Document QXxkKXe66vRZmm789oEVJ1D4v

fatDCHEMICAL MANUFACTURING CO. KnlC vum off'cc anq plant: ct-cvcuANo. onto <411 WSM W K|M<wne MAddNtxioa GS741 MATERIAL SAFETY DATA SHEET L lOEt4TimCA7\ON Ntrrw; ALLSTATES SS-261 SOLUBLE CUTTING OIL TyptM WATER SOLUBLE CUTTING OK D.O.T Shipping Nam*mot aapicabu (n/aj Hazard Claaa: h/a 10 NO.: NOT AfPUCABl(WA) Label: none required II. HAZARDOUS. INGREDIENTS Material Weight HYDROTREATEO HEAVY NAPHTHENIC <30% PETROLEUM DISH.LATE (CAS *64742.62-6) HYDROTREATED LIGHT NAPHTHENIC <HK PETROLEUM OWTLLATE (CAS *64742-6S6) ux SMG/M^ SMG/M3 PHYSICAL DATA Hog Point (F*)3oo-4oof >dflo Gravity (Watersl)s^7i atile By Weight (%)?*gugable JqM Par Gallon; (pounds)j^i pounds lublllty In WaterxusPERsiBLE iX/A pearance & Odor* dark brown louid with a oi-lke oooa . FIRE & EXPLOSION HAZARD DATA sshpolnt (F> (Method UsmQvlbove 2mf totingulaWng MediaxARBON dioxide, dry chemical or foam Special Rre Rghtlng Procedures same as any oi. base proouct Unusual Firs & Explosion Hazards: none V. HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE^hoouct can irritate eyes ANO SKM CHRONIC HEALTH EFFECTS: chronic exposure to petro leum distillates may cause effects to central nervous system, kidney and uvea FIRST AID PROCEDURES: If Swallowed: do not induce vomitno. contact a phscian. If Inhaled: wa InIf EyesTLusH eyes immediately with plenty of cox water for at lest is minutes, if fritation persists, contact a physician. If On Skin: wash thoroughly with soap ano water, f fr/tatjon oeyel- S. CONTACT A PHYSICIAN YL REACTIVITY DATA Stability: stable Condttlona to AvoldaoNE INCOMPATIBILITY (Malaria* rold>3TRONO OXIDIZINO AGENTS SUCH AS CHROMC ACID. HYDROGEN PEROWOE ANO BROMINE Hazardous Decomposition Products: carbon monoxide, oxides of SULFUR HAZARDOUS POLYMERZAWOH WILL NOT OCCUR V1L SPILL OR LEAK PROCEDURES Steps To Be Taken If Material Is Released Or Spilled: stop leak. CONTAIN LARGE SPIL9 ANO RETURN TO CONTAINER. USE Ofc. ABSORBENT MATE RIAL FOR CLEAN UP. Waste Disposal Method! bury in an approved landfill dump, this PROOUCT IS NOT A HAZARDOUS WASTE AS FORMULATED. Follow All Fadaral, Slaw and Local Regulation* Regarding Waata Dlapoaal Vl: SPECIAL PRQTECnQN INFORMATION: Ey* protection and protoclNw glov*a aro racommandod any tjma your work with any concentrated Industrial etrangth claanlng product*. Respiratory Protection: none required under normal conditions Ventilation: normal room ventilation Protective Gloves: recommended (rubber) Eye Protection: safety glasses Other Protective EquIpmentaoNE reouired. IX. SPECIAL PRECAUTIONS: Precautions To Be Taken In Handling Storage: store n a cool, DRY PLACE. KEEP FROM FREEZING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. AVOID CONTACT WITH EYES. OTHER PRECAUTIONS: HMIS RATING: HEALTH 1 FLAMMA8ILJTY1 PERSONAL PROTECTION B REACTIVITYO Read and follow all label directions and precautions before using the product These products are Intended for Industrial and Institutional use only. Not Intended for householduse or resale. KEEP OUT OF THE REACH OF CHILDREN While we believe that the data contained herein is factual and the opinions expressed are those of qualified experts, the data are not to be taken