Arsenic (As)
Chlorine 23=23luorine Non ; Barium (Be) --
Bromine
Iodine Jiflae} Cadmium (Cd).
Chromium (Cr)
^ r*\ *
J&L jLLI nmrz
Reactivity:
CStone.-
Explosive
Pyrophoric
Shock Sensitive
Water Reactive
EHologicai
Cyanides -- ^one (ppm) PCS'* ^one
Radioactive
Acutely Hazardous Waste
(ppm) Pesticides None
Sulfides __ kone (ppm) PhenoUcs ^one (ppm)
Mercury (Hg) _ I (Pb)-------
ONLY
Chromium-Hex (Cr+6)
Selenium (Se)-----------
CHEMICAL COMPOSITION (MUST TOTAL 100%)
Chloroethane
l -2~31%
Trichloroethwnp
|Q--1 1%
1.1.1 -IriAlnroethana ilQ=12%
Filter Cartridge
(25=63%
Silver (Ag)---------------i% Copper (Cu)_________ i% Nickel (NO__________ . i% Zinc (Zn)____________ i% Thallium (Ti)__
ii%
i% Other (Specify).
i____ i%
i%
i____ i% i____ i%
i% SL 021669
i%
ii%
I HEREBY CERTIFY THAT AU. INFORMATION SUBMITTED M THIS AND ALL ATTACHED DOCUMENTS IS COMPLETE AND ACCURATE. AND THAT ALL KNOWN OR SUSPECTED HAZARDS HAVE BEEN DISCLOSED.
i% PC/WSE
enscquseonly
./ TS^NAI
AUTHORBED
TURE*
`A' TITLE
/
H. DATE
HECamPtCAnON DATE
I
31-701
'ASTE ANALYSIS REPORT -..vironmental Laboratory
PPG Industries, Inc., Lake Charles, La.
ple:
Kation of Sample:
Sample Collector:
Product Still Bottom Filters. (VMDS-114940) Drums at HWSA. W. Cooper - G. Prejean
Sample Method/Device:
Random grab - hack saw
Date/Time of Sampling :
8- 7-90 1:10 pm
Date All Analyses Completed 9- 19-90
Report Submitted By: Date:
Gary Prejean 10-2-90
ANALYSIS RESULTS
Test Parameters
lenitabilitv ( 'y') N/A
Corrosivity
pH_____
( -'f N/A
mch/vr
Reactivity
( U N/A
TCLP Toxicity
( mg/L)
N/A
As Ba Cd
On_______ Pb
Hg Se
_______
Standard 140 F 2-12.5 0.250 max
Lab Log Sample No 1366
5.0 max
100.0 max 1.0 max 5.0 max 5.0 max 0.2 max 1.0 max 5.0 max
0.3
0,2 0.1 61.0 11.0 _ ND____
ND ND
Other Parameters (if needed) (^ N/A
N'D/none detected
CHLORINATED HYDROCARBONS (X)
Chloroethene
(VC)
Chloroethane
(EC)
Dichlormethane
(MeC12)
1.1-Dichloroethene
(VDC)
1,1-Dichloroethane
(DCE)
1,2-Dichloroethene Tricfoloromethane
(cis/trans) (CHC13 )
1,2-Dichloroethane
(EDO
1.1.1-Trichloroethane
(MC)
Tetrachloromethane
(CC14)
Trichloroethene
(Trichlor)
1,1,2-Trichloroethane
(TCE)
Tetrachlorethene
(Perchlor)
1,1,1,2-Tetrachloroethane (unsvm)
1.1,2.2-Tetrachloroethane (svm)
Pentachloroethane
(Penta)
para-Dichlorobenzene
(o-DCB)
Hexachloroethane
(HEXA)
Hexachlorobutadiene
(HCBD)
Unknown C1HC
Total C1HC
(X)
Disposal Method Profile No
WMDS - 114940
__________ Ensco__________
PCBs Heat Value Chlorine Water Densitv Ash Sodium
ppm
BTU/lb %
wt%
-
g/ml wt% wt%
bL 021670
*
^TST PROCEDURE
1
PARAMETER
j
METHOD USED
. . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . 1_ _ _ _ _ _ -_ _ __ _ ._ _ _ _ ._ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
LAB LOG NO. 1366 .