as a warranty or representation for which the company assumes legal responsibility. They are offered solely for your consldoration, Investigation, and verification. Any use of these data and Information must be determined by the user to be In accordance with applicable Federal, Stale, and Local laws and regulations. HEALTH AND SAFETY INFORMATION (216) 861-7114 MAY 1990 SAL 000009665 JfLSLsl ----- Cconoco) , Information Conoco Inc. Purchase Requisition Page of Shaded Areas RQ Loc Requisition No. A CD for Purchasing Dept. Use Only 316 264334 Priority RLOC Department REB Refining ) Ship' u^<L Ship Date Req'd at Dest. Order Previous P.O. Via Type NORM Tagging Instructions STATE CHEMICAL Attn: F.O.B. Point Freight Terms a- -v. Conoco Inc. Carrier Refinery Warehouse Old Spanish Trail P.O. Box 37 Project ID ** * - 'k' --a,--. Clauses Westlake, LA 70669 Payment Terms AFE Reporting 600-762-2436 TOM Requisitioner Date 316-491-5W SUE ANDEKSON 06-2S-90 Tax Status Special Instructions Charge Exempt R% Distribution Charge 74ll-3-0->t52-03-30 -t t . i "icke. Date Control W.O Equip. NO Time Time Init. sut Ordered Req'd Unit Code Date Required LUCo-uO-^O ') < Z*tQ StOCk NO. Description iULJ l*Ll 1.4 .iCLTC -lU____ 1 ________________ 74 Hem NO. - Quantity Ordered -- ALLSTATE SOLO!ABLE OIL SS261 CUM*i Mil OTT. b GAla OONTAUiEHS 1 Units of Issue crran Qty. issued y, hui.iS CONPlRhiJfG GRHEH ANDF.ft.sfJk Tm KTi'rl?( Trail rn w.<, mra (____________ A ____________________________________________ * ' //V/?v2* _P >0 -fh y -- ?? /% ^V1 c S^^c/7 a. Appi Operating De{ 4y/yu^ < -166 X8. 11-86 Approval - Purchasing Dept. SAL 000009666 material safety data sheet COOL PREP PAGE : Ol (006339-0157P -E002163B-4295 )!DATE Of ISSUE 01/26/90 SUPERSEDES 01/26/90 SECTION I - GENERAL INFORMATION CHEMICAL NAME A SYNONYMS N/A CHEMICAL FAMILY N/A TRADE NAME 6 SYNONYMS COOL PREP FORMULA A<--MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH DIV. OF NCH CORF. ADDRESS < NUMBER. STREET. CITY. STATE & ZIP CODE 1 BOX 152170 IRVING, TEXAS 75015 RREPAREO BY: KELLY 5EALS/T.S.CHEMIST | PRODUCT CODE NUMBER | EMERGENCY TELEPHONE NUMBER 4295 2 14-438 -1361 SS742 SECTION 11" HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) J HAZARD { TLV- NO HAZARDOUS INGREOI ENTS PER 29 CFR 1910.1200(0) | PEL* AS* SECTION 11A - NON-HAZARDOUS INGREDIENTS NGN -HaZA RDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NU TRADE SECRET REGISTRY * 409363-S171P COOL PREP SECTION III - PHYSICAL DATA PAGE : 02 BOILING PT.(FAHRENHEIT) 1212 r. VAPOR PRESSURE (MM HG) . ! i7 I SPEC GRAVITY (H20-1) | COLOR WATER-WHITE VAPOR DENSITY (AIR-1) (0.6 j ODOR LOW PH P 100% PERCENT. VOLATILE BY VOLUME (%> 16.3-6.5 1 |50 1 ; 1 CLARITY TRANSPARENT EVAPORATION RATE 10.10 <eu ac - i ) ; SOLUBILITY IN WATER 1 COMPLETE VISCOSITY } NCN-VISCOUS 1.12 SECTION IV - FIRE ANO EXPLOSION HAZARD FLASH POINT (METHOD NON-FLAM EXTINGUISHING MEDIA <-- FOAM USED) ALCOHOL" <"-FOAM j FLAMMABLE LIMITS i X<--C02 DRY X<--CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES N/A J , LEL J N/A WATER <--SPRAY ; UEL 'N/A <--OTHER UNUSUAL FIRE & EXPLOSION HAZARDS N/A NFPfi HAZARD RATING (0-I NS IGMFICANT. 1SLIGHT:2-MODERATE;3-HlSH:4-EXTREME): O <--HEAL TH O < *FLAMMAS ILIT V O <--PEACTI VI TV C--SPEC1AL SECTION V - HEALTH HA2ARQ DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II. EFFECTS OF OVEREXPOSURE - ACUTE - ( SHORT TERM EXPOSURE) DIRECT CONTACT WITH EYES MAY CAUSE IRRITATION. 96&7 SAL oo0 GS 7 42 (CONTINUED) COOL PREP SECTION V * HEALTH HAZARD DATA RAGE 03 - CHRONIC " (LONG TERM EXPOSURE) DIRECT-CONTACT WITH EVES FOR PROLONGED PERIOD OF TIME MAY CAUSE IRRITATION AND REDOENING. PRIMARY ROUTE OF ENTRY; <-- INHALATION EMERGENCY & FIRST AID PROCEDURES INHALATION ; NOT A HAZARD. <-- INGESTION X<-- ABSORPTION "................. EYE CONTACT: FLUSH EYES WITH PLENTY OF WATER FOR S-1 MINUTES. IF ANY IRRITATION PERSIST. ................................................ SEEK MEDICAL ATTENTION SKIN CONTACT: NOT NORMALLY A HAZARD. RINSE OFF WITH SCA=> AND WATER. INGESTION : IF SWALLOWED. DRINK TwC GLASSES OF WATER. OCCURS NOTES TO PHYSICIAN ; SEE A PHYSICIAN IF DISCOMFORT SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY; I ARC <--YES NTP <--YES OSHA <--YES ACGIH <--YES OTHER <--YE5 X<--NO X<--NO X<--NC X<--NO X < --NO N/A SECTION VII - REACTIVITY DATA STABILITY j X< - - ST ABLE <--UNSTABL [ CONDIDTIONS TO AVOIO |----------------------------------------------------------------------------------------- -.............................. N/A INCOMPATIBILITY (MATERIALS TO AVOID) N/A HAZARDOUS DECOMPOSITION PRODUCTS OXIDES OF NITROGEN HAZARDOUS ! WILL NOT ] X <--OCCUR polymerization! ! N/A MAY <--OCCUR [ CONDITIONS TO AVOIO ( COOL PREP SECTION VIII - SPILL OR LEAK PROCEDURES PAGE : 04 STEPS TAKEN IN CASE MATERIAL is released or spilled flood surface with plenty of water AND flush DOWN ORAIN. waste disposal method DISPOSE OF IN ACCORDANCE WITH STATE. FEDERAL. AND LOCAL REGULATIONS CONCERNING HEALTH POLLUTION. NEUTRALIZING AGENT N/A section ix - special protection information REOUIRED VENTILATION N/A RESPIRATORY PROTECTION TYPICAL USE OF THIS PRODUCT DOES NOT REOUtRE RESPIRATORY PROTECTION. PROTECTIVE GLOVES N/A EYE PROTECTION TYPICAL USE OF THIS PRODUCT DOES NOT REOUIRE USE OF EYE PROTECTION. OTHER PROTECTION N/A SECTION X - STCRAGE AND HANDLING INFORMATION STDRAGE TEMPERATURE ! INOOOR 120 F.<'-MAX 32 F.<--KIN | X jIHEATED PRECAUTIONS TO BE TAKEN IN HANOLING & STORING STORE AT MODERATE TEMPERATURES. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL BEFORE USING. (J REFRIGERATED!|x OUTDOOR SECTION XI - REGULATORY INFORMATION (PENNSYLVANIA RIGHT-TO-KNOW REQUIREMENT: NON-HAZAROOUS INGREDIENT NAMES ARE WITHHELO AS A TRADE SECRET) SAL 000009668 (CONTINUED) COOL PREP SECTION XI - REGULATORY INFORMATION PAGE ; OS CHEMICAL NAME C.A.S. NUMBER UPPER X LIMIT N/A THOSE INGREDIENTS LISTED ABOVE ARC SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT. END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK. OR THE PRODUCT IS USED ANC LABELED FOR FACILITY GROUNOS MAINTENANCE (SUCH AS FERTILIZERS AND HERBICIDES), OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES. GS?42 SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--lMCC SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER OOT SPS CONTAINER AEROSOL PROPELLANT(S) C--TARIFF 6 0 <--IATA <--MILITARY AIR <AFR 71-4) ! ID NUMBER i REPORT OTY ! LIMITED OTV { NET EXPLOSIVE WT . N/A SECTION XIII - REFERENCES COOL PREP (CONTINUED) SECTION XIII - REFERENCES PAGE : 06 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER. NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TC BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH CORP. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PRODUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENOED USE. STORAGE. OR OISPOSAL OF THE PRODUCT. SAL 000009669 MATERIAL. SAFETY DATA SHEET (O0633S-0157P -002*638-4297 COOL SHIELD 01/26/90 FADE : 01 SUPERSEDES 01/26/90 SECTION : - GENERAL INFORMATION CHEMICAL NAME 6 SYNONYMS N/A TRADE NAME 6 SYNONYMS COOL SHIELD CHEMICAL FAMILY ALKALINE RADIATOR TREATMENT FORMULA X<--MIXTURE MANUFACTURERS NAME NATIONAL CHEVSEARCH CIV. CF NCH CORe ADDRESS 1 NUMBER, STREET. CITY. STATE & ZIP CODE) BOX 152170 IRVINS. TEXAS 75015 PREPARED BY: KELLY SEALS/T.S.CHEMIST ! PRODUCT CODE NUMBER | EMERGENCY TELEPHONE NUMBER 429T 214-438-1381 GS743 SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT 8EN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) ! HAZARD SODIUM 2--MERCAPTOBENZOTHIAZOLE IRRITANT TLV NOT EST. | PELNOT EST. CAS* 2492-26-4 SECTION 11A - NON-HAZAROOUS INGREDIENTS NON-HAZARDOUS INGREDIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NO TRADE SECRET REGISTRY 409363-5136P SECTION III - PHYSICAL DATA (CONTINUED) COOL SHIELD SECTION III - PHYSICAL DATA BOILING PT. <FAHRENHEIT ) VAPOR PRESSURE (MM HG . VAPOR DEN5ITY <AIR*1> PH 100% PERCENT. VOLATILE BY VOLUME (%) SOLUBILITY IN WATER VISCOSITY ! 220 I\ 1 1 | SPEC GRAVITY (H20-1) 1 1 COLOR lt ODOR PURPLE LIGHT r1.11 !13-0 1 it ! CLARITY OPAQUE I it EVAPORATION RATE (BU AC 1 ) [0.10 ; | COMPLETE | WATER-LIKE PAGE : 02 SECTION IV - FIRE ANO EXPLOSION HAZARD FLASH POINT (METHOD USED) N/A EXTINGUISHING MEDIA ALCOHOL' <--FOAM <--FOAM j FLAMMABLE LIMITS 1 <--C02 DRY C--CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES N/A ! LEL !n/a WATER <--SPRAY ! UEL |N/A <--OTHER UNUSUAL FIRE & EXPLOSION HAZARDS N/A NF eA HAZARD RATING <0I NS IGNIFI CANT; 1 SLIGHT:2"MODERATE;3HIGH;4*EXTRME ) ' 2 <-- HEALTH 0 <- * F L AMMABIL1TY 0 <--REACT I V ITY <--SPCJAL SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE) IRRITANT FOR SKIN. LUNGS ANO EYES. CAN CAUSE BURNS OR SEVERE SAL 000009670 Cr S 7 48 (CONTINUED) COOL SHIELD SECTION V - HEALTH HAZARD DATA PAGE 03 IRRITATION. - CHRONIC - (LONG TERM EXPOSURE) LOCAL AREAS OF SUPERFICIAL DESTRUCTION OF THE SKIN OR OERMATITIS. INHALATION OF MIST MAY RESULT IN INCREASED SUSCEPTIBILITY TO RESPIRATORY ILLNESS OR VARYING DEGREES OF IRRITATION OF THE RESPIRATORY TRACT TISSUES. PRIMARY ROUTE OF ENTRY: <-- INHALATION <-- INGESTION X<-- ABSORPTION EMERGENCY A FIRST AID PROCEDURES INHALATION : OBJECT IS TO SEEK MEDICAL ATTENTION. GET PERSON OUT OF CONTAMINATED AREA TO FRESH AIR. IF BREATHING HAS STOPPED, ARTIFICIAL RESPIRATION SHOULD BE STARTED. OXYGEN MAV BE ADMINISTERED. IF AVAILABLE. SEEK MEDICAL ATTENTION IMMEDIATELY. EYE CONTACT: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOP 15 MINUTES HOLDING EYELIDS APART FOR MAXIMUM FLUSHING. SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. TREATMENT IS MOST EFFECTIVE IN THE FIRST MINUTE. SKIN CONTACT: WASH CONTAMINATED AREAS WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH BEFORE REUSE. SEEK MEDICAL ATTENTION IMMEDIATELY. IF IRRITATION OEVELOPS. 