1 n i t a b 11 i t y ^ N/.-.
Pensky-Martens Closed Cup Tester ASTM Standard D-93-79
Setaflash Closed Cup Tester A5TM Standard D-327S-78
Other (Specify)
C orrosivity
: pH ) y n/a
____ SW-846 Method 9040 pH measurement
t
Other
j
(Specify)
Corrosivity i :nch/yr)
___ National Association of Corrosion Engineers Standard TM-01-69
Other (Specify)
Reac tiv i ty
^N/A
Jne affirmative answer will
lassif y asze reaclive)
1. Normally unstable without detonating? 2. Reacts violently with water? 3. Forms potentially explosive mixture with water?
Cyanide or sulfide bearing waste which can generate toxic gases, vapor or fumes under pH conditions between 2 and 12.5? 5. Capable of detonation or explosive reaction if subjected to strong initiating source or if heated under confinement? 6. Readily capable of detonation or explosive decomposition or
reaction at standard temperature and pressure? 7. Forbidden Class A, or Class B explosive as defined in
49CFR 173.51, 173.53, and/or 173.88?
SW 846
SW 846
SV1 846
Parameter Method Paramete: Method 1 'arameter M;thod
TCLP*
As
6010
AB
6010
PCB
LD-2571
N /A
Ba
6010
C1HC
5030
C1HC
LD-2562A
Cd
6010
Sodium 3050.6010 Heat Value LD-2562B
Cr
6010
pH
9045
Chlorine LD-2562D
Pb 6010
Water
LD-2566
H.g 7470
Ash
LD-2561
Se 6.010
`Tonicity Characteristic Leaching Procedure
LABORATORY IDENTIFICATION
Laboratory: PPG Lake CharlesTest Parameters Analyzed
Analyst!s): SGS Labs
TCLP metals
8-27-90
TCLP volatiles
9-1-90
TCLP semi-volatiles 9-19-90
and
Date
6^ 0*2.^
iQirjMaM6Si6i*iQi*iGitiQiiQni<ii<sQiiiGt<iai*ias*iai>iari8tQMa>iai*iai*iQt|
SGS Environmental laboratories
98-^6
l
QS
s
RESULTS - sample XDt 1366 Product still Bottom Filters SGS IHi E9008-46-6
TCLP Metals I
i
Date Extracted! 8/18/90 Concentration in ppm (mg/L) In TCLP Extract
I
l
Date Analyzedi a/27/90
I
I
Method
s
EPA HW
TCLP Metals
Result
Blank
Detection Limit
iI
D004
Arsenic
0.3 HD
0.2
i
D00S
Barium
D006
Cadmium
D007
chromium
D008
Lead
D009
Mercury
0.2 0.1 61
11 HD
HD HD HD
HD ND
0.02
0.03 0.04
0.1 0.0002
i
01
i
D010
Selenium
HD
HD
0011
Silver
HD ND
0.2 0.02
S
HD denotes Not Detected at a level above the method detection limit.
i
t
SL 02l6?2
8 Momeer of the SOS Group iUum etneow m
S
?sas**astassassas*sQ8*eas'sas*sas*sastas*sai*sassa3*taasaitatsas*QS*eQSsas*sa8T
80S Environmental Laboratory*
9008-038
i
RESULTS - TCLP TOXICITY V0LATILE8 SOS ID I 89008-046-6
PPG IDi 1366 Product Still Bottom riltere Data Extractadi 8/28/90 Date Analyzedi 9/01/90
Concentration In ppb (u?/L) :.n TCLP Extract
*
i i
Benzene
Method 1366 Product Still Detection
Bottom filters __ Limit
NO 500
TCLP Blank
ND
Blank Dataction
Limit
5.0
i
s
i Carbon Tetrachloride
30,S36
500
ND
5.0
i
Chi robenzene
ND 500 ND 5.0
i
i Chloroform
1,500
500
ND
5.0
i 1,4-Dichlorobenzene
I
i
1,2-Dichloroethane
i
i l,l-Dlchloroethylene
Metbylethylketone
! Tetrachloroethylene
Trichloroethylene
Vinyl Chloride
NO NO 7,400 ND NO 2,50# ND
500 500 500 1000 S00 500 1000
ND 5.0
ND 5.0
ND 5.0
SND 10.0
ND 5.0
8ND 5.0 A
ND
10.0
8
Surrogate Standard Percent Recovery (at 0.0S0 me/ L}
1,2-Dichloroethane-d4 Toluene-d8 4-Broaofluorobenzene
1366 Product Still aow Fmtri
95 4 108 \
97 t
aitnL
98 * 101 % 112 %
SL 021673
A
o
:
ND den tee Hot Detected et e level efaeve the method detection limit.