1 nuc) I iurj ; SEEK MEDICAL ATTENTION IMMEDIATELY. GIVE LARGE OUANTITIES OF WATER AND INDUCE VOMITING. KEEP AIR PASSAGES CLEAR. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SEEK MEDICAL ATTENTION IMMEDIATELY. N/A NOTES TO PHYSICIAN : SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: IARC < -- YES NTP <-- YES 05HA <--YES ACGIH <--YES OTHER <--YES X<--NO X<--NO x--no x<--no x<--nc SODIUM 2-MERCAPTOBENZOTHIAZOLE ORL-RAT L050: 5200MG/KG 1. SKN-RBT LD50: 5010MG/KG 1. EYE IRRITATION (RABBIT): (FHS*) CORROSIVE 1. SKIN IRRITATION (RABBIT): {FHSA) CORROSIVE 1. SECTION VII - REACTIVITY DATA STABILITY !x<--STABLE <--UNSTABL ! CONDIDTIONS TO AVOID i......................... ..................................................................... N/ (CONTINUED) COOL SHIELD SECTION VII - REACTIVITY DATA INCOMPATIBILITY (MATERIALS TO AVOID) REACTS VIGOROUSLY WITH STRONG OXIDIZERS SUCH AS HYDROPEROXIOESCONTACT WITH STRONG MINERAL ACIDS OR AGIO FUMES MAY LIBERATE HEAT HAZARDOUS DECOMPOSITION PRODUCTS 0XIDE5 OF CARBON, SULPHUR. NITROGEN MAY BE GIVEN OFF UPON THERMAL DECOMPOSITION. HAZARDOUS ! WILL NOT X <--OCCUR MAV ! CONDITIONS TO AVOID <--OCCUR \ POLYMERIZATION PAGE : 04 SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED STOP LEAKS. CONTAIN SPILL. REMOVE AS MUCH AS POSSIBLE. NEUTRALIZE REMAINING TRACES OF MATERIAL WITH DILUTED ACJO: THEN FLUSH AREA WITH WATER. REUSE SPILLED MATERIAL. IF POSSIBLE. OTHERWISE PLACE IN A CLOSED. LABELED CONTAINER ANO STORE IN A SAFE PLACE TO AWAIT PROPER DISPOSAL. WASTE OISPOSAL METHOD OISPOSE OF IN ACCORDANCE WITH ALL FEDERAL. STATE AND LOCAL REGULATIONS CONCERNING HEALTH AND POLLUTION. DISPOSE VIA APPROVED CHEMICAL WASTE DISPOSAL METHOO. IF REGULATIONS PERMIT. NEUTRALIZING AGENT NEUTRALIZE WITH ANY DILUTED INORGANIC ACID SUCH AS HYDROCHLORIC. SULFURIC. NITRIC, PHOSPHORIC OR ACETIC ACID. SECTION IX - SPECIAL PROTECTION INFORMATION REOUIRED VENTILATION MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE. RESPIRATORY PROTECTION USE MOSH APPROVED MASK IF MISTING OCCURS. PROTECTIVE GLOVES PVA GLOVES SHOULD BE WORN DEPENDING ON SEVERITY OF EXPOSURE- EYE PROTECTION GOGGLES SHOULD BE WORN DEPENDING ON SEVERITY OF EXPOSURE. OTHER PROTECTION APRON SHOUL0 BE WORN DEPENDING ON SEVERITY OF EXPOSURE. SAL 00009 672 COOL SHIELD SECTION X * STORAGE AND HANDLING INPORMATIRAOE : 09 /I ft M J ft 7 4........................ ............................................................... jr....................fcr 5 O STORAGE'TEMPERATURE" ! INDOOR 190 F.<--MAX 35 F.<--MIN { X jHEATEO "*!REFRIGERATED{ OUTDOOR j> 35 F. j | PRECAUTIONS TO 8E TAKEN IN HANDLING A STORING STORE AT MOOERATE TEMPERATURES. AVOID SKIN OR EYE CONTACT. OTHER PRECAUTIONS KEEP OUT OF REACH OF CHILDREN. READ AND FOLLOW ALL LABEL DIRECTIONS. STORE CNLY IN LABELED CONTAINER. SECTION XI REGULATORY INFORMATION CHEMICAL NAME C.A S NUMBER UPPER % LIMIT N/A THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TD THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHOR 12AT I ON ACT OF 1986 AND 