I Member at the 008 Crouc <smmm oa+m at avn*tMi ataas<aa*aQ8*tQa*Ga* as>aat*aaaaa8aast<i8*8as*8Q8*aca*iasaassos*tQa*ao8*tai1
i
i
0 8QS Environmental Laboratory
i
5 RESULTS - TCLF TOXICITY SEMIV0LATILE8 SGS IDi E9008-046-6
i! PPG ID 1366 Product still Bottom riltare
E9008-038
8
! Date Extracted! 9/18/90 Date Analyzed! 9/19/90
} Concentration In ppb (ug/L) In TCLP Extract
3
f
1366 Product Still Bottoa Flltera Blank
Method Detection Llttit
o-cresol
NO ND
10.0
a-cresol
<9
*
p-oresol
Creeol
ND ND 10.0
ND ND
10.0
ND ND 10.0
2,4-Dlnltrotolutne
NO
ND
10.0
p Hexachlorobenzene
ND
NO
10.0
Mexachlorobutadiene
ND
ND
10.0
Hexachloroethane ND ND 10.0
Nitrobenzene
ND ND 10.0
Pentaohlorophenol
ND
ND
50
Pyridine
ND ND 10.0
2 , 4,5-Trichlorophenol
ND
ND
10.0
2,4,6-Trichlorophenol
ND
ND
10.0
Surrogate Standard Percent Recovery fat 0.200 nci/L)
1366 Product Still Bottoe Flltera
lUhK
2-Fluorophenol
Phenol-dS 2,4,6-Tribro*ophenol Nltrobenzene-dS
2-Fluoroblphenyl Terphenyl-di4
12 % 10 % 32 \
38 X 41 \ 18 %
:.4 \ .5 % :u %
28 % 33 % 11 %
021&7J SL
ND denotes Not Detected at a lev 1 ab ve the v ih d detect! n Halt.
I Member of the Ml Qroue
r0Of0Q--000*000*O0*Q*Oa*Q0*Q0*O8*eO8*O*O*Oa*O*>O0OO0*Qa 000' Ot*0Q8*$O$V
31-701
*ASTE ANALYSIS REPORT . .vironmental Laboratory PPG Industries, Inc., Lake Charles, La.
^pnple:
Location of Sample: Sample Collector:
Recycle Still Bottom Filters. (WMDS -114940) Drums at HWSA. W. Cooper - G. Prejean
Sample Method/Device: Date/Time of Sampling
Random grab - hack saw 8-7-90 1:20 pm
Date All Analyses Completed: 9-20-90
Report Submitted By: Date:
Gary Prejean 10-2-90
ANALYSIS RESULTS
Test Parameters
Ianitability ( ,y\ N/A
Corrosivity
PH______
( 'A N/A
Lnch/vr
Reactivity
( A N/A
As
TCLP
Ba
Toxicity
Cd
(mg/L)
Cr
Pb
N/A
H_g Se
M_______
Standard 140 F 2-12.5 0.250 max
5.0 max 100.0 max 1.0 max 5.0 max 5.0 max 0.2 max 1.0 max 5.0 max
0.9 0.4 0.2 76.0 16.0
ND
ND. ND
Lab Log Sample No 1367
Other Parameters (if needed)
y tA N/A
ND/none detected
CHLORINATED HYDROCARBONS (X)
Chloro^thene
(VC)
Chloroethane
(EC)
Dichlormethane
(MeC12)
1,1-Dichloroethene
(VDC)
l_i 1-Dichloroethane
( DCE )
1,2-Dichloroethene
(cis/trans)
Trichloromethane
(CHC13 )
1,2-Dichloroethane
(EDC)
1.1.1-Trichloroethane
(MC)
Tetrachloromethane
(CC14)
Trichloroethene
(Trichlor)
1,1,2-Trichloroethane
(TCE)
Tetrachlorethene
(Perchlor)
1,1.1,2-Tetrachloroethane (unsvm)
1 , 1,2,2-Tetrachloroethane (svm)
Pentacl>loroethane
(Penta)
para-Dichlorobenzene
(p-DCB)
Hexachloroethane
(HEXA)
Hexachlorobutadiene
(HCBD)
Unknown C1HC
Total C1HC
(X)
Disposal M thod___________________________________ Profile No ____________ E_n sco
PCBs Heat Value Chlorine Water Density Ash Sodium
ppm
BTU/lb %
wtX
.
R/ml wt% wtX
------ SL 02 1675 WMDS - 114940
TEST PROCEDURE
LAB LOG NO. 1367
PARAMETER 1 gmtaoi i ity
A
METHOD USED
Pensky-Martens Closed Cup Tester ASTM Standard D-93-79
Setaflash Closed Cup Tester ASTM Standard D-3278-78
Other
1 1
(Specify) j
orrosivity .pH ) /A
SW-846 Method 9040 pH measurement
Other (Specify)
"orrosivity ( mch/yr ) s%/A
___ National Association of Corrosion Engineers Standard TM-01-69
Other (Specify)
Reactivity
'*4/A
hie -i11 iraiative answer will classify waste reactive)
1. Normally unstable without detonating? 2. Reacts violently with water?
3. Forms potentially explosive mixture with water? 4. Cyanide or sulfide bearing waste which can generate toxic
gases, vapor or fumes under pH conditions between 2 and 12.5? 5. Capable of detonation or explosive reaction if subjected to strong initiating source or if heated under confinement? 6. Readily capable of detonation or explosive decomposition or
reaction at standard temperature and pressure? 7. Forbidden Class A, or Class B explosive as defined in
49CFR 173.51, 173.53, and/or 173.88?
TCLP* N/A
"Toxicity
Parameter
SW 846
SW 846
SV1 846
Method Paramete] Method 1 Parameter Mesthod
As Ba Cd Cr Pb He Se Characteristic
6010
A
6010
ClHC
6010
Sodium
6010 6010
dH
7470
6010 Leaching Procedure
6010 5030 3050.6010 9045
PCB ClHC Heat Value Chlorine Water Ash
LD-2571 LD-2562A LD-2562B LD-2562D LD-2566 LD-2561
LABORATORY IDENTIFICATION Laboratorv: PPG Lake Charles Analvst(s): SGS Labs
Test Parameters Analyzed and Date
TCLP metals
8-27-90
TCLP volatiles
9-1-90
TCLP semi-volatiles 9-20-90
O^6
lOAWaa^usttaitiaitMMQMQtiiQi'iGKtaitiaMaitsaMOMQiKiQKsaitiQiioitMi^ot!
SGS Environments Laboratories
E9668-646
RESULTS - Sample H}> 1367 Recycle Still Bottom Filters SGS S31 E9888-46-7
TCLF Metals
Date Extracted* a/18/96 Date Analyzed* 8/27/96
Concentration in ppm (mg/L) In TCLF Extract
gftHB
TTT.P Mstsls
ResuJ,;
Blank
Method
D684 D665 D006 D667 D668 D669
D616 D6U
Arsenic Barium Cadmium Chromium Lead Mercury
Selenium Silver
6.9 6.4 8.2 76 16 ND
ND ND
ND ND ND ND ND ND
ND ND
8.2 6.62
8.63 6.64 6.1 8.6662
8.2 6.82
ND denotes Not Detected at a level above the method detection limit.
V
!