40 CFR PART 372. IF UE (USE EXEMPTIONS APPEARS UNDER UPPER X LIMIT. ENO USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PROOUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK, OR THE PROOUCT IS USED ANO LABELED FOR FACILITY GROUNDS MAINTENANCE (SU<bH AS FERTILIZERS AND HERBICIDES). OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <-- IMCO SHIPPING NAME HAZARD CLASS LABELS UNIT CONTAINER DOT SPS CONTAINER <--TARJFF 6 0 <-- IATA <--MILITARY AIR (AFR 71-4) | 10 NUMBER j REPORT QTY | LIMITED QTY | NET EXPLOSIVE WT. (CONTINUED) COOL SHIELD SECTION XII - TRANSPORTATION (FOR FUTURE USE) AEROSOL PROPELLANT(S) SECTION XIII - REFERENCES 1. RAW MATERIAL VENDOR'5 MATERIAL. SAFETY DATA SHEET. PAGE : 06 THE INFORMATION CONTAINED HEREIN IS BASED CN DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER. NO WARRANTY IS EXPRESSED CR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH 01V. OF NCH CORP. ASSUMES NO RESPONSIBILITY FOR PER50KAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PROOUCT IN A MANNER NOT RECOMMENDED ON THE PROOUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. OR DISPOSAL OF THE PROOUCT. S4L 00967a MATERIAL SAFETY DATA SHEET BRAKE JOB AEROSOL <BT> PAGE : 01 (OO6339-0157P -0021638-5074 )]DATE OF ISSUE { 09/11/8* SUPERSEDES 09/01/89 I SECTION 1 - GENERAL INFORMATION CHEMICAL NAME 8 SYNONYMS N/A TRADE NAME SYNONYMS BRAKE JOB AEROSOL <BT) CHEMICAL FAMILY AEROSOL CHLORINATEO SOLVENT CLEANER FORMULA < -- MIXTURE MANUFACTURERS NAME: NATIONAL CHEMSEARCH DIV. OF NCH CORP ADDRESS (NUMBER. STREET. CITY. STATE & ZIP CODE) BOX 152170 IRVING. TEXAS 75015 PREPARED BY: KEVIN UHL/T-S- CHEMIST [ PROOUCT CODE NUMBER 1 EMERGENCY TELEPHONE NUMBER 5074 214-438- 1381 SECTION 11- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTED AS A WHOLE. CHEMICAL NAME (INGREDIENTS) 1.1. 1-TRICHLOROETHANE CARBON 0 I OXIDE ! HAZARD | TLV* IRRITANT 350PPM ASPHYXIANT 50OQPPM j PEL* 3SOPPM lO.OOOPPM ! CASA 71-55-6 124-30-9 SECTION iii - PHYSICAL DATA BOILING PT. (FAHRENHEIT) ! 162 VAPOR PRESSURE (MM HG). ! to.o !! SPEC GRAVITY (H20-1) |! COLOR {WATER white : 1.29B (CONTINUED) VAPOR DENSITY (AIR-1) PH * 10054 PERCENT. VOLATILE BY VOLUME <*A) SOLUBILITY IN WATER VISCOSITY BRAKE JOB AEROSOL SECTION III - PHYSICAL DATA <BT) {4.6 { ODOR {CHLOR. HYDROCARBON i N/A i CLARITY {TRANSPARENT lOO J EVAPORATION RATE !o.75 { <60 AC - 1 1 ! ; NEGLIGIBLE i NON VISCOUS PAGE : 02 SECTION IV - FIRE AND EXPLOSION HAZARD FLASH POINT (METHOD USED) NON-FLAMC.0.C . EXTINGUISHING MEDIA ALCOHOL" <-- FOAM < - -FOAM { FLAMMABLE LIMITS i <--C02 DRV <--CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES POSITIVE PRESSURE SELF-CONTAINED RESPIRATORY EQUIPMENT. [6%-25 C. WATER < - -SPRAY ! UEL |16.7%-25 C X<--OTHER UNUSUAL FIRE 6 EXPLOSION HAZARDS CAN FORM PHOSGENE UNDER CERTAIN CONDITIONS OF HIGH HEAT. LEVEL 1 AEROSOL (NFPA 30B> NFPA HAZARD RATING <O*1 NS IGNIFICANT; 1 -SL1GHT;2-MCDESATE;3-HIGH.4.EXTREME) 3 < -- HE At TH O <--FlAMMABILITY O <--REACTJVITV <--Se'EClAL SECTION V - HEALTH HAZARC DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION II EFFECTS OF OVEREXPOSURE - ACUTE - (SHORT TERM EXPOSURE) INHALATION: OVEREXPOSURE CAN CAUSE DIZZINESS. DRUNKENNESS. DROWSINESS, UNCONSCIOUSNESS