o m
iT<e
s i
8
611 0*iv
0 Member of the 108 Group inmn hm m imwmnd
u
Mi*iQi*iQit6ai4QMai4ai*iai*iaiQt*iQiiMtiQMiNi*iai*iai(io*aas(iaiiQt*oiV
ISKi U4QMOSIOI*iai*NI*taS*IOI*iaaiQ|*QI<OI*IOI*M
^1
8G8 Environmental Laboratorlaa
59008-938
RESULTS - TCLP TOXICITY VOLATILES 30S ID. E9008-046-7 PPG 10i 1367 Recycle Still Botton Filters Date Extracted! 8/28/98 Date Analyzed! 9/81/98
Concentration In ppb (ug/L) :.n TCLP Extract
Method
1367 Reaycle Still Detection
Botton Filters
Limit
Benzene
ND 1250
Carbon Tetrachloride
5,758
1250
Chlor benzene ^Pilorofora
HD 1250 ND 1258
1,4-Dichlorobenzene
ND 1250
1,2-Dlchloroethane
ND 1258
1,1-Dlchloroethylene
4,008
1258
Methylethylketone
ND 2500
Tetrachl roethylene
ND 1250
Trichloroethylene
3,500
1250
Vinyl Chloride
ND 2500
TCLP Blank
ND ND ND ND ND ND ND ND NO ND ND
Blank Detection
Limit 5.0
5.0 5.0 8.0
5.0 5.0 5.0 10.0 5.9 5.0 10.0
1,2-Dichloroethane-d4 Toluene-d8 ^4-Br noluorobenzene
(at 8_.858 aa/U
1367 Recycle Still ftflwa,, nism
95 % 94 89 %
sinus.
96 % 181 \ 112 %
* *1*
NO denotes Not Detected at a level mb ve the aethod detection Halt
Mwemuo--e orf me M--*el Gwroouup himmmmi eapwiaMn Mm lunWWMi'
w
KUaaa*0asaas*asaa8aaa*aa8aoa*aa8*aaa*ao8*8Gt*aaa*adtsaaeeas oe*eaeoa*eaeeatv
iiaitiaiiGi*ia*ias4Qiis(U*iGs6i*iai*i6itaitiai*iaiuai*a8MMMi*MiMi*iQi
E9008-038
$
SGS Environmental Uboratorte
RESULTS - TCLP TOXICITY SEHIVOLATILES
SGS IDi E90O0-046-7
PPG ISi 1367 Recycle Still Botton Filters
Date Extracted* 9/19/9G
l
j1 Date Analyzedi
9/20/90 Concentration In ppb (ug/i) in TCLP Extract
1367 Reccyle Still
Method
o-creeol
B9t*ga-11$4C1 HO
aim* NO
Detection-Limit 10.0
\
a-creeol p-creeol Cresol
NO NO
10.0
A
:NO
NO
10.0
o
NO NO 10.0
2,4-Dinitrotoluene
NO
NO
10.0
Hexachlorobenzene
NO
NO
10.0
Hexachlorobutadiene
NO
NO
10.0
Hexachloroethane NO NO 10.0
Nitrobenzene
23 NO 10.0
Pentachlorophenol
NO
NO
50
3 Pyridine
34 NO 10.0
i 2,4,5-Trichlorophenol
NO
NO
10.0
2,4,fi-Trichloropbenol
NO
NO
10.0
Surrogate standard Percent Raccverv <at 0.200 nc/L)
1367 Recyele Still Bottoa F11tare
SlinK
! 2~Fluorophenol Phenol-d5 2,4,6-Tribronophenol Nitrobenzene-d5 2-rluorobiphenyl Terphenyl-dl4
21 % 18 % 110 4 42 % 26 4 43
14 4 15 4 31 4 28 4 23 4
<1 4
O^679 SL
NO denotee Not Detected at a level abov th aeth d detect! n Halt
3 Mocwbf of tho eoa GfOUO (MaM * m Imuiwoii
j
?MS4aMai*iMiamu*iaii6oiiat*Q8*aai as*sataaaaas>i aa*sai*aa*aas*aQt*aatacM
J 1-701
'ASTE ANALYSIS REPORT *..ivlronmental Laboratory
PPG Industries, Inc., Lake Charles, La.
^^iple:
MC Product Filters. (WMDS-114940)
Location of Sample:
Drums at HWSA.
Sample Collector:
W. Cooper - G. Prejean
Sample Method/Device:
Random grab - hack saw
Date/Time of Sampling :
8*7-90 1:25 pm
Date All Analyses Completed 9-20-90
Report Submitted By: Date:
Gary Prejean 10-2-90
ANALYSIS RESULTS
Test Parameters lanitability ( ^) N/A
Corrosivity
eh_____
( -0 N/A Reactivity
Lnch/vr
is/) N/A
As
TCLP
Ba
Toxicity
Cd
(mg/L)
Cr
Pb
N/A
Hg
Se
Aa
Standard 140 F 2-12.5 0.250 max
Lab Log Sample No 1368
5.0 max 100.0 max 1.0 max 5.0 max 5.0 max 0.2 max 1.0 max 5.0 max
ND ND 0.1 3.7 6.2 _ ND____ ND ND
Other Parameters (if needed) {/) N/A
ND/none detected
CHLORINATED'HYDROCARBONS (X)
Chloroethene
(VC)
Chloroethane
(EC)
Dichlormethane
(MeC12)
1,1-Dichloroethene
(VDC)
1,1-Dichloroethane
(DCE)
1,2-Dichloroethene
(cis/trans)
Trich4oromethane
(CHC13)
1,2-Dichloroethane
(EDC)
1,1,1-Trichloroethane
(MC)
Tetrachloromethane
(CC14)
Trichloroethene
(Trichlor)
1,1,2-Trichloroethane
(TCE)
Tetrachlorethe.ne
(Perchlor)
1,1,1.2-Tetrachloroethane (unsvm)
1,1,2,2-Tetrachloroethane (svm)
Pentachloroethane
(Penta)
para-Dichlorobenzene
(o-DCB)
Hexachloroethane
(HEXA)
Hexachlorobutadiene
(HCBD)
Unknown C1HC
Total C1HC
(X)
Disposal Method,,Profile No
WMDS - 114940
_____________ Ensco__________
PCBs Heat Value Chlorine Water Density Ash Sodium
ppm
BTU/lb %
wtX
.
a/ml wt% wtX
i
ct O21680 _
"ESI PROCEDURE
IAB LOG \0. i3 H 8
11
PARAMETER
METHOD USED
I enit abi1 itv
A
cirrciiv: y P-'i
nca
jrrosivity 1 mcn/yr )
.A/A
Pensky-Martens Closed Cup Tester ASTM Standard D-93-R9
SW-846 Method 9040 pH measurement
Setafiash Closed Cup Tester ASTM Standard E-3278-78
__.Xational Association of Corrosion Engineers Standard TM-01-69
Other (Specif y)
Other (Specify)
l
Other (Specify)
Reac 11\ i t y
v/\/A
! One 5. r' f _ rma 11 \ e answer ''ill cla s sify vast reac tivei
1. Normally unstable without detonating? 2. Reacts violently with water? 3. Forms potentially explosive mixture with water? 4. Cyanide or sulfide bearing waste which can generate toxic
gases, vapor or fumes under pH conditions between 2 and 12.5?
5. Capable of detonation or explosive reaction if subjected to strong initiating source or if heated under confinement?
6. Readily capable of detonation or explosive decomposition or reaction at standard temperature and pressure?
7. Forbidden Class A, or Class B explosive as defined in 49CFR 173.51, 173.53, and/or 173.88?
SW 846
SW 84 6
SW 846
Parameter Method Parameter Method Parameter Method
TCLP*
____ XI:
As
6010
_Ag_
6010
PCB
LD-2571
Ba
6010
C1HC
5030
C LHC
LD-2562A
Cd
6010
Sodium 3050.6010 Heat Value LD-2562B
Cr
6010
-PH.
904 5
Chlorine LD-2562D
Pb .6010
Water
LD-2566
He 7470
Ash
LD-2561
Se 6010
*Tox:city Characteristic Leaching Procedure
LABORATORY IDENTIFICATION
L ; bo rat orv : PPG Lake CharlesTest Parameters Analyzed
malvst(s):
{}S Labs
TCLP metals
8-27-90
TCLP volatiles
9-1-90
TCLP semi-volatiles 9-20-90
and
Date
l
SG8 Environmental Laboratories
E9008-046
i
&
?
RESULTS - Saapla IDi 1368 MC Product Filter! SGS IDi E900B-46-8
TCLP Metals
Data Extracted* 8/18/90 Data Analyzedi 8/27/90
Concentration in ppa (ag/L) in TCLP Extract
EPA HW
TpLP Metals
Result
Blank
Method OairsTrm Til alt
D004 D009
D006 007 D008 D009
D010 D011
Araenic Bariua Cadaiua Chromium
Lead Mercury Selenlua Silver
ND ND
0.1 3.7 6.2 ND
ND ND
ND ND
ND ND ND ND ND ND
0.2 0.02 0.03 0.04
0.1 0.0002
0.2 0.02
ND denotes Not Detected at a level above the aethod detection limit.