AND EVEN DEATH AT EXTREME OOiES. SKIN CONTACT/ABSORPTION: ABSORPTION THROUGH SKIN IS NOT A SIGNIFICANT ROUTE OF EXPOSURE - MILDLY IRRITATING ON CONTACT. SAL 0009673 G S 09 5 (CONTINUED) BRAKfc JQfc tCKt'iUL SECTION V - HEALTH HAZARD DATA PAGE : 03 INGisflON: UNLIKELY ROUTE OF EXPOSURE. iNGEsHoN*OF*SMALL'oUANTITIE5~is~ NOT LIKELY TO BE TOXIC. ALSO UNLIKELY BECAUSE IT BEING AN AEROSOL. EYES: MILD IRRITATION. BUT NO CORNEAL INJURY LIKELY. - CHRONIC - (LONS TERM EXPOSURE INHALATION: MAJOR ROUTE OF EXPOSURE LOW SYSTEMIC TOXICITY: ACUT EXPOSURES IN THE 10O0 PPM RANGE CAUSE NARCOSIS. SKIN CONTACT/ABSORPTIONt PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE DERMATITIS THROUGH DEFATTING OF SKIN. EYES: MAY CAUSE CONJUNCTIVITIS. PRIMARY ROUTE OF ENTRY: X<-- INHALATION <-- INGESTION X<-- ABSORPTION EMERGENCY A FIRST AID PROCEDURES INHALATION REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED. CR OXYGEN IF AVAILABLE. ADMINISTERED RESPIRATION EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. HOLD I NS EYELIDS APART TC ENSURE FLUSHING OF THE ENTIRE EVE SURFACE. SEEK MEDICAL ATTENTION IMMEDIATELY. 5KIN CONTACT: REMOVE CONTAMINATED CLOTHING ANO FLUSH EXPOSED AREAS WITH WATER FOR 5 TO 15 MINUTES. INGESTION : DO NOT INOUCE VOMITING. CALL A PHYSICIAN AND OBTAIN MEDICAL ATTENTION. NOTES TO PHYSICIAN : BECAUSE RAPID ABSORPTION MAY OCCUR THROUGH LUNGS. THE DECISION OF WHETHER TO INOUCE VOMITING OR NOT SHOULD BE MADE BY A PHYSICIAN. IF LAVAGE IS PERFORMED. SUGGEST ENDOTRACHEAL AND/OR ESOPHAGEAL CONTROL. DANGER MUST BE WEIGHED AGAINST TOXICITY. NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT BASED ON JUDGEMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT. SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: IARC <--YES NTP <-- YES OSHA <--YES ACGIH <--YES OTHER <--YES X < -- NO X <--NC X<--NO X<--ND X<--NO 1.1. 1 * TRICHLOROETHANE ORL-RAT LD50 > lO.OOOMG/KG SKN-RBT LD50 > 15.OOOMG/KG EYE-MAN: 450 PPM/BH 2. ORL-HMN TDLO: 670MG/KG 2. 1. 1. SECTION VII - REACTIVITY DATA (CONTINUED) BRAKE JOB AEROSOL SECTION VII - REACTIVITY DATA (BT) PAGE : 04 STABILITY {X<--STABLE <--UNSTABL CONOIDTIONS TO AVOID ---------------------------------------- ------------- ------------------------------------------------------ ------------------------------------- -- ----------- AVOID OPEN FLAMES. WELDING ARCS. OR OTHER HIGH TEMPERATURE SOURCES WHICH INDUCE THERMAL DECOMPOSITION. INCOMPATIBILITY (MATERIALS TO AVOID) N/A HAZARDOUS DECOMPOSITION PRODUCTS HYDROGEN CHLORIDE ANO VERY SMALL AMOUNTS OF PHOSGENE AND CHLORINE. HAZARDOUS WILL NOT X < -OCCUR POLYMERIZATION N/A MAY ! CONDITIONS TO AVOIO <--OCCUR , SECTION VIU - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED SPILL UNLIKELY. THE PRODUCT IS IN AN AEROSOL FORM. SMALL LEAKS: MOP UP. WIPE UP. OR SOAK UP IMMEDIATELY. OUT-OF-DOORS. LARGE SPILLS: EVACUATE AREA. CONTAIN LIQUID; TRANSFER METAL CONTAINERS. KEEP OUT OF WATER SUPPLY. REMOVE TO TO CLOSEO WASTE DISPOSAL METHOO (IN ORDER OF PREFERENCE) SENO SOLVENT TO LICENSED RECLAIMER, INCINERATE. EVAPORATE VERY SMALL OUANTITITES. OR SEND TO APPROVED LANDFILL BURIAL IN COMPLIANCE WITH LOCAL. STATE AND FEOERAL REGULATIONS. DUMPING INTO SEWERS. ON THE GROUND. OR INTO ANY BODY OF WATER IS STRONGLY OISCOURAGEO AND MAY BE ILLEGAL. NEUTRALIZING AGENT N/A SECTION IX - SPECIAL PROTECTION INFORMATION REOUIRED VENTILATION SUFFICIENT VENTILATION TO BE EQUAL TO OR BELOW THE ALLOWABLE CONCENTRATION. RESPIRATORY PROTECTION ............................................................. ... TYPICAL USE OF PRODUCT OOES NOT REOUIRE THE USE OF A RESPIRATOR. PRODUCT IS MISTED, USE NtOSH APPROVED MASK FOR SPRAY MI5TS. IN EMERGENCY SITUATIONS, THE FOLLOWING RESPIRATORS ARE RECOMMENDED: 5O0PPM: CCR0V7SA/$CeA tOOOPRM: CCROVF/GMOV/SAF/SCBAF ESCAPE: GMOV/SCBA IF SAL 000009674 (CONTINUED) BRAKE JOB AEROSOL (BT) (j ) O SECTION XX - SPECIAL PROTECTION INFORMAT10PAGE : OS PROTECTIVE GLOVES VITON, PVAL GLOVES IF REPEATED OR PROLONGED SKIN CONTACT 1$ ANTICIPATED. EVE PROTECTION CHEMICAL GOGGLES IF METHOD OF USE PRESENTS THE LIKELIHOOD OF EYE CONTACT. OTHER PROTECTION N/A O SECTION X - STORAGE AND HANDLING INFORMATION STORAGE TEMPERATURE | INDOCR 120 F.<MAX 32 F.<--KIN | X ]HEATED \ PRECAUTIONS TO BE TAKEN IN HANO LI NS S STORING AVOID BREATHING VAPORS. STORE IK COOL. DRY PLACE. VAPORS ARE HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS. 00 NOT ENTER THESE AREAS WHERE VAPORS ARE SUSPECTED. DC NOT USE WITH POWDERED ZINC OR ALUMINUM. OTHER PRECAUTIONS ALWAYS FOLLOW LABEL DIRECTIONS. REACH OF CHILDREN. KEEP OUT OF 1 REFRIGERATED! OUTDOOR \\ SECTION XI - REGULATORY INFORMATION CHEMICAL NAME C.A.S. NUMBER UPPER % LIMIT 1.1.1-TRICHLOROETHAfcE 71-55-6 >50 THOSE INGREDIENTS LISTEC ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPEHFUNC AMENDMENTS AND REAUTHOR IZAT I ON ACT OF 1986 ANO 40 CFR ART 372. IF UE (USE EXEMPTION > APPEARS UNOER UPPER X LIMIT. ENO USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK. OR THE PRODUCT IS USED AND LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS ANC HERBICIDES), OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES. SECTION XII - TRANSPORTATION - (FOR FUTURE USE) (CONTINUED) BRAKE JOB AEROSOL (BT) SECTION XII - TRANSPORTATION (FOR FUTURE USE) PAGE : 06 APPLICABLE REGULATIONS <--49 CFR -IMCO SHIPPING NAME <-TARIFF 6 D <-- IATA <--MILITARY AIR (AFR 71-4) HAZARD CLASS 1 10 NUMBER ] REPORT OTY LA8ELS UNIT CONTAINER ! LIMITED OTY OOT SPS CONTAINER j NET EXPLOSIVE WT. AEROSOL PROPELLANT(S) SECTION XIII - REFERENCES 1. 23.. INDUSTRIAL HYGIENE 6 TOXICOLOGY. 3RD EDITION. F.A. PATTY 1981 CHEMICAL REGULATION REPORT. NIOSH REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES, 1982. 4 . DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS. 6TH EDITION N. IRVING SAX. 5 . THRESHOLD LIMIT VALUE FOR CHEMICAL SUBSTANCES IN THE WORK ENVIRONMENT. 2ND EDITION. ACGIH, 1985. THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT Cf CURRENT FORMULATION HOWEVER NC WARRANTY IS EXPRESSED CR IMPLIED REGARDING THE ACCURACY OF THIS DATA DR THE RESULTS TC BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. CF NCH CDRP. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY CR PROPERTY DAMAGE CAUSED EV THE USE . STORAGE CR DISPOSAL OF THE ROOUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS A 5S0CIATED WITH SUCH UNRECOMMENDED USE. STORAGE. DR OISPCSAl OF THE PRODUCT. SAL 000009675