SL 021682
Momtoor of mo tot Qrouo (bhmo omw* m oummmi
5
L*MHQieaMomaeai a8*8aio8aa*as*aoaoeas*8aa*aotiaa*8oa*8ot8a8oaQa*eo8*80BT
L6i*soi*tai*ias'iai*tQi<iQi*iQs*iai*iasioi*Qi*iQBa8tsai<tii*iaMat*iQMMMa*otA
i
U
fa>t
SOS Environmtntal Liboratorlee
9008-038
2
RESULTS - TCLP TOXICITY VOLATILES
i? SSS IDi 28008-046-8
PPG IDt 1368 MC Product Filters
8
S
3
?
Date Extractedi 8/28/90
Date Analyzed! 9/01/90
8
Concentration in ppb (uy/L) In TCLP Extract
1368 MC Product Filters
Method
Detection Limit
TCLP Blank
Blank Deteotlon
- Lin!
ma Benzene Carbon Tetrachloride
ND 250 ND 5.0 ND 250 ND 5.0
Chlorobenzene
ND 250 ND 5.0
Chloroform
ND 250 ND 5.0
1,4-Dichlorobsnzene
ND 250 ND 5.0
1,2-Dichloroethane
ND 250 ND 5.0
l,l-Dlehloroethylene
13,800
250
ND
5.0
Hethylethylketone
ND 500
ND 10.0
Tetrachloroethylene
320 250 ND 5.0
Trichloroethylene
ND 250 ND 5.0
vinyl Chloride
ND 500
ND
surrogate Standard-Percent Recovery (at 0.050 JUMd.
i10.0
1368 MC Product niters
BltftK
l, 2-Dichloroethane-d4 Toluene-d8 4-Bronofluorobenzane
94 %
97 %
98
9(> %
101 t 111 %
S^
ND denotes Hot Detected at a lev 1 above the method deteotlon limit.
Member oi the 600 Group '(19eMeOQOoa8*6G86<IS*06W*8Q8*6Q8*IQ8e>G8e8Q8e8G8eOQ$e0a8*hG8*0Q8*8GS*O8*8Q8*8Q8oSG8l
;lQ|ita*IQI>CII*8ai*lQS*SQMQl*IQI*IQ|t|Q*IQI*iai'iaiIQI*|fll*MI*iai*$GMQ>*aai*ia9
m
3G8 Environmental Laboratorlaa
9088-838
a f
RESULTS - TCLP TOXICITY SEMIVOLATILES
i 3GS ID: S988S-846-S
i
PPG id I 1368 MC Product Filters
Date Extracted! 9/19/98
Date Analyzed! 9/28/90
i Concentration in ppb (ug/L) in TCLP Extract
o-creeol
1368 MC Product Filter.
ND
aim* ND
Method Detection Limit
18.8
i
S
e-cresol
ND ND 18.8
p-cresol
ND ND 18.8
3 Cresol
ND ND 18.8
i 2,4-Dinitrotoluene
ND
ND
18.8
! Hexachlorobentene
ND
ND
18.8
Hexachlorobutadiene
ND
ND
18.8
Hexachloroethane
ND ND
18.8
a Nitrobenzene
f
ND ND
18.8
3 Pentachlorophenol
ND
ND
58
8
i Pyridine
ND ND 18.8
3 2,4,5-Trichlorophenol
ND
ND
18.8
2,4,s-Trichlorophenol
ND
ND
18.8
Surrogate Standard Percent Recovery ( HL 8.288 ma.'L)
1368 MC Product, Filter*
Slunk
2-Fluorophenol
Q Phan 1-dS 2,4,6-Tribromophenol Mltrobanzene-dS 2-Fluorobiphanyl Terphenyl-dl4
118 % 57 \
99 \ 32 % 38 % 21 \
14 % i!i % 3:. \
2 IS \ 33 % 41 %
I
i
e A
o 0^
ND denotes Not Detected at a level ab ve the aeth d detection Unit.
3i Member or me SOS Oroue
8
?soa*sosSGS*ta&*fias*sasSQSsassas*sas>8asSQSsassa8sas*s<3s sosSQ8*8088assas